catena-Poly[2,4,6-triamino-1,3,5-triazin-1-ium [[aqua­(pyridine-2,6-dicarboxyl­ato-κ3O,N,O′)bis­muthate(III)]-μ-pyridine-2,6-dicarboxyl­ato-κ4O,N,O′:O′]]

Sharif, M.A.; Aghabozorg, H.; Moghimi, A.

doi:10.1107/S1600536807021010

catena-Poly[2,4,6-triamino-1,3,5-triazin-1-ium [[aqua(pyridine-2,6-dicarboxylato-κ³O,N,O′)bismuthate(III)]-μ-pyridine-2,6-dicarboxylato-κ⁴O,N,O′:O′]]

M. A. Sharif, H. Aghabozorg and A. Moghimi

The reaction of Bi(NO₃)₃·5H₂O with a 1:2 molecular complex of pyridine-2,6-dicarboxylic acid (pydcH₂) and 2,4,6-triamino-1,3,5-triazine (tata) in aqueous solution leads to formation of the title compound, (C₃H₇N₆)[Bi(C₇H₃NO₄)₂(H₂O)]. The Bi^III atom is octacoordinated by two tridentate pydc²⁻ ligands, one O atom of a water molecule and one O atom from a Bi—O—Bi bridge. Extensive O—H

O and N—H

O hydrogen bonding exists between the anionic polymers and the tataH⁺ cations.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807021010/bi2175sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536807021010/bi2175Isup2.hkl Contains datablock I

CCDC reference: 263829

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.007 Å
R factor = 0.026
wR factor = 0.066
Data-to-parameter ratio = 15.4

checkCIF/PLATON results

No syntax errors found



Alert level C
ABSTM02_ALERT_3_C  The ratio of expected to reported Tmax/Tmin(RR) is > 1.10
            Tmin and Tmax reported:      0.195     0.645
            Tmin and Tmax expected:      0.135     0.645
            RR =      1.440
            Please check that your absorption correction is appropriate.
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT060_ALERT_3_C Ratio Tmax/Tmin (Exp-to-Rep) (too) Large .......       1.39
PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent .....          ?
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor ....       2.04

Alert level G
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K
PLAT794_ALERT_5_G Check Predicted Bond Valency for Bi1         (3)       2.73

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   1 ALERT type 5 Informative message, check

Computing details top

Data collection: CAD-4 Software (Enraf–Nonius, 1989); cell refinement: CAD-4 Software; data reduction: XCAD4 (Harms, 1995); program(s) used to solve structure: SHELXTL (Bruker, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

catena-Poly[2,4,6-triamino-1,3,5-triazin-1-ium [[aqua(pyridine-2,6-dicarboxylato-κ³O,N,O')bismuth(III)]-µ-µ₂-pyridine-2,6-dicarboxylato-κ⁴O,N,O':O']] top

Crystal data top

(C₃H₇N₆)[Bi(C₇H₃NO₄)₂(H₂O)]	F(000) = 1312
M_r = 684.35	D_x = 2.244 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 24 reflections
a = 9.3948 (19) Å	θ = 7–13°
b = 23.351 (5) Å	µ = 8.78 mm⁻¹
c = 9.950 (2) Å	T = 293 K
β = 111.88 (3)°	Plate, colourless
V = 2025.6 (7) Å³	0.35 × 0.20 × 0.05 mm
Z = 4

Data collection top

Enraf–Nonius CAD-4 diffractometer	3715 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	R_int = 0.034
Graphite monochromator	θ_max = 28.0°, θ_min = 1.7°
ω–θ scans	h = 0→12
Absorption correction: ψ scan (North et al., 1968)	k = 0→30
T_min = 0.195, T_max = 0.645	l = −13→12
5152 measured reflections	2 standard reflections every 98 reflections
4871 independent reflections	intensity decay: 2.5%

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.026	Hydrogen site location: mixed
wR(F²) = 0.066	H-atom parameters constrained
S = 1.03	w = 1/[σ²(F_o²) + (0.0362P)²] where P = (F_o² + 2F_c²)/3
4871 reflections	(Δ/σ)_max = 0.001
316 parameters	Δρ_max = 0.69 e Å⁻³
0 restraints	Δρ_min = −1.14 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Bi1	0.552810 (17)	−0.193019 (7)	1.439182 (16)	0.02237 (6)
O1	0.6111 (3)	−0.10498 (13)	1.5581 (3)	0.0282 (7)
O2	0.6980 (4)	−0.28698 (14)	1.4813 (4)	0.0324 (7)
O3	0.7770 (4)	−0.04895 (15)	1.7231 (4)	0.0488 (10)
O4	0.8748 (4)	−0.34122 (14)	1.6453 (4)	0.0376 (8)
O5	0.3952 (4)	−0.12880 (16)	1.2400 (4)	0.0396 (9)
O6	0.4941 (3)	−0.23637 (14)	1.6281 (3)	0.0309 (7)
O7	0.1897 (3)	−0.07319 (15)	1.1434 (3)	0.0328 (7)
O8	0.3550 (4)	−0.23668 (15)	1.7681 (4)	0.0354 (8)
O9	0.7444 (4)	−0.13691 (15)	1.3525 (4)	0.0393 (8)
H9A	0.7039	−0.1078	1.3011	0.047*
H9B	0.8235	−0.1464	1.3357	0.047*
N1	0.7928 (4)	−0.19504 (15)	1.6514 (4)	0.0216 (7)
N2	0.3185 (4)	−0.15528 (15)	1.4605 (4)	0.0227 (7)
N3	0.6811 (4)	0.04424 (16)	1.0465 (4)	0.0296 (8)
H3N	0.7037	0.0475	0.9666	0.036*
N4	0.6856 (4)	−0.02450 (16)	1.2196 (4)	0.0271 (8)
N5	0.5374 (4)	0.06224 (16)	1.1893 (4)	0.0298 (8)
N6	0.8104 (4)	−0.03998 (18)	1.0631 (4)	0.0347 (9)
H6A	0.8230	−0.0775	1.0856	0.042*
H6B	0.8445	−0.0356	0.9902	0.042*
N7	0.5467 (5)	−0.0034 (2)	1.3595 (5)	0.0454 (12)
H7A	0.5980	−0.0284	1.4297	0.055*
H7B	0.4832	0.0208	1.3803	0.055*
N8	0.5389 (5)	0.12643 (17)	1.0165 (4)	0.0350 (9)
H8A	0.5557	0.1355	0.9357	0.042*
H8B	0.4649	0.1469	1.0312	0.042*
C1	0.7356 (5)	−0.09566 (19)	1.6671 (5)	0.0286 (10)
C2	0.8347 (5)	−0.14704 (19)	1.7294 (5)	0.0251 (9)
C3	0.9637 (5)	−0.1459 (2)	1.8559 (5)	0.0313 (10)
H3	0.9937	−0.1122	1.9089	0.038*
C4	1.0464 (5)	−0.1954 (2)	1.9016 (5)	0.0360 (11)
H4	1.1321	−0.1958	1.9874	0.043*
C5	1.0020 (5)	−0.2444 (2)	1.8199 (5)	0.0333 (10)
H5	1.0580	−0.2781	1.8487	0.040*
C6	0.8723 (5)	−0.24267 (18)	1.6939 (5)	0.0233 (9)
C7	0.8105 (5)	−0.29447 (19)	1.5985 (5)	0.0266 (9)
C8	0.2748 (5)	−0.10383 (19)	1.2407 (5)	0.0267 (9)
C9	0.2370 (5)	−0.11399 (19)	1.3732 (5)	0.0244 (9)
C10	0.1267 (5)	−0.0835 (2)	1.4023 (5)	0.0310 (10)
H10	0.0732	−0.0540	1.3418	0.037*
C11	0.0975 (5)	−0.0983 (2)	1.5256 (5)	0.0358 (11)
H11	0.0242	−0.0784	1.5490	0.043*
C12	0.1769 (5)	−0.1421 (2)	1.6113 (5)	0.0318 (10)
H12	0.1564	−0.1531	1.6921	0.038*
C13	0.2888 (5)	−0.1701 (2)	1.5763 (4)	0.0249 (9)
C14	0.3863 (5)	−0.2182 (2)	1.6654 (5)	0.0293 (10)
C15	0.7253 (5)	−0.00785 (19)	1.1110 (5)	0.0256 (9)
C16	0.5916 (5)	0.01188 (19)	1.2534 (5)	0.0287 (10)
C17	0.5839 (5)	0.0775 (2)	1.0865 (5)	0.0277 (9)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Bi1	0.02346 (8)	0.02507 (9)	0.01794 (8)	0.00073 (7)	0.00697 (5)	0.00121 (7)
O1	0.0299 (16)	0.0265 (16)	0.0264 (16)	0.0035 (13)	0.0084 (13)	0.0008 (13)
O2	0.0350 (17)	0.0271 (16)	0.0317 (18)	0.0022 (14)	0.0087 (14)	−0.0046 (14)
O3	0.049 (2)	0.0269 (19)	0.060 (3)	−0.0025 (16)	0.0078 (19)	−0.0104 (17)
O4	0.048 (2)	0.0248 (18)	0.039 (2)	0.0076 (15)	0.0153 (16)	0.0044 (15)
O5	0.0415 (19)	0.050 (2)	0.0328 (19)	0.0185 (17)	0.0203 (16)	0.0188 (17)
O6	0.0301 (16)	0.0366 (19)	0.0270 (17)	0.0062 (14)	0.0116 (14)	0.0088 (14)
O7	0.0328 (16)	0.0388 (19)	0.0238 (16)	0.0056 (14)	0.0071 (13)	0.0118 (14)
O8	0.0362 (18)	0.046 (2)	0.0264 (17)	0.0085 (16)	0.0149 (14)	0.0138 (15)
O9	0.0436 (19)	0.040 (2)	0.043 (2)	0.0078 (16)	0.0264 (17)	0.0117 (17)
N1	0.0218 (16)	0.0234 (17)	0.0195 (16)	−0.0008 (14)	0.0074 (13)	−0.0008 (14)
N2	0.0225 (17)	0.0236 (18)	0.0204 (17)	−0.0008 (14)	0.0062 (14)	−0.0001 (14)
N3	0.039 (2)	0.027 (2)	0.027 (2)	0.0050 (17)	0.0172 (17)	0.0046 (16)
N4	0.034 (2)	0.0241 (19)	0.0237 (18)	0.0032 (16)	0.0114 (16)	0.0065 (15)
N5	0.042 (2)	0.028 (2)	0.0213 (18)	0.0055 (16)	0.0134 (16)	0.0014 (15)
N6	0.041 (2)	0.032 (2)	0.038 (2)	0.0117 (18)	0.0223 (19)	0.0085 (18)
N7	0.067 (3)	0.044 (3)	0.039 (3)	0.023 (2)	0.035 (2)	0.021 (2)
N8	0.055 (3)	0.025 (2)	0.027 (2)	0.0102 (19)	0.0176 (19)	0.0077 (16)
C1	0.031 (2)	0.026 (2)	0.032 (2)	−0.0031 (18)	0.0156 (19)	−0.0034 (19)
C2	0.024 (2)	0.025 (2)	0.027 (2)	−0.0016 (17)	0.0115 (17)	−0.0003 (18)
C3	0.032 (2)	0.037 (3)	0.024 (2)	−0.003 (2)	0.0084 (18)	−0.008 (2)
C4	0.029 (2)	0.047 (3)	0.026 (2)	0.001 (2)	0.0033 (19)	−0.001 (2)
C5	0.033 (2)	0.034 (3)	0.028 (2)	0.006 (2)	0.0059 (19)	0.005 (2)
C6	0.023 (2)	0.026 (2)	0.022 (2)	0.0037 (16)	0.0096 (17)	0.0015 (17)
C7	0.029 (2)	0.028 (2)	0.028 (2)	−0.0014 (17)	0.0164 (19)	0.0017 (18)
C8	0.034 (2)	0.025 (2)	0.019 (2)	−0.0054 (18)	0.0078 (18)	0.0003 (17)
C9	0.022 (2)	0.028 (2)	0.019 (2)	−0.0020 (17)	0.0029 (16)	0.0012 (17)
C10	0.028 (2)	0.031 (2)	0.031 (2)	0.0022 (19)	0.0073 (18)	0.002 (2)
C11	0.031 (2)	0.044 (3)	0.035 (3)	0.006 (2)	0.015 (2)	0.002 (2)
C12	0.030 (2)	0.046 (3)	0.023 (2)	0.000 (2)	0.0136 (18)	−0.001 (2)
C13	0.025 (2)	0.031 (2)	0.017 (2)	−0.0049 (18)	0.0064 (16)	−0.0019 (17)
C14	0.024 (2)	0.044 (3)	0.017 (2)	−0.008 (2)	0.0058 (17)	−0.004 (2)
C15	0.027 (2)	0.027 (2)	0.019 (2)	−0.0017 (18)	0.0044 (17)	0.0017 (17)
C16	0.036 (2)	0.022 (2)	0.026 (2)	0.0018 (19)	0.0097 (19)	0.0000 (18)
C17	0.034 (2)	0.024 (2)	0.021 (2)	0.0000 (19)	0.0061 (17)	−0.0009 (18)

Geometric parameters (Å, º) top

Bi1—O1	2.333 (3)	N5—C16	1.344 (5)
Bi1—O6	2.374 (3)	N6—C15	1.310 (6)
Bi1—N1	2.448 (3)	N6—H6A	0.900
Bi1—N2	2.452 (3)	N6—H6B	0.900
Bi1—O5	2.486 (3)	N7—C16	1.324 (6)
Bi1—O2	2.535 (3)	N7—H7A	0.900
Bi1—O8ⁱ	2.586 (3)	N7—H7B	0.900
Bi1—O9	2.618 (3)	N8—C17	1.323 (6)
O1—C1	1.283 (5)	N8—H8A	0.900
O2—C7	1.261 (6)	N8—H8B	0.900
O3—C1	1.221 (6)	C1—C2	1.503 (6)
O4—C7	1.250 (5)	C2—C3	1.385 (6)
O5—C8	1.275 (6)	C3—C4	1.373 (7)
O6—C14	1.274 (5)	C3—H3	0.930
O7—C8	1.229 (5)	C4—C5	1.375 (7)
O8—C14	1.241 (5)	C4—H4	0.930
O8—Bi1ⁱⁱ	2.586 (3)	C5—C6	1.386 (6)
O9—H9A	0.850	C5—H5	0.930
O9—H9B	0.850	C6—C7	1.513 (6)
N1—C6	1.319 (5)	C8—C9	1.506 (6)
N1—C2	1.336 (5)	C9—C10	1.374 (6)
N2—C13	1.328 (5)	C10—C11	1.396 (7)
N2—C9	1.332 (5)	C10—H10	0.930
N3—C17	1.366 (6)	C11—C12	1.362 (7)
N3—C15	1.366 (6)	C11—H11	0.930
N3—H3N	0.900	C12—C13	1.388 (6)
N4—C15	1.325 (6)	C12—H12	0.930
N4—C16	1.355 (6)	C13—C14	1.511 (7)
N5—C17	1.303 (6)

O1—Bi1—O6	93.09 (11)	C17—N8—H8B	119.2
O1—Bi1—N1	67.22 (11)	H8A—N8—H8B	115.0
O6—Bi1—N1	73.74 (11)	O3—C1—O1	124.9 (4)
O1—Bi1—N2	71.82 (11)	O3—C1—C2	118.8 (4)
O6—Bi1—N2	66.66 (11)	O1—C1—C2	116.3 (4)
N1—Bi1—N2	119.99 (11)	N1—C2—C3	120.9 (4)
O1—Bi1—O5	80.24 (12)	N1—C2—C1	115.3 (4)
O6—Bi1—O5	130.03 (11)	C3—C2—C1	123.8 (4)
N1—Bi1—O5	141.49 (12)	C4—C3—C2	118.7 (4)
N2—Bi1—O5	64.22 (11)	C4—C3—H3	120.7
O1—Bi1—O2	131.96 (11)	C2—C3—H3	120.7
O6—Bi1—O2	76.66 (11)	C3—C4—C5	119.7 (4)
N1—Bi1—O2	64.84 (11)	C3—C4—H4	120.1
N2—Bi1—O2	137.88 (12)	C5—C4—H4	120.1
O5—Bi1—O2	141.07 (12)	C4—C5—C6	118.8 (4)
O1—Bi1—O8ⁱ	150.28 (11)	C4—C5—H5	120.6
O6—Bi1—O8ⁱ	85.91 (11)	C6—C5—H5	120.6
N1—Bi1—O8ⁱ	139.49 (12)	N1—C6—C5	121.1 (4)
N2—Bi1—O8ⁱ	80.63 (11)	N1—C6—C7	115.7 (4)
O5—Bi1—O8ⁱ	77.86 (13)	C5—C6—C7	123.1 (4)
O2—Bi1—O8ⁱ	76.69 (11)	O4—C7—O2	126.0 (4)
O1—Bi1—O9	70.48 (11)	O4—C7—C6	116.4 (4)
O6—Bi1—O9	149.91 (11)	O2—C7—C6	117.6 (4)
N1—Bi1—O9	76.62 (11)	O7—C8—O5	125.5 (4)
N2—Bi1—O9	126.72 (11)	O7—C8—C9	119.0 (4)
O5—Bi1—O9	73.39 (11)	O5—C8—C9	115.6 (4)
O2—Bi1—O9	95.40 (11)	N2—C9—C10	122.2 (4)
O8ⁱ—Bi1—O9	120.95 (11)	N2—C9—C8	114.8 (4)
C1—O1—Bi1	123.1 (3)	C10—C9—C8	123.0 (4)
C7—O2—Bi1	119.2 (3)	C9—C10—C11	117.8 (4)
C8—O5—Bi1	122.5 (3)	C9—C10—H10	121.1
C14—O6—Bi1	122.2 (3)	C11—C10—H10	121.1
C14—O8—Bi1ⁱⁱ	115.5 (3)	C12—C11—C10	119.7 (4)
Bi1—O9—H9A	112.9	C12—C11—H11	120.2
Bi1—O9—H9B	133.9	C10—C11—H11	120.2
H9A—O9—H9B	108.6	C11—C12—C13	119.0 (4)
C6—N1—C2	120.8 (4)	C11—C12—H12	120.5
C6—N1—Bi1	121.5 (3)	C13—C12—H12	120.5
C2—N1—Bi1	117.5 (3)	N2—C13—C12	121.3 (4)
C13—N2—C9	119.9 (4)	N2—C13—C14	115.1 (4)
C13—N2—Bi1	117.8 (3)	C12—C13—C14	123.6 (4)
C9—N2—Bi1	121.3 (3)	O8—C14—O6	125.6 (5)
C17—N3—C15	119.2 (4)	O8—C14—C13	117.6 (4)
C17—N3—H3N	127.9	O6—C14—C13	116.8 (4)
C15—N3—H3N	111.1	N6—C15—N4	121.6 (4)
C15—N4—C16	115.2 (4)	N6—C15—N3	117.3 (4)
C17—N5—C16	115.7 (4)	N4—C15—N3	121.1 (4)
C15—N6—H6A	120.5	N7—C16—N5	115.9 (4)
C15—N6—H6B	132.6	N7—C16—N4	117.4 (4)
H6A—N6—H6B	104.9	N5—C16—N4	126.7 (4)
C16—N7—H7A	123.8	N5—C17—N8	121.0 (4)
C16—N7—H7B	116.7	N5—C17—N3	122.0 (4)
H7A—N7—H7B	116.0	N8—C17—N3	117.0 (4)
C17—N8—H8A	123.1

O6—Bi1—O1—C1	74.8 (3)	Bi1—N1—C2—C1	−6.0 (5)
N1—Bi1—O1—C1	3.9 (3)	O3—C1—C2—N1	−171.5 (4)
N2—Bi1—O1—C1	139.0 (4)	O1—C1—C2—N1	9.2 (6)
O5—Bi1—O1—C1	−155.1 (4)	O3—C1—C2—C3	6.6 (7)
O2—Bi1—O1—C1	0.0 (4)	O1—C1—C2—C3	−172.7 (4)
O8ⁱ—Bi1—O1—C1	162.0 (3)	N1—C2—C3—C4	−1.3 (7)
O9—Bi1—O1—C1	−79.3 (3)	C1—C2—C3—C4	−179.3 (4)
O1—Bi1—O2—C7	14.0 (4)	C2—C3—C4—C5	1.5 (7)
O6—Bi1—O2—C7	−68.1 (3)	C3—C4—C5—C6	−1.1 (8)
N1—Bi1—O2—C7	10.0 (3)	C2—N1—C6—C5	−0.4 (7)
N2—Bi1—O2—C7	−97.7 (3)	Bi1—N1—C6—C5	−175.3 (3)
O5—Bi1—O2—C7	152.6 (3)	C2—N1—C6—C7	178.3 (4)
O8ⁱ—Bi1—O2—C7	−157.0 (3)	Bi1—N1—C6—C7	3.4 (5)
O9—Bi1—O2—C7	82.5 (3)	C4—C5—C6—N1	0.6 (7)
O1—Bi1—O5—C8	−70.8 (4)	C4—C5—C6—C7	−178.0 (4)
O6—Bi1—O5—C8	15.0 (4)	Bi1—O2—C7—O4	166.3 (3)
N1—Bi1—O5—C8	−102.9 (4)	Bi1—O2—C7—C6	−12.3 (5)
N2—Bi1—O5—C8	3.6 (3)	N1—C6—C7—O4	−172.5 (4)
O2—Bi1—O5—C8	139.1 (3)	C5—C6—C7—O4	6.1 (6)
O8ⁱ—Bi1—O5—C8	89.0 (4)	N1—C6—C7—O2	6.2 (6)
O9—Bi1—O5—C8	−143.2 (4)	C5—C6—C7—O2	−175.2 (4)
O1—Bi1—O6—C14	61.1 (3)	Bi1—O5—C8—O7	−177.5 (3)
N1—Bi1—O6—C14	126.3 (4)	Bi1—O5—C8—C9	2.2 (5)
N2—Bi1—O6—C14	−7.6 (3)	C13—N2—C9—C10	3.5 (6)
O5—Bi1—O6—C14	−18.7 (4)	Bi1—N2—C9—C10	−165.2 (3)
O2—Bi1—O6—C14	−166.4 (4)	C13—N2—C9—C8	−176.2 (4)
O8ⁱ—Bi1—O6—C14	−89.1 (3)	Bi1—N2—C9—C8	15.1 (5)
O9—Bi1—O6—C14	116.1 (3)	O7—C8—C9—N2	168.7 (4)
O1—Bi1—N1—C6	176.7 (3)	O5—C8—C9—N2	−11.0 (6)
O6—Bi1—N1—C6	76.1 (3)	O7—C8—C9—C10	−11.0 (7)
N2—Bi1—N1—C6	126.0 (3)	O5—C8—C9—C10	169.3 (4)
O5—Bi1—N1—C6	−148.7 (3)	N2—C9—C10—C11	−2.2 (7)
O2—Bi1—N1—C6	−6.5 (3)	C8—C9—C10—C11	177.5 (4)
O8ⁱ—Bi1—N1—C6	13.3 (4)	C9—C10—C11—C12	−0.5 (7)
O9—Bi1—N1—C6	−109.1 (3)	C10—C11—C12—C13	1.9 (7)
O1—Bi1—N1—C2	1.6 (3)	C9—N2—C13—C12	−2.0 (6)
O6—Bi1—N1—C2	−98.9 (3)	Bi1—N2—C13—C12	167.1 (3)
N2—Bi1—N1—C2	−49.1 (3)	C9—N2—C13—C14	178.8 (4)
O5—Bi1—N1—C2	36.2 (4)	Bi1—N2—C13—C14	−12.1 (5)
O2—Bi1—N1—C2	178.4 (3)	C11—C12—C13—N2	−0.7 (7)
O8ⁱ—Bi1—N1—C2	−161.8 (3)	C11—C12—C13—C14	178.5 (4)
O9—Bi1—N1—C2	75.8 (3)	Bi1ⁱⁱ—O8—C14—O6	9.6 (6)
O1—Bi1—N2—C13	−91.4 (3)	Bi1ⁱⁱ—O8—C14—C13	−170.4 (3)
O6—Bi1—N2—C13	10.3 (3)	Bi1—O6—C14—O8	−175.7 (4)
N1—Bi1—N2—C13	−42.7 (3)	Bi1—O6—C14—C13	4.3 (5)
O5—Bi1—N2—C13	−179.1 (3)	N2—C13—C14—O8	−174.4 (4)
O2—Bi1—N2—C13	41.9 (4)	C12—C13—C14—O8	6.3 (7)
O8ⁱ—Bi1—N2—C13	99.9 (3)	N2—C13—C14—O6	5.5 (6)
O9—Bi1—N2—C13	−138.3 (3)	C12—C13—C14—O6	−173.7 (4)
O1—Bi1—N2—C9	77.5 (3)	C16—N4—C15—N6	−177.1 (4)
O6—Bi1—N2—C9	179.3 (3)	C16—N4—C15—N3	4.2 (6)
N1—Bi1—N2—C9	126.2 (3)	C17—N3—C15—N6	175.7 (4)
O5—Bi1—N2—C9	−10.2 (3)	C17—N3—C15—N4	−5.5 (6)
O2—Bi1—N2—C9	−149.1 (3)	C17—N5—C16—N7	178.9 (4)
O8ⁱ—Bi1—N2—C9	−91.2 (3)	C17—N5—C16—N4	−1.6 (7)
O9—Bi1—N2—C9	30.7 (4)	C15—N4—C16—N7	178.9 (4)
Bi1—O1—C1—O3	172.4 (4)	C15—N4—C16—N5	−0.6 (7)
Bi1—O1—C1—C2	−8.3 (5)	C16—N5—C17—N8	−179.5 (4)
C6—N1—C2—C3	0.8 (6)	C16—N5—C17—N3	0.2 (6)
Bi1—N1—C2—C3	175.9 (3)	C15—N3—C17—N5	3.2 (6)
C6—N1—C2—C1	178.9 (4)	C15—N3—C17—N8	−177.0 (4)

Symmetry codes: (i) x, −y−1/2, z−1/2; (ii) x, −y−1/2, z+1/2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N3—H3N···O7ⁱⁱⁱ	0.90	1.84	2.686 (5)	156
N6—H6A···O4ⁱ	0.90	1.99	2.892 (5)	174
N6—H6B···O3^iv	0.90	2.51	3.285 (6)	144
N7—H7A···O1	0.90	2.17	3.001 (5)	152
N7—H7B···O1^v	0.90	2.33	3.190 (5)	160
N8—H8A···O5ⁱⁱⁱ	0.90	1.97	2.842 (5)	162
N8—H8B···O2^vi	0.90	2.14	3.013 (5)	162
O9—H9A···N4	0.85	2.09	2.898 (5)	159
O9—H9B···O4ⁱ	0.85	2.14	2.810 (5)	135

Symmetry codes: (i) x, −y−1/2, z−1/2; (iii) −x+1, −y, −z+2; (iv) x, y, z−1; (v) −x+1, −y, −z+3; (vi) −x+1, y+1/2, −z+5/2.

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catena-Poly[2,4,6-triamino-1,3,5-triazin-1-ium [[aqua­(pyridine-2,6-dicarboxyl­ato-κ3O,N,O′)bis­muthate(III)]-μ-pyridine-2,6-dicarboxyl­ato-κ4O,N,O′:O′]]

Supporting information

Key indicators

checkCIF/PLATON results

catena-Poly[2,4,6-triamino-1,3,5-triazin-1-ium [[aqua(pyridine-2,6-dicarboxylato-κ³O,N,O′)bismuthate(III)]-μ-pyridine-2,6-dicarboxylato-κ⁴O,N,O′:O′]]