metal-organic compounds
The title compound, (C36H30NP2)[Ru8P(CO)22]·CHCl3 or [N(PPh3)2][Ru8(μ8-P)(CO)22]·CHCl3, comprises a square antiprismatic octaruthenium cluster anion with an interstitial phosphido ligand, two bridging carbonyl ligands, and 20 terminal carbonyl ligands, together with a disordered PPN cation and a disordered chloroform solvent molecule.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806034052/bm2003sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806034052/bm2003Isup2.hkl |
CCDC reference: 620672
Computing details top
Data collection: COLLECT (Nonius, 1997); cell refinement: DENZO/SCALEPACK; data reduction: DENZO/SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: CRYSTALS (Betteridge et al., 2003); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: CRYSTALS.
Bis(triphenylphosphoranylidene)ammonium
docosacarbonyl(µ8-phosphido)octaruthenate chloroform solvate top
Crystal data top
(C36H30NP2)[Ru8P(CO)22]·CHCl3 | F(000) = 4064 |
Mr = 2113.73 | Dx = 2.106 Mg m−3 |
Orthorhombic, Pna21 | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: P 2c -2n | Cell parameters from 86582 reflections |
a = 19.1786 (2) Å | θ = 3–27° |
b = 10.5448 (1) Å | µ = 2.03 mm−1 |
c = 32.9569 (4) Å | T = 200 K |
V = 6665.02 (12) Å3 | Plate, purple |
Z = 4 | 0.27 × 0.16 × 0.02 mm |
Data collection top
Nonius KappaCCD diffractometer | 10343 reflections with I > 3σ(I) |
Graphite monochromator | Rint = 0.038 |
φ and ω scans | θmax = 27.5°, θmin = 2.7° |
Absorption correction: integration Gaussian integration (Coppens, 1970) | h = −24→24 |
Tmin = 0.644, Tmax = 0.959 | k = −13→13 |
78313 measured reflections | l = −42→42 |
15035 independent reflections |
Refinement top
Refinement on F | Hydrogen site location: inferred from neighbouring sites |
Least-squares matrix: full | H-atom parameters constrained |
R[F2 > 2σ(F2)] = 0.024 | w = [1-(Fo-Fc)2/36σ2(F)]2/[0.282To(x)-0.0449T1(x) + 0.108T2(x)]
where Ti are the Chebychev polynomials and x = Fc/Fmax (Prince, 1982; Watkin, 1994) |
wR(F2) = 0.023 | (Δ/σ)max = 0.04 |
S = 1.11 | Δρmax = 2.01 e Å−3 |
10343 reflections | Δρmin = −1.26 e Å−3 |
863 parameters | Absolute structure: Flack (1983); 7252 Friedel-pairs, partially inversion twinned |
55 restraints | Absolute structure parameter: 0.43 (2) |
Primary atom site location: structure-invariant direct methods |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Ru1 | 0.58109 (2) | 0.34806 (4) | 0.38111 (2) | 0.0228 | |
Ru2 | 0.72026 (2) | 0.30847 (3) | 0.34410 (2) | 0.0218 | |
Ru3 | 0.69029 (2) | 0.48804 (4) | 0.27856 (2) | 0.0239 | |
Ru4 | 0.54775 (2) | 0.51566 (4) | 0.31261 (2) | 0.0244 | |
Ru5 | 0.69871 (2) | 0.46478 (4) | 0.41645 (2) | 0.0210 | |
Ru6 | 0.77666 (2) | 0.56439 (3) | 0.34669 (2) | 0.0211 | |
Ru7 | 0.65353 (2) | 0.71261 (4) | 0.31893 (2) | 0.0218 | |
Ru8 | 0.58002 (2) | 0.62498 (4) | 0.39116 (2) | 0.0213 | |
Cl1 | 0.84039 (13) | 1.4452 (3) | 0.54912 (7) | 0.0900 | |
Cl2 | 0.70832 (15) | 1.3188 (3) | 0.53787 (9) | 0.0944 | |
Cl30 | 0.7751 (6) | 1.3571 (11) | 0.6229 (3) | 0.1066 | 0.346 (7) |
Cl31 | 0.73525 (19) | 1.4472 (5) | 0.60991 (11) | 0.0775 | 0.654 (7) |
P1 | 0.65630 (6) | 0.50374 (11) | 0.34856 (5) | 0.0190 | |
P2 | 0.57473 (8) | 0.69788 (14) | 0.62483 (4) | 0.0278 | |
P3 | 0.62921 (8) | 0.89465 (14) | 0.56943 (5) | 0.0289 | |
O11 | 0.5701 (2) | 0.0626 (4) | 0.37292 (15) | 0.0458 | |
O12 | 0.4326 (2) | 0.3457 (5) | 0.41279 (18) | 0.0594 | |
O13 | 0.6169 (2) | 0.2796 (4) | 0.46740 (12) | 0.0446 | |
O21 | 0.6485 (2) | 0.1397 (4) | 0.28258 (13) | 0.0391 | |
O22 | 0.7383 (3) | 0.0997 (4) | 0.40780 (14) | 0.0498 | |
O23 | 0.8560 (2) | 0.2224 (5) | 0.30501 (17) | 0.0606 | |
O31 | 0.6177 (3) | 0.3738 (6) | 0.20645 (15) | 0.0660 | |
O32 | 0.8284 (3) | 0.4357 (5) | 0.23777 (16) | 0.0591 | |
O33 | 0.6924 (3) | 0.7341 (4) | 0.23016 (13) | 0.0483 | |
O41 | 0.5064 (2) | 0.2529 (4) | 0.28364 (16) | 0.0502 | |
O42 | 0.5167 (3) | 0.6420 (5) | 0.23112 (15) | 0.0561 | |
O43 | 0.3974 (2) | 0.5481 (5) | 0.34118 (19) | 0.0625 | |
O51 | 0.6876 (3) | 0.6189 (5) | 0.49331 (13) | 0.0530 | |
O52 | 0.8238 (2) | 0.3291 (4) | 0.45283 (13) | 0.0420 | |
O61 | 0.8090 (2) | 0.7481 (5) | 0.41465 (15) | 0.0558 | |
O62 | 0.9085 (2) | 0.4224 (4) | 0.36973 (15) | 0.0486 | |
O63 | 0.8586 (2) | 0.7188 (5) | 0.28449 (14) | 0.0517 | |
O71 | 0.7472 (2) | 0.9400 (4) | 0.32877 (14) | 0.0472 | |
O72 | 0.5385 (3) | 0.8947 (4) | 0.29406 (14) | 0.0479 | |
O81 | 0.6568 (2) | 0.8527 (4) | 0.42471 (14) | 0.0476 | |
O82 | 0.4591 (2) | 0.8047 (4) | 0.37474 (15) | 0.0491 | |
O83 | 0.5157 (2) | 0.5487 (4) | 0.47208 (13) | 0.0463 | |
N1 | 0.6189 (2) | 0.7594 (4) | 0.58935 (13) | 0.0302 | |
C11 | 0.5750 (3) | 0.1710 (5) | 0.37565 (18) | 0.0322 | |
C12 | 0.4882 (3) | 0.3484 (5) | 0.4008 (2) | 0.0381 | |
C13 | 0.6273 (3) | 0.3357 (5) | 0.43734 (17) | 0.0283 | |
C21 | 0.6736 (3) | 0.2074 (5) | 0.30504 (17) | 0.0314 | |
C22 | 0.7317 (3) | 0.1798 (5) | 0.38471 (17) | 0.0313 | |
C23 | 0.8067 (3) | 0.2620 (5) | 0.3198 (2) | 0.0383 | |
C31 | 0.6431 (3) | 0.4182 (6) | 0.23401 (18) | 0.0382 | |
C32 | 0.7764 (4) | 0.4571 (6) | 0.25343 (19) | 0.0403 | |
C33 | 0.6839 (3) | 0.6763 (5) | 0.26035 (18) | 0.0309 | |
C41 | 0.5244 (3) | 0.3487 (6) | 0.2975 (2) | 0.0433 | |
C42 | 0.5292 (3) | 0.5958 (6) | 0.2618 (2) | 0.0403 | |
C43 | 0.4544 (3) | 0.5402 (6) | 0.3313 (2) | 0.0420 | |
C51 | 0.6914 (3) | 0.5624 (6) | 0.46334 (19) | 0.0359 | |
C52 | 0.7768 (3) | 0.3805 (5) | 0.43846 (17) | 0.0298 | |
C61 | 0.7940 (3) | 0.6762 (6) | 0.3907 (2) | 0.0369 | |
C62 | 0.8576 (3) | 0.4705 (6) | 0.36065 (18) | 0.0326 | |
C63 | 0.8261 (3) | 0.6615 (5) | 0.30695 (19) | 0.0331 | |
C71 | 0.7134 (3) | 0.8511 (5) | 0.32576 (17) | 0.0285 | |
C72 | 0.5813 (3) | 0.8253 (6) | 0.30404 (17) | 0.0337 | |
C81 | 0.6302 (3) | 0.7679 (5) | 0.41064 (18) | 0.0327 | |
C82 | 0.5047 (3) | 0.7344 (5) | 0.37895 (19) | 0.0354 | |
C83 | 0.5407 (3) | 0.5737 (5) | 0.44134 (19) | 0.0330 | |
C101 | 0.5632 (3) | 0.9298 (5) | 0.53255 (16) | 0.0289 | |
C102 | 0.5237 (3) | 0.8303 (6) | 0.51620 (18) | 0.0349 | |
C103 | 0.4753 (3) | 0.8534 (6) | 0.48634 (19) | 0.0408 | |
C104 | 0.4648 (4) | 0.9753 (7) | 0.4725 (2) | 0.0457 | |
C105 | 0.5034 (4) | 1.0749 (7) | 0.4882 (2) | 0.0493 | |
C106 | 0.5516 (3) | 1.0521 (6) | 0.5179 (2) | 0.0384 | |
C107 | 0.7131 (3) | 0.8944 (6) | 0.54448 (18) | 0.0360 | |
C108 | 0.7632 (3) | 0.8079 (7) | 0.5551 (2) | 0.0463 | |
C109 | 0.8296 (4) | 0.8163 (8) | 0.5396 (2) | 0.0586 | |
C110 | 0.8454 (4) | 0.9117 (9) | 0.5121 (3) | 0.0656 | |
C111 | 0.7955 (4) | 0.9935 (9) | 0.4997 (3) | 0.0646 | |
C112 | 0.7285 (4) | 0.9865 (7) | 0.5152 (2) | 0.0516 | |
C119 | 0.5268 (3) | 0.5651 (6) | 0.60490 (17) | 0.0318 | |
C120 | 0.4667 (4) | 0.5214 (7) | 0.6242 (2) | 0.0490 | |
C121 | 0.4322 (5) | 0.4145 (8) | 0.6089 (3) | 0.0644 | |
C122 | 0.4569 (5) | 0.3560 (7) | 0.5746 (2) | 0.0603 | |
C123 | 0.5160 (4) | 0.3988 (7) | 0.5560 (2) | 0.0526 | |
C124 | 0.5515 (3) | 0.5040 (6) | 0.57057 (17) | 0.0359 | |
C125 | 0.5144 (3) | 0.8015 (6) | 0.64963 (16) | 0.0325 | |
C126 | 0.4539 (4) | 0.8411 (8) | 0.6290 (2) | 0.0532 | |
C127 | 0.4097 (4) | 0.9276 (9) | 0.6473 (2) | 0.0661 | |
C128 | 0.4242 (5) | 0.9753 (8) | 0.6850 (3) | 0.0642 | |
C129 | 0.4835 (4) | 0.9368 (7) | 0.7053 (2) | 0.0532 | |
C130 | 0.5277 (4) | 0.8486 (6) | 0.68794 (18) | 0.0385 | |
C131 | 0.6320 (3) | 0.6380 (5) | 0.66378 (16) | 0.0292 | |
C132 | 0.6083 (4) | 0.5446 (6) | 0.69023 (19) | 0.0447 | |
C133 | 0.6511 (4) | 0.5021 (7) | 0.7211 (2) | 0.0552 | |
C134 | 0.7178 (4) | 0.5486 (7) | 0.7253 (2) | 0.0530 | |
C135 | 0.7410 (4) | 0.6404 (7) | 0.6990 (2) | 0.0483 | |
C136 | 0.6987 (3) | 0.6867 (6) | 0.6684 (2) | 0.0394 | |
C150 | 0.7585 (8) | 1.4217 (18) | 0.5713 (4) | 0.069 (3)* | 0.346 (7) |
C151 | 0.7728 (6) | 1.3483 (12) | 0.5719 (3) | 0.069 (3)* | 0.654 (7) |
C250 | 0.6215 (6) | 1.0211 (9) | 0.6066 (3) | 0.0278 (16)* | 0.455 (9) |
C251 | 0.5600 (7) | 1.0855 (10) | 0.6149 (4) | 0.042 (2)* | 0.455 (9) |
C252 | 0.5571 (8) | 1.1704 (11) | 0.6469 (4) | 0.051 (3)* | 0.455 (9) |
C253 | 0.6174 (8) | 1.1889 (10) | 0.6706 (4) | 0.050 (3)* | 0.455 (9) |
C254 | 0.6786 (7) | 1.1252 (11) | 0.6627 (3) | 0.047 (2)* | 0.455 (9) |
C255 | 0.6802 (7) | 1.0415 (10) | 0.6305 (3) | 0.0351 (19)* | 0.455 (9) |
C260 | 0.6426 (5) | 1.0216 (8) | 0.6051 (3) | 0.0278 (16)* | 0.545 (9) |
C261 | 0.5849 (6) | 1.0946 (9) | 0.6178 (3) | 0.042 (2)* | 0.545 (9) |
C262 | 0.5914 (7) | 1.1816 (10) | 0.6498 (3) | 0.051 (3)* | 0.545 (9) |
C263 | 0.6557 (7) | 1.1943 (10) | 0.6680 (3) | 0.050 (3)* | 0.545 (9) |
C264 | 0.7122 (6) | 1.1241 (9) | 0.6553 (3) | 0.047 (2)* | 0.545 (9) |
C265 | 0.7063 (6) | 1.0370 (9) | 0.6240 (3) | 0.0351 (19)* | 0.545 (9) |
H1021 | 0.5308 | 0.7419 | 0.52634 | 0.0418* | |
H1031 | 0.4476 | 0.7817 | 0.47467 | 0.0490* | |
H1041 | 0.4292 | 0.9919 | 0.4509 | 0.0549* | |
H1051 | 0.4959 | 1.1631 | 0.4780 | 0.0592* | |
H1061 | 0.5792 | 1.1244 | 0.5292 | 0.0461* | |
H1081 | 0.7513 | 0.7378 | 0.5744 | 0.0556* | |
H1091 | 0.8662 | 0.7542 | 0.5481 | 0.0703* | |
H1101 | 0.8940 | 0.9200 | 0.5014 | 0.0787* | |
H1111 | 0.8071 | 1.0599 | 0.4792 | 0.0774* | |
H1121 | 0.6916 | 1.0464 | 0.5056 | 0.0619* | |
H1201 | 0.4484 | 0.5661 | 0.6487 | 0.0588* | |
H1211 | 0.3899 | 0.3809 | 0.6230 | 0.0773* | |
H1221 | 0.4314 | 0.2814 | 0.5631 | 0.0723* | |
H1231 | 0.5340 | 0.3537 | 0.5315 | 0.0631* | |
H1241 | 0.5943 | 0.5352 | 0.55648 | 0.0431* | |
H1261 | 0.4430 | 0.8071 | 0.6014 | 0.0639* | |
H1271 | 0.3666 | 0.9557 | 0.6328 | 0.0793* | |
H1281 | 0.3919 | 1.0381 | 0.6978 | 0.0771* | |
H1291 | 0.4944 | 0.9727 | 0.7327 | 0.0638* | |
H1301 | 0.5697 | 0.8187 | 0.70322 | 0.0462* | |
H1321 | 0.5605 | 0.5083 | 0.68688 | 0.0536* | |
H1331 | 0.6334 | 0.4368 | 0.7406 | 0.0662* | |
H1341 | 0.7490 | 0.5162 | 0.7473 | 0.0635* | |
H1351 | 0.7894 | 0.6743 | 0.7019 | 0.0581* | |
H1361 | 0.7161 | 0.7547 | 0.6498 | 0.0472* | |
H1501 | 0.7341 | 1.5053 | 0.5738 | 0.0830* | 0.3458 |
H1511 | 0.7921 | 1.2683 | 0.5837 | 0.0830* | 0.6542 |
H2511 | 0.5178 | 1.0706 | 0.5978 | 0.0503* | 0.455 |
H2521 | 0.5131 | 1.2175 | 0.6531 | 0.0615* | 0.455 |
H2531 | 0.6157 | 1.2501 | 0.6937 | 0.0595* | 0.455 |
H2541 | 0.7209 | 1.1394 | 0.6798 | 0.0566* | 0.455 |
H2551 | 0.7243 | 0.9947 | 0.6242 | 0.0421* | 0.455 |
H2611 | 0.5390 | 1.0842 | 0.6039 | 0.0503* | 0.545 |
H2621 | 0.5506 | 1.2330 | 0.6590 | 0.0615* | 0.545 |
H2631 | 0.6615 | 1.2555 | 0.6910 | 0.0595* | 0.545 |
H2641 | 0.7583 | 1.1361 | 0.6689 | 0.0566* | 0.545 |
H2651 | 0.7475 | 0.9860 | 0.6151 | 0.0421* | 0.545 |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Ru1 | 0.0188 (2) | 0.01968 (19) | 0.0300 (2) | −0.00310 (16) | 0.00191 (18) | 0.00069 (17) |
Ru2 | 0.02051 (18) | 0.01767 (18) | 0.0273 (2) | 0.00185 (15) | 0.00015 (19) | −0.00125 (18) |
Ru3 | 0.0258 (2) | 0.0251 (2) | 0.0208 (2) | 0.00260 (18) | 0.00033 (18) | −0.00194 (17) |
Ru4 | 0.01974 (19) | 0.0244 (2) | 0.0291 (2) | 0.00095 (17) | −0.00540 (17) | −0.00240 (19) |
Ru5 | 0.02066 (19) | 0.02091 (19) | 0.02142 (19) | −0.00074 (16) | −0.00036 (17) | 0.00077 (16) |
Ru6 | 0.01672 (17) | 0.02120 (18) | 0.02526 (18) | −0.00188 (14) | 0.00038 (18) | 0.00141 (19) |
Ru7 | 0.02266 (19) | 0.01865 (19) | 0.0241 (2) | 0.00135 (16) | −0.00021 (17) | 0.00207 (16) |
Ru8 | 0.0195 (2) | 0.01918 (18) | 0.0253 (2) | 0.00195 (16) | 0.00251 (17) | −0.00183 (17) |
Cl1 | 0.0619 (13) | 0.142 (2) | 0.0663 (14) | −0.0132 (15) | 0.0080 (11) | −0.0074 (15) |
Cl2 | 0.099 (2) | 0.0900 (18) | 0.0939 (18) | −0.0240 (16) | −0.0056 (15) | −0.0055 (15) |
Cl30 | 0.109 (6) | 0.119 (6) | 0.092 (5) | −0.059 (5) | 0.026 (5) | −0.021 (5) |
Cl31 | 0.059 (2) | 0.105 (3) | 0.069 (2) | −0.016 (2) | 0.0175 (17) | −0.039 (2) |
P1 | 0.0163 (5) | 0.0186 (6) | 0.0221 (6) | 0.0003 (4) | 0.0009 (6) | 0.0003 (6) |
P2 | 0.0305 (7) | 0.0291 (7) | 0.0238 (7) | 0.0001 (6) | 0.0012 (6) | 0.0025 (6) |
P3 | 0.0368 (8) | 0.0256 (7) | 0.0244 (7) | −0.0017 (6) | 0.0009 (6) | 0.0002 (6) |
O11 | 0.045 (3) | 0.020 (2) | 0.073 (3) | −0.0063 (18) | 0.006 (2) | −0.006 (2) |
O12 | 0.027 (2) | 0.049 (3) | 0.102 (4) | −0.004 (2) | 0.026 (3) | −0.006 (3) |
O13 | 0.053 (3) | 0.051 (3) | 0.029 (2) | −0.018 (2) | 0.000 (2) | 0.014 (2) |
O21 | 0.042 (2) | 0.033 (2) | 0.042 (2) | 0.0010 (19) | −0.009 (2) | −0.015 (2) |
O22 | 0.069 (3) | 0.029 (2) | 0.051 (3) | 0.003 (2) | −0.011 (2) | 0.010 (2) |
O23 | 0.033 (3) | 0.059 (3) | 0.089 (4) | 0.001 (2) | 0.014 (3) | −0.026 (3) |
O31 | 0.085 (4) | 0.075 (4) | 0.039 (3) | 0.012 (3) | −0.032 (3) | −0.021 (3) |
O32 | 0.042 (3) | 0.072 (4) | 0.064 (3) | 0.004 (3) | 0.026 (2) | −0.007 (3) |
O33 | 0.072 (3) | 0.041 (2) | 0.032 (2) | 0.004 (2) | 0.015 (2) | 0.010 (2) |
O41 | 0.037 (2) | 0.039 (3) | 0.075 (3) | −0.003 (2) | −0.008 (2) | −0.019 (2) |
O42 | 0.061 (3) | 0.062 (3) | 0.044 (3) | −0.004 (3) | −0.020 (2) | 0.016 (3) |
O43 | 0.025 (2) | 0.068 (3) | 0.095 (4) | 0.007 (2) | −0.002 (3) | −0.013 (3) |
O51 | 0.071 (3) | 0.050 (3) | 0.037 (2) | 0.015 (3) | −0.008 (2) | −0.023 (2) |
O52 | 0.033 (2) | 0.047 (3) | 0.046 (3) | 0.011 (2) | −0.0135 (19) | 0.001 (2) |
O61 | 0.047 (3) | 0.067 (3) | 0.053 (3) | −0.015 (3) | 0.002 (2) | −0.029 (3) |
O62 | 0.026 (2) | 0.037 (2) | 0.082 (4) | 0.0052 (19) | −0.015 (2) | 0.004 (2) |
O63 | 0.050 (3) | 0.051 (3) | 0.055 (3) | −0.012 (2) | 0.020 (2) | 0.014 (2) |
O71 | 0.040 (2) | 0.025 (2) | 0.077 (3) | −0.0063 (18) | −0.006 (2) | −0.001 (2) |
O72 | 0.046 (3) | 0.039 (2) | 0.059 (3) | 0.015 (2) | −0.013 (2) | 0.012 (2) |
O81 | 0.054 (3) | 0.029 (2) | 0.059 (3) | −0.012 (2) | −0.007 (2) | −0.009 (2) |
O82 | 0.039 (2) | 0.043 (2) | 0.066 (3) | 0.021 (2) | −0.003 (2) | −0.004 (2) |
O83 | 0.056 (3) | 0.043 (3) | 0.040 (2) | 0.004 (2) | 0.024 (2) | −0.002 (2) |
N1 | 0.035 (3) | 0.028 (2) | 0.028 (2) | −0.002 (2) | 0.003 (2) | 0.009 (2) |
C11 | 0.026 (3) | 0.036 (3) | 0.034 (3) | 0.000 (2) | 0.005 (2) | 0.001 (2) |
C12 | 0.038 (4) | 0.022 (3) | 0.054 (4) | −0.002 (3) | −0.002 (3) | −0.001 (3) |
C13 | 0.029 (3) | 0.025 (3) | 0.031 (3) | 0.002 (2) | 0.005 (2) | −0.003 (2) |
C21 | 0.028 (3) | 0.029 (3) | 0.037 (3) | 0.011 (2) | 0.002 (2) | 0.000 (3) |
C22 | 0.033 (3) | 0.027 (3) | 0.034 (3) | −0.002 (2) | −0.005 (2) | −0.007 (3) |
C23 | 0.033 (3) | 0.031 (3) | 0.051 (4) | 0.000 (3) | 0.005 (3) | −0.004 (3) |
C31 | 0.044 (4) | 0.040 (3) | 0.031 (3) | 0.014 (3) | −0.003 (3) | 0.001 (3) |
C32 | 0.046 (4) | 0.036 (3) | 0.039 (3) | 0.000 (3) | 0.003 (3) | −0.007 (3) |
C33 | 0.026 (3) | 0.027 (3) | 0.040 (3) | 0.009 (2) | 0.000 (2) | 0.000 (2) |
C41 | 0.033 (3) | 0.038 (4) | 0.059 (4) | 0.004 (3) | 0.001 (3) | −0.006 (3) |
C42 | 0.028 (3) | 0.041 (4) | 0.052 (4) | −0.009 (3) | −0.012 (3) | −0.005 (3) |
C43 | 0.034 (3) | 0.034 (3) | 0.058 (4) | 0.004 (3) | −0.015 (3) | −0.006 (3) |
C51 | 0.036 (3) | 0.033 (3) | 0.039 (3) | 0.006 (3) | −0.003 (3) | 0.006 (3) |
C52 | 0.033 (3) | 0.028 (3) | 0.029 (3) | 0.000 (3) | −0.001 (3) | −0.001 (2) |
C61 | 0.025 (3) | 0.041 (3) | 0.044 (4) | −0.001 (2) | 0.001 (3) | −0.007 (3) |
C62 | 0.019 (3) | 0.034 (3) | 0.045 (3) | −0.004 (2) | −0.005 (2) | −0.002 (3) |
C63 | 0.035 (3) | 0.026 (3) | 0.039 (3) | 0.001 (2) | 0.001 (3) | 0.005 (2) |
C71 | 0.027 (3) | 0.022 (3) | 0.036 (3) | 0.006 (2) | 0.000 (2) | 0.001 (2) |
C72 | 0.035 (3) | 0.033 (3) | 0.034 (3) | −0.007 (3) | −0.003 (3) | 0.001 (2) |
C81 | 0.033 (3) | 0.028 (3) | 0.037 (3) | 0.003 (2) | 0.000 (3) | 0.000 (3) |
C82 | 0.036 (3) | 0.032 (3) | 0.039 (3) | 0.003 (3) | 0.003 (3) | −0.004 (3) |
C83 | 0.034 (3) | 0.023 (3) | 0.042 (3) | 0.006 (2) | 0.007 (3) | −0.009 (3) |
C101 | 0.032 (3) | 0.028 (3) | 0.027 (3) | 0.001 (2) | 0.014 (2) | 0.006 (2) |
C102 | 0.041 (3) | 0.026 (3) | 0.038 (3) | 0.000 (3) | −0.001 (3) | 0.002 (2) |
C103 | 0.039 (3) | 0.044 (4) | 0.039 (4) | 0.000 (3) | −0.006 (3) | 0.001 (3) |
C104 | 0.042 (4) | 0.052 (4) | 0.044 (4) | 0.005 (3) | 0.000 (3) | 0.007 (3) |
C105 | 0.045 (4) | 0.048 (4) | 0.054 (4) | 0.000 (3) | −0.007 (3) | 0.024 (3) |
C106 | 0.038 (3) | 0.029 (3) | 0.048 (4) | −0.004 (3) | −0.006 (3) | 0.006 (3) |
C107 | 0.037 (3) | 0.037 (3) | 0.034 (3) | −0.010 (3) | −0.006 (3) | 0.000 (3) |
C108 | 0.041 (4) | 0.055 (4) | 0.043 (4) | 0.010 (3) | 0.007 (3) | 0.018 (3) |
C109 | 0.037 (4) | 0.074 (5) | 0.065 (5) | 0.008 (4) | 0.000 (3) | 0.012 (4) |
C110 | 0.035 (4) | 0.086 (6) | 0.075 (6) | −0.008 (4) | 0.010 (4) | 0.012 (5) |
C111 | 0.046 (4) | 0.081 (6) | 0.067 (5) | −0.007 (4) | 0.016 (4) | 0.026 (5) |
C112 | 0.049 (4) | 0.046 (4) | 0.060 (4) | −0.004 (3) | 0.009 (3) | 0.023 (3) |
C119 | 0.038 (3) | 0.030 (3) | 0.028 (3) | 0.001 (3) | 0.005 (2) | −0.001 (2) |
C120 | 0.044 (4) | 0.057 (5) | 0.046 (4) | −0.010 (4) | 0.012 (3) | −0.001 (3) |
C121 | 0.069 (6) | 0.061 (5) | 0.063 (5) | −0.030 (4) | 0.010 (4) | −0.003 (4) |
C122 | 0.075 (6) | 0.043 (4) | 0.063 (5) | −0.008 (4) | −0.004 (4) | −0.001 (4) |
C123 | 0.082 (6) | 0.036 (4) | 0.039 (4) | 0.000 (4) | −0.003 (4) | −0.006 (3) |
C124 | 0.045 (3) | 0.032 (3) | 0.030 (3) | −0.002 (3) | 0.004 (3) | 0.002 (2) |
C125 | 0.035 (3) | 0.040 (3) | 0.022 (3) | 0.004 (3) | 0.002 (2) | 0.000 (2) |
C126 | 0.052 (4) | 0.072 (5) | 0.035 (4) | 0.021 (4) | −0.009 (3) | 0.000 (3) |
C127 | 0.047 (4) | 0.090 (6) | 0.062 (5) | 0.032 (4) | −0.004 (4) | 0.003 (5) |
C128 | 0.066 (5) | 0.057 (5) | 0.069 (5) | 0.021 (4) | 0.026 (4) | −0.003 (4) |
C129 | 0.069 (5) | 0.043 (4) | 0.047 (4) | 0.008 (4) | 0.013 (4) | −0.007 (3) |
C130 | 0.045 (4) | 0.037 (3) | 0.034 (3) | 0.005 (3) | 0.000 (3) | 0.001 (3) |
C131 | 0.034 (3) | 0.031 (3) | 0.023 (3) | 0.000 (2) | −0.002 (2) | 0.007 (2) |
C132 | 0.056 (4) | 0.040 (4) | 0.039 (3) | −0.010 (3) | −0.011 (3) | 0.011 (3) |
C133 | 0.083 (5) | 0.038 (4) | 0.045 (4) | −0.016 (4) | −0.019 (4) | 0.012 (3) |
C134 | 0.073 (5) | 0.043 (4) | 0.043 (4) | 0.006 (4) | −0.025 (4) | 0.005 (3) |
C135 | 0.047 (4) | 0.051 (4) | 0.047 (4) | 0.005 (3) | −0.016 (3) | −0.002 (3) |
C136 | 0.033 (3) | 0.039 (3) | 0.046 (4) | 0.004 (3) | −0.003 (3) | 0.001 (3) |
Geometric parameters (Å, º) top
Ru1—Ru2 | 2.9643 (6) | O72—C72 | 1.147 (7) |
Ru1—Ru4 | 2.9375 (6) | O81—C81 | 1.129 (7) |
Ru1—Ru5 | 2.8215 (6) | O82—C82 | 1.155 (7) |
Ru1—Ru8 | 2.9389 (6) | O83—C83 | 1.151 (7) |
Ru1—P1 | 2.4346 (12) | C101—C102 | 1.402 (8) |
Ru1—C11 | 1.879 (6) | C101—C106 | 1.395 (8) |
Ru1—C12 | 1.896 (6) | C102—C103 | 1.375 (8) |
Ru1—C13 | 2.059 (6) | C102—H1021 | 1.000 |
Ru2—Ru3 | 2.9294 (6) | C103—C104 | 1.379 (9) |
Ru2—Ru5 | 2.9281 (6) | C103—H1031 | 1.000 |
Ru2—Ru6 | 2.9086 (5) | C104—C105 | 1.386 (10) |
Ru2—P1 | 2.4013 (12) | C104—H1041 | 1.000 |
Ru2—C21 | 1.895 (6) | C105—C106 | 1.367 (9) |
Ru2—C22 | 1.918 (6) | C105—H1051 | 1.000 |
Ru2—C23 | 1.905 (6) | C106—H1061 | 1.000 |
Ru3—Ru4 | 2.9695 (6) | C107—C108 | 1.370 (9) |
Ru3—Ru6 | 2.9041 (6) | C107—C112 | 1.401 (8) |
Ru3—Ru7 | 2.8064 (6) | C108—C109 | 1.375 (10) |
Ru3—P1 | 2.4031 (14) | C108—H1081 | 1.000 |
Ru3—C31 | 1.875 (6) | C109—C110 | 1.387 (11) |
Ru3—C32 | 1.876 (7) | C109—H1091 | 1.000 |
Ru3—C33 | 2.078 (6) | C110—C111 | 1.352 (11) |
Ru4—Ru7 | 2.9107 (6) | C110—H1101 | 1.000 |
Ru4—Ru8 | 2.9005 (6) | C111—C112 | 1.384 (10) |
Ru4—P1 | 2.3986 (13) | C111—H1111 | 1.000 |
Ru4—C41 | 1.884 (7) | C112—H1121 | 1.000 |
Ru4—C42 | 1.909 (7) | C119—C120 | 1.394 (9) |
Ru4—C43 | 1.911 (7) | C119—C124 | 1.385 (8) |
Ru5—Ru6 | 2.9367 (6) | C120—C121 | 1.400 (10) |
Ru5—Ru8 | 2.9547 (6) | C120—H1201 | 1.000 |
Ru5—P1 | 2.4160 (14) | C121—C122 | 1.372 (11) |
Ru5—C13 | 2.050 (6) | C121—H1211 | 1.000 |
Ru5—C51 | 1.862 (6) | C122—C123 | 1.366 (11) |
Ru5—C52 | 1.887 (6) | C122—H1221 | 1.000 |
Ru6—Ru7 | 2.9759 (6) | C123—C124 | 1.386 (9) |
Ru6—P1 | 2.3960 (12) | C123—H1231 | 1.000 |
Ru6—C61 | 1.899 (6) | C124—H1241 | 1.000 |
Ru6—C62 | 1.898 (6) | C125—C126 | 1.407 (9) |
Ru6—C63 | 1.914 (6) | C125—C130 | 1.381 (8) |
Ru7—Ru8 | 2.9168 (6) | C126—C127 | 1.383 (10) |
Ru7—P1 | 2.4098 (12) | C126—H1261 | 1.000 |
Ru7—C33 | 2.053 (6) | C127—C128 | 1.368 (11) |
Ru7—C71 | 1.871 (6) | C127—H1271 | 1.000 |
Ru7—C72 | 1.891 (6) | C128—C129 | 1.381 (12) |
Ru8—P1 | 2.3970 (13) | C128—H1281 | 1.000 |
Ru8—C81 | 1.900 (6) | C129—C130 | 1.383 (9) |
Ru8—C82 | 1.893 (6) | C129—H1291 | 1.000 |
Ru8—C83 | 1.896 (6) | C130—H1301 | 1.000 |
Cl1—C150 | 1.751 (15) | C131—C132 | 1.392 (8) |
Cl1—C151 | 1.814 (11) | C131—C136 | 1.387 (8) |
Cl2—C150 | 1.821 (14) | C132—C133 | 1.383 (9) |
Cl2—C151 | 1.698 (11) | C132—H1321 | 1.000 |
Cl30—C150 | 1.859 (15) | C133—C134 | 1.377 (11) |
Cl30—C151 | 1.684 (14) | C133—H1331 | 1.000 |
Cl30—H1511 | 1.630 | C134—C135 | 1.375 (10) |
Cl31—C150 | 1.374 (15) | C134—H1341 | 1.000 |
Cl31—C151 | 1.782 (11) | C135—C136 | 1.381 (9) |
Cl31—H1501 | 1.339 | C135—H1351 | 1.000 |
P2—N1 | 1.583 (5) | C136—H1361 | 1.000 |
P2—C119 | 1.799 (6) | C150—H1501 | 1.000 |
P2—C125 | 1.789 (6) | C151—H1511 | 1.000 |
P2—C131 | 1.804 (5) | C250—C251 | 1.388 (14) |
P3—N1 | 1.582 (5) | C250—C255 | 1.390 (13) |
P3—C101 | 1.794 (6) | C251—C252 | 1.385 (14) |
P3—C107 | 1.807 (6) | C251—H2511 | 1.000 |
P3—C250 | 1.817 (12) | C252—C253 | 1.408 (15) |
P3—C260 | 1.799 (10) | C252—H2521 | 1.000 |
O11—C11 | 1.151 (7) | C253—C254 | 1.377 (14) |
O12—C12 | 1.138 (7) | C253—H2531 | 1.000 |
O13—C13 | 1.171 (7) | C254—C255 | 1.381 (14) |
O21—C21 | 1.136 (7) | C254—H2541 | 1.000 |
O22—C22 | 1.144 (7) | C255—H2551 | 1.000 |
O23—C23 | 1.143 (7) | C260—C261 | 1.412 (12) |
O31—C31 | 1.133 (7) | C260—C265 | 1.380 (12) |
O32—C32 | 1.145 (8) | C261—C262 | 1.402 (13) |
O33—C33 | 1.178 (7) | C261—H2611 | 1.000 |
O41—C41 | 1.161 (7) | C262—C263 | 1.379 (13) |
O42—C42 | 1.147 (8) | C262—H2621 | 1.000 |
O43—C43 | 1.144 (7) | C263—C264 | 1.378 (13) |
O51—C51 | 1.156 (7) | C263—H2531 | 1.285 |
O52—C52 | 1.153 (7) | C263—H2631 | 1.000 |
O61—C61 | 1.132 (7) | C264—C265 | 1.386 (13) |
O62—C62 | 1.140 (7) | C264—H2641 | 1.000 |
O63—C63 | 1.141 (7) | C265—H2651 | 1.000 |
O71—C71 | 1.144 (6) | ||
Ru2—Ru1—Ru4 | 87.961 (16) | Ru4—Ru8—C83 | 125.46 (17) |
Ru2—Ru1—Ru5 | 60.748 (15) | P1—Ru8—C83 | 126.98 (17) |
Ru4—Ru1—Ru5 | 103.225 (16) | C81—Ru8—C82 | 88.6 (2) |
Ru2—Ru1—Ru8 | 101.102 (17) | C81—Ru8—C83 | 97.6 (2) |
Ru4—Ru1—Ru8 | 59.153 (14) | C82—Ru8—C83 | 93.2 (3) |
Ru5—Ru1—Ru8 | 61.680 (14) | C150—Cl30—H1511 | 61.3 |
Ru2—Ru1—P1 | 51.69 (3) | C151—Cl31—H1501 | 69.4 |
Ru4—Ru1—P1 | 52.02 (3) | Ru1—P1—Ru5 | 71.14 (4) |
Ru5—Ru1—P1 | 54.12 (3) | Ru1—P1—Ru7 | 141.43 (5) |
Ru8—Ru1—P1 | 51.96 (3) | Ru5—P1—Ru7 | 122.55 (5) |
Ru2—Ru1—C11 | 82.91 (17) | Ru1—P1—Ru3 | 122.50 (5) |
Ru4—Ru1—C11 | 120.71 (18) | Ru5—P1—Ru3 | 141.82 (5) |
Ru5—Ru1—C11 | 121.50 (18) | Ru7—P1—Ru3 | 71.34 (4) |
Ru8—Ru1—C11 | 175.93 (17) | Ru1—P1—Ru2 | 75.61 (4) |
P1—Ru1—C11 | 131.64 (17) | Ru5—P1—Ru2 | 74.87 (4) |
Ru2—Ru1—C12 | 170.83 (18) | Ru7—P1—Ru2 | 140.37 (6) |
Ru4—Ru1—C12 | 93.29 (19) | Ru3—P1—Ru2 | 75.14 (4) |
Ru5—Ru1—C12 | 127.51 (19) | Ru1—P1—Ru4 | 74.85 (4) |
Ru8—Ru1—C12 | 87.29 (17) | Ru5—P1—Ru4 | 139.34 (6) |
P1—Ru1—C12 | 134.93 (18) | Ru7—P1—Ru4 | 74.51 (4) |
Ru2—Ru1—C13 | 88.49 (15) | Ru3—P1—Ru4 | 76.40 (4) |
Ru4—Ru1—C13 | 145.46 (15) | Ru2—P1—Ru4 | 117.26 (5) |
Ru5—Ru1—C13 | 46.50 (15) | Ru1—P1—Ru8 | 74.92 (4) |
Ru8—Ru1—C13 | 87.97 (15) | Ru5—P1—Ru8 | 75.74 (4) |
P1—Ru1—C13 | 100.61 (16) | Ru7—P1—Ru8 | 74.72 (4) |
C11—Ru1—C12 | 88.7 (2) | Ru3—P1—Ru8 | 139.87 (6) |
C11—Ru1—C13 | 92.9 (2) | Ru2—P1—Ru8 | 143.61 (6) |
C12—Ru1—C13 | 95.5 (2) | Ru1—P1—Ru6 | 139.65 (6) |
Ru1—Ru2—Ru3 | 92.049 (16) | Ru5—P1—Ru6 | 75.22 (4) |
Ru1—Ru2—Ru5 | 57.214 (14) | Ru7—P1—Ru6 | 76.52 (4) |
Ru3—Ru2—Ru5 | 102.059 (16) | Ru3—P1—Ru6 | 74.48 (4) |
Ru1—Ru2—Ru6 | 101.076 (16) | Ru2—P1—Ru6 | 74.64 (3) |
Ru3—Ru2—Ru6 | 59.661 (14) | Ru4—P1—Ru8 | 74.43 (3) |
Ru5—Ru2—Ru6 | 60.415 (14) | Ru4—P1—Ru6 | 144.04 (6) |
Ru1—Ru2—P1 | 52.70 (3) | Ru8—P1—Ru6 | 117.43 (5) |
Ru3—Ru2—P1 | 52.46 (3) | N1—P2—C119 | 108.8 (3) |
Ru5—Ru2—P1 | 52.79 (4) | N1—P2—C125 | 115.7 (3) |
Ru6—Ru2—P1 | 52.60 (3) | C119—P2—C125 | 108.1 (3) |
Ru1—Ru2—C21 | 86.19 (16) | N1—P2—C131 | 110.1 (3) |
Ru3—Ru2—C21 | 76.70 (17) | C119—P2—C131 | 107.4 (3) |
Ru5—Ru2—C21 | 143.40 (16) | C125—P2—C131 | 106.4 (3) |
Ru6—Ru2—C21 | 135.81 (17) | N1—P3—C101 | 112.3 (3) |
P1—Ru2—C21 | 106.40 (16) | N1—P3—C107 | 107.4 (3) |
Ru1—Ru2—C22 | 85.13 (17) | C101—P3—C107 | 108.7 (3) |
Ru3—Ru2—C22 | 173.72 (16) | N1—P3—C250 | 111.8 (3) |
Ru5—Ru2—C22 | 81.14 (16) | C101—P3—C250 | 104.4 (4) |
Ru6—Ru2—C22 | 126.38 (16) | C107—P3—C250 | 112.4 (4) |
P1—Ru2—C22 | 128.46 (17) | N1—P3—C260 | 114.7 (3) |
Ru1—Ru2—C23 | 173.07 (17) | C101—P3—C260 | 112.9 (4) |
Ru3—Ru2—C23 | 91.5 (2) | C107—P3—C260 | 99.9 (4) |
Ru5—Ru2—C23 | 127.63 (19) | P2—N1—P3 | 138.0 (3) |
Ru6—Ru2—C23 | 85.86 (17) | Ru1—C11—O11 | 178.5 (5) |
P1—Ru2—C23 | 133.69 (18) | Ru1—C12—O12 | 178.4 (5) |
C21—Ru2—C22 | 97.5 (2) | Ru1—C13—Ru5 | 86.7 (2) |
C21—Ru2—C23 | 88.9 (2) | Ru1—C13—O13 | 136.0 (5) |
C22—Ru2—C23 | 90.7 (3) | Ru5—C13—O13 | 137.2 (5) |
Ru2—Ru3—Ru4 | 88.013 (16) | Ru2—C21—O21 | 175.0 (5) |
Ru2—Ru3—Ru6 | 59.814 (14) | Ru2—C22—O22 | 177.4 (5) |
Ru4—Ru3—Ru6 | 101.867 (17) | Ru2—C23—O23 | 173.4 (5) |
Ru2—Ru3—Ru7 | 104.188 (19) | Ru3—C31—O31 | 176.6 (6) |
Ru4—Ru3—Ru7 | 60.443 (14) | Ru3—C32—O32 | 178.5 (6) |
Ru6—Ru3—Ru7 | 62.789 (14) | Ru3—C33—Ru7 | 85.6 (2) |
Ru2—Ru3—P1 | 52.40 (3) | Ru3—C33—O33 | 136.9 (5) |
Ru4—Ru3—P1 | 51.73 (3) | Ru7—C33—O33 | 137.5 (4) |
Ru6—Ru3—P1 | 52.65 (3) | Ru4—C41—O41 | 171.1 (6) |
Ru7—Ru3—P1 | 54.44 (3) | Ru4—C42—O42 | 178.4 (5) |
Ru2—Ru3—C31 | 114.71 (19) | Ru4—C43—O43 | 175.7 (6) |
Ru4—Ru3—C31 | 83.7 (2) | O51—C51—Ru5 | 177.3 (5) |
Ru6—Ru3—C31 | 171.65 (18) | Ru5—C52—O52 | 178.3 (5) |
Ru7—Ru3—C31 | 125.56 (18) | Ru6—C61—O61 | 173.4 (6) |
P1—Ru3—C31 | 130.4 (2) | Ru6—C62—O62 | 174.9 (5) |
Ru2—Ru3—C32 | 92.3 (2) | Ru6—C63—O63 | 176.4 (6) |
Ru4—Ru3—C32 | 173.88 (19) | Ru7—C71—O71 | 176.1 (5) |
Ru6—Ru3—C32 | 83.54 (19) | Ru7—C72—O72 | 178.1 (5) |
Ru7—Ru3—C32 | 125.3 (2) | Ru8—C81—O81 | 174.8 (5) |
P1—Ru3—C32 | 132.4 (2) | Ru8—C82—O82 | 174.4 (6) |
Ru2—Ru3—C33 | 147.37 (16) | Ru8—C83—O83 | 176.6 (5) |
Ru4—Ru3—C33 | 87.77 (15) | P3—C101—C102 | 119.2 (4) |
Ru6—Ru3—C33 | 89.54 (16) | P3—C101—C106 | 122.6 (5) |
Ru7—Ru3—C33 | 46.83 (16) | C102—C101—C106 | 118.2 (5) |
P1—Ru3—C33 | 101.27 (16) | C101—C102—C103 | 120.5 (6) |
C31—Ru3—C32 | 90.6 (3) | C101—C102—H1021 | 119.7 |
C31—Ru3—C33 | 96.9 (2) | C103—C102—H1021 | 119.7 |
C32—Ru3—C33 | 95.2 (3) | C102—C103—C104 | 120.0 (6) |
Ru3—Ru4—Ru1 | 91.783 (16) | C102—C103—H1031 | 120.0 |
Ru3—Ru4—Ru7 | 57.002 (14) | C104—C103—H1031 | 120.0 |
Ru1—Ru4—Ru7 | 102.862 (17) | C103—C104—C105 | 120.3 (6) |
Ru3—Ru4—Ru8 | 100.364 (16) | C103—C104—H1041 | 119.8 |
Ru1—Ru4—Ru8 | 60.448 (14) | C105—C104—H1041 | 119.8 |
Ru7—Ru4—Ru8 | 60.255 (14) | C104—C105—C106 | 119.7 (6) |
Ru3—Ru4—P1 | 51.87 (3) | C104—C105—H1051 | 120.1 |
Ru1—Ru4—P1 | 53.13 (3) | C106—C105—H1051 | 120.1 |
Ru7—Ru4—P1 | 52.92 (3) | C101—C106—C105 | 121.2 (6) |
Ru8—Ru4—P1 | 52.76 (3) | C101—C106—H1061 | 119.4 |
Ru3—Ru4—C41 | 91.5 (2) | C105—C106—H1061 | 119.4 |
Ru1—Ru4—C41 | 72.1 (2) | P3—C107—C108 | 120.6 (5) |
Ru7—Ru4—C41 | 148.4 (2) | P3—C107—C112 | 120.0 (5) |
Ru8—Ru4—C41 | 131.2 (2) | C108—C107—C112 | 119.4 (6) |
P1—Ru4—C41 | 106.7 (2) | C107—C108—C109 | 120.7 (6) |
Ru3—Ru4—C42 | 83.3 (2) | C107—C108—H1081 | 119.6 |
Ru1—Ru4—C42 | 168.8 (2) | C109—C108—H1081 | 119.6 |
Ru7—Ru4—C42 | 82.93 (18) | C108—C109—C110 | 119.5 (7) |
Ru8—Ru4—C42 | 130.30 (19) | C108—C109—H1091 | 120.3 |
P1—Ru4—C42 | 128.19 (18) | C110—C109—H1091 | 120.3 |
Ru3—Ru4—C43 | 176.05 (19) | C109—C110—C111 | 120.4 (7) |
Ru1—Ru4—C43 | 92.16 (19) | C109—C110—H1101 | 119.8 |
Ru7—Ru4—C43 | 122.22 (18) | C111—C110—H1101 | 119.8 |
Ru8—Ru4—C43 | 81.85 (18) | C110—C111—C112 | 120.8 (7) |
P1—Ru4—C43 | 131.38 (19) | C110—C111—H1111 | 119.6 |
C41—Ru4—C42 | 97.9 (3) | C112—C111—H1111 | 119.6 |
C41—Ru4—C43 | 89.4 (3) | C107—C112—C111 | 119.1 (7) |
C42—Ru4—C43 | 92.8 (3) | C107—C112—H1121 | 120.5 |
Ru2—Ru5—Ru1 | 62.038 (14) | C111—C112—H1121 | 120.5 |
Ru2—Ru5—Ru6 | 59.464 (14) | P2—C119—C120 | 120.9 (5) |
Ru1—Ru5—Ru6 | 103.879 (18) | P2—C119—C124 | 119.1 (5) |
Ru2—Ru5—Ru8 | 101.586 (17) | C120—C119—C124 | 120.0 (6) |
Ru1—Ru5—Ru8 | 61.116 (14) | C119—C120—C121 | 119.6 (7) |
Ru6—Ru5—Ru8 | 88.099 (16) | C119—C120—H1201 | 120.2 |
Ru2—Ru5—P1 | 52.34 (3) | C121—C120—H1201 | 120.2 |
Ru1—Ru5—P1 | 54.74 (3) | C120—C121—C122 | 119.7 (7) |
Ru6—Ru5—P1 | 52.08 (3) | C120—C121—H1211 | 120.2 |
Ru8—Ru5—P1 | 51.84 (3) | C122—C121—H1211 | 120.2 |
Ru2—Ru5—C13 | 89.65 (15) | C121—C122—C123 | 120.5 (7) |
Ru1—Ru5—C13 | 46.76 (16) | C121—C122—H1221 | 119.8 |
Ru6—Ru5—C13 | 147.19 (16) | C123—C122—H1221 | 119.8 |
Ru8—Ru5—C13 | 87.70 (15) | C122—C123—C124 | 121.1 (7) |
P1—Ru5—C13 | 101.49 (16) | C122—C123—H1231 | 119.5 |
Ru2—Ru5—C51 | 176.07 (19) | C124—C123—H1231 | 119.5 |
Ru1—Ru5—C51 | 121.58 (19) | C123—C124—C119 | 119.2 (6) |
Ru6—Ru5—C51 | 119.36 (19) | C123—C124—H1241 | 120.4 |
Ru8—Ru5—C51 | 81.96 (18) | C119—C124—H1241 | 120.4 |
P1—Ru5—C51 | 130.49 (18) | P2—C125—C126 | 119.6 (5) |
Ru2—Ru5—C52 | 86.33 (17) | P2—C125—C130 | 121.1 (5) |
Ru1—Ru5—C52 | 126.03 (17) | C126—C125—C130 | 119.2 (6) |
Ru6—Ru5—C52 | 93.74 (17) | C125—C126—C127 | 119.4 (7) |
Ru8—Ru5—C52 | 171.65 (17) | C125—C126—H1261 | 120.3 |
P1—Ru5—C52 | 134.71 (17) | C127—C126—H1261 | 120.3 |
C13—Ru5—C51 | 92.2 (2) | C126—C127—C128 | 120.9 (7) |
C13—Ru5—C52 | 95.1 (2) | C126—C127—H1271 | 119.6 |
C51—Ru5—C52 | 90.0 (2) | C128—C127—H1271 | 119.5 |
Ru5—Ru6—Ru2 | 60.121 (14) | C127—C128—C129 | 120.0 (7) |
Ru5—Ru6—Ru3 | 102.465 (16) | C127—C128—H1281 | 120.0 |
Ru2—Ru6—Ru3 | 60.526 (14) | C129—C128—H1281 | 120.0 |
Ru5—Ru6—Ru7 | 91.407 (16) | C128—C129—C130 | 120.1 (7) |
Ru2—Ru6—Ru7 | 100.555 (15) | C128—C129—H1291 | 119.9 |
Ru3—Ru6—Ru7 | 56.999 (14) | C130—C129—H1291 | 119.9 |
Ru5—Ru6—P1 | 52.70 (4) | C129—C130—C125 | 120.4 (6) |
Ru2—Ru6—P1 | 52.76 (3) | C129—C130—H1301 | 119.8 |
Ru3—Ru6—P1 | 52.87 (4) | C125—C130—H1301 | 119.8 |
Ru7—Ru6—P1 | 51.95 (3) | P2—C131—C132 | 119.6 (5) |
Ru5—Ru6—C61 | 73.34 (19) | P2—C131—C136 | 120.7 (4) |
Ru2—Ru6—C61 | 131.6 (2) | C132—C131—C136 | 119.6 (6) |
Ru3—Ru6—C61 | 149.64 (18) | C131—C132—C133 | 119.8 (6) |
Ru7—Ru6—C61 | 92.74 (18) | C131—C132—H1321 | 120.1 |
P1—Ru6—C61 | 108.36 (18) | C133—C132—H1321 | 120.1 |
Ru5—Ru6—C62 | 92.29 (18) | C132—C133—C134 | 120.6 (6) |
Ru2—Ru6—C62 | 80.05 (17) | C132—C133—H1331 | 119.7 |
Ru3—Ru6—C62 | 120.61 (18) | C134—C133—H1331 | 119.7 |
Ru7—Ru6—C62 | 176.02 (18) | C133—C134—C135 | 119.2 (6) |
P1—Ru6—C62 | 129.97 (17) | C133—C134—H1341 | 120.4 |
Ru5—Ru6—C63 | 168.33 (18) | C135—C134—H1341 | 120.4 |
Ru2—Ru6—C63 | 131.34 (18) | C134—C135—C136 | 121.3 (7) |
Ru3—Ru6—C63 | 84.36 (18) | C134—C135—H1351 | 119.3 |
Ru7—Ru6—C63 | 84.37 (18) | C136—C135—H1351 | 119.3 |
P1—Ru6—C63 | 129.62 (19) | C131—C136—C135 | 119.4 (6) |
C61—Ru6—C62 | 89.7 (2) | C131—C136—H1361 | 120.3 |
C61—Ru6—C63 | 96.0 (2) | C135—C136—H1361 | 120.3 |
C62—Ru6—C63 | 92.3 (2) | Cl30—C150—Cl2 | 115.2 (9) |
Ru6—Ru7—Ru4 | 101.557 (16) | Cl30—C150—Cl1 | 106.3 (8) |
Ru6—Ru7—Ru3 | 60.212 (15) | Cl2—C150—Cl1 | 107.8 (8) |
Ru4—Ru7—Ru3 | 62.555 (15) | Cl2—C150—Cl31 | 120.4 (9) |
Ru6—Ru7—Ru8 | 88.070 (16) | Cl31—C150—C151 | 105.7 (16) |
Ru4—Ru7—Ru8 | 59.699 (14) | Cl30—C150—H1501 | 109.2 |
Ru3—Ru7—Ru8 | 103.950 (17) | Cl2—C150—H1501 | 109.1 |
Ru6—Ru7—P1 | 51.53 (3) | Cl1—C150—H1501 | 109.1 |
Ru4—Ru7—P1 | 52.57 (3) | Cl1—C151—Cl31 | 104.5 (6) |
Ru3—Ru7—P1 | 54.22 (3) | Cl1—C151—Cl2 | 110.5 (6) |
Ru8—Ru7—P1 | 52.44 (3) | Cl31—C151—Cl2 | 106.1 (6) |
Ru6—Ru7—C33 | 88.06 (15) | Cl1—C151—Cl30 | 111.3 (6) |
Ru4—Ru7—C33 | 89.85 (16) | Cl1—C151—H1511 | 111.8 |
Ru3—Ru7—C33 | 47.58 (15) | Cl31—C151—H1511 | 111.8 |
Ru8—Ru7—C33 | 147.75 (16) | Cl2—C151—H1511 | 111.8 |
P1—Ru7—C33 | 101.80 (16) | P3—C250—C251 | 124.1 (9) |
Ru6—Ru7—C71 | 83.46 (16) | P3—C250—C255 | 115.4 (8) |
Ru4—Ru7—C71 | 173.26 (16) | C251—C250—C255 | 120.1 (10) |
Ru3—Ru7—C71 | 124.16 (16) | C250—C251—C252 | 120.0 (10) |
Ru8—Ru7—C71 | 116.46 (17) | C250—C251—H2511 | 120.0 |
P1—Ru7—C71 | 130.63 (17) | C252—C251—H2511 | 120.0 |
Ru6—Ru7—C72 | 172.60 (17) | C251—C252—C253 | 118.6 (10) |
Ru4—Ru7—C72 | 85.36 (17) | C251—C252—H2521 | 120.7 |
Ru3—Ru7—C72 | 126.27 (17) | C253—C252—H2521 | 120.7 |
Ru8—Ru7—C72 | 93.25 (18) | C252—C253—C254 | 121.9 (10) |
P1—Ru7—C72 | 134.11 (18) | C252—C253—H2531 | 119.0 |
C33—Ru7—C71 | 94.8 (2) | C254—C253—H2531 | 119.1 |
C33—Ru7—C72 | 94.6 (2) | C253—C254—C255 | 118.4 (10) |
C71—Ru7—C72 | 89.4 (2) | C253—C254—H2541 | 120.8 |
Ru5—Ru8—Ru1 | 57.204 (14) | C255—C254—H2541 | 120.8 |
Ru5—Ru8—Ru7 | 92.232 (16) | C250—C255—C254 | 121.0 (10) |
Ru1—Ru8—Ru7 | 102.678 (16) | C250—C255—H2551 | 119.5 |
Ru5—Ru8—Ru4 | 100.891 (16) | C254—C255—H2551 | 119.5 |
Ru1—Ru8—Ru4 | 60.399 (14) | P3—C260—C261 | 119.2 (7) |
Ru7—Ru8—Ru4 | 60.046 (14) | P3—C260—C265 | 120.5 (7) |
Ru5—Ru8—P1 | 52.42 (3) | C261—C260—C265 | 119.7 (9) |
Ru1—Ru8—P1 | 53.12 (3) | C260—C261—C262 | 120.8 (9) |
Ru7—Ru8—P1 | 52.84 (3) | C260—C261—H2611 | 119.6 |
Ru4—Ru8—P1 | 52.81 (3) | C262—C261—H2611 | 119.6 |
Ru5—Ru8—C81 | 88.14 (17) | C261—C262—C263 | 118.0 (9) |
Ru1—Ru8—C81 | 145.33 (17) | C261—C262—H2621 | 121.0 |
Ru7—Ru8—C81 | 77.26 (18) | C263—C262—H2621 | 121.0 |
Ru4—Ru8—C81 | 136.46 (18) | C262—C263—C264 | 121.2 (10) |
P1—Ru8—C81 | 108.15 (18) | C262—C263—H2631 | 119.4 |
Ru5—Ru8—C82 | 175.43 (18) | C264—C263—H2631 | 119.4 |
Ru1—Ru8—C82 | 125.97 (18) | C263—C264—C265 | 121.2 (9) |
Ru7—Ru8—C82 | 90.14 (18) | C263—C264—H2641 | 119.4 |
Ru4—Ru8—C82 | 83.67 (18) | C265—C264—H2641 | 119.4 |
P1—Ru8—C82 | 131.82 (19) | C264—C265—C260 | 119.1 (9) |
Ru5—Ru8—C83 | 84.11 (18) | C264—C265—H2651 | 120.5 |
Ru1—Ru8—C83 | 79.50 (16) | C260—C265—H2651 | 120.4 |
Ru7—Ru8—C83 | 173.86 (18) |