Polymeric (18-crown-6)­bis(2-amido­pyridine­caesium) toluene solvate

Liddle, S.T.; Clegg, W.

doi:10.1107/S1600536803023821

Polymeric (18-crown-6)bis(2-amidopyridinecaesium) toluene solvate

The title compound, catena-poly[[caesium(I)-μ-18-crown-6-caesium(I)-di-μ-2-amidopyridine] toluene], [{[Cs{2-N(H)C₅H₄N}]₂(C₁₂H₂₄O₆)·(C₆H₅CH₃)}_∞] or [Cs₂(C₅H₅N₂)₂(C₁₂H₂₄O₆)]·C₇H₈, crystallizes as a toluene solvate. The polymeric structure is constructed from dimeric amido-bridged Cs₂N₂ four-membered rings with additional supporting coordination by bridging pyridyl N atoms. Each dimeric unit is linked to the next in the polymeric chain by bridging κ⁶:κ⁶ 18-crown-6 ether molecules, in which each of the six O atoms bonds to both caesium ions; each caesium is ten-coordinate. The polymer has crystallographic mirror (C_s) symmetry, the mirror running through all the caesium ions, so that there is only one unique amidopyridine ligand and each crown ligand is bisected by the mirror. Consequently, the amide ligands are arranged cis with respect to each other, which is unusual.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803023821/bt6368sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536803023821/bt6368Isup2.hkl Contains datablock I

CCDC reference: 226670

checkCIF report

Key indicators

Single-crystal X-ray study
T = 160 K
Mean (C-C) = 0.016 Å
R factor = 0.028
wR factor = 0.065
Data-to-parameter ratio = 19.3

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT063_ALERT_3_A Crystal Probably too Large for Beam Size .......       1.30 mm
PLAT213_ALERT_2_A Atom C8      has ADP max/min Ratio .............       6.10 prolat

Alert level B
CRYSS02_ALERT_3_B  The value of _exptl_crystal_size_max is > 1.0
   Maximum crystal size given =   1.300
PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors ....        C10
PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors ....        Cs2
PLAT353_ALERT_3_B Long    N-H Bond (0.87A)   N2     -   H2N      =       1.10 Ang.
PLAT415_ALERT_2_B Short Inter D-H..H-X       H2N    ..  H16A     =       2.06 Ang.
PLAT415_ALERT_2_B Short Inter D-H..H-X       H2N    ..  H16D     =       2.09 Ang.

Alert level C
STRVA01_ALERT_4_C           Flack test results are ambiguous.
           From the CIF: _refine_ls_abs_structure_Flack    0.460
           From the CIF: _refine_ls_abs_structure_Flack_su    0.040
PLAT033_ALERT_2_C Flack Parameter Value Deviates from Zero .......       0.46
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       2.00 Ratio
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given .......          ?
PLAT213_ALERT_2_C Atom O3      has ADP max/min Ratio .............       3.30 prolat
PLAT213_ALERT_2_C Atom C7      has ADP max/min Ratio .............       3.40 prolat
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.95 Ratio
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....         C4
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....         C9
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        Cs1
PLAT244_ALERT_4_C Low Solvent  U(eq) as Compared to Neighbors ....        C12
PLAT250_ALERT_2_C Large U3/U1 ratio for average U(i,j) tensor ....       2.51
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         16
PLAT369_ALERT_2_C Long   C(sp2)-C(sp2) Bond  C4     -   C5       =       1.56 Ang.
PLAT420_ALERT_2_C D-H Without Acceptor       N2     -   H2N    ...          ?
PLAT731_ALERT_1_C Bond    Calc   1.350(17), Rep    1.350(8) ......       2.12 su-Rat
              N1   -C5      1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     1.48(2), Rep    1.483(9) ......       2.22 su-Rat
              C8   -C9      1.555   1.555
PLAT764_ALERT_4_C Overcomplete CIF Bond list Detected (Rep/Expd) .       1.12 Ratio

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           28.51
           From the CIF: _reflns_number_total               3879
           Count of symmetry unique reflns         2223
           Completeness (_total/calc)            174.49%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      1656
           Fraction of Friedel pairs measured     0.745
           Are heavy atom types Z>Si present          yes

   2 ALERT level A = In general: serious problem
   6 ALERT level B = Potentially serious problem
  20 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  14 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2001); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and local programs.

catena-poly[[caesium(I)-µ-18-crown-6-caesium(I)-di-µ-2-amidopyridine] toluene] top

Crystal data top

[Cs₂(C₅H₅N₂)₂(C₁₂H₂₄O₆)]·C₇H₈	F(000) = 804
M_r = 808.49	D_x = 1.592 Mg m⁻³
Monoclinic, Cm	Mo Kα radiation, λ = 0.71073 Å
a = 13.0109 (10) Å	Cell parameters from 5667 reflections
b = 17.3720 (14) Å	θ = 2.4–28.4°
c = 7.8427 (6) Å	µ = 2.21 mm⁻¹
β = 107.979 (2)°	T = 160 K
V = 1686.1 (2) Å³	Needle, yellow
Z = 2	1.30 × 0.22 × 0.12 mm

Data collection top

Bruker SMART 1K CCD diffractometer	3879 independent reflections
Radiation source: sealed tube	2911 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.025
Detector resolution: 8.192 pixels mm^-1	θ_max = 28.5°, θ_min = 2.0°
thin–slice ω scans	h = −17→16
Absorption correction: multi-scan (SADABS; Sheldrick, 2002)	k = −22→23
T_min = 0.478, T_max = 0.768	l = −10→10
7390 measured reflections

Refinement top

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.028	H atoms treated by a mixture of independent and constrained refinement
wR(F²) = 0.065	w = 1/[σ²(F_o²) + (0.03P)²] where P = (F_o² + 2F_c²)/3
S = 0.94	(Δ/σ)_max = 0.038
3879 reflections	Δρ_max = 0.81 e Å⁻³
201 parameters	Δρ_min = −0.53 e Å⁻³
65 restraints	Absolute structure: Flack (1983)
Primary atom site location: structure-invariant direct methods	Absolute structure parameter: 0.46 (4)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Cs1	0.54337 (3)	0.5000	0.55808 (5)	0.0412 (3)
Cs2	0.53181 (3)	0.5000	1.04501 (4)	0.0398 (2)
N1	0.5867 (9)	0.6431 (5)	0.3252 (12)	0.056 (2)
N2	0.4028 (4)	0.6085 (3)	0.2416 (6)	0.0515 (12)
H2N	0.322 (4)	0.635 (3)	0.191 (6)	0.037 (13)*
C1	0.6594 (6)	0.6920 (4)	0.3401 (8)	0.0607 (17)
H1	0.7316	0.6754	0.3591	0.073*
C2	0.6372 (10)	0.7678 (5)	0.3297 (17)	0.077 (2)
H2	0.6950	0.8033	0.3462	0.092*
C3	0.5353 (13)	0.7953 (3)	0.296 (2)	0.0702 (15)
H3	0.5223	0.8491	0.2859	0.084*
C4	0.4519 (10)	0.7457 (5)	0.2780 (14)	0.077 (3)
H4	0.3803	0.7633	0.2608	0.092*
C5	0.4802 (9)	0.6582 (6)	0.2867 (13)	0.051 (2)
O1	0.7602 (10)	0.5000	0.9015 (16)	0.081 (4)
O2	0.6388 (8)	0.6418 (4)	0.8835 (12)	0.074 (2)
O3	0.4197 (7)	0.6345 (4)	0.7223 (9)	0.0673 (19)
O4	0.3166 (8)	0.5000	0.7064 (15)	0.076 (3)
C6	0.8016 (9)	0.5711 (7)	0.9845 (16)	0.091 (3)
H6A	0.8804	0.5728	1.0038	0.109*
H6B	0.7901	0.5736	1.1034	0.109*
C7	0.7501 (10)	0.6398 (7)	0.8767 (16)	0.097 (3)
H7A	0.7890	0.6874	0.9286	0.117*
H7B	0.7508	0.6348	0.7513	0.117*
C8	0.6008 (13)	0.7062 (5)	0.7947 (13)	0.099 (3)
H8A	0.6020	0.7046	0.6692	0.118*
H8B	0.6395	0.7525	0.8556	0.118*
C9	0.4897 (13)	0.7008 (6)	0.8073 (16)	0.109 (4)
H9A	0.4954	0.7009	0.9361	0.131*
H9B	0.4511	0.7486	0.7549	0.131*
C10	0.3123 (10)	0.6290 (9)	0.716 (2)	0.122 (4)
H10A	0.2738	0.6767	0.6635	0.146*
H10B	0.3083	0.6242	0.8400	0.146*
C11	0.2592 (11)	0.5630 (8)	0.6108 (18)	0.114 (4)
H11A	0.1819	0.5606	0.6037	0.137*
H11B	0.2649	0.5650	0.4879	0.137*
C12	0.5908 (8)	1.0000	0.9116 (16)	0.072 (3)
C13	0.5411 (14)	0.9324 (4)	0.826 (2)	0.081 (3)
H13	0.5612	0.8844	0.8855	0.097*
C14	0.4648 (7)	0.9335 (5)	0.6611 (12)	0.094 (3)
H14	0.4398	0.8850	0.6088	0.113*
C15	0.4190 (12)	1.0000	0.559 (3)	0.096 (5)
H15	0.3669	1.0000	0.4437	0.115*
C16	0.6800 (16)	1.0000	1.069 (2)	0.155 (9)
H16A	0.7024	1.0531	1.1033	0.232*	0.25
H16B	0.7400	0.9716	1.0483	0.232*	0.25
H16C	0.6594	0.9752	1.1664	0.232*	0.25
H16D	0.6988	0.9469	1.1087	0.232*	0.25
H16E	0.6612	1.0284	1.1637	0.232*	0.25
H16F	0.7418	1.0248	1.0456	0.232*	0.25

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Cs1	0.0662 (7)	0.0356 (4)	0.0282 (6)	0.000	0.0239 (5)	0.000
Cs2	0.0638 (7)	0.0361 (4)	0.0232 (5)	0.000	0.0190 (5)	0.000
N1	0.072 (4)	0.072 (4)	0.027 (4)	−0.015 (3)	0.019 (4)	0.004 (3)
N2	0.053 (3)	0.066 (3)	0.037 (2)	−0.004 (2)	0.015 (2)	−0.003 (2)
C1	0.059 (4)	0.082 (5)	0.042 (3)	−0.014 (3)	0.019 (3)	0.003 (3)
C2	0.115 (5)	0.068 (5)	0.054 (5)	0.002 (5)	0.036 (5)	−0.008 (4)
C3	0.127 (4)	0.037 (3)	0.051 (3)	0.014 (6)	0.034 (3)	0.016 (6)
C4	0.107 (6)	0.085 (6)	0.037 (5)	−0.013 (5)	0.020 (5)	−0.005 (5)
C5	0.056 (5)	0.083 (6)	0.023 (4)	−0.039 (5)	0.024 (4)	−0.018 (4)
O1	0.077 (8)	0.127 (8)	0.036 (7)	0.000	0.013 (6)	0.000
O2	0.137 (6)	0.038 (3)	0.062 (5)	0.000 (4)	0.050 (4)	−0.001 (3)
O3	0.117 (5)	0.062 (4)	0.033 (3)	0.062 (4)	0.038 (3)	0.012 (3)
O4	0.028 (5)	0.154 (8)	0.045 (8)	0.000	0.010 (5)	0.000
C6	0.037 (4)	0.180 (9)	0.050 (6)	−0.045 (5)	0.004 (4)	−0.020 (6)
C7	0.125 (6)	0.127 (7)	0.033 (5)	−0.105 (5)	0.013 (5)	−0.006 (5)
C8	0.248 (8)	0.025 (5)	0.042 (6)	−0.040 (5)	0.073 (7)	0.001 (4)
C9	0.207 (8)	0.051 (7)	0.070 (8)	0.041 (5)	0.045 (8)	0.034 (6)
C10	0.121 (8)	0.173 (10)	0.065 (8)	0.074 (7)	0.020 (7)	−0.023 (8)
C11	0.080 (7)	0.201 (11)	0.062 (8)	0.053 (6)	0.023 (6)	−0.007 (7)
C12	0.065 (6)	0.067 (7)	0.094 (7)	0.000	0.037 (5)	0.000
C13	0.102 (5)	0.047 (3)	0.114 (8)	−0.010 (6)	0.063 (5)	−0.003 (5)
C14	0.087 (6)	0.097 (7)	0.100 (6)	−0.005 (5)	0.029 (4)	−0.014 (5)
C15	0.058 (8)	0.058 (8)	0.179 (16)	0.000	0.048 (8)	0.000
C16	0.119 (14)	0.26 (3)	0.084 (10)	0.000	0.031 (8)	0.000

Geometric parameters (Å, º) top

Cs1—N1	3.235 (9)	O2—C7	1.465 (10)
Cs1—N1ⁱ	3.235 (9)	O2—C8	1.330 (9)
Cs1—N2	3.202 (5)	O3—C9	1.492 (11)
Cs1—N2ⁱ	3.202 (5)	O3—C10	1.387 (11)
Cs1—O1	3.243 (12)	O4—C11	1.404 (10)
Cs1—O2	3.488 (8)	O4—C11ⁱ	1.404 (10)
Cs1—O2ⁱ	3.488 (8)	C6—H6A	0.990
Cs1—O3	3.315 (6)	C6—H6B	0.990
Cs1—O3ⁱ	3.315 (6)	C6—C7	1.496 (10)
Cs1—O4	3.490 (10)	C7—H7A	0.990
Cs2—N1ⁱⁱ	3.247 (9)	C7—H7B	0.990
Cs2—N1ⁱⁱⁱ	3.247 (9)	C8—H8A	0.990
Cs2—N2ⁱⁱⁱ	3.216 (5)	C8—H8B	0.990
Cs2—N2ⁱⁱ	3.216 (5)	C8—C9	1.483 (9)
Cs2—O1	3.487 (13)	C9—H9A	0.990
Cs2—O2	3.272 (8)	C9—H9B	0.990
Cs2—O2ⁱ	3.272 (8)	C10—H10A	0.990
Cs2—O3	3.423 (6)	C10—H10B	0.990
Cs2—O3ⁱ	3.423 (6)	C10—C11	1.458 (12)
Cs2—O4	3.210 (10)	C11—H11A	0.990
N1—Cs2^iv	3.247 (9)	C11—H11B	0.990
N1—C1	1.250 (11)	C12—C13	1.406 (10)
N1—C5	1.350 (8)	C12—C13^v	1.406 (10)
N2—Cs2^iv	3.216 (5)	C12—C16	1.41 (2)
N2—H2N	1.11 (5)	C13—H13	0.950
N2—C5	1.289 (10)	C13—C14	1.368 (16)
C1—H1	0.950	C14—H14	0.950
C1—C2	1.344 (10)	C14—C15	1.426 (14)
C2—H2	0.950	C15—C14^v	1.426 (14)
C2—C3	1.358 (11)	C15—H15	0.950
C3—H3	0.950	C16—H16A	0.980
C3—C4	1.357 (10)	C16—H16B	0.980
C4—H4	0.950	C16—H16C	0.980
C4—C5	1.562 (11)	C16—H16D	0.980
O1—C6	1.422 (9)	C16—H16E	0.980
O1—C6ⁱ	1.422 (9)	C16—H16F	0.980

N1—Cs1—N1ⁱ	100.4 (3)	N1—C1—C2	121.2 (10)
N1—Cs1—N2	42.9 (2)	H1—C1—C2	119.4
N1ⁱ—Cs1—N2ⁱ	42.9 (2)	C1—C2—H2	118.8
N1ⁱ—Cs1—N2	99.90 (18)	C1—C2—C3	122.3 (9)
N1—Cs1—N2ⁱ	99.90 (18)	H2—C2—C3	118.8
N1—Cs1—O1	102.1 (2)	C2—C3—H3	120.0
N1ⁱ—Cs1—O1	102.1 (2)	C2—C3—C4	119.9 (6)
N1—Cs1—O2	77.6 (2)	H3—C3—C4	120.0
N1ⁱ—Cs1—O2	150.6 (2)	C3—C4—H4	121.8
N1ⁱ—Cs1—O2ⁱ	77.6 (2)	C3—C4—C5	116.3 (8)
N1—Cs1—O2ⁱ	150.6 (2)	H4—C4—C5	121.8
N1—Cs1—O3	82.4 (2)	N1—C5—N2	126.3 (11)
N1ⁱ—Cs1—O3ⁱ	82.4 (2)	N1—C5—C4	114.3 (9)
N1—Cs1—O3ⁱ	162.0 (2)	N2—C5—C4	119.1 (10)
N1ⁱ—Cs1—O3	162.0 (2)	Cs1—O1—Cs2	70.0 (2)
N1—Cs1—O4	120.1 (2)	Cs1—O1—C6	119.3 (6)
N1ⁱ—Cs1—O4	120.1 (2)	Cs1—O1—C6ⁱ	119.3 (6)
N2—Cs1—N2ⁱ	72.11 (17)	Cs2—O1—C6	95.3 (7)
N2—Cs1—O1	141.79 (11)	Cs2—O1—C6ⁱ	95.3 (7)
N2ⁱ—Cs1—O1	141.79 (11)	C6—O1—C6ⁱ	120.5 (13)
N2—Cs1—O2	98.08 (15)	Cs1—O2—Cs2	69.72 (16)
N2ⁱ—Cs1—O2	166.39 (17)	Cs1—O2—C7	95.1 (6)
N2ⁱ—Cs1—O2ⁱ	98.08 (16)	Cs1—O2—C8	102.7 (7)
N2—Cs1—O2ⁱ	166.39 (17)	Cs2—O2—C7	122.6 (6)
N2—Cs1—O3	69.92 (14)	Cs2—O2—C8	134.6 (9)
N2ⁱ—Cs1—O3ⁱ	69.92 (15)	C7—O2—C8	102.3 (11)
N2—Cs1—O3ⁱ	119.11 (19)	Cs1—O3—Cs2	70.05 (12)
N2ⁱ—Cs1—O3	119.11 (19)	Cs1—O3—C9	114.6 (8)
N2—Cs1—O4	85.36 (17)	Cs1—O3—C10	122.9 (8)
N2ⁱ—Cs1—O4	85.36 (17)	Cs2—O3—C9	97.8 (6)
O1—Cs1—O2	50.99 (17)	Cs2—O3—C10	99.9 (8)
O1—Cs1—O2ⁱ	50.99 (17)	C9—O3—C10	122.5 (10)
O1—Cs1—O3	94.6 (2)	Cs1—O4—Cs2	70.38 (19)
O1—Cs1—O3ⁱ	94.6 (2)	Cs1—O4—C11	100.8 (7)
O1—Cs1—O4	109.3 (3)	Cs1—O4—C11ⁱ	100.8 (7)
O2—Cs1—O2ⁱ	89.9 (3)	Cs2—O4—C11	128.8 (7)
O2—Cs1—O3	47.45 (14)	Cs2—O4—C11ⁱ	128.8 (7)
O2—Cs1—O3ⁱ	108.6 (2)	C11—O4—C11ⁱ	102.4 (14)
O2ⁱ—Cs1—O3ⁱ	47.45 (14)	O1—C6—H6A	109.0
O2ⁱ—Cs1—O3	108.6 (2)	O1—C6—H6B	108.9
O2—Cs1—O4	84.4 (2)	O1—C6—C7	113.2 (8)
O2ⁱ—Cs1—O4	84.4 (2)	H6A—C6—H6B	107.8
O3—Cs1—O3ⁱ	89.7 (3)	H6A—C6—C7	108.9
O3—Cs1—O4	46.27 (17)	H6B—C6—C7	109.0
O3ⁱ—Cs1—O4	46.27 (17)	O2—C7—C6	105.9 (8)
N1ⁱⁱ—Cs2—N1ⁱⁱⁱ	99.9 (3)	O2—C7—H7A	110.6
N1ⁱⁱ—Cs2—N2ⁱⁱⁱ	99.34 (19)	O2—C7—H7B	110.6
N1ⁱⁱ—Cs2—N2ⁱⁱ	42.7 (2)	C6—C7—H7A	110.6
N1ⁱⁱⁱ—Cs2—N2ⁱⁱⁱ	42.7 (2)	C6—C7—H7B	110.5
N1ⁱⁱⁱ—Cs2—N2ⁱⁱ	99.34 (19)	H7A—C7—H7B	108.7
N1ⁱⁱ—Cs2—O1	100.8 (2)	O2—C8—H8A	112.3
N1ⁱⁱⁱ—Cs2—O1	100.8 (2)	O2—C8—H8B	112.3
N1ⁱⁱ—Cs2—O2	69.8 (2)	O2—C8—C9	97.2 (10)
N1ⁱⁱⁱ—Cs2—O2	143.8 (2)	H8A—C8—H8B	109.9
N1ⁱⁱ—Cs2—O2ⁱ	143.8 (2)	H8A—C8—C9	112.3
N1ⁱⁱⁱ—Cs2—O2ⁱ	69.8 (2)	H8B—C8—C9	112.3
N1ⁱⁱ—Cs2—O3ⁱ	167.8 (2)	Cs2—C9—O3	60.1 (5)
N1ⁱⁱⁱ—Cs2—O3ⁱ	86.1 (2)	Cs2—C9—C8	95.2 (7)
N1ⁱⁱ—Cs2—O3	86.1 (2)	Cs2—C9—H9A	63.8
N1ⁱⁱⁱ—Cs2—O3	167.8 (2)	Cs2—C9—H9B	157.3
N1ⁱⁱ—Cs2—O4	120.9 (2)	O3—C9—C8	119.5 (11)
N1ⁱⁱⁱ—Cs2—O4	120.9 (2)	O3—C9—H9A	107.5
N2ⁱⁱⁱ—Cs2—N2ⁱⁱ	71.75 (18)	O3—C9—H9B	107.5
N2ⁱⁱⁱ—Cs2—O1	141.03 (11)	C8—C9—H9A	107.5
N2ⁱⁱ—Cs2—O1	141.03 (12)	C8—C9—H9B	107.5
N2ⁱⁱⁱ—Cs2—O2	167.02 (16)	H9A—C9—H9B	107.0
N2ⁱⁱ—Cs2—O2	95.27 (18)	O3—C10—H10A	109.3
N2ⁱⁱⁱ—Cs2—O2ⁱ	95.27 (18)	O3—C10—H10B	109.3
N2ⁱⁱ—Cs2—O2ⁱ	167.02 (16)	O3—C10—C11	111.7 (11)
N2ⁱⁱⁱ—Cs2—O3ⁱ	77.76 (14)	H10A—C10—H10B	108.0
N2ⁱⁱ—Cs2—O3ⁱ	126.04 (19)	H10A—C10—C11	109.3
N2ⁱⁱⁱ—Cs2—O3	126.04 (19)	H10B—C10—C11	109.3
N2ⁱⁱ—Cs2—O3	77.76 (14)	O4—C11—C10	103.3 (10)
N2ⁱⁱⁱ—Cs2—O4	86.87 (18)	O4—C11—H11A	111.1
N2ⁱⁱ—Cs2—O4	86.87 (17)	O4—C11—H11B	111.1
O1—Cs2—O2	50.80 (16)	C10—C11—H11A	111.1
O1—Cs2—O2ⁱ	50.80 (16)	C10—C11—H11B	111.1
O1—Cs2—O3	88.4 (2)	H11A—C11—H11B	109.1
O1—Cs2—O3ⁱ	88.4 (2)	C13—C12—C13^v	113.3 (14)
O1—Cs2—O4	110.2 (3)	C13—C12—C16	123.3 (7)
O2—Cs2—O2ⁱ	97.7 (3)	C13^v—C12—C16	123.3 (7)
O2—Cs2—O3	48.29 (15)	C12—C13—H13	119.0
O2—Cs2—O3ⁱ	111.3 (2)	C12—C13—C14	122.1 (10)
O2ⁱ—Cs2—O3ⁱ	48.29 (15)	H13—C13—C14	119.0
O2ⁱ—Cs2—O3	111.3 (2)	C13—C14—H14	116.7
O2—Cs2—O4	92.7 (2)	C13—C14—C15	126.7 (11)
O2ⁱ—Cs2—O4	92.7 (2)	H14—C14—C15	116.7
O3—Cs2—O3ⁱ	86.1 (3)	C14—C15—C14^v	108.2 (16)
O3—Cs2—O4	47.51 (17)	C14—C15—H15	125.9
O3ⁱ—Cs2—O4	47.51 (17)	C14^v—C15—H15	125.9
Cs1—N1—Cs2^iv	75.75 (19)	C12—C16—H16A	109.5
Cs1—N1—C1	136.8 (7)	C12—C16—H16B	109.5
Cs1—N1—C5	86.0 (6)	C12—C16—H16C	109.5
Cs2^iv—N1—C1	125.9 (7)	C12—C16—H16D	109.5
Cs2^iv—N1—C5	90.1 (6)	C12—C16—H16E	109.5
C1—N1—C5	125.7 (11)	C12—C16—H16F	109.5
Cs1—N2—Cs2^iv	76.64 (11)	H16A—C16—H16B	109.5
Cs1—N2—H2N	141 (3)	H16A—C16—H16C	109.5
Cs1—N2—C5	88.3 (6)	H16B—C16—H16C	109.5
Cs2^iv—N2—H2N	131 (2)	H16D—C16—H16E	109.5
Cs2^iv—N2—C5	92.6 (6)	H16D—C16—H16F	109.5
H2N—N2—C5	114 (3)	H16E—C16—H16F	109.5
N1—C1—H1	119.4

Symmetry codes: (i) x, −y+1, z; (ii) x, y, z+1; (iii) x, −y+1, z+1; (iv) x, y, z−1; (v) x, −y+2, z.

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Polymeric (18-crown-6)­bis(2-amido­pyridine­caesium) toluene solvate

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Polymeric (18-crown-6)bis(2-amidopyridinecaesium) toluene solvate