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The tetrapolyphosphate (NH4)2GeP4O13 is triclinic (P{\bar 1}), with a unit cell: a = 15.08 (1), b = 7.763 (5), c = 4.914 (5) Å, β = 98.18 (1), β = 96.53 (1), γ = 84.04 (1)° and Z = 2. This salt is isotypic with the corresponding salt of silicon: (NH4)2SiP4O13, previously described by the author.
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