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Bis(monomethylammonium) tetrabromomercurate, (CH3NH3)2HgBr4, 2CH6N+.Hg2+.4Br, is monoclinic, space group P21/c. Unit-cell dimensions are: a = 7.979(4), b = 13.351(4), c = 11.289(4) Å, β = 96.36(2)°, Z = 4, Dm = 3.25, Dx = 3.24 Mgm−3. The compound undergoes a phase transition at low temperature. The JCPDS Diffraction File No. of this compound is 33-1997.
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