metal-organic compounds
In the title compound, [Sn(CH3)3(C16H13O3)], the Sn atom has fivefold coordination involving three methyl C atoms defining the equatorial plane of a trigonal bipyramid and two O atoms from two carboxylate groups occupying the axial positions. The Sn-C bond lengths [2.106 (6), 2.110 (5) and 2.116 (5) Å] are very similar. The two carboxylate O atoms have notably different distances to the metal atom [2.184 (3) and 2.433 (4) Å], with an O-Sn-O angle of 174.0 (1)°. Bidentate bridging of the carboxylate ligands via trimethyltin groups forms a polymeric structure.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129272