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The structure of the title TeIV complex, C13H19BrN2OS4Te.045(CH2Cl2), is pentagonal bipyramidal with four S atoms [Te—S 2.623 (1)–2.717 (1) Å] and the Br atom [Te—Br 2.890 (1) Å] in equatorial positions. The p-methoxyphenyl group is axial [Te—C 2.145 (3) Å] and the second axial position seems to be occupied by a dithiocarbamate group of a neighbouring molecule acting as a π-ligand [Te...C 3.751 (3) Å, C—Te...C 170.2 (1)°], so that molecules are joined into centrosymmetric associations by this secondary coordination.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, telbg

hkl

Structure factor file (CIF format)
Contains datablock telbg

CCDC reference: 126347

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