[N,N-Bis(diphenyl­phosphan­yl)-(R)-1,2,3,4-tetra­hydro-1-naphthyl­amine-κ²P,P′]dichloro­platinum(II)

The title compound, [PtCl₂(C₃₄H₃₁NP₂)], crystallizes with four crystallographically independent mol­ecules. All four mol­ecules have the same R chirality, with P—Pt—P bite angles ranging from 72.14 (5) to 72.38 (5)°.

Key indicators

• Single-crystal X-ray study
• T = 150 K
• Mean [sigma](C-C) = 0.009 Å
• R factor = 0.034
• wR factor = 0.054
• Data-to-parameter ratio = 19.7

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.76 Ratio

Alert level C
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.68 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.38 Ratio
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...          9

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           27.45
           From the CIF: _reflns_number_total              28340
           Count of symmetry unique reflns        14696
           Completeness (_total/calc)            192.84%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured     13644
           Fraction of Friedel pairs measured     0.928
           Are heavy atom types Z>Si present        yes
PLAT791_ALERT_1_G Confirm the Absolute Configuration of C1     = .          R
PLAT791_ALERT_1_G Confirm the Absolute Configuration of C35    = .          R
PLAT791_ALERT_1_G Confirm the Absolute Configuration of C69    = .          R
PLAT791_ALERT_1_G Confirm the Absolute Configuration of C103   = .          R

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
   3 ALERT level C = Check and explain
   5 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: COLLECT (Hooft, 1998); cell refinement: DIRAX (Duisenberg, 1992); data reduction: EVALCCD (Duisenberg et al., 2003); program(s) used to solve structure: SHELXS86 (Sheldrick, 1985); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: PLATON.

[N,N-Bis(diphenylphosphanyl)-(R)-1,2,3,4-tetrahydro-1- naphthylamine-κ²P,P']dichloroplatinum(II)

Crystal data

[PtCl2(C34H31NP2)]	F(000) = 3072
Mr = 781.53	Dx = 1.672 Mg m^−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2yb	Cell parameters from 399 reflections
a = 19.107 (1) Å	θ = 3.7–22.4°
b = 15.9176 (7) Å	µ = 4.82 mm^−1
c = 20.8122 (11) Å	T = 150 K
β = 101.266 (5)°	Block, colourless
V = 6207.8 (5) Å^3	0.33 × 0.13 × 0.06 mm
Z = 8

Data collection

Nonius KappaCCD diffractometer	28340 independent reflections
Radiation source: Rotating Anode	21447 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.065
Detector resolution: 18.4 pixels mm^-1	θmax = 27.5°, θmin = 1.6°
φ and ω scans	h = −24→24
Absorption correction: multi-scan (SADABS; Sheldrick, 2002)	k = −20→20
Tmin = 0.44, Tmax = 0.75	l = −26→26
151899 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.034	H-atom parameters constrained
wR(F^2) = 0.054	w = 1/[σ^2(Fo^2) + (0.0146P)^2 + 3.8989P] where P = (Fo^2 + 2Fc^2)/3
S = 1.02	(Δ/σ)max = 0.002
28340 reflections	Δρmax = 1.42 e Å^−3
1441 parameters	Δρmin = −0.87 e Å^−3
1 restraint	Absolute structure: Flack (1983)
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: −0.021 (3)

Special details

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement on F² for ALL reflections except those flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The observed criterion of F² > σ(F²) is used only for calculating -R-factor-obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt1	0.26058 (1)	0.34624 (2)	0.24145 (1)	0.0154 (1)
Cl1	0.37002 (8)	0.38303 (10)	0.21276 (7)	0.0248 (5)
Cl2	0.31780 (8)	0.29968 (10)	0.34632 (7)	0.0267 (5)
P1	0.19337 (8)	0.38076 (10)	0.14647 (7)	0.0154 (5)
P2	0.14822 (7)	0.32432 (10)	0.24862 (6)	0.0163 (5)
N1	0.1150 (2)	0.3577 (3)	0.17060 (17)	0.0148 (13)
C1	0.0384 (3)	0.3669 (4)	0.1381 (2)	0.0209 (19)
C2	0.0178 (3)	0.3006 (4)	0.0848 (3)	0.0298 (19)
C3	−0.0571 (3)	0.3178 (4)	0.0454 (3)	0.038 (2)
C4	−0.0555 (3)	0.4009 (4)	0.0086 (3)	0.039 (2)
C5	−0.0237 (3)	0.4721 (4)	0.0533 (3)	0.0297 (19)
C6	0.0197 (3)	0.4571 (4)	0.1154 (3)	0.0216 (19)
C7	0.0434 (3)	0.5242 (4)	0.1564 (3)	0.0263 (19)
C8	0.0280 (3)	0.6068 (4)	0.1361 (3)	0.036 (2)
C9	−0.0127 (3)	0.6222 (4)	0.0744 (3)	0.041 (3)
C10	−0.0380 (3)	0.5553 (5)	0.0333 (3)	0.036 (3)
C11	0.2044 (3)	0.3143 (4)	0.0791 (2)	0.0205 (19)
C12	0.1863 (3)	0.2302 (4)	0.0823 (3)	0.0259 (17)
C13	0.2005 (3)	0.1756 (4)	0.0344 (3)	0.036 (2)
C14	0.2312 (3)	0.2035 (4)	−0.0167 (3)	0.037 (3)
C15	0.2487 (3)	0.2854 (4)	−0.0196 (3)	0.037 (2)
C16	0.2370 (3)	0.3414 (4)	0.0287 (2)	0.0293 (17)
C17	0.1930 (3)	0.4888 (4)	0.1206 (3)	0.0180 (17)
C18	0.2195 (3)	0.5483 (4)	0.1670 (3)	0.0252 (19)
C19	0.2121 (3)	0.6331 (4)	0.1522 (3)	0.029 (2)
C20	0.1795 (3)	0.6585 (4)	0.0896 (3)	0.027 (2)
C21	0.1548 (3)	0.5983 (4)	0.0419 (3)	0.026 (2)
C22	0.1602 (3)	0.5132 (4)	0.0569 (3)	0.0203 (17)
C23	0.1208 (3)	0.2167 (4)	0.2572 (2)	0.0199 (17)
C24	0.1727 (3)	0.1583 (4)	0.2803 (3)	0.027 (2)
C25	0.1559 (4)	0.0739 (4)	0.2843 (3)	0.034 (2)
C26	0.0887 (4)	0.0477 (4)	0.2656 (3)	0.038 (3)
C27	0.0345 (4)	0.1044 (4)	0.2426 (3)	0.040 (2)
C28	0.0499 (3)	0.1895 (4)	0.2391 (3)	0.0265 (17)
C29	0.1092 (3)	0.3913 (4)	0.3029 (2)	0.0179 (19)
C30	0.0440 (3)	0.3744 (4)	0.3209 (2)	0.0228 (19)
C31	0.0147 (3)	0.4321 (4)	0.3567 (3)	0.031 (2)
C32	0.0498 (3)	0.5060 (4)	0.3756 (3)	0.034 (3)
C33	0.1161 (3)	0.5240 (4)	0.3588 (3)	0.034 (2)
C34	0.1458 (3)	0.4652 (4)	0.3235 (3)	0.0291 (19)
Pt2	0.26526 (1)	0.34810 (2)	0.72977 (1)	0.0145 (1)
Cl3	0.37268 (7)	0.39334 (11)	0.70052 (7)	0.0280 (5)
Cl4	0.32601 (7)	0.31012 (10)	0.83520 (6)	0.0261 (5)
P3	0.19101 (7)	0.37631 (9)	0.63637 (6)	0.0142 (4)
P4	0.15723 (7)	0.31422 (9)	0.74210 (6)	0.0138 (4)
N2	0.11664 (19)	0.3487 (3)	0.66608 (15)	0.0143 (13)
C35	0.0382 (2)	0.3453 (4)	0.63799 (19)	0.0168 (14)
C36	0.0183 (3)	0.2606 (4)	0.6036 (3)	0.023 (2)
C37	−0.0552 (3)	0.2649 (4)	0.5594 (3)	0.034 (2)
C38	−0.0547 (3)	0.3312 (4)	0.5059 (2)	0.0315 (19)
C39	−0.0301 (3)	0.4144 (4)	0.5343 (3)	0.0217 (19)
C40	0.0113 (3)	0.4216 (4)	0.5973 (3)	0.0175 (19)
C41	0.0263 (3)	0.5009 (4)	0.6254 (3)	0.0251 (19)
C42	0.0033 (3)	0.5734 (3)	0.5911 (3)	0.032 (2)
C43	−0.0361 (3)	0.5661 (4)	0.5272 (3)	0.031 (2)
C44	−0.0524 (3)	0.4884 (4)	0.5003 (3)	0.0288 (19)
C45	0.1974 (3)	0.3111 (3)	0.5662 (2)	0.0140 (16)
C46	0.2520 (3)	0.2544 (4)	0.5723 (3)	0.0234 (19)
C47	0.2571 (3)	0.2001 (4)	0.5215 (3)	0.031 (2)
C48	0.2086 (4)	0.2009 (4)	0.4654 (3)	0.034 (3)
C49	0.1522 (3)	0.2590 (4)	0.4576 (3)	0.033 (2)
C50	0.1469 (3)	0.3137 (4)	0.5081 (2)	0.0232 (17)
C51	0.1867 (3)	0.4851 (4)	0.6121 (2)	0.0161 (17)
C52	0.1910 (3)	0.5433 (4)	0.6624 (3)	0.0237 (19)
C53	0.1847 (3)	0.6289 (4)	0.6479 (3)	0.0260 (19)
C54	0.1772 (3)	0.6561 (4)	0.5839 (3)	0.026 (2)
C55	0.1760 (3)	0.5980 (4)	0.5349 (3)	0.0238 (17)
C56	0.1805 (3)	0.5130 (4)	0.5478 (2)	0.0187 (17)
C57	0.1407 (3)	0.2038 (3)	0.7491 (2)	0.0158 (17)
C58	0.1471 (3)	0.1535 (3)	0.6963 (3)	0.0226 (17)
C59	0.1387 (3)	0.0657 (4)	0.6997 (3)	0.0300 (19)
C60	0.1257 (3)	0.0311 (4)	0.7571 (3)	0.0265 (19)
C61	0.1219 (3)	0.0794 (4)	0.8096 (3)	0.028 (2)
C62	0.1296 (3)	0.1677 (4)	0.8066 (3)	0.026 (2)
C63	0.1176 (3)	0.3695 (3)	0.8010 (2)	0.0142 (16)
C64	0.0485 (2)	0.3507 (4)	0.8108 (2)	0.0197 (14)
C65	0.0164 (3)	0.4002 (4)	0.8511 (2)	0.0249 (19)
C66	0.0516 (3)	0.4681 (4)	0.8821 (3)	0.030 (2)
C67	0.1200 (3)	0.4878 (4)	0.8732 (3)	0.028 (2)
C68	0.1525 (3)	0.4379 (4)	0.8330 (2)	0.0221 (19)
Pt3	0.76090 (1)	0.33169 (1)	0.24629 (1)	0.0135 (1)
Cl5	0.86932 (8)	0.28920 (10)	0.21723 (7)	0.0261 (5)
Cl6	0.81955 (7)	0.36542 (9)	0.35365 (6)	0.0214 (4)
P5	0.69155 (7)	0.30738 (9)	0.15036 (6)	0.0143 (5)
P6	0.65016 (7)	0.36232 (10)	0.25495 (6)	0.0135 (5)
N3	0.61680 (19)	0.3459 (3)	0.17361 (15)	0.0141 (13)
C69	0.5426 (3)	0.3588 (4)	0.1363 (2)	0.0175 (18)
C70	0.5098 (3)	0.2752 (4)	0.1104 (3)	0.027 (2)
C71	0.4369 (3)	0.2903 (4)	0.0653 (3)	0.034 (2)
C72	0.4501 (3)	0.3378 (6)	0.0045 (2)	0.046 (3)
C73	0.4963 (3)	0.4125 (4)	0.0209 (3)	0.035 (2)
C74	0.5391 (3)	0.4263 (4)	0.0824 (3)	0.0256 (19)
C75	0.5783 (3)	0.4989 (4)	0.0954 (3)	0.030 (2)
C76	0.5782 (4)	0.5590 (4)	0.0473 (4)	0.044 (3)
C77	0.5372 (4)	0.5463 (6)	−0.0141 (4)	0.059 (3)
C78	0.4972 (4)	0.4764 (5)	−0.0265 (3)	0.050 (3)
C79	0.6818 (3)	0.1976 (4)	0.1281 (2)	0.0167 (17)
C80	0.6575 (3)	0.1421 (4)	0.1713 (3)	0.0217 (19)
C81	0.6549 (3)	0.0564 (4)	0.1594 (3)	0.029 (2)
C82	0.6772 (3)	0.0267 (4)	0.1045 (3)	0.030 (2)
C83	0.7011 (3)	0.0796 (4)	0.0615 (3)	0.029 (2)
C84	0.7047 (3)	0.1661 (4)	0.0736 (3)	0.0213 (17)
C85	0.7078 (3)	0.3636 (4)	0.0804 (2)	0.0167 (18)
C86	0.7626 (3)	0.4220 (4)	0.0886 (3)	0.0228 (19)
C87	0.7725 (3)	0.4724 (4)	0.0365 (3)	0.031 (2)
C88	0.7262 (3)	0.4645 (4)	−0.0239 (3)	0.029 (2)
C89	0.6717 (3)	0.4071 (4)	−0.0325 (3)	0.026 (2)
C90	0.6623 (3)	0.3555 (4)	0.0187 (2)	0.0203 (16)
C91	0.6082 (3)	0.2915 (4)	0.3036 (2)	0.0157 (17)
C92	0.5344 (3)	0.2859 (4)	0.3011 (3)	0.0249 (19)
C93	0.5082 (3)	0.2285 (4)	0.3400 (3)	0.034 (3)
C94	0.5525 (3)	0.1759 (4)	0.3816 (3)	0.034 (2)
C95	0.6257 (3)	0.1817 (4)	0.3849 (3)	0.038 (3)
C96	0.6539 (3)	0.2385 (4)	0.3471 (3)	0.0255 (19)
C97	0.6301 (3)	0.4692 (3)	0.2751 (2)	0.0165 (17)
C98	0.6773 (3)	0.5301 (4)	0.2637 (3)	0.033 (2)
C99	0.6652 (3)	0.6144 (4)	0.2758 (3)	0.041 (3)
C100	0.6063 (3)	0.6368 (4)	0.3007 (3)	0.029 (2)
C101	0.5601 (4)	0.5761 (4)	0.3134 (3)	0.039 (3)
C102	0.5715 (3)	0.4916 (4)	0.3006 (3)	0.031 (2)
Pt4	0.23842 (1)	0.83716 (2)	0.24990 (1)	0.0157 (1)
Cl7	0.12980 (8)	0.79129 (11)	0.27604 (7)	0.0307 (5)
Cl8	0.17972 (7)	0.87803 (10)	0.14418 (6)	0.0268 (5)
P7	0.30760 (7)	0.80968 (9)	0.34595 (6)	0.0147 (5)
P8	0.34942 (7)	0.87032 (10)	0.24329 (6)	0.0146 (5)
N4	0.38138 (19)	0.8523 (3)	0.32450 (16)	0.0139 (13)
C103	0.4538 (3)	0.8723 (3)	0.3645 (2)	0.0171 (17)
C104	0.4902 (3)	0.7933 (4)	0.3965 (3)	0.0249 (19)
C105	0.5585 (3)	0.8176 (4)	0.4442 (2)	0.0262 (19)
C106	0.5406 (3)	0.8676 (4)	0.4999 (2)	0.0284 (19)
C107	0.4922 (3)	0.9405 (4)	0.4772 (3)	0.0269 (19)
C108	0.4498 (3)	0.9431 (4)	0.4140 (2)	0.0184 (17)
C109	0.4056 (3)	1.0126 (3)	0.3952 (3)	0.0224 (17)
C110	0.4020 (3)	1.0783 (3)	0.4392 (3)	0.029 (2)
C111	0.4432 (3)	1.0750 (4)	0.5014 (3)	0.037 (3)
C112	0.4876 (3)	1.0075 (4)	0.5197 (3)	0.033 (2)
C113	0.3226 (3)	0.7002 (4)	0.3646 (3)	0.0207 (19)
C114	0.3501 (3)	0.6505 (4)	0.3201 (3)	0.027 (2)
C115	0.3553 (3)	0.5645 (4)	0.3281 (3)	0.033 (2)
C116	0.3332 (3)	0.5270 (4)	0.3806 (3)	0.031 (2)
C117	0.3062 (3)	0.5735 (4)	0.4247 (3)	0.035 (2)
C118	0.3007 (3)	0.6615 (4)	0.4172 (3)	0.027 (2)
C119	0.2882 (3)	0.8617 (4)	0.4177 (2)	0.0179 (18)
C120	0.2306 (3)	0.9152 (4)	0.4101 (3)	0.0237 (17)
C121	0.2190 (4)	0.9629 (4)	0.4635 (3)	0.039 (3)
C122	0.2633 (4)	0.9562 (5)	0.5232 (3)	0.045 (3)
C123	0.3208 (4)	0.9001 (4)	0.5314 (3)	0.039 (2)
C124	0.3331 (3)	0.8530 (4)	0.4789 (2)	0.0262 (16)
C125	0.3932 (3)	0.8001 (4)	0.1951 (2)	0.0168 (17)
C126	0.3491 (3)	0.7554 (4)	0.1455 (3)	0.0229 (19)
C127	0.3774 (3)	0.6969 (4)	0.1084 (3)	0.030 (2)
C128	0.4504 (3)	0.6835 (4)	0.1201 (3)	0.034 (2)
C129	0.4948 (3)	0.7299 (4)	0.1674 (3)	0.028 (2)
C130	0.4668 (3)	0.7870 (4)	0.2058 (3)	0.0218 (19)
C131	0.3692 (3)	0.9767 (4)	0.2221 (2)	0.0172 (17)
C132	0.3151 (3)	1.0359 (4)	0.2142 (3)	0.0244 (19)
C133	0.3292 (3)	1.1194 (4)	0.2022 (3)	0.029 (2)
C134	0.3968 (3)	1.1442 (4)	0.1985 (3)	0.034 (2)
C135	0.4506 (4)	1.0855 (4)	0.2048 (3)	0.039 (3)
C136	0.4377 (3)	1.0013 (4)	0.2163 (3)	0.031 (2)
H1	0.00980	0.35430	0.17240	0.0250*
H2A	0.01910	0.24420	0.10510	0.0360*
H2B	0.05250	0.30130	0.05520	0.0360*
H3A	−0.09160	0.32140	0.07510	0.0450*
H3B	−0.07210	0.27160	0.01390	0.0450*
H4A	−0.02730	0.39340	−0.02610	0.0460*
H4B	−0.10480	0.41610	−0.01290	0.0460*
H7	0.07050	0.51380	0.19910	0.0310*
H8	0.04530	0.65230	0.16430	0.0420*
H9	−0.02340	0.67830	0.06020	0.0500*
H10	−0.06550	0.56640	−0.00900	0.0430*
H12	0.16460	0.21020	0.11670	0.0310*
H13	0.18890	0.11780	0.03670	0.0430*
H14	0.23990	0.16550	−0.04940	0.0440*
H15	0.26920	0.30510	−0.05490	0.0440*
H16	0.25140	0.39830	0.02710	0.0350*
H18	0.24300	0.53110	0.20950	0.0300*
H19	0.22930	0.67390	0.18480	0.0350*
H20	0.17420	0.71660	0.07930	0.0320*
H21	0.13400	0.61560	−0.00140	0.0310*
H22	0.14200	0.47230	0.02480	0.0250*
H24	0.22080	0.17600	0.29370	0.0320*
H25	0.19250	0.03450	0.30050	0.0410*
H26	0.07780	−0.01030	0.26820	0.0450*
H27	−0.01320	0.08510	0.22910	0.0480*
H28	0.01280	0.22890	0.22460	0.0320*
H30	0.01990	0.32300	0.30830	0.0270*
H31	−0.02990	0.42090	0.36860	0.0370*
H32	0.02890	0.54570	0.40040	0.0400*
H33	0.13980	0.57550	0.37150	0.0410*
H34	0.19140	0.47510	0.31320	0.0350*
H35	0.01380	0.34630	0.67640	0.0200*
H36A	0.05430	0.24570	0.57720	0.0270*
H36B	0.01850	0.21610	0.63690	0.0270*
H37A	−0.09140	0.27980	0.58560	0.0400*
H37B	−0.06780	0.20930	0.53900	0.0400*
H38A	−0.02280	0.31230	0.47660	0.0380*
H38B	−0.10340	0.33690	0.47930	0.0380*
H41	0.05280	0.50500	0.66900	0.0300*
H42	0.01400	0.62710	0.61050	0.0380*
H43	−0.05150	0.61520	0.50240	0.0380*
H44	−0.07990	0.48470	0.45710	0.0340*
H46	0.28680	0.25220	0.61170	0.0280*
H47	0.29570	0.16150	0.52650	0.0370*
H48	0.21240	0.16250	0.43120	0.0400*
H49	0.11790	0.26080	0.41780	0.0390*
H50	0.10880	0.35290	0.50320	0.0280*
H52	0.19810	0.52480	0.70670	0.0280*
H53	0.18570	0.66860	0.68220	0.0320*
H54	0.17280	0.71430	0.57390	0.0310*
H55	0.17200	0.61690	0.49100	0.0290*
H56	0.17940	0.47380	0.51320	0.0230*
H58	0.15730	0.17820	0.65760	0.0270*
H59	0.14200	0.03100	0.66330	0.0360*
H60	0.11910	−0.02790	0.75960	0.0320*
H61	0.11420	0.05390	0.84890	0.0340*
H62	0.12710	0.20170	0.84360	0.0310*
H64	0.02380	0.30350	0.78950	0.0240*
H65	−0.03030	0.38720	0.85730	0.0300*
H66	0.02930	0.50190	0.90990	0.0350*
H67	0.14430	0.53520	0.89460	0.0340*
H68	0.19940	0.45110	0.82730	0.0270*
H69	0.51380	0.38020	0.16820	0.0210*
H70A	0.50370	0.23890	0.14750	0.0320*
H70B	0.54200	0.24610	0.08570	0.0320*
H71A	0.41310	0.23600	0.05220	0.0410*
H71B	0.40590	0.32380	0.08840	0.0410*
H72A	0.47260	0.29910	−0.02270	0.0550*
H72B	0.40360	0.35580	−0.02180	0.0550*
H75	0.60580	0.50800	0.13810	0.0360*
H76	0.60620	0.60840	0.05660	0.0530*
H77	0.53710	0.58680	−0.04770	0.0710*
H78	0.46830	0.46950	−0.06880	0.0600*
H80	0.64270	0.16350	0.20920	0.0260*
H81	0.63810	0.01890	0.18850	0.0350*
H82	0.67590	−0.03200	0.09620	0.0360*
H83	0.71520	0.05760	0.02360	0.0350*
H84	0.72260	0.20290	0.04470	0.0260*
H86	0.79350	0.42770	0.13000	0.0270*
H87	0.81050	0.51180	0.04190	0.0370*
H88	0.73240	0.49930	−0.05940	0.0350*
H89	0.64020	0.40270	−0.07380	0.0310*
H90	0.62520	0.31470	0.01220	0.0240*
H92	0.50260	0.32160	0.27260	0.0300*
H93	0.45820	0.22530	0.33800	0.0410*
H94	0.53350	0.13620	0.40760	0.0410*
H95	0.65690	0.14580	0.41380	0.0460*
H96	0.70410	0.24210	0.35030	0.0310*
H98	0.71850	0.51450	0.24730	0.0400*
H99	0.69740	0.65620	0.26690	0.0490*
H100	0.59770	0.69420	0.30900	0.0350*
H101	0.51970	0.59160	0.33110	0.0470*
H102	0.53910	0.44990	0.30940	0.0370*
H10A	0.50180	0.75530	0.36240	0.0300*
H10B	0.45770	0.76330	0.42030	0.0300*
H10C	0.58500	0.76630	0.46130	0.0320*
H10D	0.58940	0.85130	0.42100	0.0320*
H10E	0.51720	0.83030	0.52750	0.0340*
H10F	0.58530	0.88890	0.52740	0.0340*
H103	0.48360	0.89360	0.33350	0.0210*
H109	0.37780	1.01520	0.35210	0.0270*
H110	0.37130	1.12480	0.42620	0.0340*
H111	0.44080	1.11920	0.53160	0.0450*
H112	0.51610	1.00640	0.56260	0.0400*
H114	0.36550	0.67620	0.28400	0.0320*
H115	0.37390	0.53120	0.29750	0.0390*
H116	0.33700	0.46780	0.38590	0.0380*
H117	0.29120	0.54690	0.46050	0.0420*
H118	0.28190	0.69420	0.44800	0.0330*
H120	0.19900	0.91970	0.36890	0.0290*
H121	0.17970	1.00050	0.45820	0.0470*
H122	0.25520	0.98930	0.55900	0.0540*
H123	0.35140	0.89440	0.57300	0.0470*
H124	0.37190	0.81470	0.48450	0.0320*
H126	0.29910	0.76520	0.13700	0.0280*
H127	0.34690	0.66600	0.07520	0.0360*
H128	0.47000	0.64240	0.09570	0.0400*
H129	0.54500	0.72260	0.17360	0.0330*
H130	0.49760	0.81710	0.23930	0.0260*
H132	0.26810	1.01930	0.21700	0.0290*
H133	0.29160	1.15940	0.19650	0.0350*
H134	0.40660	1.20170	0.19170	0.0410*
H135	0.49730	1.10270	0.20130	0.0470*
H136	0.47500	0.96110	0.22010	0.0360*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.0116 (1)	0.0162 (2)	0.0176 (1)	0.0015 (1)	0.0008 (1)	−0.0009 (2)
Cl1	0.0156 (8)	0.0266 (10)	0.0339 (8)	0.0010 (7)	0.0088 (6)	−0.0018 (7)
Cl2	0.0246 (9)	0.0279 (10)	0.0233 (7)	0.0037 (7)	−0.0058 (6)	0.0034 (6)
P1	0.0156 (8)	0.0151 (9)	0.0156 (7)	0.0002 (6)	0.0032 (6)	−0.0008 (6)
P2	0.0142 (7)	0.0191 (10)	0.0156 (6)	−0.0002 (7)	0.0029 (5)	0.0003 (6)
N1	0.012 (2)	0.020 (3)	0.0119 (18)	−0.003 (2)	0.0015 (16)	0.001 (2)
C1	0.015 (3)	0.028 (4)	0.019 (3)	−0.004 (3)	0.002 (2)	−0.005 (2)
C2	0.020 (3)	0.036 (4)	0.031 (3)	−0.004 (3)	−0.001 (3)	−0.011 (3)
C3	0.025 (3)	0.064 (5)	0.021 (3)	−0.005 (3)	−0.003 (2)	−0.011 (3)
C4	0.023 (4)	0.072 (5)	0.017 (3)	0.002 (3)	−0.005 (3)	−0.006 (3)
C5	0.014 (3)	0.053 (4)	0.025 (3)	0.006 (3)	0.011 (2)	0.008 (3)
C6	0.009 (3)	0.041 (4)	0.015 (3)	0.002 (3)	0.003 (2)	0.002 (3)
C7	0.020 (3)	0.032 (4)	0.027 (3)	0.007 (3)	0.005 (3)	0.002 (3)
C8	0.026 (4)	0.032 (4)	0.053 (4)	0.002 (3)	0.019 (3)	−0.002 (3)
C9	0.034 (4)	0.034 (4)	0.061 (5)	0.015 (3)	0.022 (4)	0.024 (4)
C10	0.021 (4)	0.053 (5)	0.033 (4)	0.011 (3)	0.006 (3)	0.017 (3)
C11	0.018 (3)	0.023 (4)	0.022 (3)	0.000 (3)	0.008 (2)	−0.005 (2)
C12	0.020 (3)	0.028 (3)	0.030 (3)	0.001 (3)	0.006 (3)	−0.011 (3)
C13	0.027 (4)	0.024 (4)	0.055 (4)	−0.004 (3)	0.005 (3)	−0.019 (3)
C14	0.037 (4)	0.035 (5)	0.042 (4)	−0.002 (3)	0.019 (3)	−0.023 (3)
C15	0.035 (4)	0.053 (5)	0.027 (3)	0.006 (3)	0.017 (3)	−0.007 (3)
C16	0.029 (3)	0.031 (3)	0.030 (3)	0.004 (3)	0.011 (2)	−0.008 (3)
C17	0.015 (3)	0.014 (3)	0.025 (3)	0.000 (3)	0.004 (2)	0.000 (2)
C18	0.023 (3)	0.032 (4)	0.019 (3)	0.000 (3)	0.000 (2)	0.002 (3)
C19	0.029 (4)	0.022 (4)	0.034 (3)	−0.009 (3)	0.002 (3)	−0.002 (3)
C20	0.019 (4)	0.019 (4)	0.041 (4)	−0.002 (3)	0.000 (3)	0.006 (3)
C21	0.030 (4)	0.029 (4)	0.019 (3)	−0.001 (3)	0.005 (3)	0.005 (3)
C22	0.022 (3)	0.022 (3)	0.019 (3)	−0.002 (3)	0.009 (2)	−0.001 (2)
C23	0.022 (3)	0.018 (3)	0.019 (3)	0.004 (3)	0.002 (2)	0.000 (2)
C24	0.026 (4)	0.026 (4)	0.030 (3)	−0.001 (3)	0.010 (3)	0.001 (3)
C25	0.036 (4)	0.016 (4)	0.053 (4)	0.006 (3)	0.013 (3)	0.009 (3)
C26	0.049 (5)	0.018 (4)	0.052 (4)	−0.002 (3)	0.023 (4)	0.009 (3)
C27	0.042 (4)	0.041 (4)	0.040 (4)	−0.023 (3)	0.013 (3)	−0.004 (3)
C28	0.025 (3)	0.023 (3)	0.031 (3)	−0.006 (3)	0.004 (3)	−0.001 (3)
C29	0.021 (3)	0.023 (4)	0.010 (3)	0.006 (3)	0.004 (2)	0.004 (2)
C30	0.018 (3)	0.028 (4)	0.022 (3)	0.001 (3)	0.003 (2)	0.004 (2)
C31	0.019 (3)	0.046 (5)	0.030 (3)	0.002 (3)	0.010 (3)	−0.005 (3)
C32	0.033 (4)	0.039 (5)	0.033 (4)	0.006 (3)	0.014 (3)	−0.014 (3)
C33	0.036 (4)	0.039 (4)	0.027 (3)	−0.007 (3)	0.008 (3)	−0.018 (3)
C34	0.021 (3)	0.040 (4)	0.026 (3)	−0.007 (3)	0.004 (3)	−0.015 (3)
Pt2	0.0113 (1)	0.0183 (1)	0.0136 (1)	0.0008 (1)	0.0015 (1)	−0.0025 (1)
Cl3	0.0144 (8)	0.0434 (11)	0.0273 (8)	−0.0037 (7)	0.0069 (6)	−0.0002 (7)
Cl4	0.0216 (8)	0.0397 (10)	0.0157 (6)	0.0071 (7)	0.0004 (6)	−0.0003 (6)
P3	0.0137 (8)	0.0159 (9)	0.0126 (6)	−0.0005 (6)	0.0019 (6)	−0.0017 (6)
P4	0.0136 (7)	0.0154 (9)	0.0121 (6)	−0.0006 (6)	0.0017 (5)	−0.0016 (5)
N2	0.011 (2)	0.021 (3)	0.0103 (17)	0.002 (3)	0.0003 (15)	0.000 (3)
C35	0.010 (2)	0.025 (3)	0.014 (2)	−0.007 (3)	−0.0009 (18)	0.001 (3)
C36	0.019 (4)	0.025 (4)	0.022 (4)	−0.006 (3)	−0.003 (3)	−0.001 (3)
C37	0.028 (4)	0.032 (4)	0.036 (4)	−0.011 (3)	−0.006 (3)	0.000 (3)
C38	0.025 (3)	0.040 (4)	0.025 (3)	0.005 (3)	−0.006 (2)	−0.001 (3)
C39	0.016 (3)	0.029 (4)	0.020 (3)	0.005 (3)	0.003 (2)	0.000 (3)
C40	0.013 (3)	0.023 (4)	0.017 (3)	0.004 (3)	0.004 (3)	0.003 (3)
C41	0.017 (3)	0.035 (4)	0.024 (3)	−0.003 (3)	0.006 (2)	−0.005 (3)
C42	0.024 (3)	0.019 (4)	0.056 (4)	0.007 (3)	0.018 (3)	0.002 (3)
C43	0.027 (4)	0.029 (4)	0.041 (4)	0.017 (3)	0.015 (3)	0.018 (3)
C44	0.019 (3)	0.044 (4)	0.024 (3)	0.008 (3)	0.006 (2)	0.010 (3)
C45	0.015 (3)	0.015 (3)	0.011 (2)	0.000 (2)	0.000 (2)	−0.001 (2)
C46	0.021 (3)	0.030 (4)	0.018 (3)	−0.002 (3)	0.001 (2)	−0.003 (2)
C47	0.033 (4)	0.034 (4)	0.027 (3)	0.004 (3)	0.008 (3)	−0.009 (3)
C48	0.050 (5)	0.025 (4)	0.032 (4)	−0.004 (3)	0.022 (3)	−0.012 (3)
C49	0.050 (4)	0.034 (4)	0.012 (3)	−0.012 (3)	0.001 (3)	−0.004 (3)
C50	0.031 (3)	0.019 (3)	0.020 (3)	−0.003 (3)	0.006 (2)	−0.001 (2)
C51	0.015 (3)	0.015 (3)	0.019 (3)	−0.002 (3)	0.005 (2)	−0.002 (2)
C52	0.029 (4)	0.020 (3)	0.021 (3)	0.001 (3)	0.002 (3)	0.002 (2)
C53	0.035 (4)	0.015 (3)	0.028 (3)	−0.005 (3)	0.006 (3)	−0.009 (3)
C54	0.027 (4)	0.019 (4)	0.031 (3)	0.005 (3)	0.002 (3)	0.005 (3)
C55	0.023 (3)	0.024 (3)	0.023 (3)	0.002 (3)	0.001 (3)	0.007 (3)
C56	0.020 (3)	0.022 (3)	0.014 (3)	0.003 (3)	0.003 (2)	−0.003 (2)
C57	0.013 (3)	0.016 (3)	0.016 (3)	0.000 (2)	−0.003 (2)	0.003 (2)
C58	0.023 (3)	0.025 (3)	0.020 (3)	0.000 (2)	0.005 (2)	−0.001 (2)
C59	0.026 (3)	0.022 (3)	0.039 (4)	0.001 (3)	−0.001 (3)	−0.002 (3)
C60	0.023 (3)	0.019 (3)	0.037 (4)	0.003 (3)	0.005 (3)	0.007 (3)
C61	0.025 (4)	0.025 (4)	0.037 (4)	0.006 (3)	0.011 (3)	0.011 (3)
C62	0.032 (4)	0.024 (4)	0.025 (3)	0.004 (3)	0.015 (3)	0.001 (3)
C63	0.014 (3)	0.018 (3)	0.009 (2)	0.001 (2)	−0.002 (2)	0.002 (2)
C64	0.014 (2)	0.029 (3)	0.015 (2)	0.001 (3)	0.0002 (18)	−0.002 (3)
C65	0.016 (3)	0.044 (4)	0.015 (3)	0.001 (3)	0.004 (2)	−0.006 (3)
C66	0.029 (4)	0.039 (4)	0.025 (3)	0.010 (3)	0.015 (3)	−0.008 (3)
C67	0.032 (4)	0.031 (4)	0.023 (3)	−0.007 (3)	0.007 (3)	−0.013 (3)
C68	0.021 (3)	0.033 (4)	0.013 (3)	−0.004 (3)	0.005 (2)	−0.005 (2)
Pt3	0.0106 (1)	0.0142 (2)	0.0150 (1)	0.0001 (1)	0.0008 (1)	0.0016 (1)
Cl5	0.0151 (8)	0.0319 (10)	0.0328 (8)	0.0058 (7)	0.0081 (7)	0.0012 (7)
Cl6	0.0210 (7)	0.0243 (9)	0.0163 (6)	−0.0045 (6)	−0.0030 (5)	0.0024 (6)
P5	0.0129 (8)	0.0148 (9)	0.0147 (7)	0.0005 (6)	0.0018 (6)	0.0008 (6)
P6	0.0107 (7)	0.0153 (10)	0.0142 (6)	0.0028 (6)	0.0016 (5)	0.0007 (6)
N3	0.011 (2)	0.019 (3)	0.0113 (17)	0.000 (3)	−0.0001 (15)	0.003 (3)
C69	0.012 (3)	0.027 (4)	0.012 (2)	0.005 (3)	−0.001 (2)	0.002 (2)
C70	0.022 (4)	0.026 (4)	0.029 (3)	−0.003 (3)	−0.006 (3)	−0.004 (3)
C71	0.016 (3)	0.052 (5)	0.030 (3)	−0.007 (3)	−0.005 (3)	−0.008 (3)
C72	0.019 (3)	0.093 (7)	0.022 (3)	0.003 (5)	−0.005 (2)	0.001 (5)
C73	0.024 (4)	0.058 (5)	0.023 (3)	0.012 (3)	0.006 (3)	0.014 (3)
C74	0.020 (3)	0.032 (4)	0.027 (3)	0.008 (3)	0.010 (3)	0.012 (3)
C75	0.030 (4)	0.023 (4)	0.040 (4)	0.013 (3)	0.013 (3)	0.009 (3)
C76	0.045 (5)	0.028 (4)	0.067 (5)	0.015 (3)	0.032 (4)	0.022 (4)
C77	0.047 (5)	0.073 (6)	0.061 (5)	0.021 (5)	0.020 (4)	0.046 (5)
C78	0.029 (4)	0.091 (7)	0.030 (4)	0.024 (4)	0.003 (3)	0.029 (4)
C79	0.011 (3)	0.016 (3)	0.021 (3)	0.000 (3)	−0.002 (2)	−0.002 (2)
C80	0.020 (3)	0.022 (4)	0.023 (3)	−0.001 (3)	0.004 (3)	0.005 (3)
C81	0.025 (4)	0.019 (4)	0.041 (4)	−0.001 (3)	0.004 (3)	0.007 (3)
C82	0.019 (4)	0.015 (4)	0.052 (4)	0.004 (3)	−0.001 (3)	−0.003 (3)
C83	0.030 (4)	0.024 (4)	0.032 (4)	0.007 (3)	0.004 (3)	−0.010 (3)
C84	0.022 (3)	0.016 (3)	0.024 (3)	0.002 (3)	0.000 (3)	0.004 (2)
C85	0.019 (3)	0.016 (4)	0.016 (2)	0.002 (3)	0.006 (2)	0.001 (2)
C86	0.023 (3)	0.023 (4)	0.021 (3)	0.002 (3)	0.001 (3)	0.004 (3)
C87	0.031 (4)	0.029 (4)	0.033 (4)	−0.008 (3)	0.010 (3)	0.010 (3)
C88	0.042 (4)	0.030 (4)	0.019 (3)	0.001 (3)	0.014 (3)	0.015 (3)
C89	0.040 (4)	0.024 (4)	0.014 (3)	0.005 (3)	0.007 (3)	0.002 (2)
C90	0.027 (3)	0.013 (3)	0.021 (2)	0.001 (3)	0.005 (2)	−0.003 (3)
C91	0.013 (3)	0.015 (3)	0.019 (3)	−0.005 (2)	0.003 (2)	−0.002 (2)
C92	0.023 (3)	0.025 (4)	0.026 (3)	0.001 (3)	0.003 (3)	0.002 (3)
C93	0.018 (4)	0.047 (5)	0.039 (4)	−0.011 (3)	0.012 (3)	0.004 (3)
C94	0.027 (4)	0.047 (5)	0.029 (3)	−0.008 (3)	0.008 (3)	0.017 (3)
C95	0.030 (4)	0.048 (5)	0.036 (4)	−0.002 (3)	0.004 (3)	0.023 (3)
C96	0.016 (3)	0.030 (4)	0.030 (3)	0.000 (3)	0.003 (3)	0.010 (3)
C97	0.021 (3)	0.013 (3)	0.013 (3)	0.003 (3)	−0.003 (2)	−0.002 (2)
C98	0.016 (3)	0.024 (4)	0.064 (5)	0.004 (3)	0.018 (3)	−0.006 (3)
C99	0.030 (4)	0.024 (4)	0.070 (5)	−0.007 (3)	0.013 (4)	−0.010 (3)
C100	0.029 (4)	0.016 (4)	0.038 (4)	0.003 (3)	−0.002 (3)	−0.009 (3)
C101	0.045 (5)	0.033 (5)	0.044 (4)	0.015 (3)	0.022 (4)	−0.005 (3)
C102	0.040 (4)	0.018 (3)	0.039 (4)	−0.001 (3)	0.020 (3)	−0.002 (3)
Pt4	0.0110 (1)	0.0182 (2)	0.0174 (1)	−0.0002 (1)	0.0014 (1)	0.0005 (1)
Cl7	0.0155 (8)	0.0448 (12)	0.0320 (8)	−0.0070 (8)	0.0052 (7)	0.0046 (8)
Cl8	0.0191 (8)	0.0388 (11)	0.0201 (7)	0.0017 (7)	−0.0020 (6)	0.0041 (6)
P7	0.0145 (8)	0.0135 (9)	0.0161 (7)	−0.0007 (6)	0.0030 (6)	0.0006 (6)
P8	0.0110 (7)	0.0176 (10)	0.0148 (6)	−0.0006 (6)	0.0018 (6)	0.0001 (6)
N4	0.016 (2)	0.016 (3)	0.0103 (17)	−0.003 (2)	0.0042 (16)	0.001 (2)
C103	0.017 (3)	0.019 (3)	0.016 (3)	−0.001 (2)	0.005 (2)	0.000 (2)
C104	0.030 (4)	0.021 (3)	0.022 (3)	0.004 (3)	0.001 (3)	−0.003 (2)
C105	0.017 (3)	0.033 (4)	0.025 (3)	0.006 (3)	−0.005 (2)	0.003 (3)
C106	0.023 (3)	0.036 (4)	0.023 (3)	0.000 (3)	−0.003 (2)	−0.004 (3)
C107	0.021 (3)	0.038 (4)	0.022 (3)	−0.007 (3)	0.005 (3)	−0.008 (3)
C108	0.015 (3)	0.024 (3)	0.018 (3)	−0.010 (3)	0.008 (2)	−0.005 (2)
C109	0.025 (3)	0.018 (3)	0.023 (3)	−0.003 (3)	0.002 (2)	−0.003 (2)
C110	0.031 (4)	0.016 (4)	0.042 (4)	−0.003 (3)	0.015 (3)	−0.005 (3)
C111	0.038 (4)	0.035 (5)	0.038 (4)	−0.011 (3)	0.007 (3)	−0.024 (3)
C112	0.023 (4)	0.052 (5)	0.024 (3)	−0.010 (3)	0.004 (3)	−0.015 (3)
C113	0.013 (3)	0.020 (4)	0.026 (3)	−0.003 (3)	−0.004 (2)	0.002 (3)
C114	0.034 (4)	0.019 (4)	0.025 (3)	0.004 (3)	0.000 (3)	−0.003 (3)
C115	0.036 (4)	0.020 (3)	0.036 (4)	0.004 (3)	−0.008 (3)	−0.007 (3)
C116	0.030 (4)	0.013 (3)	0.043 (4)	−0.006 (3)	−0.012 (3)	0.007 (3)
C117	0.033 (4)	0.029 (4)	0.043 (4)	−0.003 (3)	0.006 (3)	0.012 (3)
C118	0.022 (4)	0.030 (4)	0.032 (4)	−0.005 (3)	0.010 (3)	0.001 (3)
C119	0.024 (3)	0.015 (4)	0.018 (2)	−0.005 (3)	0.012 (2)	0.000 (2)
C120	0.022 (3)	0.020 (3)	0.031 (3)	−0.001 (3)	0.010 (3)	0.001 (3)
C121	0.041 (4)	0.025 (4)	0.062 (5)	−0.003 (3)	0.038 (4)	−0.004 (3)
C122	0.073 (6)	0.036 (5)	0.037 (4)	−0.014 (4)	0.035 (4)	−0.008 (3)
C123	0.062 (5)	0.040 (4)	0.020 (3)	−0.012 (4)	0.019 (3)	−0.004 (3)
C124	0.034 (3)	0.027 (3)	0.019 (2)	−0.006 (3)	0.009 (2)	0.002 (3)
C125	0.015 (3)	0.017 (3)	0.017 (3)	−0.001 (3)	0.000 (2)	0.003 (2)
C126	0.017 (3)	0.027 (4)	0.024 (3)	0.003 (3)	0.002 (3)	−0.002 (3)
C127	0.037 (4)	0.027 (4)	0.021 (3)	0.004 (3)	−0.005 (3)	−0.004 (3)
C128	0.039 (4)	0.038 (5)	0.027 (3)	0.005 (4)	0.015 (3)	−0.004 (3)
C129	0.022 (4)	0.029 (4)	0.035 (4)	0.002 (3)	0.011 (3)	−0.004 (3)
C130	0.013 (3)	0.028 (4)	0.023 (3)	0.001 (3)	0.000 (2)	−0.005 (3)
C131	0.019 (3)	0.022 (3)	0.011 (3)	−0.003 (3)	0.004 (2)	0.000 (2)
C132	0.019 (3)	0.027 (4)	0.027 (3)	0.004 (3)	0.004 (3)	−0.002 (3)
C133	0.030 (4)	0.018 (4)	0.038 (4)	0.009 (3)	0.005 (3)	0.007 (3)
C134	0.037 (4)	0.023 (4)	0.045 (4)	−0.009 (3)	0.013 (3)	0.007 (3)
C135	0.030 (4)	0.030 (4)	0.064 (5)	−0.007 (3)	0.024 (4)	0.008 (3)
C136	0.024 (3)	0.029 (4)	0.042 (4)	0.008 (3)	0.014 (3)	0.002 (3)

Geometric parameters (Å, º)

Pt1—Cl1	2.3580 (16)	C43—H43	0.9500
Pt1—Cl2	2.3613 (15)	C44—H44	0.9500
Pt1—P1	2.2061 (15)	C46—H46	0.9500
Pt1—P2	2.2087 (14)	C47—H47	0.9500
Pt2—Cl3	2.3644 (14)	C48—H48	0.9500
Pt2—Cl4	2.3521 (13)	C49—H49	0.9500
Pt2—P3	2.2171 (13)	C50—H50	0.9500
Pt2—P4	2.1964 (14)	C52—H52	0.9500
Pt3—Cl5	2.3673 (16)	C53—H53	0.9500
Pt3—Cl6	2.3577 (13)	C54—H54	0.9500
Pt3—P6	2.2128 (14)	C55—H55	0.9500
Pt3—P5	2.2040 (13)	C56—H56	0.9500
Pt4—P8	2.2158 (14)	C58—H58	0.9500
Pt4—Cl8	2.3575 (13)	C59—H59	0.9500
Pt4—Cl7	2.3617 (16)	C60—H60	0.9500
Pt4—P7	2.2142 (13)	C61—H61	0.9500
P1—C11	1.801 (5)	C62—H62	0.9500
P1—N1	1.710 (4)	C64—H64	0.9500
P1—C17	1.802 (7)	C65—H65	0.9500
P2—N1	1.709 (4)	C66—H66	0.9500
P2—C23	1.810 (6)	C67—H67	0.9500
P2—C29	1.816 (6)	C68—H68	0.9500
P3—N2	1.714 (4)	C69—C74	1.545 (8)
P3—C45	1.815 (5)	C69—C70	1.524 (9)
P3—C51	1.801 (6)	C70—C71	1.539 (8)
P4—N2	1.711 (4)	C71—C72	1.537 (9)
P4—C57	1.797 (5)	C72—C73	1.481 (10)
P4—C63	1.793 (5)	C73—C74	1.395 (9)
P5—C79	1.808 (6)	C73—C78	1.419 (10)
P5—C85	1.787 (5)	C74—C75	1.375 (9)
P5—N3	1.709 (4)	C75—C76	1.384 (10)
P6—N3	1.708 (3)	C76—C77	1.377 (11)
P6—C91	1.804 (6)	C77—C78	1.346 (12)
P6—C97	1.811 (5)	C79—C80	1.403 (8)
P7—N4	1.701 (4)	C79—C84	1.387 (8)
P7—C113	1.796 (7)	C80—C81	1.386 (9)
P7—C119	1.808 (5)	C81—C82	1.379 (9)
P8—C131	1.808 (6)	C82—C83	1.371 (9)
P8—N4	1.705 (4)	C83—C84	1.399 (9)
P8—C125	1.812 (6)	C85—C90	1.409 (6)
N1—C1	1.495 (7)	C85—C86	1.386 (9)
N2—C35	1.500 (5)	C86—C87	1.391 (9)
N3—C69	1.492 (6)	C87—C88	1.394 (9)
N4—C103	1.503 (6)	C88—C89	1.371 (9)
C1—C2	1.526 (8)	C89—C90	1.385 (8)
C1—C6	1.532 (9)	C91—C92	1.404 (8)
C2—C3	1.529 (8)	C91—C96	1.409 (8)
C3—C4	1.532 (9)	C92—C93	1.378 (9)
C4—C5	1.516 (9)	C93—C94	1.371 (9)
C5—C6	1.413 (9)	C94—C95	1.390 (8)
C5—C10	1.399 (10)	C95—C96	1.376 (9)
C6—C7	1.387 (9)	C97—C102	1.377 (8)
C7—C8	1.395 (9)	C97—C98	1.376 (8)
C8—C9	1.387 (9)	C98—C99	1.393 (9)
C9—C10	1.392 (10)	C99—C100	1.375 (8)
C11—C16	1.389 (7)	C100—C101	1.369 (9)
C11—C12	1.388 (9)	C101—C102	1.397 (9)
C12—C13	1.389 (9)	C69—H69	1.0000
C13—C14	1.384 (9)	C70—H70B	0.9900
C14—C15	1.350 (9)	C70—H70A	0.9900
C15—C16	1.394 (8)	C71—H71A	0.9900
C17—C22	1.406 (9)	C71—H71B	0.9900
C17—C18	1.377 (9)	C72—H72B	0.9900
C18—C19	1.386 (9)	C72—H72A	0.9900
C19—C20	1.390 (9)	C75—H75	0.9500
C20—C21	1.394 (9)	C76—H76	0.9500
C21—C22	1.389 (9)	C77—H77	0.9500
C23—C28	1.402 (8)	C78—H78	0.9500
C23—C24	1.376 (9)	C80—H80	0.9500
C24—C25	1.388 (9)	C81—H81	0.9500
C25—C26	1.334 (11)	C82—H82	0.9500
C26—C27	1.387 (10)	C83—H83	0.9500
C27—C28	1.391 (9)	C84—H84	0.9500
C29—C30	1.395 (8)	C86—H86	0.9500
C29—C34	1.393 (9)	C87—H87	0.9500
C30—C31	1.369 (8)	C88—H88	0.9500
C31—C32	1.373 (9)	C89—H89	0.9500
C32—C33	1.408 (8)	C90—H90	0.9500
C33—C34	1.379 (9)	C92—H92	0.9500
C1—H1	1.0000	C93—H93	0.9500
C2—H2A	0.9900	C94—H94	0.9500
C2—H2B	0.9900	C95—H95	0.9500
C3—H3A	0.9900	C96—H96	0.9500
C3—H3B	0.9900	C98—H98	0.9500
C4—H4A	0.9900	C99—H99	0.9500
C4—H4B	0.9900	C100—H100	0.9500
C7—H7	0.9500	C101—H101	0.9500
C8—H8	0.9500	C102—H102	0.9500
C9—H9	0.9500	C103—C104	1.526 (8)
C10—H10	0.9500	C103—C108	1.539 (7)
C12—H12	0.9500	C104—C105	1.527 (8)
C13—H13	0.9500	C105—C106	1.500 (7)
C14—H14	0.9500	C106—C107	1.501 (9)
C15—H15	0.9500	C107—C108	1.404 (8)
C16—H16	0.9500	C107—C112	1.399 (9)
C18—H18	0.9500	C108—C109	1.400 (8)
C19—H19	0.9500	C109—C110	1.401 (8)
C20—H20	0.9500	C110—C111	1.378 (9)
C21—H21	0.9500	C111—C112	1.376 (9)
C22—H22	0.9500	C113—C114	1.396 (9)
C24—H24	0.9500	C113—C118	1.390 (9)
C25—H25	0.9500	C114—C115	1.380 (9)
C26—H26	0.9500	C115—C116	1.382 (9)
C27—H27	0.9500	C116—C117	1.357 (9)
C28—H28	0.9500	C117—C118	1.411 (9)
C30—H30	0.9500	C119—C120	1.376 (9)
C31—H31	0.9500	C119—C124	1.397 (6)
C32—H32	0.9500	C120—C121	1.399 (9)
C33—H33	0.9500	C121—C122	1.364 (9)
C34—H34	0.9500	C122—C123	1.400 (11)
C35—C36	1.539 (9)	C123—C124	1.383 (8)
C35—C40	1.512 (8)	C125—C126	1.394 (8)
C36—C37	1.523 (8)	C125—C130	1.396 (8)
C37—C38	1.536 (8)	C126—C127	1.385 (9)
C38—C39	1.489 (9)	C127—C128	1.385 (8)
C39—C40	1.397 (9)	C128—C129	1.381 (9)
C39—C44	1.397 (9)	C129—C130	1.385 (9)
C40—C41	1.397 (9)	C131—C132	1.385 (9)
C41—C42	1.383 (8)	C131—C136	1.394 (8)
C42—C43	1.399 (9)	C132—C133	1.389 (9)
C43—C44	1.368 (9)	C133—C134	1.367 (8)
C45—C46	1.367 (8)	C134—C135	1.376 (9)
C45—C50	1.393 (7)	C135—C136	1.392 (9)
C46—C47	1.384 (9)	C103—H103	1.0000
C47—C48	1.341 (9)	C104—H10A	0.9900
C48—C49	1.405 (9)	C104—H10B	0.9900
C49—C50	1.384 (8)	C105—H10C	0.9900
C51—C52	1.388 (8)	C105—H10D	0.9900
C51—C56	1.393 (6)	C106—H10E	0.9900
C52—C53	1.396 (9)	C106—H10F	0.9900
C53—C54	1.381 (9)	C109—H109	0.9500
C54—C55	1.374 (9)	C110—H110	0.9500
C55—C56	1.379 (9)	C111—H111	0.9500
C57—C62	1.381 (8)	C112—H112	0.9500
C57—C58	1.384 (7)	C114—H114	0.9500
C58—C59	1.410 (8)	C115—H115	0.9500
C59—C60	1.381 (9)	C116—H116	0.9500
C60—C61	1.350 (9)	C117—H117	0.9500
C61—C62	1.416 (9)	C118—H118	0.9500
C63—C64	1.407 (7)	C120—H120	0.9500
C63—C68	1.378 (8)	C121—H121	0.9500
C64—C65	1.379 (7)	C122—H122	0.9500
C65—C66	1.367 (9)	C123—H123	0.9500
C66—C67	1.391 (8)	C124—H124	0.9500
C67—C68	1.386 (8)	C126—H126	0.9500
C35—H35	1.0000	C127—H127	0.9500
C36—H36A	0.9900	C128—H128	0.9500
C36—H36B	0.9900	C129—H129	0.9500
C37—H37A	0.9900	C130—H130	0.9500
C37—H37B	0.9900	C132—H132	0.9500
C38—H38A	0.9900	C133—H133	0.9500
C38—H38B	0.9900	C134—H134	0.9500
C41—H41	0.9500	C135—H135	0.9500
C42—H42	0.9500	C136—H136	0.9500
Cl1—Pt1—Cl2	92.22 (5)	C43—C44—H44	119.00
Cl1—Pt1—P1	95.80 (5)	C39—C44—H44	119.00
Cl1—Pt1—P2	168.00 (5)	C45—C46—H46	120.00
Cl2—Pt1—P1	171.79 (6)	C47—C46—H46	120.00
Cl2—Pt1—P2	99.71 (5)	C46—C47—H47	119.00
P1—Pt1—P2	72.33 (5)	C48—C47—H47	119.00
P3—Pt2—P4	72.37 (5)	C47—C48—H48	120.00
Cl3—Pt2—P4	171.03 (5)	C49—C48—H48	120.00
Cl3—Pt2—Cl4	91.34 (5)	C48—C49—H49	120.00
Cl3—Pt2—P3	98.72 (5)	C50—C49—H49	120.00
Cl4—Pt2—P3	169.94 (5)	C45—C50—H50	120.00
Cl4—Pt2—P4	97.57 (5)	C49—C50—H50	120.00
P5—Pt3—P6	72.38 (5)	C51—C52—H52	120.00
Cl5—Pt3—P5	96.88 (5)	C53—C52—H52	120.00
Cl5—Pt3—P6	169.18 (5)	C54—C53—H53	120.00
Cl5—Pt3—Cl6	91.69 (5)	C52—C53—H53	120.00
Cl6—Pt3—P6	99.07 (5)	C53—C54—H54	120.00
Cl6—Pt3—P5	171.42 (5)	C55—C54—H54	120.00
Cl8—Pt4—P8	99.38 (5)	C56—C55—H55	119.00
P7—Pt4—P8	72.14 (5)	C54—C55—H55	119.00
Cl7—Pt4—Cl8	91.21 (5)	C55—C56—H56	120.00
Cl7—Pt4—P7	97.32 (5)	C51—C56—H56	120.00
Cl7—Pt4—P8	169.36 (5)	C57—C58—H58	120.00
Cl8—Pt4—P7	171.26 (5)	C59—C58—H58	120.00
C11—P1—C17	108.8 (3)	C58—C59—H59	121.00
N1—P1—C17	109.9 (3)	C60—C59—H59	121.00
Pt1—P1—C11	114.52 (19)	C61—C60—H60	119.00
Pt1—P1—N1	94.20 (14)	C59—C60—H60	119.00
N1—P1—C11	110.2 (2)	C62—C61—H61	120.00
Pt1—P1—C17	118.2 (2)	C60—C61—H61	120.00
Pt1—P2—C29	118.2 (2)	C61—C62—H62	121.00
Pt1—P2—N1	94.14 (14)	C57—C62—H62	120.00
C23—P2—C29	109.4 (3)	C65—C64—H64	120.00
N1—P2—C29	106.7 (2)	C63—C64—H64	120.00
Pt1—P2—C23	117.4 (2)	C64—C65—H65	120.00
N1—P2—C23	109.1 (2)	C66—C65—H65	120.00
Pt2—P3—C45	117.23 (17)	C65—C66—H66	120.00
N2—P3—C45	109.5 (2)	C67—C66—H66	120.00
Pt2—P3—N2	93.75 (12)	C66—C67—H67	120.00
N2—P3—C51	110.6 (2)	C68—C67—H67	120.00
C45—P3—C51	109.3 (2)	C67—C68—H68	120.00
Pt2—P3—C51	115.27 (16)	C63—C68—H68	120.00
Pt2—P4—N2	94.58 (14)	N3—C69—C70	110.3 (5)
Pt2—P4—C57	115.7 (2)	N3—C69—C74	112.1 (5)
C57—P4—C63	108.7 (2)	C70—C69—C74	113.2 (4)
Pt2—P4—C63	119.44 (19)	C69—C70—C71	109.9 (5)
N2—P4—C57	109.5 (2)	C70—C71—C72	107.7 (5)
N2—P4—C63	107.4 (2)	C71—C72—C73	113.1 (4)
Pt3—P5—C79	114.54 (16)	C72—C73—C78	120.2 (5)
Pt3—P5—C85	118.73 (19)	C72—C73—C74	123.7 (5)
Pt3—P5—N3	93.92 (12)	C74—C73—C78	116.1 (6)
N3—P5—C85	109.8 (2)	C73—C74—C75	120.8 (6)
N3—P5—C79	111.7 (2)	C69—C74—C73	119.4 (5)
C79—P5—C85	107.5 (2)	C69—C74—C75	119.8 (5)
Pt3—P6—N3	93.62 (14)	C74—C75—C76	121.0 (6)
C91—P6—C97	108.6 (3)	C75—C76—C77	119.3 (7)
Pt3—P6—C97	118.4 (2)	C76—C77—C78	119.9 (8)
N3—P6—C97	108.6 (2)	C73—C78—C77	122.9 (6)
Pt3—P6—C91	116.4 (2)	C80—C79—C84	119.6 (6)
N3—P6—C91	109.9 (2)	P5—C79—C80	118.4 (4)
N4—P7—C113	109.8 (3)	P5—C79—C84	121.7 (4)
Pt4—P7—C119	118.21 (19)	C79—C80—C81	120.7 (6)
C113—P7—C119	108.4 (3)	C80—C81—C82	118.7 (6)
Pt4—P7—C113	115.4 (2)	C81—C82—C83	121.8 (6)
Pt4—P7—N4	93.64 (13)	C82—C83—C84	119.9 (6)
N4—P7—C119	110.4 (2)	C79—C84—C83	119.4 (6)
C125—P8—C131	107.6 (3)	C86—C85—C90	119.4 (5)
Pt4—P8—C125	116.0 (2)	P5—C85—C90	121.5 (5)
Pt4—P8—N4	93.45 (14)	P5—C85—C86	118.9 (4)
N4—P8—C125	109.3 (2)	C85—C86—C87	120.4 (5)
Pt4—P8—C131	119.1 (2)	C86—C87—C88	119.5 (6)
N4—P8—C131	110.4 (2)	C87—C88—C89	120.7 (6)
P1—N1—C1	133.0 (3)	C88—C89—C90	120.3 (6)
P2—N1—C1	127.6 (3)	C85—C90—C89	119.8 (6)
P1—N1—P2	99.3 (2)	P6—C91—C96	116.6 (4)
P4—N2—C35	125.9 (3)	C92—C91—C96	118.5 (5)
P3—N2—C35	134.8 (3)	P6—C91—C92	124.9 (4)
P3—N2—P4	99.09 (19)	C91—C92—C93	119.9 (5)
P6—N3—C69	128.9 (3)	C92—C93—C94	121.7 (6)
P5—N3—P6	99.49 (19)	C93—C94—C95	118.8 (6)
P5—N3—C69	131.6 (3)	C94—C95—C96	121.2 (6)
P8—N4—C103	128.8 (3)	C91—C96—C95	119.9 (5)
P7—N4—P8	99.9 (2)	C98—C97—C102	119.6 (5)
P7—N4—C103	131.3 (3)	P6—C97—C98	116.5 (4)
N1—C1—C2	110.6 (5)	P6—C97—C102	123.9 (4)
C2—C1—C6	114.4 (4)	C97—C98—C99	120.7 (5)
N1—C1—C6	112.3 (5)	C98—C99—C100	119.7 (6)
C1—C2—C3	110.3 (5)	C99—C100—C101	119.7 (6)
C2—C3—C4	108.4 (5)	C100—C101—C102	120.8 (6)
C3—C4—C5	112.6 (5)	C97—C102—C101	119.5 (6)
C4—C5—C6	121.9 (6)	C74—C69—H69	107.00
C4—C5—C10	119.6 (5)	N3—C69—H69	107.00
C6—C5—C10	118.5 (6)	C70—C69—H69	107.00
C1—C6—C5	120.0 (5)	H70A—C70—H70B	108.00
C5—C6—C7	119.7 (6)	C69—C70—H70A	110.00
C1—C6—C7	120.3 (5)	C69—C70—H70B	110.00
C6—C7—C8	121.0 (6)	C71—C70—H70A	110.00
C7—C8—C9	119.6 (6)	C71—C70—H70B	110.00
C8—C9—C10	119.9 (6)	C70—C71—H71B	110.00
C5—C10—C9	121.1 (6)	C72—C71—H71A	110.00
C12—C11—C16	119.3 (5)	C70—C71—H71A	110.00
P1—C11—C16	122.9 (5)	C72—C71—H71B	110.00
P1—C11—C12	117.5 (4)	H71A—C71—H71B	109.00
C11—C12—C13	118.9 (5)	H72A—C72—H72B	108.00
C12—C13—C14	121.5 (6)	C73—C72—H72A	109.00
C13—C14—C15	119.3 (6)	C73—C72—H72B	109.00
C14—C15—C16	120.6 (6)	C71—C72—H72A	109.00
C11—C16—C15	120.3 (6)	C71—C72—H72B	109.00
P1—C17—C18	117.9 (5)	C74—C75—H75	119.00
C18—C17—C22	120.4 (6)	C76—C75—H75	120.00
P1—C17—C22	121.4 (5)	C77—C76—H76	120.00
C17—C18—C19	120.5 (6)	C75—C76—H76	120.00
C18—C19—C20	120.0 (6)	C76—C77—H77	120.00
C19—C20—C21	119.7 (6)	C78—C77—H77	120.00
C20—C21—C22	120.7 (6)	C73—C78—H78	119.00
C17—C22—C21	118.8 (6)	C77—C78—H78	119.00
P2—C23—C28	123.3 (5)	C81—C80—H80	120.00
C24—C23—C28	118.6 (6)	C79—C80—H80	120.00
P2—C23—C24	118.1 (4)	C80—C81—H81	121.00
C23—C24—C25	121.1 (6)	C82—C81—H81	121.00
C24—C25—C26	120.4 (6)	C81—C82—H82	119.00
C25—C26—C27	120.6 (6)	C83—C82—H82	119.00
C26—C27—C28	120.0 (7)	C84—C83—H83	120.00
C23—C28—C27	119.3 (6)	C82—C83—H83	120.00
C30—C29—C34	120.1 (5)	C79—C84—H84	120.00
P2—C29—C30	123.4 (5)	C83—C84—H84	120.00
P2—C29—C34	116.4 (4)	C85—C86—H86	120.00
C29—C30—C31	119.9 (6)	C87—C86—H86	120.00
C30—C31—C32	120.1 (6)	C88—C87—H87	120.00
C31—C32—C33	121.1 (6)	C86—C87—H87	120.00
C32—C33—C34	118.6 (6)	C89—C88—H88	120.00
C29—C34—C33	120.2 (5)	C87—C88—H88	120.00
N1—C1—H1	106.00	C88—C89—H89	120.00
C2—C1—H1	106.00	C90—C89—H89	120.00
C6—C1—H1	106.00	C85—C90—H90	120.00
H2A—C2—H2B	108.00	C89—C90—H90	120.00
C1—C2—H2A	110.00	C93—C92—H92	120.00
C1—C2—H2B	110.00	C91—C92—H92	120.00
C3—C2—H2B	110.00	C94—C93—H93	119.00
C3—C2—H2A	110.00	C92—C93—H93	119.00
C2—C3—H3A	110.00	C93—C94—H94	121.00
C4—C3—H3A	110.00	C95—C94—H94	121.00
C4—C3—H3B	110.00	C94—C95—H95	119.00
C2—C3—H3B	110.00	C96—C95—H95	119.00
H3A—C3—H3B	108.00	C91—C96—H96	120.00
C5—C4—H4B	109.00	C95—C96—H96	120.00
C3—C4—H4A	109.00	C97—C98—H98	120.00
C3—C4—H4B	109.00	C99—C98—H98	120.00
C5—C4—H4A	109.00	C98—C99—H99	120.00
H4A—C4—H4B	108.00	C100—C99—H99	120.00
C8—C7—H7	119.00	C101—C100—H100	120.00
C6—C7—H7	120.00	C99—C100—H100	120.00
C9—C8—H8	120.00	C100—C101—H101	120.00
C7—C8—H8	120.00	C102—C101—H101	120.00
C8—C9—H9	120.00	C101—C102—H102	120.00
C10—C9—H9	120.00	C97—C102—H102	120.00
C5—C10—H10	120.00	N4—C103—C104	111.0 (4)
C9—C10—H10	119.00	N4—C103—C108	111.4 (4)
C13—C12—H12	120.00	C104—C103—C108	112.9 (4)
C11—C12—H12	121.00	C103—C104—C105	109.5 (5)
C12—C13—H13	119.00	C104—C105—C106	110.0 (5)
C14—C13—H13	119.00	C105—C106—C107	112.7 (4)
C15—C14—H14	120.00	C106—C107—C108	121.7 (5)
C13—C14—H14	120.00	C106—C107—C112	120.1 (5)
C16—C15—H15	120.00	C108—C107—C112	118.3 (6)
C14—C15—H15	120.00	C103—C108—C107	120.7 (5)
C11—C16—H16	120.00	C103—C108—C109	119.8 (4)
C15—C16—H16	120.00	C107—C108—C109	119.4 (5)
C19—C18—H18	120.00	C108—C109—C110	120.7 (5)
C17—C18—H18	120.00	C109—C110—C111	119.6 (5)
C20—C19—H19	120.00	C110—C111—C112	119.9 (6)
C18—C19—H19	120.00	C107—C112—C111	122.1 (6)
C21—C20—H20	120.00	P7—C113—C114	118.1 (5)
C19—C20—H20	120.00	P7—C113—C118	122.7 (5)
C20—C21—H21	120.00	C114—C113—C118	118.8 (6)
C22—C21—H21	120.00	C113—C114—C115	120.6 (6)
C17—C22—H22	121.00	C114—C115—C116	119.9 (6)
C21—C22—H22	121.00	C115—C116—C117	121.0 (6)
C25—C24—H24	119.00	C116—C117—C118	119.8 (6)
C23—C24—H24	119.00	C113—C118—C117	120.0 (6)
C24—C25—H25	120.00	P7—C119—C120	118.5 (4)
C26—C25—H25	120.00	P7—C119—C124	121.3 (5)
C27—C26—H26	120.00	C120—C119—C124	120.1 (5)
C25—C26—H26	120.00	C119—C120—C121	119.5 (6)
C26—C27—H27	120.00	C120—C121—C122	121.0 (7)
C28—C27—H27	120.00	C121—C122—C123	119.6 (6)
C27—C28—H28	120.00	C122—C123—C124	120.0 (6)
C23—C28—H28	120.00	C119—C124—C123	119.9 (6)
C31—C30—H30	120.00	P8—C125—C126	116.6 (4)
C29—C30—H30	120.00	P8—C125—C130	124.3 (4)
C32—C31—H31	120.00	C126—C125—C130	119.1 (5)
C30—C31—H31	120.00	C125—C126—C127	120.7 (5)
C31—C32—H32	119.00	C126—C127—C128	119.7 (6)
C33—C32—H32	120.00	C127—C128—C129	120.0 (6)
C34—C33—H33	121.00	C128—C129—C130	120.6 (5)
C32—C33—H33	121.00	C125—C130—C129	119.8 (5)
C29—C34—H34	120.00	P8—C131—C132	118.7 (4)
C33—C34—H34	120.00	P8—C131—C136	121.9 (5)
C36—C35—C40	114.7 (4)	C132—C131—C136	119.4 (6)
N2—C35—C36	110.5 (4)	C131—C132—C133	120.4 (5)
N2—C35—C40	113.2 (4)	C132—C133—C134	120.4 (6)
C35—C36—C37	110.9 (5)	C133—C134—C135	119.7 (6)
C36—C37—C38	109.5 (5)	C134—C135—C136	121.1 (7)
C37—C38—C39	111.7 (4)	C131—C136—C135	119.1 (6)
C38—C39—C40	121.5 (5)	N4—C103—H103	107.00
C40—C39—C44	117.8 (6)	C104—C103—H103	107.00
C38—C39—C44	120.5 (5)	C108—C103—H103	107.00
C39—C40—C41	119.9 (6)	C103—C104—H10A	110.00
C35—C40—C39	121.9 (5)	C103—C104—H10B	110.00
C35—C40—C41	118.2 (5)	C105—C104—H10A	110.00
C40—C41—C42	121.3 (6)	C105—C104—H10B	110.00
C41—C42—C43	118.6 (5)	H10A—C104—H10B	108.00
C42—C43—C44	120.1 (6)	C104—C105—H10C	110.00
C39—C44—C43	122.2 (6)	C104—C105—H10D	110.00
P3—C45—C46	118.2 (4)	C106—C105—H10C	110.00
P3—C45—C50	122.5 (4)	C106—C105—H10D	110.00
C46—C45—C50	119.2 (5)	H10C—C105—H10D	108.00
C45—C46—C47	120.5 (5)	C105—C106—H10E	109.00
C46—C47—C48	121.3 (6)	C105—C106—H10F	109.00
C47—C48—C49	119.4 (6)	C107—C106—H10E	109.00
C48—C49—C50	119.7 (5)	C107—C106—H10F	109.00
C45—C50—C49	120.0 (5)	H10E—C106—H10F	108.00
P3—C51—C56	124.5 (4)	C108—C109—H109	120.00
P3—C51—C52	115.9 (4)	C110—C109—H109	120.00
C52—C51—C56	119.6 (6)	C109—C110—H110	120.00
C51—C52—C53	119.9 (6)	C111—C110—H110	120.00
C52—C53—C54	120.2 (6)	C110—C111—H111	120.00
C53—C54—C55	119.2 (6)	C112—C111—H111	120.00
C54—C55—C56	121.7 (5)	C107—C112—H112	119.00
C51—C56—C55	119.4 (5)	C111—C112—H112	119.00
P4—C57—C62	122.5 (4)	C113—C114—H114	120.00
P4—C57—C58	117.2 (4)	C115—C114—H114	120.00
C58—C57—C62	120.0 (5)	C114—C115—H115	120.00
C57—C58—C59	120.3 (5)	C116—C115—H115	120.00
C58—C59—C60	118.7 (6)	C115—C116—H116	119.00
C59—C60—C61	121.4 (6)	C117—C116—H116	120.00
C60—C61—C62	120.5 (6)	C116—C117—H117	120.00
C57—C62—C61	119.1 (5)	C118—C117—H117	120.00
P4—C63—C64	121.9 (4)	C113—C118—H118	120.00
C64—C63—C68	118.5 (5)	C117—C118—H118	120.00
P4—C63—C68	119.3 (4)	C119—C120—H120	120.00
C63—C64—C65	120.5 (5)	C121—C120—H120	120.00
C64—C65—C66	120.2 (5)	C120—C121—H121	120.00
C65—C66—C67	120.3 (6)	C122—C121—H121	119.00
C66—C67—C68	119.7 (6)	C121—C122—H122	120.00
C63—C68—C67	120.9 (5)	C123—C122—H122	120.00
C40—C35—H35	106.00	C122—C123—H123	120.00
C36—C35—H35	106.00	C124—C123—H123	120.00
N2—C35—H35	106.00	C119—C124—H124	120.00
C35—C36—H36B	110.00	C123—C124—H124	120.00
C35—C36—H36A	109.00	C125—C126—H126	120.00
H36A—C36—H36B	108.00	C127—C126—H126	120.00
C37—C36—H36A	110.00	C126—C127—H127	120.00
C37—C36—H36B	109.00	C128—C127—H127	120.00
C38—C37—H37A	110.00	C127—C128—H128	120.00
C36—C37—H37A	110.00	C129—C128—H128	120.00
C36—C37—H37B	110.00	C128—C129—H129	120.00
C38—C37—H37B	110.00	C130—C129—H129	120.00
H37A—C37—H37B	108.00	C125—C130—H130	120.00
C37—C38—H38B	109.00	C129—C130—H130	120.00
C39—C38—H38A	109.00	C131—C132—H132	120.00
C39—C38—H38B	109.00	C133—C132—H132	120.00
H38A—C38—H38B	108.00	C132—C133—H133	120.00
C37—C38—H38A	109.00	C134—C133—H133	120.00
C40—C41—H41	119.00	C133—C134—H134	120.00
C42—C41—H41	119.00	C135—C134—H134	120.00
C43—C42—H42	121.00	C134—C135—H135	120.00
C41—C42—H42	121.00	C136—C135—H135	119.00
C44—C43—H43	120.00	C131—C136—H136	120.00
C42—C43—H43	120.00	C135—C136—H136	121.00

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C15—H15···Cl4^i	0.95	2.72	3.635 (6)	162
C24—H24···Cl2	0.95	2.78	3.626 (6)	149
C38—H38B···Cl6^ii	0.99	2.78	3.624 (5)	144
C54—H54···Cl6^iii	0.95	2.83	3.573 (6)	136
C59—H59···Cl6^iv	0.95	2.78	3.518 (6)	136
C92—H92···Cl1	0.95	2.77	3.658 (6)	155
C116—H116···Cl2	0.95	2.80	3.689 (7)	156
C130—H130···Cl3^iii	0.95	2.82	3.706 (6)	155

Symmetry codes: (i) x, y, z−1; (ii) x−1, y, z; (iii) −x+1, y+1/2, −z+1; (iv) −x+1, y−1/2, −z+1.