energy materials
In the last few decades Li-ion batteries changed the way we store energy, becoming a key element of our everyday life. Their continuous improvement is tightly bound to the understanding of lithium (de)intercalation phenomena in electrode materials. Here we address the use of operando diffraction techniques to understand these mechanisms. We focus on powerful probes such as neutrons and synchrotron X-ray radiation, which have become increasingly familiar to the electrochemical community. After discussing the general benefits (and drawbacks) of these characterization techniques and the work of customization required to adapt standard electrochemical cells to an operando diffraction experiment, we highlight several very recent results. We concentrate on important electrode materials such as the spinels Li1 + xMn2 − xO4 (0 ≤ x ≤ 0.10) and LiNi0.4Mn1.6O4. Thorough investigations led by operando neutron powder diffraction demonstrated that neutrons are highly sensitive to structural parameters that cannot be captured by other means (for example, atomic Debye–Waller factors and lithium site occupancy). Synchrotron radiation X-ray powder diffraction reveals how LiMn2O4 is subject to irreversibility upon the first electrochemical cycle, resulting in severe Bragg peak broadening. Even more interestingly, we show for the first time an ordering scheme of the elusive composition Li0.5Mn2O4, through the coexistence of Mn3+:Mn4+ 1:3 cation ordering and lithium/vacancy ordering. More accurately written as Li0.5Mn3+0.5Mn4+1.5O4, this intermediate phase loses the symmetry, to be correctly described in the P213 space group.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S2052520615017199/kc5017sup1.cif | |
Rietveld powder data file (CIF format) https://doi.org/10.1107/S2052520615017199/kc5017Isup2.rtv | |
Text file https://doi.org/10.1107/S2052520615017199/kc5017sup3.txt |
(I) top
Crystal data top
Li0.5Mn2O4 | a = 8.152889 (13) Å |
Mr = 177.34 | V = 541.92 (1) Å3 |
Cubic, P213 | Z = 8 |
Hall symbol: P 2ac 2ab 3 | T = 293 K |
Data collection top
Alba MSPD Beam Line diffractometer | 2θmin = 1.132°, 2θmax = 50.110°, 2θstep = 0.006° |
Radiation source: Synchrotron |
Refinement top
Rp = 4.698 | 8164 data points |
Rwp = 8.007 | 16 parameters |
Rexp = 1.171 | 0 restraints |
RBragg = 8.057 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
O1 | 0.387 (7) | 0.387 (7) | 0.387 (7) | 0.02956* | |
O2 | 0.142 (9) | −0.135 (6) | 0.136 (6) | 0.02956* | |
O3 | 0.869 (6) | 0.869 (6) | 0.869 (6) | 0.02956* | |
O4 | 0.104 (6) | 0.119 (5) | 0.396 (6) | 0.02956* | |
Li1 | 0.01100 | 0.01100 | 0.01100 | 0.01267* | |
Mn1 | 0.626 (2) | 0.626 (2) | 0.626 (2) | 0.03257* | |
Mn2 | 0.128 (2) | 0.3798 (13) | −0.1274 (14) | 0.03257* |
Geometric parameters (Å, º) top
O1—O2i | 2.90 (8) | O4—Li1i | 3.44 (5) |
O1—O2ii | 2.90 (8) | O4—Mn1xxi | 2.01 (4) |
O1—O2iii | 2.90 (8) | O4—Mn2xxii | 3.31 (5) |
O1—O3iv | 2.89 (8) | O4—Mn2xxxv | 1.90 (5) |
O1—O3v | 2.89 (8) | O4—Mn2x | 1.89 (5) |
O1—O3vi | 2.89 (8) | Li1—O1xxxvi | 3.50 (6) |
O1—O4 | 3.18 (7) | Li1—O1xxii | 3.50 (6) |
O1—O4vii | 2.50 (8) | Li1—O1xvii | 3.50 (6) |
O1—O4viii | 3.18 (8) | Li1—O2 | 1.90 (5) |
O1—O4ix | 2.50 (7) | Li1—O2viii | 1.90 (6) |
O1—O4x | 3.18 (7) | Li1—O2x | 1.90 (5) |
O1—O4xi | 2.50 (7) | Li1—O3xx | 2.01 (5) |
O1—Li1xii | 3.50 (6) | Li1—O4 | 3.35 (5) |
O1—Li1xiii | 3.50 (6) | Li1—O4xxii | 3.42 (4) |
O1—Li1i | 3.50 (6) | Li1—O4xvii | 3.44 (5) |
O1—Mn1 | 3.37 (6) | Li1—O4viii | 3.35 (4) |
O1—Mn2xiv | 1.91 (6) | Li1—O4xxxvii | 3.42 (5) |
O1—Mn2xv | 1.91 (6) | Li1—O4xviii | 3.44 (5) |
O1—Mn2xvi | 1.91 (6) | Li1—O4x | 3.35 (5) |
O2—O1xvii | 2.90 (8) | Li1—O4xxxviii | 3.42 (5) |
O2—O2viii | 3.16 (8) | Li1—O4xxxix | 3.44 (4) |
O2—O2xviii | 2.60 (7) | Li1—Mn1xxi | 3.299 (16) |
O2—O2x | 3.16 (7) | Li1—Mn1xl | 3.299 (16) |
O2—O2xix | 2.60 (8) | Li1—Mn1xli | 3.299 (16) |
O2—O3xx | 3.11 (8) | Li1—Mn2 | 3.351 (11) |
O2—O3xxi | 2.66 (8) | Li1—Mn2xxxvi | 3.380 (16) |
O2—O4 | 2.98 (7) | Li1—Mn2xlii | 3.495 (12) |
O2—O4xxii | 2.85 (7) | Li1—Mn2viii | 3.351 (15) |
O2—O4xvii | 2.85 (8) | Li1—Mn2xliii | 3.380 (12) |
O2—O4xviii | 3.01 (8) | Li1—Mn2xliv | 3.495 (11) |
O2—O4x | 2.85 (7) | Li1—Mn2x | 3.351 (12) |
O2—Li1 | 1.90 (5) | Li1—Mn2xxiii | 3.380 (11) |
O2—Mn1xxi | 1.95 (5) | Li1—Mn2xlv | 3.495 (15) |
O2—Mn2i | 3.35 (6) | Mn1—O1 | 3.37 (6) |
O2—Mn2viii | 1.94 (7) | Mn1—O2vii | 1.95 (5) |
O2—Mn2xxiii | 1.94 (5) | Mn1—O2ix | 1.95 (5) |
O3—O1xxiv | 2.89 (8) | Mn1—O2xi | 1.95 (7) |
O3—O1xxv | 2.89 (8) | Mn1—O3 | 3.43 (5) |
O3—O1xxvi | 2.89 (8) | Mn1—O4vii | 2.01 (4) |
O3—O2xxvii | 3.11 (8) | Mn1—O4ix | 2.01 (5) |
O3—O2vii | 2.66 (8) | Mn1—O4xi | 2.01 (5) |
O3—O2xxviii | 3.11 (7) | Mn1—Li1vii | 3.299 (16) |
O3—O2ix | 2.66 (8) | Mn1—Li1xxxii | 3.299 (16) |
O3—O2xxix | 3.11 (8) | Mn1—Li1xiv | 3.299 (16) |
O3—O2xi | 2.66 (7) | Mn1—Mn2xxxii | 2.88 (2) |
O3—O4xxv | 2.81 (7) | Mn1—Mn2xiv | 2.93 (2) |
O3—O4xxx | 2.81 (7) | Mn1—Mn2xxxiii | 2.88 (2) |
O3—O4xxxi | 2.81 (7) | Mn1—Mn2xv | 2.93 (2) |
O3—Li1xxvii | 2.01 (5) | Mn1—Mn2xxxiv | 2.88 (2) |
O3—Mn1 | 3.43 (5) | Mn1—Mn2xvi | 2.93 (2) |
O3—Mn2xxxii | 1.97 (5) | Mn2—O1xli | 1.91 (6) |
O3—Mn2xxxiii | 1.97 (5) | Mn2—O2xvii | 3.35 (6) |
O3—Mn2xxxiv | 1.97 (5) | Mn2—O2xlvi | 1.94 (7) |
O4—O1 | 3.18 (7) | Mn2—O2x | 1.94 (5) |
O4—O1xxi | 2.50 (8) | Mn2—O3xl | 1.97 (5) |
O4—O2 | 2.98 (7) | Mn2—O4xiii | 3.31 (5) |
O4—O2xiii | 2.85 (7) | Mn2—O4viii | 1.89 (5) |
O4—O2i | 2.85 (8) | Mn2—O4xxxix | 1.90 (5) |
O4—O2viii | 2.85 (8) | Mn2—Li1 | 3.351 (11) |
O4—O2xix | 3.01 (7) | Mn2—Li1xii | 3.380 (16) |
O4—O3v | 2.81 (7) | Mn2—Li1xlvii | 3.495 (12) |
O4—O4viii | 3.28 (6) | Mn2—Mn1xl | 2.88 (2) |
O4—O4xviii | 2.57 (6) | Mn2—Mn1xli | 2.93 (2) |
O4—O4x | 3.28 (7) | Mn2—Mn2xliii | 2.864 (16) |
O4—O4xix | 2.57 (6) | Mn2—Mn2xxxvii | 2.861 (19) |
O4—Li1 | 3.35 (5) | Mn2—Mn2xlviii | 2.861 (16) |
O4—Li1xiii | 3.42 (4) | Mn2—Mn2iii | 2.86 (2) |
O2i—O1—O2ii | 120 (3) | O1xxxvi—Li1—O2viii | 102 (3) |
O2i—O1—O2iii | 120 (3) | O1xxxvi—Li1—O2x | 56 (3) |
O2i—O1—O3iv | 172 (3) | O1xxxvi—Li1—O3xx | 56 (2) |
O2i—O1—O3v | 55 (3) | O1xxxvi—Li1—O4 | 151 (3) |
O2i—O1—O3vi | 65 (3) | O1xxxvi—Li1—O4xxii | 110 (2) |
O2i—O1—O4 | 56 (2) | O1xxxvi—Li1—O4xvii | 95 (2) |
O2i—O1—O4vii | 63 (3) | O1xxxvi—Li1—O4viii | 94 (2) |
O2i—O1—O4viii | 118 (3) | O1xxxvi—Li1—O4xxxvii | 54.7 (17) |
O2i—O1—O4ix | 90 (3) | O1xxxvi—Li1—O4xviii | 145 (3) |
O2i—O1—O4x | 88 (3) | O1xxxvi—Li1—O4x | 117 (2) |
O2i—O1—O4xi | 125 (3) | O1xxxvi—Li1—O4xxxix | 54.5 (16) |
O2i—O1—Li1xii | 147 (2) | O1xxxvi—Li1—Mn1xxi | 174 (2) |
O2i—O1—Li1xiii | 88 (2) | O1xxxvi—Li1—Mn1xl | 83.0 (16) |
O2i—O1—Mn1 | 93 (2) | O1xxxvi—Li1—Mn1xli | 87.3 (17) |
O2i—O1—Mn2xiv | 138 (3) | O1xxxvi—Li1—Mn2 | 63.7 (14) |
O2i—O1—Mn2xv | 95 (3) | O1xxxvi—Li1—Mn2xxxvi | 86.0 (16) |
O2ii—O1—O2iii | 120 (4) | O1xxxvi—Li1—Mn2viii | 127 (2) |
O2ii—O1—O3iv | 55 (3) | O1xxxvi—Li1—Mn2xliv | 79.8 (15) |
O2ii—O1—O3v | 65 (3) | O1xxxvi—Li1—Mn2x | 132 (2) |
O2ii—O1—O3vi | 172 (4) | O1xxxvi—Li1—Mn2xxiii | 123 (2) |
O2ii—O1—O4 | 88 (3) | O1xxxvi—Li1—Mn2xlv | 62.3 (14) |
O2ii—O1—O4vii | 125 (4) | O1xxii—Li1—O1xvii | 91 (2) |
O2ii—O1—O4viii | 56 (2) | O1xxii—Li1—O2 | 102 (4) |
O2ii—O1—O4ix | 63 (3) | O1xxii—Li1—O2viii | 56 (3) |
O2ii—O1—O4x | 118 (3) | O1xxii—Li1—O2x | 144 (4) |
O2ii—O1—O4xi | 90 (4) | O1xxii—Li1—O3xx | 56 (2) |
O2ii—O1—Li1xii | 88 (2) | O1xxii—Li1—O4 | 94 (2) |
O2ii—O1—Li1i | 147 (3) | O1xxii—Li1—O4xxii | 54.7 (16) |
O2ii—O1—Mn1 | 93 (3) | O1xxii—Li1—O4xvii | 145 (3) |
O2ii—O1—Mn2xv | 138 (4) | O1xxii—Li1—O4viii | 117 (2) |
O2ii—O1—Mn2xvi | 95 (3) | O1xxii—Li1—O4xviii | 54.5 (17) |
O2iii—O1—O3iv | 65 (3) | O1xxii—Li1—O4x | 151 (3) |
O2iii—O1—O3v | 172 (4) | O1xxii—Li1—O4xxxviii | 110 (2) |
O2iii—O1—O3vi | 55 (3) | O1xxii—Li1—O4xxxix | 95 (2) |
O2iii—O1—O4 | 118 (3) | O1xxii—Li1—Mn1xxi | 87.3 (17) |
O2iii—O1—O4vii | 90 (3) | O1xxii—Li1—Mn1xl | 174 (2) |
O2iii—O1—O4viii | 88 (3) | O1xxii—Li1—Mn1xli | 83.0 (16) |
O2iii—O1—O4ix | 125 (4) | O1xxii—Li1—Mn2 | 127 (2) |
O2iii—O1—O4x | 56 (3) | O1xxii—Li1—Mn2xlii | 79.8 (16) |
O2iii—O1—O4xi | 63 (3) | O1xxii—Li1—Mn2viii | 132 (2) |
O2iii—O1—Li1xiii | 147 (3) | O1xxii—Li1—Mn2xliii | 123 (2) |
O2iii—O1—Li1i | 88 (2) | O1xxii—Li1—Mn2xliv | 62.3 (14) |
O2iii—O1—Mn1 | 93 (2) | O1xxii—Li1—Mn2x | 63.7 (14) |
O2iii—O1—Mn2xiv | 95 (3) | O1xxii—Li1—Mn2xxiii | 86.0 (16) |
O2iii—O1—Mn2xvi | 138 (4) | O1xvii—Li1—O2 | 56 (3) |
O3iv—O1—O3v | 120 (3) | O1xvii—Li1—O2viii | 144 (4) |
O3iv—O1—O3vi | 120 (3) | O1xvii—Li1—O2x | 102 (3) |
O3iv—O1—O4 | 117 (3) | O1xvii—Li1—O3xx | 56 (2) |
O3iv—O1—O4vii | 124 (3) | O1xvii—Li1—O4 | 117 (2) |
O3iv—O1—O4viii | 55 (2) | O1xvii—Li1—O4xvii | 54.5 (17) |
O3iv—O1—O4ix | 91 (3) | O1xvii—Li1—O4viii | 151 (3) |
O3iv—O1—O4x | 90 (3) | O1xvii—Li1—O4xxxvii | 110 (2) |
O3iv—O1—O4xi | 62 (3) | O1xvii—Li1—O4xviii | 95 (2) |
O3iv—O1—Li1xiii | 86 (2) | O1xvii—Li1—O4x | 94 (2) |
O3iv—O1—Li1i | 149 (2) | O1xvii—Li1—O4xxxviii | 54.7 (17) |
O3iv—O1—Mn1 | 93 (2) | O1xvii—Li1—O4xxxix | 145 (3) |
O3iv—O1—Mn2xv | 93 (3) | O1xvii—Li1—Mn1xxi | 83.0 (16) |
O3iv—O1—Mn2xvi | 140 (3) | O1xvii—Li1—Mn1xl | 87.3 (17) |
O3v—O1—O3vi | 120 (3) | O1xvii—Li1—Mn1xli | 174 (2) |
O3v—O1—O4 | 55 (2) | O1xvii—Li1—Mn2 | 132 (2) |
O3v—O1—O4vii | 91 (3) | O1xvii—Li1—Mn2xxxvi | 123 (2) |
O3v—O1—O4viii | 90 (3) | O1xvii—Li1—Mn2xlii | 62.3 (14) |
O3v—O1—O4ix | 62 (3) | O1xvii—Li1—Mn2viii | 63.7 (14) |
O3v—O1—O4x | 117 (3) | O1xvii—Li1—Mn2xliii | 86.0 (16) |
O3v—O1—O4xi | 124 (3) | O1xvii—Li1—Mn2x | 127 (2) |
O3v—O1—Li1xii | 149 (2) | O1xvii—Li1—Mn2xlv | 79.8 (16) |
O3v—O1—Li1i | 86 (2) | O2—Li1—O2viii | 113 (5) |
O3v—O1—Mn1 | 93 (2) | O2—Li1—O2x | 113 (4) |
O3v—O1—Mn2xiv | 93 (3) | O2—Li1—O3xx | 106 (4) |
O3v—O1—Mn2xv | 140 (3) | O2—Li1—O4 | 62 (3) |
O3vi—O1—O4 | 90 (3) | O2—Li1—O4xxii | 56 (3) |
O3vi—O1—O4vii | 62 (3) | O2—Li1—O4xvii | 56 (3) |
O3vi—O1—O4viii | 117 (3) | O2—Li1—O4viii | 109 (3) |
O3vi—O1—O4ix | 124 (3) | O2—Li1—O4xxxvii | 144 (4) |
O3vi—O1—O4x | 55 (2) | O2—Li1—O4xviii | 61 (3) |
O3vi—O1—O4xi | 91 (3) | O2—Li1—O4x | 58 (3) |
O3vi—O1—Li1xii | 86 (2) | O2—Li1—O4xxxviii | 102 (3) |
O3vi—O1—Li1xiii | 149 (2) | O2—Li1—O4xxxix | 153 (4) |
O3vi—O1—Mn1 | 93 (2) | O2—Li1—Mn1xl | 82 (3) |
O3vi—O1—Mn2xiv | 140 (3) | O2—Li1—Mn1xli | 127 (3) |
O3vi—O1—Mn2xvi | 93 (3) | O2—Li1—Mn2 | 126 (3) |
O4—O1—O4vii | 119 (3) | O2—Li1—Mn2xxxvi | 122 (3) |
O4—O1—O4viii | 62 (2) | O2—Li1—Mn2xlii | 118 (3) |
O4—O1—O4ix | 117 (3) | O2—Li1—Mn2xliii | 122 (3) |
O4—O1—O4x | 62 (2) | O2—Li1—Mn2xliv | 77 (3) |
O4—O1—O4xi | 178 (3) | O2—Li1—Mn2x | 83 (3) |
O4—O1—Li1xii | 113 (2) | O2—Li1—Mn2xlv | 118 (3) |
O4—O1—Li1xiii | 61.3 (18) | O2viii—Li1—O2x | 113 (5) |
O4—O1—Li1i | 61.9 (18) | O2viii—Li1—O3xx | 106 (4) |
O4—O1—Mn1 | 143 (2) | O2viii—Li1—O4 | 58 (3) |
O4—O1—Mn2xiv | 130 (3) | O2viii—Li1—O4xxii | 102 (3) |
O4—O1—Mn2xv | 133 (3) | O2viii—Li1—O4xvii | 153 (4) |
O4—O1—Mn2xvi | 84 (3) | O2viii—Li1—O4viii | 62 (3) |
O4vii—O1—O4viii | 178 (4) | O2viii—Li1—O4xxxvii | 56 (3) |
O4vii—O1—O4ix | 62 (3) | O2viii—Li1—O4xviii | 56 (3) |
O4vii—O1—O4x | 117 (3) | O2viii—Li1—O4x | 109 (4) |
O4vii—O1—O4xi | 62 (3) | O2viii—Li1—O4xxxviii | 144 (4) |
O4vii—O1—Li1xii | 117 (3) | O2viii—Li1—O4xxxix | 61 (3) |
O4vii—O1—Li1xiii | 120 (3) | O2viii—Li1—Mn1xxi | 82 (3) |
O4vii—O1—Li1i | 67 (2) | O2viii—Li1—Mn1xl | 127 (4) |
O4vii—O1—Mn2xiv | 96 (3) | O2viii—Li1—Mn2 | 83 (3) |
O4vii—O1—Mn2xv | 49 (3) | O2viii—Li1—Mn2xlii | 118 (3) |
O4vii—O1—Mn2xvi | 49 (3) | O2viii—Li1—Mn2viii | 126 (4) |
O4viii—O1—O4ix | 119 (3) | O2viii—Li1—Mn2xliii | 122 (3) |
O4viii—O1—O4x | 62 (2) | O2viii—Li1—Mn2xliv | 118 (3) |
O4viii—O1—O4xi | 117 (3) | O2viii—Li1—Mn2xxiii | 122 (3) |
O4viii—O1—Li1xii | 61.3 (19) | O2viii—Li1—Mn2xlv | 77 (3) |
O4viii—O1—Li1xiii | 61.9 (19) | O2x—Li1—O3xx | 106 (4) |
O4viii—O1—Li1i | 113 (2) | O2x—Li1—O4 | 109 (3) |
O4viii—O1—Mn1 | 143 (2) | O2x—Li1—O4xxii | 144 (4) |
O4viii—O1—Mn2xiv | 84 (3) | O2x—Li1—O4xvii | 61 (3) |
O4viii—O1—Mn2xv | 130 (3) | O2x—Li1—O4viii | 58 (3) |
O4viii—O1—Mn2xvi | 133 (3) | O2x—Li1—O4xxxvii | 102 (4) |
O4ix—O1—O4x | 178 (3) | O2x—Li1—O4xviii | 153 (4) |
O4ix—O1—O4xi | 62 (3) | O2x—Li1—O4x | 62 (3) |
O4ix—O1—Li1xii | 120 (3) | O2x—Li1—O4xxxviii | 56 (3) |
O4ix—O1—Li1xiii | 67 (2) | O2x—Li1—O4xxxix | 56 (3) |
O4ix—O1—Li1i | 117 (2) | O2x—Li1—Mn1xxi | 127 (3) |
O4ix—O1—Mn2xiv | 49 (3) | O2x—Li1—Mn1xli | 82 (3) |
O4ix—O1—Mn2xv | 96 (3) | O2x—Li1—Mn2xxxvi | 122 (3) |
O4ix—O1—Mn2xvi | 49 (3) | O2x—Li1—Mn2xlii | 77 (3) |
O4x—O1—O4xi | 119 (3) | O2x—Li1—Mn2viii | 83 (3) |
O4x—O1—Li1xii | 61.9 (18) | O2x—Li1—Mn2xliv | 118 (3) |
O4x—O1—Li1xiii | 113 (2) | O2x—Li1—Mn2x | 126 (3) |
O4x—O1—Li1i | 61.3 (18) | O2x—Li1—Mn2xxiii | 122 (3) |
O4x—O1—Mn1 | 143 (2) | O2x—Li1—Mn2xlv | 118 (3) |
O4x—O1—Mn2xiv | 133 (3) | O3xx—Li1—O4 | 145 (3) |
O4x—O1—Mn2xv | 84 (3) | O3xx—Li1—O4xxii | 55 (2) |
O4x—O1—Mn2xvi | 130 (3) | O3xx—Li1—O4xvii | 101 (3) |
O4xi—O1—Li1xii | 67 (2) | O3xx—Li1—O4viii | 145 (3) |
O4xi—O1—Li1xiii | 117 (3) | O3xx—Li1—O4xxxvii | 55 (2) |
O4xi—O1—Li1i | 120 (2) | O3xx—Li1—O4xviii | 101 (3) |
O4xi—O1—Mn2xiv | 49 (3) | O3xx—Li1—O4x | 145 (3) |
O4xi—O1—Mn2xv | 49 (3) | O3xx—Li1—O4xxxviii | 55 (2) |
O4xi—O1—Mn2xvi | 96 (3) | O3xx—Li1—O4xxxix | 101 (3) |
Li1xii—O1—Li1xiii | 114.8 (13) | O3xx—Li1—Mn1xxi | 119 (3) |
Li1xii—O1—Li1i | 114.8 (13) | O3xx—Li1—Mn1xl | 119 (3) |
Li1xii—O1—Mn1 | 103.4 (14) | O3xx—Li1—Mn1xli | 119 (3) |
Li1xii—O1—Mn2xiv | 74 (2) | O3xx—Li1—Mn2 | 119 (2) |
Li1xii—O1—Mn2xv | 71 (2) | O3xx—Li1—Mn2xxxvi | 77 (2) |
Li1xii—O1—Mn2xvi | 163 (2) | O3xx—Li1—Mn2viii | 119 (2) |
Li1xiii—O1—Li1i | 114.8 (13) | O3xx—Li1—Mn2xliii | 77 (2) |
Li1xiii—O1—Mn1 | 103.4 (14) | O3xx—Li1—Mn2x | 119 (2) |
Li1xiii—O1—Mn2xiv | 71 (2) | O3xx—Li1—Mn2xxiii | 77 (2) |
Li1xiii—O1—Mn2xv | 163 (2) | O4—Li1—O4xxii | 95.7 (19) |
Li1xiii—O1—Mn2xvi | 74 (2) | O4—Li1—O4xvii | 97 (2) |
Li1i—O1—Mn1 | 103.4 (14) | O4—Li1—O4viii | 58.8 (15) |
Li1i—O1—Mn2xiv | 163 (2) | O4—Li1—O4xxxvii | 114 (2) |
Li1i—O1—Mn2xv | 74 (2) | O4—Li1—O4x | 58.8 (17) |
Li1i—O1—Mn2xvi | 71 (2) | O4—Li1—O4xxxviii | 154 (3) |
Mn1—O1—Mn2xiv | 60 (2) | O4—Li1—O4xxxix | 96 (2) |
Mn1—O1—Mn2xv | 60 (2) | O4—Li1—Mn1xl | 92.3 (16) |
Mn1—O1—Mn2xvi | 60 (2) | O4—Li1—Mn1xli | 64.8 (13) |
Mn2xiv—O1—Mn2xv | 97 (3) | O4—Li1—Mn2 | 90.9 (15) |
Mn2xiv—O1—Mn2xvi | 97 (3) | O4—Li1—Mn2xxxvi | 82.9 (14) |
Mn2xv—O1—Mn2xvi | 97 (3) | O4—Li1—Mn2xlii | 173.4 (19) |
O1xvii—O2—O2viii | 117 (3) | O4—Li1—Mn2viii | 67.6 (13) |
O1xvii—O2—O2xviii | 89 (3) | O4—Li1—Mn2xliii | 137.1 (18) |
O1xvii—O2—O2x | 91 (3) | O4—Li1—Mn2xliv | 127.5 (17) |
O1xvii—O2—O2xix | 123 (4) | O4—Li1—Mn2xxiii | 86.1 (13) |
O1xvii—O2—O3xx | 57 (3) | O4—Li1—Mn2xlv | 125.1 (17) |
O1xvii—O2—O3xxi | 62 (3) | O4xxii—Li1—O4xvii | 91.3 (19) |
O1xvii—O2—O4 | 170 (3) | O4xxii—Li1—O4viii | 154 (2) |
O1xvii—O2—O4xxii | 52 (3) | O4xxii—Li1—O4xxxvii | 90.7 (18) |
O1xvii—O2—O4xvii | 67 (3) | O4xxii—Li1—O4xviii | 57.2 (15) |
O1xvii—O2—O4xviii | 120 (3) | O4xxii—Li1—O4x | 114 (2) |
O1xvii—O2—O4x | 121 (3) | O4xxii—Li1—O4xxxviii | 90.7 (19) |
O1xvii—O2—Li1 | 91 (3) | O4xxii—Li1—O4xxxix | 148 (2) |
O1xvii—O2—Mn1xxi | 136 (3) | O4xxii—Li1—Mn1xxi | 64.0 (12) |
O1xvii—O2—Mn2i | 91 (2) | O4xxii—Li1—Mn1xl | 126.0 (16) |
O1xvii—O2—Mn2viii | 94 (3) | O4xxii—Li1—Mn1xli | 133.1 (16) |
O2viii—O2—O2xviii | 119 (3) | O4xxii—Li1—Mn2 | 173.0 (16) |
O2viii—O2—O2x | 60 (3) | O4xxii—Li1—Mn2xxxvi | 86.0 (13) |
O2viii—O2—O2xix | 120 (4) | O4xxii—Li1—Mn2xlii | 79.8 (13) |
O2viii—O2—O3xx | 60 (3) | O4xxii—Li1—Mn2viii | 82.4 (13) |
O2viii—O2—O3xxi | 179 (4) | O4xxii—Li1—Mn2xliii | 122.7 (16) |
O2viii—O2—O4 | 55 (2) | O4xxii—Li1—Mn2x | 88.6 (13) |
O2viii—O2—O4xxii | 90 (3) | O4xxii—Li1—Mn2xlv | 61.2 (11) |
O2viii—O2—O4xvii | 120 (4) | O4xvii—Li1—O4viii | 96.3 (19) |
O2viii—O2—O4xviii | 55 (2) | O4xvii—Li1—O4xxxvii | 148 (2) |
O2viii—O2—O4x | 92 (3) | O4xvii—Li1—O4xviii | 116 (2) |
O2viii—O2—Mn1xxi | 85 (3) | O4xvii—Li1—O4xxxviii | 57.2 (16) |
O2viii—O2—Mn2i | 144 (3) | O4xvii—Li1—O4xxxix | 116 (2) |
O2viii—O2—Mn2viii | 134 (4) | O4xvii—Li1—Mn1xxi | 83.2 (14) |
O2viii—O2—Mn2xxiii | 131 (3) | O4xvii—Li1—Mn1xli | 131.5 (17) |
O2xviii—O2—O2x | 178 (3) | O4xvii—Li1—Mn2 | 85.7 (13) |
O2xviii—O2—O2xix | 60 (3) | O4xvii—Li1—Mn2xxxvi | 177.3 (19) |
O2xviii—O2—O3xx | 119 (3) | O4xvii—Li1—Mn2xlii | 87.6 (14) |
O2xviii—O2—O3xxi | 61 (3) | O4xvii—Li1—Mn2xliii | 66.1 (12) |
O2xviii—O2—O4 | 90 (3) | O4xvii—Li1—Mn2xliv | 85.1 (14) |
O2xviii—O2—O4xxii | 63 (3) | O4xvii—Li1—Mn2x | 129.7 (17) |
O2xviii—O2—O4xvii | 122 (3) | O4xvii—Li1—Mn2xxiii | 62.1 (12) |
O2xviii—O2—O4xviii | 64 (3) | O4xvii—Li1—Mn2xlv | 129.3 (18) |
O2xviii—O2—O4x | 122 (3) | O4viii—Li1—O4xxxvii | 96 (2) |
O2xviii—O2—Li1 | 145 (3) | O4viii—Li1—O4xviii | 97.5 (19) |
O2xviii—O2—Mn1xxi | 48 (2) | O4viii—Li1—O4x | 58.8 (15) |
O2xviii—O2—Mn2viii | 94 (4) | O4viii—Li1—O4xxxviii | 114 (2) |
O2xviii—O2—Mn2xxiii | 48 (2) | O4viii—Li1—Mn1xxi | 92.3 (14) |
O2x—O2—O2xix | 122 (3) | O4viii—Li1—Mn1xl | 64.8 (12) |
O2x—O2—O3xx | 60 (2) | O4viii—Li1—Mn2xxxvi | 86.1 (14) |
O2x—O2—O3xxi | 121 (3) | O4viii—Li1—Mn2xlii | 125.1 (16) |
O2x—O2—O4 | 90 (3) | O4viii—Li1—Mn2viii | 90.9 (13) |
O2x—O2—O4xxii | 115 (3) | O4viii—Li1—Mn2xliii | 82.9 (13) |
O2x—O2—O4xvii | 60 (3) | O4viii—Li1—Mn2xliv | 173.4 (16) |
O2x—O2—O4xviii | 115 (3) | O4viii—Li1—Mn2x | 67.6 (12) |
O2x—O2—O4x | 59 (3) | O4viii—Li1—Mn2xxiii | 137.1 (15) |
O2x—O2—Mn1xxi | 132 (3) | O4viii—Li1—Mn2xlv | 127.5 (16) |
O2x—O2—Mn2i | 147 (2) | O4xxxvii—Li1—O4xviii | 91 (2) |
O2x—O2—Mn2viii | 88 (3) | O4xxxvii—Li1—O4x | 154 (3) |
O2x—O2—Mn2xxiii | 132 (3) | O4xxxvii—Li1—O4xxxviii | 91 (2) |
O2xix—O2—O3xx | 179 (4) | O4xxxvii—Li1—O4xxxix | 57.2 (15) |
O2xix—O2—O3xxi | 61 (3) | O4xxxvii—Li1—Mn1xxi | 126.0 (18) |
O2xix—O2—O4 | 65 (3) | O4xxxvii—Li1—Mn1xl | 133.1 (18) |
O2xix—O2—O4xxii | 123 (4) | O4xxxvii—Li1—Mn1xli | 64.0 (12) |
O2xix—O2—O4xvii | 89 (3) | O4xxxvii—Li1—Mn2 | 88.6 (14) |
O2xix—O2—O4xviii | 89 (4) | O4xxxvii—Li1—Mn2xlii | 61.2 (12) |
O2xix—O2—O4x | 63 (3) | O4xxxvii—Li1—Mn2viii | 173.0 (19) |
O2xix—O2—Li1 | 142 (4) | O4xxxvii—Li1—Mn2xliii | 86.0 (14) |
O2xix—O2—Mn1xxi | 48 (3) | O4xxxvii—Li1—Mn2xliv | 79.8 (13) |
O2xix—O2—Mn2viii | 48 (3) | O4xxxvii—Li1—Mn2x | 82.4 (14) |
O2xix—O2—Mn2xxiii | 94 (3) | O4xxxvii—Li1—Mn2xxiii | 122.7 (16) |
O3xx—O2—O3xxi | 120 (3) | O4xviii—Li1—O4x | 96 (2) |
O3xx—O2—O4 | 115 (3) | O4xviii—Li1—O4xxxviii | 148 (2) |
O3xx—O2—O4xxii | 56 (2) | O4xviii—Li1—O4xxxix | 116 (2) |
O3xx—O2—O4xvii | 92 (3) | O4xviii—Li1—Mn1xl | 131.5 (18) |
O3xx—O2—O4xviii | 89 (3) | O4xviii—Li1—Mn1xli | 83.2 (13) |
O3xx—O2—O4x | 119 (3) | O4xviii—Li1—Mn2 | 129.7 (17) |
O3xx—O2—Mn1xxi | 131 (3) | O4xviii—Li1—Mn2xxxvi | 62.1 (12) |
O3xx—O2—Mn2i | 144 (2) | O4xviii—Li1—Mn2xlii | 129.3 (17) |
O3xx—O2—Mn2viii | 134 (3) | O4xviii—Li1—Mn2viii | 85.7 (14) |
O3xx—O2—Mn2xxiii | 86 (3) | O4xviii—Li1—Mn2xliii | 177.3 (19) |
O3xxi—O2—O4 | 125 (3) | O4xviii—Li1—Mn2xliv | 87.6 (14) |
O3xxi—O2—O4xxii | 89 (3) | O4xviii—Li1—Mn2xxiii | 66.1 (12) |
O3xxi—O2—O4xvii | 61 (3) | O4xviii—Li1—Mn2xlv | 85.1 (14) |
O3xxi—O2—O4xviii | 124 (3) | O4x—Li1—O4xxxviii | 96 (2) |
O3xxi—O2—O4x | 89 (3) | O4x—Li1—O4xxxix | 97 (2) |
O3xxi—O2—Li1 | 146 (3) | O4x—Li1—Mn1xxi | 64.8 (13) |
O3xxi—O2—Mn1xxi | 95 (3) | O4x—Li1—Mn1xli | 92.3 (15) |
O3xxi—O2—Mn2viii | 48 (3) | O4x—Li1—Mn2 | 67.6 (12) |
O3xxi—O2—Mn2xxiii | 48 (3) | O4x—Li1—Mn2xxxvi | 137.1 (19) |
O4—O2—O4xxii | 119 (3) | O4x—Li1—Mn2xlii | 127.5 (17) |
O4—O2—O4xvii | 122 (3) | O4x—Li1—Mn2xliii | 86.1 (15) |
O4—O2—O4xviii | 51 (2) | O4x—Li1—Mn2xliv | 125.1 (17) |
O4—O2—O4x | 69 (3) | O4x—Li1—Mn2x | 90.9 (15) |
O4—O2—Li1 | 84 (3) | O4x—Li1—Mn2xxiii | 82.9 (13) |
O4—O2—Mn2i | 94 (2) | O4x—Li1—Mn2xlv | 173.4 (19) |
O4—O2—Mn2viii | 96 (3) | O4xxxviii—Li1—O4xxxix | 91.3 (18) |
O4—O2—Mn2xxiii | 137 (3) | O4xxxviii—Li1—Mn1xxi | 133.1 (18) |
O4xxii—O2—O4xvii | 119 (3) | O4xxxviii—Li1—Mn1xl | 64.0 (12) |
O4xxii—O2—O4xviii | 68 (3) | O4xxxviii—Li1—Mn1xli | 126.0 (17) |
O4xxii—O2—O4x | 172 (3) | O4xxxviii—Li1—Mn2 | 82.4 (13) |
O4xxii—O2—Li1 | 90 (3) | O4xxxviii—Li1—Mn2xxxvi | 122.7 (17) |
O4xxii—O2—Mn1xxi | 94 (3) | O4xxxviii—Li1—Mn2viii | 88.6 (15) |
O4xxii—O2—Mn2i | 92 (2) | O4xxxviii—Li1—Mn2xliv | 61.2 (12) |
O4xxii—O2—Mn2viii | 136 (4) | O4xxxviii—Li1—Mn2x | 173.0 (19) |
O4xvii—O2—O4xviii | 172 (3) | O4xxxviii—Li1—Mn2xxiii | 86.0 (14) |
O4xvii—O2—O4x | 54 (3) | O4xxxviii—Li1—Mn2xlv | 79.8 (14) |
O4xvii—O2—Li1 | 91 (3) | O4xxxix—Li1—Mn1xxi | 131.5 (17) |
O4xvii—O2—Mn1xxi | 137 (3) | O4xxxix—Li1—Mn1xl | 83.2 (14) |
O4xvii—O2—Mn2i | 91 (2) | O4xxxix—Li1—Mn2xxxvi | 66.1 (12) |
O4xvii—O2—Mn2xxiii | 92 (3) | O4xxxix—Li1—Mn2xlii | 85.1 (12) |
O4xviii—O2—O4x | 119 (3) | O4xxxix—Li1—Mn2viii | 129.7 (16) |
O4xviii—O2—Li1 | 86 (3) | O4xxxix—Li1—Mn2xliii | 62.1 (11) |
O4xviii—O2—Mn2i | 92 (2) | O4xxxix—Li1—Mn2xliv | 129.3 (15) |
O4xviii—O2—Mn2viii | 136 (4) | O4xxxix—Li1—Mn2x | 85.7 (13) |
O4xviii—O2—Mn2xxiii | 95 (3) | O4xxxix—Li1—Mn2xxiii | 177.3 (16) |
O4x—O2—Li1 | 87 (3) | O4xxxix—Li1—Mn2xlv | 87.6 (13) |
O4x—O2—Mn1xxi | 94 (3) | Mn1xxi—Li1—Mn1xl | 98.3 (7) |
O4x—O2—Mn2i | 91 (2) | Mn1xxi—Li1—Mn1xli | 98.3 (7) |
O4x—O2—Mn2xxiii | 136 (3) | Mn1xxi—Li1—Mn2 | 121.7 (7) |
Li1—O2—Mn1xxi | 119 (2) | Mn1xxi—Li1—Mn2xxxvi | 95.7 (7) |
Li1—O2—Mn2i | 177 (2) | Mn1xxi—Li1—Mn2xlii | 142.3 (7) |
Li1—O2—Mn2viii | 121 (3) | Mn1xxi—Li1—Mn2viii | 51.4 (5) |
Li1—O2—Mn2xxiii | 124 (2) | Mn1xxi—Li1—Mn2xliii | 148.0 (7) |
Mn1xxi—O2—Mn2i | 58.9 (19) | Mn1xxi—Li1—Mn2xliv | 94.3 (6) |
Mn1xxi—O2—Mn2viii | 95 (3) | Mn1xxi—Li1—Mn2x | 52.2 (5) |
Mn1xxi—O2—Mn2xxiii | 96 (2) | Mn1xxi—Li1—Mn2xxiii | 51.1 (4) |
Mn2i—O2—Mn2viii | 58 (2) | Mn1xxi—Li1—Mn2xlv | 114.8 (7) |
Mn2i—O2—Mn2xxiii | 58.5 (19) | Mn1xl—Li1—Mn1xli | 98.3 (7) |
Mn2viii—O2—Mn2xxiii | 95 (3) | Mn1xl—Li1—Mn2 | 51.4 (5) |
O1xxiv—O3—O1xxv | 120 (3) | Mn1xl—Li1—Mn2xxxvi | 148.0 (8) |
O1xxiv—O3—O1xxvi | 120 (3) | Mn1xl—Li1—Mn2xlii | 94.3 (6) |
O1xxiv—O3—O2xxvii | 119 (3) | Mn1xl—Li1—Mn2viii | 52.2 (5) |
O1xxiv—O3—O2vii | 121 (4) | Mn1xl—Li1—Mn2xliii | 51.1 (5) |
O1xxiv—O3—O2xxviii | 92 (3) | Mn1xl—Li1—Mn2xliv | 114.8 (7) |
O1xxiv—O3—O2ix | 63 (3) | Mn1xl—Li1—Mn2x | 121.7 (7) |
O1xxiv—O3—O2xxix | 58 (3) | Mn1xl—Li1—Mn2xxiii | 95.7 (6) |
O1xxiv—O3—O2xi | 88 (3) | Mn1xl—Li1—Mn2xlv | 142.3 (8) |
O1xxiv—O3—O4xxv | 172 (4) | Mn1xli—Li1—Mn2 | 52.2 (5) |
O1xxiv—O3—O4xxx | 68 (3) | Mn1xli—Li1—Mn2xxxvi | 51.1 (5) |
O1xxiv—O3—O4xxxi | 52 (2) | Mn1xli—Li1—Mn2xlii | 114.8 (7) |
O1xxiv—O3—Li1xxvii | 89 (3) | Mn1xli—Li1—Mn2viii | 121.7 (7) |
O1xxiv—O3—Mn1 | 91 (2) | Mn1xli—Li1—Mn2xliii | 95.7 (6) |
O1xxiv—O3—Mn2xxxiii | 134 (3) | Mn1xli—Li1—Mn2xliv | 142.3 (7) |
O1xxiv—O3—Mn2xxxiv | 94 (3) | Mn1xli—Li1—Mn2x | 51.4 (5) |
O1xxv—O3—O1xxvi | 120 (3) | Mn1xli—Li1—Mn2xxiii | 148.0 (7) |
O1xxv—O3—O2xxvii | 92 (3) | Mn1xli—Li1—Mn2xlv | 94.3 (6) |
O1xxv—O3—O2vii | 63 (3) | Mn2—Li1—Mn2xxxvi | 97.0 (6) |
O1xxv—O3—O2xxviii | 58 (3) | Mn2—Li1—Mn2xlii | 93.8 (5) |
O1xxv—O3—O2ix | 88 (3) | Mn2—Li1—Mn2viii | 98.2 (5) |
O1xxv—O3—O2xxix | 119 (4) | Mn2—Li1—Mn2xliii | 50.4 (4) |
O1xxv—O3—O2xi | 121 (4) | Mn2—Li1—Mn2xliv | 141.4 (6) |
O1xxv—O3—O4xxv | 68 (3) | Mn2—Li1—Mn2x | 98.2 (5) |
O1xxv—O3—O4xxx | 52 (2) | Mn2—Li1—Mn2xxiii | 146.8 (6) |
O1xxv—O3—O4xxxi | 172 (4) | Mn2—Li1—Mn2xlv | 116.3 (6) |
O1xxv—O3—Li1xxvii | 89 (3) | Mn2xxxvi—Li1—Mn2xlii | 91.9 (5) |
O1xxv—O3—Mn1 | 91 (2) | Mn2xxxvi—Li1—Mn2viii | 146.8 (8) |
O1xxv—O3—Mn2xxxii | 134 (3) | Mn2xxxvi—Li1—Mn2xliii | 115.3 (7) |
O1xxv—O3—Mn2xxxiii | 94 (3) | Mn2xxxvi—Li1—Mn2xliv | 92.5 (5) |
O1xxvi—O3—O2xxvii | 58 (3) | Mn2xxxvi—Li1—Mn2x | 50.4 (4) |
O1xxvi—O3—O2vii | 88 (3) | Mn2xxxvi—Li1—Mn2xxiii | 115.3 (6) |
O1xxvi—O3—O2xxviii | 119 (3) | Mn2xxxvi—Li1—Mn2xlv | 49.1 (4) |
O1xxvi—O3—O2ix | 121 (4) | Mn2xlii—Li1—Mn2viii | 116.3 (7) |
O1xxvi—O3—O2xxix | 92 (3) | Mn2xlii—Li1—Mn2xliii | 49.1 (4) |
O1xxvi—O3—O2xi | 63 (3) | Mn2xlii—Li1—Mn2xliv | 48.4 (3) |
O1xxvi—O3—O4xxv | 52 (2) | Mn2xlii—Li1—Mn2x | 141.4 (6) |
O1xxvi—O3—O4xxx | 172 (4) | Mn2xlii—Li1—Mn2xxiii | 92.5 (5) |
O1xxvi—O3—O4xxxi | 68 (3) | Mn2xlii—Li1—Mn2xlv | 48.4 (4) |
O1xxvi—O3—Li1xxvii | 89 (3) | Mn2viii—Li1—Mn2xliii | 97.0 (6) |
O1xxvi—O3—Mn1 | 91 (2) | Mn2viii—Li1—Mn2xliv | 93.8 (6) |
O1xxvi—O3—Mn2xxxii | 94 (3) | Mn2viii—Li1—Mn2x | 98.2 (6) |
O1xxvi—O3—Mn2xxxiv | 134 (3) | Mn2viii—Li1—Mn2xxiii | 50.4 (4) |
O2xxvii—O3—O2vii | 120 (4) | Mn2viii—Li1—Mn2xlv | 141.4 (8) |
O2xxvii—O3—O2xxviii | 61 (3) | Mn2xliii—Li1—Mn2xliv | 91.9 (5) |
O2xxvii—O3—O2ix | 179 (4) | Mn2xliii—Li1—Mn2x | 146.8 (6) |
O2xxvii—O3—O2xxix | 61 (2) | Mn2xliii—Li1—Mn2xxiii | 115.3 (5) |
O2xxvii—O3—O2xi | 120 (3) | Mn2xliii—Li1—Mn2xlv | 92.5 (6) |
O2xxvii—O3—O4xxv | 57 (2) | Mn2xliv—Li1—Mn2x | 116.3 (5) |
O2xxvii—O3—O4xxx | 118 (3) | Mn2xliv—Li1—Mn2xxiii | 49.1 (4) |
O2xxvii—O3—O4xxxi | 91 (3) | Mn2xliv—Li1—Mn2xlv | 48.4 (4) |
O2xxvii—O3—Mn1 | 144 (3) | Mn2x—Li1—Mn2xxiii | 97.0 (5) |
O2xxvii—O3—Mn2xxxii | 134 (3) | Mn2x—Li1—Mn2xlv | 93.8 (5) |
O2xxvii—O3—Mn2xxxiii | 87 (3) | Mn2xxiii—Li1—Mn2xlv | 91.9 (6) |
O2xxvii—O3—Mn2xxxiv | 133 (4) | O1—Mn1—O2vii | 129 (4) |
O2vii—O3—O2xxviii | 120 (3) | O1—Mn1—O2ix | 129 (4) |
O2vii—O3—O2ix | 59 (3) | O1—Mn1—O2xi | 129 (4) |
O2vii—O3—O2xxix | 179 (4) | O1—Mn1—O3 | 180 (3) |
O2vii—O3—O2xi | 59 (3) | O1—Mn1—O4vii | 47 (2) |
O2vii—O3—O4xxv | 63 (3) | O1—Mn1—O4ix | 47 (2) |
O2vii—O3—O4xxx | 89 (3) | O1—Mn1—O4xi | 47 (2) |
O2vii—O3—O4xxxi | 121 (4) | O1—Mn1—Li1vii | 99.1 (18) |
O2vii—O3—Li1xxvii | 146 (4) | O1—Mn1—Li1xxxii | 99.1 (18) |
O2vii—O3—Mn2xxxii | 91 (3) | O1—Mn1—Li1xiv | 99.1 (18) |
O2vii—O3—Mn2xxxiii | 47 (3) | O1—Mn1—Mn2xxxii | 145 (2) |
O2vii—O3—Mn2xxxiv | 47 (3) | O1—Mn1—Mn2xxxiii | 145 (2) |
O2xxviii—O3—O2ix | 120 (3) | O1—Mn1—Mn2xxxiv | 145 (2) |
O2xxviii—O3—O2xxix | 61 (3) | O2vii—Mn1—O2ix | 84 (3) |
O2xxviii—O3—O2xi | 179 (3) | O2vii—Mn1—O2xi | 84 (4) |
O2xxviii—O3—O4xxv | 91 (3) | O2vii—Mn1—O3 | 51 (3) |
O2xxviii—O3—O4xxx | 57 (2) | O2vii—Mn1—O4vii | 98 (4) |
O2xxviii—O3—O4xxxi | 118 (3) | O2vii—Mn1—O4ix | 99 (4) |
O2xxviii—O3—Mn1 | 144 (2) | O2vii—Mn1—O4xi | 177 (5) |
O2xxviii—O3—Mn2xxxii | 133 (3) | O2vii—Mn1—Li1xxxii | 107 (3) |
O2xxviii—O3—Mn2xxxiii | 134 (3) | O2vii—Mn1—Li1xiv | 106 (2) |
O2xxviii—O3—Mn2xxxiv | 87 (3) | O2vii—Mn1—Mn2xxxii | 86 (3) |
O2ix—O3—O2xxix | 120 (4) | O2vii—Mn1—Mn2xiv | 139 (3) |
O2ix—O3—O2xi | 59 (3) | O2vii—Mn1—Mn2xv | 137 (3) |
O2ix—O3—O4xxv | 121 (3) | O2vii—Mn1—Mn2xvi | 95 (3) |
O2ix—O3—O4xxx | 63 (3) | O2ix—Mn1—O2xi | 84 (4) |
O2ix—O3—O4xxxi | 89 (3) | O2ix—Mn1—O3 | 51 (3) |
O2ix—O3—Li1xxvii | 146 (4) | O2ix—Mn1—O4vii | 177 (4) |
O2ix—O3—Mn2xxxii | 47 (3) | O2ix—Mn1—O4ix | 98 (4) |
O2ix—O3—Mn2xxxiii | 91 (3) | O2ix—Mn1—O4xi | 99 (4) |
O2ix—O3—Mn2xxxiv | 47 (3) | O2ix—Mn1—Li1vii | 107 (2) |
O2xxix—O3—O2xi | 120 (3) | O2ix—Mn1—Li1xxxii | 106 (3) |
O2xxix—O3—O4xxv | 118 (3) | O2ix—Mn1—Mn2xiv | 95 (3) |
O2xxix—O3—O4xxx | 91 (3) | O2ix—Mn1—Mn2xxxiii | 86 (3) |
O2xxix—O3—O4xxxi | 57 (2) | O2ix—Mn1—Mn2xv | 139 (3) |
O2xxix—O3—Mn1 | 144 (3) | O2ix—Mn1—Mn2xvi | 137 (3) |
O2xxix—O3—Mn2xxxii | 87 (3) | O2xi—Mn1—O3 | 51 (3) |
O2xxix—O3—Mn2xxxiii | 133 (3) | O2xi—Mn1—O4vii | 99 (4) |
O2xxix—O3—Mn2xxxiv | 134 (4) | O2xi—Mn1—O4ix | 177 (6) |
O2xi—O3—O4xxv | 89 (3) | O2xi—Mn1—O4xi | 98 (4) |
O2xi—O3—O4xxx | 121 (3) | O2xi—Mn1—Li1vii | 106 (3) |
O2xi—O3—O4xxxi | 63 (3) | O2xi—Mn1—Li1xiv | 107 (3) |
O2xi—O3—Li1xxvii | 146 (3) | O2xi—Mn1—Mn2xiv | 137 (4) |
O2xi—O3—Mn2xxxii | 47 (2) | O2xi—Mn1—Mn2xv | 95 (3) |
O2xi—O3—Mn2xxxiii | 47 (2) | O2xi—Mn1—Mn2xxxiv | 86 (3) |
O2xi—O3—Mn2xxxiv | 91 (3) | O2xi—Mn1—Mn2xvi | 139 (4) |
O4xxv—O3—O4xxx | 120 (3) | O3—Mn1—O4vii | 133 (3) |
O4xxv—O3—O4xxxi | 120 (3) | O3—Mn1—O4ix | 133 (3) |
O4xxv—O3—Li1xxvii | 89 (2) | O3—Mn1—O4xi | 133 (3) |
O4xxv—O3—Mn1 | 91 (2) | O3—Mn1—Li1vii | 80.9 (14) |
O4xxv—O3—Mn2xxxii | 136 (3) | O3—Mn1—Li1xxxii | 80.9 (14) |
O4xxv—O3—Mn2xxxiv | 93 (3) | O3—Mn1—Li1xiv | 80.9 (14) |
O4xxx—O3—O4xxxi | 120 (3) | O3—Mn1—Mn2xiv | 146 (2) |
O4xxx—O3—Li1xxvii | 89 (3) | O3—Mn1—Mn2xv | 146 (2) |
O4xxx—O3—Mn1 | 91 (2) | O3—Mn1—Mn2xvi | 146 (2) |
O4xxx—O3—Mn2xxxii | 93 (3) | O4vii—Mn1—O4ix | 79 (3) |
O4xxx—O3—Mn2xxxiii | 136 (3) | O4vii—Mn1—O4xi | 79 (3) |
O4xxxi—O3—Li1xxvii | 89 (3) | O4vii—Mn1—Li1vii | 73.7 (19) |
O4xxxi—O3—Mn1 | 91 (2) | O4vii—Mn1—Li1xxxii | 76.6 (19) |
O4xxxi—O3—Mn2xxxiii | 93 (3) | O4vii—Mn1—Li1xiv | 147 (2) |
O4xxxi—O3—Mn2xxxiv | 136 (3) | O4vii—Mn1—Mn2xxxii | 141 (2) |
Li1xxvii—O3—Mn1 | 180.0 (18) | O4vii—Mn1—Mn2xiv | 82 (2) |
Li1xxvii—O3—Mn2xxxii | 123 (2) | O4vii—Mn1—Mn2xxxiii | 97 (2) |
Li1xxvii—O3—Mn2xxxiii | 123 (2) | O4vii—Mn1—Mn2xxxiv | 139 (2) |
Li1xxvii—O3—Mn2xxxiv | 123 (2) | O4ix—Mn1—O4xi | 79 (3) |
Mn1—O3—Mn2xxxii | 57.1 (18) | O4ix—Mn1—Li1vii | 77 (2) |
Mn1—O3—Mn2xxxiii | 57.1 (18) | O4ix—Mn1—Li1xxxii | 147 (3) |
Mn1—O3—Mn2xxxiv | 57.1 (18) | O4ix—Mn1—Li1xiv | 73.7 (19) |
Mn2xxxii—O3—Mn2xxxiii | 93 (2) | O4ix—Mn1—Mn2xxxii | 139 (3) |
Mn2xxxii—O3—Mn2xxxiv | 93 (2) | O4ix—Mn1—Mn2xxxiii | 141 (3) |
Mn2xxxiii—O3—Mn2xxxiv | 93 (2) | O4ix—Mn1—Mn2xv | 82 (2) |
O1—O4—O1xxi | 123 (4) | O4ix—Mn1—Mn2xxxiv | 97 (2) |
O1—O4—O2 | 113 (3) | O4xi—Mn1—Li1vii | 147 (3) |
O1—O4—O2xiii | 91 (3) | O4xi—Mn1—Li1xxxii | 74 (2) |
O1—O4—O2i | 57 (2) | O4xi—Mn1—Li1xiv | 77 (2) |
O1—O4—O2viii | 116 (4) | O4xi—Mn1—Mn2xxxii | 97 (2) |
O1—O4—O2xix | 88 (3) | O4xi—Mn1—Mn2xxxiii | 139 (3) |
O1—O4—O3v | 57 (2) | O4xi—Mn1—Mn2xxxiv | 141 (3) |
O1—O4—O4viii | 59 (2) | O4xi—Mn1—Mn2xvi | 82 (2) |
O1—O4—O4xviii | 178 (4) | Li1vii—Mn1—Li1xxxii | 117.5 (4) |
O1—O4—O4x | 59 (2) | Li1vii—Mn1—Li1xiv | 117.5 (4) |
O1—O4—O4xix | 120 (3) | Li1vii—Mn1—Mn2xxxii | 115.9 (7) |
O1—O4—Li1 | 109 (2) | Li1vii—Mn1—Mn2xiv | 115.3 (6) |
O1—O4—Li1xiii | 64.0 (18) | Li1vii—Mn1—Mn2xxxiii | 65.2 (6) |
O1—O4—Li1i | 63.6 (19) | Li1vii—Mn1—Mn2xv | 113.0 (6) |
O1—O4—Mn1xxi | 128 (3) | Li1vii—Mn1—Mn2xxxiv | 66.0 (5) |
O1—O4—Mn2xxii | 146 (3) | Li1vii—Mn1—Mn2xvi | 64.8 (6) |
O1—O4—Mn2xxxv | 87 (3) | Li1xxxii—Mn1—Li1xiv | 117.5 (4) |
O1—O4—Mn2x | 134 (3) | Li1xxxii—Mn1—Mn2xxxii | 65.2 (6) |
O1xxi—O4—O2 | 124 (4) | Li1xxxii—Mn1—Mn2xiv | 113.0 (7) |
O1xxi—O4—O2xiii | 65 (3) | Li1xxxii—Mn1—Mn2xxxiii | 66.0 (6) |
O1xxi—O4—O2i | 92 (4) | Li1xxxii—Mn1—Mn2xv | 64.8 (6) |
O1xxi—O4—O2viii | 92 (3) | Li1xxxii—Mn1—Mn2xxxiv | 115.9 (6) |
O1xxi—O4—O2xix | 123 (4) | Li1xxxii—Mn1—Mn2xvi | 115.3 (7) |
O1xxi—O4—O3v | 66 (3) | Li1xiv—Mn1—Mn2xxxii | 66.0 (6) |
O1xxi—O4—O4viii | 124 (3) | Li1xiv—Mn1—Mn2xiv | 64.8 (6) |
O1xxi—O4—O4xviii | 59 (3) | Li1xiv—Mn1—Mn2xxxiii | 115.9 (7) |
O1xxi—O4—O4x | 176 (4) | Li1xiv—Mn1—Mn2xv | 115.3 (6) |
O1xxi—O4—O4xix | 59 (3) | Li1xiv—Mn1—Mn2xxxiv | 65.2 (5) |
O1xxi—O4—Li1 | 120 (3) | Li1xiv—Mn1—Mn2xvi | 113.0 (6) |
O1xxi—O4—Li1xiii | 71 (2) | Mn2xxxii—Mn1—Mn2xiv | 120.5 (9) |
O1xxi—O4—Li1i | 116 (3) | Mn2xxxii—Mn1—Mn2xxxiii | 59.6 (7) |
O1xxi—O4—Mn1xxi | 96 (3) | Mn2xxxii—Mn1—Mn2xv | 121.4 (8) |
O1xxi—O4—Mn2xxxv | 49 (3) | Mn2xxxii—Mn1—Mn2xxxiv | 59.6 (7) |
O1xxi—O4—Mn2x | 49 (3) | Mn2xxxii—Mn1—Mn2xvi | 178.9 (10) |
O2—O4—O2xiii | 120 (3) | Mn2xiv—Mn1—Mn2xxxiii | 178.9 (10) |
O2—O4—O2i | 116 (3) | Mn2xiv—Mn1—Mn2xv | 58.5 (7) |
O2—O4—O2viii | 65 (3) | Mn2xiv—Mn1—Mn2xxxiv | 121.4 (8) |
O2—O4—O2xix | 52 (2) | Mn2xiv—Mn1—Mn2xvi | 58.5 (7) |
O2—O4—O3v | 169 (3) | Mn2xxxiii—Mn1—Mn2xv | 120.5 (8) |
O2—O4—O4viii | 88 (2) | Mn2xxxiii—Mn1—Mn2xxxiv | 59.6 (7) |
O2—O4—O4xviii | 65 (3) | Mn2xxxiii—Mn1—Mn2xvi | 121.4 (9) |
O2—O4—O4x | 54 (2) | Mn2xv—Mn1—Mn2xxxiv | 178.9 (8) |
O2—O4—O4xix | 91 (3) | Mn2xv—Mn1—Mn2xvi | 58.5 (7) |
O2—O4—Li1xiii | 147 (2) | Mn2xxxiv—Mn1—Mn2xvi | 120.5 (8) |
O2—O4—Li1i | 84 (2) | O1xli—Mn2—O2xvii | 132 (4) |
O2—O4—Mn2xxii | 93 (2) | O1xli—Mn2—O2xlvi | 98 (5) |
O2—O4—Mn2xxxv | 137 (3) | O1xli—Mn2—O2x | 178 (5) |
O2—O4—Mn2x | 94 (3) | O1xli—Mn2—O3xl | 96 (4) |
O2xiii—O4—O2i | 123 (4) | O1xli—Mn2—O4xiii | 49 (3) |
O2xiii—O4—O2viii | 54 (3) | O1xli—Mn2—O4viii | 82 (4) |
O2xiii—O4—O2xix | 170 (4) | O1xli—Mn2—O4xxxix | 82 (4) |
O2xiii—O4—O3v | 67 (3) | O1xli—Mn2—Li1 | 149 (3) |
O2xiii—O4—O4viii | 58 (2) | O1xli—Mn2—Li1xii | 77 (2) |
O2xiii—O4—O4xviii | 90 (3) | O1xli—Mn2—Li1xlvii | 74 (2) |
O2xiii—O4—O4x | 118 (3) | O1xli—Mn2—Mn1xl | 139 (3) |
O2xiii—O4—O4xix | 124 (3) | O1xli—Mn2—Mn1xli | 86 (3) |
O2xiii—O4—Li1 | 87 (2) | O1xli—Mn2—Mn2xliii | 139 (3) |
O2xiii—O4—Li1i | 152 (3) | O1xli—Mn2—Mn2iii | 96 (3) |
O2xiii—O4—Mn1xxi | 139 (3) | O2xvii—Mn2—O2xlvi | 51 (3) |
O2xiii—O4—Mn2xxii | 94 (2) | O2xvii—Mn2—O2x | 51 (3) |
O2xiii—O4—Mn2xxxv | 97 (3) | O2xvii—Mn2—O3xl | 53 (3) |
O2i—O4—O2viii | 174 (4) | O2xvii—Mn2—O4xiii | 179 (3) |
O2i—O4—O2xix | 65 (3) | O2xvii—Mn2—O4viii | 130 (4) |
O2i—O4—O3v | 56 (3) | O2xvii—Mn2—O4xxxix | 128 (4) |
O2i—O4—O4viii | 116 (3) | O2xvii—Mn2—Li1 | 79.6 (17) |
O2i—O4—O4xviii | 123 (4) | O2xvii—Mn2—Li1xii | 78.4 (15) |
O2i—O4—O4x | 87 (3) | O2xvii—Mn2—Li1xlvii | 81.3 (17) |
O2i—O4—O4xix | 63 (3) | O2xvii—Mn2—Mn1xli | 143 (2) |
O2i—O4—Li1 | 145 (3) | O2xvii—Mn2—Mn2xxxvii | 145 (2) |
O2i—O4—Li1xiii | 90 (2) | O2xvii—Mn2—Mn2xlviii | 146 (2) |
O2i—O4—Mn1xxi | 92 (3) | O2xlvi—Mn2—O2x | 84 (4) |
O2i—O4—Mn2xxii | 93 (3) | O2xlvi—Mn2—O3xl | 86 (4) |
O2i—O4—Mn2x | 140 (4) | O2xlvi—Mn2—O4xiii | 130 (4) |
O2viii—O4—O2xix | 117 (4) | O2xlvi—Mn2—O4viii | 96 (4) |
O2viii—O4—O3v | 121 (3) | O2xlvi—Mn2—O4xxxix | 179 (6) |
O2viii—O4—O4viii | 58 (2) | O2xlvi—Mn2—Li1 | 104 (3) |
O2viii—O4—O4xviii | 63 (3) | O2xlvi—Mn2—Li1xlvii | 107 (3) |
O2viii—O4—O4x | 90 (3) | O2xlvi—Mn2—Mn1xli | 138 (4) |
O2viii—O4—O4xix | 123 (3) | O2xlvi—Mn2—Mn2xliii | 86 (3) |
O2viii—O4—Li1xiii | 86 (2) | O2xlvi—Mn2—Mn2xxxvii | 139 (4) |
O2viii—O4—Li1i | 147 (3) | O2xlvi—Mn2—Mn2xlviii | 95 (3) |
O2viii—O4—Mn1xxi | 93 (3) | O2x—Mn2—O3xl | 86 (3) |
O2viii—O4—Mn2xxii | 93 (2) | O2x—Mn2—O4xiii | 129 (3) |
O2viii—O4—Mn2xxxv | 141 (3) | O2x—Mn2—O4viii | 96 (4) |
O2xix—O4—O3v | 121 (3) | O2x—Mn2—O4xxxix | 96 (4) |
O2xix—O4—O4viii | 113 (3) | O2x—Mn2—Li1xii | 104 (3) |
O2xix—O4—O4xviii | 90 (3) | O2x—Mn2—Li1xlvii | 107 (2) |
O2xix—O4—O4x | 53 (2) | O2x—Mn2—Mn1xli | 92 (3) |
O2xix—O4—O4xix | 64 (3) | O2x—Mn2—Mn2xxxvii | 137 (3) |
O2xix—O4—Li1 | 84 (2) | O2x—Mn2—Mn2xlviii | 137 (3) |
O2xix—O4—Li1xiii | 151 (3) | O2x—Mn2—Mn2iii | 86 (3) |
O2xix—O4—Mn2xxii | 92 (2) | O3xl—Mn2—O4xiii | 127 (3) |
O2xix—O4—Mn2xxxv | 93 (3) | O3xl—Mn2—O4viii | 178 (5) |
O2xix—O4—Mn2x | 136 (4) | O3xl—Mn2—O4xxxix | 93 (4) |
O3v—O4—O4viii | 90 (3) | O3xl—Mn2—Li1 | 107 (2) |
O3v—O4—O4xviii | 125 (3) | O3xl—Mn2—Li1xii | 106 (2) |
O3v—O4—O4x | 116 (3) | O3xl—Mn2—Mn1xl | 88 (2) |
O3v—O4—O4xix | 92 (3) | O3xl—Mn2—Mn1xli | 136 (3) |
O3v—O4—Li1 | 148 (2) | O3xl—Mn2—Mn2xxxvii | 92 (2) |
O3v—O4—Li1i | 88 (2) | O3xl—Mn2—Mn2xlviii | 137 (3) |
O3v—O4—Mn1xxi | 141 (3) | O4xiii—Mn2—O4viii | 51 (2) |
O3v—O4—Mn2xxii | 95 (2) | O4xiii—Mn2—O4xxxix | 51 (2) |
O3v—O4—Mn2x | 96 (3) | O4xiii—Mn2—Li1 | 100.0 (14) |
O4viii—O4—O4xviii | 121 (3) | O4xiii—Mn2—Li1xii | 102.3 (16) |
O4viii—O4—O4x | 60 (2) | O4xiii—Mn2—Li1xlvii | 98.3 (15) |
O4viii—O4—O4xix | 177 (3) | O4xiii—Mn2—Mn1xl | 145.0 (19) |
O4viii—O4—Li1 | 60.6 (16) | O4xiii—Mn2—Mn2xliii | 143.8 (19) |
O4viii—O4—Li1xiii | 61.8 (16) | O4xiii—Mn2—Mn2iii | 145 (2) |
O4viii—O4—Li1i | 112.0 (19) | O4viii—Mn2—O4xxxix | 85 (4) |
O4viii—O4—Mn1xxi | 128 (3) | O4viii—Mn2—Li1 | 74 (2) |
O4viii—O4—Mn2xxii | 147 (2) | O4viii—Mn2—Li1xii | 75 (2) |
O4viii—O4—Mn2xxxv | 134 (3) | O4viii—Mn2—Li1xlvii | 149 (3) |
O4viii—O4—Mn2x | 88 (3) | O4viii—Mn2—Mn1xl | 94 (2) |
O4xviii—O4—O4x | 119 (3) | O4viii—Mn2—Mn2xliii | 138 (3) |
O4xviii—O4—O4xix | 60 (3) | O4viii—Mn2—Mn2xxxvii | 86 (2) |
O4xviii—O4—Li1 | 70 (2) | O4viii—Mn2—Mn2iii | 138 (3) |
O4xviii—O4—Li1xiii | 118 (2) | O4xxxix—Mn2—Li1 | 76 (2) |
O4xviii—O4—Li1i | 115 (2) | O4xxxix—Mn2—Li1xii | 153 (3) |
O4xviii—O4—Mn1xxi | 50 (2) | O4xxxix—Mn2—Li1xlvii | 72 (2) |
O4xviii—O4—Mn2xxxv | 94 (3) | O4xxxix—Mn2—Mn1xl | 138 (3) |
O4xviii—O4—Mn2x | 47 (2) | O4xxxix—Mn2—Mn2xliii | 93 (2) |
O4x—O4—O4xix | 117 (3) | O4xxxix—Mn2—Mn2xlviii | 86 (2) |
O4x—O4—Li1 | 60.6 (17) | O4xxxix—Mn2—Mn2iii | 136 (3) |
O4x—O4—Li1xiii | 112.7 (19) | Li1—Mn2—Li1xii | 113.9 (3) |
O4x—O4—Li1i | 61.0 (17) | Li1—Mn2—Li1xlvii | 118.9 (3) |
O4x—O4—Mn1xxi | 81 (2) | Li1—Mn2—Mn1xl | 63.4 (6) |
O4x—O4—Mn2xxii | 142 (2) | Li1—Mn2—Mn1xli | 63.0 (6) |
O4x—O4—Mn2xxxv | 130 (3) | Li1—Mn2—Mn2xliii | 65.4 (4) |
O4x—O4—Mn2x | 133 (3) | Li1—Mn2—Mn2xxxvii | 115.6 (6) |
O4xix—O4—Li1 | 118 (2) | Li1—Mn2—Mn2xlviii | 113.4 (5) |
O4xix—O4—Li1xiii | 120 (2) | Li1—Mn2—Mn2iii | 114.8 (6) |
O4xix—O4—Li1i | 65.8 (19) | Li1xii—Mn2—Li1xlvii | 118.0 (3) |
O4xix—O4—Mn1xxi | 50 (2) | Li1xii—Mn2—Mn1xl | 63.0 (6) |
O4xix—O4—Mn2xxxv | 47 (2) | Li1xii—Mn2—Mn1xli | 117.4 (7) |
O4xix—O4—Mn2x | 94 (3) | Li1xii—Mn2—Mn2xliii | 113.9 (6) |
Li1—O4—Li1xiii | 113.1 (11) | Li1xii—Mn2—Mn2xxxvii | 117.9 (7) |
Li1—O4—Li1i | 112.4 (12) | Li1xii—Mn2—Mn2xlviii | 67.5 (5) |
Li1—O4—Mn1xxi | 71.1 (16) | Li1xii—Mn2—Mn2iii | 64.2 (5) |
Li1—O4—Mn2xxii | 104.5 (12) | Li1xlvii—Mn2—Mn1xl | 116.7 (7) |
Li1—O4—Mn2xxxv | 163.8 (18) | Li1xlvii—Mn2—Mn1xli | 114.0 (7) |
Li1—O4—Mn2x | 73.7 (18) | Li1xlvii—Mn2—Mn2xliii | 65.8 (4) |
Li1xiii—O4—Li1i | 118.5 (11) | Li1xlvii—Mn2—Mn2xxxvii | 63.4 (5) |
Li1xiii—O4—Mn1xxi | 166.5 (16) | Li1xlvii—Mn2—Mn2xlviii | 114.5 (5) |
Li1xiii—O4—Mn2xxii | 105.5 (11) | Li1xlvii—Mn2—Mn2iii | 65.8 (5) |
Li1xiii—O4—Mn2xxxv | 76.4 (17) | Mn1xl—Mn2—Mn1xli | 118.6 (10) |
Li1xiii—O4—Mn2x | 72.9 (17) | Mn1xl—Mn2—Mn2xliii | 60.2 (7) |
Li1i—O4—Mn1xxi | 68.8 (16) | Mn1xl—Mn2—Mn2xxxvii | 179.0 (10) |
Li1i—O4—Mn2xxii | 100.6 (12) | Mn1xl—Mn2—Mn2xlviii | 120.4 (9) |
Li1i—O4—Mn2xxxv | 71.1 (18) | Mn1xl—Mn2—Mn2iii | 60.2 (7) |
Li1i—O4—Mn2x | 160.0 (19) | Mn1xli—Mn2—Mn2xliii | 117.6 (9) |
Mn1xxi—O4—Mn2xxii | 61.1 (16) | Mn1xli—Mn2—Mn2xxxvii | 60.8 (7) |
Mn1xxi—O4—Mn2xxxv | 97 (2) | Mn1xli—Mn2—Mn2xlviii | 60.8 (7) |
Mn1xxi—O4—Mn2x | 97 (2) | Mn1xli—Mn2—Mn2iii | 177.6 (10) |
Mn2xxii—O4—Mn2xxxv | 59.5 (18) | Mn2xliii—Mn2—Mn2xxxvii | 119.4 (8) |
Mn2xxii—O4—Mn2x | 59.5 (18) | Mn2xliii—Mn2—Mn2xlviii | 178.4 (8) |
Mn2xxxv—O4—Mn2x | 98 (2) | Mn2xliii—Mn2—Mn2iii | 60.0 (6) |
O1xxxvi—Li1—O1xxii | 91 (2) | Mn2xxxvii—Mn2—Mn2xlviii | 60.0 (6) |
O1xxxvi—Li1—O1xvii | 91 (2) | Mn2xxxvii—Mn2—Mn2iii | 120.5 (9) |
O1xxxvi—Li1—O2 | 144 (4) | Mn2xlviii—Mn2—Mn2iii | 121.6 (8) |
Symmetry codes: (i) −x+1/2, −y, z+1/2; (ii) −y, z+1/2, −x+1/2; (iii) z+1/2, −x+1/2, −y; (iv) x−1/2, −y+3/2, −z+1; (v) −x+1, y−1/2, −z+3/2; (vi) −x+3/2, −y+1, z−1/2; (vii) x+1/2, −y+1/2, −z+1; (viii) y, z, x; (ix) −y+1/2, −z+1, x+1/2; (x) z, x, y; (xi) −z+1, x+1/2, −y+1/2; (xii) x+1/2, −y+1/2, −z; (xiii) −x, y+1/2, −z+1/2; (xiv) −x+1/2, −y+1, z+1/2; (xv) −y+1, z+1/2, −x+1/2; (xvi) z+1/2, −x+1/2, −y+1; (xvii) −x+1/2, −y, z−1/2; (xviii) −y, z−1/2, −x+1/2; (xix) −z+1/2, −x, y+1/2; (xx) x−1, y−1, z−1; (xxi) x−1/2, −y+1/2, −z+1; (xxii) −x, y−1/2, −z+1/2; (xxiii) −z, x−1/2, −y+1/2; (xxiv) x+1/2, −y+3/2, −z+1; (xxv) −x+1, y+1/2, −z+3/2; (xxvi) −x+3/2, −y+1, z+1/2; (xxvii) x+1, y+1, z+1; (xxviii) y+1, z+1, x+1; (xxix) z+1, x+1, y+1; (xxx) y+1/2, −z+3/2, −x+1; (xxxi) −z+3/2, −x+1, y+1/2; (xxxii) −x+1, y+1/2, −z+1/2; (xxxiii) y+1/2, −z+1/2, −x+1; (xxxiv) −z+1/2, −x+1, y+1/2; (xxxv) −y+1/2, −z, x+1/2; (xxxvi) x−1/2, −y+1/2, −z; (xxxvii) y−1/2, −z+1/2, −x; (xxxviii) −z+1/2, −x, y−1/2; (xxxix) z−1/2, −x+1/2, −y; (xl) −x+1, y−1/2, −z+1/2; (xli) −x+1/2, −y+1, z−1/2; (xlii) −x, y−1/2, −z−1/2; (xliii) −y+1/2, −z, x−1/2; (xliv) y−1/2, −z−1/2, −x; (xlv) −z−1/2, −x, y−1/2; (xlvi) y+1/2, −z+1/2, −x; (xlvii) −x, y+1/2, −z−1/2; (xlviii) −z, x+1/2, −y+1/2. |