Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806009457/hk2009sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806009457/hk2009Isup2.hkl |
CCDC reference: 296294
Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 1999); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: SHELXL97, enCIFer (Allen et al., 2004) and PLATON (Spek, 2003).
[Sn(C12H10N3O2)Cl2(C6H5)]·CH2Cl2 | F(000) = 572 |
Mr = 579.85 | Dx = 1.686 Mg m−3 |
Monoclinic, P21 | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: P 2yb | Cell parameters from 5481 reflections |
a = 9.116 (2) Å | θ = 2.4–30.8° |
b = 12.050 (3) Å | µ = 1.61 mm−1 |
c = 11.113 (3) Å | T = 291 K |
β = 110.71 (3)° | Prism, orange |
V = 1141.9 (5) Å3 | 0.38 × 0.12 × 0.05 mm |
Z = 2 |
Bruker SMART APEX CCD area-detector diffractometer | 3998 independent reflections |
Radiation source: fine-focus sealed tube | 3737 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.032 |
Detector resolution: 0.66 pixels mm-1 | θmax = 25.0°, θmin = 2.4° |
ω scans | h = −10→10 |
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) | k = −14→14 |
Tmin = 0.705, Tmax = 0.927 | l = −13→13 |
9381 measured reflections |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.037 | H-atom parameters constrained |
wR(F2) = 0.079 | w = 1/[σ2(Fo2) + (0.0412P)2] where P = (Fo2 + 2Fc2)/3 |
S = 1.05 | (Δ/σ)max = 0.001 |
3998 reflections | Δρmax = 0.75 e Å−3 |
357 parameters | Δρmin = −0.31 e Å−3 |
199 restraints | Absolute structure: Flack (1983), 1888 Friedel Pairs |
Primary atom site location: structure-invariant direct methods | Absolute structure parameter: 0.01 (3) |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Sn1 | 0.87980 (3) | −0.01074 (5) | 0.94865 (3) | 0.03986 (11) | |
Cl1 | 0.92902 (18) | 0.09711 (14) | 0.78042 (14) | 0.0596 (4) | |
Cl2 | 0.77902 (18) | −0.11516 (15) | 1.09331 (17) | 0.0648 (4) | |
O1 | 0.7961 (4) | −0.1393 (3) | 0.8141 (4) | 0.0514 (10) | |
N1 | 0.8171 (5) | 0.1420 (3) | 1.0330 (4) | 0.0402 (10) | |
N2 | 0.6334 (5) | 0.0243 (3) | 0.8450 (4) | 0.0414 (11) | |
N3 | 0.5556 (5) | −0.0481 (3) | 0.7486 (4) | 0.0457 (11) | |
C2 | 0.6670 (6) | 0.1765 (4) | 0.9818 (5) | 0.0408 (12) | |
C3 | 0.6141 (7) | 0.2638 (5) | 1.0345 (6) | 0.0530 (15) | |
H3 | 0.5100 | 0.2862 | 0.9991 | 0.064* | |
C4 | 0.7154 (8) | 0.3178 (6) | 1.1394 (6) | 0.0601 (16) | |
H4 | 0.6799 | 0.3762 | 1.1766 | 0.072* | |
C5 | 0.8687 (8) | 0.2856 (5) | 1.1891 (6) | 0.0586 (16) | |
H5 | 0.9400 | 0.3229 | 1.2586 | 0.070* | |
C6 | 0.9150 (7) | 0.1964 (5) | 1.1336 (6) | 0.0510 (14) | |
H6 | 1.0189 | 0.1732 | 1.1679 | 0.061* | |
C7 | 0.5668 (6) | 0.1100 (4) | 0.8711 (5) | 0.0432 (12) | |
C8 | 0.6505 (6) | −0.1300 (5) | 0.7441 (5) | 0.0472 (13) | |
C9 | 0.5810 (7) | −0.2171 (5) | 0.6505 (5) | 0.0531 (14) | |
C10 | 0.4347 (14) | −0.2393 (12) | 0.5694 (14) | 0.067 (2) | 0.737 (15) |
H10 | 0.3449 | −0.1974 | 0.5571 | 0.080* | 0.737 (15) |
C11 | 0.4454 (13) | −0.3392 (9) | 0.5069 (11) | 0.068 (3) | 0.737 (15) |
H11 | 0.3627 | −0.3765 | 0.4463 | 0.082* | 0.737 (15) |
C12 | 0.5931 (14) | −0.3702 (8) | 0.5497 (9) | 0.067 (2) | 0.737 (15) |
H12 | 0.6311 | −0.4333 | 0.5224 | 0.080* | 0.737 (15) |
O2 | 0.6833 (9) | −0.2973 (6) | 0.6396 (8) | 0.065 (2) | 0.737 (15) |
C10A | 0.640 (3) | −0.303 (3) | 0.603 (4) | 0.065 (4) | 0.263 (15) |
H10A | 0.7443 | −0.3230 | 0.6251 | 0.079* | 0.263 (15) |
C11A | 0.508 (4) | −0.356 (3) | 0.514 (3) | 0.067 (4) | 0.263 (15) |
H11A | 0.5089 | −0.4189 | 0.4653 | 0.081* | 0.263 (15) |
C12A | 0.384 (3) | −0.301 (2) | 0.513 (3) | 0.066 (4) | 0.263 (15) |
H12A | 0.2816 | −0.3216 | 0.4649 | 0.080* | 0.263 (15) |
O2A | 0.4207 (16) | −0.209 (2) | 0.592 (3) | 0.068 (4) | 0.263 (15) |
C13 | 0.3997 (6) | 0.1401 (6) | 0.7999 (6) | 0.0601 (16) | |
H13A | 0.3516 | 0.0843 | 0.7366 | 0.090* | |
H13B | 0.3951 | 0.2104 | 0.7581 | 0.090* | |
H13C | 0.3448 | 0.1451 | 0.8593 | 0.090* | |
C14 | 1.1209 (5) | −0.0279 (8) | 1.0668 (4) | 0.041 (2) | |
C15 | 1.2280 (6) | 0.0482 (5) | 1.0582 (6) | 0.0567 (15) | |
H15 | 1.1970 | 0.1070 | 1.0005 | 0.068* | |
C16 | 1.3848 (8) | 0.0361 (6) | 1.1376 (7) | 0.0644 (19) | |
H16 | 1.4595 | 0.0865 | 1.1323 | 0.077* | |
C17 | 1.4275 (8) | −0.0480 (7) | 1.2212 (7) | 0.073 (2) | |
H17 | 1.5323 | −0.0543 | 1.2738 | 0.088* | |
C18 | 1.3233 (8) | −0.1251 (6) | 1.2325 (6) | 0.0684 (18) | |
H18 | 1.3563 | −0.1833 | 1.2910 | 0.082* | |
C19 | 1.1677 (6) | −0.1146 (5) | 1.1550 (5) | 0.0480 (13) | |
H19 | 1.0941 | −0.1655 | 1.1616 | 0.058* | |
C20 | 0.9026 (15) | 0.9855 (18) | 0.442 (4) | 0.213 (4) | 0.544 (8) |
H20A | 0.8608 | 1.0466 | 0.4765 | 0.256* | 0.544 (8) |
H20B | 0.8691 | 0.9957 | 0.3493 | 0.256* | 0.544 (8) |
Cl3 | 0.8251 (9) | 0.8621 (8) | 0.4732 (7) | 0.177 (4) | 0.544 (8) |
Cl4 | 1.1060 (9) | 0.9898 (15) | 0.5063 (10) | 0.216 (4) | 0.544 (8) |
C20A | 1.017 (11) | 0.959 (4) | 0.519 (5) | 0.214 (5) | 0.158 (8) |
H20C | 1.1246 | 0.9845 | 0.5453 | 0.256* | 0.158 (8) |
H20D | 0.9891 | 0.9524 | 0.5949 | 0.256* | 0.158 (8) |
Cl3A | 1.003 (4) | 0.829 (3) | 0.447 (3) | 0.198 (6) | 0.158 (8) |
Cl4A | 0.895 (4) | 1.058 (3) | 0.416 (4) | 0.233 (6) | 0.158 (8) |
C20B | 1.070 (4) | 0.906 (2) | 0.452 (7) | 0.212 (5) | 0.297 (8) |
H20E | 1.0992 | 0.8913 | 0.3769 | 0.255* | 0.297 (8) |
H20F | 1.1626 | 0.8925 | 0.5276 | 0.255* | 0.297 (8) |
Cl3B | 0.925 (3) | 0.8122 (15) | 0.4515 (16) | 0.193 (5) | 0.297 (8) |
Cl4B | 1.016 (3) | 1.0443 (17) | 0.450 (2) | 0.229 (5) | 0.297 (8) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Sn1 | 0.03222 (16) | 0.03810 (16) | 0.04678 (18) | 0.0015 (2) | 0.01091 (12) | 0.0002 (2) |
Cl1 | 0.0620 (9) | 0.0646 (9) | 0.0543 (8) | 0.0054 (8) | 0.0231 (7) | 0.0113 (8) |
Cl2 | 0.0463 (8) | 0.0727 (10) | 0.0742 (10) | −0.0109 (8) | 0.0201 (8) | 0.0195 (9) |
O1 | 0.045 (2) | 0.040 (2) | 0.063 (2) | −0.0008 (17) | 0.0099 (19) | −0.0165 (18) |
N1 | 0.038 (3) | 0.037 (2) | 0.046 (3) | 0.0023 (19) | 0.016 (2) | −0.004 (2) |
N2 | 0.034 (2) | 0.045 (3) | 0.042 (2) | 0.0006 (18) | 0.0098 (19) | −0.0025 (19) |
N3 | 0.041 (2) | 0.048 (3) | 0.046 (2) | −0.0020 (19) | 0.012 (2) | −0.0065 (19) |
C2 | 0.039 (3) | 0.037 (3) | 0.048 (3) | 0.006 (2) | 0.017 (2) | 0.005 (2) |
C3 | 0.047 (3) | 0.054 (4) | 0.061 (4) | 0.003 (3) | 0.023 (3) | 0.003 (3) |
C4 | 0.062 (4) | 0.061 (4) | 0.063 (4) | 0.003 (3) | 0.030 (3) | −0.014 (3) |
C5 | 0.062 (4) | 0.059 (4) | 0.057 (4) | −0.011 (3) | 0.024 (3) | −0.016 (3) |
C6 | 0.044 (3) | 0.050 (3) | 0.062 (4) | −0.010 (3) | 0.021 (3) | −0.010 (3) |
C7 | 0.037 (3) | 0.045 (3) | 0.047 (3) | 0.006 (2) | 0.014 (2) | 0.006 (3) |
C8 | 0.044 (3) | 0.047 (3) | 0.048 (3) | −0.006 (3) | 0.012 (3) | −0.007 (3) |
C9 | 0.059 (4) | 0.049 (3) | 0.045 (3) | −0.007 (3) | 0.012 (3) | −0.004 (3) |
C10 | 0.076 (5) | 0.056 (6) | 0.049 (6) | −0.010 (4) | −0.001 (4) | −0.023 (4) |
C11 | 0.083 (5) | 0.055 (5) | 0.049 (4) | −0.006 (4) | 0.003 (4) | −0.018 (4) |
C12 | 0.085 (5) | 0.056 (4) | 0.050 (4) | −0.001 (4) | 0.011 (4) | −0.012 (3) |
O2 | 0.073 (4) | 0.055 (3) | 0.058 (5) | 0.001 (3) | 0.012 (3) | −0.016 (3) |
C10A | 0.079 (6) | 0.056 (6) | 0.049 (7) | −0.003 (6) | 0.006 (6) | −0.019 (6) |
C11A | 0.082 (7) | 0.055 (6) | 0.049 (6) | −0.005 (6) | 0.006 (6) | −0.021 (5) |
C12A | 0.081 (6) | 0.053 (7) | 0.050 (6) | −0.007 (6) | 0.004 (6) | −0.024 (5) |
O2A | 0.080 (7) | 0.053 (8) | 0.053 (8) | −0.014 (6) | 0.001 (6) | −0.028 (6) |
C13 | 0.038 (3) | 0.077 (4) | 0.059 (4) | 0.014 (3) | 0.009 (3) | −0.006 (3) |
C14 | 0.032 (2) | 0.049 (6) | 0.041 (2) | 0.003 (3) | 0.0108 (19) | −0.002 (3) |
C15 | 0.037 (3) | 0.063 (4) | 0.064 (4) | −0.006 (3) | 0.009 (3) | 0.003 (3) |
C16 | 0.043 (4) | 0.080 (5) | 0.074 (5) | −0.021 (3) | 0.025 (3) | −0.010 (4) |
C17 | 0.047 (4) | 0.102 (7) | 0.064 (4) | 0.008 (4) | 0.012 (3) | −0.016 (4) |
C18 | 0.064 (4) | 0.073 (4) | 0.062 (4) | 0.025 (4) | 0.014 (3) | 0.019 (4) |
C19 | 0.043 (3) | 0.047 (3) | 0.053 (3) | 0.008 (3) | 0.016 (3) | 0.007 (3) |
C20 | 0.111 (5) | 0.279 (9) | 0.219 (9) | −0.071 (8) | 0.021 (8) | 0.025 (9) |
Cl3 | 0.108 (5) | 0.281 (8) | 0.116 (4) | −0.045 (5) | 0.007 (4) | 0.050 (5) |
Cl4 | 0.108 (4) | 0.285 (9) | 0.226 (7) | −0.051 (6) | 0.024 (5) | 0.006 (9) |
C20A | 0.112 (6) | 0.284 (9) | 0.218 (9) | −0.063 (8) | 0.024 (7) | 0.016 (8) |
Cl3A | 0.097 (10) | 0.302 (10) | 0.186 (9) | −0.050 (9) | 0.041 (10) | 0.010 (9) |
Cl4A | 0.135 (9) | 0.294 (10) | 0.229 (11) | −0.054 (10) | 0.012 (10) | 0.018 (11) |
C20B | 0.109 (7) | 0.290 (9) | 0.214 (9) | −0.059 (7) | 0.027 (8) | 0.012 (9) |
Cl3B | 0.114 (9) | 0.293 (9) | 0.152 (7) | −0.059 (8) | 0.022 (8) | 0.015 (7) |
Cl4B | 0.127 (7) | 0.289 (9) | 0.228 (9) | −0.054 (8) | 0.011 (8) | 0.022 (9) |
Sn1—O1 | 2.101 (3) | C10A—C11A | 1.41 (2) |
Sn1—C14 | 2.135 (5) | C10A—H10A | 0.9300 |
Sn1—N2 | 2.173 (4) | C11A—C12A | 1.31 (2) |
Sn1—N1 | 2.229 (4) | C11A—H11A | 0.9300 |
Sn1—Cl1 | 2.4451 (16) | C12A—O2A | 1.373 (10) |
Sn1—Cl2 | 2.4611 (16) | C12A—H12A | 0.9300 |
O1—C8 | 1.285 (6) | C13—H13A | 0.9600 |
N1—C6 | 1.330 (7) | C13—H13B | 0.9600 |
N1—C2 | 1.349 (6) | C13—H13C | 0.9600 |
N2—C7 | 1.282 (6) | C14—C15 | 1.367 (9) |
N2—N3 | 1.369 (6) | C14—C19 | 1.393 (9) |
N3—C8 | 1.324 (7) | C15—C16 | 1.397 (9) |
C2—C3 | 1.371 (8) | C15—H15 | 0.9300 |
C2—C7 | 1.482 (7) | C16—C17 | 1.336 (9) |
C3—C4 | 1.369 (9) | C16—H16 | 0.9300 |
C3—H3 | 0.9300 | C17—C18 | 1.366 (10) |
C4—C5 | 1.365 (9) | C17—H17 | 0.9300 |
C4—H4 | 0.9300 | C18—C19 | 1.381 (8) |
C5—C6 | 1.378 (8) | C18—H18 | 0.9300 |
C5—H5 | 0.9300 | C19—H19 | 0.9300 |
C6—H6 | 0.9300 | C20—Cl3 | 1.734 (10) |
C7—C13 | 1.492 (7) | C20—Cl4 | 1.736 (10) |
C8—C9 | 1.456 (8) | C20—H20A | 0.9700 |
C9—C10 | 1.347 (12) | C20—H20B | 0.9700 |
C9—C10A | 1.35 (2) | C20A—Cl3A | 1.746 (10) |
C9—O2A | 1.377 (10) | C20A—Cl4A | 1.747 (10) |
C9—O2 | 1.378 (7) | C20A—H20C | 0.9700 |
C10—C11 | 1.411 (13) | C20A—H20D | 0.9700 |
C10—H10 | 0.9300 | C20B—Cl3B | 1.738 (10) |
C11—C12 | 1.314 (13) | C20B—Cl4B | 1.740 (10) |
C11—H11 | 0.9300 | C20B—H20E | 0.9700 |
C12—O2 | 1.365 (8) | C20B—H20F | 0.9700 |
C12—H12 | 0.9300 | ||
O1—Sn1—C14 | 113.7 (3) | C10—C11—H11 | 126.1 |
O1—Sn1—N2 | 73.67 (15) | C11—C12—O2 | 110.9 (8) |
C14—Sn1—N2 | 172.5 (3) | C11—C12—H12 | 124.5 |
O1—Sn1—N1 | 145.67 (15) | O2—C12—H12 | 124.5 |
C14—Sn1—N1 | 100.5 (3) | C12—O2—C9 | 105.4 (7) |
N2—Sn1—N1 | 72.06 (15) | C9—C10A—C11A | 105.5 (16) |
O1—Sn1—Cl1 | 88.08 (12) | C9—C10A—H10A | 127.3 |
C14—Sn1—Cl1 | 95.42 (17) | C11A—C10A—H10A | 127.3 |
N2—Sn1—Cl1 | 85.76 (12) | C12A—C11A—C10A | 106.8 (17) |
N1—Sn1—Cl1 | 91.52 (12) | C12A—C11A—H11A | 126.6 |
O1—Sn1—Cl2 | 87.84 (12) | C10A—C11A—H11A | 126.6 |
C14—Sn1—Cl2 | 95.15 (17) | C11A—C12A—O2A | 112.9 (17) |
N2—Sn1—Cl2 | 83.74 (12) | C11A—C12A—H12A | 123.6 |
N1—Sn1—Cl2 | 86.38 (14) | O2A—C12A—H12A | 123.6 |
Cl1—Sn1—Cl2 | 169.44 (5) | C12A—O2A—C9 | 103.1 (13) |
C8—O1—Sn1 | 113.8 (3) | C7—C13—H13A | 109.5 |
C6—N1—C2 | 118.8 (5) | C7—C13—H13B | 109.5 |
C6—N1—Sn1 | 124.4 (4) | H13A—C13—H13B | 109.5 |
C2—N1—Sn1 | 116.7 (3) | C7—C13—H13C | 109.5 |
C7—N2—N3 | 122.4 (5) | H13A—C13—H13C | 109.5 |
C7—N2—Sn1 | 121.3 (4) | H13B—C13—H13C | 109.5 |
N3—N2—Sn1 | 116.3 (3) | C15—C14—C19 | 120.3 (5) |
C8—N3—N2 | 109.9 (4) | C15—C14—Sn1 | 119.8 (5) |
N1—C2—C3 | 120.9 (5) | C19—C14—Sn1 | 119.9 (4) |
N1—C2—C7 | 114.8 (4) | C14—C15—C16 | 118.8 (6) |
C3—C2—C7 | 124.3 (5) | C14—C15—H15 | 120.6 |
C4—C3—C2 | 119.7 (6) | C16—C15—H15 | 120.6 |
C4—C3—H3 | 120.2 | C17—C16—C15 | 120.0 (6) |
C2—C3—H3 | 120.2 | C17—C16—H16 | 120.0 |
C5—C4—C3 | 119.7 (6) | C15—C16—H16 | 120.0 |
C5—C4—H4 | 120.2 | C16—C17—C18 | 122.6 (7) |
C3—C4—H4 | 120.2 | C16—C17—H17 | 118.7 |
C4—C5—C6 | 118.2 (6) | C18—C17—H17 | 118.7 |
C4—C5—H5 | 120.9 | C17—C18—C19 | 118.4 (6) |
C6—C5—H5 | 120.9 | C17—C18—H18 | 120.8 |
N1—C6—C5 | 122.7 (6) | C19—C18—H18 | 120.8 |
N1—C6—H6 | 118.7 | C18—C19—C14 | 119.9 (6) |
C5—C6—H6 | 118.7 | C18—C19—H19 | 120.0 |
N2—C7—C2 | 115.0 (5) | C14—C19—H19 | 120.0 |
N2—C7—C13 | 123.5 (5) | Cl3—C20—Cl4 | 113.2 (9) |
C2—C7—C13 | 121.5 (5) | Cl3—C20—H20A | 108.9 |
O1—C8—N3 | 126.3 (5) | Cl4—C20—H20A | 108.9 |
O1—C8—C9 | 117.7 (5) | Cl3—C20—H20B | 108.9 |
N3—C8—C9 | 116.1 (5) | Cl4—C20—H20B | 108.9 |
C10—C9—C10A | 91.2 (13) | H20A—C20—H20B | 107.8 |
C10A—C9—O2A | 111.4 (13) | Cl3A—C20A—Cl4A | 112.8 (10) |
C10—C9—O2 | 110.0 (6) | Cl3A—C20A—H20C | 109.0 |
O2A—C9—O2 | 130.0 (9) | Cl4A—C20A—H20C | 109.0 |
C10—C9—C8 | 134.4 (8) | Cl3A—C20A—H20D | 109.0 |
C10A—C9—C8 | 134.3 (13) | Cl4A—C20A—H20D | 109.0 |
O2A—C9—C8 | 114.2 (9) | H20C—C20A—H20D | 107.8 |
O2—C9—C8 | 115.6 (6) | Cl3B—C20B—Cl4B | 114.2 (9) |
C9—C10—C11 | 105.9 (9) | Cl3B—C20B—H20E | 108.7 |
C9—C10—H10 | 127.0 | Cl4B—C20B—H20E | 108.7 |
C11—C10—H10 | 127.0 | Cl3B—C20B—H20F | 108.7 |
C12—C11—C10 | 107.8 (8) | Cl4B—C20B—H20F | 108.7 |
C12—C11—H11 | 126.1 | H20E—C20B—H20F | 107.6 |
C14—Sn1—O1—C8 | 179.1 (4) | N2—N3—C8—C9 | 176.7 (5) |
N2—Sn1—O1—C8 | 0.3 (4) | O1—C8—C9—C10 | 174.5 (12) |
N1—Sn1—O1—C8 | 4.0 (5) | N3—C8—C9—C10 | −5.3 (14) |
Cl1—Sn1—O1—C8 | −85.8 (4) | O1—C8—C9—C10A | −12 (3) |
Cl2—Sn1—O1—C8 | 84.4 (4) | N3—C8—C9—C10A | 169 (3) |
O1—Sn1—N1—C6 | 173.1 (4) | O1—C8—C9—O2A | 171.5 (18) |
C14—Sn1—N1—C6 | −2.3 (5) | N3—C8—C9—O2A | −8.3 (19) |
N2—Sn1—N1—C6 | 176.9 (5) | O1—C8—C9—O2 | −5.0 (9) |
Cl1—Sn1—N1—C6 | −98.1 (4) | N3—C8—C9—O2 | 175.2 (6) |
Cl2—Sn1—N1—C6 | 92.3 (4) | C10A—C9—C10—C11 | 6 (3) |
O1—Sn1—N1—C2 | −3.0 (5) | O2A—C9—C10—C11 | −170 (7) |
C14—Sn1—N1—C2 | −178.4 (4) | O2—C9—C10—C11 | 1.3 (15) |
N2—Sn1—N1—C2 | 0.7 (4) | C8—C9—C10—C11 | −178.2 (8) |
Cl1—Sn1—N1—C2 | 85.8 (4) | C9—C10—C11—C12 | −1.3 (16) |
Cl2—Sn1—N1—C2 | −83.9 (4) | C10—C11—C12—O2 | 0.9 (14) |
O1—Sn1—N2—C7 | 179.9 (4) | C11—C12—O2—C9 | −0.1 (11) |
N1—Sn1—N2—C7 | 2.1 (4) | C10—C9—O2—C12 | −0.8 (12) |
Cl1—Sn1—N2—C7 | −90.9 (4) | C10A—C9—O2—C12 | −16 (7) |
Cl2—Sn1—N2—C7 | 90.3 (4) | O2A—C9—O2—C12 | 3 (2) |
O1—Sn1—N2—N3 | −1.9 (3) | C8—C9—O2—C12 | 178.8 (6) |
N1—Sn1—N2—N3 | −179.7 (4) | C10—C9—C10A—C11A | −4 (3) |
Cl1—Sn1—N2—N3 | 87.3 (3) | O2A—C9—C10A—C11A | −3 (4) |
Cl2—Sn1—N2—N3 | −91.5 (3) | O2—C9—C10A—C11A | 162 (10) |
C7—N2—N3—C8 | −178.8 (5) | C8—C9—C10A—C11A | −180 (2) |
Sn1—N2—N3—C8 | 3.1 (5) | C9—C10A—C11A—C12A | 0 (5) |
C6—N1—C2—C3 | −2.1 (8) | C10A—C11A—C12A—O2A | 3 (5) |
Sn1—N1—C2—C3 | 174.3 (4) | C11A—C12A—O2A—C9 | −4 (4) |
C6—N1—C2—C7 | −179.4 (5) | C10—C9—O2A—C12A | 8 (5) |
Sn1—N1—C2—C7 | −3.0 (6) | C10A—C9—O2A—C12A | 5 (4) |
N1—C2—C3—C4 | 1.0 (8) | O2—C9—O2A—C12A | −2 (4) |
C7—C2—C3—C4 | 178.0 (5) | C8—C9—O2A—C12A | −177.9 (18) |
C2—C3—C4—C5 | 1.2 (10) | O1—Sn1—C14—C15 | 114.8 (6) |
C3—C4—C5—C6 | −2.1 (9) | N1—Sn1—C14—C15 | −68.0 (6) |
C2—N1—C6—C5 | 1.1 (8) | Cl1—Sn1—C14—C15 | 24.5 (6) |
Sn1—N1—C6—C5 | −175.0 (4) | Cl2—Sn1—C14—C15 | −155.3 (5) |
C4—C5—C6—N1 | 1.0 (9) | O1—Sn1—C14—C19 | −67.0 (5) |
N3—N2—C7—C2 | 177.6 (4) | N1—Sn1—C14—C19 | 110.1 (5) |
Sn1—N2—C7—C2 | −4.3 (6) | Cl1—Sn1—C14—C19 | −157.3 (5) |
N3—N2—C7—C13 | −0.3 (8) | Cl2—Sn1—C14—C19 | 22.9 (5) |
Sn1—N2—C7—C13 | 177.8 (4) | C19—C14—C15—C16 | 1.1 (10) |
N1—C2—C7—N2 | 4.7 (7) | Sn1—C14—C15—C16 | 179.2 (5) |
C3—C2—C7—N2 | −172.5 (5) | C14—C15—C16—C17 | −0.8 (10) |
N1—C2—C7—C13 | −177.3 (5) | C15—C16—C17—C18 | 0.6 (10) |
C3—C2—C7—C13 | 5.5 (8) | C16—C17—C18—C19 | −0.6 (10) |
Sn1—O1—C8—N3 | 1.6 (7) | C17—C18—C19—C14 | 0.9 (9) |
Sn1—O1—C8—C9 | −178.3 (4) | C15—C14—C19—C18 | −1.1 (10) |
N2—N3—C8—O1 | −3.1 (8) | Sn1—C14—C19—C18 | −179.3 (5) |