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InH(SO4)2.4H2O is orthorhombic, space group Pna21 or Pnam; the cell dimensions are a = 9.997 (3), b = 5.477 (2), c = 18.443 (10) Å (Z = 4). The compounds in the series MIIIH(SO4)2.4H2O (M = Al, Ga, Tl, V, Fe Ti) are isotypic. Crystal parameters and powder diffraction data are given.
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