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The structure of the ordered form of the partially ordered cubic: α-Ga2Se3 is based on a tetragonal, body-centred cell, with space group I41/acd, a = 23.235 (5), c = 10.828 (2) Å, Z = 48, Dm = 4.91 g cm−3 at 30°C. Diffractometer data up to θ ~ 80° from Cu Kα radiation are given for the β phase with nominal composition Ga2Se3.03.
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