Bis[8-(4-pyridylsulfanylmethyl-κN)quinoline]silver(I) trifluoro­methane­sulfonate

Song, R.-F.; Wang, Y.-H.

doi:10.1107/S1600536806049786

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Bis[8-(4-pyridylsulfanylmethyl-κN)quinoline]silver(I) trifluoromethanesulfonate

R.-F. Song and Y.-H. Wang

The title mononuclear complex, [Ag(C₁₅H₁₂N₂S)₂]CF₃SO₃, reveals the molecular symmetry C₂ with the Ag atom located on a crystallographic twofold axis. The Ag^I centre is coordinated by two pyridine N-donors of two 8-(4-pyridylsulfanylmethyl)quinoline ligands in an almost linear geometry. The N—Ag—N angle is 173.06 (18)° and the Ag—N distance is 2.129 (3) Å.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806049786/kp2068sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536806049786/kp2068Isup2.hkl Contains datablock I

CCDC reference: 630045

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.007 Å
Disorder in solvent or counterion
R factor = 0.048
wR factor = 0.100
Data-to-parameter ratio = 14.3

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT062_ALERT_4_C Rescale T(min) & T(max) by .....................       0.83
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         S2
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        C16
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      33.00 Perc.
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          1
            N1  -AG1 -N1  -C1   -148.40  0.30   2.654   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          2
            N1  -AG1 -N1  -C5     33.30  0.30   2.654   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         93
            C16 -C16 -F2  -O2     40.00 18.00   2.656   1.555   1.555   2.656
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         98
            C16 -C16 -F2  -S2     42.00 18.00   2.656   1.555   1.555   2.656
PLAT764_ALERT_4_C Overcomplete CIF Bond List Detected (Rep/Expd) .       1.41 Ratio
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      27.20 Deg.
              C16  -S2   -C16     2.656   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      35.00 Deg.
              O2   -S2   -F2      1.555   1.555   2.656
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      42.30 Deg.
              C16  -S2   -F2      2.656   1.555   2.656
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      33.71 Deg.
              S2   -O1   -S2      2.656   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      44.00 Deg.
              F2   -O2   -C16     2.656   1.555   2.656
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      27.03 Deg.
              S2   -C16  -S2      2.656   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      36.70 Deg.
              F2   -C16  -O2      1.555   1.555   2.656
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      35.70 Deg.
              C16  -F1   -C16     2.656   1.555   1.555
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          1
              C30 H24 Ag N4 S2

Alert level G
ABSTM02_ALERT_3_G  When printed, the submitted absorption T values will be
            replaced by the scaled T values. Since the ratio of scaled T's
            is identical to the ratio of reported T values, the scaling
            does not imply a change to the absorption corrections used in
            the study.
            Ratio of Tmax expected/reported      0.833
            Tmax scaled      0.833 Tmin scaled      0.742
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  18 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

   2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   8 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
  10 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SMART; data reduction: SAINT (Bruker, 1999); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXL97.

Bis[8-(4-pyridylsulfanylmethyl-κN)quinoline]silver(I) trifluoromethanesulfonate top

Crystal data top

[Ag(C₁₅H₁₂N₂S)₂]CF₃SO₃	F(000) = 1536
M_r = 761.59	D_x = 1.637 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 907 reflections
a = 24.851 (8) Å	θ = 3.0–25.5°
b = 9.276 (3) Å	µ = 0.91 mm⁻¹
c = 14.091 (4) Å	T = 293 K
β = 107.991 (6)°	Block, colourless
V = 3089.4 (17) Å³	0.30 × 0.22 × 0.20 mm
Z = 4

Data collection top

Bruker SMART 1000 CCD area-detector diffractometer	3182 independent reflections
Radiation source: fine-focus sealed tube	1786 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.048
φ and ω scans	θ_max = 26.5°, θ_min = 2.4°
Absorption correction: multi-scan (SADABS; Sheldrick, 1998)	h = −30→26
T_min = 0.891, T_max = 1.000	k = −11→7
8559 measured reflections	l = −16→17

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.048	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.100	H-atom parameters constrained
S = 1.00	w = 1/[σ²(F_o²) + (0.035P)² + 2.1514P] where P = (F_o² + 2F_c²)/3
3182 reflections	(Δ/σ)_max < 0.001
222 parameters	Δρ_max = 0.56 e Å⁻³
0 restraints	Δρ_min = −0.39 e Å⁻³

Special details top

Experimental. IR (KBr pellet, cm^-1): 3065 w, 2932 w, 1593 versus, 1487 m, 1426 m, 1278 versus, 1259 versus, 1224 versus, 1151 s, 1113 m, 1023 versus, 840 m, 796 m, 636 s.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ag1	0.5000	−0.00800 (5)	−0.2500	0.0726 (2)
S1	0.35979 (5)	−0.04049 (12)	0.08243 (8)	0.0663 (3)
N1	0.45310 (13)	−0.0219 (4)	−0.1468 (2)	0.0551 (8)
N2	0.20630 (17)	0.0252 (4)	0.0195 (3)	0.0715 (10)
C1	0.41510 (17)	0.0795 (5)	−0.1457 (3)	0.0585 (11)
H1A	0.4086	0.1529	−0.1929	0.070*
C2	0.38546 (16)	0.0807 (4)	−0.0790 (3)	0.0571 (11)
H2A	0.3595	0.1539	−0.0811	0.068*
C3	0.39405 (15)	−0.0275 (4)	−0.0080 (3)	0.0487 (9)
C4	0.43270 (15)	−0.1341 (4)	−0.0098 (3)	0.0512 (10)
H4A	0.4396	−0.2095	0.0359	0.061*
C5	0.46052 (16)	−0.1275 (4)	−0.0793 (3)	0.0556 (10)
H5A	0.4861	−0.2006	−0.0798	0.067*
C6	0.31761 (17)	0.1229 (5)	0.0629 (3)	0.0733 (13)
H6A	0.3418	0.2065	0.0685	0.088*
H6B	0.2903	0.1223	−0.0033	0.088*
C7	0.28718 (17)	0.1306 (5)	0.1408 (3)	0.0613 (11)
C8	0.31022 (19)	0.1859 (5)	0.2314 (4)	0.0742 (13)
H8A	0.3473	0.2190	0.2480	0.089*
C9	0.2823 (2)	0.1975 (5)	0.3027 (3)	0.0819 (14)
H9A	0.3006	0.2371	0.3649	0.098*
C10	0.2278 (2)	0.1500 (5)	0.2803 (4)	0.0801 (14)
H10A	0.2088	0.1558	0.3275	0.096*
C11	0.20039 (17)	0.0916 (4)	0.1840 (3)	0.0565 (10)
C12	0.1444 (2)	0.0473 (5)	0.1533 (5)	0.0810 (14)
H12A	0.1231	0.0522	0.1972	0.097*
C13	0.1210 (2)	−0.0022 (5)	0.0612 (5)	0.0878 (15)
H13A	0.0831	−0.0287	0.0396	0.105*
C14	0.1529 (2)	−0.0138 (5)	−0.0011 (4)	0.0816 (14)
H14A	0.1356	−0.0527	−0.0640	0.098*
C15	0.23141 (17)	0.0811 (4)	0.1161 (3)	0.0558 (10)
S2	0.49905 (12)	0.3876 (2)	0.77845 (14)	0.0505 (6)	0.50
O1	0.44902 (13)	0.3240 (3)	0.7131 (2)	0.0830 (9)
O2	0.4932 (2)	0.4210 (9)	0.8720 (4)	0.0738 (18)	0.50
C16	0.4995 (9)	0.5602 (10)	0.7206 (9)	0.074 (4)	0.50
F1	0.54457 (13)	0.6370 (3)	0.7797 (3)	0.1253 (12)
F2	0.5039 (3)	0.5437 (8)	0.6298 (6)	0.111 (2)	0.50

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ag1	0.0963 (4)	0.0723 (4)	0.0678 (3)	0.000	0.0527 (3)	0.000
S1	0.0843 (8)	0.0629 (8)	0.0674 (7)	0.0147 (6)	0.0461 (6)	0.0205 (5)
N1	0.066 (2)	0.055 (2)	0.0513 (19)	−0.0117 (18)	0.0279 (17)	−0.0031 (17)
N2	0.087 (3)	0.066 (3)	0.068 (2)	0.011 (2)	0.032 (2)	0.004 (2)
C1	0.070 (3)	0.054 (3)	0.059 (3)	0.000 (2)	0.030 (2)	0.014 (2)
C2	0.064 (3)	0.051 (3)	0.063 (3)	0.006 (2)	0.030 (2)	0.015 (2)
C3	0.050 (2)	0.050 (3)	0.048 (2)	−0.008 (2)	0.0182 (18)	0.0045 (19)
C4	0.063 (3)	0.045 (2)	0.048 (2)	−0.003 (2)	0.021 (2)	0.0067 (19)
C5	0.063 (3)	0.050 (3)	0.058 (2)	0.003 (2)	0.025 (2)	0.002 (2)
C6	0.070 (3)	0.070 (3)	0.095 (3)	0.013 (2)	0.047 (3)	0.024 (3)
C7	0.058 (3)	0.054 (3)	0.077 (3)	0.011 (2)	0.028 (2)	0.016 (2)
C8	0.064 (3)	0.074 (3)	0.082 (3)	0.006 (3)	0.019 (3)	−0.002 (3)
C9	0.083 (4)	0.085 (4)	0.071 (3)	0.006 (3)	0.013 (3)	−0.018 (3)
C10	0.096 (4)	0.075 (3)	0.082 (3)	0.013 (3)	0.047 (3)	−0.004 (3)
C11	0.055 (3)	0.052 (3)	0.070 (3)	0.004 (2)	0.029 (2)	−0.001 (2)
C12	0.069 (3)	0.069 (3)	0.117 (4)	0.003 (3)	0.047 (3)	0.002 (3)
C13	0.066 (3)	0.077 (4)	0.119 (5)	−0.005 (3)	0.026 (3)	−0.008 (4)
C14	0.075 (3)	0.075 (4)	0.083 (3)	−0.009 (3)	0.006 (3)	−0.012 (3)
C15	0.054 (3)	0.046 (2)	0.073 (3)	0.009 (2)	0.027 (2)	0.011 (2)
S2	0.0631 (13)	0.0475 (11)	0.0454 (16)	−0.0017 (12)	0.0232 (15)	−0.0016 (9)
O1	0.101 (2)	0.075 (2)	0.076 (2)	−0.0427 (19)	0.0321 (18)	−0.0094 (17)
O2	0.066 (4)	0.114 (6)	0.046 (4)	0.013 (4)	0.023 (3)	−0.004 (4)
C16	0.057 (5)	0.066 (6)	0.100 (15)	0.010 (7)	0.024 (12)	0.016 (6)
F1	0.103 (2)	0.075 (2)	0.187 (3)	−0.0400 (19)	0.028 (2)	−0.011 (2)
F2	0.137 (6)	0.115 (6)	0.091 (5)	−0.010 (5)	0.050 (4)	0.048 (5)

Geometric parameters (Å, º) top

Ag1—N1ⁱ	2.129 (3)	C11—C12	1.386 (6)
Ag1—N1	2.129 (3)	C11—C15	1.405 (5)
S1—C3	1.742 (4)	C12—C13	1.329 (7)
S1—C6	1.814 (4)	C12—H12A	0.9300
N1—C1	1.336 (5)	C13—C14	1.357 (7)
N1—C5	1.338 (5)	C13—H13A	0.9300
N2—C14	1.317 (6)	C14—H14A	0.9300
N2—C15	1.410 (5)	S2—S2ⁱⁱ	0.818 (3)
C1—C2	1.361 (5)	S2—O1ⁱⁱ	1.390 (4)
C1—H1A	0.9300	S2—O2	1.405 (6)
C2—C3	1.387 (5)	S2—O1	1.427 (4)
C2—H2A	0.9300	S2—C16ⁱⁱ	1.602 (9)
C3—C4	1.385 (5)	S2—C16	1.799 (9)
C4—C5	1.364 (5)	S2—F2ⁱⁱ	1.958 (6)
C4—H4A	0.9300	O1—S2ⁱⁱ	1.390 (4)
C5—H5A	0.9300	O2—F2ⁱⁱ	1.141 (8)
C6—C7	1.514 (5)	O2—C16ⁱⁱ	1.883 (12)
C6—H6A	0.9700	C16—C16ⁱⁱ	0.82 (2)
C6—H6B	0.9700	C16—F1ⁱⁱ	1.306 (16)
C7—C8	1.330 (5)	C16—F2	1.326 (11)
C7—C15	1.398 (5)	C16—F1	1.371 (18)
C8—C9	1.390 (6)	C16—S2ⁱⁱ	1.602 (9)
C8—H8A	0.9300	C16—O2ⁱⁱ	1.883 (12)
C9—C10	1.365 (6)	F1—C16ⁱⁱ	1.306 (16)
C9—H9A	0.9300	F2—O2ⁱⁱ	1.141 (8)
C10—C11	1.425 (6)	F2—S2ⁱⁱ	1.958 (6)
C10—H10A	0.9300

N1ⁱ—Ag1—N1	173.06 (18)	C7—C15—N2	118.0 (4)
C3—S1—C6	102.79 (18)	C11—C15—N2	120.7 (4)
C1—N1—C5	116.7 (3)	S2ⁱⁱ—S2—O1ⁱⁱ	75.6 (3)
C1—N1—Ag1	120.2 (3)	S2ⁱⁱ—S2—O2	167.0 (4)
C5—N1—Ag1	123.1 (3)	O1ⁱⁱ—S2—O2	112.0 (3)
C14—N2—C15	115.4 (4)	S2ⁱⁱ—S2—O1	70.7 (3)
N1—C1—C2	123.3 (4)	O1ⁱⁱ—S2—O1	118.7 (3)
N1—C1—H1A	118.3	O2—S2—O1	112.0 (3)
C2—C1—H1A	118.3	S2ⁱⁱ—S2—C16ⁱⁱ	90.0 (4)
C1—C2—C3	119.8 (4)	O1ⁱⁱ—S2—C16ⁱⁱ	113.9 (8)
C1—C2—H2A	120.1	O2—S2—C16ⁱⁱ	77.3 (5)
C3—C2—H2A	120.1	O1—S2—C16ⁱⁱ	115.6 (8)
C4—C3—C2	117.2 (3)	S2ⁱⁱ—S2—C16	62.9 (3)
C4—C3—S1	117.6 (3)	O1ⁱⁱ—S2—C16	106.3 (6)
C2—C3—S1	125.3 (3)	O2—S2—C16	104.2 (5)
C5—C4—C3	119.3 (4)	O1—S2—C16	101.6 (6)
C5—C4—H4A	120.3	C16ⁱⁱ—S2—C16	27.2 (7)
C3—C4—H4A	120.3	S2ⁱⁱ—S2—F2ⁱⁱ	132.3 (3)
N1—C5—C4	123.7 (4)	O1ⁱⁱ—S2—F2ⁱⁱ	118.7 (3)
N1—C5—H5A	118.2	O2—S2—F2ⁱⁱ	35.0 (3)
C4—C5—H5A	118.2	O1—S2—F2ⁱⁱ	122.0 (3)
C7—C6—S1	108.9 (3)	C16ⁱⁱ—S2—F2ⁱⁱ	42.3 (4)
C7—C6—H6A	109.9	C16—S2—F2ⁱⁱ	69.4 (5)
S1—C6—H6A	109.9	S2ⁱⁱ—O1—S2	33.71 (15)
C7—C6—H6B	109.9	F2ⁱⁱ—O2—S2	100.0 (6)
S1—C6—H6B	109.9	F2ⁱⁱ—O2—C16ⁱⁱ	44.0 (5)
H6A—C6—H6B	108.3	S2—O2—C16ⁱⁱ	56.1 (4)
C8—C7—C15	117.7 (4)	C16ⁱⁱ—C16—F1ⁱⁱ	76 (2)
C8—C7—C6	123.4 (4)	C16ⁱⁱ—C16—F2	171 (3)
C15—C7—C6	118.9 (4)	F1ⁱⁱ—C16—F2	112.3 (12)
C7—C8—C9	124.1 (4)	C16ⁱⁱ—C16—F1	68 (2)
C7—C8—H8A	118.0	F1ⁱⁱ—C16—F1	104.2 (7)
C9—C8—H8A	118.0	F2—C16—F1	110.6 (12)
C10—C9—C8	119.3 (5)	C16ⁱⁱ—C16—S2ⁱⁱ	89.9 (4)
C10—C9—H9A	120.4	F1ⁱⁱ—C16—S2ⁱⁱ	124.2 (13)
C8—C9—H9A	120.4	F2—C16—S2ⁱⁱ	83.4 (6)
C9—C10—C11	119.4 (4)	F1—C16—S2ⁱⁱ	120.2 (12)
C9—C10—H10A	120.3	C16ⁱⁱ—C16—S2	62.9 (3)
C11—C10—H10A	120.3	F1ⁱⁱ—C16—S2	111.4 (9)
C12—C11—C15	118.5 (4)	F2—C16—S2	110.4 (7)
C12—C11—C10	123.3 (4)	F1—C16—S2	107.8 (9)
C15—C11—C10	118.2 (4)	S2ⁱⁱ—C16—S2	27.03 (19)
C13—C12—C11	120.0 (5)	C16ⁱⁱ—C16—O2ⁱⁱ	136.0 (7)
C13—C12—H12A	120.0	F1ⁱⁱ—C16—O2ⁱⁱ	129.2 (13)
C11—C12—H12A	120.0	F2—C16—O2ⁱⁱ	36.7 (4)
C12—C13—C14	119.6 (5)	F1—C16—O2ⁱⁱ	122.8 (12)
C12—C13—H13A	120.2	S2ⁱⁱ—C16—O2ⁱⁱ	46.7 (3)
C14—C13—H13A	120.2	S2—C16—O2ⁱⁱ	73.7 (4)
N2—C14—C13	125.8 (5)	C16ⁱⁱ—F1—C16	35.7 (8)
N2—C14—H14A	117.1	O2ⁱⁱ—F2—C16	99.3 (7)
C13—C14—H14A	117.1	O2ⁱⁱ—F2—S2ⁱⁱ	45.0 (4)
C7—C15—C11	121.2 (4)	C16—F2—S2ⁱⁱ	54.3 (5)

N1ⁱ—Ag1—N1—C1	−148.4 (3)	C16—S2—O2—C16ⁱⁱ	−3.6 (14)
N1ⁱ—Ag1—N1—C5	33.3 (3)	F2ⁱⁱ—S2—O2—C16ⁱⁱ	2.0 (9)
C5—N1—C1—C2	1.4 (6)	S2ⁱⁱ—S2—C16—C16ⁱⁱ	−175 (3)
Ag1—N1—C1—C2	−177.1 (3)	O1ⁱⁱ—S2—C16—C16ⁱⁱ	−111 (3)
N1—C1—C2—C3	−0.2 (6)	O2—S2—C16—C16ⁱⁱ	8 (3)
C1—C2—C3—C4	−0.8 (5)	O1—S2—C16—C16ⁱⁱ	124 (3)
C1—C2—C3—S1	179.7 (3)	F2ⁱⁱ—S2—C16—C16ⁱⁱ	4 (3)
C6—S1—C3—C4	176.6 (3)	S2ⁱⁱ—S2—C16—F1ⁱⁱ	124.2 (13)
C6—S1—C3—C2	−3.9 (4)	O1ⁱⁱ—S2—C16—F1ⁱⁱ	−172.0 (8)
C2—C3—C4—C5	0.7 (5)	O2—S2—C16—F1ⁱⁱ	−53.5 (11)
S1—C3—C4—C5	−179.8 (3)	O1—S2—C16—F1ⁱⁱ	63.1 (9)
C1—N1—C5—C4	−1.6 (5)	C16ⁱⁱ—S2—C16—F1ⁱⁱ	−61 (2)
Ag1—N1—C5—C4	176.8 (3)	F2ⁱⁱ—S2—C16—F1ⁱⁱ	−56.9 (7)
C3—C4—C5—N1	0.6 (6)	S2ⁱⁱ—S2—C16—F2	−1.3 (9)
C3—S1—C6—C7	−177.1 (3)	O1ⁱⁱ—S2—C16—F2	62.5 (13)
S1—C6—C7—C8	85.8 (5)	O2—S2—C16—F2	−178.9 (11)
S1—C6—C7—C15	−96.2 (4)	O1—S2—C16—F2	−62.3 (12)
C15—C7—C8—C9	0.0 (7)	C16ⁱⁱ—S2—C16—F2	173 (4)
C6—C7—C8—C9	178.1 (4)	F2ⁱⁱ—S2—C16—F2	177.6 (14)
C7—C8—C9—C10	−0.1 (7)	S2ⁱⁱ—S2—C16—F1	−122.2 (12)
C8—C9—C10—C11	−0.9 (7)	O1ⁱⁱ—S2—C16—F1	−58.3 (8)
C9—C10—C11—C12	−176.8 (4)	O2—S2—C16—F1	60.2 (9)
C9—C10—C11—C15	1.9 (6)	O1—S2—C16—F1	176.8 (7)
C15—C11—C12—C13	−0.7 (6)	C16ⁱⁱ—S2—C16—F1	52 (2)
C10—C11—C12—C13	177.9 (5)	F2ⁱⁱ—S2—C16—F1	56.8 (6)
C11—C12—C13—C14	2.3 (7)	O1ⁱⁱ—S2—C16—S2ⁱⁱ	63.8 (6)
C15—N2—C14—C13	1.2 (7)	O2—S2—C16—S2ⁱⁱ	−177.6 (7)
C12—C13—C14—N2	−2.7 (8)	O1—S2—C16—S2ⁱⁱ	−61.0 (6)
C8—C7—C15—C11	1.0 (6)	C16ⁱⁱ—S2—C16—S2ⁱⁱ	175 (3)
C6—C7—C15—C11	−177.2 (4)	F2ⁱⁱ—S2—C16—S2ⁱⁱ	178.9 (9)
C8—C7—C15—N2	178.6 (4)	S2ⁱⁱ—S2—C16—O2ⁱⁱ	−2.2 (4)
C6—C7—C15—N2	0.4 (5)	O1ⁱⁱ—S2—C16—O2ⁱⁱ	61.6 (6)
C12—C11—C15—C7	176.8 (4)	O2—S2—C16—O2ⁱⁱ	−179.8 (4)
C10—C11—C15—C7	−2.0 (6)	O1—S2—C16—O2ⁱⁱ	−63.2 (6)
C12—C11—C15—N2	−0.7 (6)	C16ⁱⁱ—S2—C16—O2ⁱⁱ	172 (3)
C10—C11—C15—N2	−179.5 (4)	F2ⁱⁱ—S2—C16—O2ⁱⁱ	176.7 (8)
C14—N2—C15—C7	−177.1 (4)	F1ⁱⁱ—C16—F1—C16ⁱⁱ	68.7 (17)
C14—N2—C15—C11	0.5 (6)	F2—C16—F1—C16ⁱⁱ	−170 (2)
O1ⁱⁱ—S2—O1—S2ⁱⁱ	−60.5 (3)	S2ⁱⁱ—C16—F1—C16ⁱⁱ	−76.1 (12)
O2—S2—O1—S2ⁱⁱ	166.4 (4)	S2—C16—F1—C16ⁱⁱ	−49.7 (11)
C16ⁱⁱ—S2—O1—S2ⁱⁱ	80.4 (5)	O2ⁱⁱ—C16—F1—C16ⁱⁱ	−131.4 (18)
C16—S2—O1—S2ⁱⁱ	55.6 (5)	C16ⁱⁱ—C16—F2—O2ⁱⁱ	40 (18)
F2ⁱⁱ—S2—O1—S2ⁱⁱ	128.5 (4)	F1ⁱⁱ—C16—F2—O2ⁱⁱ	−126.4 (10)
S2ⁱⁱ—S2—O2—F2ⁱⁱ	−15 (3)	F1—C16—F2—O2ⁱⁱ	117.7 (9)
O1ⁱⁱ—S2—O2—F2ⁱⁱ	109.0 (6)	S2ⁱⁱ—C16—F2—O2ⁱⁱ	−2.1 (9)
O1—S2—O2—F2ⁱⁱ	−114.7 (6)	S2—C16—F2—O2ⁱⁱ	−1.5 (13)
C16ⁱⁱ—S2—O2—F2ⁱⁱ	−2.0 (9)	C16ⁱⁱ—C16—F2—S2ⁱⁱ	42 (18)
C16—S2—O2—F2ⁱⁱ	−5.6 (9)	F1ⁱⁱ—C16—F2—S2ⁱⁱ	−124.3 (15)
S2ⁱⁱ—S2—O2—C16ⁱⁱ	−13 (2)	F1—C16—F2—S2ⁱⁱ	119.8 (13)
O1ⁱⁱ—S2—O2—C16ⁱⁱ	110.9 (8)	S2—C16—F2—S2ⁱⁱ	0.6 (4)
O1—S2—O2—C16ⁱⁱ	−112.7 (8)	O2ⁱⁱ—C16—F2—S2ⁱⁱ	2.1 (9)

Symmetry codes: (i) −x+1, y, −z−1/2; (ii) −x+1, y, −z+3/2.

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