Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807048520/fi2046sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536807048520/fi2046Isup2.hkl |
CCDC reference: 667435
The title compound was formed as a side product from an amidine synthesis, involving excess aniline (reagent grade (99%); purified by distillation prior to use) and PCl5 (reagent grade (95%)), the latter of which forms POCl3 during the reaction (all reagents are from Sigma-Aldrich). It is believed that (Ph—NH)3PO is then formed and dimerizes to the title compound once it is treated with aqueous solution of KOH. The title compound was previously published by Murray and Woodward in 1989. The actual crystals were formed by slow evaporation of an ethanolic solution of the title compound.
All non-H atoms were refined by full-matrix least-squares with anisotropic displacement parameters. The H atoms bonded to C atoms were generated geometrically (C—H 0.95 Å) and were included in the refinement in the riding model approximation. The H atoms bonded to N atoms were generated geometrically, but their position was left to refine, with a restraint on the N—H distance set to 0.88 Å with a standard deviation of 0.01 Å. Their temperature factors of all H atoms were set to 1.2 times those of the equivalent isotropic temperature factors of the parent site.
The packing along the a-b plane is dominated by hydrogen-bonding interactions. Both crystallographically different molecules show the same interactions. There is one amine which forms an intramolecular hydrogen bond and one intermolecular hydrogen bond; two amines with only one intermolecular interaction, and lastly one that has no intermolecular interactions. Every oxygen atom is implicated in two hydrogen-bonding interactions.
Along the A axis, the intermolecular hydrogen bonds are formed by alternating nitrogen and oxygen atoms, two per molecule. Along the B axis, the interactions zigzag through two nitrogen atoms on one molecule forming an H bond to one oxygen atom on the other molecule. Along the C axis, only weak van der Waals forces can be seen between the aromatic rings, with no π stacking interactions visible.
Full synthetic details for this compound have been published by Murray & Woodward (1989).
Data collection: APEX2 (Bruker, 2004); cell refinement: APEX2 (Bruker, 2004); data reduction: SAINT (Bruker, 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: UdMX (local program).
C30H29N5O2P2 | F(000) = 4640 |
Mr = 553.52 | Dx = 1.276 Mg m−3 |
Orthorhombic, Pbca | Cu Kα radiation, λ = 1.54178 Å |
Hall symbol: -P 2ac 2ab | Cell parameters from 9956 reflections |
a = 24.5585 (11) Å | θ = 6.9–142.3° |
b = 18.5726 (8) Å | µ = 1.66 mm−1 |
c = 25.2655 (11) Å | T = 150 K |
V = 11524.0 (9) Å3 | Rectangular, yellow |
Z = 16 | 0.25 × 0.15 × 0.03 mm |
Bruker SMART 6000 diffractometer | 11291 independent reflections |
Radiation source: Rotating Anode | 7252 reflections with I > 2σ(I) |
Montel 200 optics monochromator | Rint = 0.046 |
Detector resolution: 5.5 pixels mm-1 | θmax = 72.1°, θmin = 3.5° |
ω scans | h = −30→30 |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | k = −21→22 |
Tmin = 0.758, Tmax = 0.949 | l = −30→31 |
139703 measured reflections |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.039 | H atoms treated by a mixture of independent and constrained refinement |
wR(F2) = 0.089 | w = 1/[σ2(Fo2) + (0.0532P)2] where P = (Fo2 + 2Fc2)/3 |
S = 1.02 | (Δ/σ)max = 0.001 |
11291 reflections | Δρmax = 0.39 e Å−3 |
728 parameters | Δρmin = −0.36 e Å−3 |
10 restraints | Extinction correction: SHELXL97 (Sheldrick, 1997), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
Primary atom site location: structure-invariant direct methods | Extinction coefficient: 0.000171 (8) |
C30H29N5O2P2 | V = 11524.0 (9) Å3 |
Mr = 553.52 | Z = 16 |
Orthorhombic, Pbca | Cu Kα radiation |
a = 24.5585 (11) Å | µ = 1.66 mm−1 |
b = 18.5726 (8) Å | T = 150 K |
c = 25.2655 (11) Å | 0.25 × 0.15 × 0.03 mm |
Bruker SMART 6000 diffractometer | 11291 independent reflections |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | 7252 reflections with I > 2σ(I) |
Tmin = 0.758, Tmax = 0.949 | Rint = 0.046 |
139703 measured reflections |
R[F2 > 2σ(F2)] = 0.039 | 10 restraints |
wR(F2) = 0.089 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.02 | Δρmax = 0.39 e Å−3 |
11291 reflections | Δρmin = −0.36 e Å−3 |
728 parameters |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
P1 | 0.65576 (2) | 0.48585 (3) | 0.754249 (19) | 0.02444 (12) | |
P2 | 0.53618 (2) | 0.50155 (3) | 0.73556 (2) | 0.02467 (12) | |
O1 | 0.65139 (5) | 0.56457 (7) | 0.75262 (5) | 0.0290 (3) | |
O2 | 0.48667 (5) | 0.45736 (7) | 0.74287 (5) | 0.0286 (3) | |
N1 | 0.59122 (6) | 0.45317 (8) | 0.75373 (6) | 0.0248 (4) | |
N2 | 0.68598 (7) | 0.44726 (9) | 0.80493 (7) | 0.0293 (4) | |
H2A | 0.7132 (6) | 0.4203 (9) | 0.7958 (7) | 0.035* | |
N3 | 0.69061 (7) | 0.44926 (9) | 0.70599 (7) | 0.0281 (4) | |
H3A | 0.7037 (7) | 0.4068 (6) | 0.7128 (7) | 0.034* | |
N4 | 0.53229 (6) | 0.57819 (9) | 0.76724 (6) | 0.0263 (4) | |
H4A | 0.5573 (6) | 0.6086 (8) | 0.7574 (7) | 0.032* | |
N5 | 0.54844 (7) | 0.52345 (9) | 0.67328 (7) | 0.0297 (4) | |
H5A | 0.5804 (5) | 0.5158 (10) | 0.6614 (7) | 0.036* | |
C11 | 0.58426 (7) | 0.37484 (10) | 0.75339 (8) | 0.0291 (5) | |
C12 | 0.58079 (8) | 0.33875 (11) | 0.80111 (9) | 0.0353 (5) | |
H12A | 0.5838 | 0.3642 | 0.8336 | 0.042* | |
C13 | 0.57285 (9) | 0.26438 (12) | 0.80081 (10) | 0.0473 (7) | |
H13A | 0.5708 | 0.2387 | 0.8333 | 0.057* | |
C14 | 0.56801 (9) | 0.22814 (13) | 0.75364 (10) | 0.0504 (7) | |
H14A | 0.5625 | 0.1775 | 0.7537 | 0.061* | |
C15 | 0.57104 (9) | 0.26442 (13) | 0.70659 (11) | 0.0509 (7) | |
H15A | 0.5671 | 0.2390 | 0.6742 | 0.061* | |
C16 | 0.57988 (8) | 0.33834 (12) | 0.70596 (9) | 0.0389 (6) | |
H16A | 0.5829 | 0.3634 | 0.6733 | 0.047* | |
C21 | 0.67473 (8) | 0.45363 (11) | 0.85936 (8) | 0.0309 (5) | |
C22 | 0.70931 (9) | 0.41966 (12) | 0.89513 (9) | 0.0408 (6) | |
H22A | 0.7394 | 0.3924 | 0.8827 | 0.049* | |
C23 | 0.69967 (11) | 0.42569 (14) | 0.94892 (9) | 0.0537 (7) | |
H23A | 0.7235 | 0.4027 | 0.9732 | 0.064* | |
C24 | 0.65608 (11) | 0.46445 (14) | 0.96771 (9) | 0.0593 (8) | |
H24A | 0.6498 | 0.4683 | 1.0047 | 0.071* | |
C25 | 0.62165 (11) | 0.49771 (13) | 0.93227 (9) | 0.0520 (7) | |
H25A | 0.5913 | 0.5242 | 0.9450 | 0.062* | |
C26 | 0.63085 (9) | 0.49286 (12) | 0.87810 (8) | 0.0375 (5) | |
H26A | 0.6071 | 0.5164 | 0.8540 | 0.045* | |
C31 | 0.68792 (8) | 0.46881 (11) | 0.65188 (8) | 0.0300 (5) | |
C32 | 0.68773 (10) | 0.41429 (13) | 0.61464 (9) | 0.0525 (7) | |
H32A | 0.6882 | 0.3654 | 0.6256 | 0.063* | |
C33 | 0.68685 (12) | 0.43123 (15) | 0.56134 (10) | 0.0706 (9) | |
H33A | 0.6868 | 0.3936 | 0.5358 | 0.085* | |
C34 | 0.68613 (11) | 0.50187 (14) | 0.54469 (9) | 0.0583 (7) | |
H34A | 0.6858 | 0.5133 | 0.5080 | 0.070* | |
C35 | 0.68586 (10) | 0.55557 (13) | 0.58215 (9) | 0.0495 (7) | |
H35A | 0.6852 | 0.6045 | 0.5712 | 0.059* | |
C36 | 0.68658 (9) | 0.53923 (12) | 0.63550 (8) | 0.0374 (5) | |
H36A | 0.6862 | 0.5769 | 0.6609 | 0.045* | |
C41 | 0.51105 (8) | 0.58915 (10) | 0.81928 (8) | 0.0282 (5) | |
C42 | 0.46391 (8) | 0.55543 (12) | 0.83649 (9) | 0.0375 (5) | |
H42A | 0.4446 | 0.5238 | 0.8136 | 0.045* | |
C43 | 0.44509 (9) | 0.56827 (13) | 0.88754 (9) | 0.0459 (6) | |
H43A | 0.4134 | 0.5440 | 0.8996 | 0.055* | |
C44 | 0.47129 (10) | 0.61517 (13) | 0.92088 (9) | 0.0467 (6) | |
H44A | 0.4581 | 0.6234 | 0.9557 | 0.056* | |
C45 | 0.51736 (10) | 0.65031 (13) | 0.90268 (9) | 0.0480 (6) | |
H45A | 0.5354 | 0.6840 | 0.9249 | 0.058* | |
C46 | 0.53746 (9) | 0.63701 (12) | 0.85246 (8) | 0.0400 (6) | |
H46A | 0.5695 | 0.6608 | 0.8407 | 0.048* | |
C51 | 0.51003 (8) | 0.54874 (11) | 0.63601 (8) | 0.0298 (5) | |
C52 | 0.45839 (9) | 0.57113 (11) | 0.65102 (8) | 0.0365 (5) | |
H52A | 0.4480 | 0.5703 | 0.6872 | 0.044* | |
C53 | 0.42208 (9) | 0.59473 (12) | 0.61288 (9) | 0.0434 (6) | |
H53A | 0.3868 | 0.6101 | 0.6234 | 0.052* | |
C54 | 0.43579 (10) | 0.59647 (14) | 0.56070 (10) | 0.0569 (7) | |
H54A | 0.4105 | 0.6131 | 0.5350 | 0.068* | |
C55 | 0.48704 (11) | 0.57370 (15) | 0.54554 (10) | 0.0634 (8) | |
H55A | 0.4970 | 0.5748 | 0.5092 | 0.076* | |
C56 | 0.52398 (10) | 0.54928 (13) | 0.58302 (9) | 0.0477 (6) | |
H56A | 0.5589 | 0.5329 | 0.5722 | 0.057* | |
P11 | 0.78654 (2) | 0.27729 (3) | 0.73290 (2) | 0.02464 (12) | |
P12 | 0.90624 (2) | 0.29401 (3) | 0.75486 (2) | 0.02492 (12) | |
O11 | 0.73709 (5) | 0.32157 (7) | 0.73999 (5) | 0.0295 (3) | |
O12 | 0.90202 (5) | 0.21522 (7) | 0.75375 (5) | 0.0298 (3) | |
N11 | 0.84200 (6) | 0.32634 (8) | 0.74910 (6) | 0.0243 (4) | |
N12 | 0.78249 (6) | 0.20195 (8) | 0.76629 (6) | 0.0251 (4) | |
H12B | 0.8073 (6) | 0.1707 (8) | 0.7580 (7) | 0.030* | |
N13 | 0.79872 (7) | 0.25319 (9) | 0.67107 (6) | 0.0309 (4) | |
H13B | 0.8304 (5) | 0.2642 (10) | 0.6590 (7) | 0.037* | |
N14 | 0.94452 (7) | 0.33005 (9) | 0.70872 (7) | 0.0283 (4) | |
H14B | 0.9577 (7) | 0.3717 (6) | 0.7180 (7) | 0.034* | |
N15 | 0.93244 (7) | 0.33257 (9) | 0.80766 (6) | 0.0286 (4) | |
H15B | 0.9548 (6) | 0.3671 (8) | 0.7995 (7) | 0.034* | |
C111 | 0.83487 (7) | 0.40416 (11) | 0.74594 (8) | 0.0271 (5) | |
C112 | 0.82790 (8) | 0.44297 (11) | 0.79193 (9) | 0.0344 (5) | |
H11A | 0.8290 | 0.4193 | 0.8252 | 0.041* | |
C113 | 0.81929 (9) | 0.51689 (12) | 0.78940 (10) | 0.0464 (6) | |
H11B | 0.8146 | 0.5438 | 0.8210 | 0.056* | |
C114 | 0.81759 (9) | 0.55119 (12) | 0.74101 (11) | 0.0497 (7) | |
H11C | 0.8117 | 0.6017 | 0.7394 | 0.060* | |
C115 | 0.82449 (9) | 0.51218 (12) | 0.69487 (10) | 0.0471 (6) | |
H11D | 0.8230 | 0.5358 | 0.6615 | 0.057* | |
C116 | 0.83359 (8) | 0.43834 (11) | 0.69735 (9) | 0.0362 (5) | |
H11E | 0.8389 | 0.4115 | 0.6658 | 0.043* | |
C121 | 0.75911 (8) | 0.19211 (10) | 0.81755 (7) | 0.0264 (5) | |
C122 | 0.71505 (8) | 0.23221 (11) | 0.83540 (8) | 0.0342 (5) | |
H12C | 0.6996 | 0.2687 | 0.8137 | 0.041* | |
C123 | 0.69384 (9) | 0.21837 (13) | 0.88524 (8) | 0.0413 (6) | |
H12D | 0.6641 | 0.2464 | 0.8977 | 0.050* | |
C124 | 0.71469 (9) | 0.16517 (12) | 0.91707 (8) | 0.0400 (6) | |
H12E | 0.6995 | 0.1564 | 0.9510 | 0.048* | |
C125 | 0.75813 (9) | 0.12454 (11) | 0.89901 (8) | 0.0381 (6) | |
H12F | 0.7727 | 0.0872 | 0.9205 | 0.046* | |
C126 | 0.78043 (8) | 0.13834 (11) | 0.84969 (8) | 0.0325 (5) | |
H12G | 0.8106 | 0.1108 | 0.8377 | 0.039* | |
C131 | 0.75926 (8) | 0.23638 (10) | 0.63213 (8) | 0.0303 (5) | |
C132 | 0.70794 (9) | 0.21190 (11) | 0.64540 (8) | 0.0377 (5) | |
H13C | 0.6983 | 0.2051 | 0.6815 | 0.045* | |
C133 | 0.67069 (10) | 0.19726 (13) | 0.60574 (10) | 0.0501 (7) | |
H13D | 0.6354 | 0.1804 | 0.6150 | 0.060* | |
C134 | 0.68368 (11) | 0.20655 (14) | 0.55348 (10) | 0.0573 (8) | |
H13E | 0.6578 | 0.1960 | 0.5266 | 0.069* | |
C135 | 0.73497 (11) | 0.23142 (13) | 0.54034 (9) | 0.0516 (7) | |
H13F | 0.7444 | 0.2380 | 0.5042 | 0.062* | |
C136 | 0.77265 (10) | 0.24683 (12) | 0.57930 (8) | 0.0396 (6) | |
H13G | 0.8077 | 0.2645 | 0.5700 | 0.048* | |
C141 | 0.94267 (8) | 0.31258 (12) | 0.65441 (8) | 0.0340 (5) | |
C142 | 0.93114 (9) | 0.24394 (12) | 0.63629 (8) | 0.0395 (6) | |
H14C | 0.9248 | 0.2061 | 0.6608 | 0.047* | |
C143 | 0.92889 (10) | 0.23030 (14) | 0.58253 (9) | 0.0566 (7) | |
H14D | 0.9206 | 0.1831 | 0.5704 | 0.068* | |
C144 | 0.93847 (13) | 0.28417 (17) | 0.54632 (10) | 0.0787 (10) | |
H14E | 0.9361 | 0.2747 | 0.5094 | 0.094* | |
C145 | 0.95154 (13) | 0.35178 (16) | 0.56418 (10) | 0.0830 (11) | |
H14F | 0.9593 | 0.3889 | 0.5394 | 0.100* | |
C146 | 0.95355 (11) | 0.36668 (14) | 0.61791 (9) | 0.0575 (8) | |
H14G | 0.9624 | 0.4138 | 0.6298 | 0.069* | |
C151 | 0.90887 (8) | 0.33299 (11) | 0.85851 (8) | 0.0286 (5) | |
C152 | 0.92385 (9) | 0.38581 (12) | 0.89471 (8) | 0.0379 (5) | |
H15C | 0.9511 | 0.4200 | 0.8856 | 0.045* | |
C153 | 0.89929 (10) | 0.38867 (13) | 0.94370 (9) | 0.0485 (6) | |
H15D | 0.9096 | 0.4251 | 0.9681 | 0.058* | |
C154 | 0.85972 (9) | 0.33911 (13) | 0.95780 (9) | 0.0459 (6) | |
H15E | 0.8428 | 0.3414 | 0.9916 | 0.055* | |
C155 | 0.84527 (9) | 0.28639 (12) | 0.92205 (8) | 0.0370 (5) | |
H15F | 0.8182 | 0.2521 | 0.9314 | 0.044* | |
C156 | 0.86962 (8) | 0.28287 (11) | 0.87282 (7) | 0.0294 (5) | |
H15G | 0.8595 | 0.2460 | 0.8487 | 0.035* |
U11 | U22 | U33 | U12 | U13 | U23 | |
P1 | 0.0215 (3) | 0.0230 (3) | 0.0288 (3) | −0.0004 (2) | −0.0015 (2) | 0.0018 (2) |
P2 | 0.0216 (3) | 0.0234 (3) | 0.0289 (3) | 0.0001 (2) | −0.0015 (2) | 0.0010 (2) |
O1 | 0.0247 (8) | 0.0224 (7) | 0.0399 (9) | −0.0023 (6) | −0.0011 (6) | 0.0000 (6) |
O2 | 0.0234 (8) | 0.0250 (8) | 0.0375 (8) | −0.0015 (6) | −0.0006 (6) | −0.0009 (6) |
N1 | 0.0214 (9) | 0.0196 (9) | 0.0333 (10) | −0.0009 (7) | −0.0024 (7) | 0.0017 (7) |
N2 | 0.0244 (10) | 0.0333 (11) | 0.0303 (10) | 0.0041 (8) | −0.0009 (8) | 0.0025 (8) |
N3 | 0.0284 (10) | 0.0223 (10) | 0.0335 (10) | 0.0044 (7) | 0.0032 (8) | 0.0036 (8) |
N4 | 0.0235 (9) | 0.0238 (10) | 0.0316 (9) | −0.0035 (7) | 0.0019 (7) | 0.0019 (8) |
N5 | 0.0240 (10) | 0.0350 (10) | 0.0301 (10) | 0.0035 (8) | 0.0009 (8) | 0.0031 (8) |
C11 | 0.0193 (11) | 0.0226 (11) | 0.0454 (13) | 0.0000 (8) | −0.0020 (9) | 0.0004 (10) |
C12 | 0.0294 (13) | 0.0303 (13) | 0.0462 (14) | −0.0034 (9) | −0.0085 (10) | 0.0064 (10) |
C13 | 0.0335 (14) | 0.0321 (14) | 0.0763 (19) | −0.0060 (11) | −0.0137 (13) | 0.0190 (13) |
C14 | 0.0383 (15) | 0.0219 (13) | 0.091 (2) | −0.0028 (10) | −0.0063 (14) | 0.0001 (13) |
C15 | 0.0436 (15) | 0.0357 (15) | 0.0735 (19) | −0.0064 (11) | 0.0061 (13) | −0.0171 (13) |
C16 | 0.0363 (14) | 0.0316 (13) | 0.0489 (14) | −0.0031 (10) | 0.0037 (11) | −0.0055 (11) |
C21 | 0.0300 (12) | 0.0309 (13) | 0.0317 (12) | −0.0065 (9) | −0.0040 (9) | 0.0052 (9) |
C22 | 0.0413 (14) | 0.0396 (14) | 0.0416 (14) | −0.0001 (11) | −0.0066 (11) | 0.0100 (11) |
C23 | 0.0658 (19) | 0.0572 (18) | 0.0383 (15) | −0.0027 (14) | −0.0118 (13) | 0.0168 (13) |
C24 | 0.083 (2) | 0.065 (2) | 0.0302 (14) | −0.0045 (16) | 0.0029 (14) | 0.0099 (13) |
C25 | 0.0602 (18) | 0.0575 (18) | 0.0384 (14) | 0.0019 (14) | 0.0087 (12) | 0.0023 (13) |
C26 | 0.0388 (14) | 0.0409 (14) | 0.0326 (12) | 0.0001 (11) | −0.0013 (10) | 0.0040 (10) |
C31 | 0.0267 (12) | 0.0309 (12) | 0.0324 (12) | 0.0030 (9) | 0.0023 (9) | 0.0045 (9) |
C32 | 0.087 (2) | 0.0325 (15) | 0.0375 (14) | 0.0138 (13) | 0.0048 (13) | 0.0008 (11) |
C33 | 0.129 (3) | 0.0465 (18) | 0.0360 (15) | 0.0196 (17) | 0.0039 (16) | −0.0059 (13) |
C34 | 0.090 (2) | 0.0552 (18) | 0.0301 (13) | 0.0126 (15) | 0.0068 (13) | 0.0077 (13) |
C35 | 0.0700 (19) | 0.0373 (15) | 0.0411 (14) | −0.0001 (13) | 0.0034 (13) | 0.0105 (12) |
C36 | 0.0467 (15) | 0.0295 (13) | 0.0359 (13) | −0.0020 (10) | 0.0037 (11) | 0.0032 (10) |
C41 | 0.0277 (12) | 0.0246 (12) | 0.0322 (12) | 0.0060 (9) | −0.0020 (9) | 0.0025 (9) |
C42 | 0.0318 (13) | 0.0374 (14) | 0.0433 (13) | −0.0028 (10) | 0.0049 (10) | −0.0086 (11) |
C43 | 0.0396 (15) | 0.0496 (16) | 0.0485 (15) | −0.0009 (12) | 0.0117 (12) | −0.0034 (12) |
C44 | 0.0524 (17) | 0.0537 (17) | 0.0340 (13) | 0.0093 (13) | 0.0050 (12) | −0.0034 (12) |
C45 | 0.0565 (17) | 0.0503 (17) | 0.0373 (14) | −0.0059 (13) | −0.0046 (12) | −0.0095 (12) |
C46 | 0.0412 (14) | 0.0402 (14) | 0.0386 (13) | −0.0092 (11) | −0.0026 (11) | −0.0019 (11) |
C51 | 0.0313 (12) | 0.0266 (12) | 0.0314 (12) | −0.0017 (9) | −0.0056 (9) | 0.0025 (9) |
C52 | 0.0392 (14) | 0.0335 (13) | 0.0366 (13) | 0.0045 (10) | −0.0066 (10) | 0.0013 (10) |
C53 | 0.0371 (14) | 0.0413 (15) | 0.0518 (15) | 0.0074 (11) | −0.0113 (11) | 0.0038 (12) |
C54 | 0.0501 (18) | 0.071 (2) | 0.0498 (17) | 0.0030 (14) | −0.0197 (13) | 0.0154 (14) |
C55 | 0.0606 (19) | 0.095 (2) | 0.0342 (15) | 0.0061 (17) | −0.0092 (13) | 0.0147 (14) |
C56 | 0.0385 (15) | 0.0673 (19) | 0.0374 (14) | 0.0020 (12) | −0.0021 (11) | 0.0071 (12) |
P11 | 0.0224 (3) | 0.0238 (3) | 0.0277 (3) | −0.0001 (2) | 0.0000 (2) | 0.0015 (2) |
P12 | 0.0217 (3) | 0.0230 (3) | 0.0301 (3) | 0.0007 (2) | 0.0011 (2) | 0.0004 (2) |
O11 | 0.0238 (8) | 0.0254 (8) | 0.0394 (8) | 0.0018 (6) | 0.0009 (6) | 0.0057 (6) |
O12 | 0.0270 (8) | 0.0213 (7) | 0.0410 (9) | 0.0020 (6) | 0.0014 (6) | 0.0004 (6) |
N11 | 0.0213 (9) | 0.0201 (9) | 0.0314 (10) | 0.0012 (7) | 0.0000 (7) | 0.0000 (7) |
N12 | 0.0248 (9) | 0.0217 (9) | 0.0290 (9) | 0.0038 (7) | 0.0032 (7) | 0.0006 (7) |
N13 | 0.0271 (10) | 0.0383 (11) | 0.0274 (10) | −0.0055 (8) | 0.0023 (8) | −0.0006 (8) |
N14 | 0.0276 (10) | 0.0250 (10) | 0.0324 (10) | −0.0046 (8) | 0.0047 (8) | −0.0036 (8) |
N15 | 0.0257 (10) | 0.0299 (11) | 0.0302 (10) | −0.0057 (7) | 0.0006 (8) | 0.0010 (8) |
C111 | 0.0178 (11) | 0.0247 (11) | 0.0390 (13) | 0.0007 (8) | 0.0000 (9) | 0.0008 (9) |
C112 | 0.0284 (12) | 0.0296 (13) | 0.0451 (14) | 0.0045 (9) | −0.0043 (10) | −0.0043 (10) |
C113 | 0.0355 (14) | 0.0324 (14) | 0.0714 (18) | 0.0062 (11) | −0.0059 (12) | −0.0135 (13) |
C114 | 0.0356 (14) | 0.0215 (13) | 0.092 (2) | 0.0035 (10) | 0.0057 (14) | 0.0059 (14) |
C115 | 0.0384 (14) | 0.0342 (15) | 0.0688 (18) | 0.0025 (11) | 0.0093 (12) | 0.0188 (13) |
C116 | 0.0313 (13) | 0.0305 (13) | 0.0469 (14) | 0.0011 (10) | 0.0091 (10) | 0.0069 (10) |
C121 | 0.0250 (11) | 0.0243 (12) | 0.0299 (11) | −0.0062 (8) | −0.0001 (9) | −0.0011 (9) |
C122 | 0.0289 (12) | 0.0387 (14) | 0.0351 (12) | 0.0017 (10) | 0.0043 (10) | 0.0049 (10) |
C123 | 0.0316 (13) | 0.0504 (16) | 0.0419 (14) | −0.0012 (11) | 0.0105 (10) | −0.0005 (12) |
C124 | 0.0436 (15) | 0.0479 (15) | 0.0286 (12) | −0.0145 (12) | 0.0060 (10) | 0.0022 (11) |
C125 | 0.0513 (16) | 0.0321 (14) | 0.0310 (12) | −0.0066 (11) | −0.0033 (11) | 0.0052 (10) |
C126 | 0.0390 (14) | 0.0245 (12) | 0.0339 (12) | 0.0006 (9) | −0.0013 (10) | 0.0002 (9) |
C131 | 0.0358 (13) | 0.0241 (12) | 0.0310 (12) | 0.0029 (9) | −0.0041 (9) | 0.0001 (9) |
C132 | 0.0421 (14) | 0.0346 (14) | 0.0365 (13) | −0.0067 (11) | −0.0038 (11) | −0.0006 (10) |
C133 | 0.0404 (15) | 0.0519 (17) | 0.0579 (17) | −0.0046 (12) | −0.0089 (13) | −0.0176 (13) |
C134 | 0.0557 (18) | 0.0668 (19) | 0.0493 (16) | 0.0148 (14) | −0.0231 (14) | −0.0260 (14) |
C135 | 0.0667 (19) | 0.0588 (18) | 0.0292 (13) | 0.0174 (14) | −0.0086 (12) | −0.0064 (12) |
C136 | 0.0471 (15) | 0.0389 (14) | 0.0329 (12) | 0.0071 (11) | −0.0009 (11) | −0.0003 (10) |
C141 | 0.0312 (13) | 0.0366 (13) | 0.0342 (12) | −0.0014 (10) | 0.0089 (10) | −0.0030 (10) |
C142 | 0.0450 (15) | 0.0375 (14) | 0.0359 (13) | −0.0016 (11) | 0.0076 (11) | −0.0041 (10) |
C143 | 0.072 (2) | 0.0527 (18) | 0.0447 (15) | −0.0124 (14) | 0.0109 (14) | −0.0123 (13) |
C144 | 0.122 (3) | 0.078 (2) | 0.0360 (16) | −0.028 (2) | 0.0170 (17) | −0.0129 (16) |
C145 | 0.142 (3) | 0.068 (2) | 0.0389 (16) | −0.031 (2) | 0.0199 (18) | 0.0012 (15) |
C146 | 0.091 (2) | 0.0434 (16) | 0.0379 (14) | −0.0185 (14) | 0.0134 (14) | −0.0015 (12) |
C151 | 0.0261 (12) | 0.0295 (12) | 0.0302 (11) | 0.0019 (9) | −0.0039 (9) | 0.0017 (9) |
C152 | 0.0394 (14) | 0.0381 (14) | 0.0361 (13) | −0.0116 (10) | −0.0064 (10) | −0.0003 (10) |
C153 | 0.0618 (17) | 0.0493 (16) | 0.0342 (13) | −0.0150 (13) | −0.0050 (12) | −0.0093 (11) |
C154 | 0.0575 (17) | 0.0507 (17) | 0.0294 (13) | −0.0083 (12) | 0.0044 (11) | −0.0056 (11) |
C155 | 0.0389 (14) | 0.0357 (14) | 0.0363 (13) | −0.0035 (10) | 0.0041 (10) | −0.0002 (10) |
C156 | 0.0294 (12) | 0.0286 (12) | 0.0301 (11) | −0.0005 (9) | −0.0013 (9) | −0.0025 (9) |
P1—O1 | 1.4665 (13) | P11—O11 | 1.4775 (13) |
P1—N3 | 1.6374 (17) | P11—N12 | 1.6368 (16) |
P1—N2 | 1.6444 (17) | P11—N13 | 1.6522 (17) |
P1—N1 | 1.6973 (16) | P11—N11 | 1.6888 (16) |
P2—O2 | 1.4787 (13) | P12—O12 | 1.4672 (13) |
P2—N4 | 1.6359 (17) | P12—N14 | 1.6404 (17) |
P2—N5 | 1.6530 (17) | P12—N15 | 1.6451 (17) |
P2—N1 | 1.6866 (15) | P12—N11 | 1.6944 (15) |
N1—C11 | 1.465 (2) | N11—C111 | 1.458 (2) |
N2—C21 | 1.408 (2) | N12—C121 | 1.428 (2) |
N2—H2A | 0.866 (9) | N12—H12B | 0.867 (9) |
N3—C31 | 1.416 (2) | N13—C131 | 1.416 (2) |
N3—H3A | 0.868 (9) | N13—H13B | 0.860 (9) |
N4—C41 | 1.429 (2) | N14—C141 | 1.411 (2) |
N4—H4A | 0.870 (7) | N14—H14B | 0.872 (7) |
N5—C51 | 1.413 (2) | N15—C151 | 1.409 (2) |
N5—H5A | 0.852 (9) | N15—H15B | 0.868 (9) |
C11—C16 | 1.381 (3) | C111—C112 | 1.378 (3) |
C11—C12 | 1.382 (3) | C111—C116 | 1.382 (3) |
C12—C13 | 1.395 (3) | C112—C113 | 1.391 (3) |
C12—H12A | 0.9500 | C112—H11A | 0.9500 |
C13—C14 | 1.374 (3) | C113—C114 | 1.379 (3) |
C13—H13A | 0.9500 | C113—H11B | 0.9500 |
C14—C15 | 1.369 (3) | C114—C115 | 1.383 (3) |
C14—H14A | 0.9500 | C114—H11C | 0.9500 |
C15—C16 | 1.390 (3) | C115—C116 | 1.391 (3) |
C15—H15A | 0.9500 | C115—H11D | 0.9500 |
C16—H16A | 0.9500 | C116—H11E | 0.9500 |
C21—C26 | 1.384 (3) | C121—C122 | 1.389 (3) |
C21—C22 | 1.392 (3) | C121—C126 | 1.390 (2) |
C22—C23 | 1.384 (3) | C122—C123 | 1.387 (3) |
C22—H22A | 0.9500 | C122—H12C | 0.9500 |
C23—C24 | 1.375 (3) | C123—C124 | 1.373 (3) |
C23—H23A | 0.9500 | C123—H12D | 0.9500 |
C24—C25 | 1.378 (3) | C124—C125 | 1.384 (3) |
C24—H24A | 0.9500 | C124—H12E | 0.9500 |
C25—C26 | 1.390 (3) | C125—C126 | 1.385 (3) |
C25—H25A | 0.9500 | C125—H12F | 0.9500 |
C26—H26A | 0.9500 | C126—H12G | 0.9500 |
C31—C36 | 1.372 (3) | C131—C132 | 1.381 (3) |
C31—C32 | 1.382 (3) | C131—C136 | 1.388 (3) |
C32—C33 | 1.383 (3) | C132—C133 | 1.384 (3) |
C32—H32A | 0.9500 | C132—H13C | 0.9500 |
C33—C34 | 1.378 (3) | C133—C134 | 1.369 (3) |
C33—H33A | 0.9500 | C133—H13D | 0.9500 |
C34—C35 | 1.375 (3) | C134—C135 | 1.382 (3) |
C34—H34A | 0.9500 | C134—H13E | 0.9500 |
C35—C36 | 1.382 (3) | C135—C136 | 1.381 (3) |
C35—H35A | 0.9500 | C135—H13F | 0.9500 |
C36—H36A | 0.9500 | C136—H13G | 0.9500 |
C41—C46 | 1.383 (3) | C141—C142 | 1.384 (3) |
C41—C42 | 1.386 (3) | C141—C146 | 1.390 (3) |
C42—C43 | 1.391 (3) | C142—C143 | 1.383 (3) |
C42—H42A | 0.9500 | C142—H14C | 0.9500 |
C43—C44 | 1.372 (3) | C143—C144 | 1.376 (3) |
C43—H43A | 0.9500 | C143—H14D | 0.9500 |
C44—C45 | 1.385 (3) | C144—C145 | 1.372 (3) |
C44—H44A | 0.9500 | C144—H14E | 0.9500 |
C45—C46 | 1.384 (3) | C145—C146 | 1.386 (3) |
C45—H45A | 0.9500 | C145—H14F | 0.9500 |
C46—H46A | 0.9500 | C146—H14G | 0.9500 |
C51—C56 | 1.382 (3) | C151—C156 | 1.388 (3) |
C51—C52 | 1.387 (3) | C151—C152 | 1.391 (3) |
C52—C53 | 1.384 (3) | C152—C153 | 1.378 (3) |
C52—H52A | 0.9500 | C152—H15C | 0.9500 |
C53—C54 | 1.361 (3) | C153—C154 | 1.385 (3) |
C53—H53A | 0.9500 | C153—H15D | 0.9500 |
C54—C55 | 1.382 (3) | C154—C155 | 1.379 (3) |
C54—H54A | 0.9500 | C154—H15E | 0.9500 |
C55—C56 | 1.388 (3) | C155—C156 | 1.382 (3) |
C55—H55A | 0.9500 | C155—H15F | 0.9500 |
C56—H56A | 0.9500 | C156—H15G | 0.9500 |
O1—P1—N3 | 115.53 (8) | O11—P11—N12 | 111.31 (8) |
O1—P1—N2 | 119.30 (8) | O11—P11—N13 | 114.46 (8) |
N3—P1—N2 | 99.38 (9) | N12—P11—N13 | 105.47 (9) |
O1—P1—N1 | 106.74 (8) | O11—P11—N11 | 109.46 (8) |
N3—P1—N1 | 109.51 (8) | N12—P11—N11 | 112.66 (8) |
N2—P1—N1 | 105.77 (8) | N13—P11—N11 | 103.25 (8) |
O2—P2—N4 | 111.96 (8) | O12—P12—N14 | 115.70 (8) |
O2—P2—N5 | 113.91 (8) | O12—P12—N15 | 118.51 (8) |
N4—P2—N5 | 105.21 (9) | N14—P12—N15 | 100.05 (8) |
O2—P2—N1 | 109.23 (8) | O12—P12—N11 | 106.62 (8) |
N4—P2—N1 | 112.16 (8) | N14—P12—N11 | 109.15 (8) |
N5—P2—N1 | 104.13 (8) | N15—P12—N11 | 106.23 (8) |
C11—N1—P2 | 115.72 (12) | C111—N11—P11 | 115.12 (12) |
C11—N1—P1 | 117.66 (12) | C111—N11—P12 | 117.89 (12) |
P2—N1—P1 | 124.05 (9) | P11—N11—P12 | 125.49 (9) |
C21—N2—P1 | 129.45 (14) | C121—N12—P11 | 126.94 (13) |
C21—N2—H2A | 117.5 (13) | C121—N12—H12B | 114.6 (12) |
P1—N2—H2A | 113.1 (13) | P11—N12—H12B | 113.9 (13) |
C31—N3—P1 | 126.02 (14) | C131—N13—P11 | 126.36 (14) |
C31—N3—H3A | 116.2 (13) | C131—N13—H13B | 115.2 (13) |
P1—N3—H3A | 115.0 (13) | P11—N13—H13B | 115.7 (13) |
C41—N4—P2 | 126.54 (13) | C141—N14—P12 | 125.38 (14) |
C41—N4—H4A | 115.3 (12) | C141—N14—H14B | 118.6 (13) |
P2—N4—H4A | 112.6 (13) | P12—N14—H14B | 112.6 (13) |
C51—N5—P2 | 126.47 (14) | C151—N15—P12 | 125.52 (14) |
C51—N5—H5A | 115.9 (14) | C151—N15—H15B | 118.2 (13) |
P2—N5—H5A | 117.5 (13) | P12—N15—H15B | 112.0 (13) |
C16—C11—C12 | 120.9 (2) | C112—C111—C116 | 120.4 (2) |
C16—C11—N1 | 120.11 (18) | C112—C111—N11 | 119.16 (18) |
C12—C11—N1 | 118.93 (18) | C116—C111—N11 | 120.45 (18) |
C11—C12—C13 | 118.9 (2) | C111—C112—C113 | 119.8 (2) |
C11—C12—H12A | 120.5 | C111—C112—H11A | 120.1 |
C13—C12—H12A | 120.5 | C113—C112—H11A | 120.1 |
C14—C13—C12 | 120.1 (2) | C114—C113—C112 | 120.1 (2) |
C14—C13—H13A | 119.9 | C114—C113—H11B | 120.0 |
C12—C13—H13A | 119.9 | C112—C113—H11B | 120.0 |
C15—C14—C13 | 120.5 (2) | C113—C114—C115 | 120.1 (2) |
C15—C14—H14A | 119.7 | C113—C114—H11C | 120.0 |
C13—C14—H14A | 119.7 | C115—C114—H11C | 120.0 |
C14—C15—C16 | 120.3 (2) | C114—C115—C116 | 119.9 (2) |
C14—C15—H15A | 119.8 | C114—C115—H11D | 120.1 |
C16—C15—H15A | 119.8 | C116—C115—H11D | 120.1 |
C11—C16—C15 | 119.2 (2) | C111—C116—C115 | 119.8 (2) |
C11—C16—H16A | 120.4 | C111—C116—H11E | 120.1 |
C15—C16—H16A | 120.4 | C115—C116—H11E | 120.1 |
C26—C21—C22 | 119.5 (2) | C122—C121—C126 | 119.29 (19) |
C26—C21—N2 | 122.08 (19) | C122—C121—N12 | 122.61 (18) |
C22—C21—N2 | 118.5 (2) | C126—C121—N12 | 118.06 (18) |
C23—C22—C21 | 119.8 (2) | C123—C122—C121 | 119.2 (2) |
C23—C22—H22A | 120.1 | C123—C122—H12C | 120.4 |
C21—C22—H22A | 120.1 | C121—C122—H12C | 120.4 |
C24—C23—C22 | 121.0 (2) | C124—C123—C122 | 121.7 (2) |
C24—C23—H23A | 119.5 | C124—C123—H12D | 119.2 |
C22—C23—H23A | 119.5 | C122—C123—H12D | 119.2 |
C23—C24—C25 | 119.2 (2) | C123—C124—C125 | 119.1 (2) |
C23—C24—H24A | 120.4 | C123—C124—H12E | 120.4 |
C25—C24—H24A | 120.4 | C125—C124—H12E | 120.4 |
C24—C25—C26 | 120.7 (2) | C124—C125—C126 | 120.0 (2) |
C24—C25—H25A | 119.6 | C124—C125—H12F | 120.0 |
C26—C25—H25A | 119.6 | C126—C125—H12F | 120.0 |
C21—C26—C25 | 119.8 (2) | C125—C126—C121 | 120.7 (2) |
C21—C26—H26A | 120.1 | C125—C126—H12G | 119.7 |
C25—C26—H26A | 120.1 | C121—C126—H12G | 119.7 |
C36—C31—C32 | 119.5 (2) | C132—C131—C136 | 119.7 (2) |
C36—C31—N3 | 122.46 (19) | C132—C131—N13 | 121.90 (19) |
C32—C31—N3 | 118.01 (19) | C136—C131—N13 | 118.37 (19) |
C31—C32—C33 | 119.8 (2) | C131—C132—C133 | 119.5 (2) |
C31—C32—H32A | 120.1 | C131—C132—H13C | 120.3 |
C33—C32—H32A | 120.1 | C133—C132—H13C | 120.3 |
C34—C33—C32 | 120.9 (2) | C134—C133—C132 | 121.3 (2) |
C34—C33—H33A | 119.5 | C134—C133—H13D | 119.4 |
C32—C33—H33A | 119.5 | C132—C133—H13D | 119.4 |
C35—C34—C33 | 118.7 (2) | C133—C134—C135 | 119.1 (2) |
C35—C34—H34A | 120.6 | C133—C134—H13E | 120.5 |
C33—C34—H34A | 120.6 | C135—C134—H13E | 120.5 |
C34—C35—C36 | 120.8 (2) | C136—C135—C134 | 120.6 (2) |
C34—C35—H35A | 119.6 | C136—C135—H13F | 119.7 |
C36—C35—H35A | 119.6 | C134—C135—H13F | 119.7 |
C31—C36—C35 | 120.3 (2) | C135—C136—C131 | 119.8 (2) |
C31—C36—H36A | 119.9 | C135—C136—H13G | 120.1 |
C35—C36—H36A | 119.9 | C131—C136—H13G | 120.1 |
C46—C41—C42 | 119.5 (2) | C142—C141—C146 | 119.1 (2) |
C46—C41—N4 | 118.55 (19) | C142—C141—N14 | 122.70 (19) |
C42—C41—N4 | 121.95 (18) | C146—C141—N14 | 118.2 (2) |
C41—C42—C43 | 119.4 (2) | C143—C142—C141 | 120.1 (2) |
C41—C42—H42A | 120.3 | C143—C142—H14C | 119.9 |
C43—C42—H42A | 120.3 | C141—C142—H14C | 119.9 |
C44—C43—C42 | 121.5 (2) | C144—C143—C142 | 120.9 (2) |
C44—C43—H43A | 119.3 | C144—C143—H14D | 119.6 |
C42—C43—H43A | 119.3 | C142—C143—H14D | 119.6 |
C43—C44—C45 | 118.6 (2) | C145—C144—C143 | 119.1 (3) |
C43—C44—H44A | 120.7 | C145—C144—H14E | 120.4 |
C45—C44—H44A | 120.7 | C143—C144—H14E | 120.4 |
C46—C45—C44 | 120.8 (2) | C144—C145—C146 | 120.9 (3) |
C46—C45—H45A | 119.6 | C144—C145—H14F | 119.6 |
C44—C45—H45A | 119.6 | C146—C145—H14F | 119.6 |
C41—C46—C45 | 120.2 (2) | C145—C146—C141 | 119.9 (2) |
C41—C46—H46A | 119.9 | C145—C146—H14G | 120.0 |
C45—C46—H46A | 119.9 | C141—C146—H14G | 120.0 |
C56—C51—C52 | 119.3 (2) | C156—C151—C152 | 119.05 (19) |
C56—C51—N5 | 118.84 (19) | C156—C151—N15 | 121.27 (18) |
C52—C51—N5 | 121.86 (19) | C152—C151—N15 | 119.66 (19) |
C53—C52—C51 | 119.6 (2) | C153—C152—C151 | 120.1 (2) |
C53—C52—H52A | 120.2 | C153—C152—H15C | 119.9 |
C51—C52—H52A | 120.2 | C151—C152—H15C | 119.9 |
C54—C53—C52 | 121.5 (2) | C152—C153—C154 | 120.8 (2) |
C54—C53—H53A | 119.3 | C152—C153—H15D | 119.6 |
C52—C53—H53A | 119.3 | C154—C153—H15D | 119.6 |
C53—C54—C55 | 119.1 (2) | C155—C154—C153 | 119.0 (2) |
C53—C54—H54A | 120.4 | C155—C154—H15E | 120.5 |
C55—C54—H54A | 120.4 | C153—C154—H15E | 120.5 |
C54—C55—C56 | 120.4 (2) | C154—C155—C156 | 120.8 (2) |
C54—C55—H55A | 119.8 | C154—C155—H15F | 119.6 |
C56—C55—H55A | 119.8 | C156—C155—H15F | 119.6 |
C51—C56—C55 | 120.1 (2) | C155—C156—C151 | 120.22 (19) |
C51—C56—H56A | 120.0 | C155—C156—H15G | 119.9 |
C55—C56—H56A | 120.0 | C151—C156—H15G | 119.9 |
O2—P2—N1—C11 | 21.87 (16) | O11—P11—N11—C111 | −23.10 (15) |
N4—P2—N1—C11 | 146.60 (13) | N12—P11—N11—C111 | −147.51 (13) |
N5—P2—N1—C11 | −100.16 (14) | N13—P11—N11—C111 | 99.21 (14) |
O2—P2—N1—P1 | −176.79 (9) | O11—P11—N11—P12 | 171.23 (10) |
N4—P2—N1—P1 | −52.06 (13) | N12—P11—N11—P12 | 46.82 (13) |
N5—P2—N1—P1 | 61.18 (12) | N13—P11—N11—P12 | −66.47 (12) |
O1—P1—N1—C11 | 178.04 (13) | O12—P12—N11—C111 | −176.42 (13) |
N3—P1—N1—C11 | 52.30 (16) | N14—P12—N11—C111 | −50.77 (15) |
N2—P1—N1—C11 | −53.94 (16) | N15—P12—N11—C111 | 56.30 (15) |
O1—P1—N1—P2 | 17.03 (13) | O12—P12—N11—P11 | −11.10 (13) |
N3—P1—N1—P2 | −108.70 (11) | N14—P12—N11—P11 | 114.55 (11) |
N2—P1—N1—P2 | 145.06 (11) | N15—P12—N11—P11 | −138.39 (11) |
O1—P1—N2—C21 | 55.5 (2) | O11—P11—N12—C121 | −37.91 (18) |
N3—P1—N2—C21 | −178.12 (18) | N13—P11—N12—C121 | −162.60 (16) |
N1—P1—N2—C21 | −64.6 (2) | N11—P11—N12—C121 | 85.48 (17) |
O1—P1—N3—C31 | −42.3 (2) | O11—P11—N13—C131 | −34.9 (2) |
N2—P1—N3—C31 | −171.27 (17) | N12—P11—N13—C131 | 87.78 (18) |
N1—P1—N3—C31 | 78.20 (18) | N11—P11—N13—C131 | −153.80 (16) |
O2—P2—N4—C41 | 41.43 (18) | O12—P12—N14—C141 | 47.0 (2) |
N5—P2—N4—C41 | 165.65 (16) | N15—P12—N14—C141 | 175.52 (17) |
N1—P2—N4—C41 | −81.78 (17) | N11—P12—N14—C141 | −73.25 (18) |
O2—P2—N5—C51 | 44.7 (2) | O12—P12—N15—C151 | −66.66 (19) |
N4—P2—N5—C51 | −78.24 (18) | N14—P12—N15—C151 | 166.65 (17) |
N1—P2—N5—C51 | 163.63 (16) | N11—P12—N15—C151 | 53.16 (18) |
P2—N1—C11—C16 | 70.9 (2) | P11—N11—C111—C112 | 103.13 (18) |
P1—N1—C11—C16 | −91.6 (2) | P12—N11—C111—C112 | −90.05 (19) |
P2—N1—C11—C12 | −107.44 (17) | P11—N11—C111—C116 | −75.1 (2) |
P1—N1—C11—C12 | 89.97 (19) | P12—N11—C111—C116 | 91.74 (19) |
C16—C11—C12—C13 | 0.1 (3) | C116—C111—C112—C113 | 0.3 (3) |
N1—C11—C12—C13 | 178.48 (18) | N11—C111—C112—C113 | −177.92 (18) |
C11—C12—C13—C14 | −0.7 (3) | C111—C112—C113—C114 | 0.2 (3) |
C12—C13—C14—C15 | 0.2 (4) | C112—C113—C114—C115 | −0.1 (3) |
C13—C14—C15—C16 | 1.0 (4) | C113—C114—C115—C116 | −0.5 (3) |
C12—C11—C16—C15 | 1.0 (3) | C112—C111—C116—C115 | −0.9 (3) |
N1—C11—C16—C15 | −177.35 (18) | N11—C111—C116—C115 | 177.32 (18) |
C14—C15—C16—C11 | −1.5 (3) | C114—C115—C116—C111 | 1.0 (3) |
P1—N2—C21—C26 | 4.7 (3) | P11—N12—C121—C122 | 32.5 (3) |
P1—N2—C21—C22 | −174.80 (16) | P11—N12—C121—C126 | −149.86 (15) |
C26—C21—C22—C23 | −0.3 (3) | C126—C121—C122—C123 | 0.9 (3) |
N2—C21—C22—C23 | 179.2 (2) | N12—C121—C122—C123 | 178.54 (18) |
C21—C22—C23—C24 | 0.4 (4) | C121—C122—C123—C124 | −1.1 (3) |
C22—C23—C24—C25 | 0.0 (4) | C122—C123—C124—C125 | 0.3 (3) |
C23—C24—C25—C26 | −0.5 (4) | C123—C124—C125—C126 | 0.8 (3) |
C22—C21—C26—C25 | −0.2 (3) | C124—C125—C126—C121 | −0.9 (3) |
N2—C21—C26—C25 | −179.7 (2) | C122—C121—C126—C125 | 0.1 (3) |
C24—C25—C26—C21 | 0.7 (4) | N12—C121—C126—C125 | −177.63 (18) |
P1—N3—C31—C36 | 43.0 (3) | P11—N13—C131—C132 | −25.2 (3) |
P1—N3—C31—C32 | −138.28 (19) | P11—N13—C131—C136 | 153.17 (16) |
C36—C31—C32—C33 | 0.8 (4) | C136—C131—C132—C133 | 0.7 (3) |
N3—C31—C32—C33 | −178.0 (2) | N13—C131—C132—C133 | 179.1 (2) |
C31—C32—C33—C34 | 0.0 (4) | C131—C132—C133—C134 | 0.0 (4) |
C32—C33—C34—C35 | −0.5 (5) | C132—C133—C134—C135 | −0.4 (4) |
C33—C34—C35—C36 | 0.3 (4) | C133—C134—C135—C136 | −0.1 (4) |
C32—C31—C36—C35 | −0.9 (3) | C134—C135—C136—C131 | 0.9 (3) |
N3—C31—C36—C35 | 177.75 (19) | C132—C131—C136—C135 | −1.2 (3) |
C34—C35—C36—C31 | 0.4 (4) | N13—C131—C136—C135 | −179.58 (19) |
P2—N4—C41—C46 | 140.39 (17) | P12—N14—C141—C142 | −33.7 (3) |
P2—N4—C41—C42 | −42.1 (3) | P12—N14—C141—C146 | 147.07 (19) |
C46—C41—C42—C43 | −2.3 (3) | C146—C141—C142—C143 | −2.0 (3) |
N4—C41—C42—C43 | −179.86 (19) | N14—C141—C142—C143 | 178.8 (2) |
C41—C42—C43—C44 | 1.8 (3) | C141—C142—C143—C144 | 0.6 (4) |
C42—C43—C44—C45 | 0.2 (4) | C142—C143—C144—C145 | 1.4 (5) |
C43—C44—C45—C46 | −1.7 (4) | C143—C144—C145—C146 | −1.9 (5) |
C42—C41—C46—C45 | 0.9 (3) | C144—C145—C146—C141 | 0.5 (5) |
N4—C41—C46—C45 | 178.47 (19) | C142—C141—C146—C145 | 1.5 (4) |
C44—C45—C46—C41 | 1.2 (4) | N14—C141—C146—C145 | −179.3 (2) |
P2—N5—C51—C56 | −165.66 (17) | P12—N15—C151—C156 | 19.9 (3) |
P2—N5—C51—C52 | 12.6 (3) | P12—N15—C151—C152 | −158.11 (16) |
C56—C51—C52—C53 | −1.1 (3) | C156—C151—C152—C153 | −1.0 (3) |
N5—C51—C52—C53 | −179.32 (19) | N15—C151—C152—C153 | 177.1 (2) |
C51—C52—C53—C54 | 0.1 (3) | C151—C152—C153—C154 | 0.3 (4) |
C52—C53—C54—C55 | 0.4 (4) | C152—C153—C154—C155 | 0.2 (4) |
C53—C54—C55—C56 | 0.1 (4) | C153—C154—C155—C156 | −0.2 (3) |
C52—C51—C56—C55 | 1.6 (3) | C154—C155—C156—C151 | −0.5 (3) |
N5—C51—C56—C55 | 179.9 (2) | C152—C151—C156—C155 | 1.0 (3) |
C54—C55—C56—C51 | −1.1 (4) | N15—C151—C156—C155 | −176.99 (18) |
D—H···A | D—H | H···A | D···A | D—H···A |
N2—H2A···O11 | 0.87 (1) | 2.39 (1) | 3.117 (2) | 142 (2) |
N3—H3A···O11 | 0.87 (1) | 1.91 (1) | 2.769 (2) | 169 (2) |
N4—H4A···O12i | 0.87 (1) | 2.22 (1) | 3.032 (2) | 155 (2) |
N4—H4A···O1 | 0.87 (1) | 2.46 (2) | 2.959 (2) | 118 (2) |
N5—H5A | 0.85 (1) | |||
N12—H12B···O1ii | 0.87 (1) | 2.22 (1) | 3.044 (2) | 158 (2) |
N12—H12B···O12 | 0.87 (1) | 2.47 (2) | 2.963 (2) | 117 (2) |
N13—H13B | 0.86 (1) | |||
N14—H14B···O2iii | 0.87 (1) | 2.00 (1) | 2.856 (2) | 166 (2) |
N15—H15B···O2iii | 0.87 (1) | 2.14 (1) | 2.962 (2) | 158 (2) |
Symmetry codes: (i) −x+3/2, y+1/2, z; (ii) −x+3/2, y−1/2, z; (iii) x+1/2, y, −z+3/2. |
Experimental details
Crystal data | |
Chemical formula | C30H29N5O2P2 |
Mr | 553.52 |
Crystal system, space group | Orthorhombic, Pbca |
Temperature (K) | 150 |
a, b, c (Å) | 24.5585 (11), 18.5726 (8), 25.2655 (11) |
V (Å3) | 11524.0 (9) |
Z | 16 |
Radiation type | Cu Kα |
µ (mm−1) | 1.66 |
Crystal size (mm) | 0.25 × 0.15 × 0.03 |
Data collection | |
Diffractometer | Bruker SMART 6000 |
Absorption correction | Multi-scan (SADABS; Sheldrick, 1996) |
Tmin, Tmax | 0.758, 0.949 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 139703, 11291, 7252 |
Rint | 0.046 |
(sin θ/λ)max (Å−1) | 0.617 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.039, 0.089, 1.02 |
No. of reflections | 11291 |
No. of parameters | 728 |
No. of restraints | 10 |
H-atom treatment | H atoms treated by a mixture of independent and constrained refinement |
Δρmax, Δρmin (e Å−3) | 0.39, −0.36 |
Computer programs: APEX2 (Bruker, 2004), SAINT (Bruker, 2004), SHELXS97 (Sheldrick, 1997), SHELXL97 (Sheldrick, 1997), SHELXTL (Bruker, 1997), UdMX (local program).
P1—O1 | 1.4665 (13) | P11—O11 | 1.4775 (13) |
P1—N3 | 1.6374 (17) | P11—N12 | 1.6368 (16) |
P1—N2 | 1.6444 (17) | P11—N13 | 1.6522 (17) |
P1—N1 | 1.6973 (16) | P11—N11 | 1.6888 (16) |
P2—O2 | 1.4787 (13) | P12—O12 | 1.4672 (13) |
P2—N4 | 1.6359 (17) | P12—N14 | 1.6404 (17) |
P2—N5 | 1.6530 (17) | P12—N15 | 1.6451 (17) |
P2—N1 | 1.6866 (15) | P12—N11 | 1.6944 (15) |
O1—P1—N3 | 115.53 (8) | O11—P11—N12 | 111.31 (8) |
O1—P1—N2 | 119.30 (8) | O11—P11—N13 | 114.46 (8) |
N3—P1—N2 | 99.38 (9) | N12—P11—N13 | 105.47 (9) |
O1—P1—N1 | 106.74 (8) | O11—P11—N11 | 109.46 (8) |
N3—P1—N1 | 109.51 (8) | N12—P11—N11 | 112.66 (8) |
N2—P1—N1 | 105.77 (8) | N13—P11—N11 | 103.25 (8) |
O2—P2—N4 | 111.96 (8) | O12—P12—N14 | 115.70 (8) |
O2—P2—N5 | 113.91 (8) | O12—P12—N15 | 118.51 (8) |
N4—P2—N5 | 105.21 (9) | N14—P12—N15 | 100.05 (8) |
O2—P2—N1 | 109.23 (8) | O12—P12—N11 | 106.62 (8) |
N4—P2—N1 | 112.16 (8) | N14—P12—N11 | 109.15 (8) |
N5—P2—N1 | 104.13 (8) | N15—P12—N11 | 106.23 (8) |
P2—N1—P1 | 124.05 (9) | P11—N11—P12 | 125.49 (9) |
D—H···A | D—H | H···A | D···A | D—H···A |
N2—H2A···O11 | 0.866 (9) | 2.386 (14) | 3.117 (2) | 142.4 (17) |
N3—H3A···O11 | 0.868 (9) | 1.911 (10) | 2.769 (2) | 169.2 (18) |
N4—H4A···O12i | 0.870 (7) | 2.220 (10) | 3.032 (2) | 155.3 (17) |
N4—H4A···O1 | 0.870 (7) | 2.455 (17) | 2.959 (2) | 117.5 (15) |
N12—H12B···O1ii | 0.867 (9) | 2.221 (11) | 3.044 (2) | 158.4 (17) |
N12—H12B···O12 | 0.867 (9) | 2.471 (18) | 2.963 (2) | 116.6 (15) |
N14—H14B···O2iii | 0.872 (7) | 2.002 (8) | 2.856 (2) | 166.0 (18) |
N15—H15B···O2iii | 0.868 (9) | 2.138 (11) | 2.962 (2) | 158.4 (18) |
Symmetry codes: (i) −x+3/2, y+1/2, z; (ii) −x+3/2, y−1/2, z; (iii) x+1/2, y, −z+3/2. |
The packing along the a-b plane is dominated by hydrogen-bonding interactions. Both crystallographically different molecules show the same interactions. There is one amine which forms an intramolecular hydrogen bond and one intermolecular hydrogen bond; two amines with only one intermolecular interaction, and lastly one that has no intermolecular interactions. Every oxygen atom is implicated in two hydrogen-bonding interactions.
Along the A axis, the intermolecular hydrogen bonds are formed by alternating nitrogen and oxygen atoms, two per molecule. Along the B axis, the interactions zigzag through two nitrogen atoms on one molecule forming an H bond to one oxygen atom on the other molecule. Along the C axis, only weak van der Waals forces can be seen between the aromatic rings, with no π stacking interactions visible.