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A novel three-dimensional CdII coordination framework, namely, poly[{μ-bis­[4-(2-methyl­imidazol-1-yl)phenyl] ether-κ2N3:N3′}(μ-naphthalene-1,4-di­car­box­yl­ato-κ3O1:O4,O4′)cadmium(II)], [Cd(C12H6O4)(C20H18N4O)]n or [Cd(1,4-NDC)(BMIOPE)]n, where 1,4-H2NDC is naphthalene-1,4-di­carb­oxy­lic acid and BMIOPE is bis­[4-(2-methyl­imidazol-1-yl)phenyl] ether, has been prepared and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermogravimetric analysis. The com­pound displays a novel fourfold inter­penetrating diamond-like network. In addition, it not only shows a strong fluorescence emission in the solid state, but also exhibits excellent photocatalytic activity for the degradation of methylene blue (MB) at room temperature.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S2053229621004642/ov3147sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2053229621004642/ov3147Isup2.hkl
Contains datablock I

pdf

Portable Document Format (PDF) file https://doi.org/10.1107/S2053229621004642/ov3147sup3.pdf
Additional figures

CCDC reference: 2081436

Computing details top

Data collection: APEX3 (Bruker, 2016); cell refinement: SAINT (Bruker, 2016); data reduction: SAINT (Bruker, 2016); program(s) used to solve structure: SHELXS2014 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: publCIF (Westrip, 2010) and TOPOS (Blatov & Shevchenko, 2006).

Poly[{µ-bis[4-(2-methylimidazol-1-yl)phenyl] ether-κ2N3:N3'}(µ-naphthalene-1,4-dicarboxylato-κ3O1:O4,O4')cadmium(II)] top
Crystal data top
[Cd(C12H6O4)(C20H18N4O)]Dx = 1.523 Mg m3
Mr = 656.96Mo Kα radiation, λ = 0.71073 Å
Tetragonal, P43Cell parameters from 9690 reflections
a = 10.6631 (6) Åθ = 2.7–27.5°
c = 25.203 (2) ŵ = 0.81 mm1
V = 2865.6 (4) Å3T = 298 K
Z = 4Block, colorless
F(000) = 13280.21 × 0.20 × 0.19 mm
Data collection top
Bruker APEXII CCD
diffractometer
5479 reflections with I > 2σ(I)
φ and ω scansRint = 0.025
Absorption correction: multi-scan
(SADABS; Bruker, 2008)
θmax = 26.0°, θmin = 2.7°
Tmin = 0.651, Tmax = 0.746h = 1313
183838 measured reflectionsk = 1313
5614 independent reflectionsl = 3131
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.026H-atom parameters constrained
wR(F2) = 0.066 w = 1/[σ2(Fo2) + (0.0312P)2 + 1.795P]
where P = (Fo2 + 2Fc2)/3
S = 1.10(Δ/σ)max < 0.001
5614 reflectionsΔρmax = 0.60 e Å3
381 parametersΔρmin = 0.35 e Å3
1 restraintAbsolute structure: Flack x determined using 2652 quotients [(I+)-(I-)]/[(I+)+(I-)] (Parsons et al., 2013)
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.009 (3)
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
C10.3840 (6)0.4034 (5)0.6654 (2)0.0606 (14)
C20.4328 (5)0.2940 (5)0.69762 (18)0.0503 (11)
C30.3787 (5)0.2754 (6)0.7465 (2)0.0628 (14)
H30.31610.32940.75830.075*
C40.4172 (6)0.1752 (6)0.7788 (2)0.0645 (15)
H40.38140.16540.81220.077*
C50.5055 (5)0.0924 (5)0.76245 (18)0.0481 (10)
C60.5618 (4)0.1062 (4)0.71158 (17)0.0405 (9)
C70.6522 (4)0.0218 (4)0.69172 (19)0.0489 (10)
H70.67710.04540.71280.059*
C80.7036 (5)0.0354 (6)0.6433 (2)0.0644 (14)
H80.76290.02180.63130.077*
C90.6669 (6)0.1369 (6)0.6111 (2)0.0685 (15)
H90.70190.14600.57750.082*
C100.5815 (5)0.2213 (6)0.62837 (19)0.0608 (13)
H100.55930.28810.60660.073*
C110.5250 (4)0.2098 (4)0.67914 (17)0.0439 (9)
C120.5434 (5)0.0112 (5)0.79977 (18)0.0502 (11)
C130.4820 (5)0.7762 (6)0.6178 (2)0.0668 (13)
H13A0.41320.77960.64240.100*
H13B0.51520.85900.61280.100*
H13C0.54630.72250.63170.100*
C140.4372 (5)0.7259 (4)0.56611 (18)0.0469 (10)
C150.3321 (6)0.6281 (5)0.5058 (2)0.0621 (14)
H150.27070.57910.48970.075*
C160.4287 (7)0.6818 (6)0.4807 (2)0.0720 (17)
H160.44710.67790.44470.086*
C170.5998 (5)0.8275 (5)0.5092 (2)0.0536 (11)
C180.7196 (5)0.8008 (5)0.5262 (2)0.0574 (12)
H180.73450.73030.54700.069*
C190.8174 (5)0.8792 (5)0.5123 (2)0.0551 (12)
H190.89850.86210.52380.066*
C200.7937 (5)0.9826 (5)0.48151 (18)0.0509 (11)
C210.6730 (5)1.0130 (5)0.4663 (2)0.0623 (14)
H210.65741.08600.44720.075*
C220.5754 (5)0.9336 (6)0.4799 (3)0.0680 (16)
H220.49390.95190.46940.082*
C230.9009 (5)1.0987 (5)0.41525 (19)0.0508 (11)
C240.8614 (6)1.0230 (5)0.3748 (2)0.0697 (15)
H240.82610.94510.38200.084*
C250.8745 (7)1.0634 (5)0.3233 (2)0.0676 (16)
H250.84921.01200.29540.081*
C260.9246 (4)1.1787 (5)0.31282 (19)0.0487 (10)
C270.9610 (6)1.2548 (6)0.3539 (2)0.0745 (18)
H270.99441.33350.34670.089*
C280.9485 (7)1.2156 (7)0.4054 (2)0.0755 (19)
H280.97211.26770.43330.091*
C290.7199 (6)1.3199 (8)0.2552 (3)0.083 (2)
H29A0.66801.35690.22830.125*
H29B0.73391.37960.28310.125*
H29C0.67891.24720.26950.125*
C300.8427 (4)1.2826 (5)0.23156 (18)0.0477 (11)
C311.0314 (5)1.2001 (5)0.2247 (2)0.0610 (13)
H311.10661.16000.23270.073*
C320.9975 (5)1.2495 (5)0.1779 (2)0.0606 (14)
H321.04641.24900.14730.073*
Cd10.20681 (3)0.57736 (3)0.61870 (2)0.04114 (9)
N10.3372 (4)0.6566 (4)0.55918 (16)0.0517 (10)
N20.4957 (4)0.7442 (4)0.51948 (18)0.0576 (11)
N30.9320 (4)1.2208 (4)0.25840 (17)0.0489 (9)
N40.8788 (4)1.3016 (4)0.18177 (15)0.0457 (9)
O10.2738 (4)0.4285 (5)0.6697 (2)0.0894 (16)
O20.4579 (6)0.4704 (6)0.6406 (3)0.130 (3)
O30.4609 (4)0.0745 (5)0.8203 (2)0.0839 (14)
O40.6577 (4)0.0308 (4)0.80877 (18)0.0804 (14)
O50.8929 (4)1.0599 (4)0.46781 (14)0.0637 (10)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.074 (4)0.063 (3)0.044 (3)0.019 (3)0.002 (2)0.016 (2)
C20.060 (3)0.054 (3)0.038 (2)0.007 (2)0.002 (2)0.015 (2)
C30.070 (3)0.072 (4)0.046 (3)0.025 (3)0.012 (3)0.014 (2)
C40.078 (4)0.079 (4)0.036 (2)0.018 (3)0.013 (2)0.021 (2)
C50.053 (3)0.055 (3)0.037 (2)0.000 (2)0.0040 (19)0.012 (2)
C60.043 (2)0.045 (2)0.0338 (19)0.0012 (17)0.0052 (16)0.0057 (16)
C70.050 (2)0.047 (2)0.049 (3)0.0036 (19)0.003 (2)0.006 (2)
C80.066 (3)0.071 (3)0.056 (3)0.008 (3)0.011 (2)0.003 (3)
C90.075 (3)0.092 (4)0.038 (3)0.011 (3)0.016 (3)0.010 (3)
C100.069 (3)0.077 (3)0.037 (3)0.006 (3)0.001 (2)0.020 (2)
C110.047 (2)0.051 (2)0.033 (2)0.0003 (19)0.0046 (18)0.0091 (18)
C120.061 (3)0.053 (3)0.037 (2)0.003 (2)0.003 (2)0.015 (2)
C130.072 (3)0.082 (3)0.046 (2)0.017 (3)0.002 (3)0.002 (3)
C140.057 (3)0.045 (2)0.039 (2)0.002 (2)0.0018 (19)0.0081 (18)
C150.078 (4)0.063 (3)0.045 (3)0.014 (3)0.001 (3)0.002 (2)
C160.097 (5)0.072 (4)0.047 (3)0.017 (3)0.005 (3)0.007 (3)
C170.056 (3)0.056 (3)0.049 (3)0.001 (2)0.012 (2)0.009 (2)
C180.060 (3)0.061 (3)0.051 (3)0.018 (2)0.007 (2)0.018 (2)
C190.046 (2)0.072 (3)0.047 (3)0.015 (2)0.003 (2)0.013 (2)
C200.053 (3)0.066 (3)0.034 (2)0.003 (2)0.0041 (19)0.010 (2)
C210.052 (3)0.065 (3)0.070 (3)0.004 (2)0.001 (2)0.026 (3)
C220.050 (3)0.073 (4)0.081 (4)0.007 (2)0.003 (3)0.029 (3)
C230.045 (2)0.069 (3)0.039 (2)0.007 (2)0.0002 (18)0.011 (2)
C240.112 (5)0.050 (3)0.047 (3)0.013 (3)0.007 (3)0.008 (2)
C250.114 (5)0.049 (3)0.040 (3)0.012 (3)0.007 (3)0.003 (2)
C260.050 (3)0.059 (3)0.037 (2)0.003 (2)0.0065 (18)0.011 (2)
C270.085 (4)0.081 (4)0.058 (4)0.041 (3)0.001 (3)0.014 (3)
C280.088 (4)0.093 (5)0.044 (3)0.042 (4)0.010 (3)0.002 (3)
C290.056 (3)0.139 (6)0.054 (3)0.021 (4)0.021 (3)0.032 (4)
C300.046 (2)0.061 (3)0.036 (2)0.000 (2)0.0074 (19)0.005 (2)
C310.057 (3)0.069 (3)0.057 (3)0.017 (2)0.022 (2)0.016 (3)
C320.073 (3)0.059 (3)0.050 (3)0.016 (3)0.028 (3)0.012 (2)
Cd10.04676 (17)0.04359 (16)0.03307 (13)0.00448 (12)0.00818 (13)0.00357 (12)
N10.067 (3)0.049 (2)0.040 (2)0.0060 (19)0.0018 (18)0.0058 (17)
N20.063 (3)0.061 (3)0.049 (2)0.005 (2)0.006 (2)0.009 (2)
N30.052 (2)0.053 (2)0.042 (2)0.0002 (18)0.0130 (16)0.0094 (17)
N40.053 (2)0.050 (2)0.0337 (19)0.0004 (17)0.0113 (16)0.0033 (16)
O10.062 (3)0.098 (3)0.108 (4)0.026 (2)0.008 (2)0.059 (3)
O20.113 (4)0.121 (5)0.157 (6)0.028 (4)0.031 (4)0.097 (5)
O30.061 (2)0.092 (3)0.099 (3)0.011 (2)0.011 (2)0.054 (3)
O40.068 (3)0.094 (3)0.079 (3)0.009 (2)0.025 (2)0.048 (2)
O50.056 (2)0.099 (3)0.0355 (17)0.0178 (19)0.0047 (14)0.0188 (18)
Geometric parameters (Å, º) top
C1—O11.210 (7)C19—C201.371 (7)
C1—O21.234 (8)C19—H190.9300
C1—C21.513 (6)C20—C211.382 (7)
C2—C31.376 (7)C20—O51.385 (6)
C2—C111.410 (7)C21—C221.384 (8)
C3—C41.405 (7)C21—H210.9300
C3—H30.9300C22—H220.9300
C4—C51.355 (7)C23—C241.366 (8)
C4—H40.9300C23—C281.368 (8)
C5—C61.423 (6)C23—O51.390 (6)
C5—C121.506 (6)C24—C251.376 (8)
C6—C71.411 (7)C24—H240.9300
C6—C111.429 (6)C25—C261.366 (7)
C7—C81.344 (8)C25—H250.9300
C7—H70.9300C26—C271.371 (8)
C8—C91.409 (8)C26—N31.445 (6)
C8—H80.9300C27—C281.371 (8)
C9—C101.353 (8)C27—H270.9300
C9—H90.9300C28—H280.9300
C10—C111.419 (6)C29—C301.492 (7)
C10—H100.9300C29—H29A0.9600
C12—O31.224 (6)C29—H29B0.9600
C12—O41.257 (6)C29—H29C0.9600
C12—Cd1i2.739 (4)C30—N41.328 (6)
C13—C141.488 (8)C30—N31.342 (6)
C13—H13A0.9600C31—C321.342 (8)
C13—H13B0.9600C31—N31.376 (6)
C13—H13C0.9600C31—H310.9300
C14—N11.310 (6)C32—N41.386 (7)
C14—N21.344 (6)C32—H320.9300
C15—C161.337 (9)Cd1—O12.164 (4)
C15—N11.381 (7)Cd1—N12.213 (4)
C15—H150.9300Cd1—N4ii2.242 (4)
C16—N21.380 (8)Cd1—O3iii2.240 (4)
C16—H160.9300Cd1—O4iii2.557 (4)
C17—C181.377 (7)Cd1—C12iii2.739 (4)
C17—C221.375 (8)N4—Cd1iv2.242 (4)
C17—N21.446 (7)O3—Cd1i2.240 (4)
C18—C191.382 (8)O4—Cd1i2.557 (4)
C18—H180.9300
O1—C1—O2122.5 (5)C20—C21—H21120.4
O1—C1—C2117.2 (5)C17—C22—C21119.6 (5)
O2—C1—C2119.9 (5)C17—C22—H22120.2
C3—C2—C11119.8 (4)C21—C22—H22120.2
C3—C2—C1116.6 (5)C24—C23—C28121.2 (5)
C11—C2—C1123.6 (4)C24—C23—O5121.1 (5)
C2—C3—C4120.4 (5)C28—C23—O5117.8 (5)
C2—C3—H3119.8C23—C24—C25119.2 (5)
C4—C3—H3119.8C23—C24—H24120.4
C5—C4—C3121.5 (5)C25—C24—H24120.4
C5—C4—H4119.3C26—C25—C24120.2 (5)
C3—C4—H4119.3C26—C25—H25119.9
C4—C5—C6120.0 (4)C24—C25—H25119.9
C4—C5—C12118.3 (4)C27—C26—C25119.8 (5)
C6—C5—C12121.7 (4)C27—C26—N3121.2 (5)
C7—C6—C5122.8 (4)C25—C26—N3118.9 (5)
C7—C6—C11118.5 (4)C26—C27—C28120.5 (5)
C5—C6—C11118.7 (4)C26—C27—H27119.7
C8—C7—C6122.1 (5)C28—C27—H27119.7
C8—C7—H7119.0C23—C28—C27119.0 (6)
C6—C7—H7119.0C23—C28—H28120.5
C7—C8—C9119.5 (5)C27—C28—H28120.5
C7—C8—H8120.2C30—C29—H29A109.5
C9—C8—H8120.2C30—C29—H29B109.5
C10—C9—C8120.8 (5)H29A—C29—H29B109.5
C10—C9—H9119.6C30—C29—H29C109.5
C8—C9—H9119.6H29A—C29—H29C109.5
C9—C10—C11121.2 (5)H29B—C29—H29C109.5
C9—C10—H10119.4N4—C30—N3110.2 (4)
C11—C10—H10119.4N4—C30—C29126.2 (5)
C2—C11—C10122.6 (4)N3—C30—C29123.5 (4)
C2—C11—C6119.6 (4)C32—C31—N3105.8 (5)
C10—C11—C6117.8 (4)C32—C31—H31127.1
O3—C12—O4121.9 (4)N3—C31—H31127.1
O3—C12—C5118.4 (5)C31—C32—N4110.0 (4)
O4—C12—C5119.7 (4)C31—C32—H32125.0
O3—C12—Cd1i53.6 (3)N4—C32—H32125.0
O4—C12—Cd1i68.3 (3)O1—Cd1—N1118.37 (17)
C5—C12—Cd1i172.0 (4)O1—Cd1—N4ii97.78 (19)
C14—C13—H13A109.5N1—Cd1—N4ii121.12 (16)
C14—C13—H13B109.5O1—Cd1—O3iii97.2 (2)
H13A—C13—H13B109.5N1—Cd1—O3iii103.80 (19)
C14—C13—H13C109.5N4ii—Cd1—O3iii116.65 (19)
H13A—C13—H13C109.5O1—Cd1—O4iii147.02 (19)
H13B—C13—H13C109.5N1—Cd1—O4iii86.17 (17)
N1—C14—N2110.0 (4)N4ii—Cd1—O4iii85.83 (14)
N1—C14—C13125.6 (4)O3iii—Cd1—O4iii53.26 (14)
N2—C14—C13124.4 (5)O1—Cd1—C12iii122.09 (19)
C16—C15—N1109.5 (5)N1—Cd1—C12iii95.70 (15)
C16—C15—H15125.2N4ii—Cd1—C12iii102.46 (15)
N1—C15—H15125.2O3iii—Cd1—C12iii26.09 (15)
C15—C16—N2105.8 (5)O4iii—Cd1—C12iii27.18 (14)
C15—C16—H16127.1C14—N1—C15106.7 (4)
N2—C16—H16127.1C14—N1—Cd1129.6 (3)
C18—C17—C22120.8 (5)C15—N1—Cd1123.5 (4)
C18—C17—N2122.0 (5)C14—N2—C16108.0 (5)
C22—C17—N2117.2 (5)C14—N2—C17127.0 (5)
C17—C18—C19119.7 (5)C16—N2—C17124.5 (5)
C17—C18—H18120.1C30—N3—C31108.3 (4)
C19—C18—H18120.1C30—N3—C26126.3 (4)
C20—C19—C18119.4 (5)C31—N3—C26125.4 (4)
C20—C19—H19120.3C30—N4—C32105.7 (4)
C18—C19—H19120.3C30—N4—Cd1iv129.8 (3)
C19—C20—C21121.1 (5)C32—N4—Cd1iv123.5 (3)
C19—C20—O5118.6 (5)C1—O1—Cd1115.4 (4)
C21—C20—O5120.2 (5)C12—O3—Cd1i100.4 (3)
C22—C21—C20119.2 (5)C12—O4—Cd1i84.5 (3)
C22—C21—H21120.4C20—O5—C23117.5 (4)
O1—C1—C2—C333.8 (8)C25—C26—C27—C280.5 (10)
O2—C1—C2—C3138.7 (7)N3—C26—C27—C28177.3 (6)
O1—C1—C2—C11143.4 (6)C24—C23—C28—C272.6 (11)
O2—C1—C2—C1144.1 (9)O5—C23—C28—C27178.1 (6)
C11—C2—C3—C41.9 (9)C26—C27—C28—C231.0 (11)
C1—C2—C3—C4179.2 (6)N3—C31—C32—N40.3 (7)
C2—C3—C4—C51.9 (10)N2—C14—N1—C150.6 (6)
C3—C4—C5—C60.3 (9)C13—C14—N1—C15178.5 (5)
C3—C4—C5—C12178.9 (6)N2—C14—N1—Cd1174.4 (3)
C4—C5—C6—C7178.6 (5)C13—C14—N1—Cd14.7 (8)
C12—C5—C6—C72.7 (7)C16—C15—N1—C140.6 (7)
C4—C5—C6—C111.3 (7)C16—C15—N1—Cd1174.9 (4)
C12—C5—C6—C11177.4 (4)N1—C14—N2—C160.4 (6)
C5—C6—C7—C8179.3 (5)C13—C14—N2—C16178.7 (5)
C11—C6—C7—C80.6 (7)N1—C14—N2—C17171.8 (5)
C6—C7—C8—C90.1 (9)C13—C14—N2—C179.1 (8)
C7—C8—C9—C100.6 (10)C15—C16—N2—C140.0 (7)
C8—C9—C10—C110.7 (10)C15—C16—N2—C17172.4 (5)
C3—C2—C11—C10177.8 (6)C18—C17—N2—C1473.6 (7)
C1—C2—C11—C100.7 (8)C22—C17—N2—C14108.5 (7)
C3—C2—C11—C60.3 (8)C18—C17—N2—C16115.4 (7)
C1—C2—C11—C6177.5 (5)C22—C17—N2—C1662.5 (8)
C9—C10—C11—C2178.0 (6)N4—C30—N3—C310.7 (6)
C9—C10—C11—C60.2 (8)C29—C30—N3—C31179.2 (6)
C7—C6—C11—C2178.7 (5)N4—C30—N3—C26177.2 (5)
C5—C6—C11—C21.2 (7)C29—C30—N3—C261.3 (9)
C7—C6—C11—C100.4 (7)C32—C31—N3—C300.6 (7)
C5—C6—C11—C10179.5 (5)C32—C31—N3—C26177.3 (5)
C4—C5—C12—O350.3 (8)C27—C26—N3—C3088.8 (7)
C6—C5—C12—O3131.0 (6)C25—C26—N3—C3088.0 (7)
C4—C5—C12—O4130.1 (6)C27—C26—N3—C3193.6 (7)
C6—C5—C12—O448.6 (7)C25—C26—N3—C3189.6 (7)
N1—C15—C16—N20.3 (7)N3—C30—N4—C320.5 (6)
C22—C17—C18—C192.1 (9)C29—C30—N4—C32178.9 (6)
N2—C17—C18—C19175.7 (5)N3—C30—N4—Cd1iv169.2 (3)
C17—C18—C19—C200.3 (8)C29—C30—N4—Cd1iv12.4 (8)
C18—C19—C20—C213.3 (9)C31—C32—N4—C300.1 (6)
C18—C19—C20—O5179.8 (5)C31—C32—N4—Cd1iv169.7 (4)
C19—C20—C21—C223.9 (9)O2—C1—O1—Cd111.7 (10)
O5—C20—C21—C22179.3 (6)C2—C1—O1—Cd1176.0 (4)
C18—C17—C22—C211.6 (10)O4—C12—O3—Cd1i0.0 (7)
N2—C17—C22—C21176.3 (6)C5—C12—O3—Cd1i179.6 (4)
C20—C21—C22—C171.4 (10)O3—C12—O4—Cd1i0.0 (6)
C28—C23—C24—C252.6 (10)C5—C12—O4—Cd1i179.6 (4)
O5—C23—C24—C25178.0 (6)C19—C20—O5—C23134.5 (5)
C23—C24—C25—C261.1 (10)C21—C20—O5—C2348.5 (7)
C24—C25—C26—C270.5 (10)C24—C23—O5—C2032.7 (8)
C24—C25—C26—N3177.3 (6)C28—C23—O5—C20146.6 (6)
Symmetry codes: (i) y, x, z+1/4; (ii) x+1, y+2, z+1/2; (iii) y, x, z1/4; (iv) x+1, y+2, z1/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C21—H21···O1v0.932.313.207 (7)162
C25—H25···O5vi0.932.533.295 (7)140
C32—H32···O4vii0.932.583.175 (7)122
Symmetry codes: (v) y+1, x+1, z1/4; (vi) y+2, x, z1/4; (vii) y+1, x+2, z3/4.
 

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