Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803023092/cf6284sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536803023092/cf6284Isup2.hkl |
CCDC reference: 226662
Data collection: SMART (Siemens, 1996); cell refinement: SMART; data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.
[Co(C16H23N2O)2]ClO4 | Z = 1 |
Mr = 677.11 | F(000) = 358 |
Triclinic, P1 | Dx = 1.417 Mg m−3 |
a = 8.547 (5) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 9.431 (6) Å | Cell parameters from 822 reflections |
c = 10.222 (6) Å | θ = 2.5–22.1° |
α = 96.143 (10)° | µ = 0.68 mm−1 |
β = 94.232 (9)° | T = 298 K |
γ = 103.217 (9)° | Block, brown |
V = 793.4 (8) Å3 | 0.22 × 0.15 × 0.13 mm |
Bruker SMART CCD area-detector diffractometer | 2732 independent reflections |
Radiation source: fine-focus sealed tube | 1653 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.045 |
φ and ω scans | θmax = 25.0°, θmin = 2.2° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −10→9 |
Tmin = 0.866, Tmax = 0.917 | k = −7→11 |
4017 measured reflections | l = −11→12 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.066 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.149 | H-atom parameters constrained |
S = 0.90 | w = 1/[σ2(Fo2) + (0.0674P)2] where P = (Fo2 + 2Fc2)/3 |
2732 reflections | (Δ/σ)max < 0.001 |
200 parameters | Δρmax = 0.47 e Å−3 |
8 restraints | Δρmin = −0.34 e Å−3 |
Experimental. C, H and N elemental analyses were performed on a Perkin-Elmer elemental analyser. The IR spectra were recorded in the 4000–600 cm-1 region using a Smart OMNI-Sampler spectrophotometer. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Co1 | 1.0000 | 1.0000 | 0.0000 | 0.0385 (3) | |
Cl1 | 1.0000 | 0.5000 | 0.5000 | 0.0832 (7) | |
N1 | 1.0069 (4) | 0.8041 (4) | −0.0741 (3) | 0.0410 (9) | |
N2 | 0.9874 (4) | 0.9328 (4) | 0.1815 (3) | 0.0403 (9) | |
H2 | 1.0346 | 1.0178 | 0.2349 | 0.048* | |
O1 | 0.7746 (3) | 0.9567 (3) | −0.0367 (3) | 0.0400 (7) | |
O2 | 1.1381 (11) | 0.5758 (10) | 0.4375 (9) | 0.110 (3)* | 0.50 |
O3 | 0.8632 (15) | 0.5495 (19) | 0.4658 (16) | 0.215 (7)* | 0.50 |
O4 | 1.0488 (13) | 0.4996 (11) | 0.6319 (9) | 0.122 (3)* | 0.50 |
O5 | 0.9773 (14) | 0.3416 (11) | 0.4360 (10) | 0.138 (4)* | 0.50 |
C1 | 0.8975 (5) | 0.7203 (5) | −0.1588 (4) | 0.0429 (11) | |
H1 | 0.9196 | 0.6339 | −0.1969 | 0.051* | |
C2 | 0.7440 (5) | 0.7475 (5) | −0.2003 (4) | 0.0395 (11) | |
C3 | 0.6405 (6) | 0.6461 (5) | −0.2984 (4) | 0.0543 (13) | |
H3 | 0.6790 | 0.5726 | −0.3441 | 0.065* | |
C4 | 0.4850 (6) | 0.6539 (6) | −0.3272 (5) | 0.0537 (13) | |
H4 | 0.4175 | 0.5863 | −0.3922 | 0.064* | |
C5 | 0.4287 (6) | 0.7625 (5) | −0.2595 (5) | 0.0521 (13) | |
H5 | 0.3223 | 0.7677 | −0.2790 | 0.063* | |
C6 | 0.5262 (5) | 0.8633 (5) | −0.1638 (4) | 0.0457 (12) | |
H6 | 0.4852 | 0.9358 | −0.1192 | 0.055* | |
C7 | 0.6869 (5) | 0.8585 (5) | −0.1322 (4) | 0.0384 (11) | |
C8 | 1.1320 (6) | 0.7389 (5) | −0.0170 (5) | 0.0492 (12) | |
H8A | 1.2369 | 0.8071 | −0.0110 | 0.059* | |
H8B | 1.1356 | 0.6498 | −0.0724 | 0.059* | |
C9 | 1.0909 (6) | 0.7040 (5) | 0.1203 (5) | 0.0553 (13) | |
H9A | 0.9842 | 0.6385 | 0.1120 | 0.066* | |
H9B | 1.1670 | 0.6518 | 0.1549 | 0.066* | |
C10 | 1.0934 (6) | 0.8353 (5) | 0.2193 (5) | 0.0529 (13) | |
H10A | 1.0627 | 0.8003 | 0.3017 | 0.063* | |
H10B | 1.2037 | 0.8940 | 0.2361 | 0.063* | |
C11 | 0.8212 (5) | 0.8976 (5) | 0.2272 (4) | 0.0453 (12) | |
H11 | 0.7620 | 0.9632 | 0.1885 | 0.054* | |
C12 | 0.7255 (6) | 0.7406 (5) | 0.1780 (4) | 0.0503 (13) | |
H12A | 0.7275 | 0.7201 | 0.0832 | 0.060* | |
H12B | 0.7734 | 0.6712 | 0.2204 | 0.060* | |
C13 | 0.5524 (6) | 0.7248 (6) | 0.2110 (5) | 0.0615 (15) | |
H13A | 0.5042 | 0.7925 | 0.1662 | 0.074* | |
H13B | 0.4901 | 0.6259 | 0.1798 | 0.074* | |
C14 | 0.5469 (6) | 0.7565 (7) | 0.3587 (5) | 0.0689 (16) | |
H14A | 0.5842 | 0.6820 | 0.4022 | 0.083* | |
H14B | 0.4361 | 0.7512 | 0.3769 | 0.083* | |
C15 | 0.6509 (7) | 0.9069 (6) | 0.4151 (5) | 0.0694 (16) | |
H15A | 0.6031 | 0.9821 | 0.3829 | 0.083* | |
H15B | 0.6537 | 0.9183 | 0.5108 | 0.083* | |
C16 | 0.8209 (6) | 0.9276 (6) | 0.3768 (4) | 0.0556 (14) | |
H16A | 0.8740 | 0.8614 | 0.4191 | 0.067* | |
H16B | 0.8812 | 1.0274 | 0.4076 | 0.067* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Co1 | 0.0395 (5) | 0.0310 (5) | 0.0443 (5) | 0.0068 (4) | 0.0056 (4) | 0.0042 (4) |
Cl1 | 0.0609 (13) | 0.124 (2) | 0.0680 (14) | 0.0309 (13) | 0.0058 (11) | 0.0085 (14) |
N1 | 0.047 (2) | 0.032 (2) | 0.044 (2) | 0.0118 (18) | 0.0086 (18) | −0.0021 (18) |
N2 | 0.037 (2) | 0.032 (2) | 0.051 (2) | 0.0068 (16) | 0.0035 (17) | 0.0085 (18) |
O1 | 0.0393 (17) | 0.0310 (16) | 0.0473 (17) | 0.0065 (13) | 0.0009 (13) | 0.0014 (14) |
C1 | 0.051 (3) | 0.030 (2) | 0.049 (3) | 0.012 (2) | 0.010 (2) | 0.002 (2) |
C2 | 0.039 (3) | 0.034 (2) | 0.042 (3) | 0.002 (2) | 0.008 (2) | 0.005 (2) |
C3 | 0.069 (4) | 0.041 (3) | 0.047 (3) | 0.006 (3) | −0.001 (3) | 0.000 (2) |
C4 | 0.054 (3) | 0.052 (3) | 0.047 (3) | 0.000 (3) | −0.004 (2) | 0.003 (3) |
C5 | 0.043 (3) | 0.056 (3) | 0.057 (3) | 0.010 (3) | 0.002 (2) | 0.010 (3) |
C6 | 0.039 (3) | 0.042 (3) | 0.054 (3) | 0.010 (2) | 0.001 (2) | 0.000 (2) |
C7 | 0.042 (3) | 0.034 (3) | 0.038 (2) | 0.005 (2) | 0.007 (2) | 0.008 (2) |
C8 | 0.049 (3) | 0.035 (3) | 0.064 (3) | 0.010 (2) | 0.008 (2) | 0.002 (2) |
C9 | 0.053 (3) | 0.041 (3) | 0.074 (3) | 0.011 (2) | 0.004 (3) | 0.021 (3) |
C10 | 0.053 (3) | 0.044 (3) | 0.061 (3) | 0.005 (2) | 0.006 (2) | 0.020 (3) |
C11 | 0.046 (3) | 0.047 (3) | 0.046 (3) | 0.013 (2) | 0.012 (2) | 0.009 (2) |
C12 | 0.051 (3) | 0.049 (3) | 0.048 (3) | 0.004 (2) | 0.011 (2) | 0.009 (2) |
C13 | 0.052 (3) | 0.058 (3) | 0.069 (3) | 0.000 (3) | 0.007 (3) | 0.015 (3) |
C14 | 0.058 (3) | 0.080 (4) | 0.072 (4) | 0.011 (3) | 0.025 (3) | 0.022 (3) |
C15 | 0.081 (4) | 0.078 (4) | 0.055 (3) | 0.024 (3) | 0.022 (3) | 0.015 (3) |
C16 | 0.067 (3) | 0.051 (3) | 0.046 (3) | 0.009 (3) | 0.009 (2) | 0.003 (2) |
Co1—O1i | 1.876 (3) | C6—H6 | 0.930 |
Co1—O1 | 1.876 (3) | C8—C9 | 1.522 (6) |
Co1—N1 | 1.936 (4) | C8—H8A | 0.970 |
Co1—N1i | 1.936 (4) | C8—H8B | 0.970 |
Co1—N2 | 2.026 (3) | C9—C10 | 1.508 (7) |
Co1—N2i | 2.026 (4) | C9—H9A | 0.970 |
Cl1—O4 | 1.383 (9) | C9—H9B | 0.970 |
Cl1—O3 | 1.390 (12) | C10—H10A | 0.970 |
Cl1—O2 | 1.462 (8) | C10—H10B | 0.970 |
Cl1—O5 | 1.529 (10) | C11—C16 | 1.525 (6) |
N1—C1 | 1.283 (5) | C11—C12 | 1.530 (6) |
N1—C8 | 1.465 (6) | C11—H11 | 0.980 |
N2—C10 | 1.490 (6) | C12—C13 | 1.519 (6) |
N2—C11 | 1.503 (5) | C12—H12A | 0.970 |
N2—H2 | 0.910 | C12—H12B | 0.970 |
O1—C7 | 1.324 (5) | C13—C14 | 1.514 (7) |
C1—C2 | 1.436 (6) | C13—H13A | 0.970 |
C1—H1 | 0.930 | C13—H13B | 0.970 |
C2—C7 | 1.395 (6) | C14—C15 | 1.519 (7) |
C2—C3 | 1.407 (6) | C14—H14A | 0.970 |
C3—C4 | 1.360 (7) | C14—H14B | 0.970 |
C3—H3 | 0.930 | C15—C16 | 1.508 (7) |
C4—C5 | 1.372 (7) | C15—H15A | 0.970 |
C4—H4 | 0.930 | C15—H15B | 0.970 |
C5—C6 | 1.369 (6) | C16—H16A | 0.970 |
C5—H5 | 0.930 | C16—H16B | 0.970 |
C6—C7 | 1.400 (6) | ||
O1i—Co1—O1 | 180.0 | N1—C8—H8A | 110.1 |
O1i—Co1—N1 | 88.48 (14) | C9—C8—H8A | 110.1 |
O1—Co1—N1 | 91.52 (14) | N1—C8—H8B | 110.1 |
O1i—Co1—N1i | 91.52 (14) | C9—C8—H8B | 110.1 |
O1—Co1—N1i | 88.48 (14) | H8A—C8—H8B | 108.4 |
N1—Co1—N1i | 180.0 | C10—C9—C8 | 115.2 (4) |
O1i—Co1—N2 | 86.94 (13) | C10—C9—H9A | 108.5 |
O1—Co1—N2 | 93.06 (13) | C8—C9—H9A | 108.5 |
N1—Co1—N2 | 89.66 (15) | C10—C9—H9B | 108.5 |
N1i—Co1—N2 | 90.34 (15) | C8—C9—H9B | 108.5 |
O1i—Co1—N2i | 93.06 (13) | H9A—C9—H9B | 107.5 |
O1—Co1—N2i | 86.94 (13) | N2—C10—C9 | 116.5 (4) |
N1—Co1—N2i | 90.34 (15) | N2—C10—H10A | 108.2 |
N1i—Co1—N2i | 89.66 (15) | C9—C10—H10A | 108.2 |
N2—Co1—N2i | 180.0 | N2—C10—H10B | 108.2 |
O4—Cl1—O3 | 119.5 (7) | C9—C10—H10B | 108.2 |
O4—Cl1—O2 | 108.5 (5) | H10A—C10—H10B | 107.3 |
O3—Cl1—O2 | 110.9 (7) | N2—C11—C16 | 113.5 (4) |
O4—Cl1—O5 | 105.4 (5) | N2—C11—C12 | 113.2 (4) |
O3—Cl1—O5 | 109.4 (8) | C16—C11—C12 | 109.6 (4) |
O2—Cl1—O5 | 101.6 (5) | N2—C11—H11 | 106.7 |
C1—N1—C8 | 117.1 (4) | C16—C11—H11 | 106.7 |
C1—N1—Co1 | 124.1 (3) | C12—C11—H11 | 106.7 |
C8—N1—Co1 | 118.2 (3) | C13—C12—C11 | 108.7 (4) |
C10—N2—C11 | 115.5 (3) | C13—C12—H12A | 110.0 |
C10—N2—Co1 | 117.5 (3) | C11—C12—H12A | 110.0 |
C11—N2—Co1 | 115.5 (3) | C13—C12—H12B | 110.0 |
C10—N2—H2 | 101.4 | C11—C12—H12B | 110.0 |
C11—N2—H2 | 101.4 | H12A—C12—H12B | 108.3 |
Co1—N2—H2 | 101.4 | C14—C13—C12 | 110.7 (4) |
C7—O1—Co1 | 126.3 (3) | C14—C13—H13A | 109.5 |
N1—C1—C2 | 126.1 (4) | C12—C13—H13A | 109.5 |
N1—C1—H1 | 117.0 | C14—C13—H13B | 109.5 |
C2—C1—H1 | 117.0 | C12—C13—H13B | 109.5 |
C7—C2—C3 | 119.6 (4) | H13A—C13—H13B | 108.1 |
C7—C2—C1 | 121.2 (4) | C13—C14—C15 | 112.0 (4) |
C3—C2—C1 | 118.5 (4) | C13—C14—H14A | 109.2 |
C4—C3—C2 | 121.0 (5) | C15—C14—H14A | 109.2 |
C4—C3—H3 | 119.5 | C13—C14—H14B | 109.2 |
C2—C3—H3 | 119.5 | C15—C14—H14B | 109.2 |
C3—C4—C5 | 119.3 (4) | H14A—C14—H14B | 107.9 |
C3—C4—H4 | 120.3 | C16—C15—C14 | 111.6 (5) |
C5—C4—H4 | 120.3 | C16—C15—H15A | 109.3 |
C6—C5—C4 | 121.2 (5) | C14—C15—H15A | 109.3 |
C6—C5—H5 | 119.4 | C16—C15—H15B | 109.3 |
C4—C5—H5 | 119.4 | C14—C15—H15B | 109.3 |
C5—C6—C7 | 120.8 (5) | H15A—C15—H15B | 108.0 |
C5—C6—H6 | 119.6 | C15—C16—C11 | 111.0 (4) |
C7—C6—H6 | 119.6 | C15—C16—H16A | 109.4 |
O1—C7—C2 | 123.7 (4) | C11—C16—H16A | 109.4 |
O1—C7—C6 | 118.2 (4) | C15—C16—H16B | 109.4 |
C2—C7—C6 | 118.1 (4) | C11—C16—H16B | 109.4 |
N1—C8—C9 | 108.2 (4) | H16A—C16—H16B | 108.0 |
O1i—Co1—N1—C1 | −156.9 (3) | C4—C5—C6—C7 | 0.0 (7) |
O1—Co1—N1—C1 | 23.1 (3) | Co1—O1—C7—C2 | 16.1 (5) |
N2—Co1—N1—C1 | 116.2 (4) | Co1—O1—C7—C6 | −166.0 (3) |
N2i—Co1—N1—C1 | −63.8 (4) | C3—C2—C7—O1 | 178.6 (4) |
O1i—Co1—N1—C8 | 32.2 (3) | C1—C2—C7—O1 | 8.4 (6) |
O1—Co1—N1—C8 | −147.8 (3) | C3—C2—C7—C6 | 0.7 (6) |
N2—Co1—N1—C8 | −54.8 (3) | C1—C2—C7—C6 | −169.5 (4) |
N2i—Co1—N1—C8 | 125.2 (3) | C5—C6—C7—O1 | −178.5 (4) |
O1i—Co1—N2—C10 | −46.4 (3) | C5—C6—C7—C2 | −0.5 (6) |
O1—Co1—N2—C10 | 133.6 (3) | C1—N1—C8—C9 | −101.2 (4) |
N1—Co1—N2—C10 | 42.1 (3) | Co1—N1—C8—C9 | 70.4 (4) |
N1i—Co1—N2—C10 | −137.9 (3) | N1—C8—C9—C10 | −64.0 (5) |
O1i—Co1—N2—C11 | 171.8 (3) | C11—N2—C10—C9 | 92.5 (5) |
O1—Co1—N2—C11 | −8.2 (3) | Co1—N2—C10—C9 | −49.3 (5) |
N1—Co1—N2—C11 | −99.7 (3) | C8—C9—C10—N2 | 56.3 (6) |
N1i—Co1—N2—C11 | 80.3 (3) | C10—N2—C11—C16 | 68.3 (5) |
N1—Co1—O1—C7 | −27.2 (3) | Co1—N2—C11—C16 | −149.1 (3) |
N1i—Co1—O1—C7 | 152.8 (3) | C10—N2—C11—C12 | −57.5 (5) |
N2—Co1—O1—C7 | −116.9 (3) | Co1—N2—C11—C12 | 85.1 (4) |
N2i—Co1—O1—C7 | 63.1 (3) | N2—C11—C12—C13 | −171.1 (4) |
C8—N1—C1—C2 | 162.6 (4) | C16—C11—C12—C13 | 61.0 (5) |
Co1—N1—C1—C2 | −8.5 (6) | C11—C12—C13—C14 | −59.6 (6) |
N1—C1—C2—C7 | −12.2 (7) | C12—C13—C14—C15 | 55.7 (7) |
N1—C1—C2—C3 | 177.6 (4) | C13—C14—C15—C16 | −52.6 (7) |
C7—C2—C3—C4 | −0.5 (7) | C14—C15—C16—C11 | 54.1 (6) |
C1—C2—C3—C4 | 170.0 (4) | N2—C11—C16—C15 | 173.5 (4) |
C2—C3—C4—C5 | 0.0 (7) | C12—C11—C16—C15 | −58.8 (6) |
C3—C4—C5—C6 | 0.2 (7) |
Symmetry code: (i) −x+2, −y+2, −z. |