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(-)-[Rh(en)3Br3.H2O is isomorphic with cobalt salts (+)-[Co(en)3Br3.H2O and (+)-[Co(en)3]Cl3.H2O. It crystallizes in the quadratic space group P4321. Lattice constants are a = 10.070 (2) and c= 16.688 (5) Å with four formula units in the unit cell.
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