metal-organic compounds
(η5-C5Me5)WO2(CH2SiMe3), which has crystallographic mirror symmetry, exhibits the three-legged piano stool geometry typical for complexes of this type. The pentamethylcyclopentadienyl ligand is asymmetrically bound to the metal atom [W-C = 2.321 (8)–2.477 (4) Å]. The W=O and W—C(alkyl) distances are 1.717 (4) and 2.128 (8) Å, respectively.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 126816