Cis/trans isomers of PtX2L2 (X = halogen, L = neutral ligand); the crystal structures of two polymorphs of cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) in the temperature range 100–295 K

Hansson, C.; Lindqvist, M.; Oskarsson, Å.

doi:10.1107/S0108768108005211

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Cis/trans isomers of PtX₂L₂ (X = halogen, L = neutral ligand); the crystal structures of two polymorphs of cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) in the temperature range 100–295 K

C. Hansson, M. Lindqvist and Å. Oskarsson

The structures of two polymorphs, one triclinic and one monoclinic, of cis-dichlorobis(dibenzyl sulfido-κS)platinum(II), cis-PtCl₂(Bz₂S)₂, have been determined at 295, 250, 200, 150 and 100 K. In both polymorphs the complex has a structure where platinum(II) coordinates two dibenzyl sulfide molecules and two chloro ligands, forming a complex with pseudo-square-planar coordination geometry. The triclinic polymorph shows disorder at all temperatures. Both polymorphs have a packing arrangement involving centrosymmetric structural dimers. cis-PtCl₂(Bz₂S)₂ belongs to a group of complexes with the general formula PtX₂L₂, where X is a halogen and L is a ligand with a donor atom from groups 14, 15 or 16. The distribution of structural classes among 173 cis-PtX₂L₂ compounds found in the Cambridge Structural Database (CSD, Version 5.28, November 2006) has been investigated. The predominant structural class [notation according to Belsky & Zorkii (1977). Acta Cryst. A33, 1004–1006] among the cis compounds is P2₁/c, Z = 4 (1) (73 structures, 42%), followed by $P\bar 1$ , Z = 2 (1) (33 structures, 19%). Inversion centres combined with the screw-axis/glide plane are the dominating packing operators (56%) followed by the inversion centre (21%). The cis and trans influence in cis/trans-PtCl₂L₂ compounds has been investigated using data from the CSD. The cis influence is small for donor atoms in groups 15 and 16. The trans influence is small for group 16 donor atoms and for nitrogen, but for phosphorus it is significantly greater than the other donor atoms studied.

Keywords: polymorphism; packing arrangement; structural classes; structural dimers; static disorder; cis and trans isomerism.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S0108768108005211/ry5016sup1.cif Contains datablocks abtri295, abtri250, abtri200, abtri150, tri100, abmon295, abmon250, abmon200, abmon150, abmon100
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abtri295sup2.hkl Contains datablock abciclbz
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abtri250sup3.hkl Contains datablock abtri250
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abtri200sup4.hkl Contains datablock abtri200
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abtri150sup5.hkl Contains datablock abinstri
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016tri100sup6.hkl Contains datablock tri100
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abmon295sup7.hkl Contains datablock abcbzcl2
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abmon250sup8.hkl Contains datablock abmon250
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abmon200sup9.hkl Contains datablock abmon200
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abmon150sup10.hkl Contains datablock abinsmon
	Structure factor file (CIF format) https://doi.org/10.1107/S0108768108005211/ry5016abmon100sup11.hkl Contains datablock CRYSTALS_cif

CCDC references: 685129; 685130; 685131; 685132; 685133; 685134; 685135; 685136; 685137; 685138

Computing details top

For all compounds, data collection: CrysAlis 1.171.29 (Oxford Diffraction, 2006); cell refinement: CrysAlis 1.171.29 (Oxford Diffraction, 2006); data reduction: CrysAlis 1.171.29 (Oxford Diffraction, 2006); program(s) used to solve structure: SHELXTL 5.1 (Sheldrick, 1998); program(s) used to refine structure: SHELXTL 5.1 (Sheldrick, 1998); molecular graphics: DIAMOND (Brandenburg, 2000), Mercury (Bruno et al., 2002; software used to prepare material for publication: enCIFer version 1.1 (CCDC, 2004).

Figures top

(abtri295) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	Z = 2
M_r = 694.61	F(000) = 680
Triclinic, P1	D_x = 1.613 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.3661 (5) Å	Cell parameters from 14109 reflections
b = 12.2534 (6) Å	θ = 2.8–32.7°
c = 15.8692 (8) Å	µ = 5.25 mm⁻¹
α = 69.052 (5)°	T = 295 K
β = 89.258 (4)°	Prism, yellow
γ = 71.378 (5)°	0.28 × 0.19 × 0.13 mm
V = 1430.29 (15) Å³

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9122 independent reflections
Radiation source: Sealed tube	7325 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.024
ω–scans	θ_max = 32.7°, θ_min = 2.8°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −12→7
T_min = 0.304, T_max = 0.569	k = −17→18
14109 measured reflections	l = −22→23

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.036	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.102	H-atom parameters constrained
S = 0.99	w = 1/[σ²(F_o²) + (0.0642P)²] where P = (F_o² + 2F_c²)/3
9122 reflections	(Δ/σ)_max = 0.010
360 parameters	Δρ_max = 2.23 e Å⁻³
72 restraints	Δρ_min = −1.88 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	γ = 71.378 (5)°
M_r = 694.61	V = 1430.29 (15) Å³
Triclinic, P1	Z = 2
a = 8.3661 (5) Å	Mo Kα radiation
b = 12.2534 (6) Å	µ = 5.25 mm⁻¹
c = 15.8692 (8) Å	T = 295 K
α = 69.052 (5)°	0.28 × 0.19 × 0.13 mm
β = 89.258 (4)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9122 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	7325 reflections with I > 2σ(I)
T_min = 0.304, T_max = 0.569	R_int = 0.024
14109 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.036	72 restraints
wR(F²) = 0.102	H-atom parameters constrained
S = 0.99	Δρ_max = 2.23 e Å⁻³
9122 reflections	Δρ_min = −1.88 e Å⁻³
360 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Pt1	0.585110 (16)	0.908476 (12)	0.766805 (9)	0.04095 (6)
S1	0.85950 (11)	0.90264 (9)	0.77090 (6)	0.03913 (18)
Cl2	0.30900 (13)	0.90808 (12)	0.76500 (9)	0.0611 (3)
Cl1	0.48356 (14)	1.12137 (10)	0.72731 (9)	0.0584 (3)
C11	0.8817 (5)	0.9379 (4)	0.9309 (3)	0.0491 (9)
C1	0.8870 (5)	0.9944 (4)	0.6564 (3)	0.0552 (10)
H1A	0.7915	1.0709	0.6308	0.066*
H1B	0.9906	1.0140	0.6558	0.066*
C23	0.6335 (6)	0.5974 (4)	0.9666 (3)	0.0574 (11)
C4	0.5729 (6)	0.6175 (4)	0.8728 (3)	0.0622 (12)
H4A	0.4522	0.6642	0.8598	0.075*
H4B	0.5905	0.5380	0.8676	0.075*
C12	0.7419 (7)	0.9834 (6)	0.9718 (4)	0.0718 (14)
H12	0.6486	1.0496	0.9362	0.086*
C16	1.0173 (7)	0.8391 (5)	0.9848 (4)	0.0712 (13)
H16	1.1122	0.8062	0.9590	0.085*
C24	0.5473 (8)	0.6783 (5)	1.0072 (4)	0.0762 (14)
H24	0.4525	0.7460	0.9751	0.091*
C28	0.7747 (7)	0.4965 (5)	1.0158 (5)	0.0816 (16)
H28	0.8347	0.4404	0.9902	0.098*
C14	0.8713 (9)	0.8352 (7)	1.1162 (4)	0.0820 (17)
H14	0.8672	0.7999	1.1783	0.098*
C13	0.7392 (9)	0.9325 (7)	1.0634 (5)	0.089 (2)
H13	0.6451	0.9653	1.0897	0.107*
C26	0.7389 (10)	0.5614 (8)	1.1427 (5)	0.094 (2)
H26	0.7747	0.5494	1.2016	0.113*
C25	0.5998 (11)	0.6601 (7)	1.0949 (5)	0.094 (2)
H25	0.5401	0.7153	1.1214	0.113*
C15	1.0118 (10)	0.7884 (6)	1.0782 (5)	0.0903 (19)
H15	1.1041	0.7224	1.1148	0.108*
C27	0.8250 (9)	0.4804 (7)	1.1038 (5)	0.101 (2)
H27	0.9195	0.4131	1.1367	0.121*
S2	0.68809 (14)	0.70264 (9)	0.79049 (8)	0.0481 (2)
C2	0.8867 (5)	0.9994 (4)	0.8310 (3)	0.0509 (9)
H2A	0.9945	1.0129	0.8205	0.061*
H2B	0.7969	1.0795	0.8076	0.061*
C3	0.6021 (8)	0.7026 (5)	0.6847 (4)	0.0706 (14)
H3A	0.4796	0.7246	0.6820	0.085*
H3B	0.6287	0.7632	0.6329	0.085*
C17A	0.6816 (19)	0.5721 (9)	0.6822 (11)	0.074 (4)	0.599 (18)
C18A	0.8503 (19)	0.5306 (11)	0.6667 (11)	0.099 (4)	0.599 (18)
H18A	0.9182	0.5790	0.6628	0.119*	0.599 (18)
C19A	0.9176 (18)	0.4168 (11)	0.6572 (10)	0.131 (6)	0.599 (18)
H19A	1.0305	0.3891	0.6468	0.157*	0.599 (18)
C20A	0.816 (2)	0.3445 (9)	0.6631 (10)	0.132 (8)	0.599 (18)
H20A	0.8612	0.2684	0.6567	0.159*	0.599 (18)
C21A	0.648 (2)	0.3860 (13)	0.6785 (10)	0.128 (7)	0.599 (18)
H21A	0.5797	0.3376	0.6825	0.154*	0.599 (18)
C22A	0.5802 (18)	0.4998 (12)	0.6881 (10)	0.107 (5)	0.599 (18)
H22A	0.4674	0.5276	0.6984	0.128*	0.599 (18)
C17B	0.637 (3)	0.5851 (13)	0.6724 (17)	0.074 (5)	0.401 (18)
C18B	0.804 (3)	0.5108 (18)	0.6758 (16)	0.100 (5)	0.401 (18)
H18B	0.8931	0.5357	0.6863	0.121*	0.401 (18)
C19B	0.837 (3)	0.3994 (17)	0.6633 (14)	0.128 (7)	0.401 (18)
H19B	0.9485	0.3497	0.6655	0.154*	0.401 (18)
C20B	0.704 (4)	0.3621 (16)	0.6475 (16)	0.134 (9)	0.401 (18)
H20B	0.7257	0.2875	0.6392	0.161*	0.401 (18)
C21B	0.537 (3)	0.436 (2)	0.6442 (17)	0.137 (8)	0.401 (18)
H21B	0.4476	0.4115	0.6336	0.164*	0.401 (18)
C22B	0.504 (3)	0.5479 (18)	0.6567 (17)	0.111 (6)	0.401 (18)
H22B	0.3922	0.5976	0.6544	0.133*	0.401 (18)
C5A	0.897 (3)	0.904 (2)	0.6012 (13)	0.045 (4)	0.32 (2)
C6A	1.038 (3)	0.798 (2)	0.6186 (15)	0.078 (5)	0.32 (2)
H6A	1.1213	0.7738	0.6662	0.094*	0.32 (2)
C7A	1.055 (3)	0.728 (2)	0.5649 (18)	0.102 (6)	0.32 (2)
H7A	1.1493	0.6566	0.5765	0.123*	0.32 (2)
C8A	0.931 (4)	0.763 (2)	0.4938 (15)	0.100 (7)	0.32 (2)
H8A	0.9419	0.7165	0.4578	0.120*	0.32 (2)
C9A	0.790 (3)	0.870 (2)	0.4764 (13)	0.069 (5)	0.32 (2)
H9A	0.7064	0.8936	0.4288	0.083*	0.32 (2)
C10A	0.773 (3)	0.940 (2)	0.5301 (13)	0.059 (4)	0.32 (2)
H10A	0.6784	1.0109	0.5184	0.071*	0.32 (2)
C5B	0.8792 (15)	0.9374 (10)	0.5914 (7)	0.052 (2)	0.68 (2)
C6B	1.0136 (13)	0.8338 (10)	0.5939 (7)	0.067 (3)	0.68 (2)
H6B	1.1103	0.8043	0.6347	0.081*	0.68 (2)
C7B	1.0035 (15)	0.7743 (11)	0.5352 (7)	0.088 (4)	0.68 (2)
H7B	1.0934	0.7049	0.5369	0.106*	0.68 (2)
C8B	0.8590 (18)	0.8183 (13)	0.4742 (6)	0.085 (5)	0.68 (2)
H8B	0.8522	0.7785	0.4349	0.102*	0.68 (2)
C9B	0.7246 (15)	0.9219 (13)	0.4717 (6)	0.081 (4)	0.68 (2)
H9B	0.6279	0.9514	0.4308	0.097*	0.68 (2)
C10B	0.7347 (14)	0.9815 (12)	0.5303 (7)	0.068 (3)	0.68 (2)
H10B	0.6448	1.0508	0.5287	0.081*	0.68 (2)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.03746 (8)	0.04703 (9)	0.04422 (9)	−0.01978 (6)	0.00816 (6)	−0.01895 (7)
S1	0.0348 (4)	0.0458 (5)	0.0430 (4)	−0.0178 (3)	0.0075 (3)	−0.0199 (4)
Cl2	0.0372 (4)	0.0808 (7)	0.0704 (7)	−0.0261 (5)	0.0100 (4)	−0.0285 (6)
Cl1	0.0521 (5)	0.0459 (5)	0.0748 (7)	−0.0132 (4)	0.0056 (5)	−0.0228 (5)
C11	0.051 (2)	0.057 (2)	0.057 (2)	−0.0273 (18)	0.0104 (18)	−0.033 (2)
C1	0.052 (2)	0.066 (3)	0.054 (2)	−0.035 (2)	0.0142 (18)	−0.016 (2)
C23	0.060 (2)	0.050 (2)	0.063 (3)	−0.033 (2)	0.008 (2)	−0.009 (2)
C4	0.074 (3)	0.059 (3)	0.066 (3)	−0.043 (2)	0.012 (2)	−0.020 (2)
C12	0.056 (3)	0.090 (4)	0.086 (4)	−0.028 (3)	0.020 (3)	−0.050 (3)
C16	0.069 (3)	0.080 (3)	0.073 (3)	−0.021 (3)	0.008 (3)	−0.041 (3)
C24	0.082 (4)	0.061 (3)	0.077 (4)	−0.021 (3)	0.005 (3)	−0.019 (3)
C28	0.072 (3)	0.067 (3)	0.089 (4)	−0.020 (3)	0.015 (3)	−0.014 (3)
C14	0.108 (5)	0.108 (5)	0.060 (3)	−0.064 (4)	0.022 (3)	−0.043 (3)
C13	0.086 (4)	0.138 (6)	0.091 (5)	−0.065 (4)	0.045 (4)	−0.076 (5)
C26	0.110 (5)	0.115 (6)	0.069 (4)	−0.065 (5)	0.002 (4)	−0.023 (4)
C25	0.127 (6)	0.090 (5)	0.076 (4)	−0.043 (4)	0.012 (4)	−0.036 (4)
C15	0.109 (5)	0.086 (4)	0.074 (4)	−0.038 (4)	−0.004 (4)	−0.023 (3)
C27	0.072 (4)	0.098 (5)	0.091 (5)	−0.021 (4)	−0.014 (3)	0.007 (4)
S2	0.0524 (5)	0.0438 (5)	0.0548 (6)	−0.0249 (4)	0.0097 (4)	−0.0188 (4)
C2	0.046 (2)	0.058 (2)	0.065 (3)	−0.0274 (18)	0.0088 (18)	−0.033 (2)
C3	0.098 (4)	0.066 (3)	0.060 (3)	−0.041 (3)	0.004 (3)	−0.027 (2)
C17A	0.120 (10)	0.064 (5)	0.057 (5)	−0.048 (6)	0.020 (6)	−0.030 (4)
C18A	0.169 (12)	0.063 (6)	0.094 (7)	−0.069 (6)	0.064 (7)	−0.038 (5)
C19A	0.220 (18)	0.077 (7)	0.118 (9)	−0.069 (9)	0.100 (10)	−0.047 (6)
C20A	0.24 (2)	0.080 (7)	0.137 (11)	−0.099 (12)	0.076 (14)	−0.066 (8)
C21A	0.21 (2)	0.099 (12)	0.128 (14)	−0.105 (14)	0.031 (13)	−0.054 (11)
C22A	0.152 (14)	0.082 (10)	0.115 (12)	−0.075 (10)	0.018 (10)	−0.039 (9)
C17B	0.123 (11)	0.062 (6)	0.058 (7)	−0.051 (7)	0.021 (8)	−0.029 (6)
C18B	0.177 (14)	0.059 (7)	0.094 (9)	−0.062 (7)	0.054 (9)	−0.042 (7)
C19B	0.222 (19)	0.071 (8)	0.111 (10)	−0.061 (10)	0.106 (11)	−0.050 (8)
C20B	0.23 (2)	0.082 (8)	0.137 (13)	−0.085 (14)	0.075 (16)	−0.070 (9)
C21B	0.21 (2)	0.107 (13)	0.143 (16)	−0.104 (15)	0.024 (14)	−0.057 (12)
C22B	0.151 (16)	0.082 (12)	0.125 (14)	−0.062 (11)	0.021 (12)	−0.049 (11)
C5A	0.053 (6)	0.055 (9)	0.031 (5)	−0.025 (7)	0.011 (5)	−0.013 (6)
C6A	0.090 (9)	0.077 (10)	0.064 (10)	−0.022 (8)	0.024 (8)	−0.028 (8)
C7A	0.129 (12)	0.080 (12)	0.075 (11)	−0.017 (10)	0.024 (10)	−0.020 (9)
C8A	0.124 (15)	0.124 (15)	0.069 (9)	−0.055 (12)	0.035 (10)	−0.047 (10)
C9A	0.083 (11)	0.104 (13)	0.053 (6)	−0.051 (10)	0.017 (8)	−0.048 (8)
C10A	0.059 (9)	0.071 (10)	0.049 (6)	−0.031 (7)	0.011 (6)	−0.016 (7)
C5B	0.054 (4)	0.053 (6)	0.051 (4)	−0.031 (4)	0.017 (3)	−0.011 (4)
C6B	0.073 (5)	0.074 (7)	0.056 (6)	−0.026 (5)	0.011 (4)	−0.024 (5)
C7B	0.121 (9)	0.078 (8)	0.062 (7)	−0.024 (7)	0.027 (7)	−0.031 (6)
C8B	0.113 (12)	0.110 (12)	0.064 (6)	−0.058 (10)	0.039 (7)	−0.053 (7)
C9B	0.088 (8)	0.115 (11)	0.052 (4)	−0.050 (8)	0.014 (5)	−0.030 (6)
C10B	0.066 (6)	0.083 (8)	0.052 (4)	−0.029 (5)	0.006 (4)	−0.020 (5)

Geometric parameters (Å, º) top

Pt1—S1	2.2748 (9)	C17A—C18A	1.3900
Pt1—S2	2.2776 (10)	C17A—C22A	1.3900
Pt1—Cl2	2.3121 (10)	C18A—C19A	1.3900
Pt1—Cl1	2.3128 (11)	C18A—H18A	0.9300
S1—C1	1.819 (4)	C19A—C20A	1.3900
S1—C2	1.831 (4)	C19A—H19A	0.9300
C11—C16	1.375 (7)	C20A—C21A	1.3900
C11—C12	1.386 (7)	C20A—H20A	0.9300
C11—C2	1.499 (6)	C21A—C22A	1.3900
C1—C5B	1.449 (8)	C21A—H21A	0.9300
C1—C5A	1.623 (16)	C22A—H22A	0.9300
C1—H1A	0.9700	C17B—C18B	1.3900
C1—H1B	0.9700	C17B—C22B	1.3900
C23—C24	1.381 (8)	C18B—C19B	1.3900
C23—C28	1.391 (7)	C18B—H18B	0.9300
C23—C4	1.487 (7)	C19B—C20B	1.3900
C4—S2	1.832 (4)	C19B—H19B	0.9300
C4—H4A	0.9700	C20B—C21B	1.3900
C4—H4B	0.9700	C20B—H20B	0.9300
C12—C13	1.366 (9)	C21B—C22B	1.3900
C12—H12	0.9300	C21B—H21B	0.9300
C16—C15	1.394 (8)	C22B—H22B	0.9300
C16—H16	0.9300	C5A—C6A	1.3900
C24—C25	1.383 (9)	C5A—C10A	1.3900
C24—H24	0.9300	C6A—C7A	1.3900
C28—C27	1.389 (10)	C6A—H6A	0.9300
C28—H28	0.9300	C7A—C8A	1.3900
C14—C13	1.346 (9)	C7A—H7A	0.9300
C14—C15	1.368 (9)	C8A—C9A	1.3900
C14—H14	0.9300	C8A—H8A	0.9300
C13—H13	0.9300	C9A—C10A	1.3900
C26—C27	1.362 (11)	C9A—H9A	0.9300
C26—C25	1.364 (11)	C10A—H10A	0.9300
C26—H26	0.9300	C5B—C6B	1.3900
C25—H25	0.9300	C5B—C10B	1.3900
C15—H15	0.9300	C6B—C7B	1.3900
C27—H27	0.9300	C6B—H6B	0.9300
S2—C3	1.835 (5)	C7B—C8B	1.3900
C2—H2A	0.9700	C7B—H7B	0.9300
C2—H2B	0.9700	C8B—C9B	1.3900
C3—C17B	1.458 (14)	C8B—H8B	0.9300
C3—C17A	1.538 (11)	C9B—C10B	1.3900
C3—H3A	0.9700	C9B—H9B	0.9300
C3—H3B	0.9700	C10B—H10B	0.9300

S1—Pt1—S2	87.15 (4)	C17A—C3—H3B	110.0
S1—Pt1—Cl2	178.29 (4)	S2—C3—H3B	110.0
S2—Pt1—Cl2	91.26 (4)	H3A—C3—H3B	108.3
S1—Pt1—Cl1	92.06 (4)	C18A—C17A—C22A	120.0
S2—Pt1—Cl1	174.17 (4)	C18A—C17A—C3	120.3 (8)
Cl2—Pt1—Cl1	89.59 (4)	C22A—C17A—C3	119.5 (8)
C1—S1—C2	99.8 (2)	C17A—C18A—C19A	120.0
C1—S1—Pt1	106.38 (14)	C17A—C18A—H18A	120.0
C2—S1—Pt1	109.56 (13)	C19A—C18A—H18A	120.0
C16—C11—C12	118.4 (5)	C20A—C19A—C18A	120.0
C16—C11—C2	121.3 (4)	C20A—C19A—H19A	120.0
C12—C11—C2	120.3 (5)	C18A—C19A—H19A	120.0
C5B—C1—S1	113.2 (6)	C19A—C20A—C21A	120.0
C5A—C1—S1	103.3 (9)	C19A—C20A—H20A	120.0
C5B—C1—H1A	100.6	C21A—C20A—H20A	120.0
C5A—C1—H1A	111.1	C22A—C21A—C20A	120.0
S1—C1—H1A	111.1	C22A—C21A—H21A	120.0
C5B—C1—H1B	111.3	C20A—C21A—H21A	120.0
C5A—C1—H1B	111.1	C21A—C22A—C17A	120.0
S1—C1—H1B	111.1	C21A—C22A—H22A	120.0
H1A—C1—H1B	109.1	C17A—C22A—H22A	120.0
C24—C23—C28	118.6 (5)	C18B—C17B—C22B	120.0
C24—C23—C4	120.1 (5)	C18B—C17B—C3	120.1 (14)
C28—C23—C4	121.3 (5)	C22B—C17B—C3	119.9 (14)
C23—C4—S2	110.2 (3)	C19B—C18B—C17B	120.0
C23—C4—H4A	109.6	C19B—C18B—H18B	120.0
S2—C4—H4A	109.6	C17B—C18B—H18B	120.0
C23—C4—H4B	109.6	C20B—C19B—C18B	120.0
S2—C4—H4B	109.6	C20B—C19B—H19B	120.0
H4A—C4—H4B	108.1	C18B—C19B—H19B	120.0
C13—C12—C11	120.9 (6)	C19B—C20B—C21B	120.0
C13—C12—H12	119.5	C19B—C20B—H20B	120.0
C11—C12—H12	119.5	C21B—C20B—H20B	120.0
C11—C16—C15	119.7 (5)	C22B—C21B—C20B	120.0
C11—C16—H16	120.2	C22B—C21B—H21B	120.0
C15—C16—H16	120.2	C20B—C21B—H21B	120.0
C23—C24—C25	121.0 (6)	C21B—C22B—C17B	120.0
C23—C24—H24	119.5	C21B—C22B—H22B	120.0
C25—C24—H24	119.5	C17B—C22B—H22B	120.0
C27—C28—C23	119.3 (6)	C6A—C5A—C10A	120.0
C27—C28—H28	120.4	C6A—C5A—C1	120.1 (13)
C23—C28—H28	120.4	C10A—C5A—C1	119.6 (12)
C13—C14—C15	119.9 (6)	C5A—C6A—C7A	120.0
C13—C14—H14	120.1	C5A—C6A—H6A	120.0
C15—C14—H14	120.1	C7A—C6A—H6A	120.0
C14—C13—C12	120.7 (6)	C6A—C7A—C8A	120.0
C14—C13—H13	119.6	C6A—C7A—H7A	120.0
C12—C13—H13	119.6	C8A—C7A—H7A	120.0
C27—C26—C25	119.7 (7)	C9A—C8A—C7A	120.0
C27—C26—H26	120.2	C9A—C8A—H8A	120.0
C25—C26—H26	120.2	C7A—C8A—H8A	120.0
C26—C25—C24	120.1 (7)	C8A—C9A—C10A	120.0
C26—C25—H25	120.0	C8A—C9A—H9A	120.0
C24—C25—H25	120.0	C10A—C9A—H9A	120.0
C14—C15—C16	120.3 (6)	C9A—C10A—C5A	120.0
C14—C15—H15	119.8	C9A—C10A—H10A	120.0
C16—C15—H15	119.8	C5A—C10A—H10A	120.0
C26—C27—C28	121.3 (6)	C6B—C5B—C10B	120.0
C26—C27—H27	119.3	C6B—C5B—C1	119.5 (6)
C28—C27—H27	119.3	C10B—C5B—C1	120.4 (7)
C4—S2—C3	100.7 (2)	C7B—C6B—C5B	120.0
C4—S2—Pt1	110.67 (17)	C7B—C6B—H6B	120.0
C3—S2—Pt1	101.33 (17)	C5B—C6B—H6B	120.0
C11—C2—S1	110.5 (3)	C6B—C7B—C8B	120.0
C11—C2—H2A	109.6	C6B—C7B—H7B	120.0
S1—C2—H2A	109.6	C8B—C7B—H7B	120.0
C11—C2—H2B	109.6	C7B—C8B—C9B	120.0
S1—C2—H2B	109.6	C7B—C8B—H8B	120.0
H2A—C2—H2B	108.1	C9B—C8B—H8B	120.0
C17B—C3—S2	119.2 (10)	C10B—C9B—C8B	120.0
C17A—C3—S2	108.6 (7)	C10B—C9B—H9B	120.0
C17B—C3—H3A	97.2	C8B—C9B—H9B	120.0
C17A—C3—H3A	110.0	C9B—C10B—C5B	120.0
S2—C3—H3A	110.0	C9B—C10B—H10B	120.0
C17B—C3—H3B	111.1	C5B—C10B—H10B	120.0

(abtri250) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	Z = 2
M_r = 694.61	F(000) = 680
Triclinic, P1	D_x = 1.623 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.3411 (7) Å	Cell parameters from 12940 reflections
b = 12.2228 (11) Å	θ = 2.6–32.6°
c = 15.8547 (19) Å	µ = 5.29 mm⁻¹
α = 69.022 (10)°	T = 250 K
β = 89.222 (8)°	Prism, yellow
γ = 71.433 (8)°	0.28 × 0.19 × 0.13 mm
V = 1421.5 (3) Å³

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	8515 independent reflections
Radiation source: Sealed tube	6931 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.043
ω–scans	θ_max = 32.6°, θ_min = 2.6°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −12→8
T_min = 0.302, T_max = 0.566	k = −18→15
12940 measured reflections	l = −23→23

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.035	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.089	H-atom parameters constrained
S = 1.01	w = 1/[σ²(F_o²) + (0.0482P)²] where P = (F_o² + 2F_c²)/3
8515 reflections	(Δ/σ)_max = 0.008
372 parameters	Δρ_max = 2.15 e Å⁻³
72 restraints	Δρ_min = −1.52 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	γ = 71.433 (8)°
M_r = 694.61	V = 1421.5 (3) Å³
Triclinic, P1	Z = 2
a = 8.3411 (7) Å	Mo Kα radiation
b = 12.2228 (11) Å	µ = 5.29 mm⁻¹
c = 15.8547 (19) Å	T = 250 K
α = 69.022 (10)°	0.28 × 0.19 × 0.13 mm
β = 89.222 (8)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	8515 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	6931 reflections with I > 2σ(I)
T_min = 0.302, T_max = 0.566	R_int = 0.043
12940 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.035	72 restraints
wR(F²) = 0.089	H-atom parameters constrained
S = 1.01	Δρ_max = 2.15 e Å⁻³
8515 reflections	Δρ_min = −1.52 e Å⁻³
372 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Pt1	0.583962 (17)	0.908871 (13)	0.766907 (10)	0.03544 (5)
S1	0.85905 (11)	0.90371 (9)	0.77091 (6)	0.03348 (18)
Cl2	0.30749 (13)	0.90730 (11)	0.76528 (8)	0.0530 (3)
Cl1	0.48136 (14)	1.12282 (9)	0.72659 (8)	0.0504 (2)
C11	0.8814 (5)	0.9392 (4)	0.9303 (3)	0.0440 (9)
C1	0.8849 (6)	0.9970 (4)	0.6553 (3)	0.0473 (10)
H1A	0.7982	1.0787	0.6351	0.057*
H1B	0.9956	1.0073	0.6542	0.057*
C23	0.6341 (6)	0.5965 (4)	0.9675 (3)	0.0484 (10)
C4	0.5748 (7)	0.6156 (4)	0.8735 (3)	0.0552 (12)
H4A	0.4535	0.6610	0.8604	0.066*
H4B	0.5947	0.5355	0.8686	0.066*
C12	0.7404 (7)	0.9852 (5)	0.9714 (4)	0.0618 (13)
H12	0.6472	1.0517	0.9359	0.074*
C16	1.0166 (7)	0.8399 (5)	0.9844 (4)	0.0589 (12)
H16	1.1119	0.8075	0.9585	0.071*
C24	0.5492 (7)	0.6780 (5)	1.0083 (4)	0.0621 (13)
H24	0.4557	0.7469	0.9757	0.074*
C28	0.7747 (7)	0.4960 (5)	1.0180 (4)	0.0713 (15)
H28	0.8352	0.4396	0.9926	0.086*
C14	0.8712 (9)	0.8351 (6)	1.1164 (4)	0.0725 (17)
H14	0.8675	0.8000	1.1788	0.087*
C13	0.7371 (8)	0.9341 (7)	1.0628 (4)	0.0754 (17)
H13	0.6426	0.9669	1.0890	0.090*
C26	0.7397 (9)	0.5607 (7)	1.1446 (5)	0.082 (2)
H26	0.7759	0.5492	1.2033	0.098*
C25	0.6004 (10)	0.6594 (6)	1.0968 (4)	0.0822 (18)
H25	0.5397	0.7142	1.1234	0.099*
C15	1.0117 (9)	0.7875 (6)	1.0777 (4)	0.0743 (16)
H15	1.1036	0.7202	1.1139	0.089*
C27	0.8256 (8)	0.4790 (6)	1.1062 (5)	0.0837 (19)
H27	0.9196	0.4110	1.1393	0.100*
S2	0.68801 (13)	0.70258 (9)	0.79071 (7)	0.0419 (2)
C2	0.8860 (5)	1.0007 (4)	0.8301 (3)	0.0442 (9)
H2A	0.9940	1.0145	0.8194	0.053*
H2B	0.7959	1.0808	0.8067	0.053*
C3	0.6016 (7)	0.7030 (4)	0.6844 (3)	0.0585 (12)
H3A	0.4784	0.7280	0.6809	0.070*
H3B	0.6315	0.7621	0.6327	0.070*
C17A	0.6748 (7)	0.5722 (4)	0.6817 (3)	0.065 (5)	0.570 (14)
C18A	0.8454 (7)	0.5313 (4)	0.6685 (3)	0.075 (4)	0.570 (14)
H18A	0.9102	0.5821	0.6642	0.089*	0.570 (14)
C19A	0.923 (3)	0.4144 (15)	0.6614 (13)	0.103 (3)	0.570 (14)
H19A	1.0380	0.3857	0.6553	0.124*	0.570 (14)
C20A	0.819 (3)	0.3441 (17)	0.6638 (13)	0.103 (3)	0.570 (14)
H20A	0.8631	0.2694	0.6551	0.124*	0.570 (14)
C21A	0.660 (3)	0.3817 (15)	0.6783 (12)	0.103 (3)	0.570 (14)
H21A	0.5961	0.3300	0.6831	0.124*	0.570 (14)
C22A	0.580 (3)	0.4964 (10)	0.6869 (11)	0.098 (5)	0.570 (14)
H22A	0.4656	0.5209	0.6959	0.118*	0.570 (14)
C17B	0.641 (3)	0.5881 (19)	0.6710 (13)	0.070 (5)	0.430 (14)
C18B	0.806 (3)	0.5075 (17)	0.6752 (14)	0.093 (6)	0.430 (14)
H18B	0.8973	0.5266	0.6915	0.112*	0.430 (14)
C19B	0.839 (3)	0.4041 (19)	0.6567 (15)	0.100 (5)	0.430 (14)
H19B	0.9496	0.3609	0.6511	0.120*	0.430 (14)
C20B	0.713 (4)	0.3627 (18)	0.6464 (17)	0.101 (5)	0.430 (14)
H20B	0.7378	0.2877	0.6382	0.121*	0.430 (14)
C21B	0.551 (4)	0.4305 (19)	0.6478 (17)	0.115 (5)	0.430 (14)
H21B	0.4617	0.4042	0.6394	0.138*	0.430 (14)
C22B	0.521 (4)	0.5418 (19)	0.662 (2)	0.103 (3)	0.43
H22B	0.4094	0.5860	0.6664	0.124*	0.43
C5A	0.870 (8)	0.935 (6)	0.597 (5)	0.076 (5)	0.27 (4)
C6A	1.033 (7)	0.800 (4)	0.617 (3)	0.076 (5)	0.27 (4)
H6A	1.1147	0.7713	0.6665	0.091*	0.27 (4)
C7A	1.047 (5)	0.731 (4)	0.561 (3)	0.076 (5)	0.27 (4)
H7A	1.1419	0.6618	0.5678	0.091*	0.27 (4)
C8A	0.910 (11)	0.773 (6)	0.495 (3)	0.084 (10)	0.27 (4)
H8A	0.9097	0.7235	0.4624	0.100*	0.27 (4)
C9A	0.789 (7)	0.872 (6)	0.476 (4)	0.068 (9)	0.27 (4)
H9A	0.7074	0.8994	0.4266	0.081*	0.27 (4)
C10A	0.781 (5)	0.939 (4)	0.533 (3)	0.051 (7)	0.27 (4)
H10A	0.6804	1.0067	0.5177	0.061*	0.27 (4)
C5B	0.8888 (18)	0.9251 (16)	0.5939 (10)	0.044 (2)	0.73 (4)
C6B	1.014 (2)	0.8329 (14)	0.5958 (9)	0.061 (3)	0.73 (4)
H6B	1.1115	0.8046	0.6361	0.073*	0.73 (4)
C7B	1.004 (3)	0.7739 (16)	0.5356 (13)	0.085 (4)	0.73 (4)
H7B	1.0942	0.7042	0.5381	0.102*	0.73 (4)
C8B	0.862 (4)	0.817 (2)	0.4724 (15)	0.089 (8)	0.73 (4)
H8B	0.8577	0.7779	0.4320	0.107*	0.73 (4)
C9B	0.731 (3)	0.917 (2)	0.4721 (12)	0.074 (5)	0.73 (4)
H9B	0.6345	0.9455	0.4313	0.089*	0.73 (4)
C10B	0.734 (2)	0.9789 (18)	0.5280 (13)	0.060 (3)	0.73 (4)
H10B	0.6451	1.0497	0.5252	0.072*	0.73 (4)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.03328 (8)	0.03915 (8)	0.03766 (8)	−0.01572 (6)	0.00646 (5)	−0.01560 (6)
S1	0.0303 (4)	0.0389 (4)	0.0367 (4)	−0.0149 (4)	0.0064 (3)	−0.0175 (4)
Cl2	0.0322 (5)	0.0695 (7)	0.0606 (7)	−0.0220 (5)	0.0086 (4)	−0.0238 (6)
Cl1	0.0454 (5)	0.0381 (5)	0.0642 (7)	−0.0096 (4)	0.0031 (5)	−0.0189 (5)
C11	0.043 (2)	0.053 (2)	0.055 (2)	−0.0270 (19)	0.0098 (18)	−0.032 (2)
C1	0.047 (2)	0.057 (2)	0.043 (2)	−0.027 (2)	0.0124 (18)	−0.016 (2)
C23	0.054 (3)	0.042 (2)	0.051 (2)	−0.027 (2)	0.007 (2)	−0.0100 (19)
C4	0.070 (3)	0.054 (3)	0.056 (3)	−0.044 (2)	0.014 (2)	−0.017 (2)
C12	0.051 (3)	0.074 (3)	0.075 (4)	−0.024 (3)	0.018 (3)	−0.042 (3)
C16	0.057 (3)	0.064 (3)	0.060 (3)	−0.017 (2)	0.008 (2)	−0.032 (3)
C24	0.072 (3)	0.049 (3)	0.059 (3)	−0.018 (2)	0.006 (3)	−0.015 (2)
C28	0.063 (3)	0.052 (3)	0.085 (4)	−0.017 (2)	0.013 (3)	−0.011 (3)
C14	0.101 (5)	0.099 (4)	0.051 (3)	−0.065 (4)	0.021 (3)	−0.039 (3)
C13	0.076 (4)	0.111 (5)	0.078 (4)	−0.054 (4)	0.035 (3)	−0.062 (4)
C26	0.091 (5)	0.095 (5)	0.061 (4)	−0.052 (4)	−0.007 (3)	−0.013 (4)
C25	0.117 (6)	0.070 (4)	0.067 (4)	−0.037 (4)	0.010 (4)	−0.029 (3)
C15	0.091 (5)	0.064 (3)	0.064 (4)	−0.027 (3)	−0.007 (3)	−0.018 (3)
C27	0.055 (3)	0.085 (4)	0.072 (4)	−0.014 (3)	−0.008 (3)	0.007 (3)
S2	0.0456 (5)	0.0366 (5)	0.0481 (6)	−0.0201 (4)	0.0080 (4)	−0.0158 (4)
C2	0.044 (2)	0.050 (2)	0.051 (2)	−0.0238 (18)	0.0062 (18)	−0.026 (2)
C3	0.081 (4)	0.058 (3)	0.052 (3)	−0.035 (3)	0.010 (2)	−0.028 (2)
C17A	0.115 (11)	0.048 (7)	0.048 (7)	−0.039 (7)	0.012 (6)	−0.026 (6)
C18A	0.142 (10)	0.040 (5)	0.066 (6)	−0.051 (5)	0.043 (6)	−0.030 (4)
C19A	0.163 (10)	0.065 (4)	0.112 (5)	−0.062 (6)	0.040 (6)	−0.048 (4)
C20A	0.163 (10)	0.065 (4)	0.112 (5)	−0.062 (6)	0.040 (6)	−0.048 (4)
C21A	0.163 (10)	0.065 (4)	0.112 (5)	−0.062 (6)	0.040 (6)	−0.048 (4)
C22A	0.154 (14)	0.060 (7)	0.110 (11)	−0.070 (9)	0.026 (9)	−0.036 (7)
C17B	0.118 (11)	0.052 (8)	0.047 (8)	−0.042 (8)	0.022 (8)	−0.014 (7)
C18B	0.160 (14)	0.047 (7)	0.083 (10)	−0.043 (9)	0.007 (10)	−0.028 (7)
C19B	0.158 (13)	0.062 (7)	0.105 (8)	−0.047 (8)	0.045 (10)	−0.053 (7)
C20B	0.171 (13)	0.060 (7)	0.102 (9)	−0.051 (9)	0.051 (10)	−0.054 (6)
C21B	0.166 (13)	0.071 (8)	0.138 (10)	−0.071 (8)	0.031 (10)	−0.046 (7)
C22B	0.163 (10)	0.065 (4)	0.112 (5)	−0.062 (6)	0.040 (6)	−0.048 (4)
C5A	0.081 (9)	0.072 (10)	0.055 (9)	−0.009 (8)	0.026 (8)	−0.018 (7)
C6A	0.081 (9)	0.072 (10)	0.055 (9)	−0.009 (8)	0.026 (8)	−0.018 (7)
C7A	0.081 (9)	0.072 (10)	0.055 (9)	−0.009 (8)	0.026 (8)	−0.018 (7)
C8A	0.14 (3)	0.12 (3)	0.037 (17)	−0.08 (2)	0.025 (16)	−0.049 (17)
C9A	0.09 (2)	0.10 (2)	0.045 (11)	−0.054 (16)	0.010 (16)	−0.044 (15)
C10A	0.041 (15)	0.056 (16)	0.038 (10)	−0.013 (10)	0.002 (12)	−0.001 (13)
C5B	0.049 (5)	0.064 (5)	0.034 (3)	−0.038 (5)	0.018 (3)	−0.021 (3)
C6B	0.072 (6)	0.070 (7)	0.049 (6)	−0.032 (6)	0.015 (5)	−0.025 (5)
C7B	0.112 (10)	0.069 (8)	0.071 (9)	−0.022 (7)	0.035 (8)	−0.029 (7)
C8B	0.14 (2)	0.108 (17)	0.050 (10)	−0.075 (16)	0.034 (12)	−0.037 (10)
C9B	0.082 (10)	0.112 (14)	0.044 (5)	−0.053 (9)	0.016 (6)	−0.031 (8)
C10B	0.053 (8)	0.072 (9)	0.045 (4)	−0.026 (6)	−0.004 (6)	−0.008 (7)

Geometric parameters (Å, º) top

Pt1—S1	2.2764 (9)	C17A—C22A	1.378 (16)
Pt1—S2	2.2776 (10)	C17A—C18A	1.3900
Pt1—Cl2	2.3128 (10)	C18A—C19A	1.413 (17)
Pt1—Cl1	2.3178 (10)	C18A—H18A	0.9300
S1—C2	1.819 (4)	C19A—C20A	1.395 (19)
S1—C1	1.831 (4)	C19A—H19A	0.9300
C11—C16	1.374 (7)	C20A—C21A	1.30 (3)
C11—C12	1.395 (7)	C20A—H20A	0.9300
C11—C2	1.500 (6)	C21A—C22A	1.40 (2)
C1—C5A	1.42 (6)	C21A—H21A	0.9300
C1—C5B	1.523 (14)	C22A—H22A	0.9300
C1—H1A	0.9700	C17B—C22B	1.33 (3)
C1—H1B	0.9700	C17B—C18B	1.40 (3)
C23—C24	1.383 (7)	C18B—C19B	1.34 (2)
C23—C28	1.389 (7)	C18B—H18B	0.9300
C23—C4	1.490 (6)	C19B—C20B	1.33 (3)
C4—S2	1.830 (4)	C19B—H19B	0.9300
C4—H4A	0.9700	C20B—C21B	1.35 (3)
C4—H4B	0.9700	C20B—H20B	0.9300
C12—C13	1.360 (8)	C21B—C22B	1.41 (3)
C12—H12	0.9300	C21B—H21B	0.9300
C16—C15	1.392 (8)	C22B—H22B	0.9298
C16—H16	0.9300	C5A—C10A	1.24 (8)
C24—C25	1.389 (8)	C5A—C6A	1.69 (9)
C24—H24	0.9300	C6A—C7A	1.41 (6)
C28—C27	1.389 (9)	C6A—H6A	0.9300
C28—H28	0.9300	C7A—C8A	1.39 (8)
C14—C13	1.366 (9)	C7A—H7A	0.9300
C14—C15	1.376 (9)	C8A—C9A	1.24 (9)
C14—H14	0.9300	C8A—H8A	0.9300
C13—H13	0.9300	C9A—C10A	1.42 (7)
C26—C27	1.359 (10)	C9A—H9A	0.9300
C26—C25	1.362 (10)	C10A—H10A	0.9300
C26—H26	0.9300	C5B—C6B	1.26 (3)
C25—H25	0.9300	C5B—C10B	1.48 (2)
C15—H15	0.9300	C6B—C7B	1.405 (17)
C27—H27	0.9300	C6B—H6B	0.9300
S2—C3	1.840 (5)	C7B—C8B	1.39 (3)
C2—H2A	0.9700	C7B—H7B	0.9300
C2—H2B	0.9700	C8B—C9B	1.36 (3)
C3—C17B	1.43 (2)	C8B—H8B	0.9300
C3—C17A	1.5359	C9B—C10B	1.36 (3)
C3—H3A	0.9700	C9B—H9B	0.9300
C3—H3B	0.9700	C10B—H10B	0.9300

S1—Pt1—S2	87.11 (4)	C17A—C3—H3B	109.8
S1—Pt1—Cl2	178.17 (4)	S2—C3—H3B	109.8
S2—Pt1—Cl2	91.18 (4)	H3A—C3—H3B	108.2
S1—Pt1—Cl1	92.04 (4)	C22A—C17A—C18A	118.5 (8)
S2—Pt1—Cl1	173.94 (4)	C22A—C17A—C3	124.0 (8)
Cl2—Pt1—Cl1	89.73 (4)	C18A—C17A—C3	117.3
C2—S1—C1	99.59 (19)	C17A—C18A—C19A	121.6 (9)
C2—S1—Pt1	109.72 (14)	C17A—C18A—H18A	119.2
C1—S1—Pt1	105.96 (14)	C19A—C18A—H18A	119.2
C16—C11—C12	118.2 (5)	C20A—C19A—C18A	117.1 (17)
C16—C11—C2	121.5 (4)	C20A—C19A—H19A	121.4
C12—C11—C2	120.2 (4)	C18A—C19A—H19A	121.4
C5A—C1—S1	109 (3)	C21A—C20A—C19A	120.9 (16)
C5B—C1—S1	109.2 (6)	C21A—C20A—H20A	119.6
C5A—C1—H1A	110.0	C19A—C20A—H20A	119.6
C5B—C1—H1A	114.6	C20A—C21A—C22A	123.2 (15)
S1—C1—H1A	110.0	C20A—C21A—H21A	118.4
C5A—C1—H1B	110.0	C22A—C21A—H21A	118.4
C5B—C1—H1B	104.5	C17A—C22A—C21A	118.6 (17)
S1—C1—H1B	110.0	C17A—C22A—H22A	120.7
H1A—C1—H1B	108.4	C21A—C22A—H22A	120.7
C24—C23—C28	117.4 (5)	C22B—C17B—C18B	113 (2)
C24—C23—C4	120.9 (5)	C22B—C17B—C3	122 (2)
C28—C23—C4	121.7 (5)	C18B—C17B—C3	124.8 (18)
C23—C4—S2	110.4 (3)	C19B—C18B—C17B	123 (2)
C23—C4—H4A	109.6	C19B—C18B—H18B	118.4
S2—C4—H4A	109.6	C17B—C18B—H18B	118.4
C23—C4—H4B	109.6	C20B—C19B—C18B	121 (2)
S2—C4—H4B	109.6	C20B—C19B—H19B	119.7
H4A—C4—H4B	108.1	C18B—C19B—H19B	119.7
C13—C12—C11	121.0 (6)	C19B—C20B—C21B	119.5 (17)
C13—C12—H12	119.5	C19B—C20B—H20B	120.3
C11—C12—H12	119.5	C21B—C20B—H20B	120.3
C11—C16—C15	120.4 (5)	C20B—C21B—C22B	118 (2)
C11—C16—H16	119.8	C20B—C21B—H21B	120.9
C15—C16—H16	119.8	C22B—C21B—H21B	120.9
C23—C24—C25	121.5 (5)	C17B—C22B—C21B	124 (3)
C23—C24—H24	119.3	C17B—C22B—H22B	117.8
C25—C24—H24	119.3	C21B—C22B—H22B	117.8
C23—C28—C27	120.6 (6)	C10A—C5A—C1	145 (7)
C23—C28—H28	119.7	C10A—C5A—C6A	102 (5)
C27—C28—H28	119.7	C1—C5A—C6A	114 (5)
C13—C14—C15	119.5 (5)	C7A—C6A—C5A	122 (4)
C13—C14—H14	120.2	C7A—C6A—H6A	119.2
C15—C14—H14	120.2	C5A—C6A—H6A	119.2
C12—C13—C14	120.7 (6)	C8A—C7A—C6A	116 (4)
C12—C13—H13	119.6	C8A—C7A—H7A	122.2
C14—C13—H13	119.6	C6A—C7A—H7A	122.2
C27—C26—C25	119.8 (6)	C9A—C8A—C7A	126 (5)
C27—C26—H26	120.1	C9A—C8A—H8A	117.2
C25—C26—H26	120.1	C7A—C8A—H8A	117.2
C26—C25—C24	119.9 (6)	C8A—C9A—C10A	116 (4)
C26—C25—H25	120.0	C8A—C9A—H9A	121.8
C24—C25—H25	120.0	C10A—C9A—H9A	121.8
C14—C15—C16	120.0 (6)	C5A—C10A—C9A	138 (5)
C14—C15—H15	120.0	C5A—C10A—H10A	110.8
C16—C15—H15	120.0	C9A—C10A—H10A	110.8
C26—C27—C28	120.8 (6)	C6B—C5B—C10B	123.4 (13)
C26—C27—H27	119.6	C6B—C5B—C1	123.5 (12)
C28—C27—H27	119.6	C10B—C5B—C1	113.0 (15)
C4—S2—C3	101.0 (2)	C5B—C6B—C7B	118.5 (12)
C4—S2—Pt1	111.14 (17)	C5B—C6B—H6B	120.7
C3—S2—Pt1	101.06 (16)	C7B—C6B—H6B	120.7
C11—C2—S1	110.4 (3)	C8B—C7B—C6B	122.0 (14)
C11—C2—H2A	109.6	C8B—C7B—H7B	119.0
S1—C2—H2A	109.6	C6B—C7B—H7B	119.0
C11—C2—H2B	109.6	C9B—C8B—C7B	117 (2)
S1—C2—H2B	109.6	C9B—C8B—H8B	121.4
H2A—C2—H2B	108.1	C7B—C8B—H8B	121.4
C17B—C3—S2	119.1 (11)	C10B—C9B—C8B	123.5 (18)
C17A—C3—S2	109.48 (16)	C10B—C9B—H9B	118.2
C17B—C3—H3A	100.7	C8B—C9B—H9B	118.2
C17A—C3—H3A	109.8	C9B—C10B—C5B	115.1 (13)
S2—C3—H3A	109.8	C9B—C10B—H10B	122.5
C17B—C3—H3B	108.6	C5B—C10B—H10B	122.5

(abtri200) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	Z = 2
M_r = 694.61	F(000) = 680
Triclinic, P1	D_x = 1.648 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.2930 (5) Å	Cell parameters from 13148 reflections
b = 12.1730 (8) Å	θ = 2.6–32.7°
c = 15.7892 (14) Å	µ = 5.37 mm⁻¹
α = 68.837 (7)°	T = 200 K
β = 89.261 (6)°	Prism, yellow
γ = 71.456 (6)°	0.28 × 0.19 × 0.13 mm
V = 1399.9 (2) Å³

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	8659 independent reflections
Radiation source: Sealed tube	7523 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.045
ω–scans	θ_max = 32.7°, θ_min = 2.6°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −12→8
T_min = 0.301, T_max = 0.562	k = −18→15
13148 measured reflections	l = −23→22

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.034	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.088	H-atom parameters constrained
S = 1.02	w = 1/[σ²(F_o²) + (0.0552P)²] where P = (F_o² + 2F_c²)/3
8659 reflections	(Δ/σ)_max = 0.010
318 parameters	Δρ_max = 2.83 e Å⁻³
36 restraints	Δρ_min = −1.88 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	γ = 71.456 (6)°
M_r = 694.61	V = 1399.9 (2) Å³
Triclinic, P1	Z = 2
a = 8.2930 (5) Å	Mo Kα radiation
b = 12.1730 (8) Å	µ = 5.37 mm⁻¹
c = 15.7892 (14) Å	T = 200 K
α = 68.837 (7)°	0.28 × 0.19 × 0.13 mm
β = 89.261 (6)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	8659 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	7523 reflections with I > 2σ(I)
T_min = 0.301, T_max = 0.562	R_int = 0.045
13148 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.034	36 restraints
wR(F²) = 0.088	H-atom parameters constrained
S = 1.02	Δρ_max = 2.83 e Å⁻³
8659 reflections	Δρ_min = −1.88 e Å⁻³
318 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Pt1	0.582473 (15)	0.909556 (11)	0.766990 (8)	0.02793 (5)
S1	0.85814 (10)	0.90527 (8)	0.77069 (5)	0.02719 (15)
Cl2	0.30529 (11)	0.90690 (10)	0.76571 (7)	0.0434 (2)
Cl1	0.47839 (12)	1.12413 (8)	0.72628 (7)	0.04017 (19)
C11	0.8804 (5)	0.9406 (3)	0.9305 (3)	0.0349 (7)
C1	0.8834 (5)	0.9985 (4)	0.6549 (2)	0.0372 (8)
H1A	0.7859	1.0751	0.6305	0.045*
H1B	0.9862	1.0202	0.6549	0.045*
C23	0.6337 (5)	0.5959 (3)	0.9684 (3)	0.0384 (8)
C4	0.5739 (6)	0.6150 (4)	0.8734 (3)	0.0465 (10)
H4A	0.4518	0.6605	0.8600	0.056*
H4B	0.5945	0.5346	0.8686	0.056*
C3	0.6018 (6)	0.7036 (4)	0.6845 (3)	0.0476 (10)
H3A	0.4787	0.7226	0.6823	0.057*
H3B	0.6259	0.7662	0.6322	0.057*
C12	0.7391 (6)	0.9874 (5)	0.9712 (3)	0.0495 (10)
H12	0.6463	1.0554	0.9355	0.059*
C16	1.0171 (6)	0.8401 (4)	0.9845 (3)	0.0463 (9)
H16	1.1125	0.8077	0.9583	0.056*
C24	0.5476 (6)	0.6785 (4)	1.0085 (3)	0.0499 (10)
H24	0.4522	0.7468	0.9760	0.060*
C28	0.7750 (6)	0.4949 (4)	1.0185 (4)	0.0571 (12)
H28	0.8350	0.4384	0.9927	0.069*
C14	0.8711 (7)	0.8348 (5)	1.1167 (3)	0.0577 (13)
H14	0.8681	0.7989	1.1794	0.069*
C13	0.7352 (7)	0.9335 (5)	1.0644 (4)	0.0597 (13)
H13	0.6399	0.9649	1.0911	0.072*
C26	0.7417 (8)	0.5588 (6)	1.1457 (4)	0.0664 (16)
H26	0.7770	0.5459	1.2052	0.080*
C25	0.6019 (8)	0.6605 (5)	1.0967 (4)	0.0654 (14)
H25	0.5438	0.7172	1.1227	0.078*
C15	1.0123 (7)	0.7871 (5)	1.0785 (3)	0.0582 (12)
H15	1.1048	0.7196	1.1151	0.070*
C27	0.8279 (7)	0.4774 (5)	1.1073 (4)	0.0665 (15)
H27	0.9231	0.4092	1.1404	0.080*
S2	0.68796 (12)	0.70283 (8)	0.79089 (6)	0.03386 (17)
C2	0.8836 (3)	1.00296 (19)	0.83009 (11)	0.0350 (7)
H2A	0.9914	1.0180	0.8190	0.042*
H2B	0.7918	1.0830	0.8067	0.042*
C17A	0.6919 (3)	0.56844 (19)	0.68332 (11)	0.0438 (16)	0.449 (10)
C18A	0.8641 (3)	0.52385 (19)	0.67222 (11)	0.042 (2)	0.449 (10)
H18A	0.9325	0.5724	0.6689	0.050*	0.449 (10)
C19A	0.9356 (3)	0.40675 (19)	0.66596 (11)	0.067 (4)	0.449 (10)
H19A	1.0527	0.3750	0.6637	0.081*	0.449 (10)
C20A	0.8307 (3)	0.33646 (19)	0.66303 (11)	0.074 (5)	0.449 (10)
H20A	0.8754	0.2626	0.6528	0.089*	0.449 (10)
C21A	0.6605 (3)	0.37951 (19)	0.67570 (11)	0.077 (4)	0.449 (10)
H21A	0.5919	0.3315	0.6775	0.093*	0.449 (10)
C22A	0.5896 (3)	0.49413 (19)	0.68592 (11)	0.065 (4)	0.449 (10)
H22A	0.4746	0.5216	0.6945	0.078*	0.449 (10)
C19B	0.8594 (3)	0.41037 (19)	0.65602 (11)	0.099 (6)	0.551 (10)
H19B	0.9728	0.3722	0.6494	0.119*	0.551 (10)
C20B	0.7316 (3)	0.35750 (19)	0.65366 (11)	0.108 (7)	0.551 (10)
H20B	0.7593	0.2795	0.6494	0.130*	0.551 (10)
C21B	0.5805 (3)	0.41792 (19)	0.65739 (11)	0.119 (6)	0.551 (10)
H21B	0.4967	0.3848	0.6511	0.143*	0.551 (10)
C22B	0.5268 (3)	0.53164 (19)	0.67035 (11)	0.097 (5)	0.551 (10)
H22B	0.4125	0.5688	0.6758	0.117*	0.551 (10)
C17B	0.6404 (3)	0.58556 (19)	0.67473 (11)	0.0438 (16)	0.55
C18B	0.8056 (3)	0.52240 (19)	0.66878 (11)	0.072 (4)	0.551 (10)
H18B	0.8882	0.5572	0.6737	0.087*	0.551 (10)
C5A	0.8960 (3)	0.91916 (19)	0.59564 (11)	0.0381 (11)	0.399 (11)
C6A	1.0384 (3)	0.81174 (19)	0.61271 (11)	0.068 (5)	0.399 (11)
H6A	1.1252	0.7888	0.6588	0.082*	0.399 (11)
C7A	1.0502 (3)	0.73911 (19)	0.56070 (11)	0.097 (6)	0.399 (11)
H7A	1.1449	0.6675	0.5719	0.116*	0.399 (11)
C8A	0.9196 (3)	0.77392 (19)	0.49162 (11)	0.101 (8)	0.399 (11)
H8A	0.9275	0.7254	0.4568	0.122*	0.399 (11)
C9A	0.7772 (3)	0.88134 (19)	0.47454 (11)	0.077 (4)	0.399 (11)
H9A	0.6904	0.9043	0.4285	0.093*	0.399 (11)
C10A	0.7655 (3)	0.95397 (19)	0.52655 (11)	0.050 (4)	0.399 (11)
H10A	0.6707	1.0256	0.5153	0.060*	0.399 (11)
C5B	0.8731 (3)	0.93735 (19)	0.59235 (11)	0.0381 (11)	0.60
C6B	1.0132 (3)	0.83423 (19)	0.59638 (11)	0.046 (2)	0.601 (11)
H6B	1.1088	0.8062	0.6385	0.055*	0.601 (11)
C7B	1.0096 (3)	0.77347 (19)	0.53725 (11)	0.063 (3)	0.601 (11)
H7B	1.1028	0.7047	0.5398	0.075*	0.601 (11)
C8B	0.8659 (3)	0.81584 (19)	0.47410 (11)	0.063 (3)	0.601 (11)
H8B	0.8636	0.7752	0.4346	0.076*	0.601 (11)
C9B	0.7258 (3)	0.91896 (19)	0.47007 (11)	0.058 (2)	0.601 (11)
H9B	0.6303	0.9470	0.4279	0.069*	0.601 (11)
C10B	0.7294 (3)	0.97971 (19)	0.52920 (11)	0.050 (2)	0.601 (11)
H10B	0.6362	1.0485	0.5267	0.060*	0.601 (11)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.02681 (7)	0.03285 (7)	0.02941 (7)	−0.01390 (5)	0.00619 (4)	−0.01439 (5)
S1	0.0250 (3)	0.0328 (4)	0.0294 (4)	−0.0134 (3)	0.0056 (3)	−0.0150 (3)
Cl2	0.0267 (4)	0.0579 (5)	0.0502 (5)	−0.0201 (4)	0.0072 (4)	−0.0207 (4)
Cl1	0.0361 (4)	0.0327 (4)	0.0506 (5)	−0.0090 (3)	0.0040 (4)	−0.0167 (4)
C11	0.0365 (17)	0.0412 (18)	0.0420 (18)	−0.0199 (15)	0.0075 (14)	−0.0265 (16)
C1	0.0372 (18)	0.047 (2)	0.0332 (17)	−0.0252 (16)	0.0097 (14)	−0.0125 (15)
C23	0.043 (2)	0.0347 (17)	0.0410 (19)	−0.0236 (15)	0.0082 (15)	−0.0092 (15)
C4	0.059 (3)	0.047 (2)	0.046 (2)	−0.037 (2)	0.0109 (19)	−0.0138 (18)
C3	0.064 (3)	0.050 (2)	0.042 (2)	−0.028 (2)	0.0087 (19)	−0.0249 (18)
C12	0.043 (2)	0.064 (3)	0.057 (3)	−0.021 (2)	0.0161 (19)	−0.038 (2)
C16	0.047 (2)	0.050 (2)	0.046 (2)	−0.0159 (19)	0.0047 (18)	−0.0229 (19)
C24	0.054 (3)	0.044 (2)	0.050 (2)	−0.0172 (19)	0.003 (2)	−0.0145 (19)
C28	0.048 (2)	0.047 (2)	0.067 (3)	−0.016 (2)	0.015 (2)	−0.013 (2)
C14	0.081 (4)	0.078 (3)	0.042 (2)	−0.050 (3)	0.021 (2)	−0.035 (2)
C13	0.061 (3)	0.088 (4)	0.063 (3)	−0.044 (3)	0.031 (2)	−0.049 (3)
C26	0.072 (4)	0.083 (4)	0.047 (3)	−0.044 (3)	−0.006 (3)	−0.011 (3)
C25	0.092 (4)	0.061 (3)	0.052 (3)	−0.033 (3)	0.011 (3)	−0.026 (2)
C15	0.070 (3)	0.056 (3)	0.049 (3)	−0.025 (2)	−0.003 (2)	−0.016 (2)
C27	0.049 (3)	0.067 (3)	0.059 (3)	−0.016 (2)	−0.008 (2)	0.003 (3)
S2	0.0384 (4)	0.0311 (4)	0.0378 (4)	−0.0173 (3)	0.0080 (3)	−0.0145 (3)
C2	0.0362 (17)	0.0407 (18)	0.0416 (18)	−0.0218 (15)	0.0081 (14)	−0.0230 (15)
C17A	0.062 (5)	0.040 (3)	0.036 (2)	−0.022 (3)	0.010 (3)	−0.018 (2)
C18A	0.056 (6)	0.037 (5)	0.044 (5)	−0.023 (4)	0.011 (4)	−0.022 (4)
C19A	0.093 (11)	0.052 (6)	0.059 (7)	−0.022 (6)	0.018 (7)	−0.028 (5)
C20A	0.128 (15)	0.048 (6)	0.082 (8)	−0.053 (8)	0.059 (9)	−0.046 (6)
C21A	0.118 (11)	0.067 (7)	0.078 (7)	−0.061 (8)	0.019 (7)	−0.036 (6)
C22A	0.090 (10)	0.056 (7)	0.075 (8)	−0.044 (7)	0.033 (7)	−0.037 (6)
C19B	0.122 (13)	0.076 (8)	0.074 (8)	0.012 (8)	0.007 (8)	−0.037 (7)
C20B	0.169 (18)	0.050 (6)	0.107 (10)	−0.030 (8)	0.067 (10)	−0.037 (6)
C21B	0.181 (15)	0.077 (8)	0.139 (12)	−0.083 (10)	0.020 (11)	−0.050 (8)
C22B	0.117 (12)	0.075 (8)	0.148 (14)	−0.060 (9)	0.036 (10)	−0.073 (9)
C17B	0.062 (5)	0.040 (3)	0.036 (2)	−0.022 (3)	0.010 (3)	−0.018 (2)
C18B	0.074 (9)	0.074 (8)	0.085 (9)	−0.026 (6)	0.004 (6)	−0.048 (7)
C5A	0.040 (2)	0.052 (3)	0.0291 (18)	−0.024 (2)	0.0114 (16)	−0.0162 (17)
C6A	0.081 (11)	0.060 (8)	0.074 (10)	−0.014 (8)	0.027 (9)	−0.046 (8)
C7A	0.107 (12)	0.094 (12)	0.078 (10)	−0.027 (10)	0.025 (10)	−0.026 (10)
C8A	0.19 (2)	0.111 (15)	0.056 (10)	−0.096 (17)	0.065 (13)	−0.048 (10)
C9A	0.118 (11)	0.067 (7)	0.078 (7)	−0.061 (8)	0.019 (7)	−0.036 (6)
C10A	0.046 (6)	0.066 (7)	0.029 (6)	−0.029 (6)	0.009 (5)	0.001 (5)
C5B	0.040 (2)	0.052 (3)	0.0291 (18)	−0.024 (2)	0.0114 (16)	−0.0162 (17)
C6B	0.048 (5)	0.063 (5)	0.035 (3)	−0.026 (4)	0.012 (3)	−0.021 (4)
C7B	0.092 (7)	0.067 (5)	0.050 (5)	−0.034 (5)	0.034 (5)	−0.040 (5)
C8B	0.109 (9)	0.076 (7)	0.038 (4)	−0.060 (7)	0.023 (5)	−0.034 (4)
C9B	0.074 (5)	0.100 (7)	0.022 (3)	−0.056 (5)	0.013 (3)	−0.026 (4)
C10B	0.049 (4)	0.076 (6)	0.036 (5)	−0.031 (4)	0.006 (3)	−0.023 (4)

Geometric parameters (Å, º) top

Pt1—S1	2.2711 (8)	C17A—C18A	1.3900
Pt1—S2	2.2722 (9)	C17A—C22A	1.4148
Pt1—Cl2	2.3096 (9)	C18A—C19A	1.3985
Pt1—Cl1	2.3127 (9)	C18A—H18A	0.9300
S1—C2	1.8188 (19)	C19A—C20A	1.4119
S1—C1	1.821 (4)	C19A—H19A	0.9300
C11—C16	1.378 (6)	C20A—C21A	1.3797
C11—C12	1.390 (6)	C20A—H20A	0.9300
C11—C2	1.494 (4)	C21A—C22A	1.3989
C1—C5B	1.452 (4)	C21A—H21A	0.9300
C1—C5A	1.550 (4)	C22A—H22A	0.9300
C1—H1A	0.9700	C19B—C18B	1.3815
C1—H1B	0.9700	C19B—C20B	1.4110
C23—C24	1.383 (6)	C19B—H19B	0.9300
C23—C28	1.384 (6)	C20B—C21B	1.2482
C23—C4	1.499 (6)	C20B—H20B	0.9300
C4—S2	1.827 (4)	C21B—C22B	1.4023
C4—H4A	0.9700	C21B—H21B	0.9300
C4—H4B	0.9700	C22B—C17B	1.3233
C3—C17B	1.435 (5)	C22B—H22B	0.9300
C3—C17A	1.584 (5)	C17B—C18B	1.3622
C3—S2	1.829 (4)	C18B—H18B	0.9300
C3—H3A	0.9700	C5A—C10A	1.3953
C3—H3B	0.9700	C5A—C6A	1.3958
C12—C13	1.382 (7)	C6A—C7A	1.3902
C12—H12	0.9300	C6A—H6A	0.9300
C16—C15	1.394 (7)	C7A—C8A	1.3953
C16—H16	0.9300	C7A—H7A	0.9300
C24—C25	1.386 (7)	C8A—C9A	1.3958
C24—H24	0.9300	C8A—H8A	0.9300
C28—C27	1.395 (8)	C9A—C10A	1.3902
C28—H28	0.9300	C9A—H9A	0.9300
C14—C13	1.357 (8)	C10A—H10A	0.9300
C14—C15	1.369 (8)	C5B—C6B	1.3951
C14—H14	0.9300	C5B—C10B	1.3960
C13—H13	0.9300	C6B—C7B	1.3902
C26—C27	1.354 (9)	C6B—H6B	0.9300
C26—C25	1.377 (8)	C7B—C8B	1.3960
C26—H26	0.9300	C7B—H7B	0.9300
C25—H25	0.9300	C8B—C9B	1.3951
C15—H15	0.9300	C8B—H8B	0.9300
C27—H27	0.9300	C9B—C10B	1.3902
C2—H2A	0.9700	C9B—H9B	0.9300
C2—H2B	0.9700	C10B—H10B	0.9300

S1—Pt1—S2	87.11 (3)	C11—C2—H2B	109.6
S1—Pt1—Cl2	178.13 (3)	S1—C2—H2B	109.6
S2—Pt1—Cl2	91.13 (4)	H2A—C2—H2B	108.1
S1—Pt1—Cl1	92.03 (3)	C18A—C17A—C22A	118.6
S2—Pt1—Cl1	173.86 (3)	C18A—C17A—C3	122.84 (18)
Cl2—Pt1—Cl1	89.79 (4)	C22A—C17A—C3	118.37 (18)
C2—S1—C1	99.91 (14)	C17A—C18A—C19A	120.8
C2—S1—Pt1	109.39 (8)	C17A—C18A—H18A	119.6
C1—S1—Pt1	105.96 (12)	C19A—C18A—H18A	119.6
C16—C11—C12	119.0 (4)	C18A—C19A—C20A	120.3
C16—C11—C2	121.5 (3)	C18A—C19A—H19A	119.8
C12—C11—C2	119.5 (4)	C20A—C19A—H19A	119.8
C5B—C1—S1	111.0 (2)	C21A—C20A—C19A	118.7
C5A—C1—S1	107.7 (2)	C21A—C20A—H20A	120.6
C5B—C1—H1A	102.2	C19A—C20A—H20A	120.6
C5A—C1—H1A	110.2	C20A—C21A—C22A	121.1
S1—C1—H1A	110.2	C20A—C21A—H21A	119.5
C5B—C1—H1B	114.5	C22A—C21A—H21A	119.5
C5A—C1—H1B	110.2	C21A—C22A—C17A	120.3
S1—C1—H1B	110.2	C21A—C22A—H22A	119.9
H1A—C1—H1B	108.5	C17A—C22A—H22A	119.9
C24—C23—C28	118.4 (4)	C18B—C19B—C20B	115.8
C24—C23—C4	120.6 (4)	C18B—C19B—H19B	122.1
C28—C23—C4	121.0 (4)	C20B—C19B—H19B	122.1
C23—C4—S2	110.0 (3)	C21B—C20B—C19B	118.4
C23—C4—H4A	109.7	C21B—C20B—H20B	120.8
S2—C4—H4A	109.7	C19B—C20B—H20B	120.8
C23—C4—H4B	109.7	C20B—C21B—C22B	125.3
S2—C4—H4B	109.7	C20B—C21B—H21B	117.3
H4A—C4—H4B	108.2	C22B—C21B—H21B	117.3
C17B—C3—S2	117.4 (3)	C17B—C22B—C21B	119.4
C17A—C3—S2	106.8 (3)	C17B—C22B—H22B	120.3
C17B—C3—H3A	96.5	C21B—C22B—H22B	120.3
C17A—C3—H3A	110.4	C22B—C17B—C18B	116.1
S2—C3—H3A	110.4	C22B—C17B—C3	125.0 (2)
C17B—C3—H3B	112.6	C18B—C17B—C3	118.8 (2)
C17A—C3—H3B	110.4	C17B—C18B—C19B	124.8
S2—C3—H3B	110.4	C17B—C18B—H18B	117.6
H3A—C3—H3B	108.6	C19B—C18B—H18B	117.6
C13—C12—C11	120.6 (5)	C10A—C5A—C6A	120.3
C13—C12—H12	119.7	C10A—C5A—C1	120.35 (17)
C11—C12—H12	119.7	C6A—C5A—C1	119.39 (17)
C11—C16—C15	120.0 (4)	C7A—C6A—C5A	119.9
C11—C16—H16	120.0	C7A—C6A—H6A	120.1
C15—C16—H16	120.0	C5A—C6A—H6A	120.1
C23—C24—C25	120.8 (5)	C6A—C7A—C8A	119.9
C23—C24—H24	119.6	C6A—C7A—H7A	120.1
C25—C24—H24	119.6	C8A—C7A—H7A	120.1
C23—C28—C27	120.4 (5)	C7A—C8A—C9A	120.3
C23—C28—H28	119.8	C7A—C8A—H8A	119.9
C27—C28—H28	119.8	C9A—C8A—H8A	119.9
C13—C14—C15	121.0 (5)	C10A—C9A—C8A	119.9
C13—C14—H14	119.5	C10A—C9A—H9A	120.1
C15—C14—H14	119.5	C8A—C9A—H9A	120.1
C14—C13—C12	119.8 (5)	C9A—C10A—C5A	119.9
C14—C13—H13	120.1	C9A—C10A—H10A	120.1
C12—C13—H13	120.1	C5A—C10A—H10A	120.1
C27—C26—C25	120.1 (5)	C6B—C5B—C10B	120.3
C27—C26—H26	120.0	C6B—C5B—C1	117.87 (19)
C25—C26—H26	120.0	C10B—C5B—C1	121.87 (19)
C26—C25—C24	119.9 (6)	C7B—C6B—C5B	119.8
C26—C25—H25	120.0	C7B—C6B—H6B	120.1
C24—C25—H25	120.0	C5B—C6B—H6B	120.1
C14—C15—C16	119.7 (5)	C6B—C7B—C8B	119.9
C14—C15—H15	120.1	C6B—C7B—H7B	120.0
C16—C15—H15	120.1	C8B—C7B—H7B	120.0
C26—C27—C28	120.5 (5)	C9B—C8B—C7B	120.3
C26—C27—H27	119.8	C9B—C8B—H8B	119.9
C28—C27—H27	119.8	C7B—C8B—H8B	119.9
C4—S2—C3	100.7 (2)	C10B—C9B—C8B	119.8
C4—S2—Pt1	111.10 (16)	C10B—C9B—H9B	120.1
C3—S2—Pt1	101.03 (15)	C8B—C9B—H9B	120.1
C11—C2—S1	110.34 (16)	C9B—C10B—C5B	119.9
C11—C2—H2A	109.6	C9B—C10B—H10B	120.0
S1—C2—H2A	109.6	C5B—C10B—H10B	120.0

(abtri150) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	Z = 2
M_r = 694.61	F(000) = 680
Triclinic, P1	D_x = 1.662 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.2603 (4) Å	Cell parameters from 13805 reflections
b = 12.1587 (7) Å	θ = 2.6–32.7°
c = 15.7688 (10) Å	µ = 5.41 mm⁻¹
α = 68.644 (5)°	T = 150 K
β = 89.262 (5)°	Prism, yellow
γ = 71.368 (5)°	0.28 × 0.19 × 0.13 mm
V = 1388.04 (14) Å³

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	8761 independent reflections
Radiation source: Sealed tube	7902 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.017
ω–scans	θ_max = 32.7°, θ_min = 2.6°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −12→8
T_min = 0.299, T_max = 0.560	k = −18→15
13680 measured reflections	l = −23→22

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.020	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.052	H-atom parameters constrained
S = 0.98	w = 1/[σ²(F_o²) + (0.0342P)²] where P = (F_o² + 2F_c²)/3
8761 reflections	(Δ/σ)_max = 0.014
336 parameters	Δρ_max = 2.13 e Å⁻³
30 restraints	Δρ_min = −0.85 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	γ = 71.368 (5)°
M_r = 694.61	V = 1388.04 (14) Å³
Triclinic, P1	Z = 2
a = 8.2603 (4) Å	Mo Kα radiation
b = 12.1587 (7) Å	µ = 5.41 mm⁻¹
c = 15.7688 (10) Å	T = 150 K
α = 68.644 (5)°	0.28 × 0.19 × 0.13 mm
β = 89.262 (5)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	8761 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	7902 reflections with I > 2σ(I)
T_min = 0.299, T_max = 0.560	R_int = 0.017
13680 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.020	30 restraints
wR(F²) = 0.052	H-atom parameters constrained
S = 0.98	Δρ_max = 2.13 e Å⁻³
8761 reflections	Δρ_min = −0.85 e Å⁻³
336 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Pt1	0.580595 (9)	0.910438 (7)	0.767088 (5)	0.02075 (3)
S1	0.85689 (6)	0.90674 (5)	0.77068 (3)	0.02070 (9)
Cl2	0.30289 (7)	0.90674 (6)	0.76613 (4)	0.03340 (11)
Cl1	0.47504 (7)	1.12590 (5)	0.72552 (4)	0.03033 (10)
C11	0.8794 (3)	0.9420 (2)	0.93069 (15)	0.0258 (4)
C1	0.8810 (3)	1.0008 (2)	0.65434 (14)	0.0279 (4)
H1A	0.7820	1.0770	0.6295	0.033*
H1B	0.9833	1.0237	0.6541	0.033*
C23	0.6342 (3)	0.5954 (2)	0.96915 (16)	0.0299 (4)
C4	0.5744 (3)	0.6144 (2)	0.87382 (16)	0.0346 (5)
H4A	0.4515	0.6594	0.8604	0.042*
H4B	0.5964	0.5336	0.8692	0.042*
C12	0.7383 (3)	0.9879 (3)	0.97200 (19)	0.0364 (5)
H12	0.6441	1.0557	0.9364	0.044*
C16	1.0171 (3)	0.8399 (2)	0.98480 (17)	0.0345 (5)
H16	1.1123	0.8074	0.9581	0.041*
C24	0.5481 (3)	0.6789 (2)	1.00908 (18)	0.0373 (5)
H24	0.4530	0.7482	0.9763	0.045*
C28	0.7761 (3)	0.4935 (2)	1.0198 (2)	0.0426 (6)
H28	0.8357	0.4367	0.9941	0.051*
C14	0.8716 (4)	0.8341 (3)	1.11783 (18)	0.0438 (6)
H14	0.8689	0.7980	1.1807	0.053*
C13	0.7365 (4)	0.9340 (3)	1.0650 (2)	0.0452 (7)
H13	0.6417	0.9663	1.0920	0.054*
C26	0.7434 (4)	0.5581 (3)	1.1467 (2)	0.0499 (7)
H26	0.7791	0.5457	1.2061	0.060*
C25	0.6028 (4)	0.6597 (3)	1.0971 (2)	0.0479 (7)
H25	0.5439	0.7161	1.1233	0.057*
C15	1.0138 (4)	0.7858 (3)	1.07853 (19)	0.0434 (6)
H15	1.1066	0.7173	1.1148	0.052*
C27	0.8303 (4)	0.4754 (3)	1.1084 (2)	0.0516 (7)
H27	0.9259	0.4068	1.1416	0.062*
S2	0.68717 (7)	0.70336 (5)	0.79120 (4)	0.02609 (10)
C2	0.8824 (3)	1.0049 (2)	0.82986 (15)	0.0265 (4)
H2A	0.9906	1.0200	0.8187	0.032*
H2B	0.7901	1.0853	0.8063	0.032*
C3	0.5996 (4)	0.7043 (2)	0.68465 (17)	0.0363 (5)
H3A	0.4755	0.7264	0.6823	0.044*
H3B	0.6253	0.7666	0.6325	0.044*
C17A	0.6794 (3)	0.57266 (16)	0.67988 (10)	0.0391 (9)	0.606 (7)
C18A	0.8518 (3)	0.53005 (16)	0.66722 (12)	0.0471 (15)	0.606 (7)
H18A	0.9205	0.5784	0.6648	0.057*	0.606 (7)
C19A	0.9215 (4)	0.41517 (18)	0.65818 (19)	0.0630 (19)	0.606 (7)
H19A	1.0369	0.3867	0.6497	0.076*	0.606 (7)
C20A	0.8189 (5)	0.34290 (17)	0.66179 (18)	0.061 (2)	0.606 (7)
H20A	0.8656	0.2660	0.6557	0.074*	0.606 (7)
C21A	0.6466 (5)	0.3855 (2)	0.67445 (15)	0.064 (2)	0.606 (7)
H21A	0.5779	0.3372	0.6769	0.077*	0.606 (7)
C22A	0.5768 (4)	0.5004 (2)	0.68349 (15)	0.0524 (16)	0.606 (7)
H22A	0.4615	0.5289	0.6920	0.063*	0.606 (7)
C17B	0.6429 (3)	0.58620 (17)	0.67502 (12)	0.0391 (9)	0.39
C18B	0.8140 (3)	0.52064 (15)	0.67285 (11)	0.054 (3)	0.394 (7)
H18B	0.8992	0.5530	0.6787	0.065*	0.394 (7)
C19B	0.8576 (4)	0.40668 (16)	0.66195 (17)	0.071 (4)	0.394 (7)
H19B	0.9720	0.3628	0.6605	0.085*	0.394 (7)
C20B	0.7301 (5)	0.35828 (19)	0.65322 (16)	0.068 (4)	0.394 (7)
H20B	0.7593	0.2820	0.6459	0.081*	0.394 (7)
C21B	0.5591 (5)	0.4238 (2)	0.65539 (17)	0.094 (5)	0.394 (7)
H21B	0.4738	0.3915	0.6496	0.113*	0.394 (7)
C22B	0.5155 (4)	0.5378 (2)	0.66630 (18)	0.075 (4)	0.394 (7)
H22B	0.4010	0.5817	0.6678	0.090*	0.394 (7)
C5A	0.8962 (3)	0.9191 (2)	0.59578 (12)	0.026 (2)	0.373 (11)
C6A	1.0386 (3)	0.8116 (3)	0.61286 (18)	0.043 (2)	0.373 (11)
H6A	1.1260	0.7884	0.6591	0.051*	0.373 (11)
C7A	1.0504 (3)	0.7390 (3)	0.5608 (2)	0.065 (3)	0.373 (11)
H7A	1.1457	0.6671	0.5723	0.078*	0.373 (11)
C8A	0.9198 (4)	0.7738 (3)	0.49176 (14)	0.059 (3)	0.373 (11)
H8A	0.9277	0.7252	0.4570	0.071*	0.373 (11)
C9A	0.7775 (4)	0.8812 (2)	0.47469 (9)	0.041 (2)	0.373 (11)
H9A	0.6901	0.9045	0.4285	0.049*	0.373 (11)
C10A	0.7657 (4)	0.9539 (2)	0.52670 (11)	0.034 (2)	0.373 (11)
H10A	0.6704	1.0257	0.5153	0.040*	0.373 (11)
C5B	0.8733 (4)	0.9372 (2)	0.59250 (12)	0.0313 (14)	0.627 (11)
C6B	1.0134 (3)	0.8341 (3)	0.59653 (17)	0.0371 (13)	0.627 (11)
H6B	1.1096	0.8058	0.6388	0.044*	0.627 (11)
C7B	1.0098 (3)	0.7734 (3)	0.53740 (18)	0.0450 (15)	0.627 (11)
H7B	1.1036	0.7044	0.5401	0.054*	0.627 (11)
C8B	0.8661 (4)	0.8157 (3)	0.47425 (11)	0.0475 (16)	0.627 (11)
H8B	0.8637	0.7751	0.4347	0.057*	0.627 (11)
C9B	0.7260 (5)	0.9189 (2)	0.47021 (10)	0.0465 (15)	0.627 (11)
H9B	0.6299	0.9472	0.4280	0.056*	0.627 (11)
C10B	0.7296 (4)	0.97961 (19)	0.52935 (13)	0.0379 (12)	0.627 (11)
H10B	0.6359	1.0486	0.5267	0.045*	0.627 (11)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.01984 (4)	0.02378 (4)	0.02193 (4)	−0.01029 (3)	0.00425 (3)	−0.00991 (3)
S1	0.0198 (2)	0.0238 (2)	0.0225 (2)	−0.01020 (17)	0.00421 (17)	−0.01087 (18)
Cl2	0.0208 (2)	0.0438 (3)	0.0388 (3)	−0.0153 (2)	0.0054 (2)	−0.0155 (2)
Cl1	0.0282 (2)	0.0241 (2)	0.0374 (3)	−0.00682 (19)	0.0031 (2)	−0.0121 (2)
C11	0.0283 (10)	0.0311 (10)	0.0294 (10)	−0.0168 (8)	0.0059 (8)	−0.0183 (9)
C1	0.0283 (10)	0.0340 (11)	0.0246 (10)	−0.0178 (9)	0.0075 (8)	−0.0085 (8)
C23	0.0334 (11)	0.0270 (10)	0.0317 (11)	−0.0186 (9)	0.0058 (9)	−0.0066 (9)
C4	0.0447 (13)	0.0332 (11)	0.0342 (12)	−0.0272 (11)	0.0088 (10)	−0.0100 (10)
C12	0.0322 (12)	0.0434 (14)	0.0428 (14)	−0.0145 (10)	0.0088 (10)	−0.0255 (12)
C16	0.0341 (12)	0.0361 (12)	0.0368 (12)	−0.0120 (10)	0.0043 (10)	−0.0175 (10)
C24	0.0404 (13)	0.0309 (11)	0.0355 (12)	−0.0113 (10)	0.0021 (10)	−0.0076 (10)
C28	0.0369 (13)	0.0348 (13)	0.0488 (15)	−0.0109 (10)	0.0104 (11)	−0.0089 (11)
C14	0.0636 (18)	0.0562 (17)	0.0316 (12)	−0.0395 (15)	0.0130 (12)	−0.0224 (12)
C13	0.0479 (15)	0.0658 (18)	0.0461 (15)	−0.0328 (14)	0.0228 (13)	−0.0373 (15)
C26	0.0531 (17)	0.0608 (19)	0.0368 (14)	−0.0325 (15)	−0.0054 (13)	−0.0082 (13)
C25	0.0658 (19)	0.0451 (15)	0.0393 (14)	−0.0241 (14)	0.0065 (13)	−0.0186 (12)
C15	0.0535 (16)	0.0410 (14)	0.0340 (13)	−0.0175 (12)	−0.0031 (12)	−0.0106 (11)
C27	0.0371 (14)	0.0504 (17)	0.0469 (16)	−0.0127 (12)	−0.0059 (12)	0.0027 (13)
S2	0.0293 (2)	0.0235 (2)	0.0298 (3)	−0.0137 (2)	0.0064 (2)	−0.0109 (2)
C2	0.0291 (10)	0.0281 (10)	0.0309 (10)	−0.0153 (8)	0.0045 (8)	−0.0159 (9)
C3	0.0505 (15)	0.0370 (12)	0.0311 (11)	−0.0225 (11)	0.0057 (10)	−0.0171 (10)
C17A	0.063 (2)	0.0338 (15)	0.0311 (13)	−0.0260 (16)	0.0150 (14)	−0.0166 (11)
C18A	0.069 (4)	0.030 (3)	0.048 (4)	−0.021 (3)	0.021 (3)	−0.017 (3)
C19A	0.098 (5)	0.046 (3)	0.056 (4)	−0.034 (3)	0.039 (3)	−0.026 (3)
C20A	0.101 (6)	0.043 (3)	0.061 (4)	−0.040 (4)	0.034 (4)	−0.033 (3)
C21A	0.097 (7)	0.046 (4)	0.072 (4)	−0.050 (5)	0.018 (4)	−0.026 (3)
C22A	0.075 (4)	0.047 (3)	0.055 (3)	−0.042 (3)	0.021 (3)	−0.024 (3)
C17B	0.063 (2)	0.0338 (15)	0.0311 (13)	−0.0260 (16)	0.0150 (14)	−0.0166 (11)
C18B	0.094 (8)	0.042 (5)	0.043 (5)	−0.034 (6)	0.026 (5)	−0.026 (4)
C19B	0.121 (9)	0.033 (4)	0.057 (6)	−0.017 (5)	0.041 (6)	−0.023 (4)
C20B	0.112 (12)	0.032 (5)	0.066 (7)	−0.031 (6)	0.031 (6)	−0.022 (4)
C21B	0.127 (11)	0.057 (6)	0.125 (10)	−0.054 (7)	0.009 (8)	−0.043 (7)
C22B	0.092 (8)	0.047 (5)	0.111 (10)	−0.037 (6)	0.024 (7)	−0.046 (6)
C5A	0.024 (3)	0.049 (4)	0.018 (4)	−0.025 (3)	0.009 (3)	−0.018 (3)
C6A	0.039 (4)	0.053 (5)	0.041 (4)	−0.008 (4)	0.008 (4)	−0.030 (4)
C7A	0.081 (8)	0.056 (6)	0.045 (5)	−0.005 (5)	0.011 (5)	−0.022 (5)
C8A	0.102 (8)	0.067 (6)	0.034 (5)	−0.052 (6)	0.026 (5)	−0.028 (4)
C9A	0.049 (5)	0.068 (6)	0.025 (4)	−0.039 (5)	0.008 (3)	−0.023 (4)
C10A	0.029 (3)	0.049 (4)	0.025 (4)	−0.021 (3)	0.012 (3)	−0.010 (3)
C5B	0.033 (2)	0.033 (2)	0.028 (3)	−0.016 (2)	0.012 (2)	−0.009 (2)
C6B	0.039 (3)	0.043 (3)	0.031 (2)	−0.017 (2)	0.007 (2)	−0.013 (2)
C7B	0.061 (3)	0.042 (3)	0.038 (3)	−0.020 (3)	0.022 (3)	−0.021 (2)
C8B	0.072 (4)	0.061 (4)	0.031 (2)	−0.041 (4)	0.022 (3)	−0.027 (3)
C9B	0.049 (3)	0.074 (4)	0.025 (2)	−0.033 (3)	0.0070 (18)	−0.017 (2)
C10B	0.033 (2)	0.056 (3)	0.029 (3)	−0.018 (2)	0.0043 (17)	−0.017 (2)

Geometric parameters (Å, º) top

Pt1—S1	2.2694 (5)	C17A—C18A	1.3900
Pt1—S2	2.2703 (5)	C17A—C22A	1.3900
Pt1—Cl2	2.3090 (5)	C18A—C19A	1.3900
Pt1—Cl1	2.3146 (5)	C18A—H18A	0.9300
S1—C2	1.821 (2)	C19A—C20A	1.3900
S1—C1	1.822 (2)	C19A—H19A	0.9300
C11—C16	1.384 (3)	C20A—C21A	1.3900
C11—C12	1.387 (3)	C20A—H20A	0.9300
C11—C2	1.496 (3)	C21A—C22A	1.3900
C1—C5B	1.461 (3)	C21A—H21A	0.9300
C1—C5A	1.562 (3)	C22A—H22A	0.9300
C1—H1A	0.9700	C17B—C18B	1.3900
C1—H1B	0.9700	C17B—C22B	1.3901
C23—C28	1.386 (3)	C18B—C19B	1.3900
C23—C24	1.387 (3)	C18B—H18B	0.9300
C23—C4	1.500 (3)	C19B—C20B	1.3900
C4—S2	1.822 (2)	C19B—H19B	0.9300
C4—H4A	0.9700	C20B—C21B	1.3900
C4—H4B	0.9700	C20B—H20B	0.9300
C12—C13	1.373 (4)	C21B—C22B	1.3900
C12—H12	0.9300	C21B—H21B	0.9300
C16—C15	1.386 (4)	C22B—H22B	0.9300
C16—H16	0.9300	C5A—C10A	1.3900
C24—C25	1.378 (4)	C5A—C6A	1.3900
C24—H24	0.9300	C6A—C7A	1.3901
C28—C27	1.389 (4)	C6A—H6A	0.9300
C28—H28	0.9300	C7A—C8A	1.3900
C14—C13	1.355 (4)	C7A—H7A	0.9300
C14—C15	1.383 (4)	C8A—C9A	1.3900
C14—H14	0.9300	C8A—H8A	0.9300
C13—H13	0.9300	C9A—C10A	1.3900
C26—C27	1.364 (5)	C9A—H9A	0.9300
C26—C25	1.374 (4)	C10A—H10A	0.9300
C26—H26	0.9300	C5B—C6B	1.3900
C25—H25	0.9300	C5B—C10B	1.3900
C15—H15	0.9300	C6B—C7B	1.3900
C27—H27	0.9300	C6B—H6B	0.9300
S2—C3	1.832 (2)	C7B—C8B	1.3900
C2—H2A	0.9700	C7B—H7B	0.9300
C2—H2B	0.9700	C8B—C9B	1.3900
C3—C17B	1.429 (3)	C8B—H8B	0.9300
C3—C17A	1.554 (3)	C9B—C10B	1.3900
C3—H3A	0.9700	C9B—H9B	0.9300
C3—H3B	0.9700	C10B—H10B	0.9300

S1—Pt1—S2	87.231 (19)	C17A—C3—H3B	109.7
S1—Pt1—Cl2	178.014 (19)	S2—C3—H3B	109.7
S2—Pt1—Cl2	90.91 (2)	H3A—C3—H3B	108.2
S1—Pt1—Cl1	91.933 (19)	C18A—C17A—C22A	120.0
S2—Pt1—Cl1	173.656 (19)	C18A—C17A—C3	119.81 (11)
Cl2—Pt1—Cl1	89.99 (2)	C22A—C17A—C3	120.10 (11)
C2—S1—C1	99.78 (10)	C19A—C18A—C17A	120.0
C2—S1—Pt1	109.57 (7)	C19A—C18A—H18A	120.0
C1—S1—Pt1	105.85 (7)	C17A—C18A—H18A	120.0
C16—C11—C12	118.7 (2)	C18A—C19A—C20A	120.0
C16—C11—C2	121.3 (2)	C18A—C19A—H19A	120.0
C12—C11—C2	119.9 (2)	C20A—C19A—H19A	120.0
C5B—C1—S1	110.45 (14)	C21A—C20A—C19A	120.0
C5A—C1—S1	107.16 (13)	C21A—C20A—H20A	120.0
C5B—C1—H1A	102.5	C19A—C20A—H20A	120.0
C5A—C1—H1A	110.3	C20A—C21A—C22A	120.0
S1—C1—H1A	110.3	C20A—C21A—H21A	120.0
C5B—C1—H1B	114.5	C22A—C21A—H21A	120.0
C5A—C1—H1B	110.3	C21A—C22A—C17A	120.0
S1—C1—H1B	110.3	C21A—C22A—H22A	120.0
H1A—C1—H1B	108.5	C17A—C22A—H22A	120.0
C28—C23—C24	118.4 (2)	C18B—C17B—C22B	120.0
C28—C23—C4	120.8 (2)	C18B—C17B—C3	119.41 (13)
C24—C23—C4	120.8 (2)	C22B—C17B—C3	120.58 (13)
C23—C4—S2	109.99 (15)	C17B—C18B—C19B	120.0
C23—C4—H4A	109.7	C17B—C18B—H18B	120.0
S2—C4—H4A	109.7	C19B—C18B—H18B	120.0
C23—C4—H4B	109.7	C18B—C19B—C20B	120.0
S2—C4—H4B	109.7	C18B—C19B—H19B	120.0
H4A—C4—H4B	108.2	C20B—C19B—H19B	120.0
C13—C12—C11	120.6 (3)	C21B—C20B—C19B	120.0
C13—C12—H12	119.7	C21B—C20B—H20B	120.0
C11—C12—H12	119.7	C19B—C20B—H20B	120.0
C11—C16—C15	120.3 (2)	C22B—C21B—C20B	120.0
C11—C16—H16	119.9	C22B—C21B—H21B	120.0
C15—C16—H16	119.9	C20B—C21B—H21B	120.0
C25—C24—C23	120.3 (3)	C21B—C22B—C17B	120.0
C25—C24—H24	119.8	C21B—C22B—H22B	120.0
C23—C24—H24	119.8	C17B—C22B—H22B	120.0
C23—C28—C27	120.8 (3)	C10A—C5A—C6A	120.0
C23—C28—H28	119.6	C10A—C5A—C1	119.58 (16)
C27—C28—H28	119.6	C6A—C5A—C1	120.42 (16)
C13—C14—C15	120.2 (3)	C5A—C6A—C7A	120.0
C13—C14—H14	119.9	C5A—C6A—H6A	120.0
C15—C14—H14	119.9	C7A—C6A—H6A	120.0
C14—C13—C12	120.6 (3)	C8A—C7A—C6A	120.0
C14—C13—H13	119.7	C8A—C7A—H7A	120.0
C12—C13—H13	119.7	C6A—C7A—H7A	120.0
C27—C26—C25	119.8 (3)	C9A—C8A—C7A	120.0
C27—C26—H26	120.1	C9A—C8A—H8A	120.0
C25—C26—H26	120.1	C7A—C8A—H8A	120.0
C26—C25—C24	120.7 (3)	C8A—C9A—C10A	120.0
C26—C25—H25	119.6	C8A—C9A—H9A	120.0
C24—C25—H25	119.6	C10A—C9A—H9A	120.0
C14—C15—C16	119.7 (3)	C5A—C10A—C9A	120.0
C14—C15—H15	120.2	C5A—C10A—H10A	120.0
C16—C15—H15	120.2	C9A—C10A—H10A	120.0
C26—C27—C28	120.0 (3)	C6B—C5B—C10B	120.0
C26—C27—H27	120.0	C6B—C5B—C1	119.06 (17)
C28—C27—H27	120.0	C10B—C5B—C1	120.94 (17)
C4—S2—C3	100.45 (11)	C5B—C6B—C7B	120.0
C4—S2—Pt1	111.39 (9)	C5B—C6B—H6B	120.0
C3—S2—Pt1	101.08 (8)	C7B—C6B—H6B	120.0
C11—C2—S1	110.20 (14)	C8B—C7B—C6B	120.0
C11—C2—H2A	109.6	C8B—C7B—H7B	120.0
S1—C2—H2A	109.6	C6B—C7B—H7B	120.0
C11—C2—H2B	109.6	C7B—C8B—C9B	120.0
S1—C2—H2B	109.6	C7B—C8B—H8B	120.0
H2A—C2—H2B	108.1	C9B—C8B—H8B	120.0
C17B—C3—S2	116.88 (18)	C8B—C9B—C10B	120.0
C17A—C3—S2	109.88 (17)	C8B—C9B—H9B	120.0
C17B—C3—H3A	100.0	C10B—C9B—H9B	120.0
C17A—C3—H3A	109.7	C5B—C10B—C9B	120.0
S2—C3—H3A	109.7	C5B—C10B—H10B	120.0
C17B—C3—H3B	111.7	C9B—C10B—H10B	120.0

(tri100) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	Z = 2
M_r = 694.61	F(000) = 680
Triclinic, P1	D_x = 1.669 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.2487 (3) Å	Cell parameters from 13506 reflections
b = 12.1346 (6) Å	θ = 2.6–32.8°
c = 15.7583 (10) Å	µ = 5.44 mm⁻¹
α = 68.528 (6)°	T = 100 K
β = 89.499 (4)°	Prism, yellow
γ = 71.565 (4)°	0.28 × 0.19 × 0.13 mm
V = 1382.26 (14) Å³

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	8697 independent reflections
Radiation source: Sealed tube	7959 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.025
ω–scans	θ_max = 32.8°, θ_min = 2.6°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −12→7
T_min = 0.297, T_max = 0.557	k = −18→16
13506 measured reflections	l = −23→23

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.021	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.055	H-atom parameters constrained
S = 1.04	w = 1/[σ²(F_o²) + (0.0342P)²] where P = (F_o² + 2F_c²)/3
8697 reflections	(Δ/σ)_max = 0.012
396 parameters	Δρ_max = 2.43 e Å⁻³
18 restraints	Δρ_min = −1.05 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	γ = 71.565 (4)°
M_r = 694.61	V = 1382.26 (14) Å³
Triclinic, P1	Z = 2
a = 8.2487 (3) Å	Mo Kα radiation
b = 12.1346 (6) Å	µ = 5.44 mm⁻¹
c = 15.7583 (10) Å	T = 100 K
α = 68.528 (6)°	0.28 × 0.19 × 0.13 mm
β = 89.499 (4)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	8697 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	7959 reflections with I > 2σ(I)
T_min = 0.297, T_max = 0.557	R_int = 0.025
13506 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.021	18 restraints
wR(F²) = 0.055	H-atom parameters constrained
S = 1.04	Δρ_max = 2.43 e Å⁻³
8697 reflections	Δρ_min = −1.05 e Å⁻³
396 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Pt1	0.579117 (9)	0.911149 (7)	0.766985 (5)	0.01553 (3)
S1	0.85592 (6)	0.90817 (5)	0.77027 (3)	0.01494 (8)
Cl2	0.30081 (7)	0.90665 (6)	0.76604 (4)	0.02579 (11)
Cl1	0.47249 (7)	1.12727 (5)	0.72525 (4)	0.02249 (10)
C11	0.8786 (3)	0.9434 (2)	0.93053 (15)	0.0187 (4)
C1	0.8783 (3)	1.0027 (2)	0.65344 (15)	0.0214 (4)
H1A	0.7781	1.0782	0.6284	0.026*
H1B	0.9794	1.0274	0.6532	0.026*
C23	0.6341 (3)	0.5947 (2)	0.96982 (16)	0.0231 (4)
C4	0.5740 (3)	0.6139 (2)	0.87404 (16)	0.0266 (5)
H4A	0.4510	0.6587	0.8604	0.032*
H4B	0.5960	0.5329	0.8695	0.032*
C12	0.7368 (3)	0.9898 (2)	0.97162 (18)	0.0265 (5)
H12	0.6428	1.0579	0.9357	0.032*
C16	1.0170 (3)	0.8401 (2)	0.98474 (17)	0.0250 (4)
H16	1.1122	0.8081	0.9581	0.030*
C24	0.5472 (3)	0.6787 (2)	1.00945 (17)	0.0264 (5)
H24	0.4520	0.7479	0.9762	0.032*
C28	0.7773 (3)	0.4921 (2)	1.02051 (19)	0.0318 (5)
H28	0.8372	0.4356	0.9947	0.038*
C14	0.8721 (4)	0.8329 (3)	1.11866 (18)	0.0315 (5)
H14	0.8700	0.7962	1.1816	0.038*
C13	0.7347 (4)	0.9355 (3)	1.06504 (19)	0.0323 (5)
H13	0.6404	0.9681	1.0920	0.039*
C26	0.7446 (4)	0.5567 (3)	1.14809 (19)	0.0355 (6)
H26	0.7814	0.5443	1.2075	0.043*
C25	0.6021 (4)	0.6594 (3)	1.09823 (19)	0.0342 (6)
H25	0.5432	0.7156	1.1245	0.041*
C15	1.0133 (4)	0.7846 (2)	1.07877 (18)	0.0309 (5)
H15	1.1055	0.7150	1.1149	0.037*
C27	0.8310 (4)	0.4737 (3)	1.1096 (2)	0.0376 (6)
H27	0.9260	0.4046	1.1432	0.045*
S2	0.68667 (7)	0.70366 (5)	0.79120 (4)	0.01970 (10)
C2	0.8822 (3)	1.00635 (19)	0.82922 (15)	0.0196 (4)
H2A	0.9908	1.0211	0.8184	0.024*
H2B	0.7902	1.0870	0.8052	0.024*
C3	0.5992 (4)	0.7045 (2)	0.68458 (17)	0.0297 (5)
H3A	0.4752	0.7252	0.6822	0.036*
H3B	0.6240	0.7674	0.6322	0.036*
C17A	0.6825 (7)	0.5724 (7)	0.6814 (6)	0.0248 (14)	0.650 (9)
C18A	0.8534 (9)	0.5265 (6)	0.6715 (5)	0.0282 (13)	0.650 (9)
H18A	0.9238	0.5727	0.6725	0.034*	0.650 (9)
C19A	0.9248 (10)	0.4137 (7)	0.6601 (6)	0.0428 (16)	0.650 (9)
H19A	1.0401	0.3859	0.6515	0.051*	0.650 (9)
C20A	0.8200 (10)	0.3427 (6)	0.6618 (5)	0.0471 (17)	0.650 (9)
H20A	0.8655	0.2666	0.6546	0.057*	0.650 (9)
C21A	0.6542 (11)	0.3836 (6)	0.6739 (5)	0.0531 (19)	0.650 (9)
H21A	0.5860	0.3349	0.6757	0.064*	0.650 (9)
C22A	0.5816 (9)	0.4985 (6)	0.6838 (5)	0.0401 (14)	0.650 (9)
H22A	0.4661	0.5256	0.6921	0.048*	0.650 (9)
C19B	0.847 (2)	0.4074 (12)	0.6584 (10)	0.051 (4)	0.350 (9)
H19B	0.9623	0.3646	0.6571	0.061*	0.350 (9)
C20B	0.723 (2)	0.3608 (12)	0.6496 (12)	0.053 (3)	0.350 (9)
H20B	0.7498	0.2857	0.6406	0.064*	0.350 (9)
C21B	0.5546 (17)	0.4258 (10)	0.6542 (10)	0.0531 (19)	0.35
H21B	0.4703	0.3912	0.6508	0.064*	0.35
C22B	0.5061 (17)	0.5404 (11)	0.6634 (10)	0.045 (3)	0.350 (9)
H22B	0.3909	0.5830	0.6643	0.054*	0.350 (9)
C17B	0.6293 (16)	0.5899 (14)	0.6711 (13)	0.0248 (14)	0.35
C18B	0.7985 (18)	0.5217 (15)	0.6695 (13)	0.048 (4)	0.350 (9)
H18B	0.8838	0.5538	0.6763	0.058*	0.350 (9)
C5A	0.896 (2)	0.9205 (19)	0.5940 (13)	0.017 (2)	0.56 (4)
C6A	1.0326 (19)	0.8162 (16)	0.6115 (12)	0.027 (2)	0.56 (4)
H6A	1.1180	0.7905	0.6595	0.032*	0.56 (4)
C7A	1.045 (3)	0.746 (2)	0.5570 (15)	0.047 (3)	0.56 (4)
H7A	1.1422	0.6762	0.5666	0.056*	0.56 (4)
C8A	0.913 (4)	0.782 (3)	0.4882 (12)	0.052 (4)	0.56 (4)
H8A	0.9201	0.7339	0.4528	0.062*	0.56 (4)
C9A	0.776 (3)	0.883 (2)	0.4731 (10)	0.046 (4)	0.56 (4)
H9A	0.6870	0.9059	0.4276	0.056*	0.56 (4)
C10A	0.764 (2)	0.9569 (17)	0.5251 (9)	0.030 (2)	0.56 (4)
H10A	0.6696	1.0291	0.5137	0.036*	0.56 (4)
C5B	0.864 (3)	0.9441 (19)	0.5925 (18)	0.016 (3)	0.44 (4)
C6B	1.009 (3)	0.8421 (17)	0.5905 (12)	0.026 (3)	0.44 (4)
H6B	1.1109	0.8181	0.6278	0.032*	0.44 (4)
C7B	1.001 (2)	0.7778 (15)	0.5336 (11)	0.031 (3)	0.44 (4)
H7B	1.0932	0.7082	0.5362	0.037*	0.44 (4)
C8B	0.855 (3)	0.8186 (17)	0.4741 (14)	0.034 (3)	0.44 (4)
H8B	0.8482	0.7771	0.4356	0.041*	0.44 (4)
C9B	0.719 (2)	0.9196 (19)	0.4712 (13)	0.029 (2)	0.44 (4)
H9B	0.6221	0.9481	0.4289	0.035*	0.44 (4)
C10B	0.721 (2)	0.9815 (14)	0.5303 (10)	0.020 (2)	0.44 (4)
H10B	0.6247	1.0488	0.5278	0.024*	0.44 (4)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.01442 (4)	0.01868 (4)	0.01623 (4)	−0.00796 (3)	0.00344 (3)	−0.00773 (3)
S1	0.0143 (2)	0.0174 (2)	0.0160 (2)	−0.00743 (17)	0.00328 (17)	−0.00788 (18)
Cl2	0.0156 (2)	0.0365 (3)	0.0280 (3)	−0.0129 (2)	0.0043 (2)	−0.0118 (2)
Cl1	0.0204 (2)	0.0188 (2)	0.0264 (2)	−0.00449 (18)	0.0024 (2)	−0.0084 (2)
C11	0.0201 (10)	0.0233 (9)	0.0216 (9)	−0.0123 (8)	0.0047 (8)	−0.0142 (8)
C1	0.0205 (10)	0.0253 (10)	0.0197 (9)	−0.0127 (8)	0.0045 (8)	−0.0060 (8)
C23	0.0254 (11)	0.0219 (10)	0.0250 (10)	−0.0157 (9)	0.0062 (9)	−0.0058 (9)
C4	0.0371 (13)	0.0291 (11)	0.0255 (11)	−0.0257 (10)	0.0109 (10)	−0.0114 (9)
C12	0.0232 (11)	0.0309 (12)	0.0322 (12)	−0.0102 (9)	0.0071 (9)	−0.0188 (10)
C16	0.0237 (11)	0.0279 (11)	0.0269 (11)	−0.0095 (9)	0.0038 (9)	−0.0138 (9)
C24	0.0286 (12)	0.0223 (10)	0.0257 (11)	−0.0088 (9)	0.0027 (9)	−0.0061 (9)
C28	0.0285 (12)	0.0261 (11)	0.0371 (14)	−0.0087 (10)	0.0107 (11)	−0.0084 (10)
C14	0.0431 (15)	0.0411 (14)	0.0249 (11)	−0.0275 (12)	0.0105 (11)	−0.0177 (11)
C13	0.0337 (13)	0.0466 (15)	0.0335 (13)	−0.0229 (12)	0.0165 (11)	−0.0265 (12)
C26	0.0389 (15)	0.0420 (15)	0.0261 (12)	−0.0225 (13)	−0.0033 (11)	−0.0057 (11)
C25	0.0460 (16)	0.0305 (12)	0.0310 (13)	−0.0170 (12)	0.0058 (12)	−0.0139 (11)
C15	0.0365 (14)	0.0297 (12)	0.0252 (11)	−0.0127 (11)	−0.0009 (10)	−0.0077 (10)
C27	0.0248 (12)	0.0358 (14)	0.0374 (14)	−0.0088 (10)	−0.0013 (11)	0.0013 (12)
S2	0.0229 (2)	0.0186 (2)	0.0225 (2)	−0.01186 (19)	0.0062 (2)	−0.0092 (2)
C2	0.0224 (10)	0.0196 (9)	0.0226 (10)	−0.0111 (8)	0.0031 (8)	−0.0110 (8)
C3	0.0421 (14)	0.0327 (12)	0.0252 (11)	−0.0213 (11)	0.0066 (10)	−0.0159 (10)
C17A	0.036 (4)	0.024 (3)	0.021 (2)	−0.016 (3)	0.005 (3)	−0.010 (2)
C18A	0.046 (4)	0.022 (2)	0.027 (2)	−0.018 (2)	0.010 (3)	−0.0161 (17)
C19A	0.068 (5)	0.030 (3)	0.039 (3)	−0.022 (3)	0.018 (3)	−0.017 (2)
C20A	0.087 (5)	0.031 (3)	0.042 (3)	−0.035 (4)	0.024 (4)	−0.022 (2)
C21A	0.079 (6)	0.041 (4)	0.060 (4)	−0.043 (4)	0.017 (4)	−0.023 (3)
C22A	0.052 (4)	0.041 (3)	0.043 (3)	−0.031 (3)	0.015 (3)	−0.021 (3)
C19B	0.091 (12)	0.023 (5)	0.035 (5)	−0.007 (7)	0.011 (8)	−0.017 (4)
C20B	0.088 (9)	0.033 (5)	0.053 (6)	−0.031 (7)	0.018 (7)	−0.024 (4)
C21B	0.079 (6)	0.041 (4)	0.060 (4)	−0.043 (4)	0.017 (4)	−0.023 (3)
C22B	0.056 (7)	0.035 (6)	0.063 (8)	−0.030 (5)	0.015 (6)	−0.029 (6)
C17B	0.036 (4)	0.024 (3)	0.021 (2)	−0.016 (3)	0.005 (3)	−0.010 (2)
C18B	0.070 (12)	0.043 (6)	0.042 (6)	−0.032 (7)	−0.013 (7)	−0.015 (5)
C5A	0.013 (6)	0.027 (7)	0.016 (3)	−0.009 (5)	0.010 (4)	−0.013 (4)
C6A	0.031 (4)	0.029 (5)	0.020 (5)	−0.007 (4)	0.009 (4)	−0.012 (4)
C7A	0.053 (7)	0.057 (8)	0.048 (8)	−0.020 (6)	0.019 (6)	−0.038 (6)
C8A	0.077 (11)	0.083 (11)	0.036 (6)	−0.056 (9)	0.034 (7)	−0.043 (7)
C9A	0.065 (12)	0.076 (12)	0.019 (3)	−0.051 (9)	0.010 (7)	−0.018 (7)
C10A	0.026 (5)	0.044 (6)	0.024 (3)	−0.017 (4)	0.011 (3)	−0.012 (3)
C5B	0.011 (6)	0.013 (5)	0.024 (4)	−0.003 (4)	0.008 (4)	−0.007 (3)
C6B	0.034 (6)	0.025 (5)	0.016 (5)	−0.018 (5)	0.000 (4)	0.003 (4)
C7B	0.036 (6)	0.031 (5)	0.025 (5)	−0.011 (4)	0.013 (4)	−0.010 (4)
C8B	0.043 (8)	0.044 (7)	0.032 (5)	−0.027 (6)	0.017 (6)	−0.023 (6)
C9B	0.032 (6)	0.046 (6)	0.017 (3)	−0.022 (5)	0.005 (4)	−0.011 (4)
C10B	0.013 (5)	0.029 (4)	0.019 (3)	−0.005 (3)	0.002 (3)	−0.011 (3)

Geometric parameters (Å, º) top

Pt1—S2	2.2720 (5)	C17A—C18A	1.373 (8)
Pt1—S1	2.2728 (5)	C17A—C22A	1.394 (8)
Pt1—Cl2	2.3139 (5)	C18A—C19A	1.386 (9)
Pt1—Cl1	2.3179 (5)	C18A—H18A	0.9300
S1—C2	1.818 (2)	C19A—C20A	1.394 (7)
S1—C1	1.823 (2)	C19A—H19A	0.9300
C11—C16	1.390 (3)	C20A—C21A	1.337 (10)
C11—C12	1.393 (3)	C20A—H20A	0.9300
C11—C2	1.501 (3)	C21A—C22A	1.399 (9)
C1—C5B	1.41 (3)	C21A—H21A	0.9300
C1—C5A	1.575 (18)	C22A—H22A	0.9300
C1—H1A	0.9700	C19B—C20B	1.353 (15)
C1—H1B	0.9700	C19B—C18B	1.392 (15)
C23—C24	1.392 (3)	C19B—H19B	0.9300
C23—C28	1.394 (3)	C20B—C21B	1.376 (14)
C23—C4	1.504 (3)	C20B—H20B	0.9300
C4—S2	1.826 (2)	C21B—C22B	1.382 (12)
C4—H4A	0.9700	C21B—H21B	0.9300
C4—H4B	0.9700	C22B—C17B	1.361 (14)
C12—C13	1.378 (4)	C22B—H22B	0.9300
C12—H12	0.9300	C17B—C18B	1.384 (14)
C16—C15	1.390 (3)	C18B—H18B	0.9300
C16—H16	0.9300	C5A—C6A	1.339 (15)
C24—C25	1.386 (4)	C5A—C10A	1.39 (2)
C24—H24	0.9300	C6A—C7A	1.392 (18)
C28—C27	1.392 (4)	C6A—H6A	0.9300
C28—H28	0.9300	C7A—C8A	1.393 (16)
C14—C13	1.380 (4)	C7A—H7A	0.9300
C14—C15	1.386 (4)	C8A—C9A	1.328 (14)
C14—H14	0.9300	C8A—H8A	0.9300
C13—H13	0.9300	C9A—C10A	1.399 (17)
C26—C27	1.369 (4)	C9A—H9A	0.9300
C26—C25	1.387 (4)	C10A—H10A	0.9300
C26—H26	0.9300	C5B—C10B	1.38 (3)
C25—H25	0.9300	C5B—C6B	1.43 (2)
C15—H15	0.9300	C6B—C7B	1.40 (2)
C27—H27	0.9300	C6B—H6B	0.9300
S2—C3	1.830 (2)	C7B—C8B	1.371 (19)
C2—H2A	0.9700	C7B—H7B	0.9300
C2—H2B	0.9700	C8B—C9B	1.361 (14)
C3—C17B	1.427 (15)	C8B—H8B	0.9300
C3—C17A	1.551 (7)	C9B—C10B	1.40 (2)
C3—H3A	0.9700	C9B—H9B	0.9300
C3—H3B	0.9700	C10B—H10B	0.9300

S2—Pt1—S1	87.072 (19)	C17A—C3—H3B	109.9
S2—Pt1—Cl2	91.03 (2)	S2—C3—H3B	109.9
S1—Pt1—Cl2	178.012 (18)	H3A—C3—H3B	108.3
S2—Pt1—Cl1	173.657 (19)	C18A—C17A—C22A	117.6 (6)
S1—Pt1—Cl1	92.053 (19)	C18A—C17A—C3	122.2 (5)
Cl2—Pt1—Cl1	89.90 (2)	C22A—C17A—C3	120.1 (5)
C2—S1—C1	99.90 (10)	C17A—C18A—C19A	122.4 (5)
C2—S1—Pt1	109.59 (7)	C17A—C18A—H18A	118.8
C1—S1—Pt1	105.70 (7)	C19A—C18A—H18A	118.8
C16—C11—C12	119.2 (2)	C18A—C19A—C20A	118.5 (6)
C16—C11—C2	120.8 (2)	C18A—C19A—H19A	120.7
C12—C11—C2	120.0 (2)	C20A—C19A—H19A	120.7
C5B—C1—S1	111.0 (10)	C21A—C20A—C19A	120.3 (5)
C5A—C1—S1	107.8 (7)	C21A—C20A—H20A	119.8
C5B—C1—H1A	99.8	C19A—C20A—H20A	119.8
C5A—C1—H1A	110.1	C20A—C21A—C22A	121.1 (5)
S1—C1—H1A	110.1	C20A—C21A—H21A	119.5
C5B—C1—H1B	116.7	C22A—C21A—H21A	119.5
C5A—C1—H1B	110.1	C17A—C22A—C21A	120.0 (6)
S1—C1—H1B	110.1	C17A—C22A—H22A	120.0
H1A—C1—H1B	108.5	C21A—C22A—H22A	120.0
C24—C23—C28	119.0 (2)	C20B—C19B—C18B	117.9 (12)
C24—C23—C4	120.6 (2)	C20B—C19B—H19B	121.1
C28—C23—C4	120.4 (2)	C18B—C19B—H19B	121.1
C23—C4—S2	110.04 (15)	C19B—C20B—C21B	119.2 (11)
C23—C4—H4A	109.7	C19B—C20B—H20B	120.4
S2—C4—H4A	109.7	C21B—C20B—H20B	120.4
C23—C4—H4B	109.7	C20B—C21B—C22B	122.8 (10)
S2—C4—H4B	109.7	C20B—C21B—H21B	118.6
H4A—C4—H4B	108.2	C22B—C21B—H21B	118.6
C13—C12—C11	120.5 (2)	C17B—C22B—C21B	119.0 (11)
C13—C12—H12	119.7	C17B—C22B—H22B	120.5
C11—C12—H12	119.7	C21B—C22B—H22B	120.5
C11—C16—C15	120.1 (2)	C22B—C17B—C18B	117.7 (13)
C11—C16—H16	120.0	C22B—C17B—C3	125.2 (11)
C15—C16—H16	120.0	C18B—C17B—C3	117.1 (11)
C25—C24—C23	120.2 (2)	C17B—C18B—C19B	123.4 (12)
C25—C24—H24	119.9	C17B—C18B—H18B	118.3
C23—C24—H24	119.9	C19B—C18B—H18B	118.3
C27—C28—C23	120.2 (3)	C6A—C5A—C10A	120.9 (14)
C27—C28—H28	119.9	C6A—C5A—C1	121.0 (14)
C23—C28—H28	119.9	C10A—C5A—C1	118.1 (9)
C13—C14—C15	120.1 (2)	C5A—C6A—C7A	119.4 (12)
C13—C14—H14	120.0	C5A—C6A—H6A	120.3
C15—C14—H14	120.0	C7A—C6A—H6A	120.3
C12—C13—C14	120.1 (2)	C6A—C7A—C8A	120.1 (11)
C12—C13—H13	119.9	C6A—C7A—H7A	120.0
C14—C13—H13	119.9	C8A—C7A—H7A	120.0
C27—C26—C25	119.9 (3)	C9A—C8A—C7A	120.0 (13)
C27—C26—H26	120.1	C9A—C8A—H8A	120.0
C25—C26—H26	120.1	C7A—C8A—H8A	120.0
C24—C25—C26	120.3 (3)	C8A—C9A—C10A	120.5 (12)
C24—C25—H25	119.9	C8A—C9A—H9A	119.7
C26—C25—H25	119.9	C10A—C9A—H9A	119.7
C14—C15—C16	120.0 (3)	C5A—C10A—C9A	119.0 (10)
C14—C15—H15	120.0	C5A—C10A—H10A	120.5
C16—C15—H15	120.0	C9A—C10A—H10A	120.5
C26—C27—C28	120.4 (3)	C10B—C5B—C1	124.7 (13)
C26—C27—H27	119.8	C10B—C5B—C6B	116.4 (19)
C28—C27—H27	119.8	C1—C5B—C6B	118.8 (18)
C4—S2—C3	100.48 (11)	C7B—C6B—C5B	121.4 (16)
C4—S2—Pt1	111.23 (9)	C7B—C6B—H6B	119.3
C3—S2—Pt1	101.17 (9)	C5B—C6B—H6B	119.3
C11—C2—S1	110.22 (13)	C8B—C7B—C6B	119.3 (14)
C11—C2—H2A	109.6	C8B—C7B—H7B	120.4
S1—C2—H2A	109.6	C6B—C7B—H7B	120.4
C11—C2—H2B	109.6	C9B—C8B—C7B	120.2 (18)
S1—C2—H2B	109.6	C9B—C8B—H8B	119.9
H2A—C2—H2B	108.1	C7B—C8B—H8B	119.9
C17B—C3—S2	120.7 (7)	C8B—C9B—C10B	121.6 (17)
C17A—C3—S2	108.8 (3)	C8B—C9B—H9B	119.2
C17B—C3—H3A	95.2	C10B—C9B—H9B	119.2
C17A—C3—H3A	109.9	C5B—C10B—C9B	121.0 (11)
S2—C3—H3A	109.9	C5B—C10B—H10B	119.5
C17B—C3—H3B	111.4	C9B—C10B—H10B	119.5

(abmon295) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	F(000) = 2720
M_r = 694.61	D_x = 1.666 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 23942 reflections
a = 28.6839 (11) Å	θ = 2.6–32.8°
b = 15.5752 (6) Å	µ = 5.43 mm⁻¹
c = 12.7019 (5) Å	T = 295 K
β = 102.584 (3)°	Plate, pale yellow
V = 5538.3 (4) Å³	0.30 × 0.19 × 0.10 mm
Z = 8

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9449 independent reflections
Radiation source: Sealed tube	6667 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.060
ω–scans	θ_max = 32.8°, θ_min = 2.6°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −41→42
T_min = 0.297, T_max = 0.581	k = −22→23
23942 measured reflections	l = −13→19

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.046	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.126	H-atom parameters constrained
S = 1.00	w = 1/[σ²(F_o²) + (0.0707P)²] where P = (F_o² + 2F_c²)/3
9449 reflections	(Δ/σ)_max = 0.002
298 parameters	Δρ_max = 2.15 e Å⁻³
0 restraints	Δρ_min = −2.34 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	V = 5538.3 (4) Å³
M_r = 694.61	Z = 8
Monoclinic, C2/c	Mo Kα radiation
a = 28.6839 (11) Å	µ = 5.43 mm⁻¹
b = 15.5752 (6) Å	T = 295 K
c = 12.7019 (5) Å	0.30 × 0.19 × 0.10 mm
β = 102.584 (3)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9449 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	6667 reflections with I > 2σ(I)
T_min = 0.297, T_max = 0.581	R_int = 0.060
23942 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.046	0 restraints
wR(F²) = 0.126	H-atom parameters constrained
S = 1.00	Δρ_max = 2.15 e Å⁻³
9449 reflections	Δρ_min = −2.34 e Å⁻³
298 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pt1	0.139050 (6)	0.853639 (11)	0.726421 (12)	0.03638 (7)
S1	0.13581 (4)	0.92964 (7)	0.57172 (8)	0.0347 (2)
S2	0.14508 (4)	0.73298 (7)	0.62907 (10)	0.0438 (2)
Cl2	0.14061 (5)	0.77413 (9)	0.88148 (10)	0.0606 (3)
Cl1	0.12548 (5)	0.97721 (9)	0.81573 (10)	0.0584 (3)
C2	0.17245 (17)	1.0274 (3)	0.6012 (4)	0.0437 (10)
H2A	0.1591	1.0720	0.5502	0.052*
H2B	0.1718	1.0477	0.6730	0.052*
C1	0.07698 (15)	0.9804 (3)	0.5444 (4)	0.0418 (9)
H1A	0.0736	1.0147	0.6061	0.050*
H1B	0.0738	1.0182	0.4826	0.050*
C5	0.03832 (15)	0.9132 (3)	0.5221 (4)	0.0432 (10)
C11	0.22332 (16)	1.0103 (3)	0.5941 (4)	0.0423 (9)
C4	0.1888 (2)	0.6582 (3)	0.7050 (5)	0.0568 (14)
H4A	0.1823	0.6501	0.7762	0.068*
H4B	0.1853	0.6030	0.6688	0.068*
C23	0.23930 (18)	0.6892 (3)	0.7165 (4)	0.0475 (11)
C10	0.01555 (18)	0.8871 (4)	0.6026 (4)	0.0535 (12)
H10	0.0259	0.9090	0.6718	0.064*
C6	0.0237 (2)	0.8778 (4)	0.4209 (5)	0.0598 (13)
H6	0.0386	0.8936	0.3657	0.072*
C3	0.08928 (19)	0.6779 (4)	0.6346 (5)	0.0607 (14)
H3A	0.0900	0.6623	0.7088	0.073*
H3B	0.0629	0.7174	0.6113	0.073*
C12	0.2528 (2)	0.9588 (4)	0.6666 (5)	0.0651 (15)
H12	0.2414	0.9330	0.7220	0.078*
C16	0.24074 (19)	1.0488 (4)	0.5122 (4)	0.0555 (13)
H16	0.2208	1.0831	0.4617	0.067*
C24	0.2636 (2)	0.7269 (4)	0.8115 (4)	0.0604 (14)
H24	0.2477	0.7382	0.8664	0.073*
C17	0.0803 (2)	0.5987 (4)	0.5664 (6)	0.0704 (17)
C8	−0.0362 (2)	0.7950 (4)	0.4811 (6)	0.0737 (18)
H8	−0.0613	0.7560	0.4673	0.088*
C28	0.2631 (2)	0.6758 (4)	0.6351 (5)	0.0622 (14)
H28	0.2470	0.6519	0.5702	0.075*
C25	0.3114 (2)	0.7476 (4)	0.8249 (5)	0.0707 (17)
H25	0.3276	0.7719	0.8894	0.085*
C9	−0.0215 (2)	0.8305 (4)	0.5833 (6)	0.0677 (17)
H9	−0.0368	0.8157	0.6381	0.081*
C15	0.2878 (2)	1.0364 (5)	0.5053 (6)	0.0748 (19)
H15	0.2997	1.0643	0.4519	0.090*
C26	0.3348 (2)	0.7328 (4)	0.7444 (6)	0.0748 (17)
H26	0.3671	0.7464	0.7544	0.090*
C14	0.3166 (2)	0.9839 (5)	0.5759 (7)	0.079 (2)
H14	0.3478	0.9743	0.5692	0.095*
C13	0.3000 (2)	0.9446 (4)	0.6580 (7)	0.085 (2)
H13	0.3199	0.9092	0.7070	0.103*
C7	−0.0137 (2)	0.8177 (5)	0.4014 (6)	0.0749 (18)
H7	−0.0232	0.7932	0.3333	0.090*
C27	0.3111 (2)	0.6977 (4)	0.6485 (6)	0.0737 (17)
H27	0.3269	0.6887	0.5930	0.088*
C22	0.0892 (3)	0.5183 (5)	0.6105 (9)	0.106 (3)
H22	0.1017	0.5148	0.6844	0.127*
C18	0.0607 (3)	0.6034 (6)	0.4609 (7)	0.097 (3)
H18	0.0543	0.6569	0.4287	0.116*
C20	0.0610 (4)	0.4509 (7)	0.4484 (12)	0.127 (4)
H20	0.0546	0.4005	0.4086	0.153*
C19	0.0495 (3)	0.5275 (9)	0.3965 (10)	0.134 (4)
H19	0.0352	0.5302	0.3235	0.161*
C21	0.0815 (4)	0.4449 (6)	0.5557 (12)	0.134 (4)
H21	0.0896	0.3922	0.5890	0.160*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.03795 (10)	0.04171 (11)	0.03060 (9)	0.00371 (6)	0.00991 (7)	0.00107 (6)
S1	0.0380 (5)	0.0360 (5)	0.0318 (4)	−0.0006 (4)	0.0115 (4)	−0.0011 (4)
S2	0.0466 (6)	0.0380 (5)	0.0486 (6)	0.0038 (5)	0.0144 (5)	−0.0004 (5)
Cl2	0.0732 (8)	0.0712 (9)	0.0414 (6)	0.0123 (7)	0.0212 (6)	0.0167 (6)
Cl1	0.0814 (9)	0.0572 (7)	0.0402 (6)	0.0120 (6)	0.0214 (6)	−0.0098 (5)
C2	0.048 (3)	0.035 (2)	0.052 (3)	−0.0026 (19)	0.020 (2)	−0.0011 (19)
C1	0.039 (2)	0.042 (2)	0.045 (2)	0.0075 (18)	0.0117 (19)	0.0090 (19)
C5	0.034 (2)	0.048 (3)	0.047 (2)	0.0087 (18)	0.0079 (18)	0.0074 (19)
C11	0.039 (2)	0.041 (2)	0.047 (2)	−0.0045 (18)	0.0087 (19)	−0.0029 (19)
C4	0.062 (3)	0.043 (3)	0.068 (4)	0.009 (2)	0.021 (3)	0.012 (2)
C23	0.050 (3)	0.038 (2)	0.055 (3)	0.013 (2)	0.013 (2)	0.007 (2)
C10	0.043 (3)	0.068 (3)	0.052 (3)	0.002 (2)	0.014 (2)	0.013 (3)
C6	0.052 (3)	0.074 (4)	0.053 (3)	0.000 (3)	0.012 (3)	−0.002 (3)
C3	0.051 (3)	0.050 (3)	0.087 (4)	−0.005 (2)	0.027 (3)	−0.011 (3)
C12	0.054 (3)	0.060 (3)	0.076 (4)	−0.009 (3)	0.003 (3)	0.019 (3)
C16	0.047 (3)	0.071 (4)	0.051 (3)	−0.006 (2)	0.014 (2)	0.004 (2)
C24	0.065 (3)	0.062 (3)	0.054 (3)	0.010 (3)	0.012 (3)	0.010 (3)
C17	0.044 (3)	0.064 (4)	0.103 (5)	−0.011 (3)	0.017 (3)	−0.018 (4)
C8	0.051 (3)	0.062 (4)	0.105 (5)	−0.008 (3)	0.011 (3)	0.008 (4)
C28	0.064 (4)	0.062 (3)	0.064 (3)	0.000 (3)	0.021 (3)	−0.011 (3)
C25	0.071 (4)	0.064 (4)	0.064 (4)	0.002 (3)	−0.013 (3)	0.010 (3)
C9	0.054 (3)	0.073 (4)	0.080 (4)	0.004 (3)	0.024 (3)	0.026 (3)
C15	0.053 (3)	0.102 (5)	0.076 (4)	−0.021 (3)	0.029 (3)	−0.014 (4)
C26	0.054 (3)	0.070 (4)	0.097 (5)	0.006 (3)	0.008 (3)	0.011 (4)
C14	0.039 (3)	0.078 (4)	0.116 (6)	−0.004 (3)	0.009 (3)	−0.023 (4)
C13	0.053 (3)	0.055 (4)	0.134 (7)	−0.002 (3)	−0.011 (4)	0.013 (4)
C7	0.068 (4)	0.072 (4)	0.077 (4)	−0.006 (3)	0.000 (3)	−0.017 (4)
C27	0.071 (4)	0.074 (4)	0.084 (4)	0.010 (3)	0.035 (4)	−0.008 (3)
C22	0.108 (6)	0.057 (4)	0.161 (8)	−0.026 (4)	0.048 (6)	−0.014 (5)
C18	0.062 (4)	0.106 (6)	0.112 (6)	0.018 (4)	−0.004 (4)	−0.029 (5)
C20	0.078 (6)	0.118 (9)	0.185 (12)	−0.038 (6)	0.024 (7)	−0.069 (9)
C19	0.046 (4)	0.192 (12)	0.151 (10)	0.009 (6)	−0.005 (5)	−0.064 (9)
C21	0.133 (9)	0.057 (5)	0.223 (14)	−0.035 (5)	0.066 (10)	−0.027 (7)

Geometric parameters (Å, º) top

Pt1—S2	2.2768 (12)	C16—C15	1.386 (8)
Pt1—S1	2.2785 (10)	C16—H16	0.9300
Pt1—Cl1	2.3097 (12)	C24—C25	1.381 (8)
Pt1—Cl2	2.3186 (12)	C24—H24	0.9300
S1—C1	1.827 (4)	C17—C18	1.337 (10)
S1—C2	1.842 (5)	C17—C22	1.373 (10)
S2—C4	1.826 (5)	C8—C7	1.361 (9)
S2—C3	1.831 (5)	C8—C9	1.389 (10)
C2—C11	1.505 (7)	C8—H8	0.9300
C2—H2A	0.9700	C28—C27	1.391 (9)
C2—H2B	0.9700	C28—H28	0.9300
C1—C5	1.506 (6)	C25—C26	1.361 (9)
C1—H1A	0.9700	C25—H25	0.9300
C1—H1B	0.9700	C9—H9	0.9300
C5—C6	1.378 (7)	C15—C14	1.354 (10)
C5—C10	1.388 (6)	C15—H15	0.9300
C11—C12	1.365 (7)	C26—C27	1.373 (9)
C11—C16	1.385 (7)	C26—H26	0.9300
C4—C23	1.503 (8)	C14—C13	1.380 (11)
C4—H4A	0.9700	C14—H14	0.9300
C4—H4B	0.9700	C13—H13	0.9300
C23—C28	1.374 (7)	C7—H7	0.9300
C23—C24	1.386 (7)	C27—H27	0.9300
C10—C9	1.360 (9)	C22—C21	1.331 (12)
C10—H10	0.9300	C22—H22	0.9300
C6—C7	1.404 (9)	C18—C19	1.434 (13)
C6—H6	0.9300	C18—H18	0.9300
C3—C17	1.497 (8)	C20—C21	1.365 (15)
C3—H3A	0.9700	C20—C19	1.368 (15)
C3—H3B	0.9700	C20—H20	0.9300
C12—C13	1.400 (9)	C19—H19	0.9300
C12—H12	0.9300	C21—H21	0.9300

S2—Pt1—S1	87.37 (4)	C15—C16—C11	120.2 (6)
S2—Pt1—Cl1	174.49 (5)	C15—C16—H16	119.9
S1—Pt1—Cl1	90.63 (4)	C11—C16—H16	119.9
S2—Pt1—Cl2	91.76 (4)	C25—C24—C23	120.3 (6)
S1—Pt1—Cl2	178.46 (5)	C25—C24—H24	119.9
Cl1—Pt1—Cl2	90.12 (5)	C23—C24—H24	119.9
C1—S1—C2	98.2 (2)	C18—C17—C22	117.3 (7)
C1—S1—Pt1	104.54 (15)	C18—C17—C3	121.1 (7)
C2—S1—Pt1	109.88 (16)	C22—C17—C3	121.5 (7)
C4—S2—C3	100.7 (3)	C7—C8—C9	119.7 (6)
C4—S2—Pt1	111.4 (2)	C7—C8—H8	120.2
C3—S2—Pt1	101.29 (18)	C9—C8—H8	120.2
C11—C2—S1	111.0 (3)	C23—C28—C27	120.7 (6)
C11—C2—H2A	109.4	C23—C28—H28	119.6
S1—C2—H2A	109.4	C27—C28—H28	119.6
C11—C2—H2B	109.4	C26—C25—C24	120.4 (6)
S1—C2—H2B	109.4	C26—C25—H25	119.8
H2A—C2—H2B	108.0	C24—C25—H25	119.8
C5—C1—S1	110.3 (3)	C10—C9—C8	119.5 (6)
C5—C1—H1A	109.6	C10—C9—H9	120.2
S1—C1—H1A	109.6	C8—C9—H9	120.2
C5—C1—H1B	109.6	C14—C15—C16	120.3 (6)
S1—C1—H1B	109.6	C14—C15—H15	119.9
H1A—C1—H1B	108.1	C16—C15—H15	119.9
C6—C5—C10	118.3 (5)	C25—C26—C27	120.2 (6)
C6—C5—C1	121.0 (4)	C25—C26—H26	119.9
C10—C5—C1	120.7 (5)	C27—C26—H26	119.9
C12—C11—C16	119.3 (5)	C15—C14—C13	120.4 (6)
C12—C11—C2	122.0 (5)	C15—C14—H14	119.8
C16—C11—C2	118.8 (4)	C13—C14—H14	119.8
C23—C4—S2	112.5 (3)	C14—C13—C12	119.2 (6)
C23—C4—H4A	109.1	C14—C13—H13	120.4
S2—C4—H4A	109.1	C12—C13—H13	120.4
C23—C4—H4B	109.1	C8—C7—C6	120.6 (6)
S2—C4—H4B	109.1	C8—C7—H7	119.7
H4A—C4—H4B	107.8	C6—C7—H7	119.7
C28—C23—C24	118.8 (5)	C26—C27—C28	119.6 (6)
C28—C23—C4	120.3 (5)	C26—C27—H27	120.2
C24—C23—C4	120.8 (5)	C28—C27—H27	120.2
C9—C10—C5	122.1 (6)	C21—C22—C17	125.1 (10)
C9—C10—H10	119.0	C21—C22—H22	117.5
C5—C10—H10	119.0	C17—C22—H22	117.5
C5—C6—C7	119.8 (6)	C17—C18—C19	121.3 (10)
C5—C6—H6	120.1	C17—C18—H18	119.3
C7—C6—H6	120.1	C19—C18—H18	119.3
C17—C3—S2	114.0 (4)	C21—C20—C19	123.1 (10)
C17—C3—H3A	108.8	C21—C20—H20	118.4
S2—C3—H3A	108.8	C19—C20—H20	118.4
C17—C3—H3B	108.8	C20—C19—C18	116.3 (11)
S2—C3—H3B	108.8	C20—C19—H19	121.8
H3A—C3—H3B	107.7	C18—C19—H19	121.9
C11—C12—C13	120.5 (6)	C22—C21—C20	116.8 (11)
C11—C12—H12	119.8	C22—C21—H21	121.6
C13—C12—H12	119.8	C20—C21—H21	121.6

(abmon250) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	F(000) = 2720
M_r = 694.61	D_x = 1.688 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 24554 reflections
a = 28.5503 (10) Å	θ = 2.4–32.7°
b = 15.5016 (6) Å	µ = 5.50 mm⁻¹
c = 12.6508 (5) Å	T = 250 K
β = 102.560 (3)°	Plate, pale yellow
V = 5464.9 (4) Å³	0.30 × 0.19 × 0.10 mm
Z = 8

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9148 independent reflections
Radiation source: Sealed tube	6689 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.036
ω–scans	θ_max = 32.7°, θ_min = 2.4°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −42→41
T_min = 0.297, T_max = 0.579	k = −22→23
24554 measured reflections	l = −19→13

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.031	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.079	H-atom parameters constrained
S = 0.99	w = 1/[σ²(F_o²) + (0.0448P)²] where P = (F_o² + 2F_c²)/3
9148 reflections	(Δ/σ)_max = 0.003
298 parameters	Δρ_max = 2.00 e Å⁻³
0 restraints	Δρ_min = −1.54 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	V = 5464.9 (4) Å³
M_r = 694.61	Z = 8
Monoclinic, C2/c	Mo Kα radiation
a = 28.5503 (10) Å	µ = 5.50 mm⁻¹
b = 15.5016 (6) Å	T = 250 K
c = 12.6508 (5) Å	0.30 × 0.19 × 0.10 mm
β = 102.560 (3)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9148 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	6689 reflections with I > 2σ(I)
T_min = 0.297, T_max = 0.579	R_int = 0.036
24554 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.031	0 restraints
wR(F²) = 0.079	H-atom parameters constrained
S = 0.99	Δρ_max = 2.00 e Å⁻³
9148 reflections	Δρ_min = −1.54 e Å⁻³
298 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pt1	0.139451 (4)	0.854010 (7)	0.727129 (8)	0.02963 (4)
S1	0.13627 (3)	0.93023 (5)	0.57211 (6)	0.02883 (14)
S2	0.14505 (3)	0.73289 (5)	0.62924 (7)	0.03580 (16)
Cl2	0.14098 (3)	0.77428 (6)	0.88282 (7)	0.0496 (2)
Cl1	0.12607 (4)	0.97789 (6)	0.81699 (7)	0.0481 (2)
C2	0.17299 (11)	1.0278 (2)	0.6012 (3)	0.0358 (7)
H2A	0.1594	1.0728	0.5506	0.043*
H2B	0.1727	1.0478	0.6737	0.043*
C1	0.07738 (11)	0.9813 (2)	0.5453 (3)	0.0358 (7)
H1A	0.0741	1.0156	0.6074	0.043*
H1B	0.0742	1.0195	0.4834	0.043*
C5	0.03825 (11)	0.9137 (2)	0.5227 (3)	0.0358 (7)
C11	0.22367 (11)	1.01067 (19)	0.5926 (3)	0.0347 (6)
C4	0.18908 (13)	0.6577 (2)	0.7060 (3)	0.0462 (9)
H4A	0.1826	0.6497	0.7775	0.055*
H4B	0.1856	0.6021	0.6698	0.055*
C23	0.23933 (12)	0.6889 (2)	0.7169 (3)	0.0394 (7)
C10	0.01562 (12)	0.8883 (2)	0.6040 (3)	0.0426 (8)
H10	0.0259	0.9109	0.6733	0.051*
C6	0.02397 (14)	0.8782 (3)	0.4213 (3)	0.0499 (9)
H6	0.0393	0.8936	0.3662	0.060*
C3	0.08910 (13)	0.6783 (2)	0.6356 (3)	0.0511 (9)
H3A	0.0897	0.6638	0.7105	0.061*
H3B	0.0627	0.7181	0.6115	0.061*
C12	0.25375 (13)	0.9583 (2)	0.6645 (3)	0.0521 (9)
H12	0.2424	0.9315	0.7198	0.062*
C16	0.24146 (13)	1.0499 (2)	0.5105 (3)	0.0463 (8)
H16	0.2215	1.0850	0.4604	0.056*
C24	0.26347 (14)	0.7268 (2)	0.8113 (3)	0.0488 (8)
H24	0.2475	0.7384	0.8665	0.059*
C17	0.07979 (13)	0.5985 (3)	0.5695 (4)	0.0567 (10)
C8	−0.03619 (14)	0.7949 (3)	0.4821 (4)	0.0579 (10)
H8	−0.0611	0.7550	0.4684	0.069*
C28	0.26360 (14)	0.6749 (3)	0.6351 (3)	0.0505 (9)
H28	0.2476	0.6501	0.5702	0.061*
C25	0.31179 (15)	0.7478 (3)	0.8242 (3)	0.0586 (10)
H25	0.3281	0.7723	0.8889	0.070*
C9	−0.02153 (13)	0.8308 (3)	0.5846 (3)	0.0528 (10)
H9	−0.0369	0.8158	0.6397	0.063*
C15	0.28846 (15)	1.0372 (3)	0.5027 (4)	0.0608 (11)
H15	0.3002	1.0650	0.4487	0.073*
C26	0.33542 (14)	0.7331 (3)	0.7435 (4)	0.0577 (10)
H26	0.3677	0.7473	0.7530	0.069*
C14	0.31751 (14)	0.9843 (3)	0.5737 (4)	0.0638 (12)
H14	0.3488	0.9746	0.5667	0.077*
C13	0.30078 (14)	0.9447 (3)	0.6563 (4)	0.0694 (14)
H13	0.3209	0.9093	0.7057	0.083*
C7	−0.01371 (15)	0.8187 (3)	0.4013 (4)	0.0625 (11)
H7	−0.0236	0.7950	0.3326	0.075*
C27	0.31170 (15)	0.6975 (3)	0.6490 (4)	0.0602 (11)
H27	0.3277	0.6882	0.5933	0.072*
C22	0.08983 (19)	0.5185 (3)	0.6154 (5)	0.0825 (15)
H22	0.1032	0.5160	0.6893	0.099*
C18	0.05978 (16)	0.6025 (4)	0.4628 (4)	0.0767 (14)
H18	0.0528	0.6559	0.4297	0.092*
C20	0.0605 (2)	0.4483 (4)	0.4544 (6)	0.095 (2)
H20	0.0530	0.3972	0.4159	0.114*
C19	0.04901 (17)	0.5240 (5)	0.3988 (6)	0.106 (2)
H19	0.0353	0.5251	0.3251	0.128*
C21	0.0815 (2)	0.4419 (4)	0.5595 (7)	0.106 (2)
H21	0.0899	0.3890	0.5927	0.127*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.03186 (6)	0.03097 (7)	0.02703 (6)	0.00282 (4)	0.00850 (4)	0.00074 (4)
S1	0.0320 (3)	0.0271 (3)	0.0288 (3)	−0.0001 (3)	0.0097 (3)	−0.0001 (3)
S2	0.0386 (4)	0.0284 (4)	0.0418 (4)	0.0033 (3)	0.0117 (3)	−0.0013 (3)
Cl2	0.0609 (5)	0.0546 (5)	0.0366 (4)	0.0099 (4)	0.0178 (4)	0.0143 (4)
Cl1	0.0681 (6)	0.0439 (5)	0.0354 (4)	0.0088 (4)	0.0182 (4)	−0.0082 (3)
C2	0.0411 (17)	0.0269 (14)	0.0419 (17)	−0.0045 (13)	0.0141 (14)	0.0002 (13)
C1	0.0351 (16)	0.0313 (16)	0.0416 (17)	0.0061 (13)	0.0093 (13)	0.0058 (13)
C5	0.0302 (15)	0.0361 (17)	0.0407 (17)	0.0058 (12)	0.0068 (13)	0.0059 (13)
C11	0.0346 (15)	0.0279 (15)	0.0408 (17)	−0.0057 (12)	0.0066 (13)	−0.0032 (12)
C4	0.047 (2)	0.0338 (18)	0.060 (2)	0.0087 (14)	0.0154 (17)	0.0123 (15)
C23	0.0429 (18)	0.0293 (16)	0.0468 (18)	0.0094 (14)	0.0110 (14)	0.0062 (14)
C10	0.0330 (17)	0.049 (2)	0.0468 (19)	0.0031 (15)	0.0109 (14)	0.0085 (16)
C6	0.049 (2)	0.054 (2)	0.048 (2)	−0.0022 (17)	0.0129 (17)	−0.0013 (17)
C3	0.045 (2)	0.0397 (19)	0.072 (3)	−0.0014 (16)	0.0201 (18)	−0.0090 (19)
C12	0.045 (2)	0.044 (2)	0.064 (2)	−0.0048 (16)	0.0039 (17)	0.0148 (18)
C16	0.0401 (18)	0.054 (2)	0.0445 (19)	−0.0072 (16)	0.0086 (15)	0.0041 (16)
C24	0.059 (2)	0.044 (2)	0.0434 (19)	0.0091 (17)	0.0104 (17)	0.0058 (16)
C17	0.0366 (19)	0.051 (2)	0.083 (3)	−0.0055 (17)	0.0144 (19)	−0.016 (2)
C8	0.041 (2)	0.046 (2)	0.084 (3)	−0.0068 (16)	0.008 (2)	0.006 (2)
C28	0.054 (2)	0.045 (2)	0.054 (2)	0.0013 (18)	0.0145 (18)	−0.0104 (17)
C25	0.060 (2)	0.052 (2)	0.054 (2)	−0.0001 (19)	−0.0073 (19)	0.0068 (18)
C9	0.040 (2)	0.056 (2)	0.064 (3)	0.0028 (17)	0.0164 (18)	0.017 (2)
C15	0.045 (2)	0.075 (3)	0.068 (3)	−0.016 (2)	0.025 (2)	−0.010 (2)
C26	0.041 (2)	0.053 (2)	0.078 (3)	0.0046 (18)	0.0106 (19)	0.007 (2)
C14	0.037 (2)	0.059 (3)	0.096 (4)	−0.0034 (18)	0.015 (2)	−0.015 (2)
C13	0.040 (2)	0.048 (2)	0.107 (4)	0.0027 (18)	−0.011 (2)	0.013 (2)
C7	0.058 (3)	0.063 (3)	0.060 (3)	−0.001 (2)	0.001 (2)	−0.012 (2)
C27	0.059 (3)	0.062 (3)	0.067 (3)	0.006 (2)	0.029 (2)	−0.005 (2)
C22	0.083 (3)	0.046 (3)	0.125 (5)	−0.023 (2)	0.038 (3)	−0.011 (3)
C18	0.051 (3)	0.080 (4)	0.091 (4)	0.016 (2)	−0.002 (2)	−0.019 (3)
C20	0.066 (3)	0.084 (4)	0.132 (6)	−0.024 (3)	0.011 (4)	−0.035 (4)
C19	0.036 (2)	0.163 (7)	0.112 (5)	−0.006 (3)	−0.002 (3)	−0.047 (5)
C21	0.099 (5)	0.052 (3)	0.167 (7)	−0.021 (3)	0.032 (5)	−0.009 (4)

Geometric parameters (Å, º) top

Pt1—S2	2.2739 (8)	C16—C15	1.381 (5)
Pt1—S1	2.2744 (7)	C16—H16	0.9300
Pt1—Cl1	2.3054 (8)	C24—C25	1.392 (5)
Pt1—Cl2	2.3177 (8)	C24—H24	0.9300
S1—C1	1.822 (3)	C17—C18	1.348 (6)
S1—C2	1.831 (3)	C17—C22	1.372 (6)
S2—C3	1.825 (4)	C8—C7	1.370 (6)
S2—C4	1.830 (3)	C8—C9	1.390 (6)
C2—C11	1.498 (4)	C8—H8	0.9300
C2—H2A	0.9700	C28—C27	1.391 (5)
C2—H2B	0.9700	C28—H28	0.9300
C1—C5	1.513 (4)	C25—C26	1.361 (6)
C1—H1A	0.9700	C25—H25	0.9300
C1—H1B	0.9700	C9—H9	0.9300
C5—C6	1.374 (5)	C15—C14	1.358 (6)
C5—C10	1.386 (4)	C15—H15	0.9300
C11—C12	1.373 (5)	C26—C27	1.356 (6)
C11—C16	1.391 (5)	C26—H26	0.9300
C4—C23	1.491 (5)	C14—C13	1.384 (7)
C4—H4A	0.9700	C14—H14	0.9300
C4—H4B	0.9700	C13—H13	0.9300
C23—C24	1.374 (5)	C7—H7	0.9300
C23—C28	1.383 (5)	C27—H27	0.9300
C10—C9	1.367 (5)	C22—C21	1.376 (7)
C10—H10	0.9300	C22—H22	0.9300
C6—C7	1.398 (6)	C18—C19	1.457 (8)
C6—H6	0.9300	C18—H18	0.9300
C3—C17	1.485 (5)	C20—C21	1.338 (9)
C3—H3A	0.9700	C20—C19	1.370 (9)
C3—H3B	0.9700	C20—H20	0.9300
C12—C13	1.385 (5)	C19—H19	0.9300
C12—H12	0.9300	C21—H21	0.9300

S2—Pt1—S1	87.35 (3)	C15—C16—C11	120.6 (4)
S2—Pt1—Cl1	174.36 (3)	C15—C16—H16	119.7
S1—Pt1—Cl1	90.72 (3)	C11—C16—H16	119.7
S2—Pt1—Cl2	91.83 (3)	C23—C24—C25	120.0 (4)
S1—Pt1—Cl2	178.51 (3)	C23—C24—H24	120.0
Cl1—Pt1—Cl2	89.98 (3)	C25—C24—H24	120.0
C1—S1—C2	98.25 (15)	C18—C17—C22	118.0 (5)
C1—S1—Pt1	104.40 (10)	C18—C17—C3	120.7 (4)
C2—S1—Pt1	109.98 (11)	C22—C17—C3	121.3 (5)
C3—S2—C4	100.85 (18)	C7—C8—C9	119.6 (4)
C3—S2—Pt1	101.11 (12)	C7—C8—H8	120.2
C4—S2—Pt1	111.01 (13)	C9—C8—H8	120.2
C11—C2—S1	111.1 (2)	C23—C28—C27	120.5 (4)
C11—C2—H2A	109.4	C23—C28—H28	119.8
S1—C2—H2A	109.4	C27—C28—H28	119.8
C11—C2—H2B	109.4	C26—C25—C24	120.8 (4)
S1—C2—H2B	109.4	C26—C25—H25	119.6
H2A—C2—H2B	108.0	C24—C25—H25	119.6
C5—C1—S1	110.4 (2)	C10—C9—C8	119.5 (4)
C5—C1—H1A	109.6	C10—C9—H9	120.2
S1—C1—H1A	109.6	C8—C9—H9	120.2
C5—C1—H1B	109.6	C14—C15—C16	120.1 (4)
S1—C1—H1B	109.6	C14—C15—H15	119.9
H1A—C1—H1B	108.1	C16—C15—H15	119.9
C6—C5—C10	119.2 (3)	C27—C26—C25	119.8 (4)
C6—C5—C1	120.7 (3)	C27—C26—H26	120.1
C10—C5—C1	120.1 (3)	C25—C26—H26	120.1
C12—C11—C16	118.4 (3)	C15—C14—C13	120.4 (4)
C12—C11—C2	122.1 (3)	C15—C14—H14	119.8
C16—C11—C2	119.5 (3)	C13—C14—H14	119.8
C23—C4—S2	112.3 (2)	C14—C13—C12	119.3 (4)
C23—C4—H4A	109.2	C14—C13—H13	120.4
S2—C4—H4A	109.2	C12—C13—H13	120.4
C23—C4—H4B	109.2	C8—C7—C6	120.7 (4)
S2—C4—H4B	109.2	C8—C7—H7	119.7
H4A—C4—H4B	107.9	C6—C7—H7	119.7
C24—C23—C28	118.6 (3)	C26—C27—C28	120.3 (4)
C24—C23—C4	120.7 (3)	C26—C27—H27	119.9
C28—C23—C4	120.5 (3)	C28—C27—H27	119.9
C9—C10—C5	121.4 (4)	C17—C22—C21	124.4 (6)
C9—C10—H10	119.3	C17—C22—H22	117.8
C5—C10—H10	119.3	C21—C22—H22	117.8
C5—C6—C7	119.6 (4)	C17—C18—C19	120.7 (6)
C5—C6—H6	120.2	C17—C18—H18	119.6
C7—C6—H6	120.2	C19—C18—H18	119.6
C17—C3—S2	114.4 (3)	C21—C20—C19	125.3 (6)
C17—C3—H3A	108.7	C21—C20—H20	117.3
S2—C3—H3A	108.7	C19—C20—H20	117.3
C17—C3—H3B	108.7	C20—C19—C18	115.6 (6)
S2—C3—H3B	108.7	C20—C19—H19	122.2
H3A—C3—H3B	107.6	C18—C19—H19	122.2
C11—C12—C13	121.1 (4)	C20—C21—C22	115.9 (6)
C11—C12—H12	119.4	C20—C21—H21	122.0
C13—C12—H12	119.4	C22—C21—H21	122.0

(abmon200) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	F(000) = 2720
M_r = 694.61	D_x = 1.702 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 24317 reflections
a = 28.4657 (9) Å	θ = 2.4–32.7°
b = 15.4653 (6) Å	µ = 5.54 mm⁻¹
c = 12.6114 (5) Å	T = 200 K
β = 102.499 (3)°	Plate, pale yellow
V = 5420.3 (4) Å³	0.30 × 0.19 × 0.10 mm
Z = 8

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9100 independent reflections
Radiation source: Sealed tube	7099 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.038
ω–scans	θ_max = 32.7°, θ_min = 2.4°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −41→42
T_min = 0.298, T_max = 0.578	k = −22→23
24317 measured reflections	l = −14→19

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.078	H-atom parameters constrained
S = 1.01	w = 1/[σ²(F_o²) + (0.0468P)²] where P = (F_o² + 2F_c²)/3
9100 reflections	(Δ/σ)_max = 0.004
298 parameters	Δρ_max = 2.37 e Å⁻³
0 restraints	Δρ_min = −1.39 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	V = 5420.3 (4) Å³
M_r = 694.61	Z = 8
Monoclinic, C2/c	Mo Kα radiation
a = 28.4657 (9) Å	µ = 5.54 mm⁻¹
b = 15.4653 (6) Å	T = 200 K
c = 12.6114 (5) Å	0.30 × 0.19 × 0.10 mm
β = 102.499 (3)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9100 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	7099 reflections with I > 2σ(I)
T_min = 0.298, T_max = 0.578	R_int = 0.038
24317 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.030	0 restraints
wR(F²) = 0.078	H-atom parameters constrained
S = 1.01	Δρ_max = 2.37 e Å⁻³
9100 reflections	Δρ_min = −1.39 e Å⁻³
298 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pt1	0.139864 (4)	0.854409 (7)	0.727941 (8)	0.02260 (4)
S1	0.13669 (2)	0.93081 (4)	0.57240 (5)	0.02234 (13)
S2	0.14502 (3)	0.73274 (5)	0.62986 (6)	0.02743 (14)
Cl2	0.14142 (3)	0.77456 (6)	0.88439 (6)	0.03801 (17)
Cl1	0.12656 (3)	0.97883 (5)	0.81782 (6)	0.03699 (17)
C2	0.17372 (11)	1.02839 (19)	0.6015 (3)	0.0283 (6)
H2A	0.1599	1.0739	0.5514	0.034*
H2B	0.1738	1.0480	0.6746	0.034*
C1	0.07770 (10)	0.98182 (19)	0.5458 (2)	0.0284 (6)
H1A	0.0745	1.0164	0.6080	0.034*
H1B	0.0744	1.0199	0.4835	0.034*
C5	0.03853 (10)	0.91392 (19)	0.5238 (2)	0.0281 (6)
C11	0.22445 (10)	1.01126 (18)	0.5911 (2)	0.0271 (6)
C4	0.18909 (12)	0.6569 (2)	0.7067 (3)	0.0346 (7)
H4A	0.1827	0.6489	0.7785	0.042*
H4B	0.1856	0.6012	0.6703	0.042*
C23	0.23958 (11)	0.68840 (19)	0.7171 (3)	0.0300 (6)
C10	0.01589 (11)	0.8892 (2)	0.6055 (3)	0.0331 (6)
H10	0.0261	0.9122	0.6747	0.040*
C6	0.02402 (13)	0.8786 (2)	0.4211 (3)	0.0394 (7)
H6	0.0392	0.8946	0.3657	0.047*
C3	0.08888 (12)	0.6782 (2)	0.6379 (3)	0.0394 (8)
H3A	0.0898	0.6639	0.7132	0.047*
H3B	0.0623	0.7179	0.6139	0.047*
C12	0.25493 (12)	0.9578 (2)	0.6635 (3)	0.0400 (8)
H12	0.2438	0.9310	0.7194	0.048*
C16	0.24186 (11)	1.0515 (2)	0.5088 (3)	0.0352 (7)
H16	0.2219	1.0875	0.4597	0.042*
C24	0.26365 (12)	0.7274 (2)	0.8120 (3)	0.0370 (7)
H24	0.2475	0.7392	0.8671	0.044*
C17	0.07946 (12)	0.5975 (2)	0.5716 (3)	0.0427 (8)
C8	−0.03647 (12)	0.7952 (2)	0.4824 (3)	0.0443 (9)
H8	−0.0617	0.7558	0.4683	0.053*
C28	0.26385 (13)	0.6738 (2)	0.6347 (3)	0.0390 (7)
H28	0.2478	0.6487	0.5699	0.047*
C25	0.31230 (13)	0.7490 (2)	0.8252 (3)	0.0443 (8)
H25	0.3287	0.7744	0.8895	0.053*
C9	−0.02170 (12)	0.8308 (2)	0.5858 (3)	0.0402 (8)
H9	−0.0370	0.8154	0.6411	0.048*
C15	0.28911 (13)	1.0379 (3)	0.4998 (3)	0.0463 (9)
H15	0.3008	1.0655	0.4452	0.056*
C26	0.33593 (13)	0.7329 (2)	0.7431 (3)	0.0443 (8)
H26	0.3683	0.7469	0.7523	0.053*
C14	0.31854 (13)	0.9843 (2)	0.5709 (4)	0.0482 (9)
H14	0.3500	0.9749	0.5639	0.058*
C13	0.30168 (13)	0.9442 (3)	0.6528 (4)	0.0537 (11)
H13	0.3218	0.9078	0.7011	0.064*
C7	−0.01352 (13)	0.8186 (3)	0.4012 (3)	0.0461 (9)
H7	−0.0231	0.7943	0.3325	0.055*
C27	0.31210 (14)	0.6965 (3)	0.6482 (3)	0.0473 (9)
H27	0.3281	0.6869	0.5923	0.057*
C22	0.09041 (16)	0.5178 (3)	0.6210 (4)	0.0585 (11)
H22	0.1041	0.5157	0.6949	0.070*
C18	0.05867 (14)	0.6000 (3)	0.4651 (4)	0.0582 (11)
H18	0.0509	0.6531	0.4312	0.070*
C20	0.06037 (17)	0.4455 (3)	0.4574 (5)	0.0714 (14)
H20	0.0535	0.3941	0.4189	0.086*
C19	0.04840 (15)	0.5219 (4)	0.4030 (4)	0.0782 (17)
H19	0.0343	0.5230	0.3293	0.094*
C21	0.0814 (2)	0.4412 (3)	0.5630 (5)	0.0769 (16)
H21	0.0898	0.3881	0.5966	0.092*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.02406 (6)	0.02399 (6)	0.02062 (6)	0.00204 (4)	0.00677 (4)	0.00054 (4)
S1	0.0242 (3)	0.0215 (3)	0.0225 (3)	−0.0001 (3)	0.0077 (2)	0.0000 (2)
S2	0.0295 (3)	0.0225 (3)	0.0312 (4)	0.0020 (3)	0.0086 (3)	−0.0007 (3)
Cl2	0.0463 (4)	0.0427 (4)	0.0276 (3)	0.0071 (4)	0.0138 (3)	0.0104 (3)
Cl1	0.0533 (5)	0.0335 (4)	0.0267 (3)	0.0057 (3)	0.0141 (3)	−0.0063 (3)
C2	0.0318 (15)	0.0220 (13)	0.0329 (15)	−0.0043 (11)	0.0112 (12)	−0.0011 (11)
C1	0.0274 (14)	0.0248 (14)	0.0339 (15)	0.0045 (11)	0.0086 (12)	0.0052 (11)
C5	0.0238 (13)	0.0284 (14)	0.0320 (15)	0.0047 (11)	0.0056 (11)	0.0039 (11)
C11	0.0258 (13)	0.0237 (13)	0.0312 (14)	−0.0039 (11)	0.0048 (11)	−0.0031 (11)
C4	0.0345 (16)	0.0275 (15)	0.0434 (18)	0.0066 (12)	0.0116 (14)	0.0095 (13)
C23	0.0324 (15)	0.0226 (14)	0.0356 (15)	0.0056 (12)	0.0086 (12)	0.0048 (12)
C10	0.0261 (14)	0.0374 (17)	0.0363 (16)	0.0021 (13)	0.0080 (12)	0.0058 (14)
C6	0.0386 (18)	0.0436 (19)	0.0366 (17)	0.0011 (15)	0.0092 (14)	0.0001 (15)
C3	0.0315 (16)	0.0324 (17)	0.057 (2)	−0.0027 (14)	0.0165 (15)	−0.0090 (16)
C12	0.0329 (16)	0.0378 (19)	0.0462 (19)	−0.0059 (14)	0.0018 (14)	0.0102 (15)
C16	0.0312 (15)	0.0408 (18)	0.0342 (16)	−0.0033 (13)	0.0080 (13)	0.0039 (13)
C24	0.0420 (18)	0.0358 (17)	0.0332 (16)	0.0068 (14)	0.0081 (13)	0.0051 (13)
C17	0.0281 (16)	0.0374 (18)	0.064 (2)	−0.0043 (14)	0.0120 (15)	−0.0100 (17)
C8	0.0326 (17)	0.0337 (18)	0.065 (2)	−0.0037 (14)	0.0077 (16)	0.0027 (16)
C28	0.0432 (19)	0.0354 (17)	0.0398 (18)	0.0006 (15)	0.0121 (15)	−0.0082 (14)
C25	0.046 (2)	0.041 (2)	0.0389 (19)	−0.0015 (16)	−0.0052 (15)	0.0039 (15)
C9	0.0297 (16)	0.0422 (19)	0.051 (2)	0.0013 (14)	0.0139 (15)	0.0126 (16)
C15	0.0341 (18)	0.058 (2)	0.051 (2)	−0.0105 (17)	0.0188 (16)	−0.0077 (18)
C26	0.0315 (17)	0.0405 (19)	0.061 (2)	0.0026 (15)	0.0109 (16)	0.0080 (17)
C14	0.0269 (16)	0.044 (2)	0.075 (3)	−0.0025 (15)	0.0135 (17)	−0.0129 (19)
C13	0.0293 (17)	0.037 (2)	0.087 (3)	0.0031 (15)	−0.0048 (18)	0.012 (2)
C7	0.045 (2)	0.044 (2)	0.046 (2)	−0.0025 (17)	−0.0001 (16)	−0.0108 (17)
C27	0.045 (2)	0.049 (2)	0.054 (2)	0.0058 (17)	0.0239 (17)	−0.0035 (18)
C22	0.059 (3)	0.038 (2)	0.081 (3)	−0.0158 (19)	0.020 (2)	−0.007 (2)
C18	0.039 (2)	0.063 (3)	0.068 (3)	0.0101 (19)	0.0002 (19)	−0.009 (2)
C20	0.050 (3)	0.062 (3)	0.101 (4)	−0.019 (2)	0.014 (3)	−0.026 (3)
C19	0.031 (2)	0.123 (5)	0.074 (3)	−0.004 (3)	−0.002 (2)	−0.031 (3)
C21	0.082 (4)	0.035 (2)	0.114 (5)	−0.015 (2)	0.024 (3)	−0.002 (3)

Geometric parameters (Å, º) top

Pt1—S2	2.2739 (7)	C16—C15	1.390 (5)
Pt1—S1	2.2750 (7)	C16—H16	0.9300
Pt1—Cl1	2.3058 (7)	C24—C25	1.400 (5)
Pt1—Cl2	2.3199 (7)	C24—H24	0.9300
S1—C1	1.820 (3)	C17—C18	1.346 (6)
S1—C2	1.832 (3)	C17—C22	1.385 (6)
S2—C3	1.829 (3)	C8—C7	1.376 (5)
S2—C4	1.834 (3)	C8—C9	1.394 (5)
C2—C11	1.502 (4)	C8—H8	0.9300
C2—H2A	0.9700	C28—C27	1.392 (5)
C2—H2B	0.9700	C28—H28	0.9300
C1—C5	1.513 (4)	C25—C26	1.374 (5)
C1—H1A	0.9700	C25—H25	0.9300
C1—H1B	0.9700	C9—H9	0.9300
C5—C10	1.382 (4)	C15—C14	1.366 (6)
C5—C6	1.384 (4)	C15—H15	0.9300
C11—C12	1.389 (4)	C26—C27	1.363 (5)
C11—C16	1.390 (4)	C26—H26	0.9300
C4—C23	1.496 (4)	C14—C13	1.378 (6)
C4—H4A	0.9700	C14—H14	0.9300
C4—H4B	0.9700	C13—H13	0.9300
C23—C24	1.382 (5)	C7—H7	0.9300
C23—C28	1.385 (5)	C27—H27	0.9300
C10—C9	1.381 (5)	C22—C21	1.387 (6)
C10—H10	0.9300	C22—H22	0.9300
C6—C7	1.395 (5)	C18—C19	1.434 (7)
C6—H6	0.9300	C18—H18	0.9300
C3—C17	1.493 (5)	C20—C21	1.339 (8)
C3—H3A	0.9700	C20—C19	1.371 (8)
C3—H3B	0.9700	C20—H20	0.9300
C12—C13	1.382 (5)	C19—H19	0.9300
C12—H12	0.9300	C21—H21	0.9300

S2—Pt1—S1	87.47 (2)	C15—C16—C11	120.1 (3)
S2—Pt1—Cl1	174.13 (3)	C15—C16—H16	120.0
S1—Pt1—Cl1	90.59 (3)	C11—C16—H16	120.0
S2—Pt1—Cl2	91.75 (3)	C23—C24—C25	120.0 (3)
S1—Pt1—Cl2	178.57 (3)	C23—C24—H24	120.0
Cl1—Pt1—Cl2	90.06 (3)	C25—C24—H24	120.0
C1—S1—C2	98.50 (14)	C18—C17—C22	118.8 (4)
C1—S1—Pt1	104.30 (10)	C18—C17—C3	121.5 (4)
C2—S1—Pt1	109.95 (10)	C22—C17—C3	119.7 (4)
C3—S2—C4	100.47 (16)	C7—C8—C9	119.7 (3)
C3—S2—Pt1	101.05 (11)	C7—C8—H8	120.1
C4—S2—Pt1	111.06 (12)	C9—C8—H8	120.1
C11—C2—S1	111.1 (2)	C23—C28—C27	120.4 (3)
C11—C2—H2A	109.4	C23—C28—H28	119.8
S1—C2—H2A	109.4	C27—C28—H28	119.8
C11—C2—H2B	109.4	C26—C25—C24	120.0 (3)
S1—C2—H2B	109.4	C26—C25—H25	120.0
H2A—C2—H2B	108.0	C24—C25—H25	120.0
C5—C1—S1	110.3 (2)	C10—C9—C8	119.4 (3)
C5—C1—H1A	109.6	C10—C9—H9	120.3
S1—C1—H1A	109.6	C8—C9—H9	120.3
C5—C1—H1B	109.6	C14—C15—C16	120.3 (4)
S1—C1—H1B	109.6	C14—C15—H15	119.8
H1A—C1—H1B	108.1	C16—C15—H15	119.8
C10—C5—C6	119.7 (3)	C27—C26—C25	120.3 (3)
C10—C5—C1	120.0 (3)	C27—C26—H26	119.8
C6—C5—C1	120.3 (3)	C25—C26—H26	119.8
C12—C11—C16	119.0 (3)	C15—C14—C13	120.1 (3)
C12—C11—C2	121.6 (3)	C15—C14—H14	119.9
C16—C11—C2	119.4 (3)	C13—C14—H14	119.9
C23—C4—S2	111.9 (2)	C14—C13—C12	120.2 (4)
C23—C4—H4A	109.2	C14—C13—H13	119.9
S2—C4—H4A	109.2	C12—C13—H13	119.9
C23—C4—H4B	109.2	C8—C7—C6	120.7 (3)
S2—C4—H4B	109.2	C8—C7—H7	119.7
H4A—C4—H4B	107.9	C6—C7—H7	119.7
C24—C23—C28	119.1 (3)	C26—C27—C28	120.1 (3)
C24—C23—C4	120.3 (3)	C26—C27—H27	120.0
C28—C23—C4	120.4 (3)	C28—C27—H27	120.0
C9—C10—C5	121.0 (3)	C17—C22—C21	121.7 (5)
C9—C10—H10	119.5	C17—C22—H22	119.1
C5—C10—H10	119.5	C21—C22—H22	119.1
C5—C6—C7	119.5 (3)	C17—C18—C19	121.0 (5)
C5—C6—H6	120.3	C17—C18—H18	119.5
C7—C6—H6	120.3	C19—C18—H18	119.5
C17—C3—S2	114.1 (2)	C21—C20—C19	123.4 (5)
C17—C3—H3A	108.7	C21—C20—H20	118.3
S2—C3—H3A	108.7	C19—C20—H20	118.3
C17—C3—H3B	108.7	C20—C19—C18	116.9 (5)
S2—C3—H3B	108.7	C20—C19—H19	121.5
H3A—C3—H3B	107.6	C18—C19—H19	121.5
C13—C12—C11	120.3 (3)	C20—C21—C22	118.2 (5)
C13—C12—H12	119.9	C20—C21—H21	120.9
C11—C12—H12	119.9	C22—C21—H21	120.9

(abmon150) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	F(000) = 2720
M_r = 694.61	D_x = 1.715 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 24840 reflections
a = 28.3708 (9) Å	θ = 2.4–32.8°
b = 15.4372 (6) Å	µ = 5.58 mm⁻¹
c = 12.5812 (5) Å	T = 150 K
β = 102.432 (3)°	Plate, pale yellow
V = 5380.9 (3) Å³	0.30 × 0.19 × 0.10 mm
Z = 8

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9119 independent reflections
Radiation source: Sealed tube	7490 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.031
ω–scans	θ_max = 32.8°, θ_min = 2.4°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −41→41
T_min = 0.296, T_max = 0.573	k = −22→23
24840 measured reflections	l = −13→19

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.026	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.065	H-atom parameters constrained
S = 1.06	w = 1/[σ²(F_o²) + (0.0385P)²] where P = (F_o² + 2F_c²)/3
9119 reflections	(Δ/σ)_max = 0.005
298 parameters	Δρ_max = 2.06 e Å⁻³
0 restraints	Δρ_min = −1.61 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	V = 5380.9 (3) Å³
M_r = 694.61	Z = 8
Monoclinic, C2/c	Mo Kα radiation
a = 28.3708 (9) Å	µ = 5.58 mm⁻¹
b = 15.4372 (6) Å	T = 150 K
c = 12.5812 (5) Å	0.30 × 0.19 × 0.10 mm
β = 102.432 (3)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9119 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	7490 reflections with I > 2σ(I)
T_min = 0.296, T_max = 0.573	R_int = 0.031
24840 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.026	0 restraints
wR(F²) = 0.065	H-atom parameters constrained
S = 1.06	Δρ_max = 2.06 e Å⁻³
9119 reflections	Δρ_min = −1.61 e Å⁻³
298 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pt1	0.140239 (3)	0.854789 (5)	0.728799 (6)	0.01612 (3)
S1	0.137136 (19)	0.93129 (4)	0.57284 (4)	0.01624 (10)
S2	0.14499 (2)	0.73258 (4)	0.63064 (5)	0.01975 (11)
Cl2	0.14177 (2)	0.77489 (4)	0.88585 (5)	0.02708 (13)
Cl1	0.12713 (2)	0.97978 (4)	0.81889 (5)	0.02688 (12)
C2	0.17443 (9)	1.02898 (15)	0.6021 (2)	0.0206 (4)
H2A	0.1605	1.0748	0.5524	0.025*
H2B	0.1749	1.0483	0.6756	0.025*
C1	0.07795 (8)	0.98236 (15)	0.5466 (2)	0.0204 (4)
H1A	0.0747	1.0168	0.6091	0.024*
H1B	0.0746	1.0207	0.4843	0.024*
C5	0.03894 (8)	0.91444 (16)	0.52460 (19)	0.0205 (4)
C11	0.22511 (8)	1.01175 (15)	0.59036 (19)	0.0193 (4)
C4	0.18893 (9)	0.65642 (16)	0.7075 (2)	0.0248 (5)
H4A	0.1825	0.6485	0.7795	0.030*
H4B	0.1854	0.6007	0.6710	0.030*
C23	0.23969 (9)	0.68811 (15)	0.7178 (2)	0.0215 (5)
C10	0.01592 (9)	0.88940 (17)	0.6069 (2)	0.0240 (5)
H10	0.0260	0.9124	0.6764	0.029*
C6	0.02446 (10)	0.87840 (19)	0.4220 (2)	0.0289 (5)
H6	0.0399	0.8941	0.3667	0.035*
C3	0.08850 (9)	0.67852 (18)	0.6398 (2)	0.0288 (5)
H3A	0.0892	0.6655	0.7156	0.035*
H3B	0.0619	0.7181	0.6145	0.035*
C12	0.25552 (9)	0.95733 (17)	0.6617 (2)	0.0284 (6)
H12	0.2444	0.9301	0.7174	0.034*
C16	0.24235 (9)	1.05231 (17)	0.5074 (2)	0.0255 (5)
H16	0.2222	1.0885	0.4586	0.031*
C24	0.26401 (10)	0.72771 (17)	0.8127 (2)	0.0268 (5)
H24	0.2479	0.7397	0.8680	0.032*
C17	0.07919 (9)	0.59639 (18)	0.5753 (2)	0.0293 (6)
C8	−0.03652 (10)	0.79530 (18)	0.4830 (3)	0.0324 (6)
H8	−0.0620	0.7561	0.4688	0.039*
C28	0.26397 (10)	0.67287 (19)	0.6344 (2)	0.0284 (5)
H28	0.2478	0.6473	0.5699	0.034*
C25	0.31263 (10)	0.74961 (19)	0.8255 (2)	0.0315 (6)
H25	0.3289	0.7754	0.8897	0.038*
C9	−0.02173 (9)	0.83086 (19)	0.5866 (2)	0.0299 (6)
H9	−0.0372	0.8152	0.6419	0.036*
C15	0.28958 (10)	1.0390 (2)	0.4974 (2)	0.0330 (6)
H15	0.3011	1.0671	0.4427	0.040*
C26	0.33654 (10)	0.73308 (19)	0.7431 (3)	0.0330 (6)
H26	0.3690	0.7471	0.7521	0.040*
C14	0.31929 (10)	0.98443 (19)	0.5677 (3)	0.0350 (6)
H14	0.3507	0.9750	0.5599	0.042*
C13	0.30260 (10)	0.94331 (19)	0.6503 (3)	0.0379 (7)
H13	0.3228	0.9064	0.6980	0.045*
C7	−0.01322 (10)	0.8186 (2)	0.4013 (2)	0.0348 (6)
H7	−0.0227	0.7942	0.3324	0.042*
C27	0.31235 (11)	0.69585 (19)	0.6476 (3)	0.0344 (6)
H27	0.3284	0.6860	0.5915	0.041*
C22	0.09115 (11)	0.51654 (19)	0.6258 (3)	0.0392 (7)
H22	0.1055	0.5146	0.6995	0.047*
C18	0.05758 (10)	0.5984 (2)	0.4667 (3)	0.0393 (7)
H18	0.0494	0.6512	0.4321	0.047*
C20	0.06005 (12)	0.4432 (2)	0.4595 (3)	0.0495 (9)
H20	0.0534	0.3918	0.4206	0.059*
C19	0.04769 (11)	0.5205 (3)	0.4074 (3)	0.0505 (9)
H19	0.0330	0.5216	0.3338	0.061*
C21	0.08181 (13)	0.4399 (2)	0.5671 (3)	0.0492 (9)
H21	0.0903	0.3868	0.6009	0.059*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.01667 (5)	0.01738 (5)	0.01462 (5)	0.00128 (3)	0.00405 (3)	0.00030 (3)
S1	0.0171 (2)	0.0161 (2)	0.0162 (2)	0.0001 (2)	0.00498 (19)	0.00003 (19)
S2	0.0208 (3)	0.0168 (3)	0.0219 (3)	0.0015 (2)	0.0053 (2)	−0.0005 (2)
Cl2	0.0326 (3)	0.0306 (3)	0.0195 (3)	0.0045 (3)	0.0087 (2)	0.0069 (2)
Cl1	0.0377 (3)	0.0247 (3)	0.0198 (3)	0.0043 (2)	0.0096 (2)	−0.0043 (2)
C2	0.0233 (11)	0.0156 (10)	0.0244 (11)	−0.0020 (9)	0.0085 (9)	0.0005 (9)
C1	0.0193 (10)	0.0174 (11)	0.0248 (11)	0.0030 (9)	0.0055 (9)	0.0023 (9)
C5	0.0169 (10)	0.0220 (11)	0.0217 (11)	0.0031 (8)	0.0023 (8)	0.0029 (8)
C11	0.0179 (10)	0.0182 (11)	0.0215 (11)	−0.0033 (8)	0.0033 (8)	−0.0035 (8)
C4	0.0226 (12)	0.0207 (12)	0.0315 (13)	0.0049 (9)	0.0069 (10)	0.0063 (9)
C23	0.0234 (11)	0.0157 (10)	0.0252 (11)	0.0042 (9)	0.0049 (9)	0.0035 (9)
C10	0.0193 (11)	0.0270 (13)	0.0260 (12)	0.0020 (10)	0.0052 (9)	0.0031 (10)
C6	0.0279 (13)	0.0321 (14)	0.0273 (13)	−0.0003 (11)	0.0074 (11)	−0.0005 (11)
C3	0.0218 (12)	0.0254 (13)	0.0407 (15)	−0.0010 (10)	0.0098 (11)	−0.0060 (11)
C12	0.0230 (12)	0.0275 (14)	0.0321 (14)	−0.0033 (10)	0.0000 (10)	0.0066 (10)
C16	0.0229 (11)	0.0284 (13)	0.0254 (12)	−0.0018 (10)	0.0057 (9)	0.0025 (10)
C24	0.0321 (13)	0.0245 (12)	0.0234 (12)	0.0048 (11)	0.0052 (10)	0.0043 (10)
C17	0.0186 (11)	0.0260 (13)	0.0436 (16)	−0.0037 (10)	0.0073 (11)	−0.0074 (12)
C8	0.0242 (13)	0.0233 (13)	0.0482 (17)	−0.0037 (10)	0.0042 (12)	0.0005 (12)
C28	0.0302 (13)	0.0276 (13)	0.0283 (13)	−0.0001 (11)	0.0082 (11)	−0.0052 (11)
C25	0.0320 (14)	0.0296 (14)	0.0272 (13)	−0.0008 (11)	−0.0060 (11)	0.0027 (11)
C9	0.0205 (12)	0.0341 (14)	0.0362 (15)	0.0030 (11)	0.0086 (11)	0.0092 (12)
C15	0.0260 (13)	0.0410 (16)	0.0349 (15)	−0.0069 (12)	0.0128 (11)	−0.0026 (12)
C26	0.0248 (13)	0.0278 (14)	0.0464 (17)	0.0020 (11)	0.0079 (12)	0.0058 (12)
C14	0.0185 (12)	0.0338 (15)	0.0533 (19)	−0.0020 (11)	0.0089 (12)	−0.0093 (13)
C13	0.0211 (12)	0.0261 (14)	0.060 (2)	0.0009 (11)	−0.0050 (12)	0.0080 (13)
C7	0.0324 (15)	0.0332 (16)	0.0358 (15)	−0.0034 (12)	0.0006 (12)	−0.0101 (12)
C27	0.0337 (15)	0.0329 (15)	0.0411 (16)	0.0010 (12)	0.0177 (12)	−0.0051 (12)
C22	0.0365 (16)	0.0291 (15)	0.0517 (19)	−0.0068 (13)	0.0092 (14)	−0.0011 (14)
C18	0.0264 (14)	0.0429 (18)	0.0447 (18)	0.0071 (13)	−0.0011 (12)	−0.0026 (14)
C20	0.0369 (17)	0.0425 (19)	0.069 (3)	−0.0152 (15)	0.0119 (16)	−0.0194 (18)
C19	0.0236 (14)	0.075 (3)	0.048 (2)	−0.0046 (16)	−0.0027 (13)	−0.0196 (19)
C21	0.051 (2)	0.0255 (15)	0.072 (3)	−0.0072 (14)	0.0134 (18)	−0.0034 (16)

Geometric parameters (Å, º) top

Pt1—S2	2.2747 (6)	C16—C15	1.388 (4)
Pt1—S1	2.2755 (5)	C16—H16	0.9300
Pt1—Cl1	2.3082 (6)	C24—C25	1.395 (4)
Pt1—Cl2	2.3217 (6)	C24—H24	0.9300
S1—C1	1.820 (2)	C17—C18	1.372 (4)
S1—C2	1.833 (2)	C17—C22	1.395 (4)
S2—C4	1.831 (2)	C8—C7	1.384 (4)
S2—C3	1.833 (3)	C8—C9	1.393 (4)
C2—C11	1.500 (3)	C8—H8	0.9300
C2—H2A	0.9700	C28—C27	1.393 (4)
C2—H2B	0.9700	C28—H28	0.9300
C1—C5	1.506 (3)	C25—C26	1.380 (4)
C1—H1A	0.9700	C25—H25	0.9300
C1—H1B	0.9700	C9—H9	0.9300
C5—C6	1.385 (4)	C15—C14	1.372 (4)
C5—C10	1.392 (3)	C15—H15	0.9300
C11—C12	1.386 (3)	C26—C25	1.375 (4)
C11—C16	1.393 (3)	C26—H26	0.9300
C4—C23	1.500 (4)	C14—C13	1.385 (4)
C4—H4A	0.9700	C14—H14	0.9300
C4—H4B	0.9700	C13—H13	0.9300
C23—C24	1.386 (4)	C7—H7	0.9300
C23—C28	1.393 (4)	C27—H27	0.9300
C10—C9	1.380 (4)	C22—C21	1.390 (5)
C10—H10	0.9300	C22—H22	0.9300
C6—C7	1.394 (4)	C18—C19	1.412 (5)
C6—H6	0.9300	C18—H18	0.9300
C3—C17	1.498 (4)	C20—C21	1.362 (5)
C3—H3A	0.9700	C20—C19	1.370 (5)
C3—H3B	0.9700	C20—H20	0.9300
C12—C13	1.391 (4)	C19—H19	0.9300
C12—H12	0.9300	C21—H21	0.9300

S2—Pt1—S1	87.60 (2)	C15—C16—C11	120.2 (2)
S2—Pt1—Cl1	174.03 (2)	C15—C16—H16	119.9
S1—Pt1—Cl1	90.53 (2)	C11—C16—H16	119.9
S2—Pt1—Cl2	91.66 (2)	C23—C24—C25	120.2 (2)
S1—Pt1—Cl2	178.62 (2)	C23—C24—H24	119.9
Cl1—Pt1—Cl2	90.09 (2)	C25—C24—H24	119.9
C1—S1—C2	98.63 (11)	C18—C17—C22	119.1 (3)
C1—S1—Pt1	104.13 (8)	C18—C17—C3	120.6 (3)
C2—S1—Pt1	109.90 (8)	C22—C17—C3	120.3 (3)
C4—S2—C1	156.12 (9)	C7—C8—C9	119.8 (3)
C4—S2—Pt1	111.05 (9)	C7—C8—H8	120.1
C3—S2—Pt1	100.88 (9)	C9—C8—H8	120.1
C11—C2—S1	111.00 (16)	C27—C28—C23	120.1 (3)
C11—C2—H2A	109.4	C27—C28—H28	119.9
S1—C2—H2A	109.4	C23—C28—H28	119.9
C11—C2—H2B	109.4	C26—C25—C24	120.1 (3)
S1—C2—H2B	109.4	C26—C25—H25	119.9
H2A—C2—H2B	108.0	C24—C25—H25	119.9
C5—C1—S1	110.16 (16)	C10—C9—C8	119.7 (3)
C5—C1—H1A	109.6	C10—C9—H9	120.1
S1—C1—H1A	109.6	C8—C9—H9	120.1
C5—C1—H1B	109.6	C14—C15—C16	120.2 (3)
S1—C1—H1B	109.6	C14—C15—H15	119.9
H1A—C1—H1B	108.1	C16—C15—H15	119.9
C6—C5—C10	119.3 (2)	C27—C26—C25	120.0 (3)
C6—C5—C1	120.7 (2)	C27—C26—H26	120.0
C10—C5—C1	120.0 (2)	C25—C26—H26	120.0
C12—C11—C16	119.2 (2)	C15—C14—C13	120.2 (3)
C12—C11—C2	121.3 (2)	C15—C14—H14	119.9
C16—C11—C2	119.5 (2)	C13—C14—H14	119.9
C23—C4—S2	111.60 (17)	C14—C13—C12	119.8 (3)
C23—C4—H4A	109.3	C14—C13—H13	120.1
S2—C4—H4A	109.3	C12—C13—H13	120.1
C23—C4—H4B	109.3	C8—C7—C6	120.2 (3)
S2—C4—H4B	109.3	C8—C7—H7	119.9
H4A—C4—H4B	108.0	C6—C7—H7	119.9
C24—C23—C28	119.2 (2)	C26—C27—C28	120.3 (3)
C24—C23—C4	120.6 (2)	C26—C27—H27	119.9
C28—C23—C4	120.1 (2)	C28—C27—H27	119.9
C9—C10—C5	120.8 (2)	C21—C22—C17	120.7 (3)
C9—C10—H10	119.6	C21—C22—H22	119.6
C5—C10—H10	119.6	C17—C22—H22	119.6
C5—C6—C7	120.1 (3)	C17—C18—C19	120.2 (3)
C5—C6—H6	119.9	C17—C18—H18	119.9
C7—C6—H6	119.9	C19—C18—H18	119.9
C17—C3—S2	113.95 (18)	C21—C20—C19	121.6 (3)
C17—C3—H3A	108.8	C21—C20—H20	119.2
S2—C3—H3A	108.8	C19—C20—H20	119.2
C17—C3—H3B	108.8	C20—C19—C18	119.2 (3)
S2—C3—H3B	108.8	C20—C19—H19	120.4
H3A—C3—H3B	107.7	C18—C19—H19	120.4
C11—C12—C13	120.4 (3)	C20—C21—C22	119.3 (3)
C11—C12—H12	119.8	C20—C21—H21	120.4
C13—C12—H12	119.8	C22—C21—H21	120.4

(abmon100) cis-dichlorobis(dibenzyl sulfido-κS)platinum(II) top

Crystal data top

C₂₈H₂₈Cl₂PtS₂	F(000) = 2720
M_r = 694.61	D_x = 1.727 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 23700 reflections
a = 28.3057 (8) Å	θ = 2.4–32.7°
b = 15.3972 (6) Å	µ = 5.62 mm⁻¹
c = 12.5488 (5) Å	T = 100 K
β = 102.259 (3)°	Plate, pale yellow
V = 5344.4 (3) Å³	0.30 × 0.19 × 0.10 mm
Z = 8

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9026 independent reflections
Radiation source: Sealed tube	7633 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.041
ω–scans	θ_max = 32.7°, θ_min = 2.4°
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	h = −42→40
T_min = 0.285, T_max = 0.572	k = −22→23
23700 measured reflections	l = −19→14

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.032	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.081	H-atom parameters constrained
S = 1.01	w = 1/[σ²(F_o²) + (0.0556P)²] where P = (F_o² + 2F_c²)/3
9026 reflections	(Δ/σ)_max = 0.003
298 parameters	Δρ_max = 2.41 e Å⁻³
0 restraints	Δρ_min = −2.25 e Å⁻³

Crystal data top

C₂₈H₂₈Cl₂PtS₂	V = 5344.4 (3) Å³
M_r = 694.61	Z = 8
Monoclinic, C2/c	Mo Kα radiation
a = 28.3057 (8) Å	µ = 5.62 mm⁻¹
b = 15.3972 (6) Å	T = 100 K
c = 12.5488 (5) Å	0.30 × 0.19 × 0.10 mm
β = 102.259 (3)°

Data collection top

Oxford Diffraction XCALIBUR3 diffractometer	9026 independent reflections
Absorption correction: numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	7633 reflections with I > 2σ(I)
T_min = 0.285, T_max = 0.572	R_int = 0.041
23700 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.032	0 restraints
wR(F²) = 0.081	H-atom parameters constrained
S = 1.01	Δρ_max = 2.41 e Å⁻³
9026 reflections	Δρ_min = −2.25 e Å⁻³
298 parameters

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pt1	0.140544 (3)	0.855040 (6)	0.729602 (7)	0.01131 (4)
S1	0.13752 (2)	0.93162 (4)	0.57341 (5)	0.01183 (11)
S2	0.14495 (2)	0.73216 (4)	0.63147 (5)	0.01394 (12)
Cl2	0.14213 (2)	0.77512 (4)	0.88720 (5)	0.01844 (12)
Cl1	0.12755 (3)	0.98057 (4)	0.81973 (5)	0.01894 (13)
C2	0.17494 (10)	1.02944 (17)	0.6023 (2)	0.0149 (5)
H2A	0.1609	1.0755	0.5529	0.018*
H2B	0.1756	1.0487	0.6762	0.018*
C1	0.07827 (9)	0.98290 (17)	0.5473 (2)	0.0145 (5)
H1A	0.0750	1.0176	0.6098	0.017*
H1B	0.0750	1.0212	0.4847	0.017*
C5	0.03916 (9)	0.91506 (17)	0.5255 (2)	0.0147 (5)
C11	0.22571 (9)	1.01229 (17)	0.5895 (2)	0.0143 (5)
C4	0.18913 (11)	0.65625 (17)	0.7088 (2)	0.0172 (5)
H4A	0.1828	0.6489	0.7812	0.021*
H4B	0.1855	0.6001	0.6729	0.021*
C23	0.23991 (10)	0.68759 (17)	0.7181 (2)	0.0156 (5)
C10	0.01594 (10)	0.89020 (19)	0.6081 (2)	0.0171 (5)
H10	0.0259	0.9135	0.6776	0.021*
C6	0.02470 (11)	0.8781 (2)	0.4225 (2)	0.0203 (5)
H6	0.0403	0.8937	0.3672	0.024*
C3	0.08823 (10)	0.67837 (19)	0.6421 (2)	0.0195 (5)
H3A	0.0891	0.6658	0.7182	0.023*
H3B	0.0616	0.7180	0.6167	0.023*
C12	0.25615 (10)	0.95675 (19)	0.6600 (2)	0.0198 (5)
H12	0.2450	0.9290	0.7157	0.024*
C16	0.24279 (10)	1.05329 (18)	0.5062 (2)	0.0181 (5)
H16	0.2226	1.0900	0.4581	0.022*
C24	0.26430 (10)	0.72821 (18)	0.8134 (2)	0.0180 (5)
H24	0.2481	0.7406	0.8688	0.022*
C17	0.07891 (10)	0.59553 (19)	0.5781 (2)	0.0188 (5)
C8	−0.03673 (10)	0.79529 (18)	0.4839 (3)	0.0219 (6)
H8	−0.0624	0.7563	0.4698	0.026*
C28	0.26437 (11)	0.67217 (19)	0.6343 (2)	0.0196 (5)
H28	0.2482	0.6465	0.5698	0.024*
C25	0.31285 (11)	0.75020 (19)	0.8258 (2)	0.0204 (5)
H25	0.3291	0.7765	0.8899	0.024*
C9	−0.02184 (11)	0.8313 (2)	0.5878 (3)	0.0215 (6)
H9	−0.0373	0.8157	0.6434	0.026*
C15	0.29014 (11)	1.0395 (2)	0.4948 (3)	0.0223 (6)
H15	0.3015	1.0678	0.4399	0.027*
C26	0.33703 (11)	0.73304 (19)	0.7431 (3)	0.0220 (6)
H26	0.3696	0.7470	0.7520	0.026*
C14	0.32018 (11)	0.9840 (2)	0.5647 (3)	0.0246 (6)
H14	0.3516	0.9743	0.5563	0.029*
C13	0.30315 (11)	0.9424 (2)	0.6477 (3)	0.0254 (6)
H13	0.3233	0.9050	0.6950	0.030*
C7	−0.01286 (11)	0.8182 (2)	0.4014 (3)	0.0241 (6)
H7	−0.0221	0.7934	0.3325	0.029*
C27	0.31255 (11)	0.6949 (2)	0.6466 (3)	0.0241 (6)
H27	0.3286	0.6846	0.5904	0.029*
C22	0.09162 (11)	0.51570 (19)	0.6292 (3)	0.0237 (6)
H22	0.1064	0.5140	0.7028	0.028*
C18	0.05660 (11)	0.5972 (2)	0.4687 (3)	0.0241 (6)
H18	0.0478	0.6500	0.4340	0.029*
C20	0.05992 (12)	0.4411 (2)	0.4607 (3)	0.0311 (7)
H20	0.0536	0.3898	0.4213	0.037*
C19	0.04727 (11)	0.5194 (2)	0.4104 (3)	0.0301 (7)
H19	0.0324	0.5207	0.3369	0.036*
C21	0.08211 (12)	0.4386 (2)	0.5702 (3)	0.0294 (7)
H21	0.0907	0.3856	0.6043	0.035*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.01169 (6)	0.01247 (6)	0.01037 (5)	0.00069 (3)	0.00370 (4)	0.00013 (3)
S1	0.0124 (3)	0.0124 (3)	0.0116 (3)	−0.0002 (2)	0.0044 (2)	−0.0002 (2)
S2	0.0150 (3)	0.0126 (3)	0.0148 (3)	0.0010 (2)	0.0045 (2)	−0.0002 (2)
Cl2	0.0220 (3)	0.0212 (3)	0.0134 (3)	0.0023 (3)	0.0066 (2)	0.0039 (2)
Cl1	0.0268 (3)	0.0178 (3)	0.0137 (3)	0.0025 (3)	0.0076 (2)	−0.0027 (2)
C2	0.0166 (12)	0.0114 (11)	0.0182 (12)	−0.0014 (9)	0.0069 (9)	0.0006 (9)
C1	0.0160 (12)	0.0131 (11)	0.0148 (11)	0.0013 (9)	0.0043 (9)	0.0018 (9)
C5	0.0132 (11)	0.0153 (11)	0.0157 (11)	0.0020 (9)	0.0032 (9)	0.0019 (9)
C11	0.0131 (11)	0.0129 (11)	0.0167 (11)	−0.0034 (9)	0.0029 (9)	−0.0032 (9)
C4	0.0160 (13)	0.0151 (12)	0.0214 (13)	0.0024 (10)	0.0062 (10)	0.0041 (9)
C23	0.0155 (12)	0.0118 (11)	0.0195 (12)	0.0023 (9)	0.0040 (9)	0.0021 (9)
C10	0.0139 (12)	0.0207 (13)	0.0173 (12)	0.0020 (10)	0.0045 (9)	0.0027 (10)
C6	0.0189 (13)	0.0226 (13)	0.0199 (13)	0.0019 (11)	0.0054 (10)	0.0008 (11)
C3	0.0149 (12)	0.0182 (13)	0.0266 (14)	−0.0011 (10)	0.0072 (10)	−0.0057 (11)
C12	0.0182 (13)	0.0209 (13)	0.0196 (13)	−0.0022 (10)	0.0025 (10)	0.0033 (10)
C16	0.0150 (12)	0.0207 (13)	0.0188 (12)	0.0000 (10)	0.0046 (10)	0.0026 (10)
C24	0.0200 (13)	0.0183 (12)	0.0161 (12)	0.0026 (10)	0.0046 (10)	0.0028 (10)
C17	0.0138 (12)	0.0177 (12)	0.0255 (14)	−0.0008 (10)	0.0056 (10)	−0.0023 (10)
C8	0.0167 (13)	0.0162 (13)	0.0322 (16)	−0.0017 (10)	0.0038 (11)	−0.0006 (11)
C28	0.0211 (14)	0.0197 (13)	0.0184 (13)	−0.0012 (11)	0.0053 (10)	−0.0030 (10)
C25	0.0209 (13)	0.0206 (13)	0.0171 (12)	−0.0004 (11)	−0.0019 (10)	0.0029 (10)
C9	0.0179 (13)	0.0232 (13)	0.0251 (14)	0.0024 (11)	0.0083 (11)	0.0080 (11)
C15	0.0177 (13)	0.0272 (15)	0.0242 (14)	−0.0047 (11)	0.0094 (11)	−0.0027 (11)
C26	0.0195 (13)	0.0187 (13)	0.0282 (15)	0.0022 (11)	0.0062 (11)	0.0043 (11)
C14	0.0138 (13)	0.0237 (14)	0.0366 (17)	−0.0006 (11)	0.0063 (11)	−0.0069 (12)
C13	0.0157 (13)	0.0200 (14)	0.0374 (17)	0.0010 (11)	−0.0013 (12)	0.0045 (12)
C7	0.0240 (15)	0.0228 (15)	0.0245 (14)	−0.0009 (12)	0.0031 (11)	−0.0059 (12)
C27	0.0212 (14)	0.0237 (14)	0.0309 (16)	0.0014 (12)	0.0134 (12)	−0.0029 (12)
C22	0.0229 (14)	0.0203 (13)	0.0276 (15)	−0.0047 (11)	0.0047 (12)	0.0007 (11)
C18	0.0177 (13)	0.0258 (15)	0.0272 (15)	0.0034 (12)	0.0011 (11)	0.0013 (12)
C20	0.0256 (16)	0.0282 (16)	0.0401 (19)	−0.0083 (13)	0.0080 (14)	−0.0134 (14)
C19	0.0165 (14)	0.0429 (19)	0.0290 (16)	−0.0027 (14)	0.0004 (12)	−0.0114 (14)
C21	0.0287 (16)	0.0171 (14)	0.0422 (19)	−0.0026 (12)	0.0072 (14)	−0.0011 (13)

Geometric parameters (Å, º) top

Pt1—S1	2.2733 (6)	C16—C15	1.394 (4)
Pt1—S2	2.2753 (6)	C16—H16	0.9300
Pt1—Cl1	2.3080 (6)	C24—C25	1.392 (4)
Pt1—Cl2	2.3216 (6)	C24—H24	0.9300
S1—C1	1.819 (3)	C17—C18	1.384 (4)
S1—C2	1.833 (3)	C17—C22	1.398 (4)
S2—C4	1.832 (3)	C8—C7	1.397 (4)
S2—C3	1.836 (3)	C8—C9	1.397 (4)
C2—C11	1.503 (4)	C8—H8	0.9300
C2—H2A	0.9700	C28—C27	1.384 (4)
C2—H2B	0.9700	C28—H28	0.9300
C1—C5	1.504 (4)	C25—C26	1.385 (4)
C1—H1A	0.9700	C25—H25	0.9300
C1—H1B	0.9700	C9—H9	0.9300
C5—C6	1.392 (4)	C15—C14	1.381 (4)
C5—C10	1.393 (4)	C15—H15	0.9300
C11—C12	1.390 (4)	C26—C27	1.391 (4)
C11—C16	1.393 (4)	C26—H26	0.9300
C4—C23	1.497 (4)	C14—C13	1.393 (5)
C4—H4A	0.9700	C14—H14	0.9300
C4—H4B	0.9700	C13—H13	0.9300
C23—C24	1.396 (4)	C7—H7	0.9300
C23—C28	1.396 (4)	C27—H27	0.9300
C10—C9	1.384 (4)	C22—C21	1.395 (4)
C10—H10	0.9300	C22—H22	0.9300
C6—C7	1.390 (4)	C18—C19	1.400 (5)
C6—H6	0.9300	C18—H18	0.9300
C3—C17	1.501 (4)	C20—C19	1.372 (5)
C3—H3A	0.9700	C20—C21	1.384 (5)
C3—H3B	0.9700	C20—H20	0.9300
C12—C13	1.389 (4)	C19—H19	0.9300
C12—H12	0.9300	C21—H21	0.9300

S1—Pt1—S2	87.77 (2)	C11—C16—C15	120.2 (3)
S1—Pt1—Cl1	90.42 (2)	C11—C16—H16	119.9
S2—Pt1—Cl1	173.90 (2)	C15—C16—H16	119.9
S1—Pt1—Cl2	178.73 (2)	C25—C24—C23	120.1 (3)
S2—Pt1—Cl2	91.54 (2)	C25—C24—H24	119.9
Cl1—Pt1—Cl2	90.16 (2)	C23—C24—H24	119.9
C1—S1—C2	98.68 (12)	C18—C17—C22	119.4 (3)
C1—S1—Pt1	104.19 (9)	C18—C17—C3	120.4 (3)
C2—S1—Pt1	109.95 (9)	C22—C17—C3	120.2 (3)
C4—S2—C3	100.54 (13)	C7—C8—C9	119.6 (3)
C4—S2—Pt1	110.71 (10)	C7—C8—H8	120.2
C3—S2—Pt1	100.75 (9)	C9—C8—H8	120.2
C11—C2—S1	111.10 (18)	C27—C28—C23	120.5 (3)
C11—C2—H2A	109.4	C27—C28—H28	119.8
S1—C2—H2A	109.4	C23—C28—H28	119.8
C11—C2—H2B	109.4	C26—C25—C24	120.2 (3)
S1—C2—H2B	109.4	C26—C25—H25	119.9
H2A—C2—H2B	108.0	C24—C25—H25	119.9
C5—C1—S1	110.25 (18)	C10—C9—C8	120.0 (3)
C5—C1—H1A	109.6	C10—C9—H9	120.0
S1—C1—H1A	109.6	C8—C9—H9	120.0
C5—C1—H1B	109.6	C14—C15—C16	120.3 (3)
S1—C1—H1B	109.6	C14—C15—H15	119.8
H1A—C1—H1B	108.1	C16—C15—H15	119.8
C6—C5—C10	119.1 (3)	C25—C26—C27	119.9 (3)
C6—C5—C1	120.8 (2)	C25—C26—H26	120.0
C10—C5—C1	120.1 (2)	C27—C26—H26	120.0
C12—C11—C16	119.3 (3)	C15—C14—C13	119.7 (3)
C12—C11—C2	121.2 (2)	C15—C14—H14	120.2
C16—C11—C2	119.5 (2)	C13—C14—H14	120.2
C23—C4—S2	111.84 (18)	C12—C13—C14	120.1 (3)
C23—C4—H4A	109.2	C12—C13—H13	119.9
S2—C4—H4A	109.2	C14—C13—H13	119.9
C23—C4—H4B	109.2	C6—C7—C8	119.8 (3)
S2—C4—H4B	109.2	C6—C7—H7	120.1
H4A—C4—H4B	107.9	C8—C7—H7	120.1
C24—C23—C28	119.2 (3)	C28—C27—C26	120.0 (3)
C24—C23—C4	120.2 (2)	C28—C27—H27	120.0
C28—C23—C4	120.5 (3)	C26—C27—H27	120.0
C9—C10—C5	120.8 (3)	C21—C22—C17	120.1 (3)
C9—C10—H10	119.6	C21—C22—H22	119.9
C5—C10—H10	119.6	C17—C22—H22	119.9
C7—C6—C5	120.7 (3)	C17—C18—C19	119.9 (3)
C7—C6—H6	119.7	C17—C18—H18	120.1
C5—C6—H6	119.7	C19—C18—H18	120.1
C17—C3—S2	113.68 (19)	C19—C20—C21	120.0 (3)
C17—C3—H3A	108.8	C19—C20—H20	120.0
S2—C3—H3A	108.8	C21—C20—H20	120.0
C17—C3—H3B	108.8	C20—C19—C18	120.7 (3)
S2—C3—H3B	108.8	C20—C19—H19	119.7
H3A—C3—H3B	107.7	C18—C19—H19	119.7
C13—C12—C11	120.4 (3)	C20—C21—C22	120.0 (3)
C13—C12—H12	119.8	C20—C21—H21	120.0
C11—C12—H12	119.8	C22—C21—H21	120.0

Experimental details

	(abtri295)	(abtri250)	(abtri200)	(abtri150)
Crystal data
Chemical formula	C₂₈H₂₈Cl₂PtS₂	C₂₈H₂₈Cl₂PtS₂	C₂₈H₂₈Cl₂PtS₂	C₂₈H₂₈Cl₂PtS₂
M_r	694.61	694.61	694.61	694.61
Crystal system, space group	Triclinic, P1	Triclinic, P1	Triclinic, P1	Triclinic, P1
Temperature (K)	295	250	200	150
a, b, c (Å)	8.3661 (5), 12.2534 (6), 15.8692 (8)	8.3411 (7), 12.2228 (11), 15.8547 (19)	8.2930 (5), 12.1730 (8), 15.7892 (14)	8.2603 (4), 12.1587 (7), 15.7688 (10)
α, β, γ (°)	69.052 (5), 89.258 (4), 71.378 (5)	69.022 (10), 89.222 (8), 71.433 (8)	68.837 (7), 89.261 (6), 71.456 (6)	68.644 (5), 89.262 (5), 71.368 (5)
V (Å³)	1430.29 (15)	1421.5 (3)	1399.9 (2)	1388.04 (14)
Z	2	2	2	2
Radiation type	Mo Kα	Mo Kα	Mo Kα	Mo Kα
µ (mm⁻¹)	5.25	5.29	5.37	5.41
Crystal size (mm)	0.28 × 0.19 × 0.13	0.28 × 0.19 × 0.13	0.28 × 0.19 × 0.13	0.28 × 0.19 × 0.13

Data collection
Diffractometer	Oxford Diffraction XCALIBUR3 diffractometer	Oxford Diffraction XCALIBUR3 diffractometer	Oxford Diffraction XCALIBUR3 diffractometer	Oxford Diffraction XCALIBUR3 diffractometer
Absorption correction	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)
T_min, T_max	0.304, 0.569	0.302, 0.566	0.301, 0.562	0.299, 0.560
No. of measured, independent and observed [I > 2σ(I)] reflections	14109, 9122, 7325	12940, 8515, 6931	13148, 8659, 7523	13680, 8761, 7902
R_int	0.024	0.043	0.045	0.017
(sin θ/λ)_max (Å⁻¹)	0.760	0.758	0.761	0.761

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.036, 0.102, 0.99	0.035, 0.089, 1.01	0.034, 0.088, 1.02	0.020, 0.052, 0.98
No. of reflections	9122	8515	8659	8761
No. of parameters	360	372	318	336
No. of restraints	72	72	36	30
H-atom treatment	H-atom parameters constrained	H-atom parameters constrained	H-atom parameters constrained	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	2.23, −1.88	2.15, −1.52	2.83, −1.88	2.13, −0.85

	(tri100)	(abmon295)	(abmon250)	(abmon200)
Crystal data
Chemical formula	C₂₈H₂₈Cl₂PtS₂	C₂₈H₂₈Cl₂PtS₂	C₂₈H₂₈Cl₂PtS₂	C₂₈H₂₈Cl₂PtS₂
M_r	694.61	694.61	694.61	694.61
Crystal system, space group	Triclinic, P1	Monoclinic, C2/c	Monoclinic, C2/c	Monoclinic, C2/c
Temperature (K)	100	295	250	200
a, b, c (Å)	8.2487 (3), 12.1346 (6), 15.7583 (10)	28.6839 (11), 15.5752 (6), 12.7019 (5)	28.5503 (10), 15.5016 (6), 12.6508 (5)	28.4657 (9), 15.4653 (6), 12.6114 (5)
α, β, γ (°)	68.528 (6), 89.499 (4), 71.565 (4)	90, 102.584 (3), 90	90, 102.560 (3), 90	90, 102.499 (3), 90
V (Å³)	1382.26 (14)	5538.3 (4)	5464.9 (4)	5420.3 (4)
Z	2	8	8	8
Radiation type	Mo Kα	Mo Kα	Mo Kα	Mo Kα
µ (mm⁻¹)	5.44	5.43	5.50	5.54
Crystal size (mm)	0.28 × 0.19 × 0.13	0.30 × 0.19 × 0.10	0.30 × 0.19 × 0.10	0.30 × 0.19 × 0.10

Data collection
Diffractometer	Oxford Diffraction XCALIBUR3 diffractometer	Oxford Diffraction XCALIBUR3 diffractometer	Oxford Diffraction XCALIBUR3 diffractometer	Oxford Diffraction XCALIBUR3 diffractometer
Absorption correction	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)
T_min, T_max	0.297, 0.557	0.297, 0.581	0.297, 0.579	0.298, 0.578
No. of measured, independent and observed [I > 2σ(I)] reflections	13506, 8697, 7959	23942, 9449, 6667	24554, 9148, 6689	24317, 9100, 7099
R_int	0.025	0.060	0.036	0.038
(sin θ/λ)_max (Å⁻¹)	0.762	0.761	0.759	0.761

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.021, 0.055, 1.04	0.046, 0.126, 1.00	0.031, 0.079, 0.99	0.030, 0.078, 1.01
No. of reflections	8697	9449	9148	9100
No. of parameters	396	298	298	298
No. of restraints	18	0	0	0
H-atom treatment	H-atom parameters constrained	H-atom parameters constrained	H-atom parameters constrained	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	2.43, −1.05	2.15, −2.34	2.00, −1.54	2.37, −1.39

	(abmon150)	(abmon100)
Crystal data
Chemical formula	C₂₈H₂₈Cl₂PtS₂	C₂₈H₂₈Cl₂PtS₂
M_r	694.61	694.61
Crystal system, space group	Monoclinic, C2/c	Monoclinic, C2/c
Temperature (K)	150	100
a, b, c (Å)	28.3708 (9), 15.4372 (6), 12.5812 (5)	28.3057 (8), 15.3972 (6), 12.5488 (5)
α, β, γ (°)	90, 102.432 (3), 90	90, 102.259 (3), 90
V (Å³)	5380.9 (3)	5344.4 (3)
Z	8	8
Radiation type	Mo Kα	Mo Kα
µ (mm⁻¹)	5.58	5.62
Crystal size (mm)	0.30 × 0.19 × 0.10	0.30 × 0.19 × 0.10

Data collection
Diffractometer	Oxford Diffraction XCALIBUR3 diffractometer	Oxford Diffraction XCALIBUR3 diffractometer
Absorption correction	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)	Numerical (CrysAlis 1.171.29, Oxford Diffraction, 2006)
T_min, T_max	0.296, 0.573	0.285, 0.572
No. of measured, independent and observed [I > 2σ(I)] reflections	24840, 9119, 7490	23700, 9026, 7633
R_int	0.031	0.041
(sin θ/λ)_max (Å⁻¹)	0.762	0.761

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.026, 0.065, 1.06	0.032, 0.081, 1.01
No. of reflections	9119	9026
No. of parameters	298	298
No. of restraints	0	0
H-atom treatment	H-atom parameters constrained	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	2.06, −1.61	2.41, −2.25

Computer programs: CrysAlis 1.171.29 (Oxford Diffraction, 2006), SHELXTL 5.1 (Sheldrick, 1998), DIAMOND (Brandenburg, 2000), Mercury (Bruno et al., 2002, enCIFer version 1.1 (CCDC, 2004).

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