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The α-phase structure of the title compound, C6H4Cl2, has been accurately redetermined at room temperature. Comparison with 100 K data shows that all different shortest intermolecular contacts (Cl...Cl, Cl...C, Cl...H, C...C, C...H, H...H) undergo thermal expansion. A three-centred hydrogen-bonding geometry is considered for some Cl...H contacts.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock pdcb

fcf

Structure factor file (CIF format)
Contains datablock pdcb

CCDC reference: 129368

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