Key indicators
- Single-crystal X-ray study
- T = 90 K
- Mean
(C-C) = 0.008 Å
- H-atom completeness 78%
- Disorder in solvent or counterion
- R factor = 0.051
- wR factor = 0.167
- Data-to-parameter ratio = 18.9
checkCIF/PLATON results
No syntax errors found
Alert level A
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... O16
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... O17
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... O18
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... O19
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_A Short Inter D...A Contact O24A .. O25B .. 2.48 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_A Short Inter D...A Contact O22A .. O22A .. 2.25 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT431_ALERT_2_A Short Inter HL..A Contact Cl2 .. O25D .. 2.75 Ang.
| Author Response: disorder in the hydrate sites yields a short contact
|
Alert level B
PLAT430_ALERT_2_B Short Inter D...A Contact O2 .. O24A .. 2.82 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O8 .. O21A .. 2.77 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O8 .. O21B .. 2.80 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O15 .. O23A .. 2.76 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O15 .. O23B .. 2.78 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O16 .. O22B .. 2.77 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O17 .. O27 .. 2.72 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O17 .. O18 .. 2.76 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O17 .. O19 .. 2.80 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O18 .. O23B .. 2.72 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O18 .. O23A .. 2.78 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O19 .. O28 .. 2.75 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O20 .. O31 .. 2.77 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O21A .. O31 .. 2.54 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O24A .. O25B .. 2.71 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_B Short Inter D...A Contact O25B .. O25B .. 2.56 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT431_ALERT_2_B Short Inter HL..A Contact Cl2 .. O25C .. 2.93 Ang.
| Author Response: disorder in the hydrate sites yields a short contact
|
PLAT910_ALERT_3_B Missing # of FCF Reflections Below Th(Min) ..... 13
Alert level C
CHEMW03_ALERT_2_C The ratio of given/expected molecular weight as
calculated from the _atom_site* data lies outside
the range 0.99 <> 1.01
From the CIF: _cell_formula_units_Z 1
From the CIF: _chemical_formula_weight 3099.42
TEST: Calculate formula weight from _atom_site_*
atom mass num sum
C 12.01 62.00 744.68
H 1.01 162.00 163.30
N 14.01 24.00 336.17
O 16.00 54.00 863.95
Mn 54.94 12.00 659.26
Cl 35.45 8.00 283.62
Calculated formula weight 3050.97
PLAT202_ALERT_3_C Isotropic non-H Atoms in Anion/Solvent ......... 3
PLAT213_ALERT_2_C Atom C31 has ADP max/min Ratio ..... 3.20 prola
PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.88 Ratio
PLAT222_ALERT_3_C Large Non-Solvent H Uiso(max)/Uso(min) ... 4.11 Rati
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor .... 2.15
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... >O21A
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... >O23A
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... >O24A
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O21B
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O22A
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O22B
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O22C
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O23B
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O24B
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O25A
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O25B
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O26A
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O26B
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O27
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O28
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O29
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O30
PLAT311_ALERT_2_C Isolated Disordered Oxygen Atom (No H's ?) ..... <O31
PLAT341_ALERT_3_C Low Bond Precision on C-C Bonds (x 1000) Ang .. 8
PLAT420_ALERT_2_C D-H Without Acceptor N12 - H12 ... ?
PLAT430_ALERT_2_C Short Inter D...A Contact O16 .. O22A .. 2.87 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_C Short Inter D...A Contact O23A .. O30 .. 2.89 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT430_ALERT_2_C Short Inter D...A Contact O24A .. O25A .. 2.85 Ang.
| Author Response: hydrogen atoms were not located for this hydrate group
|
PLAT431_ALERT_2_C Short Inter HL..A Contact Cl1 .. O16 .. 3.15 Ang.
| Author Response: disorder in the hydrate sites yields a short contact
|
PLAT431_ALERT_2_C Short Inter HL..A Contact Cl1 .. O19 .. 3.15 Ang.
| Author Response: disorder in the hydrate sites yields a short contact
|
PLAT431_ALERT_2_C Short Inter HL..A Contact Cl2 .. O16 .. 3.08 Ang.
| Author Response: disorder in the hydrate sites yields a short contact
|
PLAT911_ALERT_3_C Missing # FCF Refl Between THmin & STh/L= 0.600 9
PLAT041_ALERT_1_C Calc. and Reported SumFormula Strings Differ ?
PLAT042_ALERT_1_C Calc. and Reported MoietyFormula Strings Differ ?
PLAT043_ALERT_1_C Check Reported Molecular Weight ................ 3099.42
PLAT044_ALERT_1_C Calculated and Reported Dx Differ .............. ?
PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)... ?
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 2
O2
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 9
O
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 10
O
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 12
O
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 16
Cl
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 17
Cl
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 28
O
PLAT912_ALERT_4_C Missing # of FCF Reflections Above STh/L= 0.600 32
Alert level G
FORMU01_ALERT_2_G There is a discrepancy between the atom counts in the
_chemical_formula_sum and the formula from the _atom_site* data.
Atom count from _chemical_formula_sum:C62 H210 Cl8 Mn12 N24 O54
Atom count from the _atom_site data: C62 H162 Cl8 Mn12 N24 O54
CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected.
CELLZ01_ALERT_1_G WARNING: H atoms missing from atom site list. Is this intentional?
From the CIF: _cell_formula_units_Z 1
From the CIF: _chemical_formula_sum C62 H210 Cl8 Mn12 N24 O54
TEST: Compare cell contents of formula and atom_site data
atom Z*formula cif sites diff
C 62.00 62.00 0.00
H 210.00 162.00 48.00
Cl 8.00 8.00 0.00
Mn 12.00 12.00 0.00
N 24.00 24.00 0.00
O 54.00 54.00 0.00
PLAT860_ALERT_3_G Note: Number of Least-Squares Restraints ....... 12
PLAT302_ALERT_4_G Note: Anion/Solvent Disorder ................... 31.00 Perc.
PLAT764_ALERT_4_G Overcomplete CIF Bond List Detected (Rep/Expd) . 1.17 Ratio
PLAT793_ALERT_4_G The Model has Chirality at N1 (Verify) .... S
PLAT793_ALERT_4_G The Model has Chirality at N2 (Verify) .... S
PLAT793_ALERT_4_G The Model has Chirality at N3 (Verify) .... S
PLAT793_ALERT_4_G The Model has Chirality at N4 (Verify) .... S
PLAT793_ALERT_4_G The Model has Chirality at N5 (Verify) .... S
PLAT793_ALERT_4_G The Model has Chirality at N6 (Verify) .... S
PLAT793_ALERT_4_G The Model has Chirality at N7 (Verify) .... S
PLAT793_ALERT_4_G The Model has Chirality at N8 (Verify) .... S
PLAT793_ALERT_4_G The Model has Chirality at N9 (Verify) .... R
PLAT793_ALERT_4_G The Model has Chirality at N10 (Verify) .... R
PLAT793_ALERT_4_G The Model has Chirality at N11 (Verify) .... R
PLAT793_ALERT_4_G The Model has Chirality at N12 (Verify) .... R
PLAT811_ALERT_5_G No ADDSYM Analysis: Too Many Excluded Atoms .... !
7 ALERT level A = In general: serious problem
18 ALERT level B = Potentially serious problem
46 ALERT level C = Check and explain
19 ALERT level G = General alerts; check
7 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
54 ALERT type 2 Indicator that the structure model may be wrong or deficient
6 ALERT type 3 Indicator that the structure quality may be low
22 ALERT type 4 Improvement, methodology, query or suggestion
1 ALERT type 5 Informative message, check
To a mixture of MnCl2.4H2O (136 mg, 687 mmol), cyclam
(1,4,8,11-tetraazacyclotetradecane) (144 mg, 722 mmol), and sodium
tetraphenylborate (289 mg, 844 mmol) in a 200 ml round bottom flask was added
150 ml of acetonitrile. The reaction was continuously stirred for 5 days over
which time it turned from pale yellow to dark brown to dark olive green and a
solid material was formed. The solid was filtered and redissolved in a 1:2
mixture of H2O:acetonitrile and placed in upcapped 5 mm diameter tubes in
the refrigerator. After 2 weeks, black plates formed. The crystal selected for
data collection was cut from a large plate.
Hydrogen atoms on water O and aza-N atoms were located in a difference map and
subsequently refined with Uiso = 1.2Ueq(N or O) and distance
restraints of 0.84 (1) Å for O—H, 0.93 Å for N—H and H···H of 1.32 (3) Å for water. The C—H geometry was determined by idealized geometry and a
C—H distance of 0.99 Å. The C—H and N—H H atoms were refined as riding
on the parent atoms. There are seven different positions for the four chloride
ions in the asymmetric unit. Of these, Cl1 and Cl2 are included at full
occupancy while Cl3, Cl4, and Cl6 are at half occupancy and Cl5A/Cl5B
respresent a split position of occupancy 0.40/0.10 occupancy. These disordered
chlorides were selected based on longer hydrogen bonding distances and
reasonable distribution within the structure. Four hydrate water O atoms, O16,
O17, O18, and O19, were in sites of full occupancy and were refined with
anisotropic thermal parameters. The remainder were refined with isotropic
thermal parameters and fixed occupancies that were determined by an ad
hoc method. Most of the hydrogen atoms were not reliably located for the
hydrate molecules and none were included in the structure factor calculation.
The final difference map contains a number of peaks in the region of the
chloride ions and solvate water molecules that are possibly additional minor
water sites or part of disordered chloride sites.
Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXL97 (Sheldrick, 2008).
hexaaquadi-µ
3-carbonato-hexacyclamhexa-µ
2-hydroxido-dodeca-µ
2-oxido-
hexamanganese(IV)hexamanganese(III) octachloride tetracosahydrate
top
Crystal data top
[Mn12(CO3)2O12(OH)6(C10H24N4)6(H2O)6]Cl8·24H2O | Z = 1 |
Mr = 3099.42 | F(000) = 1618 |
Triclinic, P1 | Dx = 1.586 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 15.2421 (15) Å | Cell parameters from 9868 reflections |
b = 15.5037 (15) Å | θ = 2.6–29.4° |
c = 17.1306 (17) Å | µ = 1.38 mm−1 |
α = 90.707 (6)° | T = 90 K |
β = 114.523 (7)° | Parallelepiped, black |
γ = 115.128 (7)° | 0.43 × 0.18 × 0.14 mm |
V = 3245.8 (6) Å3 | |
Data collection top
Bruker SMART APEXII diffractometer | 14856 independent reflections |
Radiation source: fine-focus sealed tube | 10648 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.042 |
Detector resolution: 8.3 pixels mm-1 | θmax = 27.5°, θmin = 2.7° |
ω scans | h = −19→19 |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | k = −20→20 |
Tmin = 0.589, Tmax = 0.831 | l = −22→22 |
40135 measured reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.051 | Hydrogen site location: difference Fourier map |
wR(F2) = 0.167 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.14 | w = 1/[σ2(Fo2) + (0.0959P)2] where P = (Fo2 + 2Fc2)/3 |
14856 reflections | (Δ/σ)max = 0.006 |
787 parameters | Δρmax = 1.40 e Å−3 |
12 restraints | Δρmin = −1.14 e Å−3 |
Crystal data top
[Mn12(CO3)2O12(OH)6(C10H24N4)6(H2O)6]Cl8·24H2O | γ = 115.128 (7)° |
Mr = 3099.42 | V = 3245.8 (6) Å3 |
Triclinic, P1 | Z = 1 |
a = 15.2421 (15) Å | Mo Kα radiation |
b = 15.5037 (15) Å | µ = 1.38 mm−1 |
c = 17.1306 (17) Å | T = 90 K |
α = 90.707 (6)° | 0.43 × 0.18 × 0.14 mm |
β = 114.523 (7)° | |
Data collection top
Bruker SMART APEXII diffractometer | 14856 independent reflections |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | 10648 reflections with I > 2σ(I) |
Tmin = 0.589, Tmax = 0.831 | Rint = 0.042 |
40135 measured reflections | |
Refinement top
R[F2 > 2σ(F2)] = 0.051 | 12 restraints |
wR(F2) = 0.167 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.14 | Δρmax = 1.40 e Å−3 |
14856 reflections | Δρmin = −1.14 e Å−3 |
787 parameters | |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Mn1 | 0.61048 (5) | 0.82243 (4) | 0.74029 (4) | 0.02005 (14) | |
Mn2 | 0.48190 (5) | 0.66143 (4) | 0.60353 (4) | 0.01677 (13) | |
Mn3 | 0.68442 (4) | 0.74479 (4) | 0.31273 (4) | 0.01583 (13) | |
Mn4 | 0.56057 (4) | 0.57784 (4) | 0.34706 (3) | 0.01455 (13) | |
Mn5 | 0.10236 (4) | 0.49328 (4) | 0.28193 (4) | 0.01948 (14) | |
Mn6 | 0.32112 (4) | 0.55349 (4) | 0.36584 (3) | 0.01522 (13) | |
O1 | 0.5427 (2) | 0.69222 (18) | 0.72622 (16) | 0.0195 (5) | |
O2 | 0.5479 (2) | 0.79948 (18) | 0.62323 (17) | 0.0235 (6) | |
O3 | 0.6380 (2) | 0.65305 (17) | 0.62194 (16) | 0.0174 (5) | |
C31 | 0.6579 (3) | 0.6311 (2) | 0.5602 (2) | 0.0160 (7) | |
O4 | 0.3075 (2) | 0.6456 (2) | 0.55926 (19) | 0.0259 (6) | |
H4D | 0.279 (3) | 0.631 (3) | 0.5055 (13) | 0.031* | |
H4E | 0.310 (4) | 0.696 (2) | 0.578 (3) | 0.031* | |
O5 | 0.4100 (2) | 0.52276 (17) | 0.59896 (16) | 0.0156 (5) | |
H5D | 0.365 (3) | 0.495 (3) | 0.5456 (14) | 0.019* | |
O6 | 0.4395 (2) | 0.64189 (17) | 0.47837 (16) | 0.0157 (5) | |
H6D | 0.500 (2) | 0.658 (3) | 0.481 (3) | 0.019* | |
O7 | 0.5504 (2) | 0.68689 (17) | 0.30572 (16) | 0.0171 (5) | |
O8 | 0.6949 (2) | 0.63902 (17) | 0.34421 (17) | 0.0180 (5) | |
O9 | 0.4763 (2) | 0.46920 (19) | 0.21367 (17) | 0.0217 (6) | |
H9D | 0.433 (3) | 0.457 (3) | 0.1600 (14) | 0.026* | |
H9E | 0.457 (3) | 0.4095 (17) | 0.221 (3) | 0.026* | |
O10 | 0.62797 (19) | 0.66251 (17) | 0.48852 (16) | 0.0161 (5) | |
O11 | 0.41448 (19) | 0.52118 (17) | 0.33573 (16) | 0.0153 (5) | |
H11D | 0.395 (3) | 0.4645 (17) | 0.344 (3) | 0.018* | |
O12 | 0.3795 (2) | 0.6940 (2) | 0.31251 (18) | 0.0225 (6) | |
H12C | 0.431 (3) | 0.695 (3) | 0.306 (3) | 0.027* | |
H12D | 0.337 (3) | 0.700 (3) | 0.2668 (19) | 0.027* | |
O13 | 0.2941 (2) | 0.42210 (17) | 0.43119 (16) | 0.0168 (5) | |
O14 | 0.2164 (2) | 0.56917 (18) | 0.38531 (17) | 0.0207 (6) | |
O15 | 0.1984 (2) | 0.47938 (18) | 0.25634 (16) | 0.0186 (5) | |
N1 | 0.4899 (3) | 0.8385 (2) | 0.7517 (3) | 0.0329 (9) | |
H1 | 0.4326 | 0.8173 | 0.6946 | 0.039* | |
N2 | 0.6871 (3) | 0.8367 (2) | 0.8772 (2) | 0.0299 (8) | |
H2 | 0.7216 | 0.9024 | 0.9049 | 0.036* | |
N3 | 0.7501 (3) | 0.8279 (2) | 0.7488 (2) | 0.0277 (8) | |
H3 | 0.7309 | 0.7636 | 0.7277 | 0.033* | |
N4 | 0.6771 (3) | 0.9739 (2) | 0.7492 (2) | 0.0308 (8) | |
H4 | 0.7301 | 1.0060 | 0.8071 | 0.037* | |
N5 | 0.6293 (3) | 0.6958 (2) | 0.1816 (2) | 0.0220 (7) | |
H5 | 0.6090 | 0.6294 | 0.1742 | 0.026* | |
N6 | 0.6648 (3) | 0.8692 (2) | 0.2847 (2) | 0.0198 (7) | |
H6 | 0.7222 | 0.9115 | 0.2747 | 0.024* | |
N7 | 0.7583 (3) | 0.8187 (2) | 0.4409 (2) | 0.0197 (7) | |
H7 | 0.7066 | 0.7878 | 0.4604 | 0.024* | |
N8 | 0.8384 (3) | 0.7991 (2) | 0.3170 (2) | 0.0222 (7) | |
H8 | 0.8620 | 0.8644 | 0.3140 | 0.027* | |
N9 | 0.0652 (3) | 0.3703 (2) | 0.3302 (2) | 0.0280 (8) | |
H9 | 0.1263 | 0.3867 | 0.3841 | 0.034* | |
N10 | −0.0219 (3) | 0.4080 (3) | 0.1564 (2) | 0.0276 (8) | |
H10 | −0.0890 | 0.3919 | 0.1544 | 0.033* | |
N11 | 0.1099 (3) | 0.6064 (3) | 0.2213 (3) | 0.0349 (9) | |
H11 | 0.1700 | 0.6246 | 0.2111 | 0.042* | |
N12 | −0.0018 (3) | 0.5104 (3) | 0.3234 (3) | 0.0381 (9) | |
H12 | −0.0707 | 0.4860 | 0.2751 | 0.046* | |
C1 | 0.4406 (4) | 0.7784 (4) | 0.8054 (3) | 0.0433 (12) | |
H1A | 0.4079 | 0.7080 | 0.7793 | 0.052* | |
H1B | 0.3815 | 0.7913 | 0.8033 | 0.052* | |
C2 | 0.5257 (5) | 0.8021 (4) | 0.9006 (4) | 0.0575 (16) | |
H2A | 0.5589 | 0.8729 | 0.9252 | 0.069* | |
H2B | 0.4879 | 0.7665 | 0.9342 | 0.069* | |
C3 | 0.6154 (4) | 0.7779 (4) | 0.9158 (3) | 0.0444 (13) | |
H3A | 0.5829 | 0.7076 | 0.8898 | 0.053* | |
H3B | 0.6608 | 0.7894 | 0.9801 | 0.053* | |
C4 | 0.7723 (4) | 0.8054 (3) | 0.8941 (3) | 0.0413 (12) | |
H4A | 0.7376 | 0.7333 | 0.8752 | 0.050* | |
H4B | 0.8241 | 0.8252 | 0.9579 | 0.050* | |
C5 | 0.8319 (4) | 0.8533 (4) | 0.8431 (3) | 0.0423 (12) | |
H5A | 0.8724 | 0.9252 | 0.8659 | 0.051* | |
H5B | 0.8852 | 0.8299 | 0.8494 | 0.051* | |
C6 | 0.7960 (4) | 0.8854 (3) | 0.6931 (3) | 0.0396 (12) | |
H6A | 0.7425 | 0.8548 | 0.6302 | 0.048* | |
H6B | 0.8635 | 0.8823 | 0.7036 | 0.048* | |
C7 | 0.8227 (4) | 0.9928 (3) | 0.7118 (3) | 0.0455 (14) | |
H7A | 0.8752 | 1.0225 | 0.7750 | 0.055* | |
H7B | 0.8593 | 1.0275 | 0.6772 | 0.055* | |
C8 | 0.7266 (5) | 1.0086 (3) | 0.6908 (3) | 0.0465 (14) | |
H8A | 0.7496 | 1.0794 | 0.6956 | 0.056* | |
H8B | 0.6709 | 0.9741 | 0.6291 | 0.056* | |
C9 | 0.5843 (4) | 0.9973 (3) | 0.7282 (4) | 0.0476 (14) | |
H9A | 0.6131 | 1.0687 | 0.7463 | 0.057* | |
H9B | 0.5341 | 0.9757 | 0.6640 | 0.057* | |
C10 | 0.5250 (4) | 0.9442 (4) | 0.7779 (4) | 0.0535 (15) | |
H10A | 0.5739 | 0.9690 | 0.8421 | 0.064* | |
H10B | 0.4606 | 0.9543 | 0.7633 | 0.064* | |
C11 | 0.5300 (3) | 0.7012 (3) | 0.1180 (3) | 0.0270 (9) | |
H11A | 0.4682 | 0.6607 | 0.1297 | 0.032* | |
H11B | 0.5108 | 0.6727 | 0.0575 | 0.032* | |
C12 | 0.5439 (3) | 0.8035 (3) | 0.1223 (3) | 0.0275 (9) | |
H12A | 0.4782 | 0.8016 | 0.0737 | 0.033* | |
H12B | 0.6075 | 0.8445 | 0.1128 | 0.033* | |
C13 | 0.5608 (3) | 0.8510 (3) | 0.2084 (3) | 0.0244 (8) | |
H13A | 0.5596 | 0.9141 | 0.2030 | 0.029* | |
H13B | 0.4991 | 0.8084 | 0.2195 | 0.029* | |
C14 | 0.6760 (3) | 0.9175 (3) | 0.3670 (3) | 0.0234 (8) | |
H14A | 0.6088 | 0.8804 | 0.3730 | 0.028* | |
H14B | 0.6870 | 0.9849 | 0.3645 | 0.028* | |
C15 | 0.7724 (3) | 0.9199 (3) | 0.4441 (3) | 0.0248 (9) | |
H15A | 0.8407 | 0.9634 | 0.4417 | 0.030* | |
H15B | 0.7774 | 0.9457 | 0.4998 | 0.030* | |
C16 | 0.8569 (3) | 0.8134 (3) | 0.5043 (3) | 0.0246 (8) | |
H16A | 0.8366 | 0.7444 | 0.5077 | 0.030* | |
H16B | 0.8832 | 0.8512 | 0.5634 | 0.030* | |
C17 | 0.9504 (3) | 0.8531 (3) | 0.4794 (3) | 0.0266 (9) | |
H17A | 0.9682 | 0.9212 | 0.4734 | 0.032* | |
H17B | 1.0160 | 0.8550 | 0.5280 | 0.032* | |
C18 | 0.9251 (3) | 0.7943 (3) | 0.3954 (3) | 0.0247 (8) | |
H18A | 0.9924 | 0.8187 | 0.3886 | 0.030* | |
H18B | 0.9020 | 0.7251 | 0.3994 | 0.030* | |
C19 | 0.8205 (3) | 0.7441 (3) | 0.2352 (3) | 0.0272 (9) | |
H19A | 0.8085 | 0.6770 | 0.2407 | 0.033* | |
H19B | 0.8856 | 0.7774 | 0.2255 | 0.033* | |
C20 | 0.7220 (3) | 0.7402 (3) | 0.1592 (3) | 0.0296 (9) | |
H20A | 0.7044 | 0.6997 | 0.1044 | 0.035* | |
H20B | 0.7360 | 0.8068 | 0.1503 | 0.035* | |
C21 | 0.0490 (4) | 0.2806 (3) | 0.2803 (3) | 0.0384 (11) | |
H21A | 0.0326 | 0.2275 | 0.3118 | 0.046* | |
H21B | 0.1180 | 0.2943 | 0.2790 | 0.046* | |
C22 | −0.0434 (4) | 0.2451 (3) | 0.1854 (3) | 0.0376 (11) | |
H22A | −0.0541 | 0.1822 | 0.1587 | 0.045* | |
H22B | −0.1121 | 0.2327 | 0.1867 | 0.045* | |
C23 | −0.0229 (4) | 0.3161 (3) | 0.1279 (3) | 0.0334 (10) | |
H23A | 0.0483 | 0.3325 | 0.1298 | 0.040* | |
H23B | −0.0806 | 0.2846 | 0.0662 | 0.040* | |
C24 | −0.0075 (4) | 0.4717 (4) | 0.0938 (3) | 0.0409 (12) | |
H24A | −0.0740 | 0.4424 | 0.0360 | 0.049* | |
H24B | 0.0553 | 0.4785 | 0.0852 | 0.049* | |
C25 | 0.0127 (4) | 0.5694 (4) | 0.1313 (4) | 0.0518 (14) | |
H25A | −0.0522 | 0.5636 | 0.1357 | 0.062* | |
H25B | 0.0279 | 0.6151 | 0.0932 | 0.062* | |
C26 | 0.1297 (4) | 0.6964 (4) | 0.2709 (4) | 0.0506 (14) | |
H26A | 0.1339 | 0.7455 | 0.2343 | 0.061* | |
H26B | 0.2013 | 0.7233 | 0.3245 | 0.061* | |
C27 | 0.0424 (5) | 0.6807 (4) | 0.2976 (5) | 0.0619 (17) | |
H27A | −0.0293 | 0.6516 | 0.2439 | 0.074* | |
H27B | 0.0563 | 0.7453 | 0.3241 | 0.074* | |
C28 | 0.0351 (4) | 0.6150 (4) | 0.3628 (4) | 0.0562 (16) | |
H28A | 0.1078 | 0.6414 | 0.4151 | 0.067* | |
H28B | −0.0169 | 0.6162 | 0.3826 | 0.067* | |
C29 | −0.0100 (4) | 0.4490 (4) | 0.3874 (3) | 0.0488 (14) | |
H29A | −0.0731 | 0.4392 | 0.3969 | 0.059* | |
H29B | 0.0573 | 0.4817 | 0.4446 | 0.059* | |
C30 | −0.0244 (4) | 0.3517 (4) | 0.3525 (3) | 0.0454 (13) | |
H30A | −0.0218 | 0.3122 | 0.3976 | 0.055* | |
H30B | −0.0962 | 0.3151 | 0.2994 | 0.055* | |
Cl1 | 0.91039 (8) | 1.01855 (7) | 0.29167 (7) | 0.0268 (2) | |
Cl2 | 0.24589 (13) | 0.79935 (12) | 0.60522 (13) | 0.0769 (6) | |
Cl3 | 0.86737 (18) | 1.07361 (15) | 0.96304 (14) | 0.0367 (5) | 0.50 |
Cl4 | 0.2516 (2) | 0.7178 (3) | 0.1287 (2) | 0.0673 (10) | 0.50 |
Cl5A | −0.2407 (3) | 0.4394 (3) | 0.1490 (3) | 0.0730 (12) | 0.40 |
Cl5B | −0.2790 (9) | 0.2686 (11) | 0.0485 (8) | 0.045 (3) | 0.10 |
Cl6 | 0.5772 (2) | 0.49181 (16) | 0.08903 (17) | 0.0465 (6) | 0.50 |
O16 | 0.2661 (3) | 0.9080 (3) | 0.7683 (3) | 0.0518 (10) | |
O17 | 1.0355 (3) | 1.1982 (3) | 0.8871 (2) | 0.0498 (9) | |
O18 | −0.2086 (3) | 0.6154 (3) | 0.0340 (2) | 0.0507 (9) | |
O19 | 0.8974 (3) | 0.9445 (3) | 0.1130 (3) | 0.0585 (10) | |
O20 | −0.2526 (7) | 0.3240 (7) | 0.1109 (6) | 0.068 (2)* | 0.50 |
O21A | 0.2119 (5) | 0.4846 (5) | 0.6239 (4) | 0.0420 (15)* | 0.55 |
O21B | 0.1753 (6) | 0.4493 (6) | 0.5731 (5) | 0.0388 (17)* | 0.45 |
O22A | 0.4103 (9) | 0.9540 (8) | 0.9533 (7) | 0.061 (3)* | 0.45 |
O22B | 0.3601 (10) | 0.9330 (9) | 0.9500 (8) | 0.049 (3)* | 0.35 |
O22C | 0.3772 (14) | 0.8915 (13) | 0.9507 (11) | 0.037 (4)* | 0.20 |
O23A | 0.2723 (4) | 0.4768 (4) | 0.1348 (4) | 0.0357 (12)* | 0.60 |
O23B | 0.2584 (7) | 0.4259 (7) | 0.1386 (5) | 0.0369 (19)* | 0.40 |
O24A | 0.4901 (5) | 0.8550 (4) | 0.4605 (4) | 0.0360 (13)* | 0.60 |
O24B | 0.4420 (7) | 0.8431 (6) | 0.4547 (5) | 0.0337 (19)* | 0.40 |
O25A | 0.6386 (9) | 1.0576 (7) | 0.4969 (6) | 0.037 (2)* | 0.35 |
O25B | 0.5869 (11) | 1.0364 (9) | 0.4906 (8) | 0.030 (3)* | 0.25 |
O25C | 0.7427 (14) | 1.1185 (12) | 0.5456 (11) | 0.038 (4)* | 0.20 |
O25D | 0.7994 (10) | 1.1247 (9) | 0.5422 (8) | 0.017 (3)* | 0.20 |
O26A | 0.3055 (10) | 0.8377 (9) | 0.0711 (8) | 0.045 (3)* | 0.31 |
O26B | 0.3085 (13) | 0.8749 (13) | 0.0392 (11) | 0.075 (5)* | 0.30 |
O27 | 0.8491 (6) | 1.1410 (5) | 0.9027 (5) | 0.0325 (16)* | 0.42 |
O28 | 0.7746 (6) | 1.0212 (6) | 1.0010 (5) | 0.0361 (18)* | 0.40 |
O29 | 0.2422 (9) | 0.6563 (8) | 0.1076 (7) | 0.049 (3)* | 0.40 |
O30 | 0.2682 (14) | 0.6482 (13) | 0.0730 (12) | 0.091 (5)* | 0.33 |
O31 | 0.7693 (9) | 0.4686 (9) | 0.2254 (8) | 0.054 (3)* | 0.34 |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Mn1 | 0.0274 (3) | 0.0092 (3) | 0.0139 (3) | 0.0021 (2) | 0.0082 (2) | −0.0014 (2) |
Mn2 | 0.0219 (3) | 0.0074 (2) | 0.0125 (3) | 0.0006 (2) | 0.0073 (2) | −0.0006 (2) |
Mn3 | 0.0165 (3) | 0.0086 (3) | 0.0168 (3) | 0.0003 (2) | 0.0087 (2) | 0.0013 (2) |
Mn4 | 0.0145 (3) | 0.0078 (2) | 0.0147 (3) | −0.0003 (2) | 0.0068 (2) | 0.0009 (2) |
Mn5 | 0.0152 (3) | 0.0159 (3) | 0.0197 (3) | 0.0015 (2) | 0.0077 (2) | 0.0024 (2) |
Mn6 | 0.0143 (3) | 0.0104 (3) | 0.0128 (3) | 0.0001 (2) | 0.0053 (2) | −0.0018 (2) |
O1 | 0.0248 (14) | 0.0118 (12) | 0.0140 (13) | 0.0025 (10) | 0.0086 (11) | 0.0008 (10) |
O2 | 0.0320 (15) | 0.0104 (12) | 0.0139 (13) | 0.0036 (11) | 0.0052 (12) | −0.0005 (10) |
O3 | 0.0203 (13) | 0.0113 (12) | 0.0119 (12) | 0.0011 (10) | 0.0067 (10) | −0.0018 (9) |
C31 | 0.0131 (16) | 0.0070 (15) | 0.0147 (18) | −0.0051 (13) | 0.0053 (14) | −0.0015 (13) |
O4 | 0.0355 (16) | 0.0237 (15) | 0.0235 (15) | 0.0149 (13) | 0.0171 (14) | 0.0052 (12) |
O5 | 0.0163 (12) | 0.0103 (12) | 0.0109 (12) | 0.0005 (10) | 0.0043 (10) | −0.0005 (9) |
O6 | 0.0150 (12) | 0.0112 (12) | 0.0121 (12) | −0.0002 (10) | 0.0054 (10) | −0.0021 (9) |
O7 | 0.0181 (12) | 0.0107 (12) | 0.0167 (13) | 0.0028 (10) | 0.0073 (11) | 0.0030 (10) |
O8 | 0.0170 (12) | 0.0098 (12) | 0.0213 (14) | 0.0015 (10) | 0.0088 (11) | 0.0026 (10) |
O9 | 0.0269 (15) | 0.0164 (13) | 0.0145 (13) | 0.0051 (11) | 0.0088 (12) | 0.0012 (11) |
O10 | 0.0156 (12) | 0.0107 (11) | 0.0160 (13) | 0.0008 (10) | 0.0076 (10) | 0.0015 (10) |
O11 | 0.0162 (12) | 0.0077 (11) | 0.0160 (13) | 0.0009 (10) | 0.0072 (10) | 0.0018 (10) |
O12 | 0.0239 (15) | 0.0227 (14) | 0.0207 (14) | 0.0105 (12) | 0.0107 (12) | 0.0062 (11) |
O13 | 0.0172 (12) | 0.0118 (12) | 0.0137 (13) | 0.0012 (10) | 0.0065 (10) | 0.0000 (10) |
O14 | 0.0188 (13) | 0.0166 (13) | 0.0210 (14) | 0.0036 (11) | 0.0095 (11) | −0.0010 (11) |
O15 | 0.0151 (12) | 0.0180 (13) | 0.0121 (12) | 0.0002 (10) | 0.0053 (10) | −0.0005 (10) |
N1 | 0.033 (2) | 0.0193 (18) | 0.040 (2) | 0.0093 (15) | 0.0152 (18) | −0.0016 (16) |
N2 | 0.037 (2) | 0.0174 (17) | 0.0154 (17) | 0.0010 (15) | 0.0069 (15) | −0.0011 (13) |
N3 | 0.0266 (18) | 0.0146 (16) | 0.0287 (19) | −0.0007 (14) | 0.0125 (15) | −0.0042 (14) |
N4 | 0.041 (2) | 0.0092 (15) | 0.0228 (18) | 0.0010 (14) | 0.0093 (16) | −0.0027 (13) |
N5 | 0.0236 (17) | 0.0156 (15) | 0.0230 (17) | 0.0049 (13) | 0.0122 (14) | 0.0021 (13) |
N6 | 0.0211 (16) | 0.0117 (14) | 0.0229 (17) | 0.0015 (12) | 0.0134 (14) | 0.0027 (13) |
N7 | 0.0196 (16) | 0.0129 (15) | 0.0174 (16) | −0.0001 (12) | 0.0087 (13) | 0.0007 (12) |
N8 | 0.0222 (16) | 0.0138 (15) | 0.0291 (19) | 0.0031 (13) | 0.0161 (15) | 0.0045 (13) |
N9 | 0.0241 (17) | 0.0188 (17) | 0.0214 (18) | −0.0022 (14) | 0.0065 (15) | 0.0041 (14) |
N10 | 0.0178 (16) | 0.0301 (19) | 0.0185 (17) | 0.0007 (14) | 0.0053 (14) | 0.0044 (14) |
N11 | 0.030 (2) | 0.0240 (19) | 0.040 (2) | 0.0112 (16) | 0.0080 (17) | 0.0096 (17) |
N12 | 0.0235 (19) | 0.040 (2) | 0.041 (2) | 0.0077 (17) | 0.0141 (18) | −0.0052 (18) |
C1 | 0.050 (3) | 0.038 (3) | 0.045 (3) | 0.016 (2) | 0.030 (3) | 0.002 (2) |
C2 | 0.074 (4) | 0.045 (3) | 0.047 (3) | 0.012 (3) | 0.041 (3) | −0.005 (3) |
C3 | 0.061 (3) | 0.031 (3) | 0.023 (2) | 0.003 (2) | 0.023 (2) | 0.0019 (19) |
C4 | 0.039 (3) | 0.028 (2) | 0.023 (2) | 0.005 (2) | −0.003 (2) | −0.0016 (19) |
C5 | 0.028 (2) | 0.031 (3) | 0.039 (3) | −0.001 (2) | 0.007 (2) | −0.006 (2) |
C6 | 0.042 (3) | 0.025 (2) | 0.037 (3) | −0.003 (2) | 0.025 (2) | −0.0042 (19) |
C7 | 0.052 (3) | 0.020 (2) | 0.039 (3) | −0.011 (2) | 0.028 (3) | −0.0087 (19) |
C8 | 0.068 (4) | 0.016 (2) | 0.027 (3) | 0.002 (2) | 0.017 (2) | 0.0015 (18) |
C9 | 0.049 (3) | 0.020 (2) | 0.047 (3) | 0.014 (2) | 0.002 (2) | 0.001 (2) |
C10 | 0.042 (3) | 0.026 (3) | 0.079 (4) | 0.012 (2) | 0.021 (3) | −0.010 (3) |
C11 | 0.028 (2) | 0.025 (2) | 0.020 (2) | 0.0079 (17) | 0.0090 (18) | 0.0011 (16) |
C12 | 0.028 (2) | 0.029 (2) | 0.025 (2) | 0.0144 (18) | 0.0115 (18) | 0.0074 (18) |
C13 | 0.028 (2) | 0.0187 (19) | 0.027 (2) | 0.0111 (17) | 0.0125 (18) | 0.0076 (16) |
C14 | 0.029 (2) | 0.0136 (18) | 0.032 (2) | 0.0077 (16) | 0.0201 (18) | 0.0043 (16) |
C15 | 0.029 (2) | 0.0116 (17) | 0.026 (2) | 0.0009 (16) | 0.0152 (18) | −0.0032 (15) |
C16 | 0.0218 (19) | 0.0180 (19) | 0.022 (2) | 0.0020 (15) | 0.0077 (16) | 0.0012 (15) |
C17 | 0.0167 (18) | 0.0174 (19) | 0.030 (2) | −0.0013 (15) | 0.0075 (17) | 0.0018 (16) |
C18 | 0.0199 (19) | 0.0191 (19) | 0.031 (2) | 0.0050 (16) | 0.0123 (17) | 0.0070 (17) |
C19 | 0.034 (2) | 0.025 (2) | 0.030 (2) | 0.0135 (18) | 0.0213 (19) | 0.0072 (17) |
C20 | 0.034 (2) | 0.030 (2) | 0.026 (2) | 0.0116 (19) | 0.0189 (19) | 0.0066 (18) |
C21 | 0.036 (3) | 0.016 (2) | 0.034 (3) | −0.0011 (18) | 0.005 (2) | 0.0042 (18) |
C22 | 0.028 (2) | 0.021 (2) | 0.035 (3) | −0.0041 (18) | 0.006 (2) | −0.0037 (19) |
C23 | 0.026 (2) | 0.028 (2) | 0.021 (2) | −0.0017 (18) | 0.0049 (18) | −0.0031 (18) |
C24 | 0.031 (2) | 0.045 (3) | 0.022 (2) | 0.006 (2) | 0.0033 (19) | 0.016 (2) |
C25 | 0.043 (3) | 0.047 (3) | 0.047 (3) | 0.019 (3) | 0.008 (3) | 0.023 (3) |
C26 | 0.045 (3) | 0.026 (3) | 0.069 (4) | 0.017 (2) | 0.016 (3) | 0.008 (3) |
C27 | 0.051 (3) | 0.044 (3) | 0.092 (5) | 0.030 (3) | 0.027 (3) | 0.002 (3) |
C28 | 0.037 (3) | 0.052 (3) | 0.075 (4) | 0.017 (3) | 0.027 (3) | −0.018 (3) |
C29 | 0.034 (3) | 0.061 (4) | 0.041 (3) | 0.004 (2) | 0.028 (2) | −0.001 (3) |
C30 | 0.036 (3) | 0.043 (3) | 0.033 (3) | −0.004 (2) | 0.019 (2) | 0.005 (2) |
Cl1 | 0.0260 (5) | 0.0144 (4) | 0.0314 (5) | 0.0009 (4) | 0.0150 (4) | 0.0040 (4) |
Cl2 | 0.0516 (9) | 0.0594 (10) | 0.0962 (13) | 0.0178 (8) | 0.0241 (9) | −0.0287 (9) |
Cl3 | 0.0369 (12) | 0.0217 (10) | 0.0243 (11) | −0.0075 (9) | 0.0134 (9) | −0.0130 (8) |
Cl4 | 0.0354 (14) | 0.076 (2) | 0.0549 (19) | 0.0091 (15) | 0.0080 (13) | 0.0296 (17) |
Cl5A | 0.0283 (17) | 0.079 (3) | 0.078 (3) | 0.0061 (17) | 0.0153 (18) | 0.008 (2) |
Cl5B | 0.020 (5) | 0.065 (8) | 0.041 (7) | 0.017 (5) | 0.009 (5) | 0.016 (6) |
Cl6 | 0.0596 (16) | 0.0195 (10) | 0.0430 (14) | 0.0106 (10) | 0.0176 (12) | −0.0006 (10) |
O16 | 0.043 (2) | 0.044 (2) | 0.077 (3) | 0.0195 (18) | 0.037 (2) | 0.028 (2) |
O17 | 0.048 (2) | 0.046 (2) | 0.035 (2) | 0.0090 (17) | 0.0154 (17) | −0.0040 (16) |
O18 | 0.049 (2) | 0.049 (2) | 0.038 (2) | 0.0144 (18) | 0.0151 (17) | −0.0024 (17) |
O19 | 0.072 (3) | 0.054 (2) | 0.047 (2) | 0.023 (2) | 0.033 (2) | 0.0101 (19) |
Geometric parameters (Å, º) top
Mn1—O2 | 1.779 (3) | C1—C2 | 1.517 (8) |
Mn1—O1 | 1.792 (2) | C1—H1A | 0.99 |
Mn1—N3 | 2.037 (4) | C1—H1B | 0.99 |
Mn1—N1 | 2.041 (4) | C2—C3 | 1.489 (8) |
Mn1—N2 | 2.100 (3) | C2—H2A | 0.99 |
Mn1—N4 | 2.100 (3) | C2—H2B | 0.99 |
Mn1—Mn2 | 2.7295 (8) | C3—H3A | 0.99 |
Mn2—O1 | 1.867 (3) | C3—H3B | 0.99 |
Mn2—O2 | 1.892 (3) | C4—C5 | 1.497 (7) |
Mn2—O5 | 1.937 (2) | C4—H4A | 0.99 |
Mn2—O6 | 1.943 (2) | C4—H4B | 0.99 |
Mn2—O3 | 2.327 (3) | C5—H5A | 0.99 |
Mn2—O4 | 2.339 (3) | C5—H5B | 0.99 |
Mn3—O8 | 1.783 (2) | C6—C7 | 1.531 (7) |
Mn3—O7 | 1.797 (2) | C6—H6A | 0.99 |
Mn3—N5 | 2.043 (3) | C6—H6B | 0.99 |
Mn3—N7 | 2.047 (3) | C7—C8 | 1.484 (8) |
Mn3—N8 | 2.098 (3) | C7—H7A | 0.99 |
Mn3—N6 | 2.105 (3) | C7—H7B | 0.99 |
Mn3—Mn4 | 2.7237 (8) | C8—H8A | 0.99 |
Mn4—O8 | 1.879 (2) | C8—H8B | 0.99 |
Mn4—O7 | 1.883 (2) | C9—C10 | 1.498 (8) |
Mn4—O11 | 1.935 (2) | C9—H9A | 0.99 |
Mn4—O5i | 1.943 (3) | C9—H9B | 0.99 |
Mn4—O9 | 2.311 (3) | C10—H10A | 0.99 |
Mn4—O10 | 2.315 (2) | C10—H10B | 0.99 |
Mn5—O15 | 1.783 (3) | C11—C12 | 1.505 (6) |
Mn5—O14 | 1.788 (3) | C11—H11A | 0.99 |
Mn5—N11 | 2.034 (4) | C11—H11B | 0.99 |
Mn5—N9 | 2.038 (3) | C12—C13 | 1.510 (6) |
Mn5—N10 | 2.093 (3) | C12—H12A | 0.99 |
Mn5—N12 | 2.095 (4) | C12—H12B | 0.99 |
Mn5—Mn6 | 2.7204 (9) | C13—H13A | 0.99 |
Mn6—O14 | 1.868 (3) | C13—H13B | 0.99 |
Mn6—O15 | 1.883 (2) | C14—C15 | 1.498 (6) |
Mn6—O11 | 1.937 (3) | C14—H14A | 0.99 |
Mn6—O6 | 1.949 (2) | C14—H14B | 0.99 |
Mn6—O13 | 2.302 (2) | C15—H15A | 0.99 |
Mn6—O12 | 2.335 (3) | C15—H15B | 0.99 |
O3—C31 | 1.293 (4) | C16—C17 | 1.535 (5) |
C31—O13i | 1.289 (4) | C16—H16A | 0.99 |
C31—O10 | 1.301 (4) | C16—H16B | 0.99 |
O4—H4D | 0.82 (4) | C17—C18 | 1.503 (6) |
O4—H4E | 0.82 (4) | C17—H17A | 0.99 |
O5—Mn4i | 1.943 (3) | C17—H17B | 0.99 |
O5—H5D | 0.84 (4) | C18—H18A | 0.99 |
O6—H6D | 0.82 (4) | C18—H18B | 0.99 |
O9—H9D | 0.84 (4) | C19—C20 | 1.500 (6) |
O9—H9E | 0.87 (3) | C19—H19A | 0.99 |
O11—H11D | 0.83 (4) | C19—H19B | 0.99 |
O12—H12C | 0.83 (5) | C20—H20A | 0.99 |
O12—H12D | 0.82 (5) | C20—H20B | 0.99 |
O13—C31i | 1.289 (4) | C21—C22 | 1.532 (6) |
N1—C10 | 1.486 (6) | C21—H21A | 0.99 |
N1—C1 | 1.509 (6) | C21—H21B | 0.99 |
N1—H1 | 0.93 | C22—C23 | 1.506 (6) |
N2—C3 | 1.494 (6) | C22—H22A | 0.99 |
N2—C4 | 1.495 (6) | C22—H22B | 0.99 |
N2—H2 | 0.93 | C23—H23A | 0.99 |
N3—C5 | 1.489 (6) | C23—H23B | 0.99 |
N3—C6 | 1.497 (5) | C24—C25 | 1.489 (8) |
N3—H3 | 0.93 | C24—H24A | 0.99 |
N4—C8 | 1.468 (6) | C24—H24B | 0.99 |
N4—C9 | 1.509 (6) | C25—H25A | 0.99 |
N4—H4 | 0.93 | C25—H25B | 0.99 |
N5—C11 | 1.492 (5) | C26—C27 | 1.508 (8) |
N5—C20 | 1.501 (5) | C26—H26A | 0.99 |
N5—H5 | 0.93 | C26—H26B | 0.99 |
N6—C13 | 1.481 (5) | C27—C28 | 1.528 (9) |
N6—C14 | 1.498 (5) | C27—H27A | 0.99 |
N6—H6 | 0.93 | C27—H27B | 0.99 |
N7—C16 | 1.482 (5) | C28—H28A | 0.99 |
N7—C15 | 1.488 (5) | C28—H28B | 0.99 |
N7—H7 | 0.93 | C29—C30 | 1.506 (8) |
N8—C18 | 1.473 (5) | C29—H29A | 0.99 |
N8—C19 | 1.490 (5) | C29—H29B | 0.99 |
N8—H8 | 0.93 | C30—H30A | 0.99 |
N9—C30 | 1.483 (6) | C30—H30B | 0.99 |
N9—C21 | 1.493 (6) | Cl3—O27 | 1.507 (8) |
N9—H9 | 0.93 | Cl3—O28 | 1.697 (8) |
N10—C24 | 1.486 (5) | Cl4—O29 | 0.945 (10) |
N10—C23 | 1.492 (6) | Cl4—O30 | 1.597 (19) |
N10—H10 | 0.93 | Cl4—O26A | 2.127 (13) |
N11—C26 | 1.470 (6) | Cl5A—O31ii | 1.304 (12) |
N11—C25 | 1.503 (6) | Cl5A—O20 | 1.806 (11) |
N11—H11 | 0.93 | Cl5B—O20 | 1.169 (16) |
N12—C29 | 1.470 (7) | O29—O30 | 0.873 (17) |
N12—C28 | 1.511 (6) | O31—Cl5Aiii | 1.304 (12) |
N12—H12 | 0.93 | | |
| | | |
O2—Mn1—O1 | 86.28 (12) | C30—N9—H9 | 104.8 |
O2—Mn1—N3 | 92.60 (14) | C21—N9—H9 | 104.8 |
O1—Mn1—N3 | 94.14 (13) | Mn5—N9—H9 | 104.8 |
O2—Mn1—N1 | 95.52 (15) | C24—N10—C23 | 109.0 (4) |
O1—Mn1—N1 | 93.32 (13) | C24—N10—Mn5 | 106.1 (3) |
N3—Mn1—N1 | 169.31 (15) | C23—N10—Mn5 | 115.9 (3) |
O2—Mn1—N2 | 173.95 (14) | C24—N10—H10 | 108.5 |
O1—Mn1—N2 | 89.08 (12) | C23—N10—H10 | 108.5 |
N3—Mn1—N2 | 83.87 (15) | Mn5—N10—H10 | 108.5 |
N1—Mn1—N2 | 88.61 (16) | C26—N11—C25 | 112.8 (4) |
O2—Mn1—N4 | 90.63 (13) | C26—N11—Mn5 | 117.8 (3) |
O1—Mn1—N4 | 175.16 (14) | C25—N11—Mn5 | 109.4 (3) |
N3—Mn1—N4 | 89.71 (15) | C26—N11—H11 | 105.2 |
N1—Mn1—N4 | 83.26 (15) | C25—N11—H11 | 105.2 |
N2—Mn1—N4 | 94.25 (14) | Mn5—N11—H11 | 105.2 |
O2—Mn1—Mn2 | 43.57 (8) | C29—N12—C28 | 111.0 (4) |
O1—Mn1—Mn2 | 42.83 (8) | C29—N12—Mn5 | 106.2 (3) |
N3—Mn1—Mn2 | 92.08 (10) | C28—N12—Mn5 | 114.4 (3) |
N1—Mn1—Mn2 | 98.60 (11) | C29—N12—H12 | 108.3 |
N2—Mn1—Mn2 | 131.44 (10) | C28—N12—H12 | 108.3 |
N4—Mn1—Mn2 | 134.20 (10) | Mn5—N12—H12 | 108.3 |
O1—Mn2—O2 | 81.01 (11) | N1—C1—C2 | 111.6 (4) |
O1—Mn2—O5 | 91.51 (11) | N1—C1—H1A | 109.3 |
O2—Mn2—O5 | 170.92 (11) | C2—C1—H1A | 109.3 |
O1—Mn2—O6 | 171.82 (11) | N1—C1—H1B | 109.3 |
O2—Mn2—O6 | 94.09 (11) | C2—C1—H1B | 109.3 |
O5—Mn2—O6 | 93.92 (10) | H1A—C1—H1B | 108.0 |
O1—Mn2—O3 | 87.64 (10) | C3—C2—C1 | 116.1 (4) |
O2—Mn2—O3 | 94.66 (11) | C3—C2—H2A | 108.3 |
O5—Mn2—O3 | 90.15 (10) | C1—C2—H2A | 108.3 |
O6—Mn2—O3 | 86.24 (10) | C3—C2—H2B | 108.3 |
O1—Mn2—O4 | 102.12 (11) | C1—C2—H2B | 108.3 |
O2—Mn2—O4 | 92.91 (11) | H2A—C2—H2B | 107.4 |
O5—Mn2—O4 | 83.57 (10) | C2—C3—N2 | 113.2 (4) |
O6—Mn2—O4 | 84.58 (10) | C2—C3—H3A | 108.9 |
O3—Mn2—O4 | 168.49 (9) | N2—C3—H3A | 108.9 |
O1—Mn2—Mn1 | 40.72 (8) | C2—C3—H3B | 108.9 |
O2—Mn2—Mn1 | 40.40 (8) | N2—C3—H3B | 108.9 |
O5—Mn2—Mn1 | 132.21 (8) | H3A—C3—H3B | 107.8 |
O6—Mn2—Mn1 | 133.67 (7) | N2—C4—C5 | 108.2 (4) |
O3—Mn2—Mn1 | 89.21 (6) | N2—C4—H4A | 110.1 |
O4—Mn2—Mn1 | 102.16 (8) | C5—C4—H4A | 110.1 |
O8—Mn3—O7 | 86.63 (11) | N2—C4—H4B | 110.1 |
O8—Mn3—N5 | 95.31 (12) | C5—C4—H4B | 110.1 |
O7—Mn3—N5 | 94.42 (12) | H4A—C4—H4B | 108.4 |
O8—Mn3—N7 | 92.66 (12) | N3—C5—C4 | 108.3 (4) |
O7—Mn3—N7 | 93.53 (12) | N3—C5—H5A | 110.0 |
N5—Mn3—N7 | 169.05 (12) | C4—C5—H5A | 110.0 |
O8—Mn3—N8 | 88.84 (12) | N3—C5—H5B | 110.0 |
O7—Mn3—N8 | 174.58 (12) | C4—C5—H5B | 110.0 |
N5—Mn3—N8 | 83.04 (13) | H5A—C5—H5B | 108.4 |
N7—Mn3—N8 | 89.64 (13) | N3—C6—C7 | 113.1 (4) |
O8—Mn3—N6 | 173.89 (12) | N3—C6—H6A | 109.0 |
O7—Mn3—N6 | 88.92 (12) | C7—C6—H6A | 109.0 |
N5—Mn3—N6 | 89.20 (13) | N3—C6—H6B | 109.0 |
N7—Mn3—N6 | 83.44 (12) | C7—C6—H6B | 109.0 |
N8—Mn3—N6 | 95.81 (12) | H6A—C6—H6B | 107.8 |
O8—Mn3—Mn4 | 43.30 (8) | C8—C7—C6 | 114.8 (4) |
O7—Mn3—Mn4 | 43.48 (8) | C8—C7—H7A | 108.6 |
N5—Mn3—Mn4 | 99.53 (9) | C6—C7—H7A | 108.6 |
N7—Mn3—Mn4 | 91.41 (9) | C8—C7—H7B | 108.6 |
N8—Mn3—Mn4 | 132.13 (9) | C6—C7—H7B | 108.6 |
N6—Mn3—Mn4 | 131.84 (9) | H7A—C7—H7B | 107.5 |
O8—Mn4—O7 | 81.51 (11) | N4—C8—C7 | 112.9 (4) |
O8—Mn4—O11 | 172.17 (11) | N4—C8—H8A | 109.0 |
O7—Mn4—O11 | 92.09 (11) | C7—C8—H8A | 109.0 |
O8—Mn4—O5i | 93.45 (11) | N4—C8—H8B | 109.0 |
O7—Mn4—O5i | 172.62 (11) | C7—C8—H8B | 109.0 |
O11—Mn4—O5i | 93.34 (10) | H8A—C8—H8B | 107.8 |
O8—Mn4—O9 | 92.53 (10) | C10—C9—N4 | 107.4 (4) |
O7—Mn4—O9 | 99.40 (10) | C10—C9—H9A | 110.2 |
O11—Mn4—O9 | 84.01 (10) | N4—C9—H9A | 110.2 |
O5i—Mn4—O9 | 86.15 (10) | C10—C9—H9B | 110.2 |
O8—Mn4—O10 | 95.15 (10) | N4—C9—H9B | 110.2 |
O7—Mn4—O10 | 88.53 (10) | H9A—C9—H9B | 108.5 |
O11—Mn4—O10 | 89.17 (10) | N1—C10—C9 | 107.5 (4) |
O5i—Mn4—O10 | 86.55 (10) | N1—C10—H10A | 110.2 |
O9—Mn4—O10 | 169.69 (9) | C9—C10—H10A | 110.2 |
O8—Mn4—Mn3 | 40.60 (8) | N1—C10—H10B | 110.2 |
O7—Mn4—Mn3 | 41.04 (8) | C9—C10—H10B | 110.2 |
O11—Mn4—Mn3 | 133.13 (8) | H10A—C10—H10B | 108.5 |
O5i—Mn4—Mn3 | 133.36 (8) | N5—C11—C12 | 113.8 (3) |
O9—Mn4—Mn3 | 100.44 (7) | N5—C11—H11A | 108.8 |
O10—Mn4—Mn3 | 89.86 (6) | C12—C11—H11A | 108.8 |
O15—Mn5—O14 | 86.53 (11) | N5—C11—H11B | 108.8 |
O15—Mn5—N11 | 92.78 (14) | C12—C11—H11B | 108.8 |
O14—Mn5—N11 | 94.52 (14) | H11A—C11—H11B | 107.7 |
O15—Mn5—N9 | 94.10 (13) | C11—C12—C13 | 114.0 (3) |
O14—Mn5—N9 | 93.53 (13) | C11—C12—H12A | 108.7 |
N11—Mn5—N9 | 169.71 (15) | C13—C12—H12A | 108.7 |
O15—Mn5—N10 | 89.18 (13) | C11—C12—H12B | 108.7 |
O14—Mn5—N10 | 175.15 (13) | C13—C12—H12B | 108.7 |
N11—Mn5—N10 | 83.40 (14) | H12A—C12—H12B | 107.6 |
N9—Mn5—N10 | 89.04 (14) | N6—C13—C12 | 113.4 (3) |
O15—Mn5—N12 | 175.04 (14) | N6—C13—H13A | 108.9 |
O14—Mn5—N12 | 89.28 (14) | C12—C13—H13A | 108.9 |
N11—Mn5—N12 | 90.20 (17) | N6—C13—H13B | 108.9 |
N9—Mn5—N12 | 83.51 (16) | C12—C13—H13B | 108.9 |
N10—Mn5—N12 | 95.11 (15) | H13A—C13—H13B | 107.7 |
O15—Mn5—Mn6 | 43.54 (8) | N6—C14—C15 | 108.3 (3) |
O14—Mn5—Mn6 | 43.05 (8) | N6—C14—H14A | 110.0 |
N11—Mn5—Mn6 | 96.77 (11) | C15—C14—H14A | 110.0 |
N9—Mn5—Mn6 | 93.48 (10) | N6—C14—H14B | 110.0 |
N10—Mn5—Mn6 | 132.72 (10) | C15—C14—H14B | 110.0 |
N12—Mn5—Mn6 | 132.11 (11) | H14A—C14—H14B | 108.4 |
O14—Mn6—O15 | 81.47 (11) | N7—C15—C14 | 108.6 (3) |
O14—Mn6—O11 | 172.64 (11) | N7—C15—H15A | 110.0 |
O15—Mn6—O11 | 92.11 (11) | C14—C15—H15A | 110.0 |
O14—Mn6—O6 | 92.30 (11) | N7—C15—H15B | 110.0 |
O15—Mn6—O6 | 172.26 (11) | C14—C15—H15B | 110.0 |
O11—Mn6—O6 | 94.39 (11) | H15A—C15—H15B | 108.4 |
O14—Mn6—O13 | 89.99 (10) | N7—C16—C17 | 113.3 (3) |
O15—Mn6—O13 | 93.85 (10) | N7—C16—H16A | 108.9 |
O11—Mn6—O13 | 86.85 (9) | C17—C16—H16A | 108.9 |
O6—Mn6—O13 | 90.71 (10) | N7—C16—H16B | 108.9 |
O14—Mn6—O12 | 97.18 (11) | C17—C16—H16B | 108.9 |
O15—Mn6—O12 | 93.50 (10) | H16A—C16—H16B | 107.7 |
O11—Mn6—O12 | 86.74 (10) | C18—C17—C16 | 114.1 (3) |
O6—Mn6—O12 | 82.68 (10) | C18—C17—H17A | 108.7 |
O13—Mn6—O12 | 170.42 (10) | C16—C17—H17A | 108.7 |
O14—Mn6—Mn5 | 40.82 (8) | C18—C17—H17B | 108.7 |
O15—Mn6—Mn5 | 40.70 (8) | C16—C17—H17B | 108.7 |
O11—Mn6—Mn5 | 132.53 (8) | H17A—C17—H17B | 107.6 |
O6—Mn6—Mn5 | 133.08 (8) | N8—C18—C17 | 112.7 (3) |
O13—Mn6—Mn5 | 90.94 (6) | N8—C18—H18A | 109.0 |
O12—Mn6—Mn5 | 98.65 (7) | C17—C18—H18A | 109.0 |
Mn1—O1—Mn2 | 96.45 (12) | N8—C18—H18B | 109.0 |
Mn1—O2—Mn2 | 96.04 (12) | C17—C18—H18B | 109.0 |
C31—O3—Mn2 | 126.7 (2) | H18A—C18—H18B | 107.8 |
O13i—C31—O3 | 120.8 (3) | N8—C19—C20 | 108.2 (3) |
O13i—C31—O10 | 120.0 (3) | N8—C19—H19A | 110.1 |
O3—C31—O10 | 119.2 (3) | C20—C19—H19A | 110.1 |
Mn2—O4—H4D | 103 (3) | N8—C19—H19B | 110.1 |
Mn2—O4—H4E | 112 (3) | C20—C19—H19B | 110.1 |
H4D—O4—H4E | 113 (4) | H19A—C19—H19B | 108.4 |
Mn2—O5—Mn4i | 141.16 (14) | C19—C20—N5 | 106.9 (3) |
Mn2—O5—H5D | 106 (3) | C19—C20—H20A | 110.3 |
Mn4i—O5—H5D | 106 (3) | N5—C20—H20A | 110.3 |
Mn2—O6—Mn6 | 140.94 (13) | C19—C20—H20B | 110.3 |
Mn2—O6—H6D | 99 (3) | N5—C20—H20B | 110.3 |
Mn6—O6—H6D | 111 (3) | H20A—C20—H20B | 108.6 |
Mn3—O7—Mn4 | 95.48 (12) | N9—C21—C22 | 113.5 (4) |
Mn3—O8—Mn4 | 96.10 (12) | N9—C21—H21A | 108.9 |
Mn4—O9—H9D | 144 (3) | C22—C21—H21A | 108.9 |
Mn4—O9—H9E | 110 (3) | N9—C21—H21B | 108.9 |
H9D—O9—H9E | 99 (3) | C22—C21—H21B | 108.9 |
C31—O10—Mn4 | 126.1 (2) | H21A—C21—H21B | 107.7 |
Mn4—O11—Mn6 | 141.70 (13) | C23—C22—C21 | 113.9 (3) |
Mn4—O11—H11D | 110 (3) | C23—C22—H22A | 108.8 |
Mn6—O11—H11D | 100 (3) | C21—C22—H22A | 108.8 |
Mn6—O12—H12C | 103 (3) | C23—C22—H22B | 108.8 |
Mn6—O12—H12D | 121 (3) | C21—C22—H22B | 108.8 |
H12C—O12—H12D | 109 (3) | H22A—C22—H22B | 107.7 |
C31i—O13—Mn6 | 125.7 (2) | N10—C23—C22 | 112.2 (4) |
Mn5—O14—Mn6 | 96.13 (12) | N10—C23—H23A | 109.2 |
Mn5—O15—Mn6 | 95.76 (12) | C22—C23—H23A | 109.2 |
C10—N1—C1 | 112.6 (4) | N10—C23—H23B | 109.2 |
C10—N1—Mn1 | 109.8 (3) | C22—C23—H23B | 109.2 |
C1—N1—Mn1 | 117.9 (3) | H23A—C23—H23B | 107.9 |
C10—N1—H1 | 105.1 | N10—C24—C25 | 108.3 (4) |
C1—N1—H1 | 105.1 | N10—C24—H24A | 110.0 |
Mn1—N1—H1 | 105.1 | C25—C24—H24A | 110.0 |
C3—N2—C4 | 109.0 (4) | N10—C24—H24B | 110.0 |
C3—N2—Mn1 | 116.4 (3) | C25—C24—H24B | 110.0 |
C4—N2—Mn1 | 105.0 (3) | H24A—C24—H24B | 108.4 |
C3—N2—H2 | 108.7 | C24—C25—N11 | 107.2 (4) |
C4—N2—H2 | 108.7 | C24—C25—H25A | 110.3 |
Mn1—N2—H2 | 108.7 | N11—C25—H25A | 110.3 |
C5—N3—C6 | 113.7 (3) | C24—C25—H25B | 110.3 |
C5—N3—Mn1 | 109.6 (3) | N11—C25—H25B | 110.3 |
C6—N3—Mn1 | 117.2 (3) | H25A—C25—H25B | 108.5 |
C5—N3—H3 | 105.0 | N11—C26—C27 | 113.2 (4) |
C6—N3—H3 | 105.0 | N11—C26—H26A | 108.9 |
Mn1—N3—H3 | 105.0 | C27—C26—H26A | 108.9 |
C8—N4—C9 | 110.4 (4) | N11—C26—H26B | 108.9 |
C8—N4—Mn1 | 114.8 (3) | C27—C26—H26B | 108.9 |
C9—N4—Mn1 | 105.9 (3) | H26A—C26—H26B | 107.8 |
C8—N4—H4 | 108.5 | C26—C27—C28 | 114.8 (5) |
C9—N4—H4 | 108.5 | C26—C27—H27A | 108.6 |
Mn1—N4—H4 | 108.5 | C28—C27—H27A | 108.6 |
C11—N5—C20 | 112.7 (3) | C26—C27—H27B | 108.6 |
C11—N5—Mn3 | 117.3 (2) | C28—C27—H27B | 108.6 |
C20—N5—Mn3 | 110.1 (2) | H27A—C27—H27B | 107.6 |
C11—N5—H5 | 105.2 | N12—C28—C27 | 112.5 (5) |
C20—N5—H5 | 105.2 | N12—C28—H28A | 109.1 |
Mn3—N5—H5 | 105.2 | C27—C28—H28A | 109.1 |
C13—N6—C14 | 110.1 (3) | N12—C28—H28B | 109.1 |
C13—N6—Mn3 | 116.1 (2) | C27—C28—H28B | 109.1 |
C14—N6—Mn3 | 105.7 (2) | H28A—C28—H28B | 107.8 |
C13—N6—H6 | 108.2 | N12—C29—C30 | 109.0 (4) |
C14—N6—H6 | 108.2 | N12—C29—H29A | 109.9 |
Mn3—N6—H6 | 108.2 | C30—C29—H29A | 109.9 |
C16—N7—C15 | 113.8 (3) | N12—C29—H29B | 109.9 |
C16—N7—Mn3 | 117.5 (2) | C30—C29—H29B | 109.9 |
C15—N7—Mn3 | 110.0 (2) | H29A—C29—H29B | 108.3 |
C16—N7—H7 | 104.7 | N9—C30—C29 | 108.1 (4) |
C15—N7—H7 | 104.7 | N9—C30—H30A | 110.1 |
Mn3—N7—H7 | 104.7 | C29—C30—H30A | 110.1 |
C18—N8—C19 | 110.7 (3) | N9—C30—H30B | 110.1 |
C18—N8—Mn3 | 116.4 (2) | C29—C30—H30B | 110.1 |
C19—N8—Mn3 | 106.3 (2) | H30A—C30—H30B | 108.4 |
C18—N8—H8 | 107.7 | O27—Cl3—O28 | 116.6 (4) |
C19—N8—H8 | 107.7 | O29—Cl4—O26A | 120.7 (8) |
Mn3—N8—H8 | 107.7 | O30—Cl4—O26A | 94.1 (7) |
C30—N9—C21 | 113.1 (3) | O31ii—Cl5A—O20 | 125.5 (7) |
C30—N9—Mn5 | 110.0 (3) | Cl5B—O20—Cl5A | 144.3 (10) |
C21—N9—Mn5 | 118.0 (3) | | |
| | | |
O2—Mn1—Mn2—O1 | −174.57 (19) | N3—Mn1—N1—C10 | 37.6 (10) |
N3—Mn1—Mn2—O1 | 93.85 (16) | N2—Mn1—N1—C10 | 82.9 (4) |
N1—Mn1—Mn2—O1 | −85.59 (17) | N4—Mn1—N1—C10 | −11.6 (4) |
N2—Mn1—Mn2—O1 | 10.20 (19) | Mn2—Mn1—N1—C10 | −145.4 (3) |
N4—Mn1—Mn2—O1 | −174.5 (2) | O2—Mn1—N1—C1 | 127.8 (3) |
O1—Mn1—Mn2—O2 | 174.57 (19) | O1—Mn1—N1—C1 | 41.2 (3) |
N3—Mn1—Mn2—O2 | −91.58 (17) | N3—Mn1—N1—C1 | −93.0 (8) |
N1—Mn1—Mn2—O2 | 88.98 (18) | N2—Mn1—N1—C1 | −47.8 (3) |
N2—Mn1—Mn2—O2 | −175.2 (2) | N4—Mn1—N1—C1 | −142.3 (3) |
N4—Mn1—Mn2—O2 | 0.0 (2) | Mn2—Mn1—N1—C1 | 83.9 (3) |
O2—Mn1—Mn2—O5 | −172.38 (17) | O1—Mn1—N2—C3 | −46.7 (3) |
O1—Mn1—Mn2—O5 | 2.18 (16) | N3—Mn1—N2—C3 | −141.0 (3) |
N3—Mn1—Mn2—O5 | 96.03 (15) | N1—Mn1—N2—C3 | 46.6 (3) |
N1—Mn1—Mn2—O5 | −83.40 (15) | N4—Mn1—N2—C3 | 129.7 (3) |
N2—Mn1—Mn2—O5 | 12.38 (18) | Mn2—Mn1—N2—C3 | −53.7 (4) |
N4—Mn1—Mn2—O5 | −172.35 (18) | O1—Mn1—N2—C4 | 73.9 (3) |
O2—Mn1—Mn2—O6 | 14.10 (17) | N3—Mn1—N2—C4 | −20.4 (3) |
O1—Mn1—Mn2—O6 | −171.34 (17) | N1—Mn1—N2—C4 | 167.2 (3) |
N3—Mn1—Mn2—O6 | −77.49 (15) | N4—Mn1—N2—C4 | −109.6 (3) |
N1—Mn1—Mn2—O6 | 103.07 (16) | Mn2—Mn1—N2—C4 | 67.0 (3) |
N2—Mn1—Mn2—O6 | −161.14 (18) | O2—Mn1—N3—C5 | 176.5 (3) |
N4—Mn1—Mn2—O6 | 14.1 (2) | O1—Mn1—N3—C5 | −97.1 (3) |
O2—Mn1—Mn2—O3 | 98.13 (15) | N1—Mn1—N3—C5 | 37.1 (9) |
O1—Mn1—Mn2—O3 | −87.30 (14) | N2—Mn1—N3—C5 | −8.4 (3) |
N3—Mn1—Mn2—O3 | 6.55 (12) | N4—Mn1—N3—C5 | 85.9 (3) |
N1—Mn1—Mn2—O3 | −172.89 (13) | Mn2—Mn1—N3—C5 | −139.9 (3) |
N2—Mn1—Mn2—O3 | −77.10 (16) | O2—Mn1—N3—C6 | 45.0 (3) |
N4—Mn1—Mn2—O3 | 98.17 (17) | O1—Mn1—N3—C6 | 131.4 (3) |
O2—Mn1—Mn2—O4 | −80.04 (16) | N1—Mn1—N3—C6 | −94.4 (8) |
O1—Mn1—Mn2—O4 | 94.53 (15) | N2—Mn1—N3—C6 | −140.0 (3) |
N3—Mn1—Mn2—O4 | −171.62 (12) | N4—Mn1—N3—C6 | −45.7 (3) |
N1—Mn1—Mn2—O4 | 8.94 (13) | Mn2—Mn1—N3—C6 | 88.6 (3) |
N2—Mn1—Mn2—O4 | 104.73 (16) | O2—Mn1—N4—C8 | −44.9 (3) |
N4—Mn1—Mn2—O4 | −80.00 (17) | N3—Mn1—N4—C8 | 47.7 (3) |
O7—Mn3—Mn4—O8 | 173.98 (17) | N1—Mn1—N4—C8 | −140.3 (4) |
N5—Mn3—Mn4—O8 | 87.63 (15) | N2—Mn1—N4—C8 | 131.6 (3) |
N7—Mn3—Mn4—O8 | −92.38 (15) | Mn2—Mn1—N4—C8 | −44.9 (4) |
N8—Mn3—Mn4—O8 | −1.59 (17) | O2—Mn1—N4—C9 | 77.2 (3) |
N6—Mn3—Mn4—O8 | −174.83 (17) | N3—Mn1—N4—C9 | 169.8 (3) |
O8—Mn3—Mn4—O7 | −173.98 (17) | N1—Mn1—N4—C9 | −18.3 (3) |
N5—Mn3—Mn4—O7 | −86.36 (15) | N2—Mn1—N4—C9 | −106.4 (3) |
N7—Mn3—Mn4—O7 | 93.64 (15) | Mn2—Mn1—N4—C9 | 77.2 (3) |
N8—Mn3—Mn4—O7 | −175.57 (17) | O8—Mn3—N5—C11 | 130.4 (3) |
N6—Mn3—Mn4—O7 | 11.19 (16) | O7—Mn3—N5—C11 | 43.4 (3) |
O8—Mn3—Mn4—O11 | −173.18 (16) | N7—Mn3—N5—C11 | −93.1 (7) |
O7—Mn3—Mn4—O11 | 0.81 (15) | N8—Mn3—N5—C11 | −141.4 (3) |
N5—Mn3—Mn4—O11 | −85.55 (14) | N6—Mn3—N5—C11 | −45.5 (3) |
N7—Mn3—Mn4—O11 | 94.45 (14) | Mn4—Mn3—N5—C11 | 86.9 (3) |
N8—Mn3—Mn4—O11 | −174.76 (16) | O8—Mn3—N5—C20 | −99.0 (3) |
N6—Mn3—Mn4—O11 | 12.00 (16) | O7—Mn3—N5—C20 | 174.0 (3) |
O8—Mn3—Mn4—O5i | 12.97 (15) | N7—Mn3—N5—C20 | 37.6 (8) |
O7—Mn3—Mn4—O5i | −173.04 (16) | N8—Mn3—N5—C20 | −10.8 (3) |
N5—Mn3—Mn4—O5i | 100.60 (14) | N6—Mn3—N5—C20 | 85.2 (3) |
N7—Mn3—Mn4—O5i | −79.40 (14) | Mn4—Mn3—N5—C20 | −142.5 (2) |
N8—Mn3—Mn4—O5i | 11.39 (17) | O7—Mn3—N6—C13 | −48.7 (3) |
N6—Mn3—Mn4—O5i | −161.85 (15) | N5—Mn3—N6—C13 | 45.7 (3) |
O8—Mn3—Mn4—O9 | −81.61 (14) | N7—Mn3—N6—C13 | −142.4 (3) |
O7—Mn3—Mn4—O9 | 92.37 (14) | N8—Mn3—N6—C13 | 128.6 (3) |
N5—Mn3—Mn4—O9 | 6.01 (12) | Mn4—Mn3—N6—C13 | −56.4 (3) |
N7—Mn3—Mn4—O9 | −173.99 (12) | O7—Mn3—N6—C14 | 73.6 (2) |
N8—Mn3—Mn4—O9 | −83.20 (14) | N5—Mn3—N6—C14 | 168.1 (2) |
N6—Mn3—Mn4—O9 | 103.56 (14) | N7—Mn3—N6—C14 | −20.1 (2) |
O8—Mn3—Mn4—O10 | 98.10 (13) | N8—Mn3—N6—C14 | −109.0 (2) |
O7—Mn3—Mn4—O10 | −87.92 (13) | Mn4—Mn3—N6—C14 | 65.9 (3) |
N5—Mn3—Mn4—O10 | −174.28 (11) | O8—Mn3—N7—C16 | 44.0 (3) |
N7—Mn3—Mn4—O10 | 5.72 (11) | O7—Mn3—N7—C16 | 130.8 (2) |
N8—Mn3—Mn4—O10 | 96.51 (14) | N5—Mn3—N7—C16 | −92.7 (7) |
N6—Mn3—Mn4—O10 | −76.73 (13) | N8—Mn3—N7—C16 | −44.8 (3) |
O15—Mn5—Mn6—O14 | 176.28 (17) | N6—Mn3—N7—C16 | −140.7 (3) |
N11—Mn5—Mn6—O14 | 89.38 (17) | Mn4—Mn3—N7—C16 | 87.4 (2) |
N9—Mn5—Mn6—O14 | −91.44 (16) | O8—Mn3—N7—C15 | 176.5 (2) |
N10—Mn5—Mn6—O14 | 176.65 (18) | O7—Mn3—N7—C15 | −96.7 (2) |
N12—Mn5—Mn6—O14 | −7.0 (2) | N5—Mn3—N7—C15 | 39.8 (8) |
O14—Mn5—Mn6—O15 | −176.28 (17) | N8—Mn3—N7—C15 | 87.7 (2) |
N11—Mn5—Mn6—O15 | −86.89 (17) | N6—Mn3—N7—C15 | −8.2 (2) |
N9—Mn5—Mn6—O15 | 92.28 (16) | Mn4—Mn3—N7—C15 | −140.2 (2) |
N10—Mn5—Mn6—O15 | 0.37 (17) | O8—Mn3—N8—C18 | −47.0 (3) |
N12—Mn5—Mn6—O15 | 176.7 (2) | N5—Mn3—N8—C18 | −142.5 (3) |
O15—Mn5—Mn6—O11 | −8.24 (15) | N7—Mn3—N8—C18 | 45.7 (3) |
O14—Mn5—Mn6—O11 | 175.48 (16) | N6—Mn3—N8—C18 | 129.0 (3) |
N11—Mn5—Mn6—O11 | −95.13 (16) | Mn4—Mn3—N8—C18 | −45.9 (3) |
N9—Mn5—Mn6—O11 | 84.04 (14) | N5—Mn3—N8—C19 | −18.7 (2) |
N10—Mn5—Mn6—O11 | −7.87 (17) | N7—Mn3—N8—C19 | 169.4 (3) |
N12—Mn5—Mn6—O11 | 168.44 (18) | N6—Mn3—N8—C19 | −107.2 (2) |
O15—Mn5—Mn6—O6 | 173.33 (16) | Mn4—Mn3—N8—C19 | 77.9 (3) |
O14—Mn5—Mn6—O6 | −2.95 (16) | O15—Mn5—N9—C30 | −175.0 (3) |
N11—Mn5—Mn6—O6 | 86.44 (16) | O14—Mn5—N9—C30 | 98.2 (3) |
N9—Mn5—Mn6—O6 | −94.39 (15) | N11—Mn5—N9—C30 | −43.2 (10) |
N10—Mn5—Mn6—O6 | 173.70 (16) | N10—Mn5—N9—C30 | −85.9 (3) |
N12—Mn5—Mn6—O6 | −10.0 (2) | N12—Mn5—N9—C30 | 9.4 (3) |
O15—Mn5—Mn6—O13 | −94.82 (13) | Mn6—Mn5—N9—C30 | 141.4 (3) |
O14—Mn5—Mn6—O13 | 88.90 (14) | O15—Mn5—N9—C21 | −43.2 (3) |
N11—Mn5—Mn6—O13 | 178.29 (13) | O14—Mn5—N9—C21 | −130.0 (3) |
N9—Mn5—Mn6—O13 | −2.54 (12) | N11—Mn5—N9—C21 | 88.6 (9) |
N10—Mn5—Mn6—O13 | −94.45 (15) | N10—Mn5—N9—C21 | 45.9 (3) |
N12—Mn5—Mn6—O13 | 81.86 (17) | N12—Mn5—N9—C21 | 141.1 (3) |
O15—Mn5—Mn6—O12 | 85.29 (14) | Mn6—Mn5—N9—C21 | −86.9 (3) |
O14—Mn5—Mn6—O12 | −90.99 (14) | O15—Mn5—N10—C24 | −74.8 (3) |
N11—Mn5—Mn6—O12 | −1.60 (14) | N11—Mn5—N10—C24 | 18.1 (3) |
N9—Mn5—Mn6—O12 | 177.57 (12) | N9—Mn5—N10—C24 | −168.9 (3) |
N10—Mn5—Mn6—O12 | 85.66 (15) | N12—Mn5—N10—C24 | 107.7 (3) |
N12—Mn5—Mn6—O12 | −98.03 (17) | Mn6—Mn5—N10—C24 | −75.0 (3) |
O2—Mn1—O1—Mn2 | 3.75 (13) | O15—Mn5—N10—C23 | 46.4 (3) |
N3—Mn1—O1—Mn2 | −88.59 (14) | N11—Mn5—N10—C23 | 139.3 (3) |
N1—Mn1—O1—Mn2 | 99.07 (15) | N9—Mn5—N10—C23 | −47.7 (3) |
N2—Mn1—O1—Mn2 | −172.37 (14) | N12—Mn5—N10—C23 | −131.1 (3) |
O2—Mn2—O1—Mn1 | −3.56 (12) | Mn6—Mn5—N10—C23 | 46.1 (3) |
O5—Mn2—O1—Mn1 | −178.38 (12) | O15—Mn5—N11—C26 | −129.2 (3) |
O3—Mn2—O1—Mn1 | 91.53 (11) | O14—Mn5—N11—C26 | −42.4 (3) |
O4—Mn2—O1—Mn1 | −94.63 (12) | N9—Mn5—N11—C26 | 98.9 (9) |
O1—Mn1—O2—Mn2 | −3.70 (13) | N10—Mn5—N11—C26 | 142.0 (4) |
N3—Mn1—O2—Mn2 | 90.28 (14) | N12—Mn5—N11—C26 | 46.8 (3) |
N1—Mn1—O2—Mn2 | −96.68 (14) | Mn6—Mn5—N11—C26 | −85.7 (3) |
N4—Mn1—O2—Mn2 | −179.97 (15) | O15—Mn5—N11—C25 | 100.1 (4) |
O1—Mn2—O2—Mn1 | 3.59 (12) | O14—Mn5—N11—C25 | −173.1 (3) |
O6—Mn2—O2—Mn1 | −169.83 (12) | N9—Mn5—N11—C25 | −31.7 (11) |
O3—Mn2—O2—Mn1 | −83.28 (12) | N10—Mn5—N11—C25 | 11.3 (4) |
O4—Mn2—O2—Mn1 | 105.40 (13) | N12—Mn5—N11—C25 | −83.8 (4) |
O1—Mn2—O3—C31 | 178.5 (3) | Mn6—Mn5—N11—C25 | 143.7 (3) |
O2—Mn2—O3—C31 | −100.7 (3) | O14—Mn5—N12—C29 | −74.7 (3) |
O5—Mn2—O3—C31 | 87.0 (3) | N11—Mn5—N12—C29 | −169.2 (3) |
O6—Mn2—O3—C31 | −6.9 (3) | N9—Mn5—N12—C29 | 18.9 (3) |
O4—Mn2—O3—C31 | 30.2 (6) | N10—Mn5—N12—C29 | 107.4 (3) |
Mn1—Mn2—O3—C31 | −140.8 (3) | Mn6—Mn5—N12—C29 | −69.9 (3) |
Mn2—O3—C31—O13i | −141.3 (3) | N11—Mn5—N12—C28 | −46.4 (4) |
Mn2—O3—C31—O10 | 38.1 (4) | N9—Mn5—N12—C28 | 141.7 (4) |
O1—Mn2—O5—Mn4i | −48.7 (2) | N10—Mn5—N12—C28 | −129.8 (4) |
O6—Mn2—O5—Mn4i | 125.2 (2) | Mn6—Mn5—N12—C28 | 52.9 (4) |
O3—Mn2—O5—Mn4i | 38.9 (2) | C10—N1—C1—C2 | −68.1 (5) |
O4—Mn2—O5—Mn4i | −150.8 (2) | Mn1—N1—C1—C2 | 61.3 (5) |
Mn1—Mn2—O5—Mn4i | −50.2 (3) | N1—C1—C2—C3 | −64.4 (6) |
O2—Mn2—O6—Mn6 | −143.2 (2) | C1—C2—C3—N2 | 65.0 (6) |
O5—Mn2—O6—Mn6 | 32.5 (2) | C4—N2—C3—C2 | −178.6 (4) |
O3—Mn2—O6—Mn6 | 122.4 (2) | Mn1—N2—C3—C2 | −60.1 (5) |
O4—Mn2—O6—Mn6 | −50.7 (2) | C3—N2—C4—C5 | 171.2 (3) |
Mn1—Mn2—O6—Mn6 | −152.32 (16) | Mn1—N2—C4—C5 | 45.8 (4) |
O14—Mn6—O6—Mn2 | 54.3 (2) | C6—N3—C5—C4 | 169.5 (4) |
O11—Mn6—O6—Mn2 | −122.6 (2) | Mn1—N3—C5—C4 | 36.2 (4) |
O13—Mn6—O6—Mn2 | −35.7 (2) | N2—C4—C5—N3 | −55.4 (5) |
O12—Mn6—O6—Mn2 | 151.3 (2) | C5—N3—C6—C7 | −71.2 (6) |
Mn5—Mn6—O6—Mn2 | 56.2 (3) | Mn1—N3—C6—C7 | 58.4 (5) |
O8—Mn3—O7—Mn4 | 4.13 (11) | N3—C6—C7—C8 | −64.0 (6) |
N5—Mn3—O7—Mn4 | 99.20 (13) | C9—N4—C8—C7 | 176.7 (4) |
N7—Mn3—O7—Mn4 | −88.33 (12) | Mn1—N4—C8—C7 | −63.7 (4) |
N6—Mn3—O7—Mn4 | −171.69 (12) | C6—C7—C8—N4 | 67.9 (5) |
O8—Mn4—O7—Mn3 | −3.95 (11) | C8—N4—C9—C10 | 169.7 (4) |
O11—Mn4—O7—Mn3 | −179.41 (11) | Mn1—N4—C9—C10 | 44.9 (4) |
O9—Mn4—O7—Mn3 | −95.13 (11) | C1—N1—C10—C9 | 173.2 (4) |
O10—Mn4—O7—Mn3 | 91.48 (11) | Mn1—N1—C10—C9 | 39.8 (5) |
O7—Mn3—O8—Mn4 | −4.14 (11) | N4—C9—C10—N1 | −56.6 (5) |
N5—Mn3—O8—Mn4 | −98.28 (13) | C20—N5—C11—C12 | −68.6 (4) |
N7—Mn3—O8—Mn4 | 89.24 (12) | Mn3—N5—C11—C12 | 60.9 (4) |
N8—Mn3—O8—Mn4 | 178.82 (12) | N5—C11—C12—C13 | −65.1 (5) |
O7—Mn4—O8—Mn3 | 3.99 (11) | C14—N6—C13—C12 | 179.2 (3) |
O5i—Mn4—O8—Mn3 | −170.59 (11) | Mn3—N6—C13—C12 | −60.8 (4) |
O9—Mn4—O8—Mn3 | 103.12 (11) | C11—C12—C13—N6 | 65.8 (4) |
O10—Mn4—O8—Mn3 | −83.75 (11) | C13—N6—C14—C15 | 171.1 (3) |
O13i—C31—O10—Mn4 | 36.4 (4) | Mn3—N6—C14—C15 | 44.9 (3) |
O3—C31—O10—Mn4 | −142.9 (2) | C16—N7—C15—C14 | 169.8 (3) |
O8—Mn4—O10—C31 | −97.8 (3) | Mn3—N7—C15—C14 | 35.5 (4) |
O7—Mn4—O10—C31 | −179.2 (3) | N6—C14—C15—N7 | −54.1 (4) |
O11—Mn4—O10—C31 | 88.7 (3) | C15—N7—C16—C17 | −71.1 (4) |
O5i—Mn4—O10—C31 | −4.7 (3) | Mn3—N7—C16—C17 | 59.6 (4) |
O9—Mn4—O10—C31 | 40.3 (7) | N7—C16—C17—C18 | −65.4 (5) |
Mn3—Mn4—O10—C31 | −138.1 (3) | C19—N8—C18—C17 | 177.0 (3) |
O7—Mn4—O11—Mn6 | −49.4 (2) | Mn3—N8—C18—C17 | −61.6 (4) |
O5i—Mn4—O11—Mn6 | 125.6 (2) | C16—C17—C18—N8 | 66.8 (4) |
O9—Mn4—O11—Mn6 | −148.7 (2) | C18—N8—C19—C20 | 172.5 (3) |
O10—Mn4—O11—Mn6 | 39.1 (2) | Mn3—N8—C19—C20 | 45.2 (3) |
Mn3—Mn4—O11—Mn6 | −50.0 (3) | N8—C19—C20—N5 | −55.6 (4) |
O15—Mn6—O11—Mn4 | 140.5 (2) | C11—N5—C20—C19 | 171.3 (3) |
O6—Mn6—O11—Mn4 | −35.3 (2) | Mn3—N5—C20—C19 | 38.2 (4) |
O13—Mn6—O11—Mn4 | −125.7 (2) | C30—N9—C21—C22 | 71.0 (5) |
O12—Mn6—O11—Mn4 | 47.1 (2) | Mn5—N9—C21—C22 | −59.4 (5) |
Mn5—Mn6—O11—Mn4 | 145.89 (16) | N9—C21—C22—C23 | 64.0 (6) |
O14—Mn6—O13—C31i | 178.3 (3) | C24—N10—C23—C22 | −176.9 (3) |
O15—Mn6—O13—C31i | 96.8 (3) | Mn5—N10—C23—C22 | 63.5 (4) |
O11—Mn6—O13—C31i | 4.9 (3) | C21—C22—C23—N10 | −66.7 (5) |
O6—Mn6—O13—C31i | −89.4 (3) | C23—N10—C24—C25 | −170.3 (4) |
Mn5—Mn6—O13—C31i | 137.5 (3) | Mn5—N10—C24—C25 | −44.8 (4) |
O15—Mn5—O14—Mn6 | −2.57 (12) | N10—C24—C25—N11 | 56.0 (5) |
N11—Mn5—O14—Mn6 | −95.08 (15) | C26—N11—C25—C24 | −172.1 (4) |
N9—Mn5—O14—Mn6 | 91.33 (14) | Mn5—N11—C25—C24 | −38.8 (5) |
N12—Mn5—O14—Mn6 | 174.78 (15) | C25—N11—C26—C27 | 68.5 (6) |
O15—Mn6—O14—Mn5 | 2.45 (11) | Mn5—N11—C26—C27 | −60.6 (6) |
O6—Mn6—O14—Mn5 | 177.85 (11) | N11—C26—C27—C28 | 65.0 (7) |
O13—Mn6—O14—Mn5 | −91.44 (11) | C29—N12—C28—C27 | −178.9 (4) |
O12—Mn6—O14—Mn5 | 94.94 (12) | Mn5—N12—C28—C27 | 61.0 (5) |
O14—Mn5—O15—Mn6 | 2.54 (12) | C26—C27—C28—N12 | −66.4 (6) |
N11—Mn5—O15—Mn6 | 96.91 (14) | C28—N12—C29—C30 | −168.7 (4) |
N9—Mn5—O15—Mn6 | −90.75 (13) | Mn5—N12—C29—C30 | −43.7 (4) |
N10—Mn5—O15—Mn6 | −179.73 (13) | C21—N9—C30—C29 | −169.8 (4) |
O14—Mn6—O15—Mn5 | −2.46 (11) | Mn5—N9—C30—C29 | −35.6 (5) |
O11—Mn6—O15—Mn5 | 173.93 (11) | N12—C29—C30—N9 | 53.5 (5) |
O13—Mn6—O15—Mn5 | 86.95 (11) | O31ii—Cl5A—O20—Cl5B | 162.0 (15) |
O12—Mn6—O15—Mn5 | −99.20 (11) | O26A—Cl4—O29—O30 | 14 (2) |
O2—Mn1—N1—C10 | −101.6 (4) | O26A—Cl4—O30—O29 | −168 (2) |
O1—Mn1—N1—C10 | 171.9 (4) | | |
Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) x−1, y, z; (iii) x+1, y, z. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
N6—H6···Cl1 | 0.93 | 2.51 | 3.413 (3) | 163 |
N8—H8···Cl1 | 0.93 | 2.27 | 3.198 (3) | 174 |
O4—H4E···Cl2 | 0.82 (4) | 2.33 (3) | 3.106 (3) | 158 (4) |
N1—H1···Cl2 | 0.93 | 2.49 | 3.285 (4) | 143 |
N2—H2···Cl3 | 0.93 | 2.46 | 3.338 (4) | 157 |
N4—H4···Cl3 | 0.93 | 2.46 | 3.384 (4) | 174 |
N11—H11···Cl4 | 0.93 | 2.37 | 3.148 (5) | 141 |
N10—H10···Cl5A | 0.93 | 2.68 | 3.523 (6) | 152 |
N10—H10···Cl5B | 0.93 | 2.49 | 3.185 (12) | 132 |
N5—H5···Cl6 | 0.93 | 2.32 | 3.138 (4) | 147 |
O4—H4D···O14 | 0.82 (4) | 1.90 (2) | 2.701 (4) | 166 (4) |
O5—H5D···O13 | 0.84 (4) | 1.86 (2) | 2.674 (3) | 164 (4) |
O6—H6D···O10 | 0.82 (4) | 1.88 (2) | 2.681 (4) | 166 (4) |
O9—H9E···O1i | 0.87 (3) | 1.83 (2) | 2.665 (4) | 161 (4) |
O11—H11D···O3i | 0.83 (2) | 1.85 (2) | 2.675 (3) | 172 (4) |
O12—H12C···O7 | 0.83 (5) | 1.88 (5) | 2.704 (4) | 171 (4) |
O12—H12D···Cl4 | 0.82 (2) | 2.26 (2) | 3.065 (4) | 165 (4) |
N2—H2···O28 | 0.93 | 2.08 | 2.952 (9) | 156 |
N3—H3···O3 | 0.93 | 1.99 | 2.798 (4) | 144 |
N7—H7···O10 | 0.93 | 1.99 | 2.790 (4) | 143 |
N9—H9···O13 | 0.93 | 2.14 | 2.896 (4) | 138 |
N10—H10···O20 | 0.93 | 2.02 | 2.912 (10) | 160 |
Symmetry code: (i) −x+1, −y+1, −z+1. |
Experimental details
Crystal data |
Chemical formula | [Mn12(CO3)2O12(OH)6(C10H24N4)6(H2O)6]Cl8·24H2O |
Mr | 3099.42 |
Crystal system, space group | Triclinic, P1 |
Temperature (K) | 90 |
a, b, c (Å) | 15.2421 (15), 15.5037 (15), 17.1306 (17) |
α, β, γ (°) | 90.707 (6), 114.523 (7), 115.128 (7) |
V (Å3) | 3245.8 (6) |
Z | 1 |
Radiation type | Mo Kα |
µ (mm−1) | 1.38 |
Crystal size (mm) | 0.43 × 0.18 × 0.14 |
|
Data collection |
Diffractometer | Bruker SMART APEXII diffractometer |
Absorption correction | Multi-scan (SADABS; Sheldrick, 1996) |
Tmin, Tmax | 0.589, 0.831 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 40135, 14856, 10648 |
Rint | 0.042 |
(sin θ/λ)max (Å−1) | 0.650 |
|
Refinement |
R[F2 > 2σ(F2)], wR(F2), S | 0.051, 0.167, 1.14 |
No. of reflections | 14856 |
No. of parameters | 787 |
No. of restraints | 12 |
H-atom treatment | H atoms treated by a mixture of independent and constrained refinement |
Δρmax, Δρmin (e Å−3) | 1.40, −1.14 |
Selected geometric parameters (Å, º) topMn1—O2 | 1.779 (3) | Mn4—O7 | 1.883 (2) |
Mn1—O1 | 1.792 (2) | Mn4—O5i | 1.943 (3) |
Mn1—N3 | 2.037 (4) | Mn4—O9 | 2.311 (3) |
Mn1—N1 | 2.041 (4) | Mn4—O10 | 2.315 (2) |
Mn1—N2 | 2.100 (3) | Mn5—O15 | 1.783 (3) |
Mn1—N4 | 2.100 (3) | Mn5—O14 | 1.788 (3) |
Mn2—O1 | 1.867 (3) | Mn5—N11 | 2.034 (4) |
Mn2—O2 | 1.892 (3) | Mn5—N9 | 2.038 (3) |
Mn2—O5 | 1.937 (2) | Mn5—N10 | 2.093 (3) |
Mn2—O6 | 1.943 (2) | Mn5—N12 | 2.095 (4) |
Mn2—O3 | 2.327 (3) | Mn6—O14 | 1.868 (3) |
Mn2—O4 | 2.339 (3) | Mn6—O15 | 1.883 (2) |
Mn3—O8 | 1.783 (2) | Mn6—O11 | 1.937 (3) |
Mn3—O7 | 1.797 (2) | Mn6—O6 | 1.949 (2) |
Mn3—N5 | 2.043 (3) | Mn6—O13 | 2.302 (2) |
Mn3—N7 | 2.047 (3) | Mn6—O12 | 2.335 (3) |
Mn3—N8 | 2.098 (3) | O3—C31 | 1.293 (4) |
Mn3—N6 | 2.105 (3) | C31—O13i | 1.289 (4) |
Mn4—O8 | 1.879 (2) | C31—O10 | 1.301 (4) |
| | | |
O13i—C31—O3 | 120.8 (3) | O3—C31—O10 | 119.2 (3) |
O13i—C31—O10 | 120.0 (3) | | |
Symmetry code: (i) −x+1, −y+1, −z+1. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
N6—H6···Cl1 | 0.93 | 2.51 | 3.413 (3) | 163 |
N8—H8···Cl1 | 0.93 | 2.27 | 3.198 (3) | 174 |
O4—H4E···Cl2 | 0.82 (4) | 2.33 (3) | 3.106 (3) | 158 (4) |
N1—H1···Cl2 | 0.93 | 2.49 | 3.285 (4) | 143 |
N2—H2···Cl3 | 0.93 | 2.46 | 3.338 (4) | 157 |
N4—H4···Cl3 | 0.93 | 2.46 | 3.384 (4) | 174 |
N11—H11···Cl4 | 0.93 | 2.37 | 3.148 (5) | 141 |
N10—H10···Cl5A | 0.93 | 2.68 | 3.523 (6) | 152 |
N10—H10···Cl5B | 0.93 | 2.49 | 3.185 (12) | 132 |
N5—H5···Cl6 | 0.93 | 2.32 | 3.138 (4) | 147 |
O4—H4D···O14 | 0.82 (4) | 1.90 (2) | 2.701 (4) | 166 (4) |
O5—H5D···O13 | 0.84 (4) | 1.86 (2) | 2.674 (3) | 164 (4) |
O6—H6D···O10 | 0.82 (4) | 1.88 (2) | 2.681 (4) | 166 (4) |
O9—H9E···O1i | 0.87 (3) | 1.83 (2) | 2.665 (4) | 161 (4) |
O11—H11D···O3i | 0.83 (2) | 1.85 (2) | 2.675 (3) | 172 (4) |
O12—H12C···O7 | 0.83 (5) | 1.88 (5) | 2.704 (4) | 171 (4) |
O12—H12D···Cl4 | 0.82 (2) | 2.26 (2) | 3.065 (4) | 165 (4) |
N2—H2···O28 | 0.93 | 2.08 | 2.952 (9) | 156 |
N3—H3···O3 | 0.93 | 1.99 | 2.798 (4) | 144 |
N7—H7···O10 | 0.93 | 1.99 | 2.790 (4) | 143 |
N9—H9···O13 | 0.93 | 2.14 | 2.896 (4) | 138 |
N10—H10···O20 | 0.93 | 2.02 | 2.912 (10) | 160 |
Symmetry code: (i) −x+1, −y+1, −z+1. |
Reactions of carbon dioxide with metals and metal clusters have recently attracted a great deal of interest (Bian et al., 2009). Complexes of manganese rarely exhibit such reactivity. We wish to report the fortuitous fixation of carbon dioxide as carbonate ion in a mixed valent MnIII/MnIV cluster of 12 metal ions. An interesting structural feature consists of two triply bridged carbonate anions on opposite faces of the cluster. Previously, a MnIII cluster containing carbonate was reported (Chakov et al., 2005), but it has little in common with the title compound. Many Mn12 clusters are known, some of which have mixed valent MnIII/MnIV ions (Sun et al., 1998; Kuroda-Sowa et al., 2001; Bian et al., 2004). The most famous is Mn12O12(MeCO2)16(H2O)4 (Lis, 1980; Aubin, et al., 1996), which opened up the field of single molecule magnets. These structures are unlike that of the title compound. They contain an internal cubane of four MnIV ions with µ3-O bridges and eight outer MnIII ions. The production of the title compound was unexpected. We presume that prolonged stirring of a manganese(II) chloride solution in an open vessel in the presence of base (cyclam, (1,4,8,11-tetraazacyclotetradecane)) yielded a basic MnIII/MnIV oxide which took up CO2 from the air and formed the triply bridged carbonate species of the title compound.
The cluster of the title compound has a center of symmetry. It has the overall formula {[(cyclam)MnIV(µ-O)2MnIII(H2O)(µ-OH)]6(µ3-CO3)}2}8+ with charge balanced by chloride ions. There are 24 molecules of non-coordinated water in the model, many of which are disordered. The Mn12 cluster is shown in the Scheme.
For simplicity, only one half of the cluster is depicted in Fig. 1. The atoms labeled Mn1, Mn3, and Mn5 are MnIV and those labeled Mn2, Mn4, Mn6 are MnIII. The oxidation states for the Mn ions were verified by Bond Valence Sum analysis (Palenik, 1997). Details of the bond distances and angles are given in Table 1. The asymmetric unit of the title compound contains a carbonate anion coordinated to three MnIII ions through each of its three O atoms. Within experimental error, the µ3-CO3 group is planar. The average C—O distance is 1.294 (4) Å. Each carbonate O atom accepts an intramolecular hydrogen bond from a µ-(OH) donor group that is ligated to two MnIII's. A second hydrogen bond to each carbonate oxygen is formed by donation from a N—H group of cyclam, as shown in Figure 2. A single water molecule is coordinated to each MnIII in a position trans- to the carbonate oxygen. The Mn—O(carbonate) distances, average 2.315 (8) Å, and Mn—O(H2O) distances, average 2.328 (11) Å, are long, indicating a Jahn-Teller effect of the d4 ion and strong trans-effect of carbonate. The remainder of the coordination sphere of the MnIII ion is made up of two oxo bridges, average distance 1.879 (7) Å. These bridges link the MnIII ions to MnIV ions. The average MnIV—O distance is 1.787 (6) Å. The coordination sphere of the MnIV ions is completed by four amino N atoms of the cyclam ligand. The Mn—N bond distances reflect the trans-effect of the µ-oxo bridges; the average MnIV—N(trans) distance is 2.097 (5)Å as compared to 2.040 (4)Å for MnIV—N(cis). Fig. 3 depicts the entire Mn12 cluster with cyclam CH2 groups omitted for clarity. In sum, both MnIII and MnIV have coordination number six and a pseudo- octahedral geometry. The inversion-related halves of the cluster are connected via the µ-(OH) groups. A diverse set of Mn—O bonds is exhibited in the structure, involving oxo, hydroxo, and aqua ligation to MnIII and MnIV ions as well as intramolecular hydrogen bonding. The chloride counterions are primarily nestled in cyclam cavities, hydrogen bonded to N—H donor groups of the cylam ligands as well as to non-coordinated water molecules.