metal-organic compounds
The title compound {systematic name: tricarbonyl-1κC, 2κ2C-μ-formato(2-)-1κC: 2κ2CO,O'-nitrosyl-1κN-[1(η5)-pentamethylcyclopentadienyl]bis(triphenylphosphine)-2κ2P-dirhenium}, [Re2(CO2)(NO)(C10H15)(C18H15P)2(CO)3], has a carbon dioxide ligand bridged between two octahedral rhenium centers. The presence of two triphenylphosphine ligands, which are trans to one another on Re(2), alters the orientation of the bridging CO2 ligand relative to ligands bound to Re(1) in this compound as compared with the analog having a single triphenylphosphine ligand on Re(2).
Supporting information
Crystallographic Information File (CIF) |
CCDC reference: 126506