Poly­[[tri­aqua­bis­(μ4-3-carboxy-4-hydroxy­benzene­sulfonato)disilver(I)] monohydrate]

Gao, S.; Zhu, Z.-B.; Huo, L.-H.; Ng, S.W.

doi:10.1107/S1600536805000504

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Poly[[triaquabis(μ₄-3-carboxy-4-hydroxybenzenesulfonato)disilver(I)] monohydrate]

S. Gao, Z.-B. Zhu, L.-H. Huo and S. W. Ng

In the layer structure of the title polymeric complex, {[Ag₂(C₇H₅O₆S)₂(H₂O)₃]·H₂O}_n, both substituted benzenesulfonate anions use two of their sulfonyl O atoms to link to three Ag atoms and their double-bond carbonyl O atom to another Ag atom in a μ₄-bonding mode. The two symmetry-independent Ag atoms are coordinated by water molecules, one by one water molecule and the other by two water molecules so that one Ag atom is five- and the other six-coordinate.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805000504/bt6578sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536805000504/bt6578Isup2.hkl Contains datablock I

CCDC reference: 263546

checkCIF report

Key indicators

Single-crystal X-ray study
T = 295 K
Mean (C-C) = 0.004 Å
R factor = 0.028
wR factor = 0.074
Data-to-parameter ratio = 13.6

checkCIF/PLATON results

No syntax errors found



Alert level B
ABSTM02_ALERT_3_B  The ratio of expected to reported Tmax/Tmin(RR') is < 0.75
            Tmin and Tmax reported:      0.316     0.668
            Tmin' and Tmax expected:      0.439     0.669
            RR' =      0.720
            Please check that your absorption correction is appropriate.
PLAT061_ALERT_3_B Tmax/Tmin Range Test RR' too Large .............       0.70

Alert level C
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.03 Ratio
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          8
PLAT731_ALERT_1_C Bond    Calc     0.86(4), Rep   0.850(10) ......       4.00 su-Rat
              O4   -H4O     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.85(3), Rep   0.850(10) ......       3.00 su-Rat
              O6   -H6O     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.85(4), Rep   0.850(10) ......       4.00 su-Rat
              O10  -H10O    1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.85(3), Rep   0.850(10) ......       3.00 su-Rat
              O12  -H12O    1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.85(4), Rep   0.850(10) ......       4.00 su-Rat
              O1W  -H1W2    1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.85(4), Rep   0.850(10) ......       4.00 su-Rat
              O2W  -H2W2    1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.85(4), Rep   0.850(10) ......       4.00 su-Rat
              O3W  -H3W2    1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.85(3), Rep   0.850(10) ......       3.00 su-Rat
              O4W  -H4W1    1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.86(4), Rep   0.850(10) ......       4.00 su-Rat
              O4   -H4O     1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.85(3), Rep   0.850(10) ......       3.00 su-Rat
              O6   -H6O     1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.85(4), Rep   0.850(10) ......       4.00 su-Rat
              O10  -H10O    1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.85(3), Rep   0.850(10) ......       3.00 su-Rat
              O12  -H12O    1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.85(4), Rep   0.850(10) ......       4.00 su-Rat
              O1W  -H2#     1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.85(4), Rep   0.850(10) ......       4.00 su-Rat
              O2W  -H4#     1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.85(4), Rep   0.850(10) ......       4.00 su-Rat
              O3W  -H6#     1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.85(3), Rep   0.850(10) ......       3.00 su-Rat
              O4W  -H7#     1.555   1.555
PLAT736_ALERT_1_C H...A   Calc     1.77(3), Rep   1.770(10) ......       3.00 su-Rat
              H6O  -O3W     1.555   2.777
PLAT736_ALERT_1_C H...A   Calc     1.88(4), Rep   1.890(10) ......       4.00 su-Rat
              H6#  -O1W     1.555   2.676
PLAT736_ALERT_1_C H...A   Calc     2.00(3), Rep   2.000(10) ......       3.00 su-Rat
              H7#  -O9      1.555   1.455
PLAT804_ALERT_4_C ARU-Pack Problem in PLATON Analysis ............          !
PLAT804_ALERT_4_C ARU-Pack Problem in PLATON Analysis ............          !

   0 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
  23 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

  19 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Poly[[triaquadisilver(I)]bis[µ₄-3-carboxy-4-hydroxybenzenesulfonato] monohydrate] top

Crystal data top

[Ag₂(C₇H₅O₆S)₂(H₂O)₃]·H₂O	Z = 2
M_r = 722.14	F(000) = 712
Triclinic, P1	D_x = 2.252 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.309 (1) Å	Cell parameters from 8670 reflections
b = 11.264 (2) Å	θ = 3.2–27.4°
c = 12.611 (2) Å	µ = 2.12 mm⁻¹
α = 112.743 (6)°	T = 295 K
β = 97.608 (7)°	Block, colorless
γ = 95.516 (7)°	0.38 × 0.26 × 0.19 mm
V = 1064.9 (3) Å³

Data collection top

Rigaku R-AXIS-RAPID diffractometer	4829 independent reflections
Radiation source: fine-focus sealed tube	4464 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.024
ω scans	θ_max = 27.4°, θ_min = 3.2°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −10→10
T_min = 0.316, T_max = 0.668	k = −14→14
10379 measured reflections	l = −16→16

Refinement top

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.028	H atoms treated by a mixture of independent and constrained refinement
wR(F²) = 0.074	w = 1/[σ²(F_o²) + (0.0411P)² + 1.1907P] where P = (F_o² + 2F_c²)/3
S = 1.00	(Δ/σ)_max = 0.001
4829 reflections	Δρ_max = 1.11 e Å⁻³
356 parameters	Δρ_min = −1.04 e Å⁻³
16 restraints	Extinction correction: SHELXL97, Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.070 (2)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Ag1	0.52516 (3)	0.56586 (2)	0.380653 (18)	0.0414 (1)
Ag2	0.91174 (3)	0.97340 (2)	0.62508 (2)	0.0398 (1)
S1	0.84399 (8)	0.65784 (6)	0.62869 (5)	0.0290 (1)
S2	1.32987 (7)	1.13100 (6)	0.63031 (5)	0.0280 (1)
O1	0.6839 (3)	0.5850 (2)	0.5591 (2)	0.0395 (4)
O2	0.9252 (3)	0.7361 (2)	0.5757 (2)	0.0400 (4)
O3	0.9500 (2)	0.5747 (2)	0.6581 (2)	0.0365 (4)
O4	0.7099 (3)	1.0423 (2)	1.0677 (2)	0.0479 (5)
O5	0.9347 (3)	0.9642 (2)	1.1794 (2)	0.0389 (4)
O6	1.0574 (3)	0.8000 (2)	1.0750 (2)	0.0404 (5)
O7	1.1689 (2)	1.0499 (2)	0.5705 (2)	0.0400 (5)
O8	1.3978 (3)	1.1925 (2)	0.5608 (2)	0.0420 (5)
O9	1.4407 (2)	1.0572 (2)	0.6696 (2)	0.0381 (4)
O10	1.2007 (3)	1.5483 (2)	1.0521 (2)	0.0484 (5)
O11	1.4136 (3)	1.4757 (2)	1.1741 (2)	0.0425 (5)
O12	1.5437 (3)	1.3111 (2)	1.0824 (2)	0.0404 (5)
O1w	0.2464 (3)	0.6562 (2)	0.3676 (2)	0.0502 (5)
O2w	0.6997 (3)	0.3771 (2)	0.2946 (2)	0.0414 (5)
O3w	0.7707 (3)	1.1588 (2)	0.7207 (2)	0.0380 (4)
O4w	0.2744 (3)	0.8000 (2)	0.6073 (3)	0.0549 (6)
C1	0.8036 (3)	0.7688 (2)	0.7616 (2)	0.0275 (5)
C2	0.6848 (3)	0.8493 (3)	0.7593 (2)	0.0330 (5)
C3	0.6554 (3)	0.9392 (3)	0.8624 (3)	0.0377 (6)
C4	0.7429 (3)	0.9518 (3)	0.9699 (2)	0.0330 (5)
C5	0.8606 (3)	0.8706 (2)	0.9723 (2)	0.0277 (5)
C6	0.8898 (3)	0.7796 (2)	0.8669 (2)	0.0274 (5)
C7	0.9545 (3)	0.8822 (3)	1.0847 (2)	0.0299 (5)
C8	1.2953 (3)	1.2560 (2)	0.7580 (2)	0.0269 (5)
C9	1.1806 (3)	1.3366 (3)	0.7483 (2)	0.0331 (5)
C10	1.1508 (3)	1.4332 (3)	0.8477 (3)	0.0372 (6)
C11	1.2344 (3)	1.4521 (3)	0.9582 (2)	0.0316 (5)
C12	1.3503 (3)	1.3713 (2)	0.9675 (2)	0.0279 (5)
C13	1.3789 (3)	1.2735 (2)	0.8661 (2)	0.0275 (5)
C14	1.4386 (3)	1.3902 (3)	1.0836 (2)	0.0304 (5)
H4o	0.776 (4)	1.033 (4)	1.121 (3)	0.05 (1)*
H6o	1.116 (4)	0.815 (4)	1.141 (2)	0.05 (1)*
H10o	1.268 (4)	1.542 (4)	1.106 (3)	0.05 (1)*
H12o	1.600 (4)	1.332 (4)	1.150 (2)	0.05 (1)*
H1w1	0.259 (5)	0.700 (3)	0.441 (1)	0.06 (1)*
H1w2	0.178 (5)	0.587 (3)	0.347 (3)	0.10 (2)*
H2w1	0.802 (2)	0.400 (3)	0.298 (3)	0.06 (1)*
H2w2	0.688 (4)	0.317 (3)	0.319 (3)	0.06 (1)*
H3w1	0.670 (2)	1.128 (3)	0.710 (3)	0.04 (1)*
H3w2	0.779 (4)	1.221 (3)	0.698 (3)	0.06 (1)*
H4w1	0.317 (4)	0.877 (2)	0.619 (4)	0.08 (2)*
H4w2	0.170 (1)	0.796 (4)	0.600 (4)	0.08 (2)*
H2	0.6264	0.8417	0.6881	0.040*
H3	0.5768	0.9921	0.8606	0.045*
H6	0.9678	0.7259	0.8679	0.033*
H9	1.1250	1.3249	0.6751	0.040*
H10	1.0744	1.4864	0.8413	0.045*
H13	1.4550	1.2198	0.8715	0.033*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.0479 (2)	0.0431 (1)	0.0282 (1)	0.0033 (1)	−0.0046 (1)	0.0138 (1)
Ag2	0.0452 (1)	0.0456 (2)	0.0266 (1)	0.0061 (1)	0.0029 (1)	0.0139 (1)
S1	0.0307 (3)	0.0289 (3)	0.0252 (3)	−0.0010 (2)	−0.0018 (2)	0.0123 (2)
S2	0.0267 (3)	0.0294 (3)	0.0235 (3)	−0.0004 (2)	−0.0013 (2)	0.0091 (2)
O1	0.041 (1)	0.038 (1)	0.031 (1)	−0.006 (1)	−0.009 (1)	0.012 (1)
O2	0.047 (1)	0.041 (1)	0.038 (1)	0.003 (1)	0.012 (1)	0.021 (1)
O3	0.039 (1)	0.032 (1)	0.036 (1)	0.006 (1)	−0.001 (1)	0.013 (1)
O4	0.048 (1)	0.058 (1)	0.038 (1)	0.022 (1)	0.013 (1)	0.015 (1)
O5	0.042 (1)	0.045 (1)	0.027 (1)	0.002 (1)	0.002 (1)	0.014 (1)
O6	0.048 (1)	0.040 (1)	0.031 (1)	0.010 (1)	−0.004 (1)	0.016 (1)
O7	0.033 (1)	0.045 (1)	0.029 (1)	−0.008 (1)	−0.005 (1)	0.008 (1)
O8	0.049 (1)	0.043 (1)	0.039 (1)	0.006 (1)	0.016 (1)	0.020 (1)
O9	0.041 (1)	0.033 (1)	0.034 (1)	0.008 (1)	−0.004 (1)	0.009 (1)
O10	0.050 (1)	0.051 (1)	0.039 (1)	0.020 (1)	0.009 (1)	0.010 (1)
O11	0.048 (1)	0.046 (1)	0.027 (1)	0.005 (1)	0.003 (1)	0.010 (1)
O12	0.048 (1)	0.041 (1)	0.029 (1)	0.009 (1)	−0.004 (1)	0.014 (1)
O1w	0.055 (1)	0.038 (1)	0.056 (2)	−0.002 (1)	0.004 (1)	0.022 (1)
O2w	0.043 (1)	0.048 (1)	0.036 (1)	0.003 (1)	−0.002 (1)	0.023 (1)
O3w	0.037 (1)	0.043 (1)	0.036 (1)	0.006 (1)	−0.002 (1)	0.021 (1)
O4w	0.048 (1)	0.044 (1)	0.079 (2)	0.004 (1)	0.003 (1)	0.035 (1)
C1	0.027 (1)	0.028 (1)	0.0258 (11)	−0.002 (1)	0.001 (1)	0.0122 (9)
C2	0.026 (1)	0.043 (1)	0.032 (1)	0.004 (1)	0.000 (1)	0.020 (1)
C3	0.029 (1)	0.046 (2)	0.044 (2)	0.010 (1)	0.005 (1)	0.024 (1)
C4	0.029 (1)	0.036 (1)	0.034 (1)	0.004 (1)	0.009 (1)	0.014 (1)
C5	0.025 (1)	0.030 (1)	0.027 (1)	−0.002 (1)	0.000 (1)	0.014 (1)
C6	0.028 (1)	0.027 (1)	0.027 (1)	0.001 (1)	−0.001 (1)	0.013 (1)
C7	0.029 (1)	0.031 (1)	0.029 (1)	−0.005 (1)	0.001 (1)	0.015 (1)
C8	0.028 (1)	0.026 (1)	0.025 (1)	0.001 (1)	0.002 (1)	0.010 (1)
C9	0.029 (1)	0.038 (1)	0.032 (1)	0.004 (1)	−0.002 (1)	0.016 (1)
C10	0.034 (1)	0.043 (2)	0.040 (1)	0.014 (1)	0.006 (1)	0.020 (1)
C11	0.030 (1)	0.031 (1)	0.033 (1)	0.004 (1)	0.006 (1)	0.012 (1)
C12	0.028 (1)	0.028 (1)	0.027 (1)	−0.001 (1)	0.001 (1)	0.013 (1)
C13	0.027 (1)	0.024 (1)	0.028 (1)	−0.001 (1)	−0.001 (1)	0.010 (1)
C14	0.031 (1)	0.031 (1)	0.027 (1)	−0.003 (1)	0.002 (1)	0.013 (1)

Geometric parameters (Å, º) top

Ag1—O1	2.374 (2)	C4—C5	1.406 (4)
Ag1—O1ⁱ	2.695 (2)	C5—C6	1.398 (4)
Ag1—O8ⁱⁱ	2.520 (2)	C5—C7	1.477 (3)
Ag1—O11ⁱⁱⁱ	2.411 (2)	C8—C13	1.376 (3)
Ag1—O1w	2.629 (3)	C8—C9	1.404 (4)
Ag1—O2w	2.651 (2)	C9—C10	1.377 (4)
Ag2—O2	2.517 (2)	C10—C11	1.399 (4)
Ag2—O5^iv	2.420 (2)	C11—C12	1.410 (4)
Ag2—O7	2.505 (2)	C12—C13	1.396 (4)
Ag2—O7ⁱⁱ	2.373 (2)	C12—C14	1.474 (3)
Ag2—O3w	2.467 (2)	O4—H4o	0.85 (1)
S1—O3	1.460 (2)	O6—H6o	0.85 (1)
S1—O1	1.462 (2)	O10—H10o	0.85 (1)
S1—O2	1.463 (2)	O12—H12o	0.85 (1)
S1—C1	1.759 (3)	O1w—H1w1	0.85 (1)
S2—O8	1.446 (2)	O1w—H1w2	0.85 (1)
S2—O9	1.459 (2)	O2w—H2w1	0.85 (1)
S2—O7	1.469 (2)	O2w—H2w2	0.85 (1)
S2—C8	1.762 (3)	O3w—H3w1	0.85 (1)
O4—C4	1.345 (3)	O3w—H3w2	0.85 (1)
O5—C7	1.239 (3)	O4w—H4w1	0.85 (1)
O6—C7	1.302 (3)	O4w—H4w2	0.85 (1)
O10—C11	1.345 (3)	C2—H2	0.93
O11—C14	1.235 (3)	C3—H3	0.93
O12—C14	1.304 (3)	C6—H6	0.93
C1—C6	1.377 (3)	C9—H9	0.93
C1—C2	1.408 (4)	C10—H10	0.93
C2—C3	1.374 (4)	C13—H13	0.93
C3—C4	1.399 (4)

O1—Ag1—O1ⁱ	80.07 (7)	O4—C4—C5	122.6 (2)
O1—Ag1—O8ⁱⁱ	90.15 (7)	C3—C4—C5	119.6 (2)
O1—Ag1—O11ⁱⁱⁱ	158.51 (8)	C6—C5—C4	119.4 (2)
O1—Ag1—O1w	123.46 (8)	C6—C5—C7	120.0 (2)
O1—Ag1—O2w	81.31 (7)	C4—C5—C7	120.5 (2)
O1ⁱ—Ag1—O8ⁱⁱ	135.29 (7)	C1—C6—C5	120.4 (2)
O1ⁱ—Ag1—O11ⁱⁱⁱ	97.81 (7)	O5—C7—O6	123.9 (2)
O1ⁱ—Ag1—O1w	75.70 (7)	O5—C7—C5	121.6 (2)
O1ⁱ—Ag1—O2w	92.68 (7)	O6—C7—C5	114.5 (2)
O8ⁱⁱ—Ag1—O11ⁱⁱⁱ	105.60 (7)	C13—C8—C9	120.4 (2)
O8ⁱⁱ—Ag1—O1w	73.95 (7)	C13—C8—S2	120.3 (2)
O8ⁱⁱ—Ag1—O2w	129.05 (7)	C9—C8—S2	119.3 (2)
O11ⁱⁱⁱ—Ag1—O1w	75.84 (8)	C10—C9—C8	119.7 (2)
O11ⁱⁱⁱ—Ag1—O2w	77.42 (7)	C9—C10—C11	120.6 (2)
O1w—Ag1—O2w	148.95 (7)	O10—C11—C10	117.9 (2)
O2—Ag2—O5^iv	91.56 (7)	O10—C11—C12	122.6 (2)
O2—Ag2—O7	102.94 (7)	C10—C11—C12	119.5 (2)
O2—Ag2—O7ⁱⁱ	96.13 (7)	C13—C12—C11	119.3 (2)
O2—Ag2—O3w	146.10 (7)	C13—C12—C14	120.8 (2)
O5^iv—Ag2—O7	88.40 (7)	C11—C12—C14	119.9 (2)
O5^iv—Ag2—O7ⁱⁱ	162.89 (7)	C8—C13—C12	120.5 (2)
O5^iv—Ag2—O3w	83.95 (7)	O11—C14—O12	123.5 (2)
O7—Ag2—O7ⁱⁱ	75.01 (7)	O11—C14—C12	121.5 (2)
O7—Ag2—O3w	110.47 (7)	O12—C14—C12	115.0 (2)
O7ⁱⁱ—Ag2—O3w	97.79 (7)	C4—O4—H4o	102 (3)
O3—S1—O1	112.3 (1)	C7—O6—H6o	111 (3)
O3—S1—O2	112.5 (1)	C11—O10—H10o	100 (3)
O1—S1—O2	112.6 (1)	C14—O12—H12o	111 (3)
O3—S1—C1	106.6 (1)	Ag1—O1w—H1w1	94 (3)
O1—S1—C1	105.9 (1)	Ag1—O1w—H1w2	100 (4)
O2—S1—C1	106.4 (1)	H1w1—O1w—H1w2	110 (2)
O8—S2—O9	113.8 (1)	Ag1—O2w—H2w1	117 (3)
O8—S2—O7	112.0 (1)	Ag1—O2w—H2w2	115 (3)
O9—S2—O7	110.8 (1)	H2w1—O2w—H2w2	109 (2)
O8—S2—C8	107.5 (1)	Ag2—O3w—H3w1	107 (2)
O9—S2—C8	106.1 (1)	Ag2—O3w—H3w2	117 (3)
O7—S2—C8	106.3 (1)	H3w1—O3w—H3w2	109 (2)
S1—O1—Ag1	134.6 (1)	H4w1—O4w—H4w2	109 (2)
S1—O2—Ag2	125.0 (1)	C3—C2—H2	120.1
C7—O5—Ag2^iv	130.0 (2)	C1—C2—H2	120.1
S2—O7—Ag2ⁱⁱ	114.6 (1)	C2—C3—H3	119.7
S2—O7—Ag2	137.9 (1)	C4—C3—H3	119.7
Ag2ⁱⁱ—O7—Ag2	104.99 (7)	C1—C6—H6	119.8
S2—O8—Ag1ⁱⁱ	126.2 (1)	C5—C6—H6	119.8
C14—O11—Ag1^v	137.8 (2)	C10—C9—H9	120.2
C6—C1—C2	120.2 (2)	C8—C9—H9	120.2
C6—C1—S1	120.6 (2)	C9—C10—H10	119.7
C2—C1—S1	119.15 (19)	C11—C10—H10	119.7
C3—C2—C1	119.8 (2)	C8—C13—H13	119.8
C2—C3—C4	120.6 (3)	C12—C13—H13	119.8
O4—C4—C3	117.9 (3)

O3—S1—O1—Ag1	−128.7 (2)	C2—C3—C4—O4	179.4 (3)
O2—S1—O1—Ag1	−0.5 (2)	C2—C3—C4—C5	−0.6 (4)
C1—S1—O1—Ag1	115.4 (2)	O4—C4—C5—C6	−179.3 (2)
O11ⁱⁱⁱ—Ag1—O1—S1	96.8 (2)	C3—C4—C5—C6	0.7 (4)
O8ⁱⁱ—Ag1—O1—S1	−41.0 (2)	O4—C4—C5—C7	0.0 (4)
O1w—Ag1—O1—S1	−111.7 (2)	C3—C4—C5—C7	180.0 (2)
O2w—Ag1—O1—S1	88.6 (2)	C2—C1—C6—C5	−0.2 (4)
O1ⁱ—Ag1—O1—S1	−177.1 (2)	S1—C1—C6—C5	178.07 (18)
O3—S1—O2—Ag2	−136.8 (1)	C4—C5—C6—C1	−0.3 (4)
O1—S1—O2—Ag2	95.1 (2)	C7—C5—C6—C1	−179.6 (2)
C1—S1—O2—Ag2	−20.5 (2)	Ag2^iv—O5—C7—O6	8.3 (4)
O7ⁱⁱ—Ag2—O2—S1	−128.5 (2)	Ag2^iv—O5—C7—C5	−171.7 (2)
O5^iv—Ag2—O2—S1	66.8 (2)	C6—C5—C7—O5	178.1 (2)
O3w—Ag2—O2—S1	−14.7 (2)	C4—C5—C7—O5	−1.2 (4)
O7—Ag2—O2—S1	155.5 (1)	C6—C5—C7—O6	−1.9 (3)
O8—S2—O7—Ag2ⁱⁱ	6.65 (17)	C4—C5—C7—O6	178.8 (2)
O9—S2—O7—Ag2ⁱⁱ	−121.5 (1)	O8—S2—C8—C13	−116.9 (2)
C8—S2—O7—Ag2ⁱⁱ	123.7 (1)	O9—S2—C8—C13	5.2 (2)
O8—S2—O7—Ag2	−151.8 (2)	O7—S2—C8—C13	123.1 (2)
O9—S2—O7—Ag2	80.1 (2)	O8—S2—C8—C9	63.7 (2)
C8—S2—O7—Ag2	−34.8 (2)	O9—S2—C8—C9	−174.3 (2)
O7ⁱⁱ—Ag2—O7—S2	159.8 (3)	O7—S2—C8—C9	−56.4 (2)
O5^iv—Ag2—O7—S2	−16.0 (2)	C13—C8—C9—C10	−0.5 (4)
O3w—Ag2—O7—S2	66.9 (2)	S2—C8—C9—C10	179.0 (2)
O2—Ag2—O7—S2	−107.2 (2)	C8—C9—C10—C11	0.3 (4)
O7ⁱⁱ—Ag2—O7—Ag2ⁱⁱ	0.0	C9—C10—C11—O10	179.7 (3)
O5^iv—Ag2—O7—Ag2ⁱⁱ	−175.79 (9)	C9—C10—C11—C12	0.1 (4)
O3w—Ag2—O7—Ag2ⁱⁱ	−92.86 (9)	O10—C11—C12—C13	−179.9 (2)
O2—Ag2—O7—Ag2ⁱⁱ	92.98 (9)	C10—C11—C12—C13	−0.3 (4)
O9—S2—O8—Ag1ⁱⁱ	−112.5 (2)	O10—C11—C12—C14	0.5 (4)
O7—S2—O8—Ag1ⁱⁱ	121.0 (2)	C10—C11—C12—C14	−179.9 (2)
C8—S2—O8—Ag1ⁱⁱ	4.7 (2)	C9—C8—C13—C12	0.3 (4)
O3—S1—C1—C6	10.8 (2)	S2—C8—C13—C12	−179.17 (18)
O1—S1—C1—C6	130.6 (2)	C11—C12—C13—C8	0.1 (4)
O2—S1—C1—C6	−109.4 (2)	C14—C12—C13—C8	179.6 (2)
O3—S1—C1—C2	−170.9 (2)	Ag1^v—O11—C14—O12	5.6 (4)
O1—S1—C1—C2	−51.1 (2)	Ag1^v—O11—C14—C12	−174.1 (2)
O2—S1—C1—C2	68.9 (2)	C13—C12—C14—O11	−179.4 (2)
C6—C1—C2—C3	0.2 (4)	C11—C12—C14—O11	0.1 (4)
S1—C1—C2—C3	−178.0 (2)	C13—C12—C14—O12	0.8 (3)
C1—C2—C3—C4	0.2 (4)	C11—C12—C14—O12	−179.6 (2)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+2, −y+2, −z+1; (iii) x−1, y−1, z−1; (iv) −x+2, −y+2, −z+2; (v) x+1, y+1, z+1.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O4—H4o···O5	0.85 (1)	1.81 (2)	2.612 (3)	156 (4)
O6—H6o···O3w^iv	0.85 (1)	1.77 (1)	2.621 (3)	177 (4)
O10—H10o···O11	0.85 (1)	1.77 (2)	2.587 (3)	159 (4)
O12—H12o···O2w^v	0.85 (1)	1.76 (1)	2.599 (3)	174 (4)
O1w—H1w1···O4w	0.85 (1)	1.94 (1)	2.787 (4)	177 (4)
O1w—H1w2···O3ⁱ	0.85 (1)	1.99 (2)	2.815 (3)	164 (5)
O2w—H2w1···O3^vi	0.85 (1)	2.03 (2)	2.847 (3)	162 (3)
O2w—H2w2···O4wⁱ	0.85 (1)	1.91 (2)	2.734 (3)	164 (3)
O3w—H3w1···O9^vii	0.85 (1)	1.91 (1)	2.757 (3)	174 (3)
O3w—H3w2···O1w^viii	0.85 (1)	1.89 (1)	2.722 (3)	169 (3)
O4w—H4w2···O2^vii	0.85 (1)	2.03 (1)	2.858 (3)	165 (4)
O4w—H4w1···O9^vii	0.85 (1)	2.00 (1)	2.847 (3)	170 (5)

Symmetry codes: (i) −x+1, −y+1, −z+1; (iv) −x+2, −y+2, −z+2; (v) x+1, y+1, z+1; (vi) −x+2, −y+1, −z+1; (vii) x−1, y, z; (viii) −x+1, −y+2, −z+1.

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