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The title compound, [Ag(C12H8F2NO4S2)(H2O)]n, consists of infinite strands [(RSO2)2N–Ag(μ-H2O)] (R = 4-fluorophenyl), in which Ag extends its coordination number to five by accepting one Ag—O bond from each of the (RSO2)2N ligands in the adjacent repeat units. By means of OH...O hydrogen bonds the strands are associated to form parallel layers. These display an inner polar region of Ag atoms, H2O molecules and N(SO2)2 groups, outer apolar regions of stacked benzene fragments, and interlayer regions consisting of F atoms.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks silbi, global

fcf

Structure factor file (CIF format)
Contains datablock silbi

CCDC reference: 129022

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