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Methylammonium manganese(II) trichloride dihydrate crystallizes with a monoclinic unit cell, a = 7.795 (2), b = 9.154 (2), c = 11.462 (4) Å, β = 91.28 (3)°, space group P21/c. Its structure is related to that of α-RbMnCl3.2H2O.
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