metal-organic compounds
The SnIV atom in the title compound, [Sn(CH3)2(C15H21N7S2)]Cl2, is chelated by the deprotonated 2,6-diacetylpyridine bis(4-ethylthiosemicarbazone) ligand in a trans-C2SnN3S2 pentagonal–bipyramidal geometry.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806042619/ci2193sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806042619/ci2193Isup2.hkl |
CCDC reference: 627465
Computing details top
Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: SHELXL97.
[2,6-Diacetylpyridine
bis(4-ethylthiosemicarbazonato)-κ5N,N',N'',S',S'']dimethyltin(IV) dichloride top
Crystal data top
[Sn(CH3)2(C15H21N7S2)]Cl2 | Z = 2 |
Mr = 583.17 | F(000) = 588 |
Triclinic, P1 | Dx = 1.564 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 8.533 (1) Å | Cell parameters from 941 reflections |
b = 10.031 (1) Å | θ = 3.2–28.0° |
c = 15.451 (2) Å | µ = 1.43 mm−1 |
α = 79.736 (1)° | T = 293 K |
β = 87.300 (1)° | Block, yellow |
γ = 72.100 (1)° | 0.45 × 0.41 × 0.25 mm |
V = 1238.4 (2) Å3 |
Data collection top
Bruker APEX area-detector diffractometer | 5443 independent reflections |
Radiation source: fine-focus sealed tube | 5145 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.018 |
ω and φ scans | θmax = 27.5°, θmin = 2.2° |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | h = −11→11 |
Tmin = 0.586, Tmax = 0.732 | k = −12→12 |
13463 measured reflections | l = −19→20 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.033 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.100 | H-atom parameters constrained |
S = 1.08 | w = 1/[σ2(Fo2) + (0.0661P)2 + 0.8148P] where P = (Fo2 + 2Fc2)/3 |
5443 reflections | (Δ/σ)max = 0.001 |
268 parameters | Δρmax = 0.90 e Å−3 |
0 restraints | Δρmin = −1.13 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Sn1 | 0.79770 (2) | 0.599310 (17) | 0.712883 (11) | 0.03523 (8) | |
Cl1 | 0.71367 (12) | −0.03272 (8) | 0.89050 (6) | 0.0560 (2) | |
Cl2 | 0.6095 (5) | 0.1469 (5) | 1.0467 (3) | 0.2397 (19) | |
S1 | 0.64997 (12) | 0.80390 (9) | 0.58716 (7) | 0.0634 (3) | |
S2 | 0.56393 (12) | 0.47327 (9) | 0.67315 (6) | 0.0561 (2) | |
N1 | 0.7256 (4) | 1.0422 (3) | 0.5399 (2) | 0.0558 (7) | |
H1N | 0.6482 | 1.0594 | 0.5020 | 0.067* | |
N2 | 0.8855 (3) | 0.8985 (3) | 0.65061 (18) | 0.0452 (6) | |
N3 | 0.9294 (3) | 0.7712 (2) | 0.70776 (16) | 0.0387 (5) | |
N4 | 1.0150 (3) | 0.5251 (3) | 0.81960 (15) | 0.0387 (5) | |
N5 | 0.8406 (3) | 0.3512 (3) | 0.80875 (16) | 0.0413 (5) | |
N6 | 0.7430 (3) | 0.2685 (3) | 0.80014 (18) | 0.0483 (6) | |
N7 | 0.5367 (4) | 0.2216 (3) | 0.7396 (2) | 0.0541 (7) | |
H7N | 0.5710 | 0.1409 | 0.7741 | 0.065* | |
C1 | 0.7348 (6) | 1.2778 (4) | 0.4719 (3) | 0.0716 (11) | |
H1A | 0.7960 | 1.3441 | 0.4705 | 0.107* | |
H1B | 0.6222 | 1.3219 | 0.4863 | 0.107* | |
H1C | 0.7394 | 1.2499 | 0.4154 | 0.107* | |
C2 | 0.8084 (5) | 1.1484 (3) | 0.5406 (3) | 0.0557 (8) | |
H2A | 0.9246 | 1.1085 | 0.5289 | 0.067* | |
H2B | 0.7983 | 1.1757 | 0.5982 | 0.067* | |
C3 | 0.7647 (4) | 0.9178 (3) | 0.5962 (2) | 0.0454 (6) | |
C4 | 1.0468 (4) | 0.7542 (3) | 0.7625 (2) | 0.0421 (6) | |
C5 | 1.1269 (5) | 0.8655 (4) | 0.7652 (3) | 0.0610 (9) | |
H5A | 1.0466 | 0.9577 | 0.7524 | 0.092* | |
H5B | 1.2127 | 0.8582 | 0.7222 | 0.092* | |
H5C | 1.1730 | 0.8526 | 0.8226 | 0.092* | |
C6 | 1.0990 (4) | 0.6174 (3) | 0.82387 (19) | 0.0413 (6) | |
C7 | 1.2291 (5) | 0.5848 (4) | 0.8826 (2) | 0.0579 (9) | |
H7 | 1.2838 | 0.6508 | 0.8863 | 0.070* | |
C8 | 1.2754 (5) | 0.4526 (5) | 0.9353 (3) | 0.0705 (12) | |
H8 | 1.3654 | 0.4269 | 0.9731 | 0.085* | |
C9 | 1.1879 (5) | 0.3582 (4) | 0.9319 (2) | 0.0618 (10) | |
H9 | 1.2170 | 0.2694 | 0.9679 | 0.074* | |
C10 | 1.0561 (4) | 0.3981 (3) | 0.87385 (19) | 0.0432 (6) | |
C11 | 0.9548 (4) | 0.3039 (3) | 0.8680 (2) | 0.0440 (6) | |
C12 | 0.9868 (5) | 0.1650 (4) | 0.9302 (3) | 0.0671 (11) | |
H12A | 0.8865 | 0.1597 | 0.9594 | 0.101* | |
H12B | 1.0679 | 0.1584 | 0.9731 | 0.101* | |
H12C | 1.0266 | 0.0880 | 0.8979 | 0.101* | |
C13 | 0.6169 (4) | 0.3149 (3) | 0.7405 (2) | 0.0423 (6) | |
C14 | 0.3944 (5) | 0.2467 (4) | 0.6841 (3) | 0.0696 (11) | |
H14A | 0.4257 | 0.2608 | 0.6228 | 0.083* | |
H14B | 0.3100 | 0.3324 | 0.6946 | 0.083* | |
C15 | 0.3271 (6) | 0.1237 (5) | 0.7028 (4) | 0.0856 (15) | |
H15A | 0.4120 | 0.0384 | 0.6948 | 0.128* | |
H15B | 0.2370 | 0.1398 | 0.6634 | 0.128* | |
H15C | 0.2890 | 0.1140 | 0.7624 | 0.128* | |
C17 | 0.6367 (5) | 0.6716 (4) | 0.8150 (3) | 0.0579 (8) | |
H16A | 0.6867 | 0.7195 | 0.8488 | 0.087* | |
H16B | 0.6156 | 0.5918 | 0.8525 | 0.087* | |
H16C | 0.5348 | 0.7362 | 0.7899 | 0.087* | |
C18 | 0.9632 (5) | 0.4826 (4) | 0.6267 (2) | 0.0571 (8) | |
H18A | 1.0599 | 0.5131 | 0.6197 | 0.086* | |
H18B | 0.9109 | 0.4988 | 0.5705 | 0.086* | |
H18C | 0.9937 | 0.3830 | 0.6510 | 0.086* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Sn1 | 0.03691 (12) | 0.03071 (12) | 0.03857 (12) | −0.01388 (8) | −0.00577 (7) | 0.00074 (7) |
Cl1 | 0.0761 (5) | 0.0416 (4) | 0.0543 (4) | −0.0290 (4) | −0.0122 (4) | 0.0045 (3) |
Cl2 | 0.205 (3) | 0.308 (5) | 0.261 (4) | −0.114 (3) | 0.033 (3) | −0.135 (4) |
S1 | 0.0701 (5) | 0.0424 (4) | 0.0787 (6) | −0.0304 (4) | −0.0414 (5) | 0.0217 (4) |
S2 | 0.0623 (5) | 0.0368 (4) | 0.0704 (5) | −0.0253 (3) | −0.0331 (4) | 0.0147 (3) |
N1 | 0.0622 (17) | 0.0391 (13) | 0.0641 (17) | −0.0231 (12) | −0.0228 (13) | 0.0160 (12) |
N2 | 0.0518 (14) | 0.0345 (12) | 0.0505 (14) | −0.0215 (10) | −0.0126 (11) | 0.0076 (10) |
N3 | 0.0416 (12) | 0.0337 (11) | 0.0416 (12) | −0.0181 (9) | −0.0077 (9) | 0.0050 (9) |
N4 | 0.0406 (12) | 0.0382 (12) | 0.0385 (11) | −0.0183 (9) | −0.0091 (9) | 0.0042 (9) |
N5 | 0.0474 (13) | 0.0340 (11) | 0.0447 (13) | −0.0204 (10) | −0.0131 (10) | 0.0056 (9) |
N6 | 0.0541 (15) | 0.0373 (13) | 0.0561 (16) | −0.0253 (11) | −0.0194 (12) | 0.0104 (11) |
N7 | 0.0544 (15) | 0.0383 (13) | 0.0722 (18) | −0.0252 (12) | −0.0227 (13) | 0.0100 (12) |
C1 | 0.093 (3) | 0.051 (2) | 0.072 (2) | −0.037 (2) | −0.015 (2) | 0.0168 (18) |
C2 | 0.063 (2) | 0.0399 (16) | 0.065 (2) | −0.0241 (14) | −0.0110 (16) | 0.0065 (14) |
C3 | 0.0477 (15) | 0.0347 (14) | 0.0525 (16) | −0.0170 (12) | −0.0112 (13) | 0.0072 (12) |
C4 | 0.0450 (15) | 0.0393 (14) | 0.0455 (15) | −0.0226 (12) | −0.0079 (12) | 0.0032 (11) |
C5 | 0.067 (2) | 0.0533 (19) | 0.073 (2) | −0.0400 (17) | −0.0215 (18) | 0.0068 (16) |
C6 | 0.0443 (14) | 0.0437 (15) | 0.0396 (13) | −0.0232 (12) | −0.0075 (11) | 0.0031 (11) |
C7 | 0.062 (2) | 0.064 (2) | 0.0552 (18) | −0.0396 (17) | −0.0223 (15) | 0.0119 (16) |
C8 | 0.073 (2) | 0.075 (3) | 0.067 (2) | −0.041 (2) | −0.0408 (19) | 0.0243 (19) |
C9 | 0.067 (2) | 0.058 (2) | 0.060 (2) | −0.0325 (17) | −0.0310 (17) | 0.0221 (16) |
C10 | 0.0463 (15) | 0.0423 (15) | 0.0421 (14) | −0.0214 (12) | −0.0128 (12) | 0.0078 (11) |
C11 | 0.0499 (16) | 0.0373 (14) | 0.0444 (15) | −0.0194 (12) | −0.0133 (12) | 0.0082 (11) |
C12 | 0.083 (3) | 0.0475 (18) | 0.071 (2) | −0.0349 (18) | −0.039 (2) | 0.0261 (17) |
C13 | 0.0440 (14) | 0.0336 (13) | 0.0512 (16) | −0.0178 (11) | −0.0109 (12) | 0.0014 (11) |
C14 | 0.061 (2) | 0.055 (2) | 0.097 (3) | −0.0319 (17) | −0.036 (2) | 0.0093 (19) |
C15 | 0.071 (3) | 0.062 (2) | 0.135 (4) | −0.041 (2) | −0.026 (3) | −0.003 (3) |
C17 | 0.0559 (19) | 0.058 (2) | 0.067 (2) | −0.0243 (16) | 0.0121 (16) | −0.0187 (17) |
C18 | 0.061 (2) | 0.057 (2) | 0.0528 (18) | −0.0167 (16) | 0.0051 (15) | −0.0120 (15) |
Geometric parameters (Å, º) top
Sn1—C17 | 2.120 (3) | C4—C5 | 1.484 (4) |
Sn1—C18 | 2.121 (3) | C4—C6 | 1.477 (4) |
Sn1—N3 | 2.319 (2) | C5—H5A | 0.96 |
Sn1—N4 | 2.390 (2) | C5—H5B | 0.96 |
Sn1—N5 | 2.588 (2) | C5—H5C | 0.96 |
Sn1—S1 | 2.607 (1) | C6—C7 | 1.389 (4) |
Sn1—S2 | 2.810 (1) | C7—C8 | 1.379 (5) |
S1—C3 | 1.744 (3) | C7—H7 | 0.93 |
S2—C13 | 1.681 (3) | C8—C9 | 1.384 (5) |
N1—C3 | 1.345 (4) | C8—H8 | 0.93 |
N1—C2 | 1.450 (4) | C9—C10 | 1.385 (4) |
N1—H1N | 0.86 | C9—H9 | 0.93 |
N2—C3 | 1.307 (4) | C10—C11 | 1.479 (4) |
N2—N3 | 1.373 (3) | C11—C12 | 1.501 (4) |
N3—C4 | 1.292 (4) | C12—H12A | 0.96 |
N4—C6 | 1.345 (4) | C12—H12B | 0.96 |
N4—C10 | 1.349 (4) | C12—H12C | 0.96 |
N5—C11 | 1.288 (4) | C14—C15 | 1.493 (5) |
N5—N6 | 1.369 (3) | C14—H14A | 0.97 |
N6—C13 | 1.362 (4) | C14—H14B | 0.97 |
N7—C13 | 1.320 (4) | C15—H15A | 0.96 |
N7—C14 | 1.452 (4) | C15—H15B | 0.96 |
N7—H7N | 0.86 | C15—H15C | 0.96 |
C1—C2 | 1.509 (5) | C17—H16A | 0.96 |
C1—H1A | 0.96 | C17—H16B | 0.96 |
C1—H1B | 0.96 | C17—H16C | 0.96 |
C1—H1C | 0.96 | C18—H18A | 0.96 |
C2—H2A | 0.97 | C18—H18B | 0.96 |
C2—H2B | 0.97 | C18—H18C | 0.96 |
C17—Sn1—C18 | 167.5 (2) | C4—C5—H5A | 109.5 |
C17—Sn1—N3 | 93.9 (1) | C4—C5—H5B | 109.5 |
C17—Sn1—N4 | 86.9 (1) | H5A—C5—H5B | 109.5 |
C17—Sn1—N5 | 83.9 (1) | C4—C5—H5C | 109.5 |
C17—Sn1—S1 | 96.6 (1) | H5A—C5—H5C | 109.5 |
C17—Sn1—S2 | 86.1 (1) | H5B—C5—H5C | 109.5 |
C18—Sn1—N3 | 95.3 (1) | N4—C6—C7 | 121.5 (3) |
C18—Sn1—N4 | 88.5 (1) | N4—C6—C4 | 116.6 (2) |
C18—Sn1—N5 | 83.7 (1) | C7—C6—C4 | 121.8 (3) |
C18—Sn1—S1 | 94.0 (1) | C8—C7—C6 | 118.6 (3) |
C18—Sn1—S2 | 88.5 (1) | C8—C7—H7 | 120.7 |
N3—Sn1—N4 | 68.9 (1) | C6—C7—H7 | 120.7 |
N3—Sn1—N5 | 133.0 (1) | C9—C8—C7 | 119.9 (3) |
N3—Sn1—S1 | 74.7 (1) | C9—C8—H8 | 120.0 |
N3—Sn1—S2 | 158.5 (1) | C7—C8—H8 | 120.0 |
N4—Sn1—N5 | 64.1 (1) | C8—C9—C10 | 118.9 (3) |
N4—Sn1—S1 | 143.7 (1) | C8—C9—H9 | 120.6 |
N4—Sn1—S2 | 132.4 (1) | C10—C9—H9 | 120.6 |
N5—Sn1—S1 | 152.2 (1) | N4—C10—C9 | 121.2 (3) |
N5—Sn1—S2 | 68.4 (1) | N4—C10—C11 | 116.9 (2) |
S1—Sn1—S2 | 83.9 (1) | C9—C10—C11 | 121.8 (3) |
C3—S1—Sn1 | 97.22 (10) | N5—C11—C10 | 115.6 (2) |
C13—S2—Sn1 | 103.40 (10) | N5—C11—C12 | 124.6 (3) |
C3—N1—C2 | 122.7 (3) | C10—C11—C12 | 119.9 (3) |
C3—N1—H1N | 118.6 | C11—C12—H12A | 109.5 |
C2—N1—H1N | 118.6 | C11—C12—H12B | 109.5 |
C3—N2—N3 | 115.9 (2) | H12A—C12—H12B | 109.5 |
C4—N3—N2 | 115.5 (2) | C11—C12—H12C | 109.5 |
C4—N3—Sn1 | 120.92 (18) | H12A—C12—H12C | 109.5 |
N2—N3—Sn1 | 123.52 (17) | H12B—C12—H12C | 109.5 |
C6—N4—C10 | 119.7 (2) | N7—C13—N6 | 113.2 (3) |
C6—N4—Sn1 | 116.54 (18) | N7—C13—S2 | 121.6 (2) |
C10—N4—Sn1 | 123.73 (18) | N6—C13—S2 | 125.2 (2) |
C11—N5—N6 | 118.2 (2) | N7—C14—C15 | 110.6 (3) |
C11—N5—Sn1 | 119.62 (19) | N7—C14—H14A | 109.5 |
N6—N5—Sn1 | 122.15 (17) | C15—C14—H14A | 109.5 |
C13—N6—N5 | 120.9 (2) | N7—C14—H14B | 109.5 |
C13—N7—C14 | 124.1 (3) | C15—C14—H14B | 109.5 |
C13—N7—H7N | 118.0 | H14A—C14—H14B | 108.1 |
C14—N7—H7N | 118.0 | C14—C15—H15A | 109.5 |
C2—C1—H1A | 109.5 | C14—C15—H15B | 109.5 |
C2—C1—H1B | 109.5 | H15A—C15—H15B | 109.5 |
H1A—C1—H1B | 109.5 | C14—C15—H15C | 109.5 |
C2—C1—H1C | 109.5 | H15A—C15—H15C | 109.5 |
H1A—C1—H1C | 109.5 | H15B—C15—H15C | 109.5 |
H1B—C1—H1C | 109.5 | Sn1—C17—H16A | 109.5 |
N1—C2—C1 | 110.6 (3) | Sn1—C17—H16B | 109.5 |
N1—C2—H2A | 109.5 | H16A—C17—H16B | 109.5 |
C1—C2—H2A | 109.5 | Sn1—C17—H16C | 109.5 |
N1—C2—H2B | 109.5 | H16A—C17—H16C | 109.5 |
C1—C2—H2B | 109.5 | H16B—C17—H16C | 109.5 |
H2A—C2—H2B | 108.1 | Sn1—C18—H18A | 109.5 |
N2—C3—N1 | 114.9 (3) | Sn1—C18—H18B | 109.5 |
N2—C3—S1 | 128.6 (2) | H18A—C18—H18B | 109.5 |
N1—C3—S1 | 116.5 (2) | Sn1—C18—H18C | 109.5 |
N3—C4—C5 | 122.6 (3) | H18A—C18—H18C | 109.5 |
N3—C4—C6 | 116.9 (2) | H18B—C18—H18C | 109.5 |
C5—C4—C6 | 120.5 (3) | ||
C18—Sn1—S1—C3 | −94.98 (16) | S1—Sn1—N5—N6 | −3.2 (3) |
C17—Sn1—S1—C3 | 91.64 (16) | S2—Sn1—N5—N6 | 1.0 (2) |
N3—Sn1—S1—C3 | −0.62 (14) | C11—N5—N6—C13 | 177.8 (3) |
N4—Sn1—S1—C3 | −2.05 (17) | Sn1—N5—N6—C13 | −0.6 (4) |
N5—Sn1—S1—C3 | −178.98 (17) | C3—N1—C2—C1 | −178.3 (4) |
S2—Sn1—S1—C3 | 177.01 (13) | N3—N2—C3—N1 | −179.0 (3) |
C18—Sn1—S2—C13 | 82.74 (16) | N3—N2—C3—S1 | 0.7 (5) |
C17—Sn1—S2—C13 | −86.02 (17) | C2—N1—C3—N2 | −1.3 (5) |
N3—Sn1—S2—C13 | −176.8 (2) | C2—N1—C3—S1 | 179.0 (3) |
N4—Sn1—S2—C13 | −3.83 (15) | Sn1—S1—C3—N2 | 0.2 (3) |
N5—Sn1—S2—C13 | −1.08 (14) | Sn1—S1—C3—N1 | 179.9 (3) |
S1—Sn1—S2—C13 | 176.92 (13) | N2—N3—C4—C5 | 1.3 (5) |
C3—N2—N3—C4 | −178.7 (3) | Sn1—N3—C4—C5 | −175.9 (3) |
C3—N2—N3—Sn1 | −1.5 (4) | N2—N3—C4—C6 | −179.0 (3) |
C18—Sn1—N3—C4 | −89.0 (3) | Sn1—N3—C4—C6 | 3.7 (4) |
C17—Sn1—N3—C4 | 82.5 (3) | C10—N4—C6—C7 | 0.6 (5) |
N4—Sn1—N3—C4 | −2.6 (2) | Sn1—N4—C6—C7 | −179.1 (3) |
N5—Sn1—N3—C4 | −2.8 (3) | C10—N4—C6—C4 | −180.0 (3) |
S1—Sn1—N3—C4 | 178.3 (3) | Sn1—N4—C6—C4 | 0.3 (4) |
S2—Sn1—N3—C4 | 171.83 (18) | N3—C4—C6—N4 | −2.6 (4) |
C18—Sn1—N3—N2 | 93.9 (3) | C5—C4—C6—N4 | 177.1 (3) |
C17—Sn1—N3—N2 | −94.5 (3) | N3—C4—C6—C7 | 176.8 (3) |
N4—Sn1—N3—N2 | −179.7 (3) | C5—C4—C6—C7 | −3.5 (5) |
N5—Sn1—N3—N2 | −179.8 (2) | N4—C6—C7—C8 | 2.2 (6) |
S1—Sn1—N3—N2 | 1.2 (2) | C4—C6—C7—C8 | −177.2 (4) |
S2—Sn1—N3—N2 | −5.2 (4) | C6—C7—C8—C9 | −3.0 (7) |
C18—Sn1—N4—C6 | 97.3 (2) | C7—C8—C9—C10 | 1.1 (7) |
C17—Sn1—N4—C6 | −94.3 (2) | C6—N4—C10—C9 | −2.6 (5) |
N3—Sn1—N4—C6 | 1.1 (2) | Sn1—N4—C10—C9 | 177.2 (3) |
N5—Sn1—N4—C6 | −179.0 (2) | C6—N4—C10—C11 | 177.8 (3) |
S1—Sn1—N4—C6 | 2.5 (3) | Sn1—N4—C10—C11 | −2.5 (4) |
S2—Sn1—N4—C6 | −176.20 (18) | C8—C9—C10—N4 | 1.7 (6) |
C18—Sn1—N4—C10 | −82.5 (3) | C8—C9—C10—C11 | −178.6 (4) |
C17—Sn1—N4—C10 | 85.9 (3) | N6—N5—C11—C10 | 179.9 (3) |
N3—Sn1—N4—C10 | −178.7 (3) | Sn1—N5—C11—C10 | −1.6 (4) |
N5—Sn1—N4—C10 | 1.2 (2) | N6—N5—C11—C12 | −1.3 (5) |
S1—Sn1—N4—C10 | −177.2 (2) | Sn1—N5—C11—C12 | 177.2 (3) |
S2—Sn1—N4—C10 | 4.1 (3) | N4—C10—C11—N5 | 2.6 (5) |
C18—Sn1—N5—C11 | 91.8 (3) | C9—C10—C11—N5 | −177.0 (4) |
C17—Sn1—N5—C11 | −89.2 (3) | N4—C10—C11—C12 | −176.3 (3) |
N3—Sn1—N5—C11 | 0.5 (3) | C9—C10—C11—C12 | 4.1 (5) |
N4—Sn1—N5—C11 | 0.3 (2) | C14—N7—C13—N6 | 178.0 (4) |
S1—Sn1—N5—C11 | 178.32 (19) | C14—N7—C13—S2 | −2.2 (6) |
S2—Sn1—N5—C11 | −177.4 (3) | N5—N6—C13—N7 | 179.0 (3) |
C18—Sn1—N5—N6 | −89.8 (3) | N5—N6—C13—S2 | −0.8 (5) |
C17—Sn1—N5—N6 | 89.3 (3) | Sn1—S2—C13—N7 | −178.2 (3) |
N3—Sn1—N5—N6 | 178.9 (2) | Sn1—S2—C13—N6 | 1.5 (3) |
N4—Sn1—N5—N6 | 178.8 (3) | C13—N7—C14—C15 | −176.6 (4) |