Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804022925/kp6001sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804022925/kp6001Isup2.hkl |
CCDC reference: 253019
Data collection: CrysAlis CCD (Oxford Diffraction, 2003); cell refinement: CrysAlis RED (Oxford Diffraction, 2003); data reduction: CrysAlis RED; program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON98 (Spek, 2003); software used to prepare material for publication: SHELXL97.
C21H36O8 | F(000) = 452 |
Mr = 416.50 | Dx = 1.173 Mg m−3 |
Monoclinic, P21 | Mo Kα radiation, λ = 0.71069 Å |
Hall symbol: P 2yb | Cell parameters from 1573 reflections |
a = 9.828 (1) Å | θ = 15.0–25.0° |
b = 6.849 (1) Å | µ = 0.09 mm−1 |
c = 17.634 (1) Å | T = 100 K |
β = 96.36 (1)° | Prismatic, colorless |
V = 1179.7 (2) Å3 | 0.3 × 0.3 × 0.2 mm |
Z = 2 |
Xcalibur CCD diffractometer | 3234 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.088 |
Graphite monochromator | θmax = 29.0°, θmin = 4.6° |
ω scans | h = −13→13 |
38147 measured reflections | k = −9→9 |
3376 independent reflections | l = −24→24 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.039 | Hydrogen site location: difference Fourier map |
wR(F2) = 0.094 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.14 | w = 1/[σ2(Fo2) + (0.0504P)2 + 0.2141P] where P = (Fo2 + 2Fc2)/3 |
3376 reflections | (Δ/σ)max < 0.001 |
406 parameters | Δρmax = 0.37 e Å−3 |
1 restraint | Δρmin = −0.21 e Å−3 |
Experimental. The data did not permit the determination of the absolute structure; (the stereochemistry is the relative configuration based on the absolute stereochemistry of related compounds). |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
O1 | 0.90467 (12) | 0.9963 (2) | 0.27885 (7) | 0.0210 (3) | |
O2 | 0.67472 (12) | 1.14493 (19) | 0.33822 (6) | 0.0177 (2) | |
O3 | 0.43427 (12) | 1.17869 (19) | 0.23208 (7) | 0.0181 (2) | |
O4 | 0.40081 (11) | 0.8702 (2) | 0.12167 (6) | 0.0206 (3) | |
O5 | 0.77279 (11) | 0.8747 (2) | 0.17460 (7) | 0.0206 (3) | |
O6 | 0.73886 (19) | 1.4510 (2) | 0.31265 (8) | 0.0374 (4) | |
O7 | 0.33988 (13) | 1.0393 (2) | 0.33006 (7) | 0.0236 (3) | |
O8 | 0.41444 (17) | 1.0010 (3) | 0.00617 (9) | 0.0502 (5) | |
C1 | 0.77493 (15) | 0.9275 (3) | 0.25305 (9) | 0.0168 (3) | |
C2 | 0.67251 (16) | 1.0922 (3) | 0.25932 (9) | 0.0143 (3) | |
C3 | 0.52954 (15) | 1.0189 (3) | 0.23020 (9) | 0.0150 (3) | |
C4 | 0.53234 (16) | 0.9531 (3) | 0.14832 (9) | 0.0171 (3) | |
C5 | 0.64225 (17) | 0.7965 (3) | 0.14567 (10) | 0.0213 (3) | |
C6 | 1.00126 (17) | 0.8407 (3) | 0.29381 (12) | 0.0262 (4) | |
C7 | 0.71448 (17) | 1.3291 (3) | 0.35805 (9) | 0.0207 (3) | |
C8 | 0.72651 (18) | 1.3565 (3) | 0.44436 (10) | 0.0258 (4) | |
C9 | 0.8546 (3) | 1.2435 (6) | 0.47813 (14) | 0.0492 (7) | |
C10 | 0.7413 (4) | 1.5740 (5) | 0.46246 (15) | 0.0500 (7) | |
C11 | 0.5994 (2) | 1.2767 (4) | 0.47661 (12) | 0.0373 (5) | |
C12 | 0.34523 (16) | 1.1722 (3) | 0.28597 (9) | 0.0163 (3) | |
C13 | 0.25306 (16) | 1.3526 (3) | 0.28059 (9) | 0.0181 (3) | |
C14 | 0.3382 (2) | 1.5371 (3) | 0.27308 (12) | 0.0254 (4) | |
C15 | 0.1789 (2) | 1.3636 (3) | 0.35238 (10) | 0.0261 (4) | |
C16 | 0.14786 (17) | 1.3264 (3) | 0.20974 (10) | 0.0226 (4) | |
C17 | 0.35381 (17) | 0.9045 (3) | 0.04765 (10) | 0.0231 (4) | |
C18 | 0.21880 (18) | 0.7985 (3) | 0.02499 (10) | 0.0234 (4) | |
C19 | 0.11581 (19) | 0.8528 (4) | 0.08105 (13) | 0.0345 (5) | |
C20 | 0.1646 (2) | 0.8584 (4) | −0.05658 (12) | 0.0358 (5) | |
C21 | 0.2473 (2) | 0.5787 (3) | 0.02853 (12) | 0.0297 (4) | |
H1 | 0.748 (2) | 0.813 (3) | 0.2817 (12) | 0.012 (5)* | |
H2 | 0.696 (2) | 1.203 (3) | 0.2313 (12) | 0.012 (5)* | |
H3 | 0.504 (2) | 0.910 (3) | 0.2612 (11) | 0.011 (5)* | |
H4 | 0.554 (2) | 1.060 (4) | 0.1196 (12) | 0.015 (5)* | |
H51 | 0.618 (2) | 0.680 (4) | 0.1751 (14) | 0.024 (6)* | |
H52 | 0.650 (2) | 0.759 (4) | 0.0963 (13) | 0.020 (5)* | |
H61 | 1.089 (3) | 0.904 (4) | 0.3153 (15) | 0.033 (7)* | |
H62 | 0.970 (3) | 0.749 (4) | 0.3303 (16) | 0.036 (7)* | |
H63 | 1.015 (3) | 0.765 (4) | 0.2466 (15) | 0.031 (6)* | |
H91 | 0.846 (4) | 1.107 (6) | 0.466 (2) | 0.057 (10)* | |
H92 | 0.863 (3) | 1.261 (6) | 0.533 (2) | 0.066 (10)* | |
H93 | 0.940 (4) | 1.297 (6) | 0.459 (2) | 0.066 (10)* | |
H101 | 0.818 (4) | 1.629 (6) | 0.446 (2) | 0.066 (11)* | |
H102 | 0.652 (4) | 1.646 (7) | 0.439 (2) | 0.086 (14)* | |
H103 | 0.748 (4) | 1.585 (7) | 0.522 (2) | 0.073 (11)* | |
H111 | 0.590 (3) | 1.130 (5) | 0.4669 (17) | 0.044 (8)* | |
H112 | 0.610 (3) | 1.298 (5) | 0.5322 (17) | 0.041 (7)* | |
H113 | 0.515 (3) | 1.348 (6) | 0.4560 (17) | 0.051 (8)* | |
H141 | 0.280 (2) | 1.655 (4) | 0.2735 (13) | 0.022 (5)* | |
H142 | 0.413 (3) | 1.550 (5) | 0.3189 (16) | 0.038 (7)* | |
H143 | 0.383 (3) | 1.538 (5) | 0.2262 (16) | 0.039 (7)* | |
H151 | 0.113 (3) | 1.479 (5) | 0.3487 (17) | 0.040 (7)* | |
H152 | 0.125 (3) | 1.246 (5) | 0.3617 (18) | 0.042 (8)* | |
H153 | 0.244 (3) | 1.385 (5) | 0.3980 (16) | 0.043 (8)* | |
H161 | 0.091 (2) | 1.210 (4) | 0.2149 (13) | 0.017 (5)* | |
H162 | 0.191 (2) | 1.310 (4) | 0.1663 (14) | 0.025 (6)* | |
H163 | 0.085 (3) | 1.445 (4) | 0.2023 (15) | 0.033 (7)* | |
H191 | 0.153 (3) | 0.821 (5) | 0.1338 (17) | 0.039 (7)* | |
H192 | 0.029 (3) | 0.781 (5) | 0.0696 (16) | 0.035 (7)* | |
H193 | 0.096 (3) | 0.989 (6) | 0.0821 (19) | 0.052 (9)* | |
H201 | 0.145 (3) | 0.992 (5) | −0.0610 (16) | 0.037 (7)* | |
H202 | 0.078 (3) | 0.792 (5) | −0.0687 (16) | 0.040 (7)* | |
H203 | 0.229 (3) | 0.820 (5) | −0.0927 (18) | 0.052 (9)* | |
H211 | 0.279 (3) | 0.542 (5) | 0.0833 (17) | 0.044 (8)* | |
H212 | 0.161 (3) | 0.509 (6) | 0.0114 (18) | 0.056 (9)* | |
H213 | 0.313 (3) | 0.542 (5) | −0.0068 (18) | 0.050 (8)* |
U11 | U22 | U33 | U12 | U13 | U23 | |
O1 | 0.0145 (5) | 0.0204 (7) | 0.0271 (6) | 0.0005 (5) | −0.0021 (4) | −0.0005 (5) |
O2 | 0.0213 (5) | 0.0181 (6) | 0.0132 (5) | −0.0020 (5) | 0.0003 (4) | −0.0006 (4) |
O3 | 0.0171 (5) | 0.0195 (6) | 0.0179 (5) | 0.0031 (5) | 0.0032 (4) | 0.0034 (5) |
O4 | 0.0189 (5) | 0.0271 (7) | 0.0149 (5) | −0.0070 (5) | −0.0024 (4) | 0.0004 (5) |
O5 | 0.0166 (5) | 0.0253 (7) | 0.0200 (5) | 0.0006 (5) | 0.0029 (4) | −0.0057 (5) |
O6 | 0.0682 (11) | 0.0214 (7) | 0.0231 (7) | −0.0134 (8) | 0.0064 (6) | −0.0018 (6) |
O7 | 0.0253 (6) | 0.0206 (7) | 0.0261 (6) | 0.0046 (5) | 0.0083 (5) | 0.0057 (5) |
O8 | 0.0357 (7) | 0.0768 (14) | 0.0339 (8) | −0.0261 (9) | −0.0151 (6) | 0.0298 (9) |
C1 | 0.0142 (6) | 0.0173 (8) | 0.0184 (7) | −0.0008 (6) | 0.0005 (5) | −0.0011 (6) |
C2 | 0.0159 (6) | 0.0152 (7) | 0.0117 (6) | −0.0003 (6) | 0.0008 (5) | −0.0011 (6) |
C3 | 0.0140 (6) | 0.0145 (7) | 0.0163 (6) | 0.0002 (6) | 0.0009 (5) | 0.0002 (6) |
C4 | 0.0158 (6) | 0.0193 (8) | 0.0158 (7) | −0.0032 (6) | −0.0001 (5) | −0.0010 (6) |
C5 | 0.0193 (7) | 0.0218 (9) | 0.0226 (7) | −0.0011 (7) | 0.0020 (6) | −0.0071 (7) |
C6 | 0.0176 (7) | 0.0268 (10) | 0.0338 (9) | 0.0043 (7) | 0.0005 (6) | 0.0022 (8) |
C7 | 0.0237 (7) | 0.0190 (9) | 0.0190 (7) | −0.0008 (7) | 0.0001 (6) | −0.0027 (6) |
C8 | 0.0274 (8) | 0.0333 (10) | 0.0167 (7) | −0.0059 (8) | 0.0021 (6) | −0.0065 (7) |
C9 | 0.0379 (12) | 0.085 (2) | 0.0226 (10) | 0.0080 (13) | −0.0066 (8) | −0.0003 (12) |
C10 | 0.0763 (19) | 0.0427 (15) | 0.0329 (11) | −0.0258 (15) | 0.0143 (12) | −0.0192 (11) |
C11 | 0.0379 (11) | 0.0528 (16) | 0.0231 (9) | −0.0126 (10) | 0.0115 (8) | −0.0096 (10) |
C12 | 0.0144 (6) | 0.0190 (8) | 0.0153 (6) | 0.0000 (6) | 0.0008 (5) | −0.0012 (6) |
C13 | 0.0180 (6) | 0.0171 (8) | 0.0187 (7) | 0.0038 (6) | 0.0007 (5) | 0.0009 (6) |
C14 | 0.0255 (8) | 0.0179 (9) | 0.0321 (9) | 0.0008 (7) | −0.0001 (7) | −0.0002 (8) |
C15 | 0.0310 (8) | 0.0259 (10) | 0.0225 (8) | 0.0102 (8) | 0.0078 (7) | 0.0021 (7) |
C16 | 0.0200 (7) | 0.0260 (10) | 0.0209 (7) | 0.0018 (7) | −0.0023 (6) | 0.0030 (7) |
C17 | 0.0200 (7) | 0.0283 (10) | 0.0197 (7) | −0.0012 (7) | −0.0037 (6) | 0.0048 (7) |
C18 | 0.0207 (7) | 0.0293 (10) | 0.0190 (7) | −0.0046 (7) | −0.0028 (6) | 0.0000 (7) |
C19 | 0.0188 (7) | 0.0487 (15) | 0.0356 (10) | −0.0022 (9) | 0.0018 (7) | −0.0099 (10) |
C20 | 0.0342 (10) | 0.0431 (14) | 0.0267 (9) | −0.0065 (10) | −0.0126 (8) | 0.0056 (10) |
C21 | 0.0331 (9) | 0.0289 (11) | 0.0263 (9) | −0.0051 (8) | −0.0006 (7) | −0.0018 (8) |
O1—C1 | 1.3881 (19) | C10—H101 | 0.92 (4) |
O1—C6 | 1.432 (2) | C10—H102 | 1.05 (5) |
O2—C7 | 1.355 (2) | C10—H103 | 1.05 (4) |
O2—C2 | 1.4352 (18) | C11—H111 | 1.02 (3) |
O3—C12 | 1.3620 (19) | C11—H112 | 0.99 (3) |
O3—C3 | 1.443 (2) | C11—H113 | 1.00 (3) |
O4—C17 | 1.3560 (19) | C12—C13 | 1.529 (2) |
O4—C4 | 1.4421 (19) | C13—C14 | 1.530 (3) |
O5—C1 | 1.4278 (19) | C13—C15 | 1.531 (2) |
O5—C5 | 1.431 (2) | C13—C16 | 1.541 (2) |
O6—C7 | 1.199 (2) | C14—H141 | 0.99 (3) |
O7—C12 | 1.202 (2) | C14—H142 | 1.03 (3) |
O8—C17 | 1.193 (2) | C14—H143 | 0.98 (3) |
C1—C2 | 1.524 (2) | C15—H151 | 1.02 (3) |
C1—H1 | 0.99 (2) | C15—H152 | 0.99 (3) |
C2—C3 | 1.527 (2) | C15—H153 | 0.98 (3) |
C2—H2 | 0.95 (2) | C16—H161 | 0.98 (2) |
C3—C4 | 1.515 (2) | C16—H162 | 0.92 (2) |
C3—H3 | 0.98 (2) | C16—H163 | 1.02 (3) |
C4—C5 | 1.527 (2) | C17—C18 | 1.526 (2) |
C4—H4 | 0.93 (2) | C18—C21 | 1.532 (3) |
C5—H51 | 1.00 (3) | C18—C20 | 1.533 (3) |
C5—H52 | 0.92 (2) | C18—C19 | 1.537 (3) |
C6—H61 | 1.00 (3) | C19—H191 | 0.99 (3) |
C6—H62 | 0.97 (3) | C19—H192 | 0.98 (3) |
C6—H63 | 1.00 (3) | C19—H193 | 0.96 (4) |
C7—C8 | 1.525 (2) | C20—H201 | 0.93 (3) |
C8—C10 | 1.527 (4) | C20—H202 | 0.97 (3) |
C8—C11 | 1.530 (3) | C20—H203 | 0.98 (3) |
C8—C9 | 1.540 (3) | C21—H211 | 1.01 (3) |
C9—H91 | 0.96 (4) | C21—H212 | 0.99 (3) |
C9—H92 | 0.97 (4) | C21—H213 | 0.98 (3) |
C9—H93 | 1.01 (4) | ||
C1—O1—C6 | 111.93 (14) | H102—C10—H103 | 108 (3) |
C7—O2—C2 | 117.23 (13) | C8—C11—H111 | 110.7 (17) |
C12—O3—C3 | 117.38 (13) | C8—C11—H112 | 108.6 (17) |
C17—O4—C4 | 116.30 (13) | H111—C11—H112 | 108 (2) |
C1—O5—C5 | 110.88 (12) | C8—C11—H113 | 112.0 (19) |
O1—C1—O5 | 108.55 (12) | H111—C11—H113 | 111 (3) |
O1—C1—C2 | 108.35 (14) | H112—C11—H113 | 106 (2) |
O5—C1—C2 | 108.59 (12) | O7—C12—O3 | 123.62 (16) |
O1—C1—H1 | 113.0 (12) | O7—C12—C13 | 125.74 (14) |
O5—C1—H1 | 108.6 (12) | O3—C12—C13 | 110.63 (14) |
C2—C1—H1 | 109.6 (12) | C12—C13—C14 | 110.32 (13) |
O2—C2—C1 | 108.51 (12) | C12—C13—C15 | 108.77 (14) |
O2—C2—C3 | 108.88 (12) | C14—C13—C15 | 110.23 (16) |
C1—C2—C3 | 108.82 (13) | C12—C13—C16 | 107.22 (14) |
O2—C2—H2 | 108.9 (13) | C14—C13—C16 | 110.49 (15) |
C1—C2—H2 | 110.9 (12) | C15—C13—C16 | 109.75 (14) |
C3—C2—H2 | 110.9 (12) | C13—C14—H141 | 110.7 (14) |
O3—C3—C4 | 109.13 (13) | C13—C14—H142 | 110.7 (17) |
O3—C3—C2 | 108.55 (14) | H141—C14—H142 | 106 (2) |
C4—C3—C2 | 107.77 (12) | C13—C14—H143 | 112.3 (18) |
O3—C3—H3 | 111.0 (12) | H141—C14—H143 | 108 (2) |
C4—C3—H3 | 109.9 (12) | H142—C14—H143 | 108 (2) |
C2—C3—H3 | 110.5 (12) | C13—C15—H151 | 110.1 (17) |
O4—C4—C3 | 108.50 (12) | C13—C15—H152 | 114.1 (18) |
O4—C4—C5 | 108.97 (15) | H151—C15—H152 | 107 (2) |
C3—C4—C5 | 109.00 (13) | C13—C15—H153 | 111.1 (16) |
O4—C4—H4 | 112.6 (13) | H151—C15—H153 | 107 (3) |
C3—C4—H4 | 108.4 (14) | H152—C15—H153 | 107 (3) |
C5—C4—H4 | 109.2 (13) | C13—C16—H161 | 110.8 (13) |
O5—C5—C4 | 109.61 (14) | C13—C16—H162 | 111.0 (15) |
O5—C5—H51 | 112.0 (14) | H161—C16—H162 | 107 (2) |
C4—C5—H51 | 109.4 (14) | C13—C16—H163 | 110.8 (16) |
O5—C5—H52 | 105.9 (14) | H161—C16—H163 | 108.4 (19) |
C4—C5—H52 | 111.2 (15) | H162—C16—H163 | 108 (2) |
H51—C5—H52 | 109 (2) | O8—C17—O4 | 123.09 (16) |
O1—C6—H61 | 105.9 (17) | O8—C17—C18 | 125.57 (16) |
O1—C6—H62 | 110.7 (16) | O4—C17—C18 | 111.31 (14) |
H61—C6—H62 | 110 (2) | C17—C18—C21 | 107.88 (16) |
O1—C6—H63 | 112.3 (16) | C17—C18—C20 | 108.69 (16) |
H61—C6—H63 | 111 (2) | C21—C18—C20 | 110.12 (18) |
H62—C6—H63 | 107 (2) | C17—C18—C19 | 109.41 (15) |
O6—C7—O2 | 123.31 (16) | C21—C18—C19 | 109.99 (19) |
O6—C7—C8 | 125.55 (18) | C20—C18—C19 | 110.71 (18) |
O2—C7—C8 | 111.13 (15) | C18—C19—H191 | 110.5 (16) |
C7—C8—C10 | 108.88 (18) | C18—C19—H192 | 111.4 (16) |
C7—C8—C11 | 110.53 (15) | H191—C19—H192 | 108 (2) |
C10—C8—C11 | 109.5 (2) | C18—C19—H193 | 114 (2) |
C7—C8—C9 | 107.08 (17) | H191—C19—H193 | 105 (3) |
C10—C8—C9 | 110.8 (2) | H192—C19—H193 | 109 (3) |
C11—C8—C9 | 110.1 (2) | C18—C20—H201 | 112.7 (18) |
C8—C9—H91 | 110 (2) | C18—C20—H202 | 106.7 (17) |
C8—C9—H92 | 108 (2) | H201—C20—H202 | 106 (3) |
H91—C9—H92 | 110 (3) | C18—C20—H203 | 110.7 (18) |
C8—C9—H93 | 111 (2) | H201—C20—H203 | 110 (3) |
H91—C9—H93 | 110 (3) | H202—C20—H203 | 110 (2) |
H92—C9—H93 | 108 (3) | C18—C21—H211 | 108.7 (18) |
C8—C10—H101 | 113 (3) | C18—C21—H212 | 108 (2) |
C8—C10—H102 | 109 (3) | H211—C21—H212 | 110 (3) |
H101—C10—H102 | 111 (4) | C18—C21—H213 | 111 (2) |
C8—C10—H103 | 106 (2) | H211—C21—H213 | 113 (3) |
H101—C10—H103 | 109 (3) | H212—C21—H213 | 107 (3) |