1,2-Bis(4-ferrocenylphen­yl)ethene

The mol­ecular structure of the centrosymmetric title compound, [Fe₂(C₅H₅)₂(C₂₄H₁₈)], represents a new application of cross-metathesis for the preparation of functionalized olefins containing two organometallic groups. The two benzene and attached cyclopentadienyl (Cp) rings and the double bond are almost coplanar.

Key indicators

• Single-crystal X-ray study
• T = 113 K
• Mean [sigma](C-C) = 0.005 Å
• R factor = 0.061
• wR factor = 0.152
• Data-to-parameter ratio = 14.7

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.50 Ratio
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical .          ?

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   4 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

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Computing details

Data collection: CrystalStructure (Rigaku/MSC, 2004); cell refinement: CrystalStructure; data reduction: CrystalStructure; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: please provide; software used to prepare material for publication: CrystalStructure.

1,2-bis(4-ferrocenylphenyl)ethene

Crystal data

[(C5H5)2Fe2(C24H18)]	F(000) = 568
Mr = 548.26	Dx = 1.477 Mg m^−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71070 Å
Hall symbol: -P 2ybc	Cell parameters from 3251 reflections
a = 12.452 (2) Å	θ = 1.7–27.9°
b = 8.1688 (14) Å	µ = 1.20 mm^−1
c = 12.5419 (18) Å	T = 113 K
β = 104.880 (9)°	Platelet, orange
V = 1233.0 (3) Å^3	0.20 × 0.16 × 0.02 mm
Z = 2

Data collection

Rigaku Saturn diffractometer	2424 independent reflections
Radiation source: rotating anode	2113 reflections with I > 2σ(I)
Confocal monochromator	Rint = 0.066
Detector resolution: 7.31 pixels mm^-1	θmax = 26.0°, θmin = 1.7°
ω scans	h = −15→15
Absorption correction: multi-scan (Jacobson, 1998)	k = −9→10
Tmin = 0.796, Tmax = 0.976	l = −15→15
12668 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.061	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.152	H-atom parameters constrained
S = 1.13	w = 1/[σ^2(Fo^2) + (0.0721P)^2 + 1.1009P] where P = (Fo^2 + 2Fc^2)/3
2424 reflections	(Δ/σ)max < 0.001
165 parameters	Δρmax = 0.92 e Å^−3
0 restraints	Δρmin = −0.90 e Å^−3

Special details

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All e.s.d.'s are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Fe1	0.32776 (4)	0.17867 (7)	0.08230 (4)	0.0256 (2)
C1	0.4662 (3)	0.3233 (5)	0.0886 (3)	0.0335 (10)
H1	0.5141	0.3170	0.0408	0.040*
C2	0.4778 (3)	0.2333 (5)	0.1894 (3)	0.0321 (9)
H2	0.5346	0.1562	0.2196	0.038*
C3	0.3895 (3)	0.2797 (5)	0.2359 (3)	0.0307 (9)
H3	0.3780	0.2393	0.3031	0.037*
C4	0.3208 (3)	0.3976 (5)	0.1651 (3)	0.0322 (9)
H4	0.2560	0.4481	0.1768	0.039*
C5	0.3678 (4)	0.4256 (5)	0.0729 (4)	0.0386 (10)
H5	0.3397	0.4978	0.0129	0.046*
C6	0.2390 (3)	0.0939 (5)	−0.0698 (3)	0.0315 (9)
H6	0.2280	0.1493	−0.1384	0.038*
C7	0.3288 (3)	−0.0141 (5)	−0.0232 (3)	0.0294 (9)
H7	0.3880	−0.0427	−0.0546	0.035*
C8	0.3134 (3)	−0.0722 (5)	0.0806 (3)	0.0280 (9)
H8	0.3608	−0.1464	0.1292	0.034*
C9	0.2140 (3)	0.0013 (4)	0.0983 (3)	0.0260 (8)
C10	0.1681 (3)	0.1050 (5)	0.0037 (3)	0.0300 (9)
H10	0.1025	0.1691	−0.0076	0.036*
C11	0.1672 (3)	−0.0155 (4)	0.1960 (3)	0.0238 (8)
C12	0.0816 (3)	0.0891 (5)	0.2094 (3)	0.0312 (9)
H12	0.0523	0.1681	0.1540	0.037*
C13	0.0388 (3)	0.0805 (5)	0.3013 (3)	0.0318 (9)
H13	−0.0188	0.1533	0.3075	0.038*
C14	0.0799 (3)	−0.0353 (5)	0.3855 (3)	0.0244 (8)
C15	0.1620 (3)	−0.1440 (5)	0.3706 (3)	0.0271 (8)
H15	0.1886	−0.2265	0.4243	0.033*
C16	0.2060 (3)	−0.1340 (5)	0.2783 (3)	0.0276 (8)
H16	0.2626	−0.2081	0.2713	0.033*
C17	0.0384 (3)	−0.0462 (5)	0.4865 (3)	0.0266 (8)
H17	0.0708	−0.1291	0.5378	0.032*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Fe1	0.0289 (4)	0.0273 (4)	0.0215 (4)	−0.0007 (2)	0.0080 (2)	0.0006 (2)
C1	0.033 (2)	0.034 (2)	0.037 (2)	−0.0074 (17)	0.0147 (18)	−0.0011 (18)
C2	0.032 (2)	0.032 (2)	0.032 (2)	−0.0018 (18)	0.0082 (17)	−0.0053 (18)
C3	0.034 (2)	0.036 (2)	0.023 (2)	−0.0061 (18)	0.0069 (16)	−0.0078 (17)
C4	0.035 (2)	0.028 (2)	0.035 (2)	−0.0003 (17)	0.0115 (18)	−0.0097 (18)
C5	0.048 (3)	0.028 (2)	0.037 (2)	−0.012 (2)	0.006 (2)	0.0062 (19)
C6	0.036 (2)	0.038 (2)	0.0206 (19)	−0.0057 (19)	0.0083 (16)	−0.0022 (17)
C7	0.032 (2)	0.034 (2)	0.025 (2)	−0.0050 (17)	0.0127 (16)	−0.0086 (17)
C8	0.031 (2)	0.027 (2)	0.027 (2)	0.0002 (16)	0.0094 (16)	−0.0017 (16)
C9	0.0298 (19)	0.0236 (19)	0.0251 (19)	−0.0025 (16)	0.0082 (15)	−0.0023 (16)
C10	0.036 (2)	0.032 (2)	0.0221 (19)	−0.0021 (17)	0.0064 (16)	0.0019 (17)
C11	0.0246 (18)	0.0257 (19)	0.0210 (18)	−0.0050 (15)	0.0059 (14)	−0.0018 (15)
C12	0.037 (2)	0.032 (2)	0.028 (2)	0.0077 (18)	0.0130 (17)	0.0075 (17)
C13	0.033 (2)	0.036 (2)	0.027 (2)	0.0098 (18)	0.0097 (17)	0.0034 (18)
C14	0.0277 (19)	0.0249 (19)	0.0216 (18)	−0.0055 (15)	0.0082 (15)	−0.0002 (15)
C15	0.032 (2)	0.028 (2)	0.0222 (19)	−0.0003 (16)	0.0077 (15)	0.0046 (16)
C16	0.028 (2)	0.028 (2)	0.028 (2)	0.0047 (16)	0.0097 (16)	0.0007 (17)
C17	0.034 (2)	0.028 (2)	0.0187 (18)	−0.0035 (16)	0.0079 (15)	−0.0002 (15)

Geometric parameters (Å, º)

Fe1—C1	2.075 (4)	C11—C16	1.407 (5)
Fe1—C2	2.051 (4)	C12—C13	1.390 (5)
Fe1—C3	2.055 (4)	C13—C14	1.412 (5)
Fe1—C4	2.081 (4)	C14—C15	1.402 (6)
Fe1—C5	2.088 (4)	C14—C17	1.489 (5)
Fe1—C6	2.063 (4)	C15—C16	1.405 (5)
Fe1—C7	2.059 (4)	C17—C17^i	1.329 (6)
Fe1—C8	2.057 (4)	C1—H1	0.9494
Fe1—C9	2.072 (4)	C2—H2	0.9501
Fe1—C10	2.069 (4)	C3—H3	0.9496
C1—C2	1.437 (5)	C4—H4	0.9506
C1—C5	1.454 (6)	C5—H5	0.9494
C2—C3	1.422 (5)	C6—H6	0.9504
C3—C4	1.434 (6)	C7—H7	0.9498
C4—C5	1.442 (6)	C8—H8	0.9500
C6—C7	1.426 (6)	C10—H10	0.9498
C6—C10	1.434 (5)	C12—H12	0.9498
C7—C8	1.444 (5)	C13—H13	0.9501
C8—C9	1.443 (5)	C15—H15	0.9502
C9—C10	1.450 (5)	C16—H16	0.9501
C9—C11	1.492 (5)	C17—H17	0.9497
C11—C12	1.409 (5)
C1—Fe1—C2	40.78 (15)	Fe1—C7—C6	69.9 (2)
C1—Fe1—C3	68.19 (15)	Fe1—C7—C8	69.4 (2)
C1—Fe1—C4	68.42 (15)	C6—C7—C8	107.5 (3)
C1—Fe1—C5	40.89 (18)	Fe1—C8—C7	69.5 (2)
C1—Fe1—C6	117.96 (15)	Fe1—C8—C9	70.1 (2)
C1—Fe1—C7	108.53 (15)	C7—C8—C9	108.6 (3)
C1—Fe1—C8	129.57 (16)	Fe1—C9—C8	69.0 (2)
C1—Fe1—C9	167.61 (15)	Fe1—C9—C10	69.4 (2)
C1—Fe1—C10	150.61 (15)	Fe1—C9—C11	124.4 (2)
C2—Fe1—C3	40.53 (15)	C8—C9—C10	106.9 (3)
C2—Fe1—C4	68.52 (15)	C8—C9—C11	128.3 (3)
C2—Fe1—C5	68.67 (18)	C10—C9—C11	124.8 (3)
C2—Fe1—C6	149.35 (15)	Fe1—C10—C6	69.5 (2)
C2—Fe1—C7	115.62 (16)	Fe1—C10—C9	69.6 (2)
C2—Fe1—C8	106.61 (16)	C6—C10—C9	108.1 (3)
C2—Fe1—C9	128.27 (15)	C9—C11—C12	120.6 (3)
C2—Fe1—C10	167.92 (15)	C9—C11—C16	122.2 (3)
C3—Fe1—C4	40.58 (15)	C12—C11—C16	117.2 (3)
C3—Fe1—C5	68.15 (17)	C11—C12—C13	122.1 (4)
C3—Fe1—C6	169.79 (16)	C12—C13—C14	120.8 (4)
C3—Fe1—C7	147.89 (16)	C13—C14—C15	117.5 (3)
C3—Fe1—C8	114.87 (15)	C13—C14—C17	122.6 (3)
C3—Fe1—C9	106.89 (15)	C15—C14—C17	120.0 (3)
C3—Fe1—C10	130.24 (15)	C14—C15—C16	121.7 (4)
C4—Fe1—C5	40.47 (17)	C11—C16—C15	120.8 (4)
C4—Fe1—C6	131.97 (15)	C14—C17—C17^i	127.8 (4)
C4—Fe1—C7	170.36 (15)	Fe1—C1—H1	126.56
C4—Fe1—C8	147.87 (15)	C2—C1—H1	126.17
C4—Fe1—C9	115.82 (15)	C5—C1—H1	126.14
C4—Fe1—C10	109.25 (15)	Fe1—C2—H2	125.21
C5—Fe1—C6	110.54 (18)	C1—C2—H2	125.88
C5—Fe1—C7	131.41 (17)	C3—C2—H2	126.02
C5—Fe1—C8	169.48 (18)	Fe1—C3—H3	125.95
C5—Fe1—C9	149.32 (17)	C2—C3—H3	125.46
C5—Fe1—C10	117.92 (18)	C4—C3—H3	125.51
C6—Fe1—C7	40.49 (15)	Fe1—C4—H4	126.57
C6—Fe1—C8	68.38 (15)	C3—C4—H4	126.21
C6—Fe1—C9	68.75 (15)	C5—C4—H4	126.18
C6—Fe1—C10	40.60 (15)	Fe1—C5—H5	126.87
C7—Fe1—C8	41.08 (15)	C1—C5—H5	126.20
C7—Fe1—C9	69.19 (15)	C4—C5—H5	126.25
C7—Fe1—C10	68.60 (15)	Fe1—C6—H6	126.56
C8—Fe1—C9	40.92 (15)	C7—C6—H6	125.52
C8—Fe1—C10	68.58 (16)	C10—C6—H6	125.63
C9—Fe1—C10	41.01 (15)	Fe1—C7—H7	126.03
Fe1—C1—C2	68.7 (2)	C6—C7—H7	126.33
Fe1—C1—C5	70.1 (2)	C8—C7—H7	126.15
C2—C1—C5	107.7 (3)	Fe1—C8—H8	126.23
Fe1—C2—C1	70.5 (2)	C7—C8—H8	125.71
Fe1—C2—C3	69.9 (2)	C9—C8—H8	125.65
C1—C2—C3	108.1 (3)	Fe1—C10—H10	126.52
Fe1—C3—C2	69.6 (2)	C6—C10—H10	125.94
Fe1—C3—C4	70.7 (2)	C9—C10—H10	125.96
C2—C3—C4	109.0 (3)	C11—C12—H12	119.00
Fe1—C4—C3	68.7 (2)	C13—C12—H12	118.93
Fe1—C4—C5	70.0 (2)	C12—C13—H13	119.63
C3—C4—C5	107.6 (3)	C14—C13—H13	119.62
Fe1—C5—C1	69.0 (2)	C14—C15—H15	119.21
Fe1—C5—C4	69.5 (2)	C16—C15—H15	119.12
C1—C5—C4	107.6 (4)	C11—C16—H16	119.58
Fe1—C6—C7	69.6 (2)	C15—C16—H16	119.65
Fe1—C6—C10	69.9 (2)	C14—C17—H17	116.06
C7—C6—C10	108.8 (3)	C17^i—C17—H17	116.15
C2—Fe1—C1—C5	−119.2 (3)	C2—Fe1—C8—C9	130.0 (2)
C3—Fe1—C1—C2	37.9 (2)	C3—Fe1—C8—C7	−152.8 (2)
C3—Fe1—C1—C5	−81.4 (3)	C3—Fe1—C8—C9	87.4 (2)
C4—Fe1—C1—C2	81.7 (2)	C4—Fe1—C8—C7	174.0 (3)
C4—Fe1—C1—C5	−37.5 (2)	C4—Fe1—C8—C9	54.1 (4)
C5—Fe1—C1—C2	119.2 (3)	C6—Fe1—C8—C7	37.8 (2)
C6—Fe1—C1—C2	−151.1 (2)	C6—Fe1—C8—C9	−82.1 (2)
C6—Fe1—C1—C5	89.6 (3)	C7—Fe1—C8—C9	−119.9 (3)
C7—Fe1—C1—C2	−108.0 (2)	C9—Fe1—C8—C7	119.9 (3)
C7—Fe1—C1—C5	132.7 (3)	C10—Fe1—C8—C7	81.6 (2)
C8—Fe1—C1—C2	−67.0 (3)	C10—Fe1—C8—C9	−38.3 (2)
C8—Fe1—C1—C5	173.8 (2)	C2—Fe1—C9—C8	−69.2 (3)
C10—Fe1—C1—C2	172.9 (3)	C2—Fe1—C9—C10	172.3 (2)
C10—Fe1—C1—C5	53.6 (4)	C2—Fe1—C9—C11	53.5 (4)
C1—Fe1—C2—C3	118.7 (3)	C3—Fe1—C9—C8	−108.7 (2)
C3—Fe1—C2—C1	−118.7 (3)	C3—Fe1—C9—C10	132.8 (2)
C4—Fe1—C2—C1	−81.4 (2)	C3—Fe1—C9—C11	14.0 (3)
C4—Fe1—C2—C3	37.3 (2)	C4—Fe1—C9—C8	−151.4 (2)
C5—Fe1—C2—C1	−37.8 (2)	C4—Fe1—C9—C10	90.1 (2)
C5—Fe1—C2—C3	80.9 (3)	C4—Fe1—C9—C11	−28.7 (3)
C6—Fe1—C2—C1	56.8 (4)	C5—Fe1—C9—C8	175.8 (3)
C6—Fe1—C2—C3	175.5 (3)	C5—Fe1—C9—C10	57.3 (4)
C7—Fe1—C2—C1	89.1 (3)	C5—Fe1—C9—C11	−61.4 (5)
C7—Fe1—C2—C3	−152.2 (2)	C6—Fe1—C9—C8	81.1 (2)
C8—Fe1—C2—C1	132.2 (2)	C6—Fe1—C9—C10	−37.4 (2)
C8—Fe1—C2—C3	−109.1 (2)	C6—Fe1—C9—C11	−156.2 (3)
C9—Fe1—C2—C1	172.0 (2)	C7—Fe1—C9—C8	37.6 (2)
C9—Fe1—C2—C3	−69.3 (3)	C7—Fe1—C9—C10	−80.9 (2)
C1—Fe1—C3—C2	−38.1 (2)	C7—Fe1—C9—C11	160.3 (3)
C1—Fe1—C3—C4	81.9 (2)	C8—Fe1—C9—C10	−118.5 (3)
C2—Fe1—C3—C4	120.0 (3)	C8—Fe1—C9—C11	122.7 (4)
C4—Fe1—C3—C2	−120.0 (3)	C10—Fe1—C9—C8	118.5 (3)
C5—Fe1—C3—C2	−82.3 (3)	C10—Fe1—C9—C11	−118.8 (4)
C5—Fe1—C3—C4	37.7 (2)	C1—Fe1—C10—C6	52.9 (4)
C7—Fe1—C3—C2	52.3 (4)	C1—Fe1—C10—C9	172.5 (3)
C7—Fe1—C3—C4	172.2 (3)	C3—Fe1—C10—C6	173.6 (2)
C8—Fe1—C3—C2	86.7 (3)	C3—Fe1—C10—C9	−66.9 (3)
C8—Fe1—C3—C4	−153.3 (2)	C4—Fe1—C10—C6	132.9 (2)
C9—Fe1—C3—C2	129.9 (2)	C4—Fe1—C10—C9	−107.5 (2)
C9—Fe1—C3—C4	−110.2 (2)	C5—Fe1—C10—C6	89.5 (3)
C10—Fe1—C3—C2	169.0 (2)	C5—Fe1—C10—C9	−150.9 (2)
C10—Fe1—C3—C4	−71.1 (3)	C6—Fe1—C10—C9	119.5 (3)
C1—Fe1—C4—C3	−81.2 (2)	C7—Fe1—C10—C6	−37.1 (2)
C1—Fe1—C4—C5	37.9 (3)	C7—Fe1—C10—C9	82.5 (2)
C2—Fe1—C4—C3	−37.2 (2)	C8—Fe1—C10—C6	−81.3 (2)
C2—Fe1—C4—C5	81.9 (3)	C8—Fe1—C10—C9	38.2 (2)
C3—Fe1—C4—C5	119.1 (3)	C9—Fe1—C10—C6	−119.5 (3)
C5—Fe1—C4—C3	−119.1 (3)	C5—C1—C2—C3	−0.6 (5)
C6—Fe1—C4—C3	170.0 (2)	Fe1—C1—C5—C4	59.0 (3)
C6—Fe1—C4—C5	−70.9 (3)	C5—C1—C2—Fe1	59.4 (3)
C8—Fe1—C4—C3	49.9 (4)	C2—C1—C5—C4	0.4 (5)
C8—Fe1—C4—C5	169.1 (3)	C2—C1—C5—Fe1	−58.6 (3)
C9—Fe1—C4—C3	86.1 (2)	Fe1—C1—C2—C3	−60.0 (3)
C9—Fe1—C4—C5	−154.8 (3)	Fe1—C2—C3—C4	−59.9 (3)
C10—Fe1—C4—C3	130.1 (2)	C1—C2—C3—C4	0.5 (5)
C10—Fe1—C4—C5	−110.8 (3)	C1—C2—C3—Fe1	60.4 (3)
C1—Fe1—C5—C4	−119.2 (3)	Fe1—C3—C4—C5	−59.5 (3)
C2—Fe1—C5—C1	37.7 (2)	C2—C3—C4—Fe1	59.2 (3)
C2—Fe1—C5—C4	−81.5 (3)	C2—C3—C4—C5	−0.3 (5)
C3—Fe1—C5—C1	81.5 (2)	Fe1—C4—C5—C1	−58.7 (3)
C3—Fe1—C5—C4	−37.8 (2)	C3—C4—C5—Fe1	58.7 (3)
C4—Fe1—C5—C1	119.2 (3)	C3—C4—C5—C1	−0.1 (5)
C6—Fe1—C5—C1	−109.4 (2)	C10—C6—C7—C8	0.4 (4)
C6—Fe1—C5—C4	131.4 (2)	Fe1—C6—C10—C9	−59.1 (3)
C7—Fe1—C5—C1	−68.2 (3)	C10—C6—C7—Fe1	−59.0 (3)
C7—Fe1—C5—C4	172.6 (2)	C7—C6—C10—C9	−0.2 (4)
C9—Fe1—C5—C1	167.9 (3)	C7—C6—C10—Fe1	58.9 (3)
C9—Fe1—C5—C4	48.7 (4)	Fe1—C6—C7—C8	59.4 (3)
C10—Fe1—C5—C1	−153.4 (2)	Fe1—C7—C8—C9	59.4 (3)
C10—Fe1—C5—C4	87.4 (3)	C6—C7—C8—Fe1	−59.8 (3)
C1—Fe1—C6—C7	86.1 (3)	C6—C7—C8—C9	−0.4 (4)
C1—Fe1—C6—C10	−153.7 (2)	Fe1—C8—C9—C10	59.3 (2)
C2—Fe1—C6—C7	47.9 (4)	Fe1—C8—C9—C11	−117.9 (4)
C2—Fe1—C6—C10	168.1 (3)	C7—C8—C9—Fe1	−59.0 (3)
C4—Fe1—C6—C7	171.4 (2)	C7—C8—C9—C10	0.2 (4)
C4—Fe1—C6—C10	−68.4 (3)	C7—C8—C9—C11	−176.9 (3)
C5—Fe1—C6—C7	130.5 (2)	C8—C9—C10—C6	0.0 (4)
C5—Fe1—C6—C10	−109.3 (3)	C11—C9—C10—Fe1	118.3 (3)
C7—Fe1—C6—C10	120.2 (3)	C11—C9—C10—C6	177.3 (3)
C8—Fe1—C6—C7	−38.3 (2)	Fe1—C9—C11—C12	78.4 (4)
C8—Fe1—C6—C10	81.9 (2)	Fe1—C9—C11—C16	−101.3 (4)
C9—Fe1—C6—C7	−82.4 (2)	C8—C9—C11—C12	167.6 (4)
C9—Fe1—C6—C10	37.8 (2)	C8—C9—C11—C16	−12.1 (6)
C10—Fe1—C6—C7	−120.2 (3)	Fe1—C9—C10—C6	59.0 (3)
C1—Fe1—C7—C6	−111.7 (2)	C8—C9—C10—Fe1	−59.0 (3)
C1—Fe1—C7—C8	129.6 (2)	C10—C9—C11—C16	171.2 (4)
C2—Fe1—C7—C6	−155.2 (2)	C10—C9—C11—C12	−9.1 (6)
C2—Fe1—C7—C8	86.1 (2)	C9—C11—C12—C13	−177.7 (4)
C3—Fe1—C7—C6	170.1 (3)	C16—C11—C12—C13	2.0 (6)
C3—Fe1—C7—C8	51.4 (4)	C12—C11—C16—C15	−1.2 (5)
C5—Fe1—C7—C6	−71.8 (3)	C9—C11—C16—C15	178.4 (3)
C5—Fe1—C7—C8	169.5 (3)	C11—C12—C13—C14	−0.2 (6)
C6—Fe1—C7—C8	−118.7 (3)	C12—C13—C14—C17	178.5 (4)
C8—Fe1—C7—C6	118.7 (3)	C12—C13—C14—C15	−2.3 (6)
C9—Fe1—C7—C6	81.3 (2)	C17—C14—C15—C16	−177.8 (4)
C9—Fe1—C7—C8	−37.4 (2)	C13—C14—C17—C17^i	−0.8 (7)
C10—Fe1—C7—C6	37.2 (2)	C13—C14—C15—C16	3.0 (6)
C10—Fe1—C7—C8	−81.5 (2)	C15—C14—C17—C17^i	−180.0 (4)
C1—Fe1—C8—C7	−71.3 (3)	C14—C15—C16—C11	−1.3 (6)
C1—Fe1—C8—C9	168.9 (2)	C14—C17—C17^i—C14^i	180.0 (4)
C2—Fe1—C8—C7	−110.2 (2)

Symmetry code: (i) −x, −y, −z+1.