(μ-4,4′-Bipyridine-κ²N:N′)bis­[(1,10-phenanthroline-κ²N,N′)(triphenyl­phosphine-κP)copper(I)] bis­(tetra­fluoro­borate)

The dinuclear cation in the title compound, [Cu₂(C₁₀H₈N₂)(C₁₂H₈N₂)₂(C₁₈H₁₅P)₂](BF₄)₂, lies on a centre of inversion. Each Cu^I atom is coordinated by 1,10-phenanthroline, triphenyl­phosphine and a bridging 4,4′-bipyridine mol­ecule, and has a distorted tetra­hedral coordination geometry. The two Cu^I atoms are displaced by 0.32 (1) Å on either side of the mean plane of the 4,4′-bipyridine unit.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.008 Å
• R factor = 0.058
• wR factor = 0.163
• Data-to-parameter ratio = 16.1

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.65 Ratio
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Cu1    -   P1      ..       5.96 su
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C3
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C15
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         B1
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...          8
PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of .      31.00 A   3 

Alert level G
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   7 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.

(µ-4,4'-Bipyridine-κ²N:N')bis[(1,10-phenanthroline- κ²N,N')(triphenylphosphine-κP)copper(I)] bis(tetrafluoroborate)

Crystal data

[Cu2(C10H8N2)(C12H8N2)2(C18H15P)2](BF4)2	F(000) = 1372
Mr = 1341.83	Dx = 1.409 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 885 reflections
a = 14.192 (7) Å	θ = 2.4–22.2°
b = 15.372 (7) Å	µ = 0.79 mm^−1
c = 14.515 (6) Å	T = 293 K
β = 92.495 (9)°	Block, brown
V = 3164 (2) Å^3	0.26 × 0.20 × 0.16 mm
Z = 2

Data collection

Bruker SMART CCD diffractometer	6518 independent reflections
Radiation source: fine-focus sealed tube	3572 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.058
φ and ω scans	θmax = 26.5°, θmin = 1.9°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −17→17
Tmin = 0.850, Tmax = 0.880	k = −19→17
17926 measured reflections	l = −13→18

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.058	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.163	H-atom parameters constrained
S = 1.00	w = 1/[σ^2(Fo^2) + (0.0746P)^2 + 1.4838P] where P = (Fo^2 + 2Fc^2)/3
6518 reflections	(Δ/σ)max = 0.003
406 parameters	Δρmax = 0.78 e Å^−3
0 restraints	Δρmin = −0.39 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Cu1	0.84510 (4)	0.18547 (3)	0.61886 (4)	0.04451 (19)
P1	0.72864 (8)	0.22427 (7)	0.70523 (8)	0.0441 (3)
N1	0.8246 (3)	0.0785 (2)	0.5380 (2)	0.0473 (9)
N2	0.9533 (2)	0.1068 (2)	0.6760 (3)	0.0476 (9)
N3	0.9052 (2)	0.2946 (2)	0.5637 (2)	0.0450 (9)
C1	0.7596 (4)	0.0646 (4)	0.4717 (3)	0.0728 (15)
H1	0.7193	0.1099	0.4540	0.087*
C2	0.7492 (5)	−0.0153 (5)	0.4275 (4)	0.100 (2)
H2	0.7021	−0.0232	0.3816	0.120*
C3	0.8075 (6)	−0.0809 (5)	0.4515 (5)	0.105 (3)
H3	0.8009	−0.1341	0.4214	0.126*
C4	0.8776 (4)	−0.0708 (3)	0.5206 (4)	0.0724 (17)
C5	0.9435 (6)	−0.1358 (4)	0.5506 (6)	0.101 (3)
H5	0.9400	−0.1904	0.5232	0.121*
C6	1.0094 (5)	−0.1214 (4)	0.6157 (6)	0.102 (3)
H6	1.0526	−0.1650	0.6314	0.122*
C7	1.0151 (4)	−0.0401 (4)	0.6622 (4)	0.0723 (17)
C8	1.0805 (4)	−0.0218 (5)	0.7342 (5)	0.096 (2)
H8	1.1232	−0.0643	0.7544	0.115*
C9	1.0820 (4)	0.0568 (6)	0.7743 (5)	0.093 (2)
H9	1.1255	0.0690	0.8223	0.111*
C10	1.0175 (3)	0.1202 (4)	0.7432 (4)	0.0670 (14)
H10	1.0199	0.1746	0.7712	0.080*
C11	0.9512 (3)	0.0266 (3)	0.6350 (3)	0.0503 (12)
C12	0.8824 (3)	0.0113 (3)	0.5629 (3)	0.0497 (12)
C13	0.9869 (3)	0.3240 (3)	0.5990 (4)	0.0569 (12)
H13	1.0198	0.2894	0.6420	0.068*
C14	1.0258 (3)	0.4027 (3)	0.5758 (3)	0.0540 (12)
H14	1.0837	0.4193	0.6027	0.065*
C15	0.9799 (3)	0.4567 (2)	0.5133 (3)	0.0396 (10)
C16	0.8957 (3)	0.4258 (3)	0.4763 (3)	0.0650 (14)
H16	0.8615	0.4589	0.4329	0.078*
C17	0.8615 (4)	0.3457 (3)	0.5029 (4)	0.0656 (14)
H17	0.8043	0.3269	0.4763	0.079*
C18	0.6229 (3)	0.1576 (3)	0.7100 (3)	0.0509 (11)
C19	0.6280 (4)	0.0705 (3)	0.6881 (4)	0.0690 (14)
H19	0.6838	0.0473	0.6675	0.083*
C20	0.5499 (5)	0.0174 (4)	0.6968 (5)	0.100 (2)
H20	0.5539	−0.0417	0.6834	0.120*
C21	0.4681 (5)	0.0510 (5)	0.7246 (5)	0.102 (2)
H21	0.4161	0.0149	0.7304	0.123*
C22	0.4611 (4)	0.1373 (5)	0.7442 (4)	0.092 (2)
H22	0.4041	0.1600	0.7625	0.111*
C23	0.5376 (3)	0.1908 (4)	0.7370 (4)	0.0701 (15)
H23	0.5322	0.2497	0.7503	0.084*
C24	0.7702 (3)	0.2359 (3)	0.8251 (3)	0.0494 (11)
C25	0.7269 (4)	0.1995 (3)	0.8988 (4)	0.0644 (14)
H25	0.6687	0.1722	0.8900	0.077*
C26	0.7705 (5)	0.2034 (4)	0.9870 (4)	0.0865 (19)
H26	0.7412	0.1778	1.0362	0.104*
C27	0.8534 (5)	0.2434 (4)	1.0018 (5)	0.093 (2)
H27	0.8806	0.2466	1.0612	0.112*
C28	0.8985 (5)	0.2798 (4)	0.9293 (5)	0.0874 (18)
H28	0.9564	0.3074	0.9393	0.105*
C29	0.8576 (4)	0.2751 (3)	0.8421 (4)	0.0675 (14)
H29	0.8890	0.2987	0.7931	0.081*
C30	0.6806 (3)	0.3289 (3)	0.6666 (3)	0.0474 (11)
C31	0.7023 (3)	0.4066 (3)	0.7095 (3)	0.0579 (12)
H31	0.7368	0.4066	0.7654	0.069*
C32	0.6733 (4)	0.4851 (3)	0.6703 (5)	0.0768 (16)
H32	0.6882	0.5373	0.6999	0.092*
C33	0.6228 (4)	0.4855 (4)	0.5883 (5)	0.0854 (18)
H33	0.6040	0.5379	0.5614	0.102*
C34	0.5998 (4)	0.4083 (5)	0.5454 (5)	0.0907 (19)
H34	0.5643	0.4084	0.4900	0.109*
C35	0.6292 (4)	0.3308 (3)	0.5845 (4)	0.0736 (15)
H35	0.6140	0.2788	0.5547	0.088*
B1	0.6996 (5)	0.2007 (5)	0.2675 (6)	0.080 (2)
F1	0.6244 (4)	0.1931 (4)	0.3168 (4)	0.194 (3)
F2	0.7778 (4)	0.2170 (3)	0.3161 (4)	0.159 (2)
F3	0.7113 (3)	0.1178 (3)	0.2326 (4)	0.1578 (19)
F4	0.6833 (3)	0.2545 (2)	0.1956 (2)	0.1069 (12)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.0474 (3)	0.0311 (3)	0.0552 (4)	−0.0012 (2)	0.0047 (2)	0.0003 (2)
P1	0.0461 (7)	0.0335 (6)	0.0530 (7)	−0.0005 (5)	0.0065 (5)	−0.0021 (5)
N1	0.054 (2)	0.044 (2)	0.044 (2)	−0.0073 (18)	0.0078 (18)	−0.0001 (17)
N2	0.040 (2)	0.050 (2)	0.053 (2)	−0.0025 (17)	0.0028 (18)	0.0078 (18)
N3	0.044 (2)	0.035 (2)	0.056 (2)	−0.0041 (16)	0.0059 (18)	0.0051 (16)
C1	0.082 (4)	0.079 (4)	0.057 (3)	−0.023 (3)	−0.003 (3)	−0.001 (3)
C2	0.129 (6)	0.102 (5)	0.067 (4)	−0.047 (5)	−0.005 (4)	−0.028 (4)
C3	0.159 (8)	0.068 (4)	0.091 (5)	−0.061 (5)	0.052 (5)	−0.038 (4)
C4	0.102 (5)	0.037 (3)	0.081 (4)	−0.022 (3)	0.047 (4)	−0.012 (3)
C5	0.144 (7)	0.026 (3)	0.140 (7)	0.009 (4)	0.097 (6)	0.005 (4)
C6	0.101 (6)	0.056 (4)	0.155 (8)	0.032 (4)	0.086 (5)	0.041 (5)
C7	0.068 (4)	0.061 (4)	0.091 (4)	0.022 (3)	0.041 (3)	0.032 (3)
C8	0.063 (4)	0.116 (6)	0.111 (6)	0.031 (4)	0.023 (4)	0.056 (5)
C9	0.051 (4)	0.142 (7)	0.084 (5)	0.013 (4)	−0.010 (3)	0.035 (5)
C10	0.047 (3)	0.083 (4)	0.071 (4)	−0.004 (3)	0.000 (3)	0.012 (3)
C11	0.051 (3)	0.037 (3)	0.065 (3)	0.006 (2)	0.026 (2)	0.016 (2)
C12	0.061 (3)	0.033 (2)	0.057 (3)	−0.006 (2)	0.028 (2)	0.002 (2)
C13	0.051 (3)	0.039 (3)	0.080 (3)	0.001 (2)	−0.007 (2)	0.013 (2)
C14	0.047 (3)	0.041 (3)	0.073 (3)	−0.009 (2)	−0.010 (2)	0.008 (2)
C15	0.041 (2)	0.035 (2)	0.043 (2)	−0.0015 (18)	0.006 (2)	0.0012 (19)
C16	0.059 (3)	0.058 (3)	0.076 (3)	−0.020 (2)	−0.019 (3)	0.031 (3)
C17	0.059 (3)	0.059 (3)	0.077 (4)	−0.022 (3)	−0.015 (3)	0.014 (3)
C18	0.052 (3)	0.045 (3)	0.055 (3)	−0.007 (2)	0.001 (2)	0.003 (2)
C19	0.063 (3)	0.050 (3)	0.094 (4)	−0.008 (3)	0.001 (3)	0.007 (3)
C20	0.080 (5)	0.057 (4)	0.162 (7)	−0.024 (3)	−0.014 (4)	0.023 (4)
C21	0.071 (5)	0.101 (6)	0.132 (6)	−0.040 (4)	−0.023 (4)	0.049 (5)
C22	0.055 (4)	0.128 (6)	0.095 (5)	−0.004 (4)	0.014 (3)	0.035 (4)
C23	0.055 (3)	0.071 (4)	0.086 (4)	0.001 (3)	0.021 (3)	0.002 (3)
C24	0.056 (3)	0.040 (3)	0.053 (3)	0.009 (2)	0.003 (2)	−0.007 (2)
C25	0.066 (3)	0.065 (3)	0.062 (3)	0.008 (3)	0.008 (3)	0.003 (3)
C26	0.125 (6)	0.079 (4)	0.056 (4)	0.022 (4)	0.007 (4)	0.002 (3)
C27	0.108 (5)	0.093 (5)	0.075 (5)	0.021 (4)	−0.033 (4)	−0.027 (4)
C28	0.087 (4)	0.088 (4)	0.086 (5)	−0.002 (4)	−0.013 (4)	−0.017 (4)
C29	0.070 (4)	0.068 (3)	0.064 (4)	−0.006 (3)	−0.002 (3)	−0.009 (3)
C30	0.046 (3)	0.040 (3)	0.057 (3)	0.0036 (19)	0.006 (2)	0.003 (2)
C31	0.066 (3)	0.043 (3)	0.065 (3)	0.006 (2)	0.001 (3)	0.002 (2)
C32	0.080 (4)	0.040 (3)	0.111 (5)	0.007 (3)	0.010 (4)	0.004 (3)
C33	0.077 (4)	0.064 (4)	0.116 (5)	0.019 (3)	0.013 (4)	0.034 (4)
C34	0.087 (4)	0.092 (5)	0.091 (5)	0.014 (4)	−0.015 (4)	0.022 (4)
C35	0.083 (4)	0.059 (3)	0.078 (4)	0.011 (3)	−0.014 (3)	0.008 (3)
B1	0.065 (4)	0.086 (6)	0.089 (5)	0.021 (4)	−0.002 (4)	0.025 (4)
F1	0.142 (4)	0.269 (7)	0.176 (5)	0.088 (4)	0.069 (4)	0.135 (5)
F2	0.148 (4)	0.134 (4)	0.186 (5)	−0.038 (3)	−0.088 (4)	0.028 (3)
F3	0.149 (4)	0.106 (4)	0.214 (5)	0.014 (3)	−0.047 (4)	0.011 (3)
F4	0.106 (3)	0.112 (3)	0.103 (3)	0.028 (2)	0.011 (2)	0.049 (2)

Geometric parameters (Å, º)

Cu1—N1	2.033 (4)	C16—H16	0.930
Cu1—N3	2.060 (3)	C17—H17	0.930
Cu1—N2	2.096 (4)	C18—C19	1.379 (6)
Cu1—P1	2.1999 (14)	C18—C23	1.386 (6)
P1—C24	1.822 (5)	C19—C20	1.387 (7)
P1—C18	1.821 (5)	C19—H19	0.930
P1—C30	1.826 (4)	C20—C21	1.347 (9)
N1—C1	1.322 (6)	C20—H20	0.930
N1—C12	1.358 (5)	C21—C22	1.362 (9)
N2—C10	1.322 (6)	C21—H21	0.9300
N2—C11	1.369 (6)	C22—C23	1.369 (8)
N3—C17	1.316 (6)	C22—H22	0.930
N3—C13	1.325 (5)	C23—H23	0.930
C1—C2	1.391 (8)	C24—C25	1.375 (6)
C1—H1	0.930	C24—C29	1.391 (7)
C2—C3	1.340 (10)	C25—C26	1.398 (8)
C2—H2	0.930	C25—H25	0.930
C3—C4	1.391 (9)	C26—C27	1.338 (9)
C3—H3	0.930	C26—H26	0.930
C4—C12	1.405 (6)	C27—C28	1.374 (9)
C4—C5	1.423 (9)	C27—H27	0.930
C5—C6	1.319 (9)	C28—C29	1.372 (8)
C5—H5	0.930	C28—H28	0.930
C6—C7	1.420 (9)	C29—H29	0.930
C6—H6	0.930	C30—C35	1.370 (7)
C7—C8	1.395 (9)	C30—C31	1.376 (6)
C7—C11	1.414 (6)	C31—C32	1.389 (7)
C8—C9	1.341 (9)	C31—H31	0.930
C8—H8	0.930	C32—C33	1.362 (8)
C9—C10	1.398 (8)	C32—H32	0.930
C9—H9	0.930	C33—C34	1.372 (8)
C10—H10	0.930	C33—H33	0.930
C11—C12	1.420 (6)	C34—C35	1.377 (7)
C13—C14	1.378 (6)	C34—H34	0.930
C13—H13	0.930	C35—H35	0.930
C14—C15	1.373 (6)	B1—F2	1.313 (8)
C14—H14	0.930	B1—F1	1.317 (8)
C15—C16	1.374 (6)	B1—F4	1.344 (7)
C15—C15^i	1.504 (8)	B1—F3	1.383 (9)
C16—C17	1.385 (6)
N1—Cu1—N3	119.04 (14)	C15—C16—C17	120.5 (4)
N1—Cu1—N2	81.13 (15)	C15—C16—H16	119.7
N3—Cu1—N2	108.35 (14)	C17—C16—H16	119.7
N1—Cu1—P1	117.14 (10)	N3—C17—C16	123.8 (5)
N3—Cu1—P1	109.56 (10)	N3—C17—H17	118.1
N2—Cu1—P1	119.09 (11)	C16—C17—H17	118.1
C24—P1—C18	104.6 (2)	C19—C18—C23	118.5 (5)
C24—P1—C30	107.9 (2)	C19—C18—P1	119.1 (4)
C18—P1—C30	102.2 (2)	C23—C18—P1	122.4 (4)
C24—P1—Cu1	110.55 (15)	C18—C19—C20	120.1 (5)
C18—P1—Cu1	120.67 (16)	C18—C19—H19	120.0
C30—P1—Cu1	110.08 (15)	C20—C19—H19	120.0
C1—N1—C12	117.7 (4)	C21—C20—C19	120.2 (6)
C1—N1—Cu1	129.0 (4)	C21—C20—H20	119.9
C12—N1—Cu1	113.1 (3)	C19—C20—H20	119.9
C10—N2—C11	117.5 (4)	C20—C21—C22	120.5 (6)
C10—N2—Cu1	132.2 (3)	C20—C21—H21	119.7
C11—N2—Cu1	110.3 (3)	C22—C21—H21	119.7
C17—N3—C13	115.8 (4)	C21—C22—C23	120.3 (6)
C17—N3—Cu1	123.7 (3)	C21—C22—H22	119.9
C13—N3—Cu1	119.8 (3)	C23—C22—H22	119.9
N1—C1—C2	122.4 (6)	C22—C23—C18	120.4 (5)
N1—C1—H1	118.8	C22—C23—H23	119.8
C2—C1—H1	118.8	C18—C23—H23	119.8
C3—C2—C1	119.5 (6)	C25—C24—C29	117.6 (5)
C3—C2—H2	120.3	C25—C24—P1	124.5 (4)
C1—C2—H2	120.3	C29—C24—P1	117.4 (4)
C2—C3—C4	121.2 (6)	C24—C25—C26	119.9 (5)
C2—C3—H3	119.4	C24—C25—H25	120.0
C4—C3—H3	119.4	C26—C25—H25	120.0
C3—C4—C12	115.8 (6)	C27—C26—C25	121.3 (6)
C3—C4—C5	125.7 (6)	C27—C26—H26	119.4
C12—C4—C5	118.6 (6)	C25—C26—H26	119.4
C6—C5—C4	122.5 (7)	C26—C27—C28	120.0 (6)
C6—C5—H5	118.7	C26—C27—H27	120.0
C4—C5—H5	118.7	C28—C27—H27	120.0
C5—C6—C7	120.8 (7)	C29—C28—C27	119.5 (6)
C5—C6—H6	119.6	C29—C28—H28	120.2
C7—C6—H6	119.6	C27—C28—H28	120.2
C8—C7—C11	117.4 (6)	C28—C29—C24	121.7 (6)
C8—C7—C6	123.7 (6)	C28—C29—H29	119.2
C11—C7—C6	118.9 (6)	C24—C29—H29	119.2
C9—C8—C7	120.3 (6)	C35—C30—C31	118.3 (4)
C9—C8—H8	119.9	C35—C30—P1	117.6 (4)
C7—C8—H8	119.9	C31—C30—P1	123.6 (4)
C8—C9—C10	119.4 (6)	C30—C31—C32	120.9 (5)
C8—C9—H9	120.3	C30—C31—H31	119.6
C10—C9—H9	120.3	C32—C31—H31	119.6
N2—C10—C9	123.4 (6)	C33—C32—C31	119.8 (5)
N2—C10—H10	118.3	C33—C32—H32	120.1
C9—C10—H10	118.3	C31—C32—H32	120.1
N2—C11—C7	122.1 (5)	C32—C33—C34	119.9 (5)
N2—C11—C12	118.0 (4)	C32—C33—H33	120.0
C7—C11—C12	119.8 (5)	C34—C33—H33	120.0
N1—C12—C4	123.4 (5)	C33—C34—C35	119.9 (6)
N1—C12—C11	117.3 (4)	C33—C34—H34	120.0
C4—C12—C11	119.3 (5)	C35—C34—H34	120.0
N3—C13—C14	123.8 (4)	C30—C35—C34	121.2 (5)
N3—C13—H13	118.1	C30—C35—H35	119.4
C14—C13—H13	118.1	C34—C35—H35	119.4
C15—C14—C13	120.6 (4)	F2—B1—F1	114.2 (7)
C15—C14—H14	119.7	F2—B1—F4	114.4 (7)
C13—C14—H14	119.7	F1—B1—F4	111.1 (5)
C14—C15—C16	115.4 (4)	F2—B1—F3	105.1 (5)
C14—C15—C15^i	122.1 (5)	F1—B1—F3	103.4 (7)
C16—C15—C15^i	122.6 (5)	F4—B1—F3	107.6 (6)
N1—Cu1—P1—C24	127.1 (2)	C3—C4—C12—C11	179.2 (4)
N3—Cu1—P1—C24	−93.35 (19)	C5—C4—C12—C11	−1.1 (6)
N2—Cu1—P1—C24	32.1 (2)	N2—C11—C12—N1	1.7 (5)
N1—Cu1—P1—C18	4.8 (2)	C7—C11—C12—N1	−178.2 (4)
N3—Cu1—P1—C18	144.3 (2)	N2—C11—C12—C4	−179.0 (4)
N2—Cu1—P1—C18	−90.2 (2)	C7—C11—C12—C4	1.1 (6)
N1—Cu1—P1—C30	−113.7 (2)	C17—N3—C13—C14	0.3 (7)
N3—Cu1—P1—C30	25.8 (2)	Cu1—N3—C13—C14	−170.4 (4)
N2—Cu1—P1—C30	151.3 (2)	N3—C13—C14—C15	0.5 (7)
N3—Cu1—N1—C1	−75.7 (4)	C13—C14—C15—C16	−1.0 (7)
N2—Cu1—N1—C1	178.2 (4)	C13—C14—C15—C15^i	179.7 (5)
P1—Cu1—N1—C1	60.0 (4)	C14—C15—C16—C17	0.8 (7)
N3—Cu1—N1—C12	110.2 (3)	C15^i—C15—C16—C17	180.0 (5)
N2—Cu1—N1—C12	4.1 (3)	C13—N3—C17—C16	−0.6 (8)
P1—Cu1—N1—C12	−114.2 (3)	Cu1—N3—C17—C16	169.7 (4)
N1—Cu1—N2—C10	179.3 (4)	C15—C16—C17—N3	0.0 (9)
N3—Cu1—N2—C10	61.5 (4)	C24—P1—C18—C19	−102.0 (4)
P1—Cu1—N2—C10	−64.5 (4)	C30—P1—C18—C19	145.6 (4)
N1—Cu1—N2—C11	−3.1 (3)	Cu1—P1—C18—C19	23.2 (5)
N3—Cu1—N2—C11	−120.9 (3)	C24—P1—C18—C23	76.6 (5)
P1—Cu1—N2—C11	113.1 (3)	C30—P1—C18—C23	−35.9 (5)
N1—Cu1—N3—C17	71.9 (4)	Cu1—P1—C18—C23	−158.3 (4)
N2—Cu1—N3—C17	161.8 (4)	C23—C18—C19—C20	−2.6 (8)
P1—Cu1—N3—C17	−66.7 (4)	P1—C18—C19—C20	176.0 (5)
N1—Cu1—N3—C13	−118.1 (3)	C18—C19—C20—C21	1.6 (10)
N2—Cu1—N3—C13	−28.2 (4)	C19—C20—C21—C22	0.2 (11)
P1—Cu1—N3—C13	103.2 (3)	C20—C21—C22—C23	−0.9 (10)
C12—N1—C1—C2	−0.2 (7)	C21—C22—C23—C18	−0.2 (9)
Cu1—N1—C1—C2	−174.2 (4)	C19—C18—C23—C22	1.9 (8)
N1—C1—C2—C3	−0.8 (10)	P1—C18—C23—C22	−176.6 (4)
C1—C2—C3—C4	0.7 (10)	C18—P1—C24—C25	0.4 (4)
C2—C3—C4—C12	0.4 (9)	C30—P1—C24—C25	108.6 (4)
C2—C3—C4—C5	−179.3 (6)	Cu1—P1—C24—C25	−131.0 (4)
C3—C4—C5—C6	178.9 (6)	C18—P1—C24—C29	172.1 (4)
C12—C4—C5—C6	−0.8 (9)	C30—P1—C24—C29	−79.7 (4)
C4—C5—C6—C7	2.6 (10)	Cu1—P1—C24—C29	40.8 (4)
C5—C6—C7—C8	177.4 (6)	C29—C24—C25—C26	0.6 (7)
C5—C6—C7—C11	−2.5 (8)	P1—C24—C25—C26	172.3 (4)
C11—C7—C8—C9	−0.6 (8)	C24—C25—C26—C27	1.1 (8)
C6—C7—C8—C9	179.5 (6)	C25—C26—C27—C28	−1.5 (9)
C7—C8—C9—C10	−0.1 (9)	C26—C27—C28—C29	0.3 (10)
C11—N2—C10—C9	−0.5 (7)	C27—C28—C29—C24	1.4 (9)
Cu1—N2—C10—C9	177.0 (4)	C25—C24—C29—C28	−1.8 (8)
C8—C9—C10—N2	0.7 (9)	P1—C24—C29—C28	−174.1 (4)
C10—N2—C11—C7	−0.3 (6)	C24—P1—C30—C35	−167.8 (4)
Cu1—N2—C11—C7	−178.3 (3)	C18—P1—C30—C35	−57.9 (4)
C10—N2—C11—C12	179.8 (4)	Cu1—P1—C30—C35	71.5 (4)
Cu1—N2—C11—C12	1.8 (4)	C24—P1—C30—C31	20.1 (4)
C8—C7—C11—N2	0.9 (7)	C18—P1—C30—C31	130.0 (4)
C6—C7—C11—N2	−179.3 (4)	Cu1—P1—C30—C31	−100.7 (4)
C8—C7—C11—C12	−179.2 (4)	C35—C30—C31—C32	−0.4 (7)
C6—C7—C11—C12	0.7 (6)	P1—C30—C31—C32	171.7 (4)
C1—N1—C12—C4	1.4 (6)	C30—C31—C32—C33	−0.1 (8)
Cu1—N1—C12—C4	176.3 (3)	C31—C32—C33—C34	0.9 (9)
C1—N1—C12—C11	−179.2 (4)	C32—C33—C34—C35	−1.2 (10)
Cu1—N1—C12—C11	−4.4 (4)	C31—C30—C35—C34	0.1 (8)
C3—C4—C12—N1	−1.5 (7)	P1—C30—C35—C34	−172.5 (5)
C5—C4—C12—N1	178.2 (4)	C33—C34—C35—C30	0.7 (9)

Symmetry code: (i) −x+2, −y+1, −z+1.