Structural complexity in minerals: twinning, polytypism and disorder in the crystal structure of polybasite, (Ag,Cu)16(Sb,As)2S11

Evain, M.; Bindi, L.; Menchetti, S.

doi:10.1107/S010876810600975X

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Structural complexity in minerals: twinning, polytypism and disorder in the crystal structure of polybasite, (Ag,Cu)₁₆(Sb,As)₂S₁₁

M. Evain, L. Bindi and S. Menchetti

The crystal structures of 222- and 221-polybasite [(Ag,Cu)₁₆(Sb,As)₂S₁₁] crystals have been solved and refined by means of X-ray diffraction data (collected at 100 and 120 K, respectively) from twinned crystals. Both structures consist of the stacking of [(Ag,Cu)₆Sb₂S₇]²⁻ and [Ag₉CuS₄]²⁺ module layers in which Sb forms isolated SbS₃ pyramids typically occurring in sulfosalts; copper links two S atoms in a linear coordination and silver occupies sites with coordination ranging from quasi-linear to almost tetrahedral. An Ag → Cu substitution in the [(Ag,Cu)₆Sb₂S₇]²⁻ module layer is observed in both structures, the substitution amount being larger in the 221- than in the 222-polybasite. A pattern of the possible mechanism regulating the type of unit cell that is stabilized is proposed: starting from the hypothetical stoichiometric and fully ordered Ag₁₅CuSb₂S₁₁ 222-polybasite structure, with a low C2/c monoclinic symmetry and a large 222 supercell, the disorder introduced by the substitution of Cu for Ag increases the symmetry with a cell reduction along the c axis yielding the 221 supercell and a trigonal crystal system. A further increase of the substitution gives rise to a folding of the cell along the a and b axes and the 111-pearceite structure, space group $P\bar3m1$ .

Keywords: polybasite; crystal X-ray structure determination; twin; polytype; disorder.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S010876810600975X/lc5045sup1.cif Contains datablocks global, polybasite221, polybasite222
	Structure factor file (CIF format) https://doi.org/10.1107/S010876810600975X/lc5045polybasite221sup2.hkl Contains datablock polybasite221
	Structure factor file (CIF format) https://doi.org/10.1107/S010876810600975X/lc5045polybasite222sup3.hkl Contains datablock polybasite222

Computing details top

For both compounds, program(s) used to refine structure: (Jana2000; Petricek and Dusek, 2000); software used to prepare material for publication: (Jana2000; Petricek and Dusek, 2000).

Figures top

(polybasite221) top

Crystal data top

Ag_14.52Cu_1.48S₁₁Sb₂	D_x = 6.390 Mg m⁻³
M_r = 2256.5	Mo Kα radiation, λ = 0.71069 Å
Trigonal, P321	Cell parameters from 162 reflections
Hall symbol: P 3;2"	θ = 6.4–35°
a = 15.0954 (12) Å	µ = 16.32 mm⁻¹
c = 11.8825 (8) Å	T = 120 K
V = 2344.9 (3) Å³	Block, black
Z = 4	0.14 × 0.08 × 0.06 mm
F(000) = 4013

Data collection top

Nonius CCD diffractometer	R_int = 0.063
ω, ϕ scans	θ_max = 35.0°, θ_min = 6.4°
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	h = −24→24
T_min = 0.196, T_max = 0.417	k = −24→24
6847 independent reflections	l = −19→19
6224 reflections with I > 2σ(I)

Refinement top

Refinement on F	Weighting scheme based on measured s.u.'s w = 1/(σ²(F) + 0.000484F²)
R[F² > 2σ(F²)] = 0.036	(Δ/σ)_max = 0.001
wR(F²) = 0.046	Δρ_max = 1.05 e Å⁻³
S = 1.41	Δρ_min = −0.81 e Å⁻³
6847 reflections	Extinction correction: B-C type 1 Lorentzian isotropic (Becker & Coppens, 1974)
224 parameters	Extinction coefficient: 0.108 (16)

Crystal data top

Ag_14.52Cu_1.48S₁₁Sb₂	Z = 4
M_r = 2256.5	Mo Kα radiation
Trigonal, P321	µ = 16.32 mm⁻¹
a = 15.0954 (12) Å	T = 120 K
c = 11.8825 (8) Å	0.14 × 0.08 × 0.06 mm
V = 2344.9 (3) Å³

Data collection top

Nonius CCD diffractometer	6847 independent reflections
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	6224 reflections with I > 2σ(I)
T_min = 0.196, T_max = 0.417	R_int = 0.063

Refinement top

R[F² > 2σ(F²)] = 0.036	224 parameters
wR(F²) = 0.046	Δρ_max = 1.05 e Å⁻³
S = 1.41	Δρ_min = −0.81 e Å⁻³
6847 reflections

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Sb1	0.333333	0.666667	0.08748 (6)	0.01292 (16)
Sb2	0.33285 (3)	0.15587 (3)	0.08778 (3)	0.01123 (13)
Ag1	0.36661 (4)	0.42990 (4)	0.10137 (5)	0.01845 (18)
Ag2	0.09007 (5)	0.42358 (5)	0.14418 (6)	0.0247 (3)	0.785 (10)
Ag2cu	0.090066	0.423581	0.144176	0.0247 (3)	0.215 (10)
Ag3	0.07708 (13)	0.14671 (14)	0.12156 (13)	0.0403 (4)	0.895 (11)
Ag3cu	0.077083	0.146706	0.121558	0.0403 (4)	0.105 (11)
Ag4	0.56682 (5)	0.41741 (4)	0.11845 (5)	0.02131 (19)
Ag5	0.34923 (5)	0.55037 (5)	0.39194 (5)	0.0234 (2)
Ag6	0.27335 (11)	0.07446 (10)	0.39259 (10)	0.0244 (2)
Ag7	0.13137 (5)	0.17613 (4)	0.37640 (5)	0.0260 (2)
Ag8	0.52806 (15)	0.16567 (11)	0.37649 (11)	0.0393 (3)
Ag9	0.09891 (5)	0.41993 (4)	0.39861 (5)	0.0215 (2)
Ag10	0.37973 (15)	0.30736 (10)	0.36194 (11)	0.0400 (3)
Cu1	0	0.51322 (7)	0.5	0.0121 (3)
Cu2	0	0	0.5	0.0153 (5)
S1	0.26964 (13)	0.50882 (12)	0.19090 (13)	0.0137 (5)
S2	−0.00297 (12)	0.24192 (14)	0.20453 (13)	0.0166 (5)
S3	0.26011 (14)	0.24957 (14)	0.17635 (13)	0.0149 (6)
S4	0.48834 (13)	0.24179 (13)	0.19616 (14)	0.0150 (5)
S5	0.49297 (11)	0.50299 (11)	0.31858 (11)	0.0110 (5)
S6	0	0	0.3189 (2)	0.0101 (5)
S7	0.20146 (12)	0.34647 (12)	0.46132 (12)	0.0121 (5)
S8	0.333333	0.666667	0.5400 (2)	0.0102 (5)
S9	0.53714 (18)	0.53714 (18)	0	0.0335 (8)
S10	0.0323 (6)	0.0323 (6)	0	0.050 (3)	0.3333

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sb1	0.0137 (2)	0.0137 (2)	0.0113 (3)	0.00687 (10)	0	0
Sb2	0.01299 (19)	0.01127 (15)	0.01014 (14)	0.00659 (14)	0.00027 (12)	−0.00019 (11)
Ag1	0.0181 (2)	0.0194 (2)	0.0193 (2)	0.0105 (2)	0.00089 (16)	−0.00345 (18)
Ag2	0.0138 (3)	0.0230 (4)	0.0316 (3)	0.0048 (2)	−0.0045 (2)	−0.0058 (2)
Ag2cu	0.0138 (3)	0.0230 (4)	0.0316 (3)	0.0048 (2)	−0.0045 (2)	−0.0058 (2)
Ag3	0.0288 (4)	0.0515 (6)	0.0477 (5)	0.0255 (4)	0.0144 (3)	0.0267 (4)
Ag3cu	0.0288 (4)	0.0515 (6)	0.0477 (5)	0.0255 (4)	0.0144 (3)	0.0267 (4)
Ag4	0.0193 (3)	0.0160 (2)	0.0216 (2)	0.0035 (2)	0.00119 (19)	0.00045 (18)
Ag5	0.0232 (3)	0.0263 (3)	0.0216 (2)	0.0131 (2)	−0.00162 (19)	−0.0077 (2)
Ag6	0.0368 (3)	0.0220 (3)	0.0172 (2)	0.0168 (3)	−0.0034 (2)	−0.00234 (18)
Ag7	0.0350 (3)	0.0117 (2)	0.0220 (2)	0.0046 (2)	−0.0083 (2)	0.00048 (19)
Ag8	0.0769 (6)	0.0152 (3)	0.0165 (3)	0.0160 (3)	−0.0053 (3)	0.0005 (2)
Ag9	0.0273 (3)	0.0215 (3)	0.0245 (2)	0.0187 (2)	−0.0080 (2)	−0.00499 (19)
Ag10	0.0683 (6)	0.0127 (2)	0.0174 (2)	0.0040 (3)	−0.0015 (3)	0.00146 (19)
Cu1	0.0155 (5)	0.0136 (3)	0.0077 (4)	0.0078 (3)	−0.0011 (3)	−0.00057 (17)
Cu2	0.0185 (6)	0.0185 (6)	0.0088 (7)	0.0092 (3)	0	0
S1	0.0146 (7)	0.0115 (7)	0.0160 (6)	0.0073 (6)	−0.0001 (5)	−0.0009 (5)
S2	0.0110 (6)	0.0227 (8)	0.0160 (6)	0.0084 (6)	0.0006 (5)	0.0013 (6)
S3	0.0191 (8)	0.0170 (8)	0.0138 (6)	0.0130 (6)	0.0022 (5)	0.0018 (5)
S4	0.0111 (6)	0.0114 (6)	0.0218 (7)	0.0050 (5)	−0.0013 (5)	0.0008 (5)
S5	0.0135 (6)	0.0109 (6)	0.0086 (5)	0.0061 (5)	0.0007 (4)	0.0012 (4)
S6	0.0108 (6)	0.0108 (6)	0.0087 (9)	0.0054 (3)	0	0
S7	0.0162 (6)	0.0118 (6)	0.0102 (5)	0.0085 (5)	−0.0030 (4)	−0.0014 (5)
S8	0.0099 (6)	0.0099 (6)	0.0107 (9)	0.0050 (3)	0	0
S9	0.0265 (9)	0.0265 (9)	0.0219 (12)	−0.0058 (11)	−0.0102 (6)	0.0102 (6)
S10	0.039 (4)	0.039 (4)	0.027 (4)	−0.014 (4)	−0.020 (3)	0.020 (3)

Geometric parameters (Å, º) top

Sb1—S1	2.4127 (17)	Ag4—S4^vi	2.609 (2)
Sb1—S1ⁱ	2.4127 (16)	Ag4—S9	2.502 (3)
Sb1—S1ⁱⁱ	2.413 (3)	Ag5—Cu1ⁱ	2.9790 (14)
Sb2—S2ⁱⁱⁱ	2.4392 (15)	Ag5—S1	2.6058 (17)
Sb2—S3	2.422 (3)	Ag5—S5	2.744 (2)
Sb2—S4	2.4095 (16)	Ag5—S7	2.8747 (14)
Ag1—Ag1^iv	2.9227 (9)	Ag5—S8	2.5800 (18)
Ag1—S1	2.537 (2)	Ag6—S2ⁱⁱⁱ	2.425 (2)
Ag1—S3	2.5324 (18)	Ag6—S7^vii	2.4065 (18)
Ag1—S9	2.556 (2)	Ag7—Cu2	2.8083 (5)
Ag2—Ag2cu	0	Ag7—S3	2.9156 (17)
Ag2—S1	2.4133 (18)	Ag7—S6	2.4891 (8)
Ag2—S2	2.4810 (19)	Ag7—S7	2.4552 (17)
Ag2—S5ⁱⁱ	2.977 (2)	Ag8—Cu1^vii	2.8103 (18)
Ag2—S9ⁱⁱ	2.437 (3)	Ag8—S4	2.638 (3)
Ag2cu—S1	2.4133 (17)	Ag8—S5^viii	2.546 (3)
Ag2cu—S2	2.4810 (18)	Ag8—S8^vii	2.5442 (16)
Ag2cu—S5ⁱⁱ	2.977 (2)	Ag9—Cu1	2.7868 (11)
Ag2cu—S9ⁱⁱ	2.437 (3)	Ag9—S5ⁱⁱ	2.490 (3)
Ag3—Ag3cu	0	Ag9—S7	2.429 (2)
Ag3—S2	2.497 (3)	Ag10—Cu1ⁱ	2.8743 (15)
Ag3—S3	2.486 (2)	Ag10—S3	2.704 (2)
Ag3—S10	2.088 (6)	Ag10—S5	2.6192 (18)
Ag3—S10^v	2.462 (8)	Ag10—S7^vii	2.533 (2)
Ag3—S10ⁱⁱⁱ	2.756 (7)	Cu1—S5ⁱⁱ	2.1663 (13)
Ag3cu—S2	2.497 (2)	Cu1—S5^ix	2.1663 (13)
Ag3cu—S3	2.4855 (17)	Cu2—S6	2.152 (2)
Ag3cu—S10	2.088 (6)	Cu2—S6^vii	2.152 (2)
Ag3cu—S10^v	2.462 (8)	S10—S10^v	0.844 (11)
Ag3cu—S10ⁱⁱⁱ	2.756 (7)	S10—S10ⁱⁱⁱ	0.844 (11)
Ag4—S4	2.4786 (18)

S1—Sb1—S1ⁱ	96.37 (7)	Ag1—S3—Ag3cu	119.29 (9)
S1—Sb1—S1ⁱⁱ	96.37 (7)	Ag1—S3—Ag7	129.77 (9)
S1ⁱ—Sb1—S1	96.37 (7)	Ag1—S3—Ag10	88.71 (5)
S1ⁱ—Sb1—S1ⁱⁱ	96.37 (8)	Ag3—S3—Ag3cu	0
S1ⁱⁱ—Sb1—S1	96.37 (7)	Ag3—S3—Ag7	69.80 (6)
S1ⁱⁱ—Sb1—S1ⁱ	96.37 (8)	Ag3—S3—Ag10	140.33 (8)
S2ⁱⁱⁱ—Sb2—S3	96.56 (7)	Ag3cu—S3—Ag7	69.80 (4)
S2ⁱⁱⁱ—Sb2—S4	97.37 (7)	Ag3cu—S3—Ag10	140.33 (7)
S3—Sb2—S4	93.30 (7)	Ag7—S3—Ag10	70.63 (5)
Ag1^iv—Ag1—S1	149.18 (5)	Sb2—S4—Ag4	101.11 (7)
Ag1^iv—Ag1—S3	94.25 (5)	Sb2—S4—Ag4^viii	99.67 (6)
Ag1^iv—Ag1—S9	55.12 (5)	Sb2—S4—Ag8	124.89 (7)
S1—Ag1—S3	98.74 (6)	Ag4—S4—Ag4^viii	110.07 (6)
S1—Ag1—S9	122.35 (8)	Ag4—S4—Ag8	132.63 (7)
S3—Ag1—S9	138.06 (10)	Ag4^viii—S4—Ag4	110.07 (6)
Ag2cu—Ag2—S1	0	Ag4^viii—S4—Ag8	75.59 (8)
Ag2cu—Ag2—S2	0	Ag2ⁱ—S5—Ag2cuⁱ	0
Ag2cu—Ag2—S5ⁱⁱ	0	Ag2ⁱ—S5—Ag5	93.84 (6)
Ag2cu—Ag2—S9ⁱⁱ	0	Ag2ⁱ—S5—Ag8^vi	107.12 (6)
S1—Ag2—S2	112.77 (7)	Ag2ⁱ—S5—Ag9ⁱ	66.58 (4)
S1—Ag2—S5ⁱⁱ	101.51 (6)	Ag2ⁱ—S5—Ag10	147.00 (6)
S1—Ag2—S9ⁱⁱ	130.28 (7)	Ag2ⁱ—S5—Cu1ⁱ	139.71 (6)
S2—Ag2—S5ⁱⁱ	98.12 (6)	Ag2cuⁱ—S5—Ag5	93.84 (6)
S2—Ag2—S9ⁱⁱ	113.31 (7)	Ag2cuⁱ—S5—Ag8^vi	107.12 (6)
S5ⁱⁱ—Ag2—S9ⁱⁱ	89.57 (8)	Ag2cuⁱ—S5—Ag9ⁱ	66.58 (4)
Ag2—Ag2cu—S1	0	Ag2cuⁱ—S5—Ag10	147.00 (6)
Ag2—Ag2cu—S2	0	Ag2cuⁱ—S5—Cu1ⁱ	139.71 (6)
Ag2—Ag2cu—S5ⁱⁱ	0	Ag5—S5—Ag8^vi	145.55 (6)
Ag2—Ag2cu—S9ⁱⁱ	0	Ag5—S5—Ag9ⁱ	70.43 (5)
S1—Ag2cu—S2	112.77 (6)	Ag5—S5—Ag10	94.36 (7)
S1—Ag2cu—S5ⁱⁱ	101.51 (6)	Ag5—S5—Cu1ⁱ	73.64 (6)
S1—Ag2cu—S9ⁱⁱ	130.28 (7)	Ag8^vi—S5—Ag9ⁱ	92.82 (6)
S2—Ag2cu—S5ⁱⁱ	98.12 (5)	Ag8^vi—S5—Ag10	82.85 (8)
S2—Ag2cu—S9ⁱⁱ	113.31 (7)	Ag8^vi—S5—Cu1ⁱ	72.71 (7)
S5ⁱⁱ—Ag2cu—S9ⁱⁱ	89.57 (8)	Ag9ⁱ—S5—Ag10	145.76 (6)
Ag3cu—Ag3—S2	0	Ag9ⁱ—S5—Cu1ⁱ	73.16 (5)
Ag3cu—Ag3—S3	0	Ag10—S5—Cu1ⁱ	73.14 (5)
Ag3cu—Ag3—S10	0	Ag7—S6—Ag7^v	112.77 (5)
Ag3cu—Ag3—S10^v	0	Ag7—S6—Ag7ⁱⁱⁱ	112.77 (5)
Ag3cu—Ag3—S10ⁱⁱⁱ	0	Ag7—S6—Cu2	74.08 (5)
S2—Ag3—S3	104.11 (9)	Ag7^v—S6—Ag7	112.77 (5)
S2—Ag3—S10	134.4 (3)	Ag7^v—S6—Ag7ⁱⁱⁱ	112.77 (5)
S2—Ag3—S10^v	116.7 (3)	Ag7^v—S6—Cu2	74.08 (5)
S2—Ag3—S10ⁱⁱⁱ	133.0 (3)	Ag7ⁱⁱⁱ—S6—Ag7	112.77 (5)
S3—Ag3—S10	119.8 (3)	Ag7ⁱⁱⁱ—S6—Ag7^v	112.77 (5)
S3—Ag3—S10^v	138.7 (3)	Ag7ⁱⁱⁱ—S6—Cu2	74.08 (6)
S3—Ag3—S10ⁱⁱⁱ	122.8 (3)	Ag5—S7—Ag6^vii	135.37 (8)
S10—Ag3—S10^v	19.2 (3)	Ag5—S7—Ag7	134.50 (6)
S10—Ag3—S10ⁱⁱⁱ	12.33 (17)	Ag5—S7—Ag9	75.74 (5)
S10^v—Ag3—S10	19.2 (3)	Ag5—S7—Ag10^vii	87.16 (5)
S10^v—Ag3—S10ⁱⁱⁱ	17.5 (4)	Ag6^vii—S7—Ag7	89.36 (6)
S10ⁱⁱⁱ—Ag3—S10	12.33 (17)	Ag6^vii—S7—Ag9	83.53 (8)
S10ⁱⁱⁱ—Ag3—S10^v	17.5 (4)	Ag6^vii—S7—Ag10^vii	76.82 (6)
Ag3—Ag3cu—S2	0	Ag7—S7—Ag9	108.23 (6)
Ag3—Ag3cu—S3	0	Ag7—S7—Ag10^vii	116.56 (9)
Ag3—Ag3cu—S10	0	Ag9—S7—Ag10^vii	130.32 (9)
Ag3—Ag3cu—S10^v	0	Ag5—S8—Ag5ⁱ	78.60 (7)
Ag3—Ag3cu—S10ⁱⁱⁱ	0	Ag5—S8—Ag5ⁱⁱ	78.60 (7)
S2—Ag3cu—S3	104.11 (6)	Ag5—S8—Ag8^vii	95.68 (5)
S2—Ag3cu—S10	134.4 (3)	Ag5—S8—Ag8^xii	77.54 (5)
S2—Ag3cu—S10^v	116.7 (3)	Ag5—S8—Ag8^ix	156.13 (8)
S2—Ag3cu—S10ⁱⁱⁱ	133.0 (3)	Ag5ⁱ—S8—Ag5	78.60 (7)
S3—Ag3cu—S10	119.8 (3)	Ag5ⁱ—S8—Ag5ⁱⁱ	78.61 (6)
S3—Ag3cu—S10^v	138.7 (3)	Ag5ⁱ—S8—Ag8^vii	156.13 (8)
S3—Ag3cu—S10ⁱⁱⁱ	122.8 (3)	Ag5ⁱ—S8—Ag8^xii	95.68 (4)
S10—Ag3cu—S10^v	19.2 (3)	Ag5ⁱ—S8—Ag8^ix	77.54 (4)
S10—Ag3cu—S10ⁱⁱⁱ	12.33 (17)	Ag5ⁱⁱ—S8—Ag5	78.60 (7)
S10^v—Ag3cu—S10	19.2 (3)	Ag5ⁱⁱ—S8—Ag5ⁱ	78.61 (6)
S10^v—Ag3cu—S10ⁱⁱⁱ	17.5 (4)	Ag5ⁱⁱ—S8—Ag8^vii	77.54 (4)
S10ⁱⁱⁱ—Ag3cu—S10	12.33 (17)	Ag5ⁱⁱ—S8—Ag8^xii	156.13 (9)
S10ⁱⁱⁱ—Ag3cu—S10^v	17.5 (4)	Ag5ⁱⁱ—S8—Ag8^ix	95.68 (6)
S4—Ag4—S4^vi	105.05 (7)	Ag8^vii—S8—Ag8^xii	105.78 (8)
S4—Ag4—S9	145.08 (7)	Ag8^vii—S8—Ag8^ix	105.78 (9)
S4^vi—Ag4—S4	105.05 (7)	Ag8^xii—S8—Ag8^vii	105.78 (8)
S4^vi—Ag4—S9	109.86 (7)	Ag8^xii—S8—Ag8^ix	105.78 (10)
Cu1ⁱ—Ag5—S1	129.00 (6)	Ag8^ix—S8—Ag8^vii	105.78 (9)
Cu1ⁱ—Ag5—S5	44.25 (3)	Ag8^ix—S8—Ag8^xii	105.78 (10)
Cu1ⁱ—Ag5—S7	79.87 (5)	Ag1—S9—Ag1^iv	69.75 (5)
Cu1ⁱ—Ag5—S8	104.02 (4)	Ag1—S9—Ag2ⁱ	86.60 (6)
S1—Ag5—S5	88.60 (6)	Ag1—S9—Ag2^xiii	156.35 (9)
S1—Ag5—S7	89.29 (4)	Ag1—S9—Ag2cuⁱ	86.60 (6)
S1—Ag5—S8	126.90 (7)	Ag1—S9—Ag2cu^xiii	156.35 (9)
S5—Ag5—S7	95.93 (5)	Ag1—S9—Ag4	76.39 (5)
S5—Ag5—S8	138.47 (4)	Ag1—S9—Ag4^iv	77.85 (8)
S7—Ag5—S8	104.28 (5)	Ag1^iv—S9—Ag1	69.75 (5)
S2ⁱⁱⁱ—Ag6—S7^vii	158.12 (7)	Ag1^iv—S9—Ag2ⁱ	156.35 (9)
Cu2—Ag7—S3	143.83 (5)	Ag1^iv—S9—Ag2^xiii	86.60 (6)
Cu2—Ag7—S6	47.46 (5)	Ag1^iv—S9—Ag2cuⁱ	156.35 (9)
Cu2—Ag7—S7	120.47 (4)	Ag1^iv—S9—Ag2cu^xiii	86.60 (6)
S3—Ag7—S6	101.89 (6)	Ag1^iv—S9—Ag4	77.85 (8)
S3—Ag7—S7	94.62 (5)	Ag1^iv—S9—Ag4^iv	76.39 (5)
S6—Ag7—S7	158.03 (6)	Ag2ⁱ—S9—Ag2^xiii	117.05 (8)
Cu1^vii—Ag8—S4	151.33 (6)	Ag2ⁱ—S9—Ag2cuⁱ	0
Cu1^vii—Ag8—S5^viii	47.39 (5)	Ag2ⁱ—S9—Ag2cu^xiii	117.05 (8)
Cu1^vii—Ag8—S8^vii	109.97 (7)	Ag2ⁱ—S9—Ag4	97.10 (4)
S4—Ag8—S5^viii	105.70 (7)	Ag2ⁱ—S9—Ag4^iv	99.22 (12)
S4—Ag8—S8^vii	97.84 (7)	Ag2^xiii—S9—Ag2ⁱ	117.05 (8)
S5^viii—Ag8—S8^vii	140.63 (11)	Ag2^xiii—S9—Ag2cuⁱ	117.05 (8)
Cu1—Ag9—S5ⁱⁱ	48.07 (4)	Ag2^xiii—S9—Ag2cu^xiii	0
Cu1—Ag9—S7	136.30 (4)	Ag2^xiii—S9—Ag4	99.22 (12)
S5ⁱⁱ—Ag9—S7	173.36 (5)	Ag2^xiii—S9—Ag4^iv	97.10 (4)
Cu1ⁱ—Ag10—S3	137.70 (9)	Ag2cuⁱ—S9—Ag2cu^xiii	117.05 (8)
Cu1ⁱ—Ag10—S5	46.16 (4)	Ag2cuⁱ—S9—Ag4	97.10 (3)
Cu1ⁱ—Ag10—S7^vii	87.83 (5)	Ag2cuⁱ—S9—Ag4^iv	99.22 (12)
S3—Ag10—S5	99.06 (7)	Ag2cu^xiii—S9—Ag2cuⁱ	117.05 (8)
S3—Ag10—S7^vii	125.66 (7)	Ag2cu^xiii—S9—Ag4	99.22 (12)
S5—Ag10—S7^vii	133.35 (7)	Ag2cu^xiii—S9—Ag4^iv	97.10 (3)
Ag5ⁱⁱ—Cu1—Ag5^ix	158.40 (5)	Ag4—S9—Ag4^iv	148.46 (9)
Ag5ⁱⁱ—Cu1—Ag8^v	121.57 (3)	Ag4^iv—S9—Ag4	148.46 (9)
Ag5ⁱⁱ—Cu1—Ag8^vii	67.25 (3)	Ag3—S10—Ag3^v	85.5 (2)
Ag5ⁱⁱ—Cu1—Ag9	63.19 (2)	Ag3—S10—Ag3^iv	109.7 (3)
Ag5ⁱⁱ—Cu1—Ag9^x	137.80 (4)	Ag3—S10—Ag3ⁱⁱⁱ	93.49 (16)
Ag5ⁱⁱ—Cu1—Ag10ⁱⁱ	84.47 (5)	Ag3—S10—Ag3^xiv	101.1 (4)
Ag5ⁱⁱ—Cu1—Ag10^ix	79.31 (5)	Ag3—S10—Ag3^xv	164.7 (3)
Ag5ⁱⁱ—Cu1—S5ⁱⁱ	62.12 (5)	Ag3—S10—Ag3cu	0
Ag5ⁱⁱ—Cu1—S5^ix	119.79 (5)	Ag3—S10—Ag3cu^v	85.5 (2)
Ag5^ix—Cu1—Ag5ⁱⁱ	158.40 (5)	Ag3—S10—Ag3cu^iv	109.7 (3)
Ag5^ix—Cu1—Ag8^v	67.25 (4)	Ag3—S10—Ag3cuⁱⁱⁱ	93.49 (15)
Ag5^ix—Cu1—Ag8^vii	121.57 (3)	Ag3—S10—Ag3cu^xiv	101.1 (4)
Ag5^ix—Cu1—Ag9	137.80 (4)	Ag3—S10—Ag3cu^xv	164.7 (3)
Ag5^ix—Cu1—Ag9^x	63.19 (2)	Ag3—S10—S10^v	106.3 (9)
Ag5^ix—Cu1—Ag10ⁱⁱ	79.31 (5)	Ag3—S10—S10ⁱⁱⁱ	135.77 (19)
Ag5^ix—Cu1—Ag10^ix	84.47 (5)	Ag3^v—S10—Ag3	85.5 (2)
Ag5^ix—Cu1—S5ⁱⁱ	119.79 (6)	Ag3^v—S10—Ag3^iv	164.7 (3)
Ag5^ix—Cu1—S5^ix	62.12 (6)	Ag3^v—S10—Ag3ⁱⁱⁱ	78.91 (16)
Ag8^v—Cu1—Ag8^vii	137.15 (8)	Ag3^v—S10—Ag3^xiv	81.5 (3)
Ag8^v—Cu1—Ag9	81.34 (6)	Ag3^v—S10—Ag3^xv	79.44 (19)
Ag8^v—Cu1—Ag9^x	65.53 (5)	Ag3^v—S10—Ag3cu	85.5 (2)
Ag8^v—Cu1—Ag10ⁱⁱ	73.92 (6)	Ag3^v—S10—Ag3cu^v	0
Ag8^v—Cu1—Ag10^ix	145.74 (8)	Ag3^v—S10—Ag3cu^iv	164.7 (3)
Ag8^v—Cu1—S5ⁱⁱ	59.90 (5)	Ag3^v—S10—Ag3cuⁱⁱⁱ	78.91 (15)
Ag8^v—Cu1—S5^ix	116.40 (5)	Ag3^v—S10—Ag3cu^xiv	81.5 (3)
Ag8^vii—Cu1—Ag8^v	137.15 (8)	Ag3^v—S10—Ag3cu^xv	79.44 (18)
Ag8^vii—Cu1—Ag9	65.53 (4)	Ag3^v—S10—S10^v	31.90 (15)
Ag8^vii—Cu1—Ag9^x	81.34 (4)	Ag3^v—S10—S10ⁱⁱⁱ	61.1 (9)
Ag8^vii—Cu1—Ag10ⁱⁱ	145.74 (6)	Ag3^iv—S10—Ag3	109.7 (3)
Ag8^vii—Cu1—Ag10^ix	73.92 (7)	Ag3^iv—S10—Ag3^v	164.7 (3)
Ag8^vii—Cu1—S5ⁱⁱ	116.40 (7)	Ag3^iv—S10—Ag3ⁱⁱⁱ	101.1 (4)
Ag8^vii—Cu1—S5^ix	59.90 (7)	Ag3^iv—S10—Ag3^xiv	93.49 (16)
Ag9—Cu1—Ag9^x	78.72 (3)	Ag3^iv—S10—Ag3^xv	85.5 (2)
Ag9—Cu1—Ag10ⁱⁱ	119.19 (4)	Ag3^iv—S10—Ag3cu	109.7 (3)
Ag9—Cu1—Ag10^ix	132.50 (5)	Ag3^iv—S10—Ag3cu^v	164.7 (3)
Ag9—Cu1—S5ⁱⁱ	58.76 (7)	Ag3^iv—S10—Ag3cu^iv	0
Ag9—Cu1—S5^ix	113.45 (7)	Ag3^iv—S10—Ag3cuⁱⁱⁱ	101.1 (4)
Ag9^x—Cu1—Ag9	78.72 (3)	Ag3^iv—S10—Ag3cu^xiv	93.49 (15)
Ag9^x—Cu1—Ag10ⁱⁱ	132.50 (4)	Ag3^iv—S10—Ag3cu^xv	85.5 (2)
Ag9^x—Cu1—Ag10^ix	119.19 (3)	Ag3^iv—S10—S10^v	135.77 (19)
Ag9^x—Cu1—S5ⁱⁱ	113.45 (5)	Ag3^iv—S10—S10ⁱⁱⁱ	106.3 (9)
Ag9^x—Cu1—S5^ix	58.76 (4)	Ag3ⁱⁱⁱ—S10—Ag3	93.49 (16)
Ag10ⁱⁱ—Cu1—Ag10^ix	82.43 (6)	Ag3ⁱⁱⁱ—S10—Ag3^v	78.91 (16)
Ag10ⁱⁱ—Cu1—S5ⁱⁱ	60.70 (8)	Ag3ⁱⁱⁱ—S10—Ag3^iv	101.1 (4)
Ag10ⁱⁱ—Cu1—S5^ix	127.35 (8)	Ag3ⁱⁱⁱ—S10—Ag3^xiv	154.5 (3)
Ag10^ix—Cu1—Ag10ⁱⁱ	82.43 (6)	Ag3ⁱⁱⁱ—S10—Ag3^xv	81.5 (3)
Ag10^ix—Cu1—S5ⁱⁱ	127.35 (6)	Ag3ⁱⁱⁱ—S10—Ag3cu	93.49 (15)
Ag10^ix—Cu1—S5^ix	60.70 (5)	Ag3ⁱⁱⁱ—S10—Ag3cu^v	78.91 (15)
S5ⁱⁱ—Cu1—S5^ix	171.05 (9)	Ag3ⁱⁱⁱ—S10—Ag3cu^iv	101.1 (4)
S5^ix—Cu1—S5ⁱⁱ	171.05 (9)	Ag3ⁱⁱⁱ—S10—Ag3cuⁱⁱⁱ	0
Ag7—Cu2—Ag7^v	95.15 (2)	Ag3ⁱⁱⁱ—S10—Ag3cu^xiv	154.5 (3)
Ag7—Cu2—Ag7^vii	68.524 (18)	Ag3ⁱⁱⁱ—S10—Ag3cu^xv	81.5 (3)
Ag7—Cu2—Ag7ⁱⁱⁱ	95.15 (2)	Ag3ⁱⁱⁱ—S10—S10^v	101.4 (9)
Ag7—Cu2—Ag7^x	107.16 (2)	Ag3ⁱⁱⁱ—S10—S10ⁱⁱⁱ	54.5 (8)
Ag7—Cu2—Ag7^xi	153.08 (3)	Ag3^xiv—S10—Ag3	101.1 (4)
Ag7—Cu2—S6	58.467 (12)	Ag3^xiv—S10—Ag3^v	81.5 (3)
Ag7—Cu2—S6^vii	121.533 (12)	Ag3^xiv—S10—Ag3^iv	93.49 (16)
Ag7^v—Cu2—Ag7	95.15 (2)	Ag3^xiv—S10—Ag3ⁱⁱⁱ	154.5 (3)
Ag7^v—Cu2—Ag7^vii	153.08 (3)	Ag3^xiv—S10—Ag3^xv	78.91 (16)
Ag7^v—Cu2—Ag7ⁱⁱⁱ	95.15 (3)	Ag3^xiv—S10—Ag3cu	101.1 (4)
Ag7^v—Cu2—Ag7^x	68.52 (2)	Ag3^xiv—S10—Ag3cu^v	81.5 (3)
Ag7^v—Cu2—Ag7^xi	107.16 (2)	Ag3^xiv—S10—Ag3cu^iv	93.49 (15)
Ag7^v—Cu2—S6	58.467 (13)	Ag3^xiv—S10—Ag3cuⁱⁱⁱ	154.5 (3)
Ag7^v—Cu2—S6^vii	121.533 (13)	Ag3^xiv—S10—Ag3cu^xiv	0
Ag7^vii—Cu2—Ag7	68.524 (18)	Ag3^xiv—S10—Ag3cu^xv	78.91 (15)
Ag7^vii—Cu2—Ag7^v	153.08 (3)	Ag3^xiv—S10—S10^v	54.5 (8)
Ag7^vii—Cu2—Ag7ⁱⁱⁱ	107.16 (2)	Ag3^xiv—S10—S10ⁱⁱⁱ	101.4 (9)
Ag7^vii—Cu2—Ag7^x	95.15 (2)	Ag3^xv—S10—Ag3	164.7 (3)
Ag7^vii—Cu2—Ag7^xi	95.15 (2)	Ag3^xv—S10—Ag3^v	79.44 (19)
Ag7^vii—Cu2—S6	121.533 (12)	Ag3^xv—S10—Ag3^iv	85.5 (2)
Ag7^vii—Cu2—S6^vii	58.467 (12)	Ag3^xv—S10—Ag3ⁱⁱⁱ	81.5 (3)
Ag7ⁱⁱⁱ—Cu2—Ag7	95.15 (2)	Ag3^xv—S10—Ag3^xiv	78.91 (16)
Ag7ⁱⁱⁱ—Cu2—Ag7^v	95.15 (3)	Ag3^xv—S10—Ag3cu	164.7 (3)
Ag7ⁱⁱⁱ—Cu2—Ag7^vii	107.16 (2)	Ag3^xv—S10—Ag3cu^v	79.44 (18)
Ag7ⁱⁱⁱ—Cu2—Ag7^x	153.08 (2)	Ag3^xv—S10—Ag3cu^iv	85.5 (2)
Ag7ⁱⁱⁱ—Cu2—Ag7^xi	68.52 (2)	Ag3^xv—S10—Ag3cuⁱⁱⁱ	81.5 (3)
Ag7ⁱⁱⁱ—Cu2—S6	58.467 (15)	Ag3^xv—S10—Ag3cu^xiv	78.91 (15)
Ag7ⁱⁱⁱ—Cu2—S6^vii	121.533 (15)	Ag3^xv—S10—Ag3cu^xv	0
Ag7^x—Cu2—Ag7	107.16 (2)	Ag3^xv—S10—S10^v	61.1 (9)
Ag7^x—Cu2—Ag7^v	68.52 (2)	Ag3^xv—S10—S10ⁱⁱⁱ	31.90 (15)
Ag7^x—Cu2—Ag7^vii	95.15 (2)	Ag3cu—S10—Ag3cu^v	85.5 (2)
Ag7^x—Cu2—Ag7ⁱⁱⁱ	153.08 (2)	Ag3cu—S10—Ag3cu^iv	109.7 (3)
Ag7^x—Cu2—Ag7^xi	95.15 (3)	Ag3cu—S10—Ag3cuⁱⁱⁱ	93.49 (14)
Ag7^x—Cu2—S6	121.533 (15)	Ag3cu—S10—Ag3cu^xiv	101.1 (4)
Ag7^x—Cu2—S6^vii	58.467 (15)	Ag3cu—S10—Ag3cu^xv	164.7 (3)
Ag7^xi—Cu2—Ag7	153.08 (3)	Ag3cu—S10—S10^v	106.3 (9)
Ag7^xi—Cu2—Ag7^v	107.16 (2)	Ag3cu—S10—S10ⁱⁱⁱ	135.77 (19)
Ag7^xi—Cu2—Ag7^vii	95.15 (2)	Ag3cu^v—S10—Ag3cu	85.5 (2)
Ag7^xi—Cu2—Ag7ⁱⁱⁱ	68.52 (2)	Ag3cu^v—S10—Ag3cu^iv	164.7 (3)
Ag7^xi—Cu2—Ag7^x	95.15 (3)	Ag3cu^v—S10—Ag3cuⁱⁱⁱ	78.91 (14)
Ag7^xi—Cu2—S6	121.533 (13)	Ag3cu^v—S10—Ag3cu^xiv	81.5 (3)
Ag7^xi—Cu2—S6^vii	58.467 (13)	Ag3cu^v—S10—Ag3cu^xv	79.44 (17)
S6—Cu2—S6^vii	180	Ag3cu^v—S10—S10^v	31.90 (15)
S6^vii—Cu2—S6	180	Ag3cu^v—S10—S10ⁱⁱⁱ	61.1 (9)
Sb1—S1—Ag1	102.21 (6)	Ag3cu^iv—S10—Ag3cu	109.7 (3)
Sb1—S1—Ag2	101.31 (8)	Ag3cu^iv—S10—Ag3cu^v	164.7 (3)
Sb1—S1—Ag2cu	101.31 (8)	Ag3cu^iv—S10—Ag3cuⁱⁱⁱ	101.1 (4)
Sb1—S1—Ag5	108.73 (6)	Ag3cu^iv—S10—Ag3cu^xiv	93.49 (14)
Ag1—S1—Ag2	114.28 (7)	Ag3cu^iv—S10—Ag3cu^xv	85.5 (2)
Ag1—S1—Ag2cu	114.28 (6)	Ag3cu^iv—S10—S10^v	135.77 (19)
Ag1—S1—Ag5	101.10 (8)	Ag3cu^iv—S10—S10ⁱⁱⁱ	106.3 (9)
Ag2—S1—Ag2cu	0	Ag3cuⁱⁱⁱ—S10—Ag3cu	93.49 (14)
Ag2—S1—Ag5	126.80 (7)	Ag3cuⁱⁱⁱ—S10—Ag3cu^v	78.91 (14)
Ag2cu—S1—Ag5	126.80 (7)	Ag3cuⁱⁱⁱ—S10—Ag3cu^iv	101.1 (4)
Sb2^v—S2—Ag2	100.30 (8)	Ag3cuⁱⁱⁱ—S10—Ag3cu^xiv	154.5 (3)
Sb2^v—S2—Ag2cu	100.30 (8)	Ag3cuⁱⁱⁱ—S10—Ag3cu^xv	81.5 (3)
Sb2^v—S2—Ag3	100.21 (7)	Ag3cuⁱⁱⁱ—S10—S10^v	101.4 (9)
Sb2^v—S2—Ag3cu	100.21 (6)	Ag3cuⁱⁱⁱ—S10—S10ⁱⁱⁱ	54.5 (8)
Sb2^v—S2—Ag6^v	102.21 (7)	Ag3cu^xiv—S10—Ag3cu	101.1 (4)
Ag2—S2—Ag2cu	0	Ag3cu^xiv—S10—Ag3cu^v	81.5 (3)
Ag2—S2—Ag3	110.65 (7)	Ag3cu^xiv—S10—Ag3cu^iv	93.49 (14)
Ag2—S2—Ag3cu	110.65 (6)	Ag3cu^xiv—S10—Ag3cuⁱⁱⁱ	154.5 (3)
Ag2—S2—Ag6^v	119.51 (10)	Ag3cu^xiv—S10—Ag3cu^xv	78.91 (14)
Ag2cu—S2—Ag3	110.65 (7)	Ag3cu^xiv—S10—S10^v	54.5 (8)
Ag2cu—S2—Ag3cu	110.65 (6)	Ag3cu^xiv—S10—S10ⁱⁱⁱ	101.4 (9)
Ag2cu—S2—Ag6^v	119.51 (9)	Ag3cu^xv—S10—Ag3cu	164.7 (3)
Ag3—S2—Ag3cu	0	Ag3cu^xv—S10—Ag3cu^v	79.44 (17)
Ag3—S2—Ag6^v	119.23 (11)	Ag3cu^xv—S10—Ag3cu^iv	85.5 (2)
Ag3cu—S2—Ag6^v	119.23 (10)	Ag3cu^xv—S10—Ag3cuⁱⁱⁱ	81.5 (3)
Sb2—S3—Ag1	104.20 (7)	Ag3cu^xv—S10—Ag3cu^xiv	78.91 (14)
Sb2—S3—Ag3	102.02 (8)	Ag3cu^xv—S10—S10^v	61.1 (9)
Sb2—S3—Ag3cu	102.02 (6)	Ag3cu^xv—S10—S10ⁱⁱⁱ	31.90 (15)
Sb2—S3—Ag7	122.88 (8)	S10^v—S10—S10ⁱⁱⁱ	60.0 (14)
Sb2—S3—Ag10	96.78 (9)	S10ⁱⁱⁱ—S10—S10^v	60.0 (14)
Ag1—S3—Ag3	119.29 (10)

Symmetry codes: (i) −y+1, x−y+1, z; (ii) −x+y, −x+1, z; (iii) −x+y, −x, z; (iv) y, x, −z; (v) −y, x−y, z; (vi) −x+y+1, −x+1, z; (vii) y, x, −z+1; (viii) −y+1, x−y, z; (ix) x−y, −y+1, −z+1; (x) −x, −x+y, −z+1; (xi) x−y, −y, −z+1; (xii) −x+1, −x+y+1, −z+1; (xiii) x−y+1, −y+1, −z; (xiv) −x, −x+y, −z; (xv) x−y, −y, −z.

(polybasite222) top

Crystal data top

Ag_14.814Cu_1.186S₁₁Sb₂	F(000) = 16139
M_r = 2269.5	D_x = 6.401 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -C 2yc	Cell parameters from 228 reflections
a = 26.188 (3) Å	θ = 6.4–36°
b = 15.1199 (18) Å	µ = 16.25 mm⁻¹
c = 23.784 (3) Å	T = 100 K
β = 90°	Block, black
V = 9418 (2) Å³	0.15 × 0.12 × 0.09 mm
Z = 16

Data collection top

Nonius CCD diffractometer	R_int = 0.073
ω, ϕ scans	θ_max = 36.0°, θ_min = 6.5°
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	h = −43→39
T_min = 0.186, T_max = 0.268	k = −25→24
43813 independent reflections	l = −38→39
38767 reflections with I > 2σ(I)

Refinement top

Refinement on F	Weighting scheme based on measured s.u.'s w = 1/(σ²(F) + 0.000484F²)
R[F² > 2σ(F²)] = 0.050	(Δ/σ)_max = 0.002
wR(F²) = 0.057	Δρ_max = 1.15 e Å⁻³
S = 1.48	Δρ_min = −1.10 e Å⁻³
43813 reflections	Extinction correction: B-C type 1 Gaussian isotropic (Becker & Coppens, 1974)
592 parameters	Extinction coefficient: 0.058449

Crystal data top

Ag_14.814Cu_1.186S₁₁Sb₂	V = 9418 (2) Å³
M_r = 2269.5	Z = 16
Monoclinic, C2/c	Mo Kα radiation
a = 26.188 (3) Å	µ = 16.25 mm⁻¹
b = 15.1199 (18) Å	T = 100 K
c = 23.784 (3) Å	0.15 × 0.12 × 0.09 mm
β = 90°

Data collection top

Nonius CCD diffractometer	43813 independent reflections
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	38767 reflections with I > 2σ(I)
T_min = 0.186, T_max = 0.268	R_int = 0.073

Refinement top

R[F² > 2σ(F²)] = 0.050	592 parameters
wR(F²) = 0.057	Δρ_max = 1.15 e Å⁻³
S = 1.48	Δρ_min = −1.10 e Å⁻³
43813 reflections

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Sb1	0.16691 (2)	0.24468 (4)	0.043172 (19)	0.00956 (11)
Sb2	0.16495 (2)	0.75956 (3)	0.04531 (2)	0.00994 (11)
Sb3	0.42279 (2)	−0.00463 (3)	0.04458 (2)	0.00930 (11)
Sb4	0.41010 (2)	0.50144 (3)	0.04556 (2)	0.00909 (11)
Ag1	0.03265 (3)	0.15019 (4)	0.05067 (3)	0.01525 (15)
Ag2	0.04411 (3)	0.35807 (5)	0.06687 (3)	0.02130 (18)
Ag3	0.04367 (7)	0.62582 (12)	0.07179 (7)	0.0183 (2)	0.629 (10)
Ag3cu	0.043671	0.625823	0.071791	0.0183 (2)	0.371 (10)
Ag4	0.02949 (3)	0.86029 (5)	0.05571 (3)	0.01601 (15)
Ag5	0.16341 (3)	0.00236 (4)	0.07795 (3)	0.01789 (15)
Ag6	0.18568 (3)	0.50214 (4)	0.04781 (3)	0.01345 (14)
Ag7	0.28893 (3)	0.10133 (4)	0.05286 (3)	0.01352 (14)
Ag8	0.28366 (3)	0.37619 (4)	0.06492 (3)	0.01808 (16)
Ag9	0.28776 (6)	0.62742 (10)	0.06453 (6)	0.02113 (18)
Ag10	0.28782 (3)	0.90120 (4)	0.05781 (3)	0.01542 (15)
Ag11	0.43191 (3)	0.25277 (4)	0.05661 (3)	0.01649 (16)
Ag12	0.41473 (8)	0.74569 (10)	0.06274 (7)	0.0292 (3)
Ag13	0.16136 (2)	0.00334 (5)	0.20404 (3)	0.01731 (15)
Ag14	0.34606 (6)	0.02735 (14)	0.17942 (7)	0.0278 (2)
Ag15	0.46076 (3)	0.00332 (5)	0.19763 (3)	0.01657 (15)
Ag16	0.09979 (3)	0.19379 (5)	0.19995 (3)	0.01964 (17)
Ag17	0.22299 (3)	0.17223 (4)	0.19582 (3)	0.01814 (16)
Ag18	0.41209 (3)	0.20694 (5)	0.18710 (3)	0.01792 (16)
Ag19	0.05294 (3)	0.37623 (4)	0.19771 (3)	0.01483 (14)
Ag20	0.17400 (3)	0.37194 (5)	0.19025 (3)	0.01810 (16)
Ag21	0.29031 (3)	0.36252 (4)	0.19557 (3)	0.01846 (16)
Ag22	0.40081 (3)	0.42196 (5)	0.19368 (3)	0.01853 (16)
Ag23	0.06107 (3)	0.63423 (4)	0.19347 (3)	0.01860 (16)
Ag24	0.18582 (7)	0.63050 (10)	0.18493 (6)	0.02220 (18)
Ag25	0.30915 (3)	0.60887 (5)	0.18989 (3)	0.02353 (19)
Ag26	0.46596 (4)	0.59302 (5)	0.18331 (3)	0.0265 (2)
Ag27	0.01979 (3)	0.90541 (4)	0.18484 (3)	0.02073 (17)
Ag28	0.13309 (7)	0.80839 (10)	0.19781 (6)	0.02180 (19)
Ag29	0.25624 (6)	0.84547 (6)	0.19081 (4)	0.0504 (4)
Ag30	0.41597 (3)	0.80262 (5)	0.18696 (3)	0.02007 (17)
Cu1	0	0.23886 (9)	0.25	0.0097 (3)
Cu2	0	0.75503 (10)	0.25	0.0127 (3)
Cu3	0.24135 (4)	0.50395 (7)	0.24890 (4)	0.0107 (2)
S1	0.11844 (8)	0.14076 (13)	0.09828 (8)	0.0124 (4)
S2	0.13520 (8)	0.37545 (13)	0.08965 (8)	0.0117 (4)
S3	0.24561 (8)	0.23559 (12)	0.09666 (8)	0.0096 (4)
S4	0.13478 (8)	0.62719 (13)	0.09082 (8)	0.0125 (5)
S5	0.11857 (8)	0.86442 (13)	0.10367 (9)	0.0135 (5)
S6	0.24456 (8)	0.76115 (13)	0.09706 (9)	0.0123 (5)
S7	0.49861 (8)	−0.00273 (13)	0.10515 (8)	0.0128 (4)
S8	0.37890 (8)	0.11781 (13)	0.08808 (8)	0.0102 (4)
S9	0.37867 (8)	0.37455 (13)	0.09860 (8)	0.0113 (4)
S10	0.49477 (7)	0.50546 (12)	0.08729 (8)	0.0099 (4)
S11	0.37878 (8)	0.61442 (13)	0.10859 (9)	0.0133 (5)
S12	0.37553 (8)	0.88766 (13)	0.09824 (9)	0.0127 (5)
S13	0.22726 (8)	−0.00277 (16)	0.00135 (9)	0.0155 (5)
S14	0.48778 (12)	0.77813 (18)	−0.00040 (10)	0.0278 (7)
S15	0.07259 (7)	0.01881 (13)	0.23137 (8)	0.0097 (4)
S16	0.24775 (8)	0.00902 (13)	0.16066 (8)	0.0097 (4)
S17	0.00440 (8)	0.24792 (13)	0.15961 (7)	0.0095 (4)
S18	0.32644 (7)	0.22384 (12)	0.22820 (7)	0.0090 (4)
S19	0.10304 (7)	0.50215 (12)	0.22999 (8)	0.0088 (4)
S20	0.24470 (7)	0.49395 (12)	0.15820 (7)	0.0088 (4)
S21	0.00012 (8)	0.74821 (13)	0.15950 (7)	0.0086 (4)
S22	0.33157 (7)	0.75747 (11)	0.23146 (6)	0.0070 (4)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sb1	0.0107 (2)	0.0090 (2)	0.00900 (17)	−0.00039 (17)	0.00115 (18)	0.00059 (16)
Sb2	0.0117 (2)	0.00890 (19)	0.00920 (18)	−0.00008 (16)	0.00150 (18)	0.00023 (15)
Sb3	0.01021 (19)	0.0092 (2)	0.00850 (19)	0.00040 (16)	0.00135 (15)	−0.00093 (16)
Sb4	0.01014 (19)	0.00880 (19)	0.00834 (18)	−0.00010 (16)	0.00106 (15)	−0.00067 (16)
Ag1	0.0145 (3)	0.0157 (3)	0.0156 (3)	−0.0025 (2)	−0.0003 (2)	0.0005 (2)
Ag2	0.0128 (3)	0.0251 (3)	0.0261 (3)	0.0018 (2)	0.0000 (2)	0.0072 (3)
Ag3	0.0155 (4)	0.0192 (4)	0.0201 (4)	−0.0052 (3)	0.0004 (3)	0.0038 (3)
Ag3cu	0.0155 (4)	0.0192 (4)	0.0201 (4)	−0.0052 (3)	0.0004 (3)	0.0038 (3)
Ag4	0.0137 (3)	0.0173 (3)	0.0170 (3)	0.0017 (2)	0.0003 (2)	0.0006 (2)
Ag5	0.0214 (3)	0.0120 (2)	0.0202 (3)	0.0008 (2)	0.0061 (2)	−0.0007 (2)
Ag6	0.0141 (2)	0.0140 (2)	0.0122 (2)	0.0004 (2)	0.00375 (19)	0.0001 (2)
Ag7	0.0133 (3)	0.0123 (2)	0.0149 (3)	0.00038 (19)	0.0027 (2)	−0.00264 (19)
Ag8	0.0170 (3)	0.0135 (3)	0.0237 (3)	−0.0031 (2)	0.0055 (2)	0.0001 (2)
Ag9	0.0226 (3)	0.0198 (3)	0.0209 (3)	0.0098 (3)	0.0012 (3)	−0.0030 (2)
Ag10	0.0144 (3)	0.0143 (3)	0.0175 (3)	−0.0001 (2)	0.0011 (2)	0.0032 (2)
Ag11	0.0183 (3)	0.0121 (3)	0.0191 (3)	−0.0023 (2)	−0.0008 (2)	0.0016 (2)
Ag12	0.0542 (6)	0.0129 (3)	0.0204 (3)	−0.0067 (3)	0.0004 (4)	0.0032 (2)
Ag13	0.0103 (2)	0.0233 (3)	0.0183 (3)	−0.0039 (2)	0.0046 (2)	−0.0056 (2)
Ag14	0.0102 (3)	0.0612 (6)	0.0119 (3)	−0.0024 (3)	−0.0004 (2)	0.0029 (3)
Ag15	0.0142 (2)	0.0236 (3)	0.0119 (2)	0.0034 (2)	0.00292 (19)	0.0011 (2)
Ag16	0.0208 (3)	0.0207 (3)	0.0174 (3)	0.0053 (2)	−0.0049 (2)	−0.0065 (2)
Ag17	0.0226 (3)	0.0187 (3)	0.0131 (2)	0.0005 (2)	0.0079 (2)	−0.0004 (2)
Ag18	0.0098 (2)	0.0293 (3)	0.0147 (3)	−0.0016 (2)	0.0009 (2)	0.0046 (2)
Ag19	0.0185 (3)	0.0090 (2)	0.0170 (3)	−0.00400 (19)	−0.0035 (2)	0.0010 (2)
Ag20	0.0190 (3)	0.0192 (3)	0.0161 (3)	−0.0003 (2)	0.0042 (2)	0.0047 (2)
Ag21	0.0186 (3)	0.0140 (3)	0.0228 (3)	0.0071 (2)	0.0050 (2)	0.0052 (2)
Ag22	0.0195 (3)	0.0232 (3)	0.0129 (3)	−0.0053 (2)	0.0028 (2)	−0.0033 (2)
Ag23	0.0239 (3)	0.0135 (3)	0.0184 (3)	0.0080 (2)	−0.0062 (2)	−0.0031 (2)
Ag24	0.0319 (4)	0.0202 (3)	0.0145 (3)	0.0156 (3)	−0.0016 (3)	−0.0033 (2)
Ag25	0.0374 (4)	0.0211 (3)	0.0121 (3)	−0.0170 (3)	0.0048 (3)	−0.0019 (2)
Ag26	0.0467 (5)	0.0204 (3)	0.0125 (3)	−0.0202 (3)	−0.0029 (3)	0.0038 (2)
Ag27	0.0315 (4)	0.0144 (3)	0.0163 (3)	−0.0115 (2)	0.0074 (3)	−0.0036 (2)
Ag28	0.0377 (4)	0.0153 (3)	0.0124 (3)	0.0037 (3)	−0.0027 (3)	0.0013 (2)
Ag29	0.1043 (10)	0.0296 (4)	0.0174 (3)	0.0423 (5)	−0.0133 (5)	−0.0080 (3)
Ag30	0.0112 (3)	0.0371 (4)	0.0119 (3)	0.0036 (2)	0.0000 (2)	0.0022 (2)
Cu1	0.0121 (5)	0.0108 (6)	0.0063 (5)	0	0.0023 (5)	0
Cu2	0.0159 (6)	0.0147 (6)	0.0075 (5)	0	0.0017 (5)	0
Cu3	0.0126 (4)	0.0125 (4)	0.0070 (3)	0.0019 (3)	0.0012 (3)	0.0015 (3)
S1	0.0121 (8)	0.0121 (8)	0.0130 (8)	−0.0022 (6)	−0.0003 (6)	0.0010 (6)
S2	0.0123 (8)	0.0078 (7)	0.0149 (8)	0.0001 (6)	0.0019 (6)	0.0006 (6)
S3	0.0095 (7)	0.0097 (7)	0.0095 (7)	−0.0004 (6)	0.0009 (6)	0.0013 (6)
S4	0.0176 (9)	0.0083 (7)	0.0115 (7)	0.0006 (6)	0.0021 (7)	−0.0002 (6)
S5	0.0123 (8)	0.0132 (8)	0.0151 (8)	0.0035 (6)	−0.0014 (7)	−0.0002 (6)
S6	0.0096 (8)	0.0118 (7)	0.0155 (9)	0.0003 (6)	−0.0015 (6)	−0.0029 (6)
S7	0.0078 (7)	0.0185 (8)	0.0122 (7)	0.0013 (6)	0.0009 (6)	−0.0023 (6)
S8	0.0129 (8)	0.0086 (7)	0.0092 (7)	0.0009 (6)	0.0015 (6)	0.0002 (6)
S9	0.0132 (8)	0.0104 (7)	0.0101 (7)	−0.0032 (6)	−0.0013 (6)	−0.0010 (6)
S10	0.0071 (7)	0.0096 (7)	0.0129 (7)	−0.0002 (6)	0.0009 (6)	0.0031 (6)
S11	0.0146 (8)	0.0100 (7)	0.0154 (8)	0.0019 (6)	0.0018 (7)	−0.0016 (6)
S12	0.0145 (8)	0.0103 (7)	0.0134 (8)	−0.0022 (6)	−0.0006 (7)	0.0032 (6)
S13	0.0127 (7)	0.0219 (9)	0.0120 (8)	−0.0009 (8)	−0.0004 (6)	0.0008 (7)
S14	0.0401 (15)	0.0262 (12)	0.0172 (10)	0.0170 (10)	−0.0002 (10)	−0.0101 (9)
S15	0.0082 (7)	0.0121 (7)	0.0088 (7)	−0.0017 (5)	0.0014 (6)	−0.0029 (6)
S16	0.0081 (7)	0.0132 (8)	0.0078 (7)	0.0005 (6)	0.0022 (6)	−0.0013 (6)
S17	0.0118 (8)	0.0097 (7)	0.0070 (6)	−0.0022 (6)	0.0027 (6)	0.0010 (6)
S18	0.0089 (7)	0.0101 (7)	0.0080 (6)	0.0013 (6)	0.0005 (6)	0.0014 (5)
S19	0.0080 (7)	0.0091 (7)	0.0094 (7)	−0.0010 (6)	0.0005 (5)	0.0003 (6)
S20	0.0107 (7)	0.0090 (7)	0.0067 (6)	0.0021 (6)	0.0007 (6)	−0.0007 (6)
S21	0.0103 (7)	0.0089 (7)	0.0065 (6)	−0.0001 (6)	0.0007 (6)	−0.0005 (6)
S22	0.0079 (7)	0.0061 (6)	0.0070 (6)	−0.0031 (5)	0.0012 (6)	−0.0009 (5)

Geometric parameters (Å, º) top

Sb1—S1	2.408 (2)	Ag14—S19^viii	2.562 (2)
Sb1—S2	2.413 (2)	Ag15—S7	2.414 (2)
Sb1—S3	2.426 (2)	Ag15—S19^viii	2.3992 (19)
Sb2—S4	2.409 (2)	Ag16—Cu1	2.9514 (8)
Sb2—S5	2.432 (2)	Ag16—S1	2.594 (2)
Sb2—S6	2.421 (2)	Ag16—S15	2.840 (2)
Sb3—S7	2.453 (2)	Ag16—S17	2.798 (2)
Sb3—S8	2.412 (2)	Ag16—S22^viii	2.6115 (19)
Sb3—S12ⁱ	2.411 (2)	Ag17—S3	2.614 (2)
Sb4—S9	2.439 (2)	Ag17—S16	2.685 (2)
Sb4—S10	2.430 (2)	Ag17—S18	2.923 (2)
Sb4—S11	2.416 (2)	Ag17—S22^viii	2.5872 (18)
Ag1—S1	2.520 (2)	Ag18—Cu2^ix	2.8402 (8)
Ag1—S10ⁱⁱ	2.556 (2)	Ag18—S8	2.849 (2)
Ag1—S14ⁱⁱ	2.569 (3)	Ag18—S18	2.460 (2)
Ag2—S2	2.461 (2)	Ag18—S21^ix	2.477 (2)
Ag2—S7ⁱⁱⁱ	2.584 (2)	Ag19—Cu1	2.7899 (12)
Ag2—S14ⁱⁱ	2.489 (3)	Ag19—S17	2.490 (2)
Ag2—S17	2.953 (2)	Ag19—S19	2.4363 (19)
Ag3—Ag3cu	0	Ag20—S2	2.600 (2)
Ag3—Ag23	2.9324 (18)	Ag20—S19	2.8674 (19)
Ag3—S4	2.429 (3)	Ag20—S20	2.723 (2)
Ag3—S7ⁱⁱⁱ	2.408 (3)	Ag20—S22^viii	2.5463 (17)
Ag3—S14^iv	2.381 (3)	Ag21—Ag29^viii	2.9757 (12)
Ag3cu—Ag23	2.9324 (7)	Ag21—Cu3	2.7976 (12)
Ag3cu—S4	2.429 (2)	Ag21—S18	2.4277 (19)
Ag3cu—S7ⁱⁱⁱ	2.408 (2)	Ag21—S20	2.483 (2)
Ag3cu—S14^iv	2.381 (3)	Ag22—S9	2.442 (2)
Ag4—S5	2.598 (2)	Ag22—S15^x	2.410 (2)
Ag4—S10ⁱⁱⁱ	2.492 (2)	Ag23—Cu2	2.7752 (12)
Ag4—S14^iv	2.513 (3)	Ag23—S19	2.4395 (19)
Ag5—Ag13	2.9994 (10)	Ag23—S21	2.484 (2)
Ag5—S1	2.450 (2)	Ag24—Cu3	2.8444 (19)
Ag5—S5ⁱ	2.470 (2)	Ag24—S4	2.607 (3)
Ag5—S13	2.474 (2)	Ag24—S18^x	2.523 (2)
Ag5—S16	2.959 (2)	Ag24—S20	2.654 (3)
Ag6—Ag7^v	2.9364 (9)	Ag25—Cu3	2.7639 (13)
Ag6—Ag10^iv	2.9879 (9)	Ag25—S11	2.659 (2)
Ag6—S2	2.531 (2)	Ag25—S20	2.537 (2)
Ag6—S4	2.530 (2)	Ag25—S22	2.5240 (18)
Ag6—S13^v	2.562 (2)	Ag26—Cu1^xi	2.8588 (13)
Ag7—S3	2.548 (2)	Ag26—S10	2.745 (2)
Ag7—S8	2.513 (2)	Ag26—S11	2.911 (2)
Ag7—S13	2.566 (2)	Ag26—S15^x	2.529 (2)
Ag8—S3	2.466 (2)	Ag26—S17^xi	2.611 (2)
Ag8—S9	2.614 (2)	Ag27—Cu2	2.7999 (14)
Ag8—S13^v	2.496 (2)	Ag27—S10ⁱⁱⁱ	2.846 (2)
Ag9—S6	2.443 (3)	Ag27—S15^vi	2.465 (2)
Ag9—S11	2.611 (3)	Ag27—S21	2.506 (2)
Ag9—S13^v	2.482 (3)	Ag28—S5	2.424 (3)
Ag10—S6	2.577 (2)	Ag28—S18^x	2.420 (2)
Ag10—S12	2.499 (2)	Ag29—Cu3^x	2.7932 (14)
Ag10—S13^vi	2.535 (2)	Ag29—S6	2.587 (2)
Ag11—S8	2.579 (2)	Ag29—S16^vi	2.584 (2)
Ag11—S9	2.516 (2)	Ag29—S22	2.568 (2)
Ag11—S14^vii	2.536 (3)	Ag30—Cu1^xi	2.8319 (8)
Ag12—S11	2.453 (3)	Ag30—S12	2.688 (2)
Ag12—S12	2.525 (3)	Ag30—S17^xi	2.544 (2)
Ag12—S14	2.481 (3)	Ag30—S22	2.544 (2)
Ag13—Cu3^viii	2.7829 (12)	Cu1—S17	2.1572 (17)
Ag13—S15	2.425 (2)	Cu1—S17^xii	2.1572 (17)
Ag13—S16	2.488 (2)	Cu2—S21	2.1549 (16)
Ag14—Cu3^viii	2.8760 (19)	Cu2—S21^xii	2.1549 (16)
Ag14—S8	2.707 (3)	Cu3—S16^x	2.171 (2)
Ag14—S12ⁱ	2.964 (3)	Cu3—S20	2.164 (2)
Ag14—S16	2.628 (3)

S1—Sb1—S2	95.96 (7)	Ag23—Cu2—S21^xii	116.95 (7)
S1—Sb1—S3	97.20 (7)	Ag23^xii—Cu2—Ag23	97.68 (5)
S2—Sb1—S3	95.66 (7)	Ag23^xii—Cu2—Ag27	155.40 (3)
S4—Sb2—S5	96.97 (7)	Ag23^xii—Cu2—Ag27^xii	99.18 (2)
S4—Sb2—S6	93.57 (7)	Ag23^xii—Cu2—S21	116.95 (7)
S5—Sb2—S6	97.67 (7)	Ag23^xii—Cu2—S21^xii	58.91 (6)
S7—Sb3—S8	97.18 (7)	Ag27—Cu2—Ag27^xii	71.41 (4)
S7—Sb3—S12ⁱ	96.46 (7)	Ag27—Cu2—S21	59.05 (6)
S8—Sb3—S12ⁱ	92.68 (7)	Ag27—Cu2—S21^xii	126.30 (8)
S9—Sb4—S10	96.68 (7)	Ag27^xii—Cu2—Ag27	71.41 (4)
S9—Sb4—S11	96.93 (7)	Ag27^xii—Cu2—S21	126.30 (8)
S10—Sb4—S11	92.21 (7)	Ag27^xii—Cu2—S21^xii	59.05 (6)
S1—Ag1—S10ⁱⁱ	98.31 (7)	S21—Cu2—S21^xii	174.51 (11)
S1—Ag1—S14ⁱⁱ	131.52 (8)	S21^xii—Cu2—S21	174.51 (11)
S10ⁱⁱ—Ag1—S14ⁱⁱ	128.93 (8)	Ag13^x—Cu3—Ag14^x	119.38 (5)
S2—Ag2—S7ⁱⁱⁱ	106.41 (7)	Ag13^x—Cu3—Ag21	76.12 (3)
S2—Ag2—S14ⁱⁱ	140.17 (9)	Ag13^x—Cu3—Ag24	133.27 (5)
S2—Ag2—S17	103.71 (7)	Ag13^x—Cu3—Ag25	67.54 (3)
S7ⁱⁱⁱ—Ag2—S14ⁱⁱ	110.41 (8)	Ag13^x—Cu3—Ag29^viii	76.70 (4)
S7ⁱⁱⁱ—Ag2—S17	91.94 (6)	Ag13^x—Cu3—S16^x	58.75 (6)
S14ⁱⁱ—Ag2—S17	89.86 (7)	Ag13^x—Cu3—S20	111.31 (7)
Ag3cu—Ag3—Ag23	0	Ag14^x—Cu3—Ag21	136.69 (6)
Ag3cu—Ag3—S4	0	Ag14^x—Cu3—Ag24	80.07 (6)
Ag3cu—Ag3—S7ⁱⁱⁱ	0	Ag14^x—Cu3—Ag25	137.88 (6)
Ag3cu—Ag3—S14^iv	0	Ag14^x—Cu3—Ag29^viii	79.58 (5)
Ag23—Ag3—S4	70.31 (6)	Ag14^x—Cu3—S16^x	60.86 (7)
Ag23—Ag3—S7ⁱⁱⁱ	77.65 (7)	Ag14^x—Cu3—S20	129.18 (7)
Ag23—Ag3—S14^iv	136.97 (10)	Ag21—Cu3—Ag24	120.40 (5)
S4—Ag3—S7ⁱⁱⁱ	115.27 (10)	Ag21—Cu3—Ag25	85.07 (3)
S4—Ag3—S14^iv	117.87 (11)	Ag21—Cu3—Ag29^viii	64.32 (3)
S7ⁱⁱⁱ—Ag3—S14^iv	123.89 (11)	Ag21—Cu3—S16^x	114.57 (7)
Ag3—Ag3cu—Ag23	0	Ag21—Cu3—S20	58.40 (6)
Ag3—Ag3cu—S4	0	Ag24—Cu3—Ag25	70.78 (4)
Ag3—Ag3cu—S7ⁱⁱⁱ	0	Ag24—Cu3—Ag29^viii	149.68 (6)
Ag3—Ag3cu—S14^iv	0	Ag24—Cu3—S16^x	124.99 (7)
Ag23—Ag3cu—S4	70.31 (5)	Ag24—Cu3—S20	62.26 (6)
Ag23—Ag3cu—S7ⁱⁱⁱ	77.65 (5)	Ag25—Cu3—Ag29^viii	137.60 (5)
Ag23—Ag3cu—S14^iv	136.97 (6)	Ag25—Cu3—S16^x	113.47 (7)
S4—Ag3cu—S7ⁱⁱⁱ	115.27 (7)	Ag25—Cu3—S20	60.52 (6)
S4—Ag3cu—S14^iv	117.87 (8)	Ag29^viii—Cu3—S16^x	61.23 (6)
S7ⁱⁱⁱ—Ag3cu—S14^iv	123.89 (8)	Ag29^viii—Cu3—S20	116.80 (7)
S5—Ag4—S10ⁱⁱⁱ	100.03 (7)	S16^x—Cu3—S20	169.92 (9)
S5—Ag4—S14^iv	114.30 (8)	Sb1—S1—Ag1	100.87 (7)
S10ⁱⁱⁱ—Ag4—S14^iv	145.66 (9)	Sb1—S1—Ag5	101.34 (8)
Ag13—Ag5—S1	77.87 (5)	Sb1—S1—Ag16	113.89 (8)
Ag13—Ag5—S5ⁱ	75.41 (5)	Ag1—S1—Ag5	112.85 (8)
Ag13—Ag5—S13	138.46 (6)	Ag1—S1—Ag16	103.50 (7)
Ag13—Ag5—S16	49.35 (4)	Ag5—S1—Ag16	122.59 (8)
S1—Ag5—S5ⁱ	116.34 (7)	Sb1—S2—Ag2	98.35 (7)
S1—Ag5—S13	119.81 (8)	Sb1—S2—Ag6	105.09 (8)
S1—Ag5—S16	101.45 (6)	Sb1—S2—Ag20	105.69 (7)
S5ⁱ—Ag5—S13	118.50 (8)	Ag2—S2—Ag6	120.04 (8)
S5ⁱ—Ag5—S16	102.65 (6)	Ag2—S2—Ag20	125.41 (8)
S13—Ag5—S16	89.21 (6)	Ag6—S2—Ag20	99.97 (7)
Ag7^v—Ag6—Ag10^iv	61.48 (2)	Sb1—S3—Ag7	102.06 (7)
Ag7^v—Ag6—S2	92.04 (5)	Sb1—S3—Ag8	97.70 (7)
Ag7^v—Ag6—S4	147.92 (5)	Sb1—S3—Ag17	107.54 (7)
Ag7^v—Ag6—S13^v	55.14 (5)	Ag7—S3—Ag8	112.44 (8)
Ag10^iv—Ag6—S2	145.28 (5)	Ag7—S3—Ag17	100.25 (7)
Ag10^iv—Ag6—S4	95.55 (5)	Ag8—S3—Ag17	133.13 (8)
Ag10^iv—Ag6—S13^v	53.69 (5)	Sb2—S4—Ag3	104.22 (9)
S2—Ag6—S4	97.55 (7)	Sb2—S4—Ag3cu	104.22 (8)
S2—Ag6—S13^v	130.31 (7)	Sb2—S4—Ag6	105.45 (8)
S4—Ag6—S13^v	130.60 (7)	Sb2—S4—Ag24	101.63 (8)
Ag6^v—Ag7—S3	149.16 (5)	Ag3—S4—Ag3cu	0
Ag6^v—Ag7—S8	96.45 (5)	Ag3—S4—Ag6	115.85 (9)
Ag6^v—Ag7—S13	55.00 (5)	Ag3—S4—Ag24	131.59 (10)
S3—Ag7—S8	101.66 (7)	Ag3cu—S4—Ag6	115.85 (8)
S3—Ag7—S13	113.80 (7)	Ag3cu—S4—Ag24	131.59 (9)
S8—Ag7—S13	144.09 (7)	Ag6—S4—Ag24	95.24 (8)
S3—Ag8—S9	106.42 (7)	Sb2—S5—Ag4	100.50 (7)
S3—Ag8—S13^v	143.90 (7)	Sb2—S5—Ag5^vi	99.88 (8)
S9—Ag8—S13^v	108.06 (7)	Sb2—S5—Ag28	102.76 (8)
S6—Ag9—S11	110.98 (9)	Ag4—S5—Ag5^vi	109.79 (8)
S6—Ag9—S13^v	139.03 (10)	Ag4—S5—Ag28	122.56 (9)
S11—Ag9—S13^v	109.92 (9)	Ag5^vi—S5—Ag28	116.69 (9)
Ag6^iv—Ag10—S6	143.97 (5)	Sb2—S6—Ag9	103.27 (8)
Ag6^iv—Ag10—S12	98.64 (5)	Sb2—S6—Ag10	101.68 (7)
Ag6^iv—Ag10—S13^vi	54.54 (5)	Sb2—S6—Ag29	123.01 (9)
S6—Ag10—S12	101.38 (7)	Ag9—S6—Ag10	111.22 (9)
S6—Ag10—S13^vi	112.81 (7)	Ag9—S6—Ag29	128.78 (10)
S12—Ag10—S13^vi	145.68 (7)	Ag10—S6—Ag29	81.68 (6)
S8—Ag11—S9	99.53 (7)	Sb3—S7—Ag2^ix	99.02 (7)
S8—Ag11—S14^vii	116.98 (8)	Sb3—S7—Ag3^ix	102.27 (8)
S9—Ag11—S14^vii	143.48 (8)	Sb3—S7—Ag3cu^ix	102.27 (7)
S11—Ag12—S12	112.53 (10)	Sb3—S7—Ag15	101.72 (8)
S11—Ag12—S14	136.48 (11)	Ag2^ix—S7—Ag3^ix	108.38 (9)
S12—Ag12—S14	110.36 (10)	Ag2^ix—S7—Ag3cu^ix	108.38 (8)
Ag5—Ag13—Cu3^viii	112.69 (3)	Ag2^ix—S7—Ag15	122.76 (8)
Ag5—Ag13—S15	106.60 (5)	Ag3^ix—S7—Ag3cu^ix	0
Ag5—Ag13—S16	64.49 (5)	Ag3^ix—S7—Ag15	118.08 (9)
Cu3^viii—Ag13—S15	140.31 (6)	Ag3cu^ix—S7—Ag15	118.08 (8)
Cu3^viii—Ag13—S16	48.25 (5)	Sb3—S8—Ag7	103.17 (7)
S15—Ag13—S16	168.37 (7)	Sb3—S8—Ag11	103.08 (7)
Cu3^viii—Ag14—S8	142.24 (8)	Sb3—S8—Ag14	96.19 (8)
Cu3^viii—Ag14—S12ⁱ	120.38 (8)	Sb3—S8—Ag18	124.90 (8)
Cu3^viii—Ag14—S16	46.20 (5)	Ag7—S8—Ag11	119.10 (8)
Cu3^viii—Ag14—S19^viii	84.10 (7)	Ag7—S8—Ag14	85.39 (7)
S8—Ag14—S12ⁱ	75.79 (7)	Ag7—S8—Ag18	127.48 (8)
S8—Ag14—S16	103.20 (8)	Ag11—S8—Ag14	143.47 (9)
S8—Ag14—S19^viii	125.78 (9)	Ag11—S8—Ag18	72.63 (5)
S12ⁱ—Ag14—S16	93.98 (8)	Ag14—S8—Ag18	70.89 (6)
S12ⁱ—Ag14—S19^viii	107.84 (9)	Sb4—S9—Ag8	98.93 (7)
S16—Ag14—S19^viii	129.56 (9)	Sb4—S9—Ag11	100.57 (7)
S7—Ag15—S19^viii	159.95 (7)	Sb4—S9—Ag22	99.67 (7)
Cu1—Ag16—S1	127.89 (5)	Ag8—S9—Ag11	114.37 (8)
Cu1—Ag16—S15	83.50 (5)	Ag8—S9—Ag22	120.46 (8)
Cu1—Ag16—S17	43.97 (4)	Ag11—S9—Ag22	116.79 (8)
Cu1—Ag16—S22^viii	105.81 (5)	Sb4—S10—Ag1^xi	103.68 (7)
S1—Ag16—S15	90.26 (6)	Sb4—S10—Ag4^ix	100.82 (7)
S1—Ag16—S17	86.50 (6)	Sb4—S10—Ag26	95.80 (7)
S1—Ag16—S22^viii	124.52 (6)	Sb4—S10—Ag27^ix	121.98 (8)
S15—Ag16—S17	97.98 (6)	Ag1^xi—S10—Ag4^ix	120.65 (8)
S15—Ag16—S22^viii	110.59 (6)	Ag1^xi—S10—Ag26	88.70 (6)
S17—Ag16—S22^viii	136.12 (6)	Ag1^xi—S10—Ag27^ix	130.06 (8)
S3—Ag17—S16	90.06 (6)	Ag4^ix—S10—Ag26	140.88 (8)
S3—Ag17—S18	85.98 (6)	Ag4^ix—S10—Ag27^ix	72.15 (5)
S3—Ag17—S22^viii	123.08 (6)	Ag26—S10—Ag27^ix	68.99 (5)
S16—Ag17—S18	95.94 (6)	Sb4—S11—Ag9	96.55 (8)
S16—Ag17—S22^viii	143.07 (6)	Sb4—S11—Ag12	99.55 (9)
S18—Ag17—S22^viii	101.70 (6)	Sb4—S11—Ag25	131.42 (8)
Cu2^ix—Ag18—S8	143.49 (5)	Sb4—S11—Ag26	91.95 (7)
Cu2^ix—Ag18—S18	120.22 (5)	Ag9—S11—Ag12	96.38 (9)
Cu2^ix—Ag18—S21^ix	47.21 (4)	Ag9—S11—Ag25	70.62 (6)
S8—Ag18—S18	95.70 (6)	Ag9—S11—Ag26	165.75 (9)
S8—Ag18—S21^ix	100.60 (6)	Ag12—S11—Ag25	127.75 (9)
S18—Ag18—S21^ix	158.10 (7)	Ag12—S11—Ag26	93.46 (8)
Cu1—Ag19—S17	47.81 (4)	Ag25—S11—Ag26	95.19 (7)
Cu1—Ag19—S19	135.15 (5)	Sb3^vi—S12—Ag10	102.29 (8)
S17—Ag19—S19	176.77 (7)	Sb3^vi—S12—Ag12	100.87 (9)
S2—Ag20—S19	92.07 (6)	Sb3^vi—S12—Ag14^vi	89.83 (7)
S2—Ag20—S20	89.67 (6)	Sb3^vi—S12—Ag30	122.43 (9)
S2—Ag20—S22^viii	131.64 (6)	Ag10—S12—Ag12	108.35 (9)
S19—Ag20—S20	93.89 (6)	Ag10—S12—Ag14^vi	87.30 (7)
S19—Ag20—S22^viii	100.87 (6)	Ag10—S12—Ag30	134.70 (9)
S20—Ag20—S22^viii	134.77 (6)	Ag12—S12—Ag14^vi	158.37 (10)
Ag29^viii—Ag21—Cu3	57.77 (3)	Ag12—S12—Ag30	72.28 (7)
Ag29^viii—Ag21—S18	78.15 (5)	Ag14^vi—S12—Ag30	86.11 (7)
Ag29^viii—Ag21—S20	101.38 (5)	Ag5—S13—Ag6^v	159.60 (10)
Cu3—Ag21—S18	133.94 (5)	Ag5—S13—Ag7	93.13 (7)
Cu3—Ag21—S20	47.94 (5)	Ag5—S13—Ag8^v	111.32 (9)
S18—Ag21—S20	173.26 (7)	Ag5—S13—Ag9^v	112.43 (9)
S9—Ag22—S15^x	158.74 (7)	Ag5—S13—Ag10ⁱ	92.91 (7)
Ag3—Ag23—Ag3cu	0	Ag6^v—S13—Ag7	69.86 (6)
Ag3—Ag23—Cu2	114.65 (4)	Ag6^v—S13—Ag8^v	79.10 (7)
Ag3—Ag23—S19	112.70 (6)	Ag6^v—S13—Ag9^v	81.70 (7)
Ag3—Ag23—S21	67.00 (5)	Ag6^v—S13—Ag10ⁱ	71.77 (6)
Ag3cu—Ag23—Cu2	114.65 (2)	Ag7—S13—Ag8^v	84.45 (7)
Ag3cu—Ag23—S19	112.70 (5)	Ag7—S13—Ag9^v	150.08 (10)
Ag3cu—Ag23—S21	67.00 (4)	Ag7—S13—Ag10ⁱ	72.83 (6)
Cu2—Ag23—S19	128.75 (5)	Ag8^v—S13—Ag9^v	99.52 (8)
Cu2—Ag23—S21	47.98 (4)	Ag8^v—S13—Ag10ⁱ	147.72 (9)
S19—Ag23—S21	166.73 (7)	Ag9^v—S13—Ag10ⁱ	89.92 (8)
Cu3—Ag24—S4	135.10 (8)	Ag1^xi—S14—Ag2^xi	77.92 (8)
Cu3—Ag24—S18^x	90.18 (6)	Ag1^xi—S14—Ag3^iv	162.68 (13)
Cu3—Ag24—S20	46.20 (5)	Ag1^xi—S14—Ag3cu^iv	162.68 (12)
S4—Ag24—S18^x	130.43 (9)	Ag1^xi—S14—Ag4^iv	72.70 (8)
S4—Ag24—S20	94.44 (8)	Ag1^xi—S14—Ag11^vii	74.40 (8)
S18^x—Ag24—S20	134.85 (9)	Ag1^xi—S14—Ag12	85.27 (9)
Cu3—Ag25—S11	145.89 (6)	Ag2^xi—S14—Ag3^iv	111.54 (12)
Cu3—Ag25—S20	47.96 (5)	Ag2^xi—S14—Ag3cu^iv	111.54 (11)
Cu3—Ag25—S22	117.48 (5)	Ag2^xi—S14—Ag4^iv	147.94 (13)
S11—Ag25—S20	105.18 (6)	Ag2^xi—S14—Ag11^vii	86.38 (10)
S11—Ag25—S22	95.58 (6)	Ag2^xi—S14—Ag12	99.43 (10)
S20—Ag25—S22	151.74 (7)	Ag3^iv—S14—Ag3cu^iv	0
Cu1^xi—Ag26—S10	138.40 (5)	Ag3^iv—S14—Ag4^iv	94.15 (10)
Cu1^xi—Ag26—S11	119.84 (5)	Ag3^iv—S14—Ag11^vii	91.33 (10)
Cu1^xi—Ag26—S15^x	91.23 (5)	Ag3^iv—S14—Ag12	106.59 (13)
Cu1^xi—Ag26—S17^xi	46.18 (4)	Ag3cu^iv—S14—Ag4^iv	94.15 (9)
S10—Ag26—S11	76.19 (6)	Ag3cu^iv—S14—Ag11^vii	91.33 (9)
S10—Ag26—S15^x	124.28 (6)	Ag3cu^iv—S14—Ag12	106.59 (12)
S10—Ag26—S17^xi	98.45 (6)	Ag4^iv—S14—Ag11^vii	73.73 (8)
S11—Ag26—S15^x	103.07 (7)	Ag4^iv—S14—Ag12	90.77 (10)
S11—Ag26—S17^xi	94.07 (6)	Ag11^vii—S14—Ag12	157.27 (13)
S15^x—Ag26—S17^xi	136.48 (6)	Ag13—S15—Ag16	77.22 (6)
Cu2—Ag27—S10ⁱⁱⁱ	147.16 (5)	Ag13—S15—Ag22^viii	82.09 (6)
Cu2—Ag27—S15^vi	114.84 (5)	Ag13—S15—Ag26^viii	129.83 (8)
Cu2—Ag27—S21	47.53 (4)	Ag13—S15—Ag27ⁱ	110.50 (8)
S10ⁱⁱⁱ—Ag27—S15^vi	97.20 (6)	Ag16—S15—Ag22^viii	133.49 (8)
S10ⁱⁱⁱ—Ag27—S21	105.12 (6)	Ag16—S15—Ag26^viii	84.15 (6)
S15^vi—Ag27—S21	152.02 (7)	Ag16—S15—Ag27ⁱ	132.11 (8)
S5—Ag28—S18^x	157.70 (10)	Ag22^viii—S15—Ag26^viii	77.97 (6)
Ag21^x—Ag29—Cu3^x	57.91 (3)	Ag22^viii—S15—Ag27ⁱ	94.10 (7)
Ag21^x—Ag29—S6	140.99 (7)	Ag26^viii—S15—Ag27ⁱ	116.42 (8)
Ag21^x—Ag29—S16^vi	97.69 (5)	Ag5—S16—Ag13	66.16 (5)
Ag21^x—Ag29—S22	91.01 (5)	Ag5—S16—Ag14	147.96 (8)
Cu3^x—Ag29—S6	150.23 (6)	Ag5—S16—Ag17	93.33 (6)
Cu3^x—Ag29—S16^vi	47.43 (5)	Ag5—S16—Ag29ⁱ	102.48 (7)
Cu3^x—Ag29—S22	103.52 (6)	Ag5—S16—Cu3^viii	139.07 (9)
S6—Ag29—S16^vi	102.84 (7)	Ag13—S16—Ag14	145.51 (9)
S6—Ag29—S22	99.20 (7)	Ag13—S16—Ag17	71.52 (5)
S16^vi—Ag29—S22	131.78 (8)	Ag13—S16—Ag29ⁱ	85.99 (7)
Cu1^xi—Ag30—S12	152.18 (5)	Ag13—S16—Cu3^viii	73.00 (6)
Cu1^xi—Ag30—S17^xi	46.94 (4)	Ag14—S16—Ag17	94.98 (8)
Cu1^xi—Ag30—S22	111.32 (5)	Ag14—S16—Ag29ⁱ	88.25 (8)
S12—Ag30—S17^xi	108.26 (6)	Ag14—S16—Cu3^viii	72.94 (7)
S12—Ag30—S22	96.47 (6)	Ag17—S16—Ag29ⁱ	144.47 (8)
S17^xi—Ag30—S22	144.12 (7)	Ag17—S16—Cu3^viii	75.86 (6)
Ag16—Cu1—Ag16^xii	153.31 (5)	Ag29ⁱ—S16—Cu3^viii	71.34 (6)
Ag16—Cu1—Ag19	63.39 (2)	Ag2—S17—Ag16	96.13 (6)
Ag16—Cu1—Ag19^xii	142.34 (4)	Ag2—S17—Ag19	69.68 (5)
Ag16—Cu1—Ag26ⁱⁱ	82.78 (3)	Ag2—S17—Ag26ⁱⁱ	143.41 (7)
Ag16—Cu1—Ag26^viii	76.68 (3)	Ag2—S17—Ag30ⁱⁱ	109.16 (7)
Ag16—Cu1—Ag30ⁱⁱ	123.58 (2)	Ag2—S17—Cu1	143.04 (9)
Ag16—Cu1—Ag30^viii	66.68 (2)	Ag16—S17—Ag19	69.36 (5)
Ag16—Cu1—S17	64.24 (6)	Ag16—S17—Ag26ⁱⁱ	90.45 (6)
Ag16—Cu1—S17^xii	117.64 (6)	Ag16—S17—Ag30ⁱⁱ	145.10 (7)
Ag16^xii—Cu1—Ag16	153.31 (5)	Ag16—S17—Cu1	71.79 (6)
Ag16^xii—Cu1—Ag19	142.34 (4)	Ag19—S17—Ag26ⁱⁱ	144.81 (8)
Ag16^xii—Cu1—Ag19^xii	63.39 (2)	Ag19—S17—Ag30ⁱⁱ	96.80 (7)
Ag16^xii—Cu1—Ag26ⁱⁱ	76.68 (3)	Ag19—S17—Cu1	73.39 (6)
Ag16^xii—Cu1—Ag26^viii	82.78 (3)	Ag26ⁱⁱ—S17—Ag30ⁱⁱ	83.41 (7)
Ag16^xii—Cu1—Ag30ⁱⁱ	66.68 (2)	Ag26ⁱⁱ—S17—Cu1	72.98 (6)
Ag16^xii—Cu1—Ag30^viii	123.58 (2)	Ag30ⁱⁱ—S17—Cu1	73.57 (6)
Ag16^xii—Cu1—S17	117.64 (6)	Ag17—S18—Ag18	135.46 (7)
Ag16^xii—Cu1—S17^xii	64.24 (6)	Ag17—S18—Ag21	77.59 (5)
Ag19—Cu1—Ag19^xii	83.76 (4)	Ag17—S18—Ag24^viii	87.05 (7)
Ag19—Cu1—Ag26ⁱⁱ	118.81 (2)	Ag17—S18—Ag28^viii	137.63 (8)
Ag19—Cu1—Ag26^viii	131.81 (2)	Ag18—S18—Ag21	108.54 (7)
Ag19—Cu1—Ag30ⁱⁱ	84.07 (3)	Ag18—S18—Ag24^viii	112.54 (8)
Ag19—Cu1—Ag30^viii	66.20 (3)	Ag18—S18—Ag28^viii	86.81 (7)
Ag19—Cu1—S17	58.79 (6)	Ag21—S18—Ag24^viii	134.06 (9)
Ag19—Cu1—S17^xii	115.06 (7)	Ag21—S18—Ag28^viii	86.95 (7)
Ag19^xii—Cu1—Ag19	83.76 (4)	Ag24^viii—S18—Ag28^viii	75.85 (7)
Ag19^xii—Cu1—Ag26ⁱⁱ	131.81 (2)	Ag14^x—S19—Ag15^x	75.98 (6)
Ag19^xii—Cu1—Ag26^viii	118.81 (2)	Ag14^x—S19—Ag19	131.41 (9)
Ag19^xii—Cu1—Ag30ⁱⁱ	66.20 (3)	Ag14^x—S19—Ag20	92.41 (7)
Ag19^xii—Cu1—Ag30^viii	84.07 (3)	Ag14^x—S19—Ag23	114.34 (8)
Ag19^xii—Cu1—S17	115.06 (7)	Ag15^x—S19—Ag19	81.76 (6)
Ag19^xii—Cu1—S17^xii	58.79 (6)	Ag15^x—S19—Ag20	133.86 (7)
Ag26ⁱⁱ—Cu1—Ag26^viii	79.06 (4)	Ag15^x—S19—Ag23	86.31 (6)
Ag26ⁱⁱ—Cu1—Ag30ⁱⁱ	74.13 (3)	Ag19—S19—Ag20	73.06 (5)
Ag26ⁱⁱ—Cu1—Ag30^viii	143.00 (4)	Ag19—S19—Ag23	106.55 (7)
Ag26ⁱⁱ—Cu1—S17	60.84 (6)	Ag20—S19—Ag23	137.45 (8)
Ag26ⁱⁱ—Cu1—S17^xii	125.82 (7)	Ag20—S20—Ag21	71.62 (5)
Ag26^viii—Cu1—Ag26ⁱⁱ	79.06 (4)	Ag20—S20—Ag24	93.72 (7)
Ag26^viii—Cu1—Ag30ⁱⁱ	143.00 (4)	Ag20—S20—Ag25	146.44 (8)
Ag26^viii—Cu1—Ag30^viii	74.13 (3)	Ag20—S20—Cu3	74.97 (6)
Ag26^viii—Cu1—S17	125.82 (7)	Ag21—S20—Ag24	144.71 (8)
Ag26^viii—Cu1—S17^xii	60.84 (6)	Ag21—S20—Ag25	96.99 (7)
Ag30ⁱⁱ—Cu1—Ag30^viii	140.19 (6)	Ag21—S20—Cu3	73.66 (6)
Ag30ⁱⁱ—Cu1—S17	59.49 (6)	Ag24—S20—Ag25	77.45 (6)
Ag30ⁱⁱ—Cu1—S17^xii	117.67 (6)	Ag24—S20—Cu3	71.54 (7)
Ag30^viii—Cu1—Ag30ⁱⁱ	140.19 (6)	Ag25—S20—Cu3	71.52 (6)
Ag30^viii—Cu1—S17	117.67 (6)	Ag18ⁱⁱⁱ—S21—Ag23	109.70 (7)
Ag30^viii—Cu1—S17^xii	59.49 (6)	Ag18ⁱⁱⁱ—S21—Ag27	111.50 (8)
S17—Cu1—S17^xii	172.71 (10)	Ag18ⁱⁱⁱ—S21—Cu2	75.28 (6)
S17^xii—Cu1—S17	172.71 (10)	Ag23—S21—Ag27	116.61 (8)
Ag18ⁱⁱⁱ—Cu2—Ag18^x	150.33 (6)	Ag23—S21—Cu2	73.10 (6)
Ag18ⁱⁱⁱ—Cu2—Ag23	92.49 (4)	Ag27—S21—Cu2	73.42 (7)
Ag18ⁱⁱⁱ—Cu2—Ag23^xii	67.64 (3)	Ag16^x—S22—Ag17^x	77.22 (5)
Ag18ⁱⁱⁱ—Cu2—Ag27	93.80 (3)	Ag16^x—S22—Ag20^x	80.40 (5)
Ag18ⁱⁱⁱ—Cu2—Ag27^xii	110.45 (3)	Ag16^x—S22—Ag25	94.39 (6)
Ag18ⁱⁱⁱ—Cu2—S21	57.51 (6)	Ag16^x—S22—Ag29	162.72 (7)
Ag18ⁱⁱⁱ—Cu2—S21^xii	120.84 (6)	Ag16^x—S22—Ag30	76.15 (6)
Ag18^x—Cu2—Ag18ⁱⁱⁱ	150.33 (6)	Ag17^x—S22—Ag20^x	79.52 (5)
Ag18^x—Cu2—Ag23	67.64 (3)	Ag17^x—S22—Ag25	71.94 (5)
Ag18^x—Cu2—Ag23^xii	92.49 (4)	Ag17^x—S22—Ag29	94.91 (7)
Ag18^x—Cu2—Ag27	110.45 (3)	Ag17^x—S22—Ag30	153.07 (8)
Ag18^x—Cu2—Ag27^xii	93.80 (3)	Ag20^x—S22—Ag25	151.43 (8)
Ag18^x—Cu2—S21	120.84 (6)	Ag20^x—S22—Ag29	83.06 (6)
Ag18^x—Cu2—S21^xii	57.51 (6)	Ag20^x—S22—Ag30	99.88 (7)
Ag23—Cu2—Ag23^xii	97.68 (5)	Ag25—S22—Ag29	97.76 (7)
Ag23—Cu2—Ag27	99.18 (2)	Ag25—S22—Ag30	106.14 (7)
Ag23—Cu2—Ag27^xii	155.40 (3)	Ag29—S22—Ag30	111.82 (7)
Ag23—Cu2—S21	58.91 (6)

Symmetry codes: (i) x, y−1, z; (ii) x−1/2, y−1/2, z; (iii) x−1/2, y+1/2, z; (iv) −x+1/2, −y+3/2, −z; (v) −x+1/2, −y+1/2, −z; (vi) x, y+1, z; (vii) −x+1, −y+1, −z; (viii) −x+1/2, y−1/2, −z+1/2; (ix) x+1/2, y−1/2, z; (x) −x+1/2, y+1/2, −z+1/2; (xi) x+1/2, y+1/2, z; (xii) −x, y, −z+1/2.

Experimental details

	(polybasite221)	(polybasite222)
Crystal data
Chemical formula	Ag_14.52Cu_1.48S₁₁Sb₂	Ag_14.814Cu_1.186S₁₁Sb₂
M_r	2256.5	2269.5
Crystal system, space group	Trigonal, P321	Monoclinic, C2/c
Temperature (K)	120	100
a, b, c (Å)	15.0954 (12), 15.0954 (12), 11.8825 (8)	26.188 (3), 15.1199 (18), 23.784 (3)
α, β, γ (°)	90, 90, 120	90, 90, 90
V (Å³)	2344.9 (3)	9418 (2)
Z	4	16
Radiation type	Mo Kα	Mo Kα
µ (mm⁻¹)	16.32	16.25
Crystal size (mm)	0.14 × 0.08 × 0.06	0.15 × 0.12 × 0.09

Data collection
Diffractometer	Nonius CCD diffractometer	Nonius CCD diffractometer
Absorption correction	Gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	Gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)
T_min, T_max	0.196, 0.417	0.186, 0.268
No. of measured, independent and observed [I > 2σ(I)] reflections	?, 6847, 6224	?, 43813, 38767
R_int	0.063	0.073
(sin θ/λ)_max (Å⁻¹)	0.807	0.827

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.036, 0.046, 1.41	0.050, 0.057, 1.48
No. of reflections	6847	43813
No. of parameters	224	592
No. of restraints	?	?
Δρ_max, Δρ_min (e Å⁻³)	1.05, −0.81	1.15, −1.10

Computer programs: (Jana2000; Petricek and Dusek, 2000).

Selected geometric parameters (Å, º) for (polybasite221) top

Sb1—S1	2.4127 (17)	Ag4—S4^vi	2.609 (2)
Sb1—S1ⁱ	2.4127 (16)	Ag4—S9	2.502 (3)
Sb1—S1ⁱⁱ	2.413 (3)	Ag5—Cu1ⁱ	2.9790 (14)
Sb2—S2ⁱⁱⁱ	2.4392 (15)	Ag5—S1	2.6058 (17)
Sb2—S3	2.422 (3)	Ag5—S5	2.744 (2)
Sb2—S4	2.4095 (16)	Ag5—S7	2.8747 (14)
Ag1—Ag1^iv	2.9227 (9)	Ag5—S8	2.5800 (18)
Ag1—S1	2.537 (2)	Ag6—S2ⁱⁱⁱ	2.425 (2)
Ag1—S3	2.5324 (18)	Ag6—S7^vii	2.4065 (18)
Ag1—S9	2.556 (2)	Ag7—Cu2	2.8083 (5)
Ag2—Ag2cu	0	Ag7—S3	2.9156 (17)
Ag2—S1	2.4133 (18)	Ag7—S6	2.4891 (8)
Ag2—S2	2.4810 (19)	Ag7—S7	2.4552 (17)
Ag2—S5ⁱⁱ	2.977 (2)	Ag8—Cu1^vii	2.8103 (18)
Ag2—S9ⁱⁱ	2.437 (3)	Ag8—S4	2.638 (3)
Ag2cu—S1	2.4133 (17)	Ag8—S5^viii	2.546 (3)
Ag2cu—S2	2.4810 (18)	Ag8—S8^vii	2.5442 (16)
Ag2cu—S5ⁱⁱ	2.977 (2)	Ag9—Cu1	2.7868 (11)
Ag2cu—S9ⁱⁱ	2.437 (3)	Ag9—S5ⁱⁱ	2.490 (3)
Ag3—Ag3cu	0	Ag9—S7	2.429 (2)
Ag3—S2	2.497 (3)	Ag10—Cu1ⁱ	2.8743 (15)
Ag3—S3	2.486 (2)	Ag10—S3	2.704 (2)
Ag3—S10	2.088 (6)	Ag10—S5	2.6192 (18)
Ag3—S10^v	2.462 (8)	Ag10—S7^vii	2.533 (2)
Ag3—S10ⁱⁱⁱ	2.756 (7)	Cu1—S5ⁱⁱ	2.1663 (13)
Ag3cu—S2	2.497 (2)	Cu1—S5^ix	2.1663 (13)
Ag3cu—S3	2.4855 (17)	Cu2—S6	2.152 (2)
Ag3cu—S10	2.088 (6)	Cu2—S6^vii	2.152 (2)
Ag3cu—S10^v	2.462 (8)	S10—S10^v	0.844 (11)
Ag3cu—S10ⁱⁱⁱ	2.756 (7)	S10—S10ⁱⁱⁱ	0.844 (11)
Ag4—S4	2.4786 (18)

S1—Sb1—S1ⁱ	96.37 (7)	Ag1—S3—Ag3cu	119.29 (9)
S1—Sb1—S1ⁱⁱ	96.37 (7)	Ag1—S3—Ag7	129.77 (9)
S1ⁱ—Sb1—S1	96.37 (7)	Ag1—S3—Ag10	88.71 (5)
S1ⁱ—Sb1—S1ⁱⁱ	96.37 (8)	Ag3—S3—Ag3cu	0
S1ⁱⁱ—Sb1—S1	96.37 (7)	Ag3—S3—Ag7	69.80 (6)
S1ⁱⁱ—Sb1—S1ⁱ	96.37 (8)	Ag3—S3—Ag10	140.33 (8)
S2ⁱⁱⁱ—Sb2—S3	96.56 (7)	Ag3cu—S3—Ag7	69.80 (4)
S2ⁱⁱⁱ—Sb2—S4	97.37 (7)	Ag3cu—S3—Ag10	140.33 (7)
S3—Sb2—S4	93.30 (7)	Ag7—S3—Ag10	70.63 (5)
Ag1^iv—Ag1—S1	149.18 (5)	Sb2—S4—Ag4	101.11 (7)
Ag1^iv—Ag1—S3	94.25 (5)	Sb2—S4—Ag4^viii	99.67 (6)
Ag1^iv—Ag1—S9	55.12 (5)	Sb2—S4—Ag8	124.89 (7)
S1—Ag1—S3	98.74 (6)	Ag4—S4—Ag4^viii	110.07 (6)
S1—Ag1—S9	122.35 (8)	Ag4—S4—Ag8	132.63 (7)
S3—Ag1—S9	138.06 (10)	Ag4^viii—S4—Ag4	110.07 (6)
Ag2cu—Ag2—S1	0	Ag4^viii—S4—Ag8	75.59 (8)
Ag2cu—Ag2—S2	0	Ag2ⁱ—S5—Ag2cuⁱ	0
Ag2cu—Ag2—S5ⁱⁱ	0	Ag2ⁱ—S5—Ag5	93.84 (6)
Ag2cu—Ag2—S9ⁱⁱ	0	Ag2ⁱ—S5—Ag8^vi	107.12 (6)
S1—Ag2—S2	112.77 (7)	Ag2ⁱ—S5—Ag9ⁱ	66.58 (4)
S1—Ag2—S5ⁱⁱ	101.51 (6)	Ag2ⁱ—S5—Ag10	147.00 (6)
S1—Ag2—S9ⁱⁱ	130.28 (7)	Ag2ⁱ—S5—Cu1ⁱ	139.71 (6)
S2—Ag2—S5ⁱⁱ	98.12 (6)	Ag2cuⁱ—S5—Ag5	93.84 (6)
S2—Ag2—S9ⁱⁱ	113.31 (7)	Ag2cuⁱ—S5—Ag8^vi	107.12 (6)
S5ⁱⁱ—Ag2—S9ⁱⁱ	89.57 (8)	Ag2cuⁱ—S5—Ag9ⁱ	66.58 (4)
Ag2—Ag2cu—S1	0	Ag2cuⁱ—S5—Ag10	147.00 (6)
Ag2—Ag2cu—S2	0	Ag2cuⁱ—S5—Cu1ⁱ	139.71 (6)
Ag2—Ag2cu—S5ⁱⁱ	0	Ag5—S5—Ag8^vi	145.55 (6)
Ag2—Ag2cu—S9ⁱⁱ	0	Ag5—S5—Ag9ⁱ	70.43 (5)
S1—Ag2cu—S2	112.77 (6)	Ag5—S5—Ag10	94.36 (7)
S1—Ag2cu—S5ⁱⁱ	101.51 (6)	Ag5—S5—Cu1ⁱ	73.64 (6)
S1—Ag2cu—S9ⁱⁱ	130.28 (7)	Ag8^vi—S5—Ag9ⁱ	92.82 (6)
S2—Ag2cu—S5ⁱⁱ	98.12 (5)	Ag8^vi—S5—Ag10	82.85 (8)
S2—Ag2cu—S9ⁱⁱ	113.31 (7)	Ag8^vi—S5—Cu1ⁱ	72.71 (7)
S5ⁱⁱ—Ag2cu—S9ⁱⁱ	89.57 (8)	Ag9ⁱ—S5—Ag10	145.76 (6)
Ag3cu—Ag3—S2	0	Ag9ⁱ—S5—Cu1ⁱ	73.16 (5)
Ag3cu—Ag3—S3	0	Ag10—S5—Cu1ⁱ	73.14 (5)
Ag3cu—Ag3—S10	0	Ag7—S6—Ag7^v	112.77 (5)
Ag3cu—Ag3—S10^v	0	Ag7—S6—Ag7ⁱⁱⁱ	112.77 (5)
Ag3cu—Ag3—S10ⁱⁱⁱ	0	Ag7—S6—Cu2	74.08 (5)
S2—Ag3—S3	104.11 (9)	Ag7^v—S6—Ag7	112.77 (5)
S2—Ag3—S10	134.4 (3)	Ag7^v—S6—Ag7ⁱⁱⁱ	112.77 (5)
S2—Ag3—S10^v	116.7 (3)	Ag7^v—S6—Cu2	74.08 (5)
S2—Ag3—S10ⁱⁱⁱ	133.0 (3)	Ag7ⁱⁱⁱ—S6—Ag7	112.77 (5)
S3—Ag3—S10	119.8 (3)	Ag7ⁱⁱⁱ—S6—Ag7^v	112.77 (5)
S3—Ag3—S10^v	138.7 (3)	Ag7ⁱⁱⁱ—S6—Cu2	74.08 (6)
S3—Ag3—S10ⁱⁱⁱ	122.8 (3)	Ag5—S7—Ag6^vii	135.37 (8)
S10—Ag3—S10^v	19.2 (3)	Ag5—S7—Ag7	134.50 (6)
S10—Ag3—S10ⁱⁱⁱ	12.33 (17)	Ag5—S7—Ag9	75.74 (5)
S10^v—Ag3—S10	19.2 (3)	Ag5—S7—Ag10^vii	87.16 (5)
S10^v—Ag3—S10ⁱⁱⁱ	17.5 (4)	Ag6^vii—S7—Ag7	89.36 (6)
S10ⁱⁱⁱ—Ag3—S10	12.33 (17)	Ag6^vii—S7—Ag9	83.53 (8)
S10ⁱⁱⁱ—Ag3—S10^v	17.5 (4)	Ag6^vii—S7—Ag10^vii	76.82 (6)
Ag3—Ag3cu—S2	0	Ag7—S7—Ag9	108.23 (6)
Ag3—Ag3cu—S3	0	Ag7—S7—Ag10^vii	116.56 (9)
Ag3—Ag3cu—S10	0	Ag9—S7—Ag10^vii	130.32 (9)
Ag3—Ag3cu—S10^v	0	Ag5—S8—Ag5ⁱ	78.60 (7)
Ag3—Ag3cu—S10ⁱⁱⁱ	0	Ag5—S8—Ag5ⁱⁱ	78.60 (7)
S2—Ag3cu—S3	104.11 (6)	Ag5—S8—Ag8^vii	95.68 (5)
S2—Ag3cu—S10	134.4 (3)	Ag5—S8—Ag8^xii	77.54 (5)
S2—Ag3cu—S10^v	116.7 (3)	Ag5—S8—Ag8^ix	156.13 (8)
S2—Ag3cu—S10ⁱⁱⁱ	133.0 (3)	Ag5ⁱ—S8—Ag5	78.60 (7)
S3—Ag3cu—S10	119.8 (3)	Ag5ⁱ—S8—Ag5ⁱⁱ	78.61 (6)
S3—Ag3cu—S10^v	138.7 (3)	Ag5ⁱ—S8—Ag8^vii	156.13 (8)
S3—Ag3cu—S10ⁱⁱⁱ	122.8 (3)	Ag5ⁱ—S8—Ag8^xii	95.68 (4)
S10—Ag3cu—S10^v	19.2 (3)	Ag5ⁱ—S8—Ag8^ix	77.54 (4)
S10—Ag3cu—S10ⁱⁱⁱ	12.33 (17)	Ag5ⁱⁱ—S8—Ag5	78.60 (7)
S10^v—Ag3cu—S10	19.2 (3)	Ag5ⁱⁱ—S8—Ag5ⁱ	78.61 (6)
S10^v—Ag3cu—S10ⁱⁱⁱ	17.5 (4)	Ag5ⁱⁱ—S8—Ag8^vii	77.54 (4)
S10ⁱⁱⁱ—Ag3cu—S10	12.33 (17)	Ag5ⁱⁱ—S8—Ag8^xii	156.13 (9)
S10ⁱⁱⁱ—Ag3cu—S10^v	17.5 (4)	Ag5ⁱⁱ—S8—Ag8^ix	95.68 (6)
S4—Ag4—S4^vi	105.05 (7)	Ag8^vii—S8—Ag8^xii	105.78 (8)
S4—Ag4—S9	145.08 (7)	Ag8^vii—S8—Ag8^ix	105.78 (9)
S4^vi—Ag4—S4	105.05 (7)	Ag8^xii—S8—Ag8^vii	105.78 (8)
S4^vi—Ag4—S9	109.86 (7)	Ag8^xii—S8—Ag8^ix	105.78 (10)
Cu1ⁱ—Ag5—S1	129.00 (6)	Ag8^ix—S8—Ag8^vii	105.78 (9)
Cu1ⁱ—Ag5—S5	44.25 (3)	Ag8^ix—S8—Ag8^xii	105.78 (10)
Cu1ⁱ—Ag5—S7	79.87 (5)	Ag1—S9—Ag1^iv	69.75 (5)
Cu1ⁱ—Ag5—S8	104.02 (4)	Ag1—S9—Ag2ⁱ	86.60 (6)
S1—Ag5—S5	88.60 (6)	Ag1—S9—Ag2^xiii	156.35 (9)
S1—Ag5—S7	89.29 (4)	Ag1—S9—Ag2cuⁱ	86.60 (6)
S1—Ag5—S8	126.90 (7)	Ag1—S9—Ag2cu^xiii	156.35 (9)
S5—Ag5—S7	95.93 (5)	Ag1—S9—Ag4	76.39 (5)
S5—Ag5—S8	138.47 (4)	Ag1—S9—Ag4^iv	77.85 (8)
S7—Ag5—S8	104.28 (5)	Ag1^iv—S9—Ag1	69.75 (5)
S2ⁱⁱⁱ—Ag6—S7^vii	158.12 (7)	Ag1^iv—S9—Ag2ⁱ	156.35 (9)
Cu2—Ag7—S3	143.83 (5)	Ag1^iv—S9—Ag2^xiii	86.60 (6)
Cu2—Ag7—S6	47.46 (5)	Ag1^iv—S9—Ag2cuⁱ	156.35 (9)
Cu2—Ag7—S7	120.47 (4)	Ag1^iv—S9—Ag2cu^xiii	86.60 (6)
S3—Ag7—S6	101.89 (6)	Ag1^iv—S9—Ag4	77.85 (8)
S3—Ag7—S7	94.62 (5)	Ag1^iv—S9—Ag4^iv	76.39 (5)
S6—Ag7—S7	158.03 (6)	Ag2ⁱ—S9—Ag2^xiii	117.05 (8)
Cu1^vii—Ag8—S4	151.33 (6)	Ag2ⁱ—S9—Ag2cuⁱ	0
Cu1^vii—Ag8—S5^viii	47.39 (5)	Ag2ⁱ—S9—Ag2cu^xiii	117.05 (8)
Cu1^vii—Ag8—S8^vii	109.97 (7)	Ag2ⁱ—S9—Ag4	97.10 (4)
S4—Ag8—S5^viii	105.70 (7)	Ag2ⁱ—S9—Ag4^iv	99.22 (12)
S4—Ag8—S8^vii	97.84 (7)	Ag2^xiii—S9—Ag2ⁱ	117.05 (8)
S5^viii—Ag8—S8^vii	140.63 (11)	Ag2^xiii—S9—Ag2cuⁱ	117.05 (8)
Cu1—Ag9—S5ⁱⁱ	48.07 (4)	Ag2^xiii—S9—Ag2cu^xiii	0
Cu1—Ag9—S7	136.30 (4)	Ag2^xiii—S9—Ag4	99.22 (12)
S5ⁱⁱ—Ag9—S7	173.36 (5)	Ag2^xiii—S9—Ag4^iv	97.10 (4)
Cu1ⁱ—Ag10—S3	137.70 (9)	Ag2cuⁱ—S9—Ag2cu^xiii	117.05 (8)
Cu1ⁱ—Ag10—S5	46.16 (4)	Ag2cuⁱ—S9—Ag4	97.10 (3)
Cu1ⁱ—Ag10—S7^vii	87.83 (5)	Ag2cuⁱ—S9—Ag4^iv	99.22 (12)
S3—Ag10—S5	99.06 (7)	Ag2cu^xiii—S9—Ag2cuⁱ	117.05 (8)
S3—Ag10—S7^vii	125.66 (7)	Ag2cu^xiii—S9—Ag4	99.22 (12)
S5—Ag10—S7^vii	133.35 (7)	Ag2cu^xiii—S9—Ag4^iv	97.10 (3)
Ag5ⁱⁱ—Cu1—Ag5^ix	158.40 (5)	Ag4—S9—Ag4^iv	148.46 (9)
Ag5ⁱⁱ—Cu1—Ag8^v	121.57 (3)	Ag4^iv—S9—Ag4	148.46 (9)
Ag5ⁱⁱ—Cu1—Ag8^vii	67.25 (3)	Ag3—S10—Ag3^v	85.5 (2)
Ag5ⁱⁱ—Cu1—Ag9	63.19 (2)	Ag3—S10—Ag3^iv	109.7 (3)
Ag5ⁱⁱ—Cu1—Ag9^x	137.80 (4)	Ag3—S10—Ag3ⁱⁱⁱ	93.49 (16)
Ag5ⁱⁱ—Cu1—Ag10ⁱⁱ	84.47 (5)	Ag3—S10—Ag3^xiv	101.1 (4)
Ag5ⁱⁱ—Cu1—Ag10^ix	79.31 (5)	Ag3—S10—Ag3^xv	164.7 (3)
Ag5ⁱⁱ—Cu1—S5ⁱⁱ	62.12 (5)	Ag3—S10—Ag3cu	0
Ag5ⁱⁱ—Cu1—S5^ix	119.79 (5)	Ag3—S10—Ag3cu^v	85.5 (2)
Ag5^ix—Cu1—Ag5ⁱⁱ	158.40 (5)	Ag3—S10—Ag3cu^iv	109.7 (3)
Ag5^ix—Cu1—Ag8^v	67.25 (4)	Ag3—S10—Ag3cuⁱⁱⁱ	93.49 (15)
Ag5^ix—Cu1—Ag8^vii	121.57 (3)	Ag3—S10—Ag3cu^xiv	101.1 (4)
Ag5^ix—Cu1—Ag9	137.80 (4)	Ag3—S10—Ag3cu^xv	164.7 (3)
Ag5^ix—Cu1—Ag9^x	63.19 (2)	Ag3—S10—S10^v	106.3 (9)
Ag5^ix—Cu1—Ag10ⁱⁱ	79.31 (5)	Ag3—S10—S10ⁱⁱⁱ	135.77 (19)
Ag5^ix—Cu1—Ag10^ix	84.47 (5)	Ag3^v—S10—Ag3	85.5 (2)
Ag5^ix—Cu1—S5ⁱⁱ	119.79 (6)	Ag3^v—S10—Ag3^iv	164.7 (3)
Ag5^ix—Cu1—S5^ix	62.12 (6)	Ag3^v—S10—Ag3ⁱⁱⁱ	78.91 (16)
Ag8^v—Cu1—Ag8^vii	137.15 (8)	Ag3^v—S10—Ag3^xiv	81.5 (3)
Ag8^v—Cu1—Ag9	81.34 (6)	Ag3^v—S10—Ag3^xv	79.44 (19)
Ag8^v—Cu1—Ag9^x	65.53 (5)	Ag3^v—S10—Ag3cu	85.5 (2)
Ag8^v—Cu1—Ag10ⁱⁱ	73.92 (6)	Ag3^v—S10—Ag3cu^v	0
Ag8^v—Cu1—Ag10^ix	145.74 (8)	Ag3^v—S10—Ag3cu^iv	164.7 (3)
Ag8^v—Cu1—S5ⁱⁱ	59.90 (5)	Ag3^v—S10—Ag3cuⁱⁱⁱ	78.91 (15)
Ag8^v—Cu1—S5^ix	116.40 (5)	Ag3^v—S10—Ag3cu^xiv	81.5 (3)
Ag8^vii—Cu1—Ag8^v	137.15 (8)	Ag3^v—S10—Ag3cu^xv	79.44 (18)
Ag8^vii—Cu1—Ag9	65.53 (4)	Ag3^v—S10—S10^v	31.90 (15)
Ag8^vii—Cu1—Ag9^x	81.34 (4)	Ag3^v—S10—S10ⁱⁱⁱ	61.1 (9)
Ag8^vii—Cu1—Ag10ⁱⁱ	145.74 (6)	Ag3^iv—S10—Ag3	109.7 (3)
Ag8^vii—Cu1—Ag10^ix	73.92 (7)	Ag3^iv—S10—Ag3^v	164.7 (3)
Ag8^vii—Cu1—S5ⁱⁱ	116.40 (7)	Ag3^iv—S10—Ag3ⁱⁱⁱ	101.1 (4)
Ag8^vii—Cu1—S5^ix	59.90 (7)	Ag3^iv—S10—Ag3^xiv	93.49 (16)
Ag9—Cu1—Ag9^x	78.72 (3)	Ag3^iv—S10—Ag3^xv	85.5 (2)
Ag9—Cu1—Ag10ⁱⁱ	119.19 (4)	Ag3^iv—S10—Ag3cu	109.7 (3)
Ag9—Cu1—Ag10^ix	132.50 (5)	Ag3^iv—S10—Ag3cu^v	164.7 (3)
Ag9—Cu1—S5ⁱⁱ	58.76 (7)	Ag3^iv—S10—Ag3cu^iv	0
Ag9—Cu1—S5^ix	113.45 (7)	Ag3^iv—S10—Ag3cuⁱⁱⁱ	101.1 (4)
Ag9^x—Cu1—Ag9	78.72 (3)	Ag3^iv—S10—Ag3cu^xiv	93.49 (15)
Ag9^x—Cu1—Ag10ⁱⁱ	132.50 (4)	Ag3^iv—S10—Ag3cu^xv	85.5 (2)
Ag9^x—Cu1—Ag10^ix	119.19 (3)	Ag3^iv—S10—S10^v	135.77 (19)
Ag9^x—Cu1—S5ⁱⁱ	113.45 (5)	Ag3^iv—S10—S10ⁱⁱⁱ	106.3 (9)
Ag9^x—Cu1—S5^ix	58.76 (4)	Ag3ⁱⁱⁱ—S10—Ag3	93.49 (16)
Ag10ⁱⁱ—Cu1—Ag10^ix	82.43 (6)	Ag3ⁱⁱⁱ—S10—Ag3^v	78.91 (16)
Ag10ⁱⁱ—Cu1—S5ⁱⁱ	60.70 (8)	Ag3ⁱⁱⁱ—S10—Ag3^iv	101.1 (4)
Ag10ⁱⁱ—Cu1—S5^ix	127.35 (8)	Ag3ⁱⁱⁱ—S10—Ag3^xiv	154.5 (3)
Ag10^ix—Cu1—Ag10ⁱⁱ	82.43 (6)	Ag3ⁱⁱⁱ—S10—Ag3^xv	81.5 (3)
Ag10^ix—Cu1—S5ⁱⁱ	127.35 (6)	Ag3ⁱⁱⁱ—S10—Ag3cu	93.49 (15)
Ag10^ix—Cu1—S5^ix	60.70 (5)	Ag3ⁱⁱⁱ—S10—Ag3cu^v	78.91 (15)
S5ⁱⁱ—Cu1—S5^ix	171.05 (9)	Ag3ⁱⁱⁱ—S10—Ag3cu^iv	101.1 (4)
S5^ix—Cu1—S5ⁱⁱ	171.05 (9)	Ag3ⁱⁱⁱ—S10—Ag3cuⁱⁱⁱ	0
Ag7—Cu2—Ag7^v	95.15 (2)	Ag3ⁱⁱⁱ—S10—Ag3cu^xiv	154.5 (3)
Ag7—Cu2—Ag7^vii	68.524 (18)	Ag3ⁱⁱⁱ—S10—Ag3cu^xv	81.5 (3)
Ag7—Cu2—Ag7ⁱⁱⁱ	95.15 (2)	Ag3ⁱⁱⁱ—S10—S10^v	101.4 (9)
Ag7—Cu2—Ag7^x	107.16 (2)	Ag3ⁱⁱⁱ—S10—S10ⁱⁱⁱ	54.5 (8)
Ag7—Cu2—Ag7^xi	153.08 (3)	Ag3^xiv—S10—Ag3	101.1 (4)
Ag7—Cu2—S6	58.467 (12)	Ag3^xiv—S10—Ag3^v	81.5 (3)
Ag7—Cu2—S6^vii	121.533 (12)	Ag3^xiv—S10—Ag3^iv	93.49 (16)
Ag7^v—Cu2—Ag7	95.15 (2)	Ag3^xiv—S10—Ag3ⁱⁱⁱ	154.5 (3)
Ag7^v—Cu2—Ag7^vii	153.08 (3)	Ag3^xiv—S10—Ag3^xv	78.91 (16)
Ag7^v—Cu2—Ag7ⁱⁱⁱ	95.15 (3)	Ag3^xiv—S10—Ag3cu	101.1 (4)
Ag7^v—Cu2—Ag7^x	68.52 (2)	Ag3^xiv—S10—Ag3cu^v	81.5 (3)
Ag7^v—Cu2—Ag7^xi	107.16 (2)	Ag3^xiv—S10—Ag3cu^iv	93.49 (15)
Ag7^v—Cu2—S6	58.467 (13)	Ag3^xiv—S10—Ag3cuⁱⁱⁱ	154.5 (3)
Ag7^v—Cu2—S6^vii	121.533 (13)	Ag3^xiv—S10—Ag3cu^xiv	0
Ag7^vii—Cu2—Ag7	68.524 (18)	Ag3^xiv—S10—Ag3cu^xv	78.91 (15)
Ag7^vii—Cu2—Ag7^v	153.08 (3)	Ag3^xiv—S10—S10^v	54.5 (8)
Ag7^vii—Cu2—Ag7ⁱⁱⁱ	107.16 (2)	Ag3^xiv—S10—S10ⁱⁱⁱ	101.4 (9)
Ag7^vii—Cu2—Ag7^x	95.15 (2)	Ag3^xv—S10—Ag3	164.7 (3)
Ag7^vii—Cu2—Ag7^xi	95.15 (2)	Ag3^xv—S10—Ag3^v	79.44 (19)
Ag7^vii—Cu2—S6	121.533 (12)	Ag3^xv—S10—Ag3^iv	85.5 (2)
Ag7^vii—Cu2—S6^vii	58.467 (12)	Ag3^xv—S10—Ag3ⁱⁱⁱ	81.5 (3)
Ag7ⁱⁱⁱ—Cu2—Ag7	95.15 (2)	Ag3^xv—S10—Ag3^xiv	78.91 (16)
Ag7ⁱⁱⁱ—Cu2—Ag7^v	95.15 (3)	Ag3^xv—S10—Ag3cu	164.7 (3)
Ag7ⁱⁱⁱ—Cu2—Ag7^vii	107.16 (2)	Ag3^xv—S10—Ag3cu^v	79.44 (18)
Ag7ⁱⁱⁱ—Cu2—Ag7^x	153.08 (2)	Ag3^xv—S10—Ag3cu^iv	85.5 (2)
Ag7ⁱⁱⁱ—Cu2—Ag7^xi	68.52 (2)	Ag3^xv—S10—Ag3cuⁱⁱⁱ	81.5 (3)
Ag7ⁱⁱⁱ—Cu2—S6	58.467 (15)	Ag3^xv—S10—Ag3cu^xiv	78.91 (15)
Ag7ⁱⁱⁱ—Cu2—S6^vii	121.533 (15)	Ag3^xv—S10—Ag3cu^xv	0
Ag7^x—Cu2—Ag7	107.16 (2)	Ag3^xv—S10—S10^v	61.1 (9)
Ag7^x—Cu2—Ag7^v	68.52 (2)	Ag3^xv—S10—S10ⁱⁱⁱ	31.90 (15)
Ag7^x—Cu2—Ag7^vii	95.15 (2)	Ag3cu—S10—Ag3cu^v	85.5 (2)
Ag7^x—Cu2—Ag7ⁱⁱⁱ	153.08 (2)	Ag3cu—S10—Ag3cu^iv	109.7 (3)
Ag7^x—Cu2—Ag7^xi	95.15 (3)	Ag3cu—S10—Ag3cuⁱⁱⁱ	93.49 (14)
Ag7^x—Cu2—S6	121.533 (15)	Ag3cu—S10—Ag3cu^xiv	101.1 (4)
Ag7^x—Cu2—S6^vii	58.467 (15)	Ag3cu—S10—Ag3cu^xv	164.7 (3)
Ag7^xi—Cu2—Ag7	153.08 (3)	Ag3cu—S10—S10^v	106.3 (9)
Ag7^xi—Cu2—Ag7^v	107.16 (2)	Ag3cu—S10—S10ⁱⁱⁱ	135.77 (19)
Ag7^xi—Cu2—Ag7^vii	95.15 (2)	Ag3cu^v—S10—Ag3cu	85.5 (2)
Ag7^xi—Cu2—Ag7ⁱⁱⁱ	68.52 (2)	Ag3cu^v—S10—Ag3cu^iv	164.7 (3)
Ag7^xi—Cu2—Ag7^x	95.15 (3)	Ag3cu^v—S10—Ag3cuⁱⁱⁱ	78.91 (14)
Ag7^xi—Cu2—S6	121.533 (13)	Ag3cu^v—S10—Ag3cu^xiv	81.5 (3)
Ag7^xi—Cu2—S6^vii	58.467 (13)	Ag3cu^v—S10—Ag3cu^xv	79.44 (17)
S6—Cu2—S6^vii	180	Ag3cu^v—S10—S10^v	31.90 (15)
S6^vii—Cu2—S6	180	Ag3cu^v—S10—S10ⁱⁱⁱ	61.1 (9)
Sb1—S1—Ag1	102.21 (6)	Ag3cu^iv—S10—Ag3cu	109.7 (3)
Sb1—S1—Ag2	101.31 (8)	Ag3cu^iv—S10—Ag3cu^v	164.7 (3)
Sb1—S1—Ag2cu	101.31 (8)	Ag3cu^iv—S10—Ag3cuⁱⁱⁱ	101.1 (4)
Sb1—S1—Ag5	108.73 (6)	Ag3cu^iv—S10—Ag3cu^xiv	93.49 (14)
Ag1—S1—Ag2	114.28 (7)	Ag3cu^iv—S10—Ag3cu^xv	85.5 (2)
Ag1—S1—Ag2cu	114.28 (6)	Ag3cu^iv—S10—S10^v	135.77 (19)
Ag1—S1—Ag5	101.10 (8)	Ag3cu^iv—S10—S10ⁱⁱⁱ	106.3 (9)
Ag2—S1—Ag2cu	0	Ag3cuⁱⁱⁱ—S10—Ag3cu	93.49 (14)
Ag2—S1—Ag5	126.80 (7)	Ag3cuⁱⁱⁱ—S10—Ag3cu^v	78.91 (14)
Ag2cu—S1—Ag5	126.80 (7)	Ag3cuⁱⁱⁱ—S10—Ag3cu^iv	101.1 (4)
Sb2^v—S2—Ag2	100.30 (8)	Ag3cuⁱⁱⁱ—S10—Ag3cu^xiv	154.5 (3)
Sb2^v—S2—Ag2cu	100.30 (8)	Ag3cuⁱⁱⁱ—S10—Ag3cu^xv	81.5 (3)
Sb2^v—S2—Ag3	100.21 (7)	Ag3cuⁱⁱⁱ—S10—S10^v	101.4 (9)
Sb2^v—S2—Ag3cu	100.21 (6)	Ag3cuⁱⁱⁱ—S10—S10ⁱⁱⁱ	54.5 (8)
Sb2^v—S2—Ag6^v	102.21 (7)	Ag3cu^xiv—S10—Ag3cu	101.1 (4)
Ag2—S2—Ag2cu	0	Ag3cu^xiv—S10—Ag3cu^v	81.5 (3)
Ag2—S2—Ag3	110.65 (7)	Ag3cu^xiv—S10—Ag3cu^iv	93.49 (14)
Ag2—S2—Ag3cu	110.65 (6)	Ag3cu^xiv—S10—Ag3cuⁱⁱⁱ	154.5 (3)
Ag2—S2—Ag6^v	119.51 (10)	Ag3cu^xiv—S10—Ag3cu^xv	78.91 (14)
Ag2cu—S2—Ag3	110.65 (7)	Ag3cu^xiv—S10—S10^v	54.5 (8)
Ag2cu—S2—Ag3cu	110.65 (6)	Ag3cu^xiv—S10—S10ⁱⁱⁱ	101.4 (9)
Ag2cu—S2—Ag6^v	119.51 (9)	Ag3cu^xv—S10—Ag3cu	164.7 (3)
Ag3—S2—Ag3cu	0	Ag3cu^xv—S10—Ag3cu^v	79.44 (17)
Ag3—S2—Ag6^v	119.23 (11)	Ag3cu^xv—S10—Ag3cu^iv	85.5 (2)
Ag3cu—S2—Ag6^v	119.23 (10)	Ag3cu^xv—S10—Ag3cuⁱⁱⁱ	81.5 (3)
Sb2—S3—Ag1	104.20 (7)	Ag3cu^xv—S10—Ag3cu^xiv	78.91 (14)
Sb2—S3—Ag3	102.02 (8)	Ag3cu^xv—S10—S10^v	61.1 (9)
Sb2—S3—Ag3cu	102.02 (6)	Ag3cu^xv—S10—S10ⁱⁱⁱ	31.90 (15)
Sb2—S3—Ag7	122.88 (8)	S10^v—S10—S10ⁱⁱⁱ	60.0 (14)
Sb2—S3—Ag10	96.78 (9)	S10ⁱⁱⁱ—S10—S10^v	60.0 (14)
Ag1—S3—Ag3	119.29 (10)

Selected geometric parameters (Å, º) for (polybasite222) top

Sb1—S1	2.408 (2)	Ag14—S19^viii	2.562 (2)
Sb1—S2	2.413 (2)	Ag15—S7	2.414 (2)
Sb1—S3	2.426 (2)	Ag15—S19^viii	2.3992 (19)
Sb2—S4	2.409 (2)	Ag16—Cu1	2.9514 (8)
Sb2—S5	2.432 (2)	Ag16—S1	2.594 (2)
Sb2—S6	2.421 (2)	Ag16—S15	2.840 (2)
Sb3—S7	2.453 (2)	Ag16—S17	2.798 (2)
Sb3—S8	2.412 (2)	Ag16—S22^viii	2.6115 (19)
Sb3—S12ⁱ	2.411 (2)	Ag17—S3	2.614 (2)
Sb4—S9	2.439 (2)	Ag17—S16	2.685 (2)
Sb4—S10	2.430 (2)	Ag17—S18	2.923 (2)
Sb4—S11	2.416 (2)	Ag17—S22^viii	2.5872 (18)
Ag1—S1	2.520 (2)	Ag18—Cu2^ix	2.8402 (8)
Ag1—S10ⁱⁱ	2.556 (2)	Ag18—S8	2.849 (2)
Ag1—S14ⁱⁱ	2.569 (3)	Ag18—S18	2.460 (2)
Ag2—S2	2.461 (2)	Ag18—S21^ix	2.477 (2)
Ag2—S7ⁱⁱⁱ	2.584 (2)	Ag19—Cu1	2.7899 (12)
Ag2—S14ⁱⁱ	2.489 (3)	Ag19—S17	2.490 (2)
Ag2—S17	2.953 (2)	Ag19—S19	2.4363 (19)
Ag3—Ag3cu	0	Ag20—S2	2.600 (2)
Ag3—Ag23	2.9324 (18)	Ag20—S19	2.8674 (19)
Ag3—S4	2.429 (3)	Ag20—S20	2.723 (2)
Ag3—S7ⁱⁱⁱ	2.408 (3)	Ag20—S22^viii	2.5463 (17)
Ag3—S14^iv	2.381 (3)	Ag21—Ag29^viii	2.9757 (12)
Ag3cu—Ag23	2.9324 (7)	Ag21—Cu3	2.7976 (12)
Ag3cu—S4	2.429 (2)	Ag21—S18	2.4277 (19)
Ag3cu—S7ⁱⁱⁱ	2.408 (2)	Ag21—S20	2.483 (2)
Ag3cu—S14^iv	2.381 (3)	Ag22—S9	2.442 (2)
Ag4—S5	2.598 (2)	Ag22—S15^x	2.410 (2)
Ag4—S10ⁱⁱⁱ	2.492 (2)	Ag23—Cu2	2.7752 (12)
Ag4—S14^iv	2.513 (3)	Ag23—S19	2.4395 (19)
Ag5—Ag13	2.9994 (10)	Ag23—S21	2.484 (2)
Ag5—S1	2.450 (2)	Ag24—Cu3	2.8444 (19)
Ag5—S5ⁱ	2.470 (2)	Ag24—S4	2.607 (3)
Ag5—S13	2.474 (2)	Ag24—S18^x	2.523 (2)
Ag5—S16	2.959 (2)	Ag24—S20	2.654 (3)
Ag6—Ag7^v	2.9364 (9)	Ag25—Cu3	2.7639 (13)
Ag6—Ag10^iv	2.9879 (9)	Ag25—S11	2.659 (2)
Ag6—S2	2.531 (2)	Ag25—S20	2.537 (2)
Ag6—S4	2.530 (2)	Ag25—S22	2.5240 (18)
Ag6—S13^v	2.562 (2)	Ag26—Cu1^xi	2.8588 (13)
Ag7—S3	2.548 (2)	Ag26—S10	2.745 (2)
Ag7—S8	2.513 (2)	Ag26—S11	2.911 (2)
Ag7—S13	2.566 (2)	Ag26—S15^x	2.529 (2)
Ag8—S3	2.466 (2)	Ag26—S17^xi	2.611 (2)
Ag8—S9	2.614 (2)	Ag27—Cu2	2.7999 (14)
Ag8—S13^v	2.496 (2)	Ag27—S10ⁱⁱⁱ	2.846 (2)
Ag9—S6	2.443 (3)	Ag27—S15^vi	2.465 (2)
Ag9—S11	2.611 (3)	Ag27—S21	2.506 (2)
Ag9—S13^v	2.482 (3)	Ag28—S5	2.424 (3)
Ag10—S6	2.577 (2)	Ag28—S18^x	2.420 (2)
Ag10—S12	2.499 (2)	Ag29—Cu3^x	2.7932 (14)
Ag10—S13^vi	2.535 (2)	Ag29—S6	2.587 (2)
Ag11—S8	2.579 (2)	Ag29—S16^vi	2.584 (2)
Ag11—S9	2.516 (2)	Ag29—S22	2.568 (2)
Ag11—S14^vii	2.536 (3)	Ag30—Cu1^xi	2.8319 (8)
Ag12—S11	2.453 (3)	Ag30—S12	2.688 (2)
Ag12—S12	2.525 (3)	Ag30—S17^xi	2.544 (2)
Ag12—S14	2.481 (3)	Ag30—S22	2.544 (2)
Ag13—Cu3^viii	2.7829 (12)	Cu1—S17	2.1572 (17)
Ag13—S15	2.425 (2)	Cu1—S17^xii	2.1572 (17)
Ag13—S16	2.488 (2)	Cu2—S21	2.1549 (16)
Ag14—Cu3^viii	2.8760 (19)	Cu2—S21^xii	2.1549 (16)
Ag14—S8	2.707 (3)	Cu3—S16^x	2.171 (2)
Ag14—S12ⁱ	2.964 (3)	Cu3—S20	2.164 (2)
Ag14—S16	2.628 (3)

S1—Sb1—S2	95.96 (7)	Ag23—Cu2—S21^xii	116.95 (7)
S1—Sb1—S3	97.20 (7)	Ag23^xii—Cu2—Ag23	97.68 (5)
S2—Sb1—S3	95.66 (7)	Ag23^xii—Cu2—Ag27	155.40 (3)
S4—Sb2—S5	96.97 (7)	Ag23^xii—Cu2—Ag27^xii	99.18 (2)
S4—Sb2—S6	93.57 (7)	Ag23^xii—Cu2—S21	116.95 (7)
S5—Sb2—S6	97.67 (7)	Ag23^xii—Cu2—S21^xii	58.91 (6)
S7—Sb3—S8	97.18 (7)	Ag27—Cu2—Ag27^xii	71.41 (4)
S7—Sb3—S12ⁱ	96.46 (7)	Ag27—Cu2—S21	59.05 (6)
S8—Sb3—S12ⁱ	92.68 (7)	Ag27—Cu2—S21^xii	126.30 (8)
S9—Sb4—S10	96.68 (7)	Ag27^xii—Cu2—Ag27	71.41 (4)
S9—Sb4—S11	96.93 (7)	Ag27^xii—Cu2—S21	126.30 (8)
S10—Sb4—S11	92.21 (7)	Ag27^xii—Cu2—S21^xii	59.05 (6)
S1—Ag1—S10ⁱⁱ	98.31 (7)	S21—Cu2—S21^xii	174.51 (11)
S1—Ag1—S14ⁱⁱ	131.52 (8)	S21^xii—Cu2—S21	174.51 (11)
S10ⁱⁱ—Ag1—S14ⁱⁱ	128.93 (8)	Ag13^x—Cu3—Ag14^x	119.38 (5)
S2—Ag2—S7ⁱⁱⁱ	106.41 (7)	Ag13^x—Cu3—Ag21	76.12 (3)
S2—Ag2—S14ⁱⁱ	140.17 (9)	Ag13^x—Cu3—Ag24	133.27 (5)
S2—Ag2—S17	103.71 (7)	Ag13^x—Cu3—Ag25	67.54 (3)
S7ⁱⁱⁱ—Ag2—S14ⁱⁱ	110.41 (8)	Ag13^x—Cu3—Ag29^viii	76.70 (4)
S7ⁱⁱⁱ—Ag2—S17	91.94 (6)	Ag13^x—Cu3—S16^x	58.75 (6)
S14ⁱⁱ—Ag2—S17	89.86 (7)	Ag13^x—Cu3—S20	111.31 (7)
Ag3cu—Ag3—Ag23	0	Ag14^x—Cu3—Ag21	136.69 (6)
Ag3cu—Ag3—S4	0	Ag14^x—Cu3—Ag24	80.07 (6)
Ag3cu—Ag3—S7ⁱⁱⁱ	0	Ag14^x—Cu3—Ag25	137.88 (6)
Ag3cu—Ag3—S14^iv	0	Ag14^x—Cu3—Ag29^viii	79.58 (5)
Ag23—Ag3—S4	70.31 (6)	Ag14^x—Cu3—S16^x	60.86 (7)
Ag23—Ag3—S7ⁱⁱⁱ	77.65 (7)	Ag14^x—Cu3—S20	129.18 (7)
Ag23—Ag3—S14^iv	136.97 (10)	Ag21—Cu3—Ag24	120.40 (5)
S4—Ag3—S7ⁱⁱⁱ	115.27 (10)	Ag21—Cu3—Ag25	85.07 (3)
S4—Ag3—S14^iv	117.87 (11)	Ag21—Cu3—Ag29^viii	64.32 (3)
S7ⁱⁱⁱ—Ag3—S14^iv	123.89 (11)	Ag21—Cu3—S16^x	114.57 (7)
Ag3—Ag3cu—Ag23	0	Ag21—Cu3—S20	58.40 (6)
Ag3—Ag3cu—S4	0	Ag24—Cu3—Ag25	70.78 (4)
Ag3—Ag3cu—S7ⁱⁱⁱ	0	Ag24—Cu3—Ag29^viii	149.68 (6)
Ag3—Ag3cu—S14^iv	0	Ag24—Cu3—S16^x	124.99 (7)
Ag23—Ag3cu—S4	70.31 (5)	Ag24—Cu3—S20	62.26 (6)
Ag23—Ag3cu—S7ⁱⁱⁱ	77.65 (5)	Ag25—Cu3—Ag29^viii	137.60 (5)
Ag23—Ag3cu—S14^iv	136.97 (6)	Ag25—Cu3—S16^x	113.47 (7)
S4—Ag3cu—S7ⁱⁱⁱ	115.27 (7)	Ag25—Cu3—S20	60.52 (6)
S4—Ag3cu—S14^iv	117.87 (8)	Ag29^viii—Cu3—S16^x	61.23 (6)
S7ⁱⁱⁱ—Ag3cu—S14^iv	123.89 (8)	Ag29^viii—Cu3—S20	116.80 (7)
S5—Ag4—S10ⁱⁱⁱ	100.03 (7)	S16^x—Cu3—S20	169.92 (9)
S5—Ag4—S14^iv	114.30 (8)	Sb1—S1—Ag1	100.87 (7)
S10ⁱⁱⁱ—Ag4—S14^iv	145.66 (9)	Sb1—S1—Ag5	101.34 (8)
Ag13—Ag5—S1	77.87 (5)	Sb1—S1—Ag16	113.89 (8)
Ag13—Ag5—S5ⁱ	75.41 (5)	Ag1—S1—Ag5	112.85 (8)
Ag13—Ag5—S13	138.46 (6)	Ag1—S1—Ag16	103.50 (7)
Ag13—Ag5—S16	49.35 (4)	Ag5—S1—Ag16	122.59 (8)
S1—Ag5—S5ⁱ	116.34 (7)	Sb1—S2—Ag2	98.35 (7)
S1—Ag5—S13	119.81 (8)	Sb1—S2—Ag6	105.09 (8)
S1—Ag5—S16	101.45 (6)	Sb1—S2—Ag20	105.69 (7)
S5ⁱ—Ag5—S13	118.50 (8)	Ag2—S2—Ag6	120.04 (8)
S5ⁱ—Ag5—S16	102.65 (6)	Ag2—S2—Ag20	125.41 (8)
S13—Ag5—S16	89.21 (6)	Ag6—S2—Ag20	99.97 (7)
Ag7^v—Ag6—Ag10^iv	61.48 (2)	Sb1—S3—Ag7	102.06 (7)
Ag7^v—Ag6—S2	92.04 (5)	Sb1—S3—Ag8	97.70 (7)
Ag7^v—Ag6—S4	147.92 (5)	Sb1—S3—Ag17	107.54 (7)
Ag7^v—Ag6—S13^v	55.14 (5)	Ag7—S3—Ag8	112.44 (8)
Ag10^iv—Ag6—S2	145.28 (5)	Ag7—S3—Ag17	100.25 (7)
Ag10^iv—Ag6—S4	95.55 (5)	Ag8—S3—Ag17	133.13 (8)
Ag10^iv—Ag6—S13^v	53.69 (5)	Sb2—S4—Ag3	104.22 (9)
S2—Ag6—S4	97.55 (7)	Sb2—S4—Ag3cu	104.22 (8)
S2—Ag6—S13^v	130.31 (7)	Sb2—S4—Ag6	105.45 (8)
S4—Ag6—S13^v	130.60 (7)	Sb2—S4—Ag24	101.63 (8)
Ag6^v—Ag7—S3	149.16 (5)	Ag3—S4—Ag3cu	0
Ag6^v—Ag7—S8	96.45 (5)	Ag3—S4—Ag6	115.85 (9)
Ag6^v—Ag7—S13	55.00 (5)	Ag3—S4—Ag24	131.59 (10)
S3—Ag7—S8	101.66 (7)	Ag3cu—S4—Ag6	115.85 (8)
S3—Ag7—S13	113.80 (7)	Ag3cu—S4—Ag24	131.59 (9)
S8—Ag7—S13	144.09 (7)	Ag6—S4—Ag24	95.24 (8)
S3—Ag8—S9	106.42 (7)	Sb2—S5—Ag4	100.50 (7)
S3—Ag8—S13^v	143.90 (7)	Sb2—S5—Ag5^vi	99.88 (8)
S9—Ag8—S13^v	108.06 (7)	Sb2—S5—Ag28	102.76 (8)
S6—Ag9—S11	110.98 (9)	Ag4—S5—Ag5^vi	109.79 (8)
S6—Ag9—S13^v	139.03 (10)	Ag4—S5—Ag28	122.56 (9)
S11—Ag9—S13^v	109.92 (9)	Ag5^vi—S5—Ag28	116.69 (9)
Ag6^iv—Ag10—S6	143.97 (5)	Sb2—S6—Ag9	103.27 (8)
Ag6^iv—Ag10—S12	98.64 (5)	Sb2—S6—Ag10	101.68 (7)
Ag6^iv—Ag10—S13^vi	54.54 (5)	Sb2—S6—Ag29	123.01 (9)
S6—Ag10—S12	101.38 (7)	Ag9—S6—Ag10	111.22 (9)
S6—Ag10—S13^vi	112.81 (7)	Ag9—S6—Ag29	128.78 (10)
S12—Ag10—S13^vi	145.68 (7)	Ag10—S6—Ag29	81.68 (6)
S8—Ag11—S9	99.53 (7)	Sb3—S7—Ag2^ix	99.02 (7)
S8—Ag11—S14^vii	116.98 (8)	Sb3—S7—Ag3^ix	102.27 (8)
S9—Ag11—S14^vii	143.48 (8)	Sb3—S7—Ag3cu^ix	102.27 (7)
S11—Ag12—S12	112.53 (10)	Sb3—S7—Ag15	101.72 (8)
S11—Ag12—S14	136.48 (11)	Ag2^ix—S7—Ag3^ix	108.38 (9)
S12—Ag12—S14	110.36 (10)	Ag2^ix—S7—Ag3cu^ix	108.38 (8)
Ag5—Ag13—Cu3^viii	112.69 (3)	Ag2^ix—S7—Ag15	122.76 (8)
Ag5—Ag13—S15	106.60 (5)	Ag3^ix—S7—Ag3cu^ix	0
Ag5—Ag13—S16	64.49 (5)	Ag3^ix—S7—Ag15	118.08 (9)
Cu3^viii—Ag13—S15	140.31 (6)	Ag3cu^ix—S7—Ag15	118.08 (8)
Cu3^viii—Ag13—S16	48.25 (5)	Sb3—S8—Ag7	103.17 (7)
S15—Ag13—S16	168.37 (7)	Sb3—S8—Ag11	103.08 (7)
Cu3^viii—Ag14—S8	142.24 (8)	Sb3—S8—Ag14	96.19 (8)
Cu3^viii—Ag14—S12ⁱ	120.38 (8)	Sb3—S8—Ag18	124.90 (8)
Cu3^viii—Ag14—S16	46.20 (5)	Ag7—S8—Ag11	119.10 (8)
Cu3^viii—Ag14—S19^viii	84.10 (7)	Ag7—S8—Ag14	85.39 (7)
S8—Ag14—S12ⁱ	75.79 (7)	Ag7—S8—Ag18	127.48 (8)
S8—Ag14—S16	103.20 (8)	Ag11—S8—Ag14	143.47 (9)
S8—Ag14—S19^viii	125.78 (9)	Ag11—S8—Ag18	72.63 (5)
S12ⁱ—Ag14—S16	93.98 (8)	Ag14—S8—Ag18	70.89 (6)
S12ⁱ—Ag14—S19^viii	107.84 (9)	Sb4—S9—Ag8	98.93 (7)
S16—Ag14—S19^viii	129.56 (9)	Sb4—S9—Ag11	100.57 (7)
S7—Ag15—S19^viii	159.95 (7)	Sb4—S9—Ag22	99.67 (7)
Cu1—Ag16—S1	127.89 (5)	Ag8—S9—Ag11	114.37 (8)
Cu1—Ag16—S15	83.50 (5)	Ag8—S9—Ag22	120.46 (8)
Cu1—Ag16—S17	43.97 (4)	Ag11—S9—Ag22	116.79 (8)
Cu1—Ag16—S22^viii	105.81 (5)	Sb4—S10—Ag1^xi	103.68 (7)
S1—Ag16—S15	90.26 (6)	Sb4—S10—Ag4^ix	100.82 (7)
S1—Ag16—S17	86.50 (6)	Sb4—S10—Ag26	95.80 (7)
S1—Ag16—S22^viii	124.52 (6)	Sb4—S10—Ag27^ix	121.98 (8)
S15—Ag16—S17	97.98 (6)	Ag1^xi—S10—Ag4^ix	120.65 (8)
S15—Ag16—S22^viii	110.59 (6)	Ag1^xi—S10—Ag26	88.70 (6)
S17—Ag16—S22^viii	136.12 (6)	Ag1^xi—S10—Ag27^ix	130.06 (8)
S3—Ag17—S16	90.06 (6)	Ag4^ix—S10—Ag26	140.88 (8)
S3—Ag17—S18	85.98 (6)	Ag4^ix—S10—Ag27^ix	72.15 (5)
S3—Ag17—S22^viii	123.08 (6)	Ag26—S10—Ag27^ix	68.99 (5)
S16—Ag17—S18	95.94 (6)	Sb4—S11—Ag9	96.55 (8)
S16—Ag17—S22^viii	143.07 (6)	Sb4—S11—Ag12	99.55 (9)
S18—Ag17—S22^viii	101.70 (6)	Sb4—S11—Ag25	131.42 (8)
Cu2^ix—Ag18—S8	143.49 (5)	Sb4—S11—Ag26	91.95 (7)
Cu2^ix—Ag18—S18	120.22 (5)	Ag9—S11—Ag12	96.38 (9)
Cu2^ix—Ag18—S21^ix	47.21 (4)	Ag9—S11—Ag25	70.62 (6)
S8—Ag18—S18	95.70 (6)	Ag9—S11—Ag26	165.75 (9)
S8—Ag18—S21^ix	100.60 (6)	Ag12—S11—Ag25	127.75 (9)
S18—Ag18—S21^ix	158.10 (7)	Ag12—S11—Ag26	93.46 (8)
Cu1—Ag19—S17	47.81 (4)	Ag25—S11—Ag26	95.19 (7)
Cu1—Ag19—S19	135.15 (5)	Sb3^vi—S12—Ag10	102.29 (8)
S17—Ag19—S19	176.77 (7)	Sb3^vi—S12—Ag12	100.87 (9)
S2—Ag20—S19	92.07 (6)	Sb3^vi—S12—Ag14^vi	89.83 (7)
S2—Ag20—S20	89.67 (6)	Sb3^vi—S12—Ag30	122.43 (9)
S2—Ag20—S22^viii	131.64 (6)	Ag10—S12—Ag12	108.35 (9)
S19—Ag20—S20	93.89 (6)	Ag10—S12—Ag14^vi	87.30 (7)
S19—Ag20—S22^viii	100.87 (6)	Ag10—S12—Ag30	134.70 (9)
S20—Ag20—S22^viii	134.77 (6)	Ag12—S12—Ag14^vi	158.37 (10)
Ag29^viii—Ag21—Cu3	57.77 (3)	Ag12—S12—Ag30	72.28 (7)
Ag29^viii—Ag21—S18	78.15 (5)	Ag14^vi—S12—Ag30	86.11 (7)
Ag29^viii—Ag21—S20	101.38 (5)	Ag5—S13—Ag6^v	159.60 (10)
Cu3—Ag21—S18	133.94 (5)	Ag5—S13—Ag7	93.13 (7)
Cu3—Ag21—S20	47.94 (5)	Ag5—S13—Ag8^v	111.32 (9)
S18—Ag21—S20	173.26 (7)	Ag5—S13—Ag9^v	112.43 (9)
S9—Ag22—S15^x	158.74 (7)	Ag5—S13—Ag10ⁱ	92.91 (7)
Ag3—Ag23—Ag3cu	0	Ag6^v—S13—Ag7	69.86 (6)
Ag3—Ag23—Cu2	114.65 (4)	Ag6^v—S13—Ag8^v	79.10 (7)
Ag3—Ag23—S19	112.70 (6)	Ag6^v—S13—Ag9^v	81.70 (7)
Ag3—Ag23—S21	67.00 (5)	Ag6^v—S13—Ag10ⁱ	71.77 (6)
Ag3cu—Ag23—Cu2	114.65 (2)	Ag7—S13—Ag8^v	84.45 (7)
Ag3cu—Ag23—S19	112.70 (5)	Ag7—S13—Ag9^v	150.08 (10)
Ag3cu—Ag23—S21	67.00 (4)	Ag7—S13—Ag10ⁱ	72.83 (6)
Cu2—Ag23—S19	128.75 (5)	Ag8^v—S13—Ag9^v	99.52 (8)
Cu2—Ag23—S21	47.98 (4)	Ag8^v—S13—Ag10ⁱ	147.72 (9)
S19—Ag23—S21	166.73 (7)	Ag9^v—S13—Ag10ⁱ	89.92 (8)
Cu3—Ag24—S4	135.10 (8)	Ag1^xi—S14—Ag2^xi	77.92 (8)
Cu3—Ag24—S18^x	90.18 (6)	Ag1^xi—S14—Ag3^iv	162.68 (13)
Cu3—Ag24—S20	46.20 (5)	Ag1^xi—S14—Ag3cu^iv	162.68 (12)
S4—Ag24—S18^x	130.43 (9)	Ag1^xi—S14—Ag4^iv	72.70 (8)
S4—Ag24—S20	94.44 (8)	Ag1^xi—S14—Ag11^vii	74.40 (8)
S18^x—Ag24—S20	134.85 (9)	Ag1^xi—S14—Ag12	85.27 (9)
Cu3—Ag25—S11	145.89 (6)	Ag2^xi—S14—Ag3^iv	111.54 (12)
Cu3—Ag25—S20	47.96 (5)	Ag2^xi—S14—Ag3cu^iv	111.54 (11)
Cu3—Ag25—S22	117.48 (5)	Ag2^xi—S14—Ag4^iv	147.94 (13)
S11—Ag25—S20	105.18 (6)	Ag2^xi—S14—Ag11^vii	86.38 (10)
S11—Ag25—S22	95.58 (6)	Ag2^xi—S14—Ag12	99.43 (10)
S20—Ag25—S22	151.74 (7)	Ag3^iv—S14—Ag3cu^iv	0
Cu1^xi—Ag26—S10	138.40 (5)	Ag3^iv—S14—Ag4^iv	94.15 (10)
Cu1^xi—Ag26—S11	119.84 (5)	Ag3^iv—S14—Ag11^vii	91.33 (10)
Cu1^xi—Ag26—S15^x	91.23 (5)	Ag3^iv—S14—Ag12	106.59 (13)
Cu1^xi—Ag26—S17^xi	46.18 (4)	Ag3cu^iv—S14—Ag4^iv	94.15 (9)
S10—Ag26—S11	76.19 (6)	Ag3cu^iv—S14—Ag11^vii	91.33 (9)
S10—Ag26—S15^x	124.28 (6)	Ag3cu^iv—S14—Ag12	106.59 (12)
S10—Ag26—S17^xi	98.45 (6)	Ag4^iv—S14—Ag11^vii	73.73 (8)
S11—Ag26—S15^x	103.07 (7)	Ag4^iv—S14—Ag12	90.77 (10)
S11—Ag26—S17^xi	94.07 (6)	Ag11^vii—S14—Ag12	157.27 (13)
S15^x—Ag26—S17^xi	136.48 (6)	Ag13—S15—Ag16	77.22 (6)
Cu2—Ag27—S10ⁱⁱⁱ	147.16 (5)	Ag13—S15—Ag22^viii	82.09 (6)
Cu2—Ag27—S15^vi	114.84 (5)	Ag13—S15—Ag26^viii	129.83 (8)
Cu2—Ag27—S21	47.53 (4)	Ag13—S15—Ag27ⁱ	110.50 (8)
S10ⁱⁱⁱ—Ag27—S15^vi	97.20 (6)	Ag16—S15—Ag22^viii	133.49 (8)
S10ⁱⁱⁱ—Ag27—S21	105.12 (6)	Ag16—S15—Ag26^viii	84.15 (6)
S15^vi—Ag27—S21	152.02 (7)	Ag16—S15—Ag27ⁱ	132.11 (8)
S5—Ag28—S18^x	157.70 (10)	Ag22^viii—S15—Ag26^viii	77.97 (6)
Ag21^x—Ag29—Cu3^x	57.91 (3)	Ag22^viii—S15—Ag27ⁱ	94.10 (7)
Ag21^x—Ag29—S6	140.99 (7)	Ag26^viii—S15—Ag27ⁱ	116.42 (8)
Ag21^x—Ag29—S16^vi	97.69 (5)	Ag5—S16—Ag13	66.16 (5)
Ag21^x—Ag29—S22	91.01 (5)	Ag5—S16—Ag14	147.96 (8)
Cu3^x—Ag29—S6	150.23 (6)	Ag5—S16—Ag17	93.33 (6)
Cu3^x—Ag29—S16^vi	47.43 (5)	Ag5—S16—Ag29ⁱ	102.48 (7)
Cu3^x—Ag29—S22	103.52 (6)	Ag5—S16—Cu3^viii	139.07 (9)
S6—Ag29—S16^vi	102.84 (7)	Ag13—S16—Ag14	145.51 (9)
S6—Ag29—S22	99.20 (7)	Ag13—S16—Ag17	71.52 (5)
S16^vi—Ag29—S22	131.78 (8)	Ag13—S16—Ag29ⁱ	85.99 (7)
Cu1^xi—Ag30—S12	152.18 (5)	Ag13—S16—Cu3^viii	73.00 (6)
Cu1^xi—Ag30—S17^xi	46.94 (4)	Ag14—S16—Ag17	94.98 (8)
Cu1^xi—Ag30—S22	111.32 (5)	Ag14—S16—Ag29ⁱ	88.25 (8)
S12—Ag30—S17^xi	108.26 (6)	Ag14—S16—Cu3^viii	72.94 (7)
S12—Ag30—S22	96.47 (6)	Ag17—S16—Ag29ⁱ	144.47 (8)
S17^xi—Ag30—S22	144.12 (7)	Ag17—S16—Cu3^viii	75.86 (6)
Ag16—Cu1—Ag16^xii	153.31 (5)	Ag29ⁱ—S16—Cu3^viii	71.34 (6)
Ag16—Cu1—Ag19	63.39 (2)	Ag2—S17—Ag16	96.13 (6)
Ag16—Cu1—Ag19^xii	142.34 (4)	Ag2—S17—Ag19	69.68 (5)
Ag16—Cu1—Ag26ⁱⁱ	82.78 (3)	Ag2—S17—Ag26ⁱⁱ	143.41 (7)
Ag16—Cu1—Ag26^viii	76.68 (3)	Ag2—S17—Ag30ⁱⁱ	109.16 (7)
Ag16—Cu1—Ag30ⁱⁱ	123.58 (2)	Ag2—S17—Cu1	143.04 (9)
Ag16—Cu1—Ag30^viii	66.68 (2)	Ag16—S17—Ag19	69.36 (5)
Ag16—Cu1—S17	64.24 (6)	Ag16—S17—Ag26ⁱⁱ	90.45 (6)
Ag16—Cu1—S17^xii	117.64 (6)	Ag16—S17—Ag30ⁱⁱ	145.10 (7)
Ag16^xii—Cu1—Ag16	153.31 (5)	Ag16—S17—Cu1	71.79 (6)
Ag16^xii—Cu1—Ag19	142.34 (4)	Ag19—S17—Ag26ⁱⁱ	144.81 (8)
Ag16^xii—Cu1—Ag19^xii	63.39 (2)	Ag19—S17—Ag30ⁱⁱ	96.80 (7)
Ag16^xii—Cu1—Ag26ⁱⁱ	76.68 (3)	Ag19—S17—Cu1	73.39 (6)
Ag16^xii—Cu1—Ag26^viii	82.78 (3)	Ag26ⁱⁱ—S17—Ag30ⁱⁱ	83.41 (7)
Ag16^xii—Cu1—Ag30ⁱⁱ	66.68 (2)	Ag26ⁱⁱ—S17—Cu1	72.98 (6)
Ag16^xii—Cu1—Ag30^viii	123.58 (2)	Ag30ⁱⁱ—S17—Cu1	73.57 (6)
Ag16^xii—Cu1—S17	117.64 (6)	Ag17—S18—Ag18	135.46 (7)
Ag16^xii—Cu1—S17^xii	64.24 (6)	Ag17—S18—Ag21	77.59 (5)
Ag19—Cu1—Ag19^xii	83.76 (4)	Ag17—S18—Ag24^viii	87.05 (7)
Ag19—Cu1—Ag26ⁱⁱ	118.81 (2)	Ag17—S18—Ag28^viii	137.63 (8)
Ag19—Cu1—Ag26^viii	131.81 (2)	Ag18—S18—Ag21	108.54 (7)
Ag19—Cu1—Ag30ⁱⁱ	84.07 (3)	Ag18—S18—Ag24^viii	112.54 (8)
Ag19—Cu1—Ag30^viii	66.20 (3)	Ag18—S18—Ag28^viii	86.81 (7)
Ag19—Cu1—S17	58.79 (6)	Ag21—S18—Ag24^viii	134.06 (9)
Ag19—Cu1—S17^xii	115.06 (7)	Ag21—S18—Ag28^viii	86.95 (7)
Ag19^xii—Cu1—Ag19	83.76 (4)	Ag24^viii—S18—Ag28^viii	75.85 (7)
Ag19^xii—Cu1—Ag26ⁱⁱ	131.81 (2)	Ag14^x—S19—Ag15^x	75.98 (6)
Ag19^xii—Cu1—Ag26^viii	118.81 (2)	Ag14^x—S19—Ag19	131.41 (9)
Ag19^xii—Cu1—Ag30ⁱⁱ	66.20 (3)	Ag14^x—S19—Ag20	92.41 (7)
Ag19^xii—Cu1—Ag30^viii	84.07 (3)	Ag14^x—S19—Ag23	114.34 (8)
Ag19^xii—Cu1—S17	115.06 (7)	Ag15^x—S19—Ag19	81.76 (6)
Ag19^xii—Cu1—S17^xii	58.79 (6)	Ag15^x—S19—Ag20	133.86 (7)
Ag26ⁱⁱ—Cu1—Ag26^viii	79.06 (4)	Ag15^x—S19—Ag23	86.31 (6)
Ag26ⁱⁱ—Cu1—Ag30ⁱⁱ	74.13 (3)	Ag19—S19—Ag20	73.06 (5)
Ag26ⁱⁱ—Cu1—Ag30^viii	143.00 (4)	Ag19—S19—Ag23	106.55 (7)
Ag26ⁱⁱ—Cu1—S17	60.84 (6)	Ag20—S19—Ag23	137.45 (8)
Ag26ⁱⁱ—Cu1—S17^xii	125.82 (7)	Ag20—S20—Ag21	71.62 (5)
Ag26^viii—Cu1—Ag26ⁱⁱ	79.06 (4)	Ag20—S20—Ag24	93.72 (7)
Ag26^viii—Cu1—Ag30ⁱⁱ	143.00 (4)	Ag20—S20—Ag25	146.44 (8)
Ag26^viii—Cu1—Ag30^viii	74.13 (3)	Ag20—S20—Cu3	74.97 (6)
Ag26^viii—Cu1—S17	125.82 (7)	Ag21—S20—Ag24	144.71 (8)
Ag26^viii—Cu1—S17^xii	60.84 (6)	Ag21—S20—Ag25	96.99 (7)
Ag30ⁱⁱ—Cu1—Ag30^viii	140.19 (6)	Ag21—S20—Cu3	73.66 (6)
Ag30ⁱⁱ—Cu1—S17	59.49 (6)	Ag24—S20—Ag25	77.45 (6)
Ag30ⁱⁱ—Cu1—S17^xii	117.67 (6)	Ag24—S20—Cu3	71.54 (7)
Ag30^viii—Cu1—Ag30ⁱⁱ	140.19 (6)	Ag25—S20—Cu3	71.52 (6)
Ag30^viii—Cu1—S17	117.67 (6)	Ag18ⁱⁱⁱ—S21—Ag23	109.70 (7)
Ag30^viii—Cu1—S17^xii	59.49 (6)	Ag18ⁱⁱⁱ—S21—Ag27	111.50 (8)
S17—Cu1—S17^xii	172.71 (10)	Ag18ⁱⁱⁱ—S21—Cu2	75.28 (6)
S17^xii—Cu1—S17	172.71 (10)	Ag23—S21—Ag27	116.61 (8)
Ag18ⁱⁱⁱ—Cu2—Ag18^x	150.33 (6)	Ag23—S21—Cu2	73.10 (6)
Ag18ⁱⁱⁱ—Cu2—Ag23	92.49 (4)	Ag27—S21—Cu2	73.42 (7)
Ag18ⁱⁱⁱ—Cu2—Ag23^xii	67.64 (3)	Ag16^x—S22—Ag17^x	77.22 (5)
Ag18ⁱⁱⁱ—Cu2—Ag27	93.80 (3)	Ag16^x—S22—Ag20^x	80.40 (5)
Ag18ⁱⁱⁱ—Cu2—Ag27^xii	110.45 (3)	Ag16^x—S22—Ag25	94.39 (6)
Ag18ⁱⁱⁱ—Cu2—S21	57.51 (6)	Ag16^x—S22—Ag29	162.72 (7)
Ag18ⁱⁱⁱ—Cu2—S21^xii	120.84 (6)	Ag16^x—S22—Ag30	76.15 (6)
Ag18^x—Cu2—Ag18ⁱⁱⁱ	150.33 (6)	Ag17^x—S22—Ag20^x	79.52 (5)
Ag18^x—Cu2—Ag23	67.64 (3)	Ag17^x—S22—Ag25	71.94 (5)
Ag18^x—Cu2—Ag23^xii	92.49 (4)	Ag17^x—S22—Ag29	94.91 (7)
Ag18^x—Cu2—Ag27	110.45 (3)	Ag17^x—S22—Ag30	153.07 (8)
Ag18^x—Cu2—Ag27^xii	93.80 (3)	Ag20^x—S22—Ag25	151.43 (8)
Ag18^x—Cu2—S21	120.84 (6)	Ag20^x—S22—Ag29	83.06 (6)
Ag18^x—Cu2—S21^xii	57.51 (6)	Ag20^x—S22—Ag30	99.88 (7)
Ag23—Cu2—Ag23^xii	97.68 (5)	Ag25—S22—Ag29	97.76 (7)
Ag23—Cu2—Ag27	99.18 (2)	Ag25—S22—Ag30	106.14 (7)
Ag23—Cu2—Ag27^xii	155.40 (3)	Ag29—S22—Ag30	111.82 (7)
Ag23—Cu2—S21	58.91 (6)

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