Download citation
Download citation
link to html
In the title complex, [Co(C2HCl2)(C4H7N2O22(C5H5N)].CHCl3, the Co atom exhibits a distorted octahedral coordination with the two dimethylglyoximate (dmgH) ligands in equatorial positions [Co-N 1.891 (2)-1.897 (3) Å]. The axial positions are occupied by the pyridine (py) and cis-1,2-dichlorovinyl ligands [N-Co-C 179.0 (1)°], which are nearly coplanar. The Co-C1 distance is 1.958 (3) Å. The Co-Npy bond length of 2.028 (2) Å indicates a lower trans influence for the dichlorovinyl ligand compared with alkyl ligands.

Supporting information


Crystallographic Information File (CIF)
Contains datablocks hallin, global


Structure factor file (CIF format)
Contains datablock hallin

CCDC reference: 128019

Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds