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Crystals of VOSO4.6H2O were grown from aqueous solution at 0°C and studied below 13°C. The compound is triclinic with lattice parameters a = 7.49±0.03, b = 10.17± 0.04, c = 6.185±0.025 Å, α = 101.7±0.3, β = 95.6±0.3, β = 92.2±0.3°.
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