metal-organic compounds
The structure of [Ni(medien)(NCS)(μ-SCN)]n [medien is N-(2-aminoethyl)-N-methylethane-1,2-diamine, C5H15N3] is a polymeric chain with each pair of neighbouring nickel(II) ions linked by one SCN− bridging ligand. The coordination polyhedron about the NiII atom is a distorted octahedron consisting of three N atoms of the medien ligand coordinating facially, one N atom of the non-bridging thiocyanate ligand, and one N and one S atom of two bridging thiocyanate ligands. The five-membered chelate rings display envelope geometry.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (SHELXL table format) |
CCDC reference: 129522