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Compounds of the formula KLiMS2, where M is one of the divalent transition elements Zn, Mn or Fe, belong to the tetragonal crystal system. They are not, however, isomorphous. KLiZnS2: P, a = 6.600(5), c = 15.570(5) Å; KLiMnS2: P, a = 6.800(5), c = 11.055(5) Å; KLiFeS2: I, a = 3.840(5), c = 13.270(5) Å. X-ray powder diffraction data for all three compounds are given. The JCPDS Diffraction File Nos. for these compounds are: KLiZnS2 33-1494; KLiMnS2 33-1493; KLiFeS2 33-1492.
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