The mixed-valent 10-manganese(III/IV)-containing 36-tungsto-4-arsenate(V), [Mn^III₆Mn^IV₄O₄(OH)₁₂(H₂O)₁₂(A-β-AsW₉O₃₄)₄]²²⁻

Inter­action of the mixed-valent 12-manganese coordination complex [Mn^III₈Mn^IV₄O₁₂(CH₃COO)₁₆(H₂O)₄] with the lacunary 9-tungstoarsenate(V) [A-α-AsW₉O₃₄]⁹⁻ resulted in the 10-­manganese(III/IV)-containing 36-tungsto-4-arsenate(V), [Mn^III₆Mn^IV₄O₄(OH)₁₂(H₂O)₁₂(A-β-AsW₉O₃₄)₄]²²⁻ (1). Polyanion 1 was isolated as a hydrated mixed potassium–sodium salt, K₁₄Na₈[Mn^III₆Mn^IV₄O₄(OH)₁₂(H₂O)₁₂(A-β-AsW₉O₃₄)₄]·104H₂O, which crystallizes in the ortho­rhom­bic space group Pbcn and was characterized by FT–IR spectroscopy and single-crystal X-ray diffraction, as well as elemental and thermogravimetric analyses. The title polyanion contains a unique [Mn^III₆Mn^IV₄O₄(OH)₁₂(H₂O)₁₂]¹⁴⁺ core stabilized within the 36-tungsto-4-arsenate(V) framework.

Computing details

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: SHELXTL (Bruker, 2007); software used to prepare material for publication: SHELXTL (Bruker, 2007).

(I)

Crystal data

K14Na8[Mn10O4(OH)12(H2O)12(AsW9O34)4]·104H2O	Dx = 3.543 Mg m^−3
Mr = 12732.94	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Pbcn	Cell parameters from 9792 reflections
a = 21.9323 (19) Å	θ = 2.2–25.1°
b = 33.945 (3) Å	µ = 18.72 mm^−1
c = 32.060 (2) Å	T = 100 K
V = 23868 (4) Å^3	Plate, brown
Z = 4	0.30 × 0.30 × 0.08 mm
F(000) = 23152

Data collection

Bruker APEXII CCD diffractometer	15473 reflections with I > 2σ(I)
φ and ω scans	Rint = 0.167
Absorption correction: multi-scan (SADABS; Bruker, 2007)	θmax = 25.7°, θmin = 3.4°
Tmin = 0.071, Tmax = 0.316	h = −26→26
746021 measured reflections	k = −41→41
22584 independent reflections	l = −37→38

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	H-atom parameters not defined
R[F^2 > 2σ(F^2)] = 0.075	w = 1/[σ^2(Fo^2) + (0.067P)^2 + 3300.P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.208	(Δ/σ)max = 0.001
S = 1.00	Δρmax = 4.38 e Å^−3
22584 reflections	Δρmin = −1.80 e Å^−3
755 parameters

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Indexing and data collection were performed on a Bruker D8 SMART APEX II CCD diffractometer with kappa geometry and Mo Kα radiation (graphite monochromator, λ = 0.71073 Å). Data integration was performed using SAINT (Bruker, 2007). Routine Lorentz and polarization corrections were applied. Multiscan absorption corrections were performed using SADABS (Sheldrick, 2007). Direct methods (SHELXS97) successfully located the tungsten atoms, and successive Fourier syntheses (SHELXL14) revealed the remaining atoms (Sheldrick, 2015). Refinements were full matrix least-squares against |F2| using all data.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
W1	0.84524 (5)	0.04948 (3)	0.80511 (3)	0.0340 (3)	0.96
W1A	0.8850 (13)	0.0907 (9)	0.7800 (9)	0.039 (6)*	0.04
W2	0.88712 (5)	0.09195 (3)	0.71285 (3)	0.0337 (3)	0.96
W2A	0.8377 (17)	0.0479 (10)	0.6893 (10)	0.049 (8)*	0.04
W3	0.79950 (5)	0.00864 (3)	0.71293 (3)	0.0332 (3)	0.96
W3A	0.7984 (17)	0.0084 (11)	0.7831 (11)	0.056 (8)*	0.04
W4	0.68565 (5)	0.06079 (3)	0.84533 (3)	0.0365 (3)
W5	0.77770 (5)	0.14233 (3)	0.84293 (3)	0.0338 (2)
W6	0.81874 (5)	0.18976 (3)	0.74045 (3)	0.0348 (2)
W7	0.77332 (5)	0.14575 (3)	0.64981 (3)	0.0332 (2)
W8	0.67259 (5)	0.05571 (3)	0.65183 (3)	0.0339 (2)
W9	0.63682 (5)	0.01300 (3)	0.74492 (3)	0.0335 (2)
W10	0.46731 (5)	0.31732 (3)	1.01514 (3)	0.0348 (3)	0.96
W10A	0.4147 (14)	0.3591 (9)	0.9851 (9)	0.040*	0.04
W11	0.46173 (5)	0.40043 (3)	0.95520 (3)	0.0339 (3)	0.96
W11A	0.5506 (13)	0.3994 (9)	0.9523 (10)	0.040*	0.04
W12	0.59932 (5)	0.36046 (3)	0.98092 (3)	0.0331 (3)	0.96
W12A	0.5485 (13)	0.3165 (9)	1.0140 (9)	0.040*	0.04
W13	0.50183 (5)	0.21976 (3)	0.96595 (3)	0.0347 (2)
W14	0.36691 (5)	0.26474 (3)	0.94075 (3)	0.0337 (2)
W15	0.36431 (5)	0.35469 (3)	0.87240 (3)	0.0354 (3)
W16	0.49940 (5)	0.39563 (3)	0.84278 (3)	0.0316 (2)
W17	0.64910 (5)	0.34745 (3)	0.87011 (3)	0.0334 (2)
W18	0.64963 (5)	0.26675 (3)	0.93360 (3)	0.0323 (2)
As1	0.72995 (11)	0.09996 (7)	0.74562 (8)	0.0292 (5)
As2	0.50555 (11)	0.30943 (7)	0.90604 (7)	0.0281 (5)
Mn1	0.5000	0.07475 (17)	0.7500	0.0341 (12)
Mn2	0.64177 (18)	0.20448 (12)	0.84110 (12)	0.0328 (9)
Mn3	0.63380 (18)	0.20450 (12)	0.65358 (12)	0.0325 (9)
Mn4	0.56473 (18)	0.17292 (12)	0.74890 (12)	0.0329 (8)
Mn5	0.50223 (17)	0.23531 (11)	0.79398 (12)	0.0315 (8)
Mn6	0.5000	0.33226 (16)	0.7500	0.0309 (12)
O1T	0.8938 (9)	0.0291 (6)	0.8416 (6)	0.046 (5)*
O2T	0.9578 (8)	0.0953 (5)	0.6902 (6)	0.039 (4)*
O3T	0.8158 (9)	−0.0379 (6)	0.6936 (6)	0.043 (5)*
O4A	0.6191 (8)	0.0900 (6)	0.8543 (6)	0.041 (4)*
O4T	0.6807 (9)	0.0269 (6)	0.8853 (6)	0.043 (5)*
O5T	0.8263 (8)	0.1598 (6)	0.8813 (6)	0.041 (4)*
O5A	0.7119 (8)	0.1743 (5)	0.8494 (5)	0.033 (4)*
O6A	0.7582 (8)	0.2240 (5)	0.7389 (5)	0.034 (4)*
O6T	0.8796 (9)	0.2217 (6)	0.7467 (6)	0.041 (4)*
O7A	0.7111 (8)	0.1803 (5)	0.6466 (5)	0.032 (4)*
O7T	0.8039 (8)	0.1503 (6)	0.6012 (6)	0.042 (5)*
O8A	0.6024 (8)	0.0812 (5)	0.6489 (5)	0.035 (4)*
O8T	0.6776 (8)	0.0335 (5)	0.6038 (5)	0.036 (4)*
O9A	0.5619 (8)	0.0372 (5)	0.7443 (5)	0.036 (4)*
O9T	0.6155 (8)	−0.0358 (6)	0.7540 (6)	0.040 (4)*
O10T	0.4391 (10)	0.3120 (6)	1.0654 (7)	0.053 (5)*
O1M1	0.4897 (9)	0.0675 (6)	0.6817 (6)	0.044 (5)*
O1A1	0.7935 (8)	0.0718 (5)	0.7449 (5)	0.032 (4)*
O11T	0.4342 (9)	0.4474 (6)	0.9645 (6)	0.047 (5)*
O1M2	0.5988 (8)	0.1625 (6)	0.8841 (6)	0.040 (4)*
O12T	0.6563 (8)	0.3791 (5)	1.0122 (5)	0.037 (4)*
O1A2	0.5072 (8)	0.3374 (5)	0.9498 (6)	0.036 (4)*
O12	0.9087 (9)	0.0690 (6)	0.7660 (6)	0.043 (5)*
O13A	0.4979 (8)	0.1866 (6)	0.9239 (6)	0.041 (4)*
O13T	0.5143 (9)	0.1886 (6)	1.0074 (6)	0.050 (5)*
O13	0.8393 (9)	0.0054 (6)	0.7673 (6)	0.046 (5)*
O1M3	0.6871 (9)	0.2539 (6)	0.6792 (6)	0.051 (5)*
O14A	0.3588 (8)	0.2304 (5)	0.8985 (5)	0.033 (4)*
O1M4	0.4979 (8)	0.1768 (6)	0.7112 (6)	0.042 (4)*
O14	0.7667 (8)	0.0390 (5)	0.8246 (6)	0.039 (4)*
O14T	0.2986 (8)	0.2609 (5)	0.9645 (5)	0.036 (4)*
O15	0.8341 (7)	0.1027 (5)	0.8228 (5)	0.028 (4)*
O15A	0.3561 (8)	0.3278 (5)	0.8249 (6)	0.039 (4)*
O15T	0.2941 (9)	0.3778 (6)	0.8776 (6)	0.047 (5)*
O1M5	0.4435 (9)	0.2329 (6)	0.7514 (6)	0.041 (4)*
O1M6	0.4004 (9)	0.3391 (6)	0.7470 (6)	0.044 (5)*
O16A	0.4942 (7)	0.3710 (5)	0.7921 (5)	0.029 (4)*
O16T	0.5127 (8)	0.4429 (5)	0.8254 (6)	0.036 (4)*
O17A	0.6569 (9)	0.3185 (6)	0.8246 (6)	0.042 (5)*
O17T	0.7058 (8)	0.3819 (5)	0.8633 (5)	0.036 (4)*
O18A	0.6580 (8)	0.2357 (5)	0.8884 (5)	0.033 (4)*
O18T	0.7087 (8)	0.2495 (6)	0.9648 (6)	0.041 (4)*
O2A1	0.7101 (8)	0.1087 (5)	0.7950 (5)	0.032 (4)*
O2M2	0.7011 (9)	0.2469 (6)	0.8082 (6)	0.043 (5)*
O2A2	0.4678 (8)	0.2668 (5)	0.9168 (5)	0.036 (4)*
O23	0.8706 (8)	0.0383 (5)	0.6960 (5)	0.028 (4)*
O2M3	0.5576 (8)	0.2322 (5)	0.6611 (6)	0.039 (4)*
O2M4	0.5614 (8)	0.1145 (5)	0.7468 (5)	0.034 (4)*
O24M	0.6260 (8)	0.1732 (5)	0.7928 (6)	0.037 (4)*
O25M	0.5672 (8)	0.2356 (5)	0.8331 (6)	0.038 (4)*
O26	0.8740 (9)	0.1410 (6)	0.7371 (6)	0.044 (5)*
O27	0.8330 (8)	0.1067 (5)	0.6697 (5)	0.034 (4)*
O3A1	0.7441 (8)	0.1429 (5)	0.7212 (5)	0.036 (4)*
O3A2	0.4676 (7)	0.3335 (5)	0.8675 (5)	0.031 (4)*
O3M3	0.5941 (8)	0.1547 (6)	0.6181 (6)	0.039 (4)*
O34M	0.6259 (8)	0.1758 (6)	0.7055 (6)	0.042 (4)*
O38	0.7540 (8)	0.0310 (5)	0.6712 (6)	0.038 (4)*
O39	0.7258 (8)	0.0024 (5)	0.7429 (5)	0.036 (4)*
O4A1	0.6705 (8)	0.0749 (5)	0.7225 (5)	0.034 (4)*
O4A2	0.5776 (8)	0.3002 (5)	0.8907 (5)	0.034 (4)*
O45	0.7383 (8)	0.0986 (5)	0.8713 (6)	0.038 (4)*
O49	0.6534 (8)	0.0339 (5)	0.7994 (6)	0.038 (4)*
O56M	0.4979 (9)	0.2931 (6)	0.7935 (6)	0.042 (4)*
O56	0.8031 (8)	0.1716 (5)	0.7952 (5)	0.036 (4)*
O67	0.8218 (7)	0.1833 (5)	0.6802 (5)	0.031 (4)*
O78	0.7209 (8)	0.1013 (5)	0.6431 (6)	0.037 (4)*
O89	0.6402 (8)	0.0127 (5)	0.6847 (5)	0.034 (4)*
O101	0.4411 (9)	0.3716 (6)	1.0044 (6)	0.041 (4)*
O102	0.5441 (9)	0.3416 (6)	1.0259 (6)	0.047 (5)*
O103	0.5025 (8)	0.2690 (5)	1.0033 (6)	0.038 (4)*
O104	0.3995 (7)	0.3028 (5)	0.9820 (5)	0.031 (4)*
O112	0.5446 (9)	0.4039 (6)	0.9786 (7)	0.045 (5)*
O115	0.3970 (8)	0.3773 (6)	0.9268 (6)	0.040 (4)*
O116	0.5003 (8)	0.4073 (5)	0.9026 (5)	0.035 (4)*
O127	0.6246 (9)	0.3709 (6)	0.9269 (6)	0.043 (5)*
O128	0.6231 (8)	0.3078 (5)	0.9736 (5)	0.034 (4)*
O134	0.4157 (8)	0.2270 (6)	0.9722 (6)	0.040 (4)*
O138	0.5810 (9)	0.2365 (6)	0.9526 (6)	0.044 (5)*
O145	0.3557 (8)	0.3089 (5)	0.9055 (5)	0.037 (4)*
O156	0.4111 (8)	0.3960 (5)	0.8485 (6)	0.038 (4)*
O167	0.5820 (8)	0.3772 (5)	0.8505 (5)	0.036 (4)*
O178	0.6912 (8)	0.3100 (5)	0.9059 (5)	0.034 (4)*
K1	0.8546 (3)	−0.05272 (19)	0.8272 (2)	0.0468 (15)
K2	0.4811 (3)	0.5187 (2)	0.8436 (2)	0.0477 (15)
K3	0.7744 (3)	0.1947 (2)	0.5331 (2)	0.0577 (19)
K4	0.7447 (4)	0.4204 (2)	1.0517 (2)	0.0605 (19)
K5	0.8104 (3)	0.2102 (3)	0.9453 (2)	0.067 (2)
K6	0.9445 (4)	0.1456 (3)	0.8104 (3)	0.051 (2)*	0.7
K7	0.5738 (5)	0.3803 (3)	1.0969 (3)	0.057 (3)*	0.7
K8	0.7569 (5)	−0.0365 (4)	0.6097 (4)	0.054 (3)*	0.6
K9	0.6887 (7)	0.1917 (4)	1.0274 (5)	0.056 (3)*	0.5
Na1	0.5000	0.4426 (5)	0.7500	0.043 (4)
Na2	0.5000	−0.0484 (7)	0.7500	0.076 (6)
O1W	0.8044 (11)	0.2523 (7)	0.8672 (7)	0.063 (6)*
O2W	0.3970 (8)	0.4232 (5)	0.7493 (6)	0.039 (4)*
O3W	0.6785 (9)	0.1453 (6)	0.5498 (6)	0.050 (5)*
O4W	0.8482 (9)	0.0534 (6)	0.6042 (6)	0.051 (5)*
O5W	0.3869 (10)	0.4731 (7)	0.8879 (7)	0.061 (6)*
O6W	0.6890 (11)	0.1582 (8)	0.9502 (8)	0.071 (7)*
O7W	0.6124 (11)	0.4557 (7)	0.9107 (7)	0.065 (6)*
O8W	0.4201 (13)	0.2833 (9)	1.1483 (9)	0.084 (8)*
O9W	0.7866 (12)	0.2571 (8)	0.6198 (8)	0.077 (7)*
O10W	0.7801 (13)	0.3411 (9)	0.9567 (9)	0.083 (8)*
O11W	0.6196 (13)	0.2620 (9)	1.0514 (9)	0.088 (8)*
O12W	0.3719 (12)	0.2165 (8)	1.0521 (8)	0.072 (7)*
O13W	0.7911 (15)	0.4234 (10)	0.9696 (10)	0.066 (9)*	0.75
O14W	0.4240 (17)	0.1257 (11)	1.0035 (12)	0.083 (11)*	0.75
O15W	0.4471 (17)	0.3841 (11)	1.1138 (12)	0.083 (10)*	0.75
O16W	0.5840 (16)	0.4706 (11)	1.0193 (11)	0.077 (10)*	0.75
O17W	0.2998 (17)	0.3593 (11)	0.9926 (12)	0.083 (11)*	0.75
O18W	0.4894 (17)	−0.0152 (11)	0.6706 (12)	0.081 (10)*	0.75
O19W	1.0000	0.0118 (8)	0.7500	0.043 (6)*
O20W	0.7341 (18)	−0.0557 (12)	0.8068 (12)	0.048 (10)*	0.5
O21W	0.4477 (18)	0.0715 (12)	0.9370 (12)	0.045 (9)*	0.5
O22W	0.7063 (19)	0.4973 (13)	1.0287 (13)	0.055 (11)*	0.5
O23W	0.630 (2)	−0.0476 (14)	0.8614 (14)	0.061 (12)*	0.5
O24W	0.525 (2)	0.5117 (13)	0.9245 (14)	0.057 (11)*	0.5
O25W	0.571 (2)	0.0664 (15)	0.9307 (16)	0.069 (13)*	0.5
O26W	0.563 (2)	0.3120 (16)	1.1419 (17)	0.079 (15)*	0.5
O27W	0.793 (2)	0.0782 (16)	0.9444 (16)	0.073 (14)*	0.5
O28W	1.0000	0.1823 (17)	0.7500	0.049 (14)*	0.5

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
W1	0.0368 (6)	0.0324 (6)	0.0327 (6)	0.0045 (5)	−0.0025 (5)	−0.0001 (5)
W2	0.0335 (6)	0.0332 (6)	0.0345 (6)	0.0028 (5)	0.0002 (5)	−0.0004 (5)
W3	0.0368 (6)	0.0312 (6)	0.0317 (6)	0.0026 (5)	−0.0003 (5)	−0.0007 (5)
W4	0.0395 (6)	0.0377 (6)	0.0322 (5)	0.0007 (5)	−0.0008 (5)	0.0022 (5)
W5	0.0353 (6)	0.0336 (6)	0.0325 (5)	0.0034 (4)	−0.0032 (4)	−0.0024 (4)
W6	0.0346 (6)	0.0322 (6)	0.0376 (6)	0.0010 (4)	0.0003 (4)	−0.0013 (5)
W7	0.0345 (6)	0.0329 (6)	0.0322 (5)	0.0026 (4)	0.0018 (4)	0.0009 (4)
W8	0.0373 (6)	0.0330 (6)	0.0314 (5)	0.0017 (5)	−0.0013 (4)	−0.0002 (4)
W9	0.0360 (6)	0.0302 (6)	0.0343 (6)	−0.0001 (4)	0.0004 (4)	0.0007 (4)
W10	0.0406 (6)	0.0362 (6)	0.0276 (5)	−0.0004 (5)	0.0014 (5)	−0.0023 (5)
W11	0.0393 (6)	0.0324 (6)	0.0300 (5)	0.0023 (5)	0.0004 (5)	−0.0031 (5)
W12	0.0383 (6)	0.0321 (6)	0.0290 (5)	0.0005 (5)	−0.0019 (4)	−0.0029 (5)
W13	0.0411 (6)	0.0325 (6)	0.0305 (5)	−0.0008 (5)	0.0010 (4)	0.0002 (4)
W14	0.0360 (6)	0.0354 (6)	0.0298 (5)	−0.0012 (5)	0.0040 (4)	−0.0017 (4)
W15	0.0347 (6)	0.0377 (6)	0.0338 (6)	0.0014 (5)	−0.0004 (4)	0.0001 (5)
W16	0.0372 (6)	0.0285 (5)	0.0291 (5)	0.0008 (4)	−0.0010 (4)	−0.0009 (4)
W17	0.0355 (6)	0.0348 (6)	0.0298 (5)	0.0003 (5)	−0.0002 (4)	0.0009 (4)
W18	0.0363 (6)	0.0317 (6)	0.0291 (5)	0.0023 (4)	−0.0047 (4)	−0.0017 (4)
As1	0.0294 (13)	0.0290 (13)	0.0293 (13)	0.0025 (10)	0.0009 (10)	−0.0005 (11)
As2	0.0301 (13)	0.0287 (13)	0.0255 (12)	−0.0008 (10)	0.0001 (10)	0.0000 (10)
Mn1	0.033 (3)	0.031 (3)	0.038 (3)	0.000	0.000 (2)	0.000
Mn2	0.035 (2)	0.036 (2)	0.0276 (19)	0.0012 (17)	−0.0023 (16)	−0.0031 (16)
Mn3	0.034 (2)	0.031 (2)	0.032 (2)	0.0032 (17)	0.0016 (16)	0.0021 (16)
Mn4	0.038 (2)	0.033 (2)	0.0280 (19)	0.0006 (17)	−0.0021 (16)	0.0015 (17)
Mn5	0.034 (2)	0.032 (2)	0.0282 (19)	−0.0013 (17)	0.0003 (16)	0.0024 (16)
Mn6	0.038 (3)	0.027 (3)	0.028 (3)	0.000	0.000 (2)	0.000
K1	0.051 (4)	0.040 (4)	0.050 (4)	0.003 (3)	0.000 (3)	0.011 (3)
K2	0.044 (4)	0.047 (4)	0.052 (4)	0.003 (3)	−0.001 (3)	0.005 (3)
K3	0.064 (4)	0.061 (5)	0.048 (4)	0.021 (4)	0.013 (3)	0.022 (3)
K4	0.058 (4)	0.062 (5)	0.062 (4)	−0.001 (4)	−0.008 (4)	−0.003 (4)
K5	0.055 (4)	0.089 (6)	0.057 (4)	0.019 (4)	−0.012 (4)	−0.027 (4)
Na1	0.043 (9)	0.046 (9)	0.040 (8)	0.000	0.001 (7)	0.000
Na2	0.030 (9)	0.076 (14)	0.123 (19)	0.000	−0.001 (10)	0.000

Geometric parameters (Å, º)

W1—O1T	1.73 (2)	Mn1—O2M4	1.907 (18)
W1—W1A	1.84 (3)	Mn1—O1M1^vi	2.214 (19)
W1—O14	1.868 (18)	Mn1—O1M1	2.214 (19)
W1—W3A	1.87 (4)	Mn2—O5A	1.867 (17)
W1—O15	1.909 (16)	Mn2—O18A	1.884 (17)
W1—O13	1.93 (2)	Mn2—O24M	1.909 (18)
W1—O12	1.987 (19)	Mn2—O25M	1.964 (19)
W1—O1A1	2.364 (17)	Mn2—O1M2	2.197 (19)
W1—K1	3.547 (7)	Mn2—O2M2	2.21 (2)
W1—K6	3.924 (10)	Mn3—O14A^vi	1.893 (17)
W1—K2^i	4.138 (7)	Mn3—O7A	1.898 (17)
W1A—O12	1.01 (3)	Mn3—O2M3	1.933 (19)
W1A—O15	1.82 (3)	Mn3—O34M	1.936 (19)
W1A—W2	2.15 (3)	Mn3—O1M3	2.20 (2)
W1A—O26	2.21 (4)	Mn3—O3M3	2.217 (19)
W1A—O1A1	2.39 (3)	Mn4—O1M4^vi	1.881 (19)
W1A—K6	2.47 (3)	Mn4—O1M4	1.904 (19)
W2—O2T	1.715 (18)	Mn4—O34M	1.935 (19)
W2—O26	1.86 (2)	Mn4—O24M	1.946 (18)
W2—O27	1.891 (17)	Mn4—O2M4	1.987 (18)
W2—O12	1.932 (19)	Mn4—O1M5^vi	2.043 (19)
W2—O23	1.934 (16)	Mn4—Mn4^vi	2.840 (8)
W2—W2A	2.00 (3)	Mn4—Mn5	2.907 (6)
W2—O1A1	2.395 (17)	Mn4—Mn5^vi	2.921 (5)
W2—K2^ii	3.704 (7)	Mn5—O1M5	1.879 (19)
W2—K6	3.831 (10)	Mn5—O1M5^vi	1.881 (19)
W2—K7^iii	3.931 (11)	Mn5—O25M	1.898 (18)
W2A—O23	0.82 (3)	Mn5—O2M3^vi	1.951 (18)
W2A—W3	1.75 (3)	Mn5—O56M	1.96 (2)
W2A—O38	2.01 (4)	Mn5—O1M4^vi	1.994 (19)
W2A—O27	2.10 (4)	Mn5—Mn5^vi	2.822 (7)
W2A—O1A1	2.19 (4)	Mn5—Mn4^vi	2.921 (6)
W2A—K2^ii	3.46 (4)	Mn6—O16A^vi	1.890 (17)
W3—O3T	1.734 (19)	Mn6—O16A	1.890 (17)
W3—O38	1.834 (18)	Mn6—O56M	1.928 (19)
W3—O39	1.893 (17)	Mn6—O56M^vi	1.928 (19)
W3—O23	1.933 (17)	Mn6—O1M6^vi	2.198 (19)
W3—O13	1.95 (2)	Mn6—O1M6	2.198 (19)
W3—W3A	2.25 (4)	O1T—K2^i	2.77 (2)
W3—O1A1	2.380 (17)	O1T—K1	2.94 (2)
W3—K8	3.766 (12)	O2T—K6^viii	2.74 (2)
W3A—O13	1.04 (4)	O2T—K2^ii	2.87 (2)
W3A—O14	1.83 (4)	O2T—K7^iii	3.18 (2)
W3A—O39	2.06 (4)	O3T—K8	2.99 (2)
W3A—O1A1	2.48 (4)	O5T—K5	2.69 (2)
W3A—K1	2.80 (4)	O7T—K3	2.73 (2)
W4—O4T	1.727 (19)	O7T—K7^iii	2.88 (2)
W4—O4A	1.788 (18)	O7T—K4^iii	3.07 (2)
W4—O49	1.872 (18)	O8T—K4^iii	2.854 (19)
W4—O45	1.917 (18)	O8T—K8	2.95 (2)
W4—O14	2.036 (18)	O9T—Na2	2.572 (19)
W4—O2A1	2.353 (17)	O10T—K5^iv	2.94 (2)
W5—O5T	1.732 (19)	O12T—K4	2.707 (19)
W5—O5A	1.817 (17)	O12T—K3^v	3.008 (19)
W5—O56	1.907 (18)	O12T—K7	3.26 (2)
W5—O15	1.938 (16)	O12—K6	3.07 (2)
W5—O45	1.943 (18)	O13—K1	2.77 (2)
W5—O2A1	2.419 (17)	O14A—Mn3^vi	1.894 (17)
W5—K6	3.805 (10)	O1M4—Mn4^vi	1.881 (19)
W5—K5	4.071 (7)	O1M4—Mn5^vi	1.994 (19)
W6—O6T	1.730 (19)	O14T—K3^vi	2.760 (19)
W6—O6A	1.766 (17)	O14T—K9^iv	2.91 (2)
W6—O56	1.892 (17)	O14T—K5^iv	3.065 (19)
W6—O67	1.945 (16)	O15—K6	2.853 (19)
W6—O26	2.05 (2)	O15T—K8^ix	3.05 (2)
W6—O3A1	2.363 (18)	O1M5—Mn5^vi	1.881 (19)
W6—K6	3.858 (10)	O1M5—Mn4^vi	2.043 (19)
W7—O7T	1.704 (19)	O16A—Na1	2.78 (2)
W7—O7A	1.801 (17)	O16T—Na1	2.434 (18)
W7—O78	1.910 (18)	O16T—K2	2.727 (19)
W7—O67	1.925 (17)	O16T—K1^vii	2.915 (19)
W7—O27	1.969 (17)	O17T—K1^vii	2.832 (19)
W7—O3A1	2.378 (17)	O18T—K5	2.67 (2)
W7—K7^iii	3.861 (11)	O18T—K9	2.84 (2)
W7—K4^iii	3.885 (8)	O18T—K3^v	2.92 (2)
W7—K3	4.095 (7)	O23—K2^ii	2.818 (18)
W8—O8T	1.719 (17)	O2M3—Mn5^vi	1.950 (18)
W8—O8A	1.768 (17)	O26—K6	2.82 (2)
W8—O78	1.896 (18)	O27—K7^iii	3.14 (2)
W8—O89	1.935 (17)	O38—K8	3.02 (2)
W8—O38	2.068 (18)	O56—K6	3.26 (2)
W8—O4A1	2.359 (17)	O78—K4^iii	3.115 (19)
W8—K4^iii	3.776 (8)	O102—K7	2.71 (2)
W8—K8	3.878 (12)	O104—K5^iv	3.075 (18)
W9—O9T	1.747 (19)	O128—K3^v	2.949 (18)
W9—O9A	1.837 (18)	O167—K1^vii	2.856 (19)
W9—O49	1.919 (18)	K1—O20W	2.72 (4)
W9—O89	1.934 (17)	K1—O2W^ii	2.75 (2)
W9—O39	1.986 (17)	K1—O7W^i	2.79 (2)
W9—O4A1	2.339 (18)	K1—O17T^i	2.832 (19)
W9—Na2	3.656 (13)	K1—O167^i	2.856 (19)
W10—O10T	1.74 (2)	K1—O16T^i	2.915 (19)
W10—W12A	1.78 (3)	K1—W17^i	3.658 (6)
W10—O103	1.850 (18)	K1—W16^i	3.684 (7)
W10—O104	1.893 (16)	K2—O1T^vii	2.77 (2)
W10—O102	1.91 (2)	K2—O24W	2.77 (5)
W10—O101	1.959 (19)	K2—O23^ix	2.818 (18)
W10—W10A	2.07 (3)	K2—O2T^ix	2.87 (2)
W10—O1A2	2.370 (18)	K2—O5W	2.95 (2)
W10—K5^iv	3.786 (7)	K2—O19W^ix	3.040 (7)
W10—K7	4.108 (11)	K2—W2A^ix	3.46 (4)
W10A—O101	0.95 (3)	K2—W2^ix	3.704 (7)
W10A—O104	1.94 (4)	K2—Na1	3.981 (13)
W10A—W11	1.99 (3)	K2—K7^x	4.106 (13)
W10A—O115	2.01 (4)	K2—W1^vii	4.138 (7)
W10A—O1A2	2.44 (3)	K3—O3W	2.74 (2)
W10A—O17W	2.53 (5)	K3—O14T^vi	2.760 (19)
W10A—K5^iv	3.97 (3)	K3—O11W^iii	2.81 (3)
W11—O11T	1.73 (2)	K3—O18T^iii	2.92 (2)
W11—O115	1.860 (19)	K3—O128^iii	2.949 (18)
W11—O116	1.902 (17)	K3—O10W^iii	2.98 (3)
W11—O101	1.913 (19)	K3—O12T^iii	3.008 (19)
W11—W11A	1.95 (3)	K3—W12^iii	3.738 (7)
W11—O112	1.97 (2)	K3—W18^iii	3.828 (7)
W11—O1A2	2.367 (18)	K3—K9^iii	3.943 (17)
W11A—O112	0.87 (3)	K3—W12A^iii	3.95 (3)
W11A—W12	1.93 (3)	K4—O4W^v	2.79 (2)
W11A—O116	1.96 (4)	K4—O3W^v	2.80 (2)
W11A—O127	2.06 (4)	K4—O13W	2.82 (3)
W11A—O1A2	2.31 (4)	K4—O22W	2.84 (5)
W12—O12T	1.722 (18)	K4—O8T^v	2.854 (19)
W12—O127	1.854 (19)	K4—O7T^v	3.07 (2)
W12—O128	1.877 (18)	K4—O78^v	3.114 (19)
W12—O112	1.90 (2)	K4—W8^v	3.776 (8)
W12—O102	1.99 (2)	K4—W7^v	3.885 (8)
W12—W12A	2.14 (3)	K4—K3^v	3.975 (11)
W12—O1A2	2.385 (18)	K4—K7	4.243 (13)
W12—K3^v	3.738 (7)	K5—O12W^xi	2.83 (3)
W12—K7	3.819 (11)	K5—O1W	2.88 (3)
W12A—O102	0.94 (3)	K5—O10T^xi	2.94 (2)
W12A—O103	1.93 (4)	K5—O14T^xi	3.065 (19)
W12A—O128	2.11 (3)	K5—O104^xi	3.076 (18)
W12A—O1A2	2.36 (3)	K5—O17W^xi	3.10 (4)
W12A—K7	3.47 (3)	K5—O6W	3.20 (3)
W12A—K3^v	3.95 (3)	K5—W10^xi	3.786 (7)
W13—O13T	1.72 (2)	K5—K9	3.802 (17)
W13—O13A	1.758 (19)	K5—W14^xi	3.952 (7)
W13—O138	1.876 (19)	K6—O28W	2.61 (3)
W13—O134	1.916 (18)	K6—O15W^xi	2.63 (4)
W13—O103	2.058 (18)	K6—O2T^viii	2.74 (2)
W13—O2A2	2.364 (18)	K6—O8W^xi	2.81 (3)
W14—O14T	1.687 (18)	K6—O26W^xi	3.34 (6)
W14—O14A	1.796 (17)	K7—O26W	2.74 (6)
W14—O145	1.891 (18)	K7—O15W	2.83 (4)
W14—O134	1.950 (18)	K7—O4W^v	2.84 (2)
W14—O104	1.983 (17)	K7—O7T^v	2.88 (2)
W14—O2A2	2.344 (18)	K7—O27^v	3.14 (2)
W14—K5^iv	3.952 (7)	K7—O2T^v	3.18 (2)
W14—K3^vi	3.995 (7)	K7—W7^v	3.861 (11)
W15—O15T	1.74 (2)	K7—W2^v	3.931 (11)
W15—O15A	1.785 (18)	K8—O5W^ii	2.87 (3)
W15—O145	1.894 (18)	K8—O22W^iii	3.03 (5)
W15—O156	1.898 (18)	K8—O15T^ii	3.05 (2)
W15—O115	2.036 (19)	K8—K4^iii	4.358 (15)
W15—O3A2	2.383 (17)	K9—O6W	2.73 (3)
W16—O16T	1.722 (18)	K9—O14T^xi	2.91 (2)
W16—O16A	1.830 (16)	K9—O11W	2.93 (3)
W16—O167	1.933 (18)	K9—O17W^xi	3.06 (4)
W16—O156	1.945 (18)	K9—K3^v	3.943 (17)
W16—O116	1.957 (17)	Na1—O19W^ix	2.35 (3)
W16—O3A2	2.358 (17)	Na1—O2W	2.353 (19)
W16—Na1	3.375 (8)	Na1—O2W^vi	2.353 (19)
W16—K1^vii	3.685 (7)	Na1—O16T^vi	2.434 (18)
W17—O17T	1.721 (18)	Na1—O16A^vi	2.78 (2)
W17—O17A	1.769 (19)	Na1—W16^vi	3.375 (8)
W17—O167	1.891 (18)	Na1—K2^vi	3.981 (13)
W17—O178	1.946 (17)	Na1—K1^vii	4.040 (7)
W17—O127	2.057 (19)	Na2—O9T^vi	2.572 (19)
W17—O4A2	2.339 (17)	Na2—O18W	2.79 (4)
W17—K1^vii	3.658 (6)	Na2—O18W^vi	2.79 (4)
W18—O18T	1.739 (18)	Na2—W9^vi	3.656 (13)
W18—O18A	1.802 (17)	O2W—K1^ix	2.75 (2)
W18—O138	1.922 (19)	O3W—K4^iii	2.80 (2)
W18—O178	1.943 (18)	O4W—K4^iii	2.79 (2)
W18—O128	1.982 (17)	O4W—K7^iii	2.84 (2)
W18—O4A2	2.383 (17)	O5W—K8^ix	2.87 (3)
W18—K3^v	3.828 (7)	O7W—K1^vii	2.79 (2)
W18—K5	4.032 (8)	O8W—K6^iv	2.81 (3)
W18—K9	4.033 (15)	O10W—K3^v	2.98 (3)
As1—O2A1	1.670 (17)	O11W—K3^v	2.81 (3)
As1—O3A1	1.685 (18)	O12W—K5^iv	2.83 (3)
As1—O1A1	1.690 (17)	O15W—K6^iv	2.63 (4)
As1—O4A1	1.724 (17)	O17W—K9^iv	3.06 (4)
As2—O4A2	1.684 (17)	O17W—K5^iv	3.10 (4)
As2—O1A2	1.695 (18)	O19W—Na1^ii	2.35 (3)
As2—O3A2	1.700 (17)	O19W—K2^i	3.040 (7)
As2—O2A2	1.702 (18)	O19W—K2^ii	3.040 (7)
Mn1—O9A	1.871 (18)	O22W—K8^v	3.03 (5)
Mn1—O9A^vi	1.871 (18)	O26W—K6^iv	3.34 (6)
Mn1—O2M4^vi	1.907 (18)	O28W—K6^viii	2.61 (3)
O1T—W1—W1A	108.1 (11)	W5—O5T—K5	132.7 (9)
O1T—W1—O14	105.4 (9)	W5—O5A—Mn2	165.0 (10)
W1A—W1—O14	137.0 (11)	W7—O7A—Mn3	162.2 (10)
O1T—W1—W3A	107.2 (13)	W7—O7T—K3	133.5 (10)
W1A—W1—W3A	131.6 (14)	W7—O7T—K7^iii	112.3 (9)
O14—W1—W3A	58.5 (13)	K3—O7T—K7^iii	112.4 (7)
O1T—W1—O15	104.9 (8)	W7—O7T—K4^iii	105.4 (8)
W1A—W1—O15	58.0 (11)	K3—O7T—K4^iii	86.3 (6)
O14—W1—O15	87.9 (7)	K7^iii—O7T—K4^iii	91.0 (6)
W3A—W1—O15	138.3 (12)	W8—O8T—K4^iii	108.8 (8)
O1T—W1—O13	99.0 (9)	W8—O8T—K8	109.5 (8)
W1A—W1—O13	110.4 (11)	K4^iii—O8T—K8	97.3 (6)
O14—W1—O13	90.0 (8)	W9—O9A—Mn1	162.4 (11)
W3A—W1—O13	31.6 (12)	W9—O9T—Na2	114.3 (10)
O15—W1—O13	155.7 (8)	W10—O10T—K5^iv	105.2 (9)
O1T—W1—O12	97.4 (9)	As1—O1A1—W2A	125.9 (13)
W1A—W1—O12	30.3 (10)	As1—O1A1—W1	124.5 (9)
O14—W1—O12	157.1 (8)	W2A—O1A1—W1	109.5 (12)
W3A—W1—O12	113.2 (13)	As1—O1A1—W3	124.1 (9)
O15—W1—O12	87.9 (8)	W2A—O1A1—W3	44.7 (10)
O13—W1—O12	84.8 (8)	W1—O1A1—W3	92.1 (6)
O1T—W1—O1A1	167.9 (8)	As1—O1A1—W1A	122.3 (11)
W1A—W1—O1A1	68.0 (10)	W2A—O1A1—W1A	96.4 (13)
O14—W1—O1A1	83.8 (7)	W1—O1A1—W1A	45.4 (8)
W3A—W1—O1A1	70.6 (12)	W3—O1A1—W1A	113.5 (10)
O15—W1—O1A1	83.0 (6)	As1—O1A1—W2	123.5 (9)
O13—W1—O1A1	72.8 (7)	W2A—O1A1—W2	51.4 (10)
O12—W1—O1A1	73.4 (7)	W1—O1A1—W2	91.8 (6)
O1T—W1—K1	55.7 (7)	W3—O1A1—W2	91.4 (6)
W1A—W1—K1	143.7 (9)	W1A—O1A1—W2	53.5 (8)
O14—W1—K1	78.4 (6)	As1—O1A1—W3A	121.3 (12)
W3A—W1—K1	51.6 (11)	W2A—O1A1—W3A	93.5 (14)
O15—W1—K1	150.9 (5)	W1—O1A1—W3A	45.4 (9)
O13—W1—K1	51.0 (6)	W3—O1A1—W3A	55.1 (9)
O12—W1—K1	114.3 (6)	W1A—O1A1—W3A	88.0 (12)
O1A1—W1—K1	120.3 (4)	W2—O1A1—W3A	115.0 (11)
O1T—W1—K6	87.8 (7)	W12—O12T—K4	169.2 (10)
W1A—W1—K6	28.6 (9)	W12—O12T—K3^v	100.9 (8)
O14—W1—K6	131.0 (6)	K4—O12T—K3^v	88.0 (5)
W3A—W1—K6	160.1 (11)	W12—O12T—K7	95.0 (7)
O15—W1—K6	43.3 (5)	K4—O12T—K7	90.1 (6)
O13—W1—K6	135.2 (6)	K3^v—O12T—K7	96.0 (5)
O12—W1—K6	50.4 (6)	As2—O1A2—W11A	123.2 (12)
O1A1—W1—K6	92.0 (4)	As2—O1A2—W12A	124.2 (12)
K1—W1—K6	140.55 (19)	W11A—O1A2—W12A	94.9 (13)
O1T—W1—K2^i	29.4 (7)	As2—O1A2—W11	123.9 (9)
W1A—W1—K2^i	83.5 (9)	W11A—O1A2—W11	49.3 (8)
O14—W1—K2^i	134.5 (6)	W12A—O1A2—W11	111.8 (11)
W3A—W1—K2^i	115.5 (11)	As2—O1A2—W10	124.2 (9)
O15—W1—K2^i	105.6 (5)	W11A—O1A2—W10	112.5 (11)
O13—W1—K2^i	93.1 (6)	W12A—O1A2—W10	44.3 (8)
O12—W1—K2^i	68.2 (6)	W11—O1A2—W10	92.3 (6)
O1A1—W1—K2^i	140.0 (4)	As2—O1A2—W12	123.3 (9)
K1—W1—K2^i	68.89 (15)	W11A—O1A2—W12	48.5 (8)
K6—W1—K2^i	71.75 (18)	W12A—O1A2—W12	53.7 (8)
O12—W1A—O15	145 (3)	W11—O1A2—W12	91.7 (6)
O12—W1A—W1	83 (2)	W10—O1A2—W12	92.2 (6)
O15—W1A—W1	63.0 (11)	As2—O1A2—W10A	122.3 (12)
O12—W1A—W2	63.7 (19)	W11A—O1A2—W10A	93.0 (12)
O15—W1A—W2	139.9 (17)	W12A—O1A2—W10A	90.4 (12)
W1—W1A—W2	117.6 (15)	W11—O1A2—W10A	48.8 (8)
O12—W1A—O26	110 (2)	W10—O1A2—W10A	50.9 (8)
O15—W1A—O26	103.4 (15)	W12—O1A2—W10A	114.4 (10)
W1—W1A—O26	144.3 (16)	W1A—O12—W2	88 (2)
W2—W1A—O26	50.5 (8)	W1A—O12—W1	67 (2)
O12—W1A—O1A1	91 (2)	W2—O12—W1	121.3 (10)
O15—W1A—O1A1	84.2 (13)	W1A—O12—K6	45.9 (19)
W1—W1A—O1A1	66.6 (10)	W2—O12—K6	97.4 (8)
W2—W1A—O1A1	63.4 (9)	W1—O12—K6	99.7 (8)
O26—W1A—O1A1	79.8 (11)	W3A—O13—W1	71 (2)
O12—W1A—K6	117 (2)	W3A—O13—W3	92 (2)
O15—W1A—K6	81.8 (12)	W1—O13—W3	123.1 (11)
W1—W1A—K6	130.7 (15)	W3A—O13—K1	81 (2)
W2—W1A—K6	111.6 (12)	W1—O13—K1	96.2 (8)
O26—W1A—K6	73.8 (10)	W3—O13—K1	135.4 (9)
O1A1—W1A—K6	146.2 (14)	W14—O14A—Mn3^vi	163.4 (11)
O2T—W2—O26	104.8 (9)	Mn4^vi—O1M4—Mn4	97.3 (9)
O2T—W2—O27	103.9 (8)	Mn4^vi—O1M4—Mn5^vi	97.2 (9)
O26—W2—O27	88.4 (8)	Mn4—O1M4—Mn5^vi	97.1 (9)
O2T—W2—O12	100.3 (8)	W3A—O14—W1	60.8 (13)
O26—W2—O12	91.8 (8)	W3A—O14—W4	141.0 (15)
O27—W2—O12	154.9 (8)	W1—O14—W4	147.7 (10)
O2T—W2—O23	96.6 (8)	W14—O14T—K3^vi	126.2 (9)
O26—W2—O23	158.5 (8)	W14—O14T—K9^iv	137.2 (9)
O27—W2—O23	85.8 (7)	K3^vi—O14T—K9^iv	88.1 (6)
O12—W2—O23	84.9 (8)	W14—O14T—K5^iv	109.1 (8)
O2T—W2—W2A	112.4 (12)	K3^vi—O14T—K5^iv	106.5 (6)
O26—W2—W2A	138.2 (12)	K9^iv—O14T—K5^iv	79.0 (5)
O27—W2—W2A	65.2 (12)	W1A—O15—W1	59.0 (11)
O12—W2—W2A	99.4 (12)	W1A—O15—W5	143.1 (13)
O23—W2—W2A	24.0 (10)	W1—O15—W5	146.9 (9)
O2T—W2—W1A	116.3 (10)	W1A—O15—K6	59.1 (10)
O26—W2—W1A	66.2 (10)	W1—O15—K6	109.4 (7)
O27—W2—W1A	136.3 (9)	W5—O15—K6	103.5 (7)
O12—W2—W1A	27.9 (9)	W15—O15T—K8^ix	133.0 (10)
O23—W2—W1A	104.9 (9)	Mn5—O1M5—Mn5^vi	97.3 (9)
W2A—W2—W1A	110.6 (12)	Mn5—O1M5—Mn4^vi	96.2 (8)
O2T—W2—O1A1	167.2 (7)	Mn5^vi—O1M5—Mn4^vi	95.5 (8)
O26—W2—O1A1	86.8 (7)	W16—O16A—Mn6	161.4 (10)
O27—W2—O1A1	81.5 (7)	W16—O16A—Na1	91.7 (6)
O12—W2—O1A1	73.5 (7)	Mn6—O16A—Na1	105.0 (7)
O23—W2—O1A1	71.9 (6)	W16—O16T—Na1	107.4 (9)
W2A—W2—O1A1	58.9 (11)	W16—O16T—K2	140.0 (9)
W1A—W2—O1A1	63.1 (9)	Na1—O16T—K2	100.8 (7)
O2T—W2—K2^ii	48.3 (6)	W16—O16T—K1^vii	102.2 (7)
O26—W2—K2^ii	153.1 (6)	Na1—O16T—K1^vii	97.7 (6)
O27—W2—K2^ii	99.7 (5)	K2—O16T—K1^vii	101.6 (6)
O12—W2—K2^ii	91.3 (6)	W17—O17T—K1^vii	104.3 (8)
O23—W2—K2^ii	48.4 (5)	W18—O18A—Mn2	163.2 (10)
W2A—W2—K2^ii	67.3 (10)	W18—O18T—K5	130.9 (9)
W1A—W2—K2^ii	119.2 (8)	W18—O18T—K9	121.6 (9)
O1A1—W2—K2^ii	119.7 (4)	K5—O18T—K9	87.1 (7)
O2T—W2—K6	91.0 (6)	W18—O18T—K3^v	107.9 (8)
O26—W2—K6	44.3 (6)	K5—O18T—K3^v	113.2 (7)
O27—W2—K6	132.7 (6)	K9—O18T—K3^v	86.4 (6)
O12—W2—K6	52.6 (6)	As1—O2A1—W4	125.9 (9)
O23—W2—K6	137.5 (5)	As1—O2A1—W5	121.8 (8)
W2A—W2—K6	147.5 (10)	W4—O2A1—W5	91.8 (6)
W1A—W2—K6	36.9 (8)	As2—O2A2—W14	123.4 (9)
O1A1—W2—K6	93.8 (4)	As2—O2A2—W13	123.8 (9)
K2^ii—W2—K6	122.39 (18)	W14—O2A2—W13	93.4 (6)
O2T—W2—K7^iii	52.2 (6)	W2A—O23—W3	65 (3)
O26—W2—K7^iii	102.4 (6)	W2A—O23—W2	82 (3)
O27—W2—K7^iii	51.8 (5)	W3—O23—W2	124.3 (9)
O12—W2—K7^iii	151.3 (6)	W2A—O23—K2^ii	137 (3)
O23—W2—K7^iii	90.2 (5)	W3—O23—K2^ii	134.2 (8)
W2A—W2—K7^iii	86.6 (10)	W2—O23—K2^ii	100.8 (7)
W1A—W2—K7^iii	162.7 (8)	Mn3—O2M3—Mn5^vi	134.4 (10)
O1A1—W2—K7^iii	131.4 (4)	Mn1—O2M4—Mn4	136.9 (10)
K2^ii—W2—K7^iii	64.99 (19)	Mn2—O24M—Mn4	135.6 (10)
K6—W2—K7^iii	125.9 (2)	Mn5—O25M—Mn2	135.1 (10)
O23—W2A—W3	90 (3)	W2—O26—W6	146.5 (11)
O23—W2A—W2	74 (3)	W2—O26—W1A	63.3 (10)
W3—W2A—W2	131.9 (19)	W6—O26—W1A	130.9 (12)
O23—W2A—O38	140 (4)	W2—O26—K6	108.3 (8)
W3—W2A—O38	58.0 (12)	W6—O26—K6	103.6 (8)
W2—W2A—O38	145 (2)	W1A—O26—K6	57.5 (9)
O23—W2A—O27	120 (3)	W2—O27—W7	146.3 (10)
W3—W2A—O27	146 (2)	W2—O27—W2A	59.8 (11)
W2—W2A—O27	55.0 (10)	W7—O27—W2A	140.5 (14)
O38—W2A—O27	98.1 (17)	W2—O27—K7^iii	100.0 (7)
O23—W2A—O1A1	109 (3)	W7—O27—K7^iii	95.6 (6)
W3—W2A—O1A1	73.6 (13)	W2A—O27—K7^iii	109.0 (12)
W2—W2A—O1A1	69.7 (12)	As1—O3A1—W6	126.1 (9)
O38—W2A—O1A1	86.4 (15)	As1—O3A1—W7	122.1 (9)
O27—W2A—O1A1	82.5 (14)	W6—O3A1—W7	92.2 (6)
O23—W2A—K2^ii	34 (2)	As2—O3A2—W16	122.0 (8)
W3—W2A—K2^ii	110.5 (16)	As2—O3A2—W15	124.2 (8)
W2—W2A—K2^ii	80.6 (11)	W16—O3A2—W15	91.9 (6)
O38—W2A—K2^ii	131.3 (15)	Mn4—O34M—Mn3	134.9 (10)
O27—W2A—K2^ii	103.0 (13)	W3—O38—W2A	53.8 (11)
O1A1—W2A—K2^ii	139.3 (15)	W3—O38—W8	149.0 (10)
O3T—W3—W2A	116.1 (13)	W2A—O38—W8	139.4 (14)
O3T—W3—O38	103.2 (8)	W3—O38—K8	98.7 (8)
W2A—W3—O38	68.2 (13)	W2A—O38—K8	112.7 (13)
O3T—W3—O39	104.8 (8)	W8—O38—K8	97.5 (7)
W2A—W3—O39	135.7 (13)	W3—O39—W9	146.6 (10)
O38—W3—O39	87.3 (8)	W3—O39—W3A	69.3 (12)
O3T—W3—O23	102.0 (8)	W9—O39—W3A	136.2 (14)
W2A—W3—O23	25.1 (11)	As1—O4A1—W9	123.4 (9)
O38—W3—O23	91.1 (8)	As1—O4A1—W8	122.3 (9)
O39—W3—O23	152.8 (7)	W9—O4A1—W8	93.1 (6)
O3T—W3—O13	100.1 (9)	As2—O4A2—W17	125.7 (9)
W2A—W3—O13	102.5 (13)	As2—O4A2—W18	122.8 (9)
O38—W3—O13	156.7 (8)	W17—O4A2—W18	92.6 (6)
O39—W3—O13	85.5 (8)	W4—O45—W5	125.1 (9)
O23—W3—O13	85.4 (8)	W4—O49—W9	165.4 (11)
O3T—W3—W3A	110.9 (11)	Mn6—O56M—Mn5	133.9 (10)
W2A—W3—W3A	116.2 (15)	W6—O56—W5	165.2 (11)
O38—W3—W3A	136.5 (11)	W6—O56—K6	93.2 (6)
O39—W3—W3A	58.8 (11)	W5—O56—K6	91.0 (6)
O23—W3—W3A	106.9 (11)	W7—O67—W6	123.9 (9)
O13—W3—W3A	27.4 (10)	W8—O78—W7	164.8 (11)
O3T—W3—O1A1	170.4 (7)	W8—O78—K4^iii	94.7 (7)
W2A—W3—O1A1	61.7 (12)	W7—O78—K4^iii	98.4 (7)
O38—W3—O1A1	84.9 (7)	W9—O89—W8	123.6 (9)
O39—W3—O1A1	80.5 (7)	W10A—O101—W11	80 (2)
O23—W3—O1A1	72.3 (6)	W10A—O101—W10	83 (2)
O13—W3—O1A1	72.0 (7)	W11—O101—W10	123.8 (10)
W3A—W3—O1A1	64.6 (10)	W12A—O102—W10	68 (2)
O3T—W3—K8	50.7 (7)	W12A—O102—W12	86 (2)
W2A—W3—K8	92.7 (11)	W10—O102—W12	123.1 (11)
O38—W3—K8	52.5 (6)	W12A—O102—K7	139 (3)
O39—W3—K8	100.9 (6)	W10—O102—K7	125.0 (10)
O23—W3—K8	99.5 (5)	W12—O102—K7	107.9 (9)
O13—W3—K8	150.8 (6)	W10—O103—W12A	56.2 (10)
W3A—W3—K8	151.1 (10)	W10—O103—W13	146.8 (10)
O1A1—W3—K8	137.0 (4)	W12A—O103—W13	141.7 (13)
O13—W3A—O14	138 (3)	W10—O104—W10A	65.3 (10)
O13—W3A—W1	77 (2)	W10—O104—W14	145.8 (9)
O14—W3A—W1	60.7 (13)	W10A—O104—W14	137.5 (13)
O13—W3A—O39	111 (3)	W10—O104—K5^iv	96.4 (6)
O14—W3A—O39	102.6 (19)	W10A—O104—K5^iv	102.2 (11)
W1—W3A—O39	137 (2)	W14—O104—K5^iv	100.5 (6)
O13—W3A—W3	60 (2)	W11A—O112—W12	79 (3)
O14—W3A—W3	137 (2)	W11A—O112—W11	76 (2)
W1—W3A—W3	111.7 (17)	W12—O112—W11	123.4 (11)
O39—W3A—W3	51.9 (10)	W11—O115—W10A	61.7 (10)
O13—W3A—O1A1	83 (2)	W11—O115—W15	147.9 (10)
O14—W3A—O1A1	81.4 (15)	W10A—O115—W15	138.6 (13)
W1—W3A—O1A1	64.1 (12)	W11—O116—W11A	60.7 (10)
O39—W3A—O1A1	75.2 (13)	W11—O116—W16	147.0 (10)
W3—W3A—O1A1	60.2 (10)	W11A—O116—W16	140.9 (13)
O13—W3A—K1	78 (2)	W12—O127—W17	146.2 (11)
O14—W3A—K1	102.7 (16)	W12—O127—W11A	58.9 (10)
W1—W3A—K1	96.9 (14)	W17—O127—W11A	137.6 (13)
O39—W3A—K1	125.7 (17)	W12—O128—W18	146.3 (10)
W3—W3A—K1	120.2 (15)	W12—O128—W12A	64.9 (10)
O1A1—W3A—K1	155.9 (16)	W18—O128—W12A	136.4 (13)
O4T—W4—O4A	101.5 (9)	W12—O128—K3^v	99.1 (7)
O4T—W4—O49	103.6 (9)	W18—O128—K3^v	100.0 (7)
O4A—W4—O49	95.1 (8)	W12A—O128—K3^v	101.5 (10)
O4T—W4—O45	99.3 (8)	W13—O134—W14	124.8 (10)
O4A—W4—O45	92.9 (8)	W13—O138—W18	163.6 (12)
O49—W4—O45	153.6 (8)	W14—O145—W15	166.6 (11)
O4T—W4—O14	93.1 (8)	W15—O156—W16	124.9 (10)
O4A—W4—O14	165.1 (8)	W17—O167—W16	160.9 (11)
O49—W4—O14	84.0 (8)	W17—O167—K1^vii	98.8 (7)
O45—W4—O14	81.9 (7)	W16—O167—K1^vii	98.8 (7)
O4T—W4—O2A1	169.8 (8)	W18—O178—W17	122.7 (9)
O4A—W4—O2A1	85.0 (7)	O20W—K1—O2W^ii	95.9 (9)
O49—W4—O2A1	83.4 (7)	O20W—K1—O13	75.1 (10)
O45—W4—O2A1	72.4 (7)	O2W^ii—K1—O13	68.6 (6)
O14—W4—O2A1	80.2 (7)	O20W—K1—O7W^i	119.1 (10)
O5T—W5—O5A	101.7 (8)	O2W^ii—K1—O7W^i	143.1 (7)
O5T—W5—O56	102.2 (8)	O13—K1—O7W^i	128.5 (7)
O5A—W5—O56	90.7 (8)	O20W—K1—W3A	58.6 (12)
O5T—W5—O15	94.7 (8)	O2W^ii—K1—W3A	85.4 (9)
O5A—W5—O15	163.5 (7)	O13—K1—W3A	21.4 (8)
O56—W5—O15	84.7 (7)	O7W^i—K1—W3A	121.6 (9)
O5T—W5—O45	101.7 (8)	O20W—K1—O17T^i	67.4 (9)
O5A—W5—O45	92.9 (8)	O2W^ii—K1—O17T^i	106.9 (6)
O56—W5—O45	154.6 (8)	O13—K1—O17T^i	141.6 (6)
O15—W5—O45	84.8 (7)	O7W^i—K1—O17T^i	79.0 (6)
O5T—W5—O2A1	171.5 (8)	W3A—K1—O17T^i	125.6 (9)
O5A—W5—O2A1	82.4 (7)	O20W—K1—O167^i	120.3 (10)
O56—W5—O2A1	85.2 (7)	O2W^ii—K1—O167^i	79.7 (5)
O15—W5—O2A1	81.5 (6)	O13—K1—O167^i	146.4 (6)
O45—W5—O2A1	70.4 (7)	O7W^i—K1—O167^i	73.0 (6)
O5T—W5—K6	66.0 (6)	W3A—K1—O167^i	164.8 (9)
O5A—W5—K6	141.0 (6)	O17T^i—K1—O167^i	57.8 (5)
O56—W5—K6	58.9 (5)	O20W—K1—O16T^i	164.1 (10)
O15—W5—K6	46.8 (5)	O2W^ii—K1—O16T^i	68.2 (5)
O45—W5—K6	125.3 (5)	O13—K1—O16T^i	98.3 (6)
O2A1—W5—K6	115.4 (4)	O7W^i—K1—O16T^i	76.4 (6)
O5T—W5—K5	29.1 (6)	W3A—K1—O16T^i	117.9 (9)
O5A—W5—K5	73.2 (5)	O17T^i—K1—O16T^i	115.8 (5)
O56—W5—K5	107.5 (6)	O167^i—K1—O16T^i	58.4 (5)
O15—W5—K5	123.3 (5)	O20W—K1—O1T	110.9 (10)
O45—W5—K5	97.6 (5)	O2W^ii—K1—O1T	108.8 (6)
O2A1—W5—K5	152.3 (4)	O13—K1—O1T	58.2 (6)
K6—W5—K5	92.02 (19)	O7W^i—K1—O1T	71.1 (7)
O6T—W6—O6A	99.9 (8)	W3A—K1—O1T	60.5 (9)
O6T—W6—O56	103.6 (8)	O17T^i—K1—O1T	144.3 (6)
O6A—W6—O56	96.1 (8)	O167^i—K1—O1T	127.1 (6)
O6T—W6—O67	99.2 (8)	O16T^i—K1—O1T	76.1 (5)
O6A—W6—O67	94.1 (7)	O20W—K1—W1	86.1 (9)
O56—W6—O67	153.0 (7)	O2W^ii—K1—W1	97.6 (4)
O6T—W6—O26	93.2 (8)	O13—K1—W1	32.8 (4)
O6A—W6—O26	166.6 (8)	O7W^i—K1—W1	96.1 (5)
O56—W6—O26	83.8 (8)	W3A—K1—W1	31.6 (8)
O67—W6—O26	80.6 (7)	O17T^i—K1—W1	145.2 (4)
O6T—W6—O3A1	170.2 (8)	O167^i—K1—W1	153.6 (4)
O6A—W6—O3A1	85.1 (7)	O16T^i—K1—W1	96.0 (4)
O56—W6—O3A1	84.1 (7)	O1T—K1—W1	29.0 (4)
O67—W6—O3A1	71.8 (6)	O20W—K1—W17^i	92.0 (9)
O26—W6—O3A1	81.6 (7)	O2W^ii—K1—W17^i	93.9 (4)
O6T—W6—K6	68.0 (6)	O13—K1—W17^i	156.4 (5)
O6A—W6—K6	144.1 (6)	O7W^i—K1—W17^i	74.9 (5)
O56—W6—K6	57.5 (5)	W3A—K1—W17^i	150.2 (8)
O67—W6—K6	120.6 (5)	O17T^i—K1—W17^i	27.1 (4)
O26—W6—K6	45.2 (6)	O167^i—K1—W17^i	30.7 (4)
O3A1—W6—K6	112.7 (5)	O16T^i—K1—W17^i	89.0 (4)
O7T—W7—O7A	100.8 (8)	O1T—K1—W17^i	145.2 (4)
O7T—W7—O78	101.9 (8)	W1—K1—W17^i	168.5 (2)
O7A—W7—O78	92.9 (8)	O20W—K1—W16^i	149.0 (9)
O7T—W7—O67	100.7 (8)	O2W^ii—K1—W16^i	71.6 (4)
O7A—W7—O67	90.9 (7)	O13—K1—W16^i	122.5 (5)
O78—W7—O67	155.9 (7)	O7W^i—K1—W16^i	72.1 (5)
O7T—W7—O27	95.4 (8)	W3A—K1—W16^i	143.6 (8)
O7A—W7—O27	163.8 (7)	O17T^i—K1—W16^i	88.8 (4)
O78—W7—O27	84.5 (7)	O167^i—K1—W16^i	31.2 (4)
O67—W7—O27	85.2 (7)	O16T^i—K1—W16^i	27.2 (4)
O7T—W7—O3A1	171.8 (8)	O1T—K1—W16^i	100.0 (4)
O7A—W7—O3A1	83.0 (7)	W1—K1—W16^i	122.87 (19)
O78—W7—O3A1	85.1 (7)	W17^i—K1—W16^i	61.81 (10)
O67—W7—O3A1	71.8 (6)	O16T—K2—O1T^vii	82.2 (6)
O27—W7—O3A1	80.8 (7)	O16T—K2—O24W	91.9 (10)
O7T—W7—K7^iii	43.6 (7)	O1T^vii—K2—O24W	72.0 (10)
O7A—W7—K7^iii	141.4 (6)	O16T—K2—O23^ix	110.2 (6)
O78—W7—K7^iii	107.0 (6)	O1T^vii—K2—O23^ix	144.3 (6)
O67—W7—K7^iii	84.0 (5)	O24W—K2—O23^ix	137.6 (10)
O27—W7—K7^iii	53.9 (5)	O16T—K2—O2T^ix	145.2 (6)
O3A1—W7—K7^iii	130.4 (5)	O1T^vii—K2—O2T^ix	93.0 (6)
O7T—W7—K4^iii	49.6 (7)	O24W—K2—O2T^ix	119.5 (10)
O7A—W7—K4^iii	104.6 (5)	O23^ix—K2—O2T^ix	57.4 (5)
O78—W7—K4^iii	52.5 (5)	O16T—K2—O5W	77.6 (6)
O67—W7—K4^iii	148.1 (5)	O1T^vii—K2—O5W	140.7 (7)
O27—W7—K4^iii	86.6 (5)	O24W—K2—O5W	75.3 (10)
O3A1—W7—K4^iii	136.8 (4)	O23^ix—K2—O5W	74.8 (6)
K7^iii—W7—K4^iii	66.4 (2)	O2T^ix—K2—O5W	122.3 (6)
O7T—W7—K3	29.0 (6)	O16T—K2—O19W^ix	71.4 (6)
O7A—W7—K3	71.8 (5)	O1T^vii—K2—O19W^ix	81.5 (4)
O78—W7—K3	102.8 (5)	O24W—K2—O19W^ix	150.4 (10)
O67—W7—K3	101.0 (5)	O23^ix—K2—O19W^ix	71.9 (4)
O27—W7—K3	124.4 (5)	O2T^ix—K2—O19W^ix	73.7 (6)
O3A1—W7—K3	153.8 (4)	O5W—K2—O19W^ix	122.1 (6)
K7^iii—W7—K3	71.69 (19)	O16T—K2—W2A^ix	115.8 (7)
K4^iii—W7—K3	59.68 (17)	O1T^vii—K2—W2A^ix	149.0 (7)
O8T—W8—O8A	102.9 (8)	O24W—K2—W2A^ix	128.5 (11)
O8T—W8—O78	100.9 (8)	O23^ix—K2—W2A^ix	9.3 (6)
O8A—W8—O78	94.6 (8)	O2T^ix—K2—W2A^ix	57.5 (7)
O8T—W8—O89	100.4 (8)	O5W—K2—W2A^ix	70.1 (7)
O8A—W8—O89	94.5 (8)	O19W^ix—K2—W2A^ix	81.1 (6)
O78—W8—O89	154.3 (7)	O16T—K2—W2^ix	132.1 (4)
O8T—W8—O38	92.0 (8)	O1T^vii—K2—W2^ix	117.0 (5)
O8A—W8—O38	165.0 (8)	O24W—K2—W2^ix	134.9 (10)
O78—W8—O38	83.9 (7)	O23^ix—K2—W2^ix	30.9 (3)
O89—W8—O38	81.2 (7)	O2T^ix—K2—W2^ix	26.6 (4)
O8T—W8—O4A1	169.6 (7)	O5W—K2—W2^ix	101.4 (5)
O8A—W8—O4A1	84.2 (7)	O19W^ix—K2—W2^ix	69.2 (4)
O78—W8—O4A1	85.9 (7)	W2A^ix—K2—W2^ix	32.1 (6)
O89—W8—O4A1	71.2 (7)	O16T—K2—Na1	36.9 (4)
O38—W8—O4A1	80.8 (6)	O1T^vii—K2—Na1	87.8 (4)
O8T—W8—K4^iii	45.7 (6)	O24W—K2—Na1	127.9 (10)
O8A—W8—K4^iii	105.5 (6)	O23^ix—K2—Na1	84.4 (4)
O78—W8—K4^iii	55.3 (6)	O2T^ix—K2—Na1	108.8 (4)
O89—W8—K4^iii	143.2 (5)	O5W—K2—Na1	95.5 (5)
O38—W8—K4^iii	85.9 (5)	O19W^ix—K2—Na1	36.0 (6)
O4A1—W8—K4^iii	140.1 (4)	W2A^ix—K2—Na1	92.9 (6)
O8T—W8—K8	45.8 (6)	W2^ix—K2—Na1	97.2 (2)
O8A—W8—K8	142.3 (6)	O16T—K2—K7^x	164.2 (5)
O78—W8—K8	109.9 (6)	O1T^vii—K2—K7^x	101.2 (5)
O89—W8—K8	75.8 (5)	O24W—K2—K7^x	74.8 (10)
O38—W8—K8	50.6 (5)	O23^ix—K2—K7^x	76.1 (4)
O4A1—W8—K8	124.5 (5)	O2T^ix—K2—K7^x	50.6 (4)
K4^iii—W8—K8	69.4 (2)	O5W—K2—K7^x	90.5 (5)
O9T—W9—O9A	100.8 (8)	O19W^ix—K2—K7^x	124.3 (6)
O9T—W9—O49	104.5 (8)	W2A^ix—K2—K7^x	68.7 (6)
O9A—W9—O49	90.8 (8)	W2^ix—K2—K7^x	60.19 (18)
O9T—W9—O89	99.9 (8)	Na1—K2—K7^x	157.3 (3)
O9A—W9—O89	91.5 (7)	O16T—K2—W1^vii	86.6 (4)
O49—W9—O89	154.6 (8)	O1T^vii—K2—W1^vii	17.9 (4)
O9T—W9—O39	95.5 (8)	O24W—K2—W1^vii	89.0 (9)
O9A—W9—O39	163.7 (8)	O23^ix—K2—W1^vii	126.7 (4)
O49—W9—O39	84.8 (7)	O2T^ix—K2—W1^vii	79.7 (4)
O89—W9—O39	85.9 (7)	O5W—K2—W1^vii	157.3 (5)
O9T—W9—O4A1	171.0 (7)	O19W^ix—K2—W1^vii	66.4 (2)
O9A—W9—O4A1	82.9 (7)	W2A^ix—K2—W1^vii	132.3 (6)
O49—W9—O4A1	83.5 (7)	W2^ix—K2—W1^vii	101.33 (15)
O89—W9—O4A1	71.7 (7)	Na1—K2—W1^vii	80.97 (15)
O39—W9—O4A1	81.0 (7)	K7^x—K2—W1^vii	101.4 (2)
O9T—W9—Na2	39.8 (7)	O7T—K3—O3W	71.8 (6)
O9A—W9—Na2	61.4 (6)	O7T—K3—O14T^vi	124.4 (6)
O49—W9—Na2	109.0 (5)	O3W—K3—O14T^vi	92.7 (6)
O89—W9—Na2	94.2 (5)	O7T—K3—O11W^iii	85.7 (8)
O39—W9—Na2	134.8 (6)	O3W—K3—O11W^iii	155.9 (8)
O4A1—W9—Na2	141.7 (5)	O14T^vi—K3—O11W^iii	92.8 (8)
O10T—W10—W12A	112.0 (12)	O7T—K3—O18T^iii	158.1 (6)
O10T—W10—O103	104.3 (9)	O3W—K3—O18T^iii	129.8 (6)
W12A—W10—O103	64.2 (12)	O14T^vi—K3—O18T^iii	64.3 (5)
O10T—W10—O104	102.3 (9)	O11W^iii—K3—O18T^iii	73.3 (7)
W12A—W10—O104	140.3 (11)	O7T—K3—O128^iii	108.7 (6)
O103—W10—O104	89.0 (8)	O3W—K3—O128^iii	133.9 (6)
O10T—W10—O102	101.1 (9)	O14T^vi—K3—O128^iii	118.9 (6)
W12A—W10—O102	29.3 (10)	O11W^iii—K3—O128^iii	61.3 (7)
O103—W10—O102	93.0 (9)	O18T^iii—K3—O128^iii	55.8 (5)
O104—W10—O102	155.2 (8)	O7T—K3—O10W^iii	121.7 (7)
O10T—W10—O101	98.9 (9)	O3W—K3—O10W^iii	66.7 (7)
W12A—W10—O101	107.8 (12)	O14T^vi—K3—O10W^iii	97.0 (7)
O103—W10—O101	156.8 (8)	O11W^iii—K3—O10W^iii	135.6 (9)
O104—W10—O101	85.1 (8)	O18T^iii—K3—O10W^iii	72.5 (7)
O102—W10—O101	83.4 (9)	O128^iii—K3—O10W^iii	76.3 (7)
O10T—W10—W10A	107.8 (11)	O7T—K3—O12T^iii	66.3 (5)
W12A—W10—W10A	124.1 (13)	O3W—K3—O12T^iii	85.5 (6)
O103—W10—W10A	138.1 (10)	O14T^vi—K3—O12T^iii	167.9 (6)
O104—W10—W10A	58.5 (10)	O11W^iii—K3—O12T^iii	93.7 (7)
O102—W10—W10A	106.3 (11)	O18T^iii—K3—O12T^iii	108.0 (5)
O101—W10—W10A	27.1 (9)	O128^iii—K3—O12T^iii	56.4 (5)
O10T—W10—O1A2	169.1 (8)	O10W^iii—K3—O12T^iii	71.3 (7)
W12A—W10—O1A2	67.5 (10)	O7T—K3—W12^iii	84.6 (4)
O103—W10—O1A2	85.4 (7)	O3W—K3—W12^iii	110.4 (5)
O104—W10—O1A2	82.5 (7)	O14T^vi—K3—W12^iii	148.2 (4)
O102—W10—O1A2	73.1 (7)	O11W^iii—K3—W12^iii	75.1 (6)
O101—W10—O1A2	71.5 (7)	O18T^iii—K3—W12^iii	84.0 (4)
W10A—W10—O1A2	66.2 (9)	O128^iii—K3—W12^iii	29.7 (3)
O10T—W10—K5^iv	48.6 (7)	O10W^iii—K3—W12^iii	74.1 (6)
W12A—W10—K5^iv	155.7 (10)	O12T^iii—K3—W12^iii	26.9 (3)
O103—W10—K5^iv	103.3 (6)	O7T—K3—W18^iii	138.7 (5)
O104—W10—K5^iv	53.8 (5)	O3W—K3—W18^iii	134.8 (5)
O102—W10—K5^iv	148.1 (6)	O14T^vi—K3—W18^iii	89.8 (4)
O101—W10—K5^iv	91.3 (6)	O11W^iii—K3—W18^iii	68.6 (6)
W10A—W10—K5^iv	79.5 (8)	O18T^iii—K3—W18^iii	25.6 (4)
O1A2—W10—K5^iv	134.7 (4)	O128^iii—K3—W18^iii	30.7 (3)
O10T—W10—K7	70.4 (7)	O10W^iii—K3—W18^iii	68.3 (6)
W12A—W10—K7	56.9 (10)	O12T^iii—K3—W18^iii	83.1 (4)
O103—W10—K7	110.8 (6)	W12^iii—K3—W18^iii	58.41 (10)
O104—W10—K7	160.0 (5)	O7T—K3—K9^iii	121.9 (5)
O102—W10—K7	32.6 (6)	O3W—K3—K9^iii	139.8 (5)
O101—W10—K7	77.9 (6)	O14T^vi—K3—K9^iii	47.5 (4)
W10A—W10—K7	105.0 (9)	O11W^iii—K3—K9^iii	47.9 (7)
O1A2—W10—K7	101.8 (5)	O18T^iii—K3—K9^iii	46.0 (4)
K5^iv—W10—K7	115.53 (19)	O128^iii—K3—K9^iii	80.9 (4)
O101—W10A—O104	125 (3)	O10W^iii—K3—K9^iii	116.3 (6)
O101—W10A—W11	72 (2)	O12T^iii—K3—K9^iii	134.5 (5)
O104—W10A—W11	139.4 (17)	W12^iii—K3—K9^iii	108.5 (3)
O101—W10A—O115	126 (3)	W18^iii—K3—K9^iii	62.5 (2)
O104—W10A—O115	102.9 (16)	O7T—K3—W12A^iii	80.7 (6)
W11—W10A—O115	55.5 (10)	O3W—K3—W12A^iii	136.5 (7)
O101—W10A—W10	70 (2)	O14T^vi—K3—W12A^iii	130.8 (7)
O104—W10A—W10	56.2 (9)	O11W^iii—K3—W12A^iii	43.1 (8)
W11—W10A—W10	114.7 (14)	O18T^iii—K3—W12A^iii	79.7 (6)
O115—W10A—W10	138.9 (16)	O128^iii—K3—W12A^iii	31.5 (6)
O101—W10A—O1A2	86 (2)	O10W^iii—K3—W12A^iii	103.2 (7)
O104—W10A—O1A2	79.7 (12)	O12T^iii—K3—W12A^iii	52.3 (6)
W11—W10A—O1A2	63.7 (9)	W12^iii—K3—W12A^iii	32.2 (4)
O115—W10A—O1A2	79.8 (12)	W18^iii—K3—W12A^iii	58.4 (5)
W10—W10A—O1A2	62.9 (9)	K9^iii—K3—W12A^iii	83.4 (5)
O101—W10A—O17W	123 (3)	O12T—K4—O4W^v	85.7 (6)
O104—W10A—O17W	80.6 (14)	O12T—K4—O3W^v	90.5 (6)
W11—W10A—O17W	124.1 (16)	O4W^v—K4—O3W^v	135.1 (7)
O115—W10A—O17W	84.0 (15)	O12T—K4—O13W	80.9 (8)
W10—W10A—O17W	120.9 (16)	O4W^v—K4—O13W	144.6 (8)
O1A2—W10A—O17W	151.0 (17)	O3W^v—K4—O13W	78.0 (8)
O101—W10A—K5^iv	104 (2)	O12T—K4—O22W	98.1 (10)
O104—W10A—K5^iv	49.2 (8)	O4W^v—K4—O22W	69.3 (10)
W11—W10A—K5^iv	171.4 (13)	O3W^v—K4—O22W	155.0 (10)
O115—W10A—K5^iv	126.6 (13)	O13W—K4—O22W	80.4 (11)
W10—W10A—K5^iv	69.7 (8)	O12T—K4—O8T^v	170.2 (6)
O1A2—W10A—K5^iv	124.2 (11)	O4W^v—K4—O8T^v	84.7 (6)
O17W—W10A—K5^iv	51.3 (10)	O3W^v—K4—O8T^v	95.2 (6)
O11T—W11—O115	101.9 (9)	O13W—K4—O8T^v	108.1 (8)
O11T—W11—O116	101.2 (9)	O22W—K4—O8T^v	79.9 (10)
O115—W11—O116	87.6 (8)	O12T—K4—O7T^v	65.7 (5)
O11T—W11—O101	104.3 (9)	O4W^v—K4—O7T^v	71.5 (6)
O115—W11—O101	90.4 (8)	O3W^v—K4—O7T^v	66.2 (6)
O116—W11—O101	154.2 (8)	O13W—K4—O7T^v	129.5 (8)
O11T—W11—W11A	111.9 (11)	O22W—K4—O7T^v	138.6 (10)
O115—W11—W11A	137.0 (11)	O8T^v—K4—O7T^v	109.5 (6)
O116—W11—W11A	61.0 (11)	O12T—K4—O78^v	119.5 (6)
O101—W11—W11A	105.5 (11)	O4W^v—K4—O78^v	71.6 (6)
O11T—W11—O112	101.6 (9)	O3W^v—K4—O78^v	71.7 (6)
O115—W11—O112	156.3 (8)	O13W—K4—O78^v	143.0 (8)
O116—W11—O112	85.4 (8)	O22W—K4—O78^v	122.2 (10)
O101—W11—O112	86.3 (8)	O8T^v—K4—O78^v	55.5 (5)
W11A—W11—O112	25.5 (9)	O7T^v—K4—O78^v	54.0 (5)
O11T—W11—W10A	112.7 (11)	O12T—K4—W8^v	148.6 (5)
O115—W11—W10A	62.7 (11)	O4W^v—K4—W8^v	76.6 (5)
O116—W11—W10A	138.2 (10)	O3W^v—K4—W8^v	84.3 (5)
O101—W11—W10A	28.1 (9)	O13W—K4—W8^v	127.7 (7)
W11A—W11—W10A	121.9 (12)	O22W—K4—W8^v	99.5 (9)
O112—W11—W10A	109.8 (11)	O8T^v—K4—W8^v	25.5 (4)
O11T—W11—O1A2	172.9 (8)	O7T^v—K4—W8^v	84.0 (4)
O115—W11—O1A2	84.5 (7)	O78^v—K4—W8^v	30.0 (3)
O116—W11—O1A2	81.9 (7)	O12T—K4—W7^v	90.4 (4)
O101—W11—O1A2	72.4 (7)	O4W^v—K4—W7^v	67.7 (5)
W11A—W11—O1A2	63.8 (10)	O3W^v—K4—W7^v	67.5 (5)
O112—W11—O1A2	72.1 (7)	O13W—K4—W7^v	144.3 (7)
W10A—W11—O1A2	67.4 (10)	O22W—K4—W7^v	135.3 (9)
O112—W11A—W12	75 (2)	O8T^v—K4—W7^v	84.5 (4)
O112—W11A—W11	78 (2)	O7T^v—K4—W7^v	25.0 (4)
W12—W11A—W11	122.8 (16)	O78^v—K4—W7^v	29.1 (3)
O112—W11A—O116	133 (3)	W8^v—K4—W7^v	58.96 (12)
W12—W11A—O116	142.4 (18)	O12T—K4—K3^v	49.1 (4)
W11—W11A—O116	58.2 (10)	O4W^v—K4—K3^v	109.1 (5)
O112—W11A—O127	126 (3)	O3W^v—K4—K3^v	43.6 (5)
W12—W11A—O127	55.3 (10)	O13W—K4—K3^v	86.2 (7)
W11—W11A—O127	144.6 (18)	O22W—K4—K3^v	146.5 (9)
O116—W11A—O127	100.7 (16)	O8T^v—K4—K3^v	133.6 (4)
O112—W11A—O1A2	98 (3)	O7T^v—K4—K3^v	43.3 (4)
W12—W11A—O1A2	67.7 (10)	O78^v—K4—K3^v	86.2 (4)
W11—W11A—O1A2	66.9 (10)	W8^v—K4—K3^v	112.9 (2)
O116—W11A—O1A2	82.3 (13)	W7^v—K4—K3^v	62.78 (16)
O127—W11A—O1A2	83.3 (13)	O12T—K4—K7	50.3 (4)
O12T—W12—O127	104.9 (8)	O4W^v—K4—K7	41.5 (5)
O12T—W12—O128	102.8 (8)	O3W^v—K4—K7	106.5 (5)
O127—W12—O128	89.0 (8)	O13W—K4—K7	130.4 (7)
O12T—W12—O112	101.2 (9)	O22W—K4—K7	97.0 (9)
O127—W12—O112	90.2 (9)	O8T^v—K4—K7	120.2 (4)
O128—W12—O112	155.3 (8)	O7T^v—K4—K7	42.7 (4)
O12T—W12—W11A	115.2 (11)	O78^v—K4—K7	79.5 (4)
O127—W12—W11A	65.8 (11)	W8^v—K4—K7	101.7 (2)
O128—W12—W11A	138.3 (11)	W7^v—K4—K7	56.52 (18)
O112—W12—W11A	26.1 (9)	K3^v—K4—K7	69.0 (2)
O12T—W12—O102	97.9 (8)	O18T—K5—O5T	127.1 (6)
O127—W12—O102	157.1 (8)	O18T—K5—O12W^xi	87.2 (7)
O128—W12—O102	87.3 (8)	O5T—K5—O12W^xi	121.2 (7)
O112—W12—O102	83.9 (9)	O18T—K5—O1W	85.3 (7)
W11A—W12—O102	103.2 (11)	O5T—K5—O1W	70.1 (6)
O12T—W12—W12A	110.2 (10)	O12W^xi—K5—O1W	67.2 (7)
O127—W12—W12A	138.7 (10)	O18T—K5—O10T^xi	162.8 (7)
O128—W12—W12A	62.7 (10)	O5T—K5—O10T^xi	68.0 (6)
O112—W12—W12A	103.4 (10)	O12W^xi—K5—O10T^xi	76.8 (7)
W11A—W12—W12A	115.1 (12)	O1W—K5—O10T^xi	94.0 (7)
O102—W12—W12A	25.9 (9)	O18T—K5—O14T^xi	63.1 (5)
O12T—W12—O1A2	168.1 (7)	O5T—K5—O14T^xi	158.9 (6)
O127—W12—O1A2	85.7 (7)	O12W^xi—K5—O14T^xi	74.4 (6)
O128—W12—O1A2	82.5 (7)	O1W—K5—O14T^xi	131.0 (7)
O112—W12—O1A2	72.8 (7)	O10T^xi—K5—O14T^xi	105.8 (6)
W11A—W12—O1A2	63.7 (10)	O18T—K5—O104^xi	115.1 (6)
O102—W12—O1A2	71.5 (7)	O5T—K5—O104^xi	113.9 (6)
W12A—W12—O1A2	62.5 (9)	O12W^xi—K5—O104^xi	78.5 (6)
O12T—W12—K3^v	52.2 (6)	O1W—K5—O104^xi	139.3 (6)
O127—W12—K3^v	107.0 (6)	O10T^xi—K5—O104^xi	56.0 (5)
O128—W12—K3^v	51.1 (5)	O14T^xi—K5—O104^xi	52.0 (5)
O112—W12—K3^v	150.8 (6)	O18T—K5—O17W^xi	99.6 (8)
W11A—W12—K3^v	164.9 (9)	O5T—K5—O17W^xi	90.9 (9)
O102—W12—K3^v	88.0 (6)	O12W^xi—K5—O17W^xi	133.3 (9)
W12A—W12—K3^v	79.3 (8)	O1W—K5—O17W^xi	158.8 (9)
O1A2—W12—K3^v	130.5 (5)	O10T^xi—K5—O17W^xi	87.2 (8)
O12T—W12—K7	58.4 (6)	O14T^xi—K5—O17W^xi	68.3 (8)
O127—W12—K7	157.0 (6)	O104^xi—K5—O17W^xi	56.6 (8)
O128—W12—K7	109.2 (5)	O18T—K5—O6W	64.5 (6)
O112—W12—K7	79.0 (7)	O5T—K5—O6W	78.2 (6)
W11A—W12—K7	105.1 (10)	O12W^xi—K5—O6W	151.6 (7)
O102—W12—K7	42.4 (6)	O1W—K5—O6W	106.2 (7)
W12A—W12—K7	64.2 (8)	O10T^xi—K5—O6W	131.6 (7)
O1A2—W12—K7	109.9 (5)	O14T^xi—K5—O6W	93.4 (6)
K3^v—W12—K7	76.19 (19)	O104^xi—K5—O6W	114.4 (6)
O102—W12A—W10	83 (2)	O17W^xi—K5—O6W	59.1 (9)
O102—W12A—O103	141 (3)	O18T—K5—W10^xi	143.4 (5)
W10—W12A—O103	59.6 (11)	O5T—K5—W10^xi	88.9 (4)
O102—W12A—O128	117 (3)	O12W^xi—K5—W10^xi	76.9 (5)
W10—W12A—O128	142.3 (17)	O1W—K5—W10^xi	117.0 (5)
O103—W12A—O128	100.4 (16)	O10T^xi—K5—W10^xi	26.3 (4)
O102—W12A—W12	68 (2)	O14T^xi—K5—W10^xi	80.7 (4)
W10—W12A—W12	121.2 (16)	O104^xi—K5—W10^xi	29.8 (3)
O103—W12A—W12	139.9 (17)	O17W^xi—K5—W10^xi	70.4 (7)
O128—W12A—W12	52.4 (8)	O6W—K5—W10^xi	127.2 (5)
O102—W12A—O1A2	92 (2)	O18T—K5—K9	48.3 (5)
W10—W12A—O1A2	68.2 (10)	O5T—K5—K9	120.9 (5)
O103—W12A—O1A2	84.0 (13)	O12W^xi—K5—K9	117.3 (6)
O128—W12A—O1A2	78.7 (12)	O1W—K5—K9	130.6 (6)
W12—W12A—O1A2	63.7 (9)	O10T^xi—K5—K9	135.4 (5)
O102—W12A—K7	30.7 (19)	O14T^xi—K5—K9	48.7 (4)
W10—W12A—K7	97.7 (12)	O104^xi—K5—K9	84.1 (4)
O103—W12A—K7	137.7 (14)	O17W^xi—K5—K9	51.4 (7)
O128—W12A—K7	115.7 (12)	O6W—K5—K9	44.8 (5)
W12—W12A—K7	82.0 (9)	W10^xi—K5—K9	111.4 (3)
O1A2—W12A—K7	122.7 (12)	O18T—K5—W14^xi	86.4 (4)
O102—W12A—K3^v	97 (2)	O5T—K5—W14^xi	143.2 (5)
W10—W12A—K3^v	168.9 (14)	O12W^xi—K5—W14^xi	68.5 (5)
O103—W12A—K3^v	117.5 (13)	O1W—K5—W14^xi	135.2 (6)
O128—W12A—K3^v	47.0 (8)	O10T^xi—K5—W14^xi	82.0 (4)
W12—W12A—K3^v	68.5 (7)	O14T^xi—K5—W14^xi	23.8 (3)
O1A2—W12A—K3^v	122.8 (11)	O104^xi—K5—W14^xi	29.5 (3)
K7—W12A—K3^v	77.6 (6)	O17W^xi—K5—W14^xi	65.9 (7)
O13T—W13—O13A	101.8 (9)	O6W—K5—W14^xi	109.5 (5)
O13T—W13—O138	102.4 (9)	W10^xi—K5—W14^xi	57.16 (11)
O13A—W13—O138	93.8 (9)	K9—K5—W14^xi	67.4 (3)
O13T—W13—O134	98.9 (9)	W1A—K6—O28W	108.3 (11)
O13A—W13—O134	96.5 (8)	W1A—K6—O15W^xi	95.0 (11)
O138—W13—O134	153.9 (8)	O28W—K6—O15W^xi	149.2 (9)
O13T—W13—O103	92.8 (9)	W1A—K6—O2T^viii	86.6 (8)
O13A—W13—O103	165.4 (8)	O28W—K6—O2T^viii	85.8 (10)
O138—W13—O103	83.1 (8)	O15W^xi—K6—O2T^viii	75.6 (9)
O134—W13—O103	80.9 (7)	W1A—K6—O8W^xi	137.2 (10)
O13T—W13—O2A2	168.6 (8)	O28W—K6—O8W^xi	91.5 (13)
O13A—W13—O2A2	84.6 (8)	O15W^xi—K6—O8W^xi	84.1 (11)
O138—W13—O2A2	86.3 (7)	O2T^viii—K6—O8W^xi	133.5 (8)
O134—W13—O2A2	70.9 (7)	W1A—K6—O26	48.7 (8)
O103—W13—O2A2	80.9 (7)	O28W—K6—O26	70.3 (6)
O14T—W14—O14A	101.8 (8)	O15W^xi—K6—O26	139.6 (10)
O14T—W14—O145	102.4 (8)	O2T^viii—K6—O26	112.9 (6)
O14A—W14—O145	92.9 (8)	O8W^xi—K6—O26	109.7 (8)
O14T—W14—O134	101.7 (8)	W1A—K6—O15	39.0 (8)
O14A—W14—O134	91.0 (8)	O28W—K6—O15	138.1 (6)
O145—W14—O134	154.2 (8)	O15W^xi—K6—O15	72.2 (9)
O14T—W14—O104	94.0 (8)	O2T^viii—K6—O15	110.4 (6)
O14A—W14—O104	164.1 (7)	O8W^xi—K6—O15	102.3 (7)
O145—W14—O104	85.9 (7)	O26—K6—O15	67.8 (6)
O134—W14—O104	83.5 (7)	W1A—K6—O12	17.0 (7)
O14T—W14—O2A2	171.7 (7)	O28W—K6—O12	100.4 (11)
O14A—W14—O2A2	82.2 (7)	O15W^xi—K6—O12	96.4 (10)
O145—W14—O2A2	84.5 (7)	O2T^viii—K6—O12	70.7 (6)
O134—W14—O2A2	70.8 (7)	O8W^xi—K6—O12	154.2 (8)
O104—W14—O2A2	81.9 (6)	O26—K6—O12	54.9 (6)
O14T—W14—K5^iv	47.1 (6)	O15—K6—O12	54.2 (5)
O14A—W14—K5^iv	143.8 (6)	W1A—K6—O56	69.1 (8)
O145—W14—K5^iv	109.9 (6)	O28W—K6—O56	101.8 (7)
O134—W14—K5^iv	80.6 (6)	O15W^xi—K6—O56	105.2 (9)
O104—W14—K5^iv	49.9 (5)	O2T^viii—K6—O56	155.8 (6)
O2A2—W14—K5^iv	126.4 (4)	O8W^xi—K6—O56	69.9 (7)
O14T—W14—K3^vi	33.9 (6)	O26—K6—O56	50.9 (5)
O14A—W14—K3^vi	72.3 (5)	O15—K6—O56	49.6 (5)
O145—W14—K3^vi	119.7 (6)	O12—K6—O56	85.2 (5)
O134—W14—K3^vi	85.8 (6)	W1A—K6—O26W^xi	156.2 (12)
O104—W14—K3^vi	121.9 (5)	O28W—K6—O26W^xi	76.7 (11)
O2A2—W14—K3^vi	145.0 (5)	O15W^xi—K6—O26W^xi	74.0 (13)
K5^iv—W14—K3^vi	71.98 (15)	O2T^viii—K6—O26W^xi	70.3 (11)
O15T—W15—O15A	102.9 (9)	O8W^xi—K6—O26W^xi	64.0 (11)
O15T—W15—O145	103.3 (9)	O26—K6—O26W^xi	146.3 (11)
O15A—W15—O145	92.8 (8)	O15—K6—O26W^xi	144.7 (11)
O15T—W15—O156	100.6 (9)	O12—K6—O26W^xi	141.0 (11)
O15A—W15—O156	95.1 (8)	O56—K6—O26W^xi	133.7 (11)
O145—W15—O156	152.5 (8)	W1A—K6—W5	65.1 (7)
O15T—W15—O115	93.4 (8)	O28W—K6—W5	131.8 (6)
O15A—W15—O115	163.6 (8)	O15W^xi—K6—W5	75.9 (9)
O145—W15—O115	82.2 (8)	O2T^viii—K6—W5	137.4 (5)
O156—W15—O115	82.9 (8)	O8W^xi—K6—W5	73.3 (6)
O15T—W15—O3A2	170.5 (8)	O26—K6—W5	72.5 (4)
O15A—W15—O3A2	83.4 (7)	O15—K6—W5	29.7 (3)
O145—W15—O3A2	83.3 (7)	O12—K6—W5	81.8 (4)
O156—W15—O3A2	71.5 (7)	O56—K6—W5	30.1 (3)
O115—W15—O3A2	80.6 (7)	O26W^xi—K6—W5	129.4 (10)
O16T—W16—O16A	98.6 (8)	W1A—K6—W2	31.5 (7)
O16T—W16—O167	100.6 (8)	O28W—K6—W2	76.9 (8)
O16A—W16—O167	91.4 (7)	O15W^xi—K6—W2	125.4 (9)
O16T—W16—O156	101.1 (8)	O2T^viii—K6—W2	87.4 (5)
O16A—W16—O156	91.5 (7)	O8W^xi—K6—W2	137.0 (7)
O167—W16—O156	157.3 (8)	O26—K6—W2	27.4 (4)
O16T—W16—O116	97.2 (8)	O15—K6—W2	66.0 (4)
O16A—W16—O116	164.2 (7)	O12—K6—W2	30.0 (4)
O167—W16—O116	86.0 (7)	O56—K6—W2	72.2 (4)
O156—W16—O116	85.2 (7)	O26W^xi—K6—W2	146.5 (10)
O16T—W16—O3A2	172.4 (7)	W5—K6—W2	83.9 (2)
O16A—W16—O3A2	82.6 (7)	O102—K7—O26W	90.7 (13)
O167—W16—O3A2	86.8 (7)	O102—K7—O15W	87.0 (9)
O156—W16—O3A2	71.3 (7)	O26W—K7—O15W	81.4 (14)
O116—W16—O3A2	81.7 (7)	O102—K7—O4W^v	126.8 (7)
O16T—W16—Na1	43.5 (6)	O26W—K7—O4W^v	132.8 (13)
O16A—W16—Na1	55.5 (6)	O15W—K7—O4W^v	122.6 (10)
O167—W16—Na1	105.2 (5)	O102—K7—O7T^v	95.2 (7)
O156—W16—Na1	94.9 (5)	O26W—K7—O7T^v	75.6 (12)
O116—W16—Na1	140.1 (6)	O15W—K7—O7T^v	157.0 (10)
O3A2—W16—Na1	136.0 (5)	O4W^v—K7—O7T^v	73.8 (6)
O16T—W16—K1^vii	50.7 (6)	O102—K7—O27^v	148.4 (7)
O16A—W16—K1^vii	98.7 (5)	O26W—K7—O27^v	77.5 (12)
O167—W16—K1^vii	50.0 (5)	O15W—K7—O27^v	119.3 (9)
O156—W16—K1^vii	151.0 (6)	O4W^v—K7—O27^v	55.4 (6)
O116—W16—K1^vii	91.6 (5)	O7T^v—K7—O27^v	53.6 (5)
O3A2—W16—K1^vii	136.7 (4)	O102—K7—O2T^v	149.9 (7)
Na1—W16—K1^vii	69.65 (14)	O26W—K7—O2T^v	72.8 (12)
O17T—W17—O17A	101.8 (8)	O15W—K7—O2T^v	66.1 (9)
O17T—W17—O167	99.1 (8)	O4W^v—K7—O2T^v	81.2 (6)
O17A—W17—O167	95.6 (8)	O7T^v—K7—O2T^v	104.5 (6)
O17T—W17—O178	100.1 (8)	O27^v—K7—O2T^v	53.5 (5)
O17A—W17—O178	94.4 (8)	O102—K7—O12T	55.1 (6)
O167—W17—O178	156.0 (7)	O26W—K7—O12T	118.5 (12)
O17T—W17—O127	92.2 (8)	O15W—K7—O12T	134.7 (9)
O17A—W17—O127	166.0 (8)	O4W^v—K7—O12T	75.2 (6)
O167—W17—O127	83.3 (8)	O7T^v—K7—O12T	61.3 (5)
O178—W17—O127	81.7 (7)	O27^v—K7—O12T	105.1 (5)
O17T—W17—O4A2	170.6 (7)	O2T^v—K7—O12T	155.0 (6)
O17A—W17—O4A2	85.2 (8)	O102—K7—W12A	10.2 (6)
O167—W17—O4A2	86.4 (7)	O26W—K7—W12A	82.1 (13)
O178—W17—O4A2	72.8 (7)	O15W—K7—W12A	91.1 (10)
O127—W17—O4A2	80.8 (7)	O4W^v—K7—W12A	130.9 (7)
O17T—W17—K1^vii	48.6 (6)	O7T^v—K7—W12A	87.8 (7)
O17A—W17—K1^vii	101.9 (6)	O27^v—K7—W12A	139.6 (7)
O167—W17—K1^vii	50.5 (6)	O2T^v—K7—W12A	147.9 (7)
O178—W17—K1^vii	146.9 (5)	O12T—K7—W12A	56.3 (6)
O127—W17—K1^vii	88.2 (6)	O102—K7—W12	29.7 (4)
O4A2—W17—K1^vii	136.6 (4)	O26W—K7—W12	112.2 (12)
O18T—W18—O18A	100.9 (8)	O15W—K7—W12	109.8 (8)
O18T—W18—O138	102.8 (8)	O4W^v—K7—W12	97.6 (5)
O18A—W18—O138	91.3 (8)	O7T^v—K7—W12	81.2 (4)
O18T—W18—O178	99.7 (8)	O27^v—K7—W12	130.8 (4)
O18A—W18—O178	91.5 (7)	O2T^v—K7—W12	173.4 (5)
O138—W18—O178	156.4 (8)	O12T—K7—W12	26.7 (3)
O18T—W18—O128	94.8 (8)	W12A—K7—W12	33.8 (5)
O18A—W18—O128	164.2 (7)	O102—K7—W7^v	117.9 (5)
O138—W18—O128	86.5 (8)	O26W—K7—W7^v	69.6 (12)
O178—W18—O128	84.5 (7)	O15W—K7—W7^v	141.0 (8)
O18T—W18—O4A2	170.7 (8)	O4W^v—K7—W7^v	67.7 (5)
O18A—W18—O4A2	83.2 (7)	O7T^v—K7—W7^v	24.1 (4)
O138—W18—O4A2	85.3 (7)	O27^v—K7—W7^v	30.5 (3)
O178—W18—O4A2	71.8 (7)	O2T^v—K7—W7^v	80.5 (4)
O128—W18—O4A2	81.0 (6)	O12T—K7—W7^v	83.2 (4)
O18T—W18—K3^v	46.5 (6)	W12A—K7—W7^v	109.4 (6)
O18A—W18—K3^v	145.7 (5)	W12—K7—W7^v	105.1 (3)
O138—W18—K3^v	105.0 (6)	O102—K7—W2^v	164.6 (6)
O178—W18—K3^v	85.3 (5)	O26W—K7—W2^v	73.9 (12)
O128—W18—K3^v	49.3 (5)	O15W—K7—W2^v	91.2 (8)
O4A2—W18—K3^v	127.4 (4)	O4W^v—K7—W2^v	66.4 (5)
O18T—W18—K5	30.1 (6)	O7T^v—K7—W2^v	80.6 (4)
O18A—W18—K5	72.9 (5)	O27^v—K7—W2^v	28.3 (3)
O138—W18—K5	113.7 (6)	O2T^v—K7—W2^v	25.2 (3)
O178—W18—K5	89.5 (5)	O12T—K7—W2^v	132.0 (4)
O128—W18—K5	122.1 (5)	W12A—K7—W2^v	155.3 (6)
O4A2—W18—K5	149.3 (4)	W12—K7—W2^v	158.6 (3)
K3^v—W18—K5	72.85 (15)	W7^v—K7—W2^v	56.59 (15)
O18T—W18—K9	36.8 (7)	O5W^ii—K8—O8T	119.7 (7)
O18A—W18—K9	102.0 (6)	O5W^ii—K8—O3T	63.1 (6)
O138—W18—K9	66.0 (6)	O8T—K8—O3T	109.0 (6)
O178—W18—K9	135.9 (6)	O5W^ii—K8—O38	85.2 (7)
O128—W18—K9	91.3 (5)	O8T—K8—O38	54.5 (5)
O4A2—W18—K9	150.7 (5)	O3T—K8—O38	55.5 (5)
K3^v—W18—K9	60.1 (2)	O5W^ii—K8—O22W^iii	73.0 (10)
K5—W18—K9	56.3 (2)	O8T—K8—O22W^iii	75.4 (9)
O2A1—As1—O3A1	109.6 (8)	O3T—K8—O22W^iii	131.6 (10)
O2A1—As1—O1A1	109.2 (8)	O38—K8—O22W^iii	103.4 (10)
O3A1—As1—O1A1	109.3 (8)	O5W^ii—K8—O15T^ii	80.7 (7)
O2A1—As1—O4A1	107.4 (8)	O8T—K8—O15T^ii	159.2 (7)
O3A1—As1—O4A1	111.6 (8)	O3T—K8—O15T^ii	75.4 (6)
O1A1—As1—O4A1	109.8 (8)	O38—K8—O15T^ii	129.8 (6)
O4A2—As2—O1A2	109.0 (8)	O22W^iii—K8—O15T^ii	117.6 (10)
O4A2—As2—O3A2	109.6 (8)	O5W^ii—K8—W3	71.5 (5)
O1A2—As2—O3A2	110.1 (8)	O8T—K8—W3	82.8 (4)
O4A2—As2—O2A2	110.9 (9)	O3T—K8—W3	26.7 (4)
O1A2—As2—O2A2	108.6 (9)	O38—K8—W3	28.8 (4)
O3A2—As2—O2A2	108.5 (8)	O22W^iii—K8—W3	120.6 (9)
O9A—Mn1—O9A^vi	94.2 (11)	O15T^ii—K8—W3	101.7 (5)
O9A—Mn1—O2M4^vi	176.9 (8)	O5W^ii—K8—W8	111.9 (6)
O9A^vi—Mn1—O2M4^vi	87.9 (8)	O8T—K8—W8	24.7 (4)
O9A—Mn1—O2M4	87.9 (8)	O3T—K8—W8	84.5 (5)
O9A^vi—Mn1—O2M4	176.9 (8)	O38—K8—W8	31.9 (4)
O2M4^vi—Mn1—O2M4	90.1 (11)	O22W^iii—K8—W8	94.1 (9)
O9A—Mn1—O1M1^vi	86.9 (7)	O15T^ii—K8—W8	148.3 (5)
O9A^vi—Mn1—O1M1^vi	84.4 (7)	W3—K8—W8	58.91 (18)
O2M4^vi—Mn1—O1M1^vi	95.6 (7)	O5W^ii—K8—K4^iii	85.2 (6)
O2M4—Mn1—O1M1^vi	93.5 (7)	O8T—K8—K4^iii	40.5 (4)
O9A—Mn1—O1M1	84.4 (7)	O3T—K8—K4^iii	113.7 (5)
O9A^vi—Mn1—O1M1	86.9 (7)	O38—K8—K4^iii	66.0 (4)
O2M4^vi—Mn1—O1M1	93.5 (7)	O22W^iii—K8—K4^iii	40.4 (9)
O2M4—Mn1—O1M1	95.6 (7)	O15T^ii—K8—K4^iii	157.3 (5)
O1M1^vi—Mn1—O1M1	167.2 (11)	W3—K8—K4^iii	90.5 (3)
O5A—Mn2—O18A	92.2 (8)	W8—K8—K4^iii	54.21 (19)
O5A—Mn2—O24M	87.7 (8)	O6W—K9—O18T	69.2 (7)
O18A—Mn2—O24M	179.3 (9)	O6W—K9—O14T^xi	108.0 (8)
O5A—Mn2—O25M	179.0 (8)	O18T—K9—O14T^xi	63.4 (6)
O18A—Mn2—O25M	87.7 (8)	O6W—K9—O11W	125.4 (10)
O24M—Mn2—O25M	92.4 (8)	O18T—K9—O11W	72.7 (8)
O5A—Mn2—O1M2	84.8 (7)	O14T^xi—K9—O11W	87.4 (8)
O18A—Mn2—O1M2	86.6 (7)	O6W—K9—O17W^xi	64.6 (9)
O24M—Mn2—O1M2	94.0 (7)	O18T—K9—O17W^xi	96.9 (9)
O25M—Mn2—O1M2	94.2 (7)	O14T^xi—K9—O17W^xi	70.8 (9)
O5A—Mn2—O2M2	86.5 (7)	O11W—K9—O17W^xi	158.2 (11)
O18A—Mn2—O2M2	84.6 (7)	O6W—K9—K5	55.8 (6)
O24M—Mn2—O2M2	94.7 (7)	O18T—K9—K5	44.6 (4)
O25M—Mn2—O2M2	94.5 (7)	O14T^xi—K9—K5	52.3 (4)
O1M2—Mn2—O2M2	167.4 (7)	O11W—K9—K5	114.2 (7)
O14A^vi—Mn3—O7A	91.2 (7)	O17W^xi—K9—K5	52.3 (8)
O14A^vi—Mn3—O2M3	87.6 (8)	O6W—K9—K3^v	116.7 (7)
O7A—Mn3—O2M3	176.5 (8)	O18T—K9—K3^v	47.6 (5)
O14A^vi—Mn3—O34M	177.5 (8)	O14T^xi—K9—K3^v	44.4 (4)
O7A—Mn3—O34M	87.9 (8)	O11W—K9—K3^v	45.3 (6)
O2M3—Mn3—O34M	93.4 (8)	O17W^xi—K9—K3^v	113.6 (8)
O14A^vi—Mn3—O1M3	86.0 (8)	K5—K9—K3^v	74.1 (3)
O7A—Mn3—O1M3	84.3 (8)	O6W—K9—W18	65.6 (6)
O2M3—Mn3—O1M3	92.4 (8)	O18T—K9—W18	21.5 (4)
O34M—Mn3—O1M3	96.3 (8)	O14T^xi—K9—W18	83.8 (5)
O14A^vi—Mn3—O3M3	86.3 (7)	O11W—K9—W18	64.6 (7)
O7A—Mn3—O3M3	87.6 (7)	O17W^xi—K9—W18	111.7 (8)
O2M3—Mn3—O3M3	95.5 (7)	K5—K9—W18	61.9 (3)
O34M—Mn3—O3M3	91.3 (8)	K3^v—K9—W18	57.4 (2)
O1M3—Mn3—O3M3	168.7 (7)	O19W^ix—Na1—O2W	106.3 (6)
O1M4^vi—Mn4—O1M4	82.2 (9)	O19W^ix—Na1—O2W^vi	106.3 (6)
O1M4^vi—Mn4—O34M	172.4 (8)	O2W—Na1—O2W^vi	147.4 (12)
O1M4—Mn4—O34M	94.2 (8)	O19W^ix—Na1—O16T	89.8 (6)
O1M4^vi—Mn4—O24M	90.7 (8)	O2W—Na1—O16T	96.9 (6)
O1M4—Mn4—O24M	172.0 (8)	O2W^vi—Na1—O16T	83.2 (6)
O34M—Mn4—O24M	92.4 (8)	O19W^ix—Na1—O16T^vi	89.8 (6)
O1M4^vi—Mn4—O2M4	93.8 (8)	O2W—Na1—O16T^vi	83.2 (6)
O1M4—Mn4—O2M4	91.1 (8)	O2W^vi—Na1—O16T^vi	96.9 (6)
O34M—Mn4—O2M4	93.0 (8)	O16T—Na1—O16T^vi	179.6 (12)
O24M—Mn4—O2M4	93.2 (7)	O19W^ix—Na1—O16A	150.8 (4)
O1M4^vi—Mn4—O1M5^vi	82.5 (8)	O2W—Na1—O16A	73.5 (6)
O1M4—Mn4—O1M5^vi	82.0 (8)	O2W^vi—Na1—O16A	78.1 (7)
O34M—Mn4—O1M5^vi	90.5 (8)	O16T—Na1—O16A	61.7 (6)
O24M—Mn4—O1M5^vi	93.4 (8)	O16T^vi—Na1—O16A	118.7 (8)
O2M4—Mn4—O1M5^vi	172.5 (8)	O19W^ix—Na1—O16A^vi	150.8 (4)
O1M4^vi—Mn4—Mn4^vi	41.7 (6)	O2W—Na1—O16A^vi	78.1 (7)
O1M4—Mn4—Mn4^vi	41.1 (6)	O2W^vi—Na1—O16A^vi	73.5 (6)
O34M—Mn4—Mn4^vi	135.3 (6)	O16T—Na1—O16A^vi	118.7 (8)
O24M—Mn4—Mn4^vi	132.3 (6)	O16T^vi—Na1—O16A^vi	61.7 (6)
O2M4—Mn4—Mn4^vi	87.9 (5)	O16A—Na1—O16A^vi	58.3 (7)
O1M5^vi—Mn4—Mn4^vi	84.9 (5)	O19W^ix—Na1—W16^vi	118.2 (2)
O1M4^vi—Mn4—Mn5	42.9 (6)	O2W—Na1—W16^vi	82.1 (5)
O1M4—Mn4—Mn5	84.4 (6)	O2W^vi—Na1—W16^vi	82.6 (5)
O34M—Mn4—Mn5	130.4 (6)	O16T—Na1—W16^vi	151.2 (8)
O24M—Mn4—Mn5	87.9 (5)	O16T^vi—Na1—W16^vi	29.1 (4)
O2M4—Mn4—Mn5	136.6 (5)	O16A—Na1—W16^vi	90.9 (5)
O1M5^vi—Mn4—Mn5	40.1 (5)	O16A^vi—Na1—W16^vi	32.8 (3)
Mn4^vi—Mn4—Mn5	61.07 (13)	O19W^ix—Na1—W16	118.2 (2)
O1M4^vi—Mn4—Mn5^vi	84.4 (6)	O2W—Na1—W16	82.6 (5)
O1M4—Mn4—Mn5^vi	42.6 (6)	O2W^vi—Na1—W16	82.1 (5)
O34M—Mn4—Mn5^vi	88.5 (6)	O16T—Na1—W16	29.1 (5)
O24M—Mn4—Mn5^vi	133.2 (6)	O16T^vi—Na1—W16	151.2 (8)
O2M4—Mn4—Mn5^vi	133.6 (5)	O16A—Na1—W16	32.8 (3)
O1M5^vi—Mn4—Mn5^vi	39.8 (5)	O16A^vi—Na1—W16	90.9 (5)
Mn4^vi—Mn4—Mn5^vi	60.59 (12)	W16^vi—Na1—W16	123.6 (5)
Mn5—Mn4—Mn5^vi	57.91 (16)	O19W^ix—Na1—K2	49.6 (2)
O1M5—Mn5—O1M5^vi	82.5 (9)	O2W—Na1—K2	95.1 (5)
O1M5—Mn5—O25M	174.2 (8)	O2W^vi—Na1—K2	106.0 (5)
O1M5^vi—Mn5—O25M	92.1 (8)	O16T—Na1—K2	42.3 (5)
O1M5—Mn5—O2M3^vi	94.2 (8)	O16T^vi—Na1—K2	137.3 (7)
O1M5^vi—Mn5—O2M3^vi	173.6 (8)	O16A—Na1—K2	101.3 (3)
O25M—Mn5—O2M3^vi	91.0 (8)	O16A^vi—Na1—K2	159.5 (5)
O1M5—Mn5—O56M	90.3 (8)	W16^vi—Na1—K2	166.3 (4)
O1M5^vi—Mn5—O56M	93.9 (8)	W16—Na1—K2	68.99 (12)
O25M—Mn5—O56M	92.1 (8)	O19W^ix—Na1—K2^vi	49.6 (2)
O2M3^vi—Mn5—O56M	91.5 (8)	O2W—Na1—K2^vi	106.0 (5)
O1M5—Mn5—O1M4^vi	83.9 (8)	O2W^vi—Na1—K2^vi	95.1 (5)
O1M5^vi—Mn5—O1M4^vi	83.8 (8)	O16T—Na1—K2^vi	137.3 (7)
O25M—Mn5—O1M4^vi	93.5 (8)	O16T^vi—Na1—K2^vi	42.3 (5)
O2M3^vi—Mn5—O1M4^vi	90.4 (8)	O16A—Na1—K2^vi	159.5 (5)
O56M—Mn5—O1M4^vi	174.0 (8)	O16A^vi—Na1—K2^vi	101.3 (3)
O1M5—Mn5—Mn5^vi	41.4 (6)	W16^vi—Na1—K2^vi	68.98 (12)
O1M5^vi—Mn5—Mn5^vi	41.3 (6)	W16—Na1—K2^vi	166.3 (4)
O25M—Mn5—Mn5^vi	133.3 (6)	K2—Na1—K2^vi	99.2 (4)
O2M3^vi—Mn5—Mn5^vi	135.6 (6)	O19W^ix—Na1—K1^vii	87.8 (2)
O56M—Mn5—Mn5^vi	89.4 (6)	O2W—Na1—K1^vii	140.7 (5)
O1M4^vi—Mn5—Mn5^vi	85.2 (6)	O2W^vi—Na1—K1^vii	41.2 (5)
O1M5—Mn5—Mn4	86.0 (6)	O16T—Na1—K1^vii	45.6 (4)
O1M5^vi—Mn5—Mn4	44.4 (6)	O16T^vi—Na1—K1^vii	134.3 (4)
O25M—Mn5—Mn4	88.8 (6)	O16A—Na1—K1^vii	76.9 (4)
O2M3^vi—Mn5—Mn4	130.2 (6)	O16A^vi—Na1—K1^vii	107.2 (4)
O56M—Mn5—Mn4	138.3 (6)	W16^vi—Na1—K1^vii	123.7 (2)
O1M4^vi—Mn5—Mn4	39.9 (6)	W16—Na1—K1^vii	58.77 (10)
Mn5^vi—Mn5—Mn4	61.29 (12)	K2—Na1—K1^vii	66.09 (17)
O1M5—Mn5—Mn4^vi	44.1 (6)	K2^vi—Na1—K1^vii	110.8 (3)
O1M5^vi—Mn5—Mn4^vi	85.6 (6)	O9T—Na2—O9T^vi	161.0 (13)
O25M—Mn5—Mn4^vi	133.8 (6)	O9T—Na2—O18W	93.5 (9)
O2M3^vi—Mn5—Mn4^vi	88.3 (6)	O9T^vi—Na2—O18W	78.8 (9)
O56M—Mn5—Mn4^vi	134.1 (6)	O9T—Na2—O18W^vi	78.8 (9)
O1M4^vi—Mn5—Mn4^vi	40.3 (6)	O9T^vi—Na2—O18W^vi	93.5 (9)
Mn5^vi—Mn5—Mn4^vi	60.80 (12)	O18W—Na2—O18W^vi	132.4 (18)
Mn4—Mn5—Mn4^vi	58.34 (17)	O9T—Na2—W9	25.8 (5)
O16A^vi—Mn6—O16A	91.7 (10)	O9T^vi—Na2—W9	135.4 (9)
O16A^vi—Mn6—O56M	177.5 (8)	O18W—Na2—W9	78.4 (8)
O16A—Mn6—O56M	87.8 (7)	O18W^vi—Na2—W9	75.1 (8)
O16A^vi—Mn6—O56M^vi	87.8 (7)	O9T—Na2—W9^vi	135.4 (9)
O16A—Mn6—O56M^vi	177.5 (8)	O9T^vi—Na2—W9^vi	25.8 (5)
O56M—Mn6—O56M^vi	92.7 (12)	O18W—Na2—W9^vi	75.1 (8)
O16A^vi—Mn6—O1M6^vi	83.8 (7)	O18W^vi—Na2—W9^vi	78.4 (8)
O16A—Mn6—O1M6^vi	87.9 (7)	W9—Na2—W9^vi	110.5 (6)
O56M—Mn6—O1M6^vi	93.7 (8)	Na1—O2W—K1^ix	104.5 (7)
O56M^vi—Mn6—O1M6^vi	94.6 (8)	K3—O3W—K4^iii	91.7 (6)
O16A^vi—Mn6—O1M6	87.9 (7)	K4^iii—O4W—K7^iii	97.9 (7)
O16A—Mn6—O1M6	83.8 (7)	K8^ix—O5W—K2	140.3 (9)
O56M—Mn6—O1M6	94.6 (8)	K9—O6W—K5	79.4 (7)
O56M^vi—Mn6—O1M6	93.7 (8)	K3^v—O11W—K9	86.8 (9)
O1M6^vi—Mn6—O1M6	168.0 (11)	K6^iv—O15W—K7	100.5 (13)
W1—O1T—K2^i	132.7 (10)	W10A—O17W—K9^iv	140.5 (17)
W1—O1T—K1	95.3 (8)	W10A—O17W—K5^iv	89.1 (13)
K2^i—O1T—K1	99.9 (6)	K9^iv—O17W—K5^iv	76.3 (9)
W2—O2T—K6^viii	138.8 (10)	Na1^ii—O19W—K2^i	94.4 (5)
W2—O2T—K2^ii	105.1 (8)	Na1^ii—O19W—K2^ii	94.4 (5)
K6^viii—O2T—K2^ii	115.0 (7)	K2^i—O19W—K2^ii	171.2 (11)
W2—O2T—K7^iii	102.6 (8)	K4—O22W—K8^v	95.9 (13)
K6^viii—O2T—K7^iii	90.1 (6)	K7—O26W—K6^iv	86.9 (15)
K2^ii—O2T—K7^iii	85.3 (5)	K6—O28W—K6^viii	123 (2)
W3—O3T—K8	102.6 (8)

Symmetry codes: (i) −x+3/2, y−1/2, z; (ii) x+1/2, y−1/2, −z+3/2; (iii) −x+3/2, −y+1/2, z−1/2; (iv) x−1/2, −y+1/2, −z+2; (v) −x+3/2, −y+1/2, z+1/2; (vi) −x+1, y, −z+3/2; (vii) −x+3/2, y+1/2, z; (viii) −x+2, y, −z+3/2; (ix) x−1/2, y+1/2, −z+3/2; (x) −x+1, −y+1, −z+2; (xi) x+1/2, −y+1/2, −z+2.