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In the title compound, {2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]diphenolato-O,N,N',O'}nitridochromium(V) nitromethane solvate, [Cr(N)(C16H14N2O2)].CH3NO2, the metal center is five-coordinated. The chromium-nitride bond length is 1.559 (2) Å, which is 0.04 Å longer than in the analogous manganese(V) compound. The structure contains a co-crystallized nitromethane molecule. In line with its accepted weak-donor properties, this solvent molecule does not interact with the coordinatively unsaturated metal center.

Supporting information


Crystallographic Information File (CIF)
Contains datablocks global, p76be1


Structure factor file (CIF format)
Contains datablock p76be1

CCDC reference: 130147

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