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Simple treatment of [FeIII(oep)Cl] (where oep is octaethylporphyrin) with dilute perchloric acid leads to facile preparation of the title compound, [Fe(C36H44N4)(CH4O)2](ClO4).2CH4O. The structure consists of discrete [Fe(oep)(HOCH3)2]+ cations, perchlorate anions and methanol molecules of solvation, which are connected by hydrogen bonds in an infinite network. The Fe atom is located in the plane of the N atoms and is coordinated by two methanol O atoms in the axial position, with an average Fe-N distance of 2.026 (3) Å and Fe-O bond lengths of 2.159 (3) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks compound, global

fcf

Structure factor file (CIF format)
Contains datablock ms200a

CCDC reference: 126324

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