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The molecule of the red title compound trans-tetra(chloro/bromo)bis(triphenylphosphine oxide-O)rhenium(IV), [ReBr2.5Cl1.5{OP(C6H5)3}2], lies on a crystallographic centre of symmetry. Coordination of rhenium by the four halides is square planar, capped by two mutually trans triphenylphosphine oxide groups.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, s365

fcf

Structure factor file (CIF format)
Contains datablock s365

CCDC reference: 130160

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