(Cyclo­butane-1,1-dicarboxyl­ato)(2-morpholinoethyl­amine)platinum(II) trihydrate

Xie, M.-J.; Chen, X.-Z.; Liu, W.-P.; Yu, Y.; Ye, Q.-S.

doi:10.1107/S1600536806052329

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(Cyclobutane-1,1-dicarboxylato)(2-morpholinoethylamine)platinum(II) trihydrate

M.-J. Xie, X.-Z. Chen, W.-P. Liu, Y. Yu and Q.-S. Ye

The reaction of 2-morpholinoethylamine and cyclobutane-1,1-dicarboxylic acid with potassium tetrachloroplatinate(II) produced the monomeric title complex, [Pt(C₆H₆O₄)(C₆H₁₄N₂O)]·3H₂O. The Pt^II ion is tetracoordinated and situated in a square-planar environment.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806052329/er2022sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536806052329/er2022Isup2.hkl Contains datablock I

CCDC reference: 633683

checkCIF report

Key indicators

Single-crystal X-ray study
T = 294 K
Mean (C-C) = 0.005 Å
Disorder in main residue
R factor = 0.015
wR factor = 0.034
Data-to-parameter ratio = 16.0

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT417_ALERT_2_B Short Inter D-H..H-D       H6B    ..  H8D     ..       2.09 Ang.

Alert level C
ABSTM02_ALERT_3_C  The ratio of expected to reported Tmax/Tmin(RR) is > 1.10
            Tmin and Tmax reported:      0.203     0.346
            Tmin and Tmax expected:      0.170     0.347
            RR =      1.201
            Please check that your absorption correction is appropriate.
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT060_ALERT_3_C Ratio Tmax/Tmin (Exp-to-Rep) (too) Large .......       1.20
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C4
PLAT301_ALERT_3_C Main Residue  Disorder .........................       5.00 Perc.
PLAT417_ALERT_2_C Short Inter D-H..H-D       H6A    ..  H8C     ..       2.13 Ang.
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          2
            N1  -PT1 -O1  -C1   -153.00  6.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          6
            N2  -PT1 -O3  -C6    156.00 12.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         43
            O1  -PT1 -N1  -C7    -50.00  7.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         47
            O3  -PT1 -N2  -C12   -45.00 12.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         50
            O3  -PT1 -N2  -C9   -163.00 12.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         53
            O3  -PT1 -N2  -C8     77.00 12.00   1.555   1.555   1.555   1.555
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          2
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      20.60 Deg.
              C4'  -C3   -C4      1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      18.90 Deg.
              H3A  -C3   -H3C     1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      18.90 Deg.
              H3B  -C3   -H3D     1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      20.50 Deg.
              C4   -C5   -C4'     1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      17.80 Deg.
              H5A  -C5   -H5C     1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      19.00 Deg.
              H5B  -C5   -H5D     1.555   1.555   1.555

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           28.26
           From the CIF: _reflns_number_total               3786
           Count of symmetry unique reflns         2154
           Completeness (_total/calc)            175.77%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured      1632
           Fraction of Friedel pairs measured     0.758
           Are heavy atom types Z>Si present        yes

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  19 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   9 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   8 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: APEX2 (Bruker, 2004); cell refinement: SAINT (Bruker, 2004); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 2000); software used to prepare material for publication: SHELXTL (Sheldrick, 2000) and DIAMOND (Bergerhoff, 1996).

(Cyclobutane-1,1-dicarboxylato)(2-morpholinoethylamine)platinum(II) trihydrate top

Crystal data top

[Pt(C₆H₆O₄)(C₆H₁₄N₂O)]·3H₂O	F(000) = 1016
M_r = 521.44	D_x = 2.002 Mg m⁻³
Monoclinic, Cc	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: C -2yc	Cell parameters from 6146 reflections
a = 15.8575 (9) Å	θ = 2.6–28.2°
b = 12.3884 (7) Å	µ = 8.15 mm⁻¹
c = 9.0359 (5) Å	T = 294 K
β = 102.889 (1)°	Block, colourless
V = 1730.37 (17) Å³	0.24 × 0.19 × 0.13 mm
Z = 4

Data collection top

Bruker APEXII CCD area-detector diffractometer	3786 independent reflections
Radiation source: fine-focus sealed tube	3509 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.019
Detector resolution: 10 pixels mm^-1	θ_max = 28.3°, θ_min = 2.1°
φ and ω scans	h = −20→20
Absorption correction: multi-scan (Sheldrick, 2002)	k = −15→15
T_min = 0.203, T_max = 0.346	l = −11→11
8167 measured reflections

Refinement top

Refinement on F²	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H atoms treated by a mixture of independent and constrained refinement
R[F² > 2σ(F²)] = 0.015	w = 1/[σ²(F_o²)] where P = (F_o² + 2F_c²)/3
wR(F²) = 0.034	(Δ/σ)_max = 0.003
S = 0.87	Δρ_max = 0.59 e Å⁻³
3786 reflections	Δρ_min = −0.72 e Å⁻³
237 parameters	Extinction correction: SHELXL97 (Sheldrick, 1997), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
33 restraints	Extinction coefficient: 0.00297 (8)
Primary atom site location: structure-invariant direct methods	Absolute structure: Flack (1983), with 1632 Friedel pairs
Secondary atom site location: difference Fourier map	Absolute structure parameter: 0.016 (7)

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Pt1	−0.00116 (4)	0.333885 (7)	0.24737 (5)	0.02662 (5)
O1	0.0894 (3)	0.3145 (2)	0.1240 (5)	0.0343 (7)
O2	0.12701 (17)	0.2429 (2)	−0.0746 (3)	0.0422 (6)
O3	−0.0902 (4)	0.3391 (2)	0.0486 (7)	0.0331 (13)
O4	−0.13866 (18)	0.2773 (2)	−0.1806 (3)	0.0455 (7)
C1	0.0738 (2)	0.2526 (3)	0.0055 (4)	0.0305 (7)
C2	−0.0116 (2)	0.1928 (3)	−0.0327 (4)	0.0310 (7)
C3	−0.0210 (3)	0.1041 (3)	−0.1563 (4)	0.0418 (9)
H3A	0.0279	0.0987	−0.2022	0.050*	0.44 (3)
H3B	−0.0739	0.1095	−0.2323	0.050*	0.44 (3)
H3C	0.0330	0.0809	−0.1769	0.050*	0.56 (3)
H3D	−0.0615	0.1226	−0.2486	0.050*	0.56 (3)
C4	−0.0248 (15)	0.0149 (7)	−0.0383 (12)	0.057 (4)	0.44 (3)
H4A	−0.0783	−0.0260	−0.0599	0.068*	0.44 (3)
H4B	0.0250	−0.0328	−0.0193	0.068*	0.44 (3)
C4'	−0.0587 (11)	0.0280 (9)	−0.0550 (10)	0.052 (3)	0.56 (3)
H4'A	−0.0338	−0.0438	−0.0471	0.062*	0.56 (3)
H4'B	−0.1214	0.0246	−0.0804	0.062*	0.56 (3)
C5	−0.0213 (2)	0.1016 (3)	0.0836 (4)	0.0390 (9)
H5A	−0.0740	0.1067	0.1188	0.047*	0.44 (3)
H5B	0.0278	0.0960	0.1674	0.047*	0.44 (3)
H5C	−0.0623	0.1185	0.1438	0.047*	0.56 (3)
H5D	0.0326	0.0777	0.1460	0.047*	0.56 (3)
C6	−0.0862 (2)	0.2732 (3)	−0.0588 (4)	0.0303 (7)
N1	−0.0900 (3)	0.3587 (3)	0.3734 (5)	0.0344 (9)
H1A	−0.1281	0.4095	0.3297	0.041*
H1B	−0.1192	0.2972	0.3801	0.041*
N2	0.0880 (5)	0.3335 (2)	0.4495 (8)	0.0302 (15)
O5	0.2714 (2)	0.3363 (2)	0.6007 (4)	0.0549 (8)
C7	−0.0442 (2)	0.3943 (4)	0.5260 (4)	0.0433 (9)
H7A	−0.0810	0.3853	0.5977	0.052*
H7B	−0.0287	0.4700	0.5240	0.052*
C8	0.0363 (3)	0.3259 (3)	0.5728 (5)	0.0418 (10)
H8A	0.0204	0.2514	0.5856	0.050*
H8B	0.0710	0.3514	0.6687	0.050*
C9	0.1478 (2)	0.2386 (3)	0.4591 (4)	0.0364 (8)
H9A	0.1716	0.2371	0.3691	0.044*
H9B	0.1149	0.1727	0.4605	0.044*
C10	0.2213 (2)	0.2413 (4)	0.5980 (5)	0.0441 (9)
H10A	0.1980	0.2384	0.6886	0.053*
H10B	0.2578	0.1785	0.5981	0.053*
C11	0.2188 (3)	0.4286 (4)	0.6047 (6)	0.0569 (12)
H11A	0.2536	0.4933	0.6071	0.068*
H11B	0.1967	0.4271	0.6965	0.068*
C12	0.1429 (3)	0.4323 (3)	0.4662 (5)	0.0416 (9)
H12A	0.1073	0.4947	0.4747	0.050*
H12B	0.1654	0.4413	0.3755	0.050*
O6	0.7856 (2)	0.4736 (2)	0.7595 (4)	0.0527 (8)
H6A	0.800 (3)	0.410 (3)	0.783 (5)	0.079*
H6B	0.756 (3)	0.476 (4)	0.664 (3)	0.079*
O7	0.3058 (2)	0.3007 (3)	0.0122 (4)	0.0569 (8)
H7C	0.328 (3)	0.298 (5)	0.107 (4)	0.085*
H7D	0.2529 (18)	0.299 (5)	−0.008 (6)	0.085*
O8	0.1955 (2)	0.0284 (3)	0.9685 (4)	0.0654 (9)
H8C	0.225 (4)	0.008 (4)	0.899 (6)	0.098*
H8D	0.193 (4)	0.098 (2)	0.961 (7)	0.098*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.03237 (6)	0.02665 (6)	0.02179 (6)	0.00370 (8)	0.00809 (4)	0.00099 (9)
O1	0.0357 (16)	0.0396 (16)	0.0298 (16)	−0.0041 (15)	0.0120 (12)	−0.0044 (16)
O2	0.0399 (14)	0.0598 (18)	0.0307 (14)	0.0023 (13)	0.0159 (12)	−0.0060 (13)
O3	0.036 (3)	0.034 (3)	0.029 (3)	0.0076 (12)	0.008 (2)	0.0034 (13)
O4	0.0515 (16)	0.0490 (16)	0.0300 (14)	0.0135 (13)	−0.0035 (12)	−0.0035 (12)
C1	0.0354 (18)	0.0330 (18)	0.0224 (17)	0.0076 (14)	0.0051 (14)	0.0052 (13)
C2	0.0392 (19)	0.0293 (16)	0.0249 (18)	0.0026 (14)	0.0080 (15)	0.0013 (13)
C3	0.051 (2)	0.037 (2)	0.035 (2)	0.0093 (17)	0.0045 (17)	−0.0115 (16)
C4	0.060 (8)	0.044 (5)	0.074 (6)	0.001 (5)	0.033 (5)	−0.012 (4)
C4'	0.052 (6)	0.034 (4)	0.072 (5)	0.002 (4)	0.022 (4)	−0.010 (3)
C5	0.047 (2)	0.0307 (19)	0.039 (2)	0.0027 (15)	0.0080 (18)	0.0071 (15)
C6	0.0359 (18)	0.0281 (17)	0.0273 (18)	0.0038 (14)	0.0079 (15)	0.0041 (14)
N1	0.0364 (19)	0.0415 (19)	0.0286 (19)	0.008 (2)	0.0142 (15)	0.002 (2)
N2	0.036 (4)	0.030 (3)	0.023 (3)	0.0003 (14)	0.003 (3)	0.0038 (14)
O5	0.0383 (16)	0.066 (2)	0.058 (2)	−0.0057 (13)	0.0057 (15)	−0.0123 (14)
C7	0.043 (2)	0.058 (3)	0.033 (2)	0.0101 (19)	0.0166 (17)	−0.0076 (18)
C8	0.040 (2)	0.059 (3)	0.028 (2)	0.0057 (18)	0.0098 (17)	0.0037 (17)
C9	0.0369 (19)	0.0341 (19)	0.037 (2)	0.0069 (15)	0.0056 (16)	−0.0015 (15)
C10	0.038 (2)	0.056 (3)	0.037 (2)	0.0060 (17)	0.0051 (17)	0.0025 (18)
C11	0.056 (3)	0.057 (3)	0.056 (3)	−0.017 (2)	0.008 (2)	−0.020 (2)
C12	0.054 (2)	0.036 (2)	0.037 (2)	−0.0038 (17)	0.0143 (18)	−0.0027 (16)
O6	0.0563 (18)	0.0386 (17)	0.059 (2)	0.0048 (13)	0.0030 (15)	0.0003 (13)
O7	0.0550 (19)	0.072 (2)	0.0421 (18)	−0.0063 (18)	0.0080 (15)	0.0031 (17)
O8	0.072 (2)	0.056 (2)	0.068 (2)	0.0170 (17)	0.0132 (18)	0.0030 (17)

Geometric parameters (Å, º) top

Pt1—O1	2.019 (4)	N1—H1A	0.9000
Pt1—O3	2.023 (6)	N1—H1B	0.9000
Pt1—N1	2.023 (5)	N2—C12	1.491 (6)
Pt1—N2	2.045 (7)	N2—C9	1.500 (6)
O1—C1	1.295 (5)	N2—C8	1.527 (9)
O2—C1	1.233 (4)	O5—C10	1.418 (5)
O3—C6	1.280 (6)	O5—C11	1.420 (6)
O4—C6	1.224 (4)	C7—C8	1.512 (6)
C1—C2	1.515 (5)	C7—H7A	0.9700
C2—C6	1.524 (5)	C7—H7B	0.9700
C2—C3	1.550 (5)	C8—H8A	0.9700
C2—C5	1.573 (5)	C8—H8B	0.9700
C3—C4'	1.527 (8)	C9—C10	1.511 (5)
C3—C4	1.546 (9)	C9—H9A	0.9700
C3—H3A	0.9600	C9—H9B	0.9700
C3—H3B	0.9600	C10—H10A	0.9700
C3—H3C	0.9601	C10—H10B	0.9700
C3—H3D	0.9600	C11—C12	1.531 (6)
C4—C5	1.531 (9)	C11—H11A	0.9700
C4—H4A	0.9700	C11—H11B	0.9700
C4—H4B	0.9700	C12—H12A	0.9700
C4'—C5	1.556 (8)	C12—H12B	0.9700
C4'—H4'A	0.9700	O6—H6A	0.83 (3)
C4'—H4'B	0.9700	O6—H6B	0.88 (2)
C5—H5A	0.9601	O7—H7C	0.85 (3)
C5—H5B	0.9600	O7—H7D	0.82 (3)
C5—H5C	0.9600	O8—H8C	0.90 (3)
C5—H5D	0.9600	O8—H8D	0.86 (3)
N1—C7	1.476 (6)

O1—Pt1—O3	87.4 (2)	H5A—C5—H5C	17.8
O1—Pt1—N1	177.92 (18)	H5B—C5—H5C	95.9
O3—Pt1—N1	93.4 (2)	C4—C5—H5D	95.2
O1—Pt1—N2	93.3 (2)	C4'—C5—H5D	115.0
O3—Pt1—N2	178.24 (14)	C2—C5—H5D	114.1
N1—Pt1—N2	85.9 (3)	H5A—C5—H5D	123.5
C1—O1—Pt1	120.0 (3)	H5B—C5—H5D	19.0
C6—O3—Pt1	120.7 (4)	H5C—C5—H5D	111.2
O2—C1—O1	120.9 (4)	O4—C6—O3	121.2 (4)
O2—C1—C2	120.9 (3)	O4—C6—C2	120.9 (3)
O1—C1—C2	118.2 (3)	O3—C6—C2	117.8 (4)
C1—C2—C6	109.8 (3)	C7—N1—Pt1	108.2 (3)
C1—C2—C3	116.6 (3)	C7—N1—H1A	110.1
C6—C2—C3	113.9 (3)	Pt1—N1—H1A	110.1
C1—C2—C5	114.5 (3)	C7—N1—H1B	110.1
C6—C2—C5	112.6 (3)	Pt1—N1—H1B	110.1
C3—C2—C5	88.0 (3)	H1A—N1—H1B	108.4
C4'—C3—C4	20.6 (6)	C12—N2—C9	106.9 (5)
C4'—C3—C2	89.6 (4)	C12—N2—C8	111.9 (4)
C4—C3—C2	91.2 (4)	C9—N2—C8	110.1 (4)
C4'—C3—H3A	132.7	C12—N2—Pt1	111.1 (3)
C4—C3—H3A	114.0	C9—N2—Pt1	110.8 (4)
C2—C3—H3A	113.9	C8—N2—Pt1	106.0 (4)
C4'—C3—H3B	94.3	C10—O5—C11	109.8 (4)
C4—C3—H3B	112.3	N1—C7—C8	107.6 (3)
C2—C3—H3B	113.3	N1—C7—H7A	110.2
H3A—C3—H3B	110.9	C8—C7—H7A	110.2
C4'—C3—H3C	114.6	N1—C7—H7B	110.2
C4—C3—H3C	95.3	C8—C7—H7B	110.2
C2—C3—H3C	113.9	H7A—C7—H7B	108.5
H3A—C3—H3C	18.9	C7—C8—N2	108.6 (4)
H3B—C3—H3C	123.8	C7—C8—H8A	110.0
C4'—C3—H3D	113.1	N2—C8—H8A	110.0
C4—C3—H3D	130.4	C7—C8—H8B	110.0
C2—C3—H3D	113.3	N2—C8—H8B	110.0
H3A—C3—H3D	95.2	H8A—C8—H8B	108.4
H3B—C3—H3D	18.9	N2—C9—C10	113.0 (4)
H3C—C3—H3D	110.9	N2—C9—H9A	109.0
C5—C4—C3	89.6 (5)	C10—C9—H9A	109.0
C5—C4—H4A	113.7	N2—C9—H9B	109.0
C3—C4—H4A	113.7	C10—C9—H9B	109.0
C5—C4—H4B	113.7	H9A—C9—H9B	107.8
C3—C4—H4B	113.7	O5—C10—C9	111.0 (3)
H4A—C4—H4B	111.0	O5—C10—H10A	109.4
C3—C4'—C5	89.4 (4)	C9—C10—H10A	109.4
C3—C4'—H4'A	113.7	O5—C10—H10B	109.4
C5—C4'—H4'A	113.7	C9—C10—H10B	109.4
C3—C4'—H4'B	113.7	H10A—C10—H10B	108.0
C5—C4'—H4'B	113.7	O5—C11—C12	111.2 (3)
H4'A—C4'—H4'B	111.0	O5—C11—H11A	109.4
C4—C5—C4'	20.5 (6)	C12—C11—H11A	109.4
C4—C5—C2	90.9 (4)	O5—C11—H11B	109.4
C4'—C5—C2	87.7 (4)	C12—C11—H11B	109.4
C4—C5—H5A	112.9	H11A—C11—H11B	108.0
C4'—C5—H5A	95.8	N2—C12—C11	113.1 (4)
C2—C5—H5A	113.3	N2—C12—H12A	108.9
C4—C5—H5B	114.2	C11—C12—H12A	108.9
C4'—C5—H5B	133.5	N2—C12—H12B	108.9
C2—C5—H5B	113.4	C11—C12—H12B	108.9
H5A—C5—H5B	110.8	H12A—C12—H12B	107.8
C4—C5—H5C	129.8	H6A—O6—H6B	110 (3)
C4'—C5—H5C	113.5	H7C—O7—H7D	114 (4)
C2—C5—H5C	113.6	H8C—O8—H8D	105 (3)

O3—Pt1—O1—C1	−40.4 (3)	Pt1—O3—C6—C2	−1.1 (6)
N1—Pt1—O1—C1	−153 (6)	C1—C2—C6—O4	120.0 (4)
N2—Pt1—O1—C1	141.2 (3)	C3—C2—C6—O4	−12.9 (5)
O1—Pt1—O3—C6	42.6 (4)	C5—C2—C6—O4	−111.1 (4)
N1—Pt1—O3—C6	−139.3 (4)	C1—C2—C6—O3	−57.2 (5)
N2—Pt1—O3—C6	156 (12)	C3—C2—C6—O3	169.9 (4)
Pt1—O1—C1—O2	177.3 (3)	C5—C2—C6—O3	71.7 (5)
Pt1—O1—C1—C2	−2.5 (5)	O1—Pt1—N1—C7	−50 (7)
O2—C1—C2—C6	−120.3 (4)	O3—Pt1—N1—C7	−162.1 (3)
O1—C1—C2—C6	59.4 (4)	N2—Pt1—N1—C7	16.3 (3)
O2—C1—C2—C3	11.2 (5)	O1—Pt1—N2—C12	68.7 (4)
O1—C1—C2—C3	−169.1 (3)	O3—Pt1—N2—C12	−45 (12)
O2—C1—C2—C5	111.8 (4)	N1—Pt1—N2—C12	−109.4 (4)
O1—C1—C2—C5	−68.4 (4)	O1—Pt1—N2—C9	−50.0 (4)
C1—C2—C3—C4'	133.8 (7)	O3—Pt1—N2—C9	−163 (12)
C6—C2—C3—C4'	−96.6 (8)	N1—Pt1—N2—C9	131.9 (4)
C5—C2—C3—C4'	17.3 (7)	O1—Pt1—N2—C8	−169.5 (2)
C1—C2—C3—C4	113.3 (9)	O3—Pt1—N2—C8	77 (12)
C6—C2—C3—C4	−117.1 (9)	N1—Pt1—N2—C8	12.4 (2)
C5—C2—C3—C4	−3.2 (9)	Pt1—N1—C7—C8	−42.0 (4)
C4'—C3—C4—C5	−82.3 (13)	N1—C7—C8—N2	54.3 (5)
C2—C3—C4—C5	3.3 (9)	C12—N2—C8—C7	82.6 (5)
C4—C3—C4'—C5	77.1 (13)	C9—N2—C8—C7	−158.7 (4)
C2—C3—C4'—C5	−17.5 (7)	Pt1—N2—C8—C7	−38.7 (4)
C3—C4—C5—C4'	77.6 (14)	C12—N2—C9—C10	52.1 (6)
C3—C4—C5—C2	−3.2 (9)	C8—N2—C9—C10	−69.7 (5)
C3—C4'—C5—C4	−81.6 (13)	Pt1—N2—C9—C10	173.4 (3)
C3—C4'—C5—C2	17.3 (7)	C11—O5—C10—C9	60.6 (5)
C1—C2—C5—C4	−115.2 (9)	N2—C9—C10—O5	−58.8 (5)
C6—C2—C5—C4	118.4 (9)	C10—O5—C11—C12	−59.4 (5)
C3—C2—C5—C4	3.2 (9)	C9—N2—C12—C11	−50.8 (6)
C1—C2—C5—C4'	−135.4 (7)	C8—N2—C12—C11	69.9 (5)
C6—C2—C5—C4'	98.1 (7)	Pt1—N2—C12—C11	−171.9 (3)
C3—C2—C5—C4'	−17.0 (7)	O5—C11—C12—N2	56.5 (6)
Pt1—O3—C6—O4	−178.4 (3)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O8—H8D···O2ⁱ	0.86 (3)	2.07 (3)	2.864 (4)	153 (6)
O8—H8C···O6ⁱⁱ	0.90 (3)	1.79 (3)	2.697 (5)	177 (6)
O7—H7D···O2	0.82 (3)	2.07 (3)	2.859 (5)	161 (6)
O7—H7C···O4ⁱⁱⁱ	0.85 (3)	2.10 (4)	2.885 (4)	154 (6)
O6—H6B···O8^iv	0.88 (2)	1.82 (3)	2.698 (5)	176 (5)
O6—H6A···O4^v	0.83 (3)	1.91 (3)	2.713 (4)	163 (6)
N1—H1A···O6^vi	0.90	2.00	2.891 (5)	173
N1—H1A···O6^vi	0.90	2.00	2.891 (5)	173

Symmetry codes: (i) x, y, z+1; (ii) x−1/2, y−1/2, z; (iii) x+1/2, −y+1/2, z+1/2; (iv) x+1/2, −y+1/2, z−1/2; (v) x+1, y, z+1; (vi) x−1, −y+1, z−1/2.

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