cif-access (metal-organic compounds)
The title compound belongs to a family of dimeric clusters formed through bonding of electron-rich iron carbonyls to electron-deficient thallium atoms previously reported. Pressurization under CO of the thallium-iron carbonyl [Et4N]2[Tl2Fe4(CO)16] yielded crystals of [Et4N]2[Tl2Fe6(CO)24], which crystallizes in the orthorhombic, centrosymmetric space group Cmca.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 130516