catena-Poly­[[[bis­(perchlorato-O)­(1,10-phenanthroline-N,N')­copper(II)]-[mu]-4,4'-bi­pyridine-N:N'] monohydrate]

The Cu atom in the title complex {[Cu(C₁₀H₈N₂)(C₁₂H₈N₂)(ClO₄)₂]·H₂O}_n, has an N₄O₂ octahedral coordination geometry, the Cu atoms being bridged by the bi­pyridine and chelated by the phenanthroline heterocycles. Adjacent mol­ecules are linked into a zigzag chain running along the c axis of the monoclinic unit cell. The chains are connected through lattice water mol­ecules to produce a layer structure.

Computing details

Data collection: R3m Software (Siemens, 1990); cell refinement: R3m Software; data reduction: R3m Software; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); software used to prepare material for publication: SHELXL97.

catena-(µ₂-4,4'-bipyridine)(1,10-phenanthroline)(diperchlorato)copper(II)monohydrate

Crystal data

[Cu(C12H8N2)(C10H8N2)(ClO4)2]·H2O	F(000) = 1252
Mr = 616.84	Dx = 1.717 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 12.553 (1) Å	Cell parameters from 25 reflections
b = 14.4169 (9) Å	θ = 7.5–15°
c = 13.2205 (9) Å	µ = 1.20 mm^−1
β = 94.377 (7)°	T = 298 K
V = 2385.5 (3) Å^3	Block, blue
Z = 4	0.42 × 0.36 × 0.34 mm

Data collection

Siemens R3m diffractometer	2883 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.004
Graphite monochromator	θmax = 25.0°, θmin = 2.2°
ω scans	h = 0→14
Absorption correction: ψ scan (North et al., 1968)	k = 0→17
Tmin = 0.596, Tmax = 0.665	l = −15→15
5775 measured reflections	2 standard reflections every 120 reflections
4185 independent reflections	intensity decay: none

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.061	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.173	H-atom parameters constrained
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0826P)^2 + 6.1274P] where P = (Fo^2 + 2Fc^2)/3
4187 reflections	(Δ/σ)max < 0.001
343 parameters	Δρmax = 0.61 e Å^−3
12 restraints	Δρmin = −0.77 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Cu1	0.65192 (6)	0.28804 (5)	−0.05341 (5)	0.0354 (2)
Cl1	0.3745 (1)	0.2847 (1)	−0.0819 (1)	0.0545 (5)
Cl2	0.9269 (1)	0.3141 (1)	−0.1729 (1)	0.0414 (4)
O1	0.4694 (3)	0.2999 (3)	−0.0172 (3)	0.059 (1)
O2	0.2859 (5)	0.3216 (6)	−0.0384 (6)	0.128 (3)
O3	0.3870 (6)	0.3170 (9)	−0.1773 (5)	0.195 (6)
O4	0.3615 (8)	0.1882 (4)	−0.0906 (8)	0.161 (4)
O5	0.8551 (4)	0.2691 (4)	−0.1112 (4)	0.073 (2)
O6	0.9684 (5)	0.3926 (3)	−0.1192 (5)	0.087 (2)
O7	1.0114 (5)	0.2548 (4)	−0.1901 (5)	0.100 (2)
O8	0.8710 (5)	0.3421 (8)	−0.2629 (5)	0.150 (4)
O1W	0.353 (1)	0.0485 (9)	0.077 (1)	0.237 (6)
N1	0.6253 (4)	0.2262 (3)	−0.1882 (3)	0.034 (1)
N2	0.6331 (4)	0.4039 (3)	−0.1398 (3)	0.035 (1)
N3	0.7026 (4)	0.3591 (3)	0.0719 (3)	0.035 (1)
N4	0.8234 (4)	0.6701 (3)	0.4719 (3)	0.037 (1)
C1	0.6174 (5)	0.2871 (4)	−0.2655 (4)	0.036 (1)
C2	0.6203 (5)	0.1362 (4)	−0.2097 (5)	0.046 (2)
C3	0.6071 (5)	0.1035 (5)	−0.3084 (6)	0.057 (2)
C4	0.6001 (6)	0.1642 (5)	−0.3869 (5)	0.057 (2)
C5	0.6050 (5)	0.2602 (5)	−0.3676 (5)	0.045 (2)
C6	0.5973 (6)	0.3303 (7)	−0.4448 (5)	0.066 (2)
C7	0.6010 (6)	0.4192 (6)	−0.4196 (5)	0.062 (2)
C8	0.6118 (5)	0.4494 (4)	−0.3160 (5)	0.044 (2)
C9	0.6131 (5)	0.5428 (5)	−0.2833 (6)	0.057 (2)
C10	0.6220 (6)	0.5637 (5)	−0.1839 (6)	0.057 (2)
C11	0.6322 (5)	0.4924 (4)	−0.1137 (5)	0.047 (2)
C12	0.6215 (4)	0.3823 (4)	−0.2398 (4)	0.033 (1)
C13	0.6464 (5)	0.3570 (4)	0.1532 (4)	0.040 (1)
C14	0.6732 (5)	0.4092 (4)	0.2372 (4)	0.039 (1)
C15	0.7589 (4)	0.4688 (4)	0.2402 (4)	0.034 (1)
C16	0.8191 (5)	0.4682 (4)	0.1563 (4)	0.041 (2)
C17	0.7897 (5)	0.4130 (4)	0.0754 (5)	0.044 (2)
C18	0.7836 (5)	0.5347 (4)	0.3250 (4)	0.034 (1)
C19	0.7010 (5)	0.5811 (4)	0.3667 (4)	0.039 (1)
C20	0.7234 (5)	0.6478 (4)	0.4381 (4)	0.042 (2)
C21	0.9038 (5)	0.6229 (4)	0.4329 (5)	0.046 (2)
C22	0.8853 (5)	0.5563 (4)	0.3614 (5)	0.048 (2)
H1W1	0.3700	0.0965	0.0364	0.050*
H1W2	0.2991	0.0760	0.1074	0.050*
H2	0.6260	0.0936	−0.1567	0.055*
H3	0.6027	0.0401	−0.3208	0.069*
H4	0.5923	0.1426	−0.4533	0.068*
H6	0.5898	0.3132	−0.5128	0.079*
H7	0.5964	0.4636	−0.4708	0.074*
H9	0.6079	0.5903	−0.3310	0.068*
H10	0.6215	0.6252	−0.1625	0.069*
H11	0.6384	0.5074	−0.0451	0.057*
H13	0.5869	0.3186	0.1528	0.048*
H14	0.6330	0.4047	0.2932	0.047*
H16	0.8795	0.5055	0.1554	0.050*
H17	0.8318	0.4127	0.0205	0.053*
H19	0.6304	0.5669	0.3460	0.046*
H20	0.6669	0.6791	0.4645	0.051*
H21	0.9740	0.6363	0.4559	0.055*
H22	0.9426	0.5250	0.3366	0.058*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.0530 (5)	0.0264 (4)	0.0261 (4)	−0.0060 (3)	−0.0008 (3)	0.0007 (3)
Cl1	0.0446 (9)	0.065 (1)	0.054 (1)	0.0032 (8)	−0.001 (1)	0.0036 (9)
Cl2	0.0442 (9)	0.0432 (9)	0.0379 (8)	−0.0048 (7)	0.0099 (6)	0.0008 (6)
O1	0.044 (3)	0.078 (3)	0.054 (3)	−0.004 (2)	0.000 (2)	0.000 (3)
O2	0.056 (4)	0.198 (8)	0.130 (6)	0.026 (4)	0.016 (4)	−0.041 (6)
O3	0.085 (5)	0.39 (2)	0.103 (6)	0.001 (7)	−0.013 (4)	0.137 (8)
O4	0.169 (8)	0.096 (6)	0.20 (1)	−0.024 (5)	−0.079 (7)	−0.040 (6)
O5	0.074 (4)	0.068 (3)	0.081 (4)	−0.021 (3)	0.036 (3)	0.009 (3)
O6	0.100 (5)	0.050 (3)	0.112 (5)	−0.027 (3)	0.024 (4)	−0.011 (3)
O7	0.098 (5)	0.081 (4)	0.127 (6)	0.030 (4)	0.059 (4)	−0.008 (4)
O8	0.094 (5)	0.29 (1)	0.063 (4)	−0.021 (6)	−0.018 (4)	0.068 (6)
O1W	0.22 (1)	0.18 (1)	0.32 (2)	0.012 (9)	0.08 (1)	0.02 (1)
N1	0.041 (3)	0.029 (3)	0.031 (2)	−0.006 (2)	0.001 (2)	−0.003 (2)
N2	0.041 (3)	0.030 (3)	0.034 (3)	−0.004 (2)	0.002 (2)	0.000 (2)
N3	0.042 (3)	0.036 (3)	0.027 (2)	−0.007 (2)	0.005 (2)	−0.003 (2)
N4	0.051 (3)	0.031 (3)	0.030 (3)	−0.001 (2)	−0.002 (2)	−0.005 (2)
C1	0.035 (3)	0.042 (3)	0.031 (3)	0.000 (3)	0.005 (2)	0.002 (3)
C2	0.049 (4)	0.034 (3)	0.054 (4)	−0.008 (3)	−0.001 (3)	−0.009 (3)
C3	0.060 (5)	0.050 (4)	0.061 (5)	−0.012 (3)	0.003 (4)	−0.024 (4)
C4	0.061 (5)	0.072 (5)	0.038 (4)	−0.008 (4)	0.002 (3)	−0.024 (4)
C5	0.037 (4)	0.062 (4)	0.037 (3)	−0.001 (3)	−0.001 (3)	−0.006 (3)
C6	0.073 (5)	0.098 (7)	0.027 (4)	0.008 (5)	−0.001 (3)	−0.001 (4)
C7	0.065 (5)	0.086 (6)	0.035 (4)	0.007 (4)	0.002 (3)	0.022 (4)
C8	0.034 (3)	0.046 (4)	0.050 (4)	0.005 (3)	0.005 (3)	0.017 (3)
C9	0.059 (4)	0.044 (4)	0.068 (5)	0.007 (3)	0.009 (4)	0.028 (4)
C10	0.062 (5)	0.032 (4)	0.078 (6)	0.001 (3)	0.006 (4)	0.004 (4)
C11	0.051 (4)	0.033 (3)	0.058 (4)	−0.004 (3)	0.005 (3)	−0.002 (3)
C12	0.026 (3)	0.041 (3)	0.035 (3)	0.000 (2)	0.009 (2)	0.006 (3)
C13	0.045 (4)	0.046 (4)	0.028 (3)	−0.015 (3)	0.003 (3)	−0.002 (3)
C14	0.042 (3)	0.049 (4)	0.026 (3)	−0.012 (3)	0.007 (2)	−0.006 (3)
C15	0.035 (3)	0.036 (3)	0.031 (3)	−0.001 (3)	0.000 (2)	−0.002 (2)
C16	0.034 (3)	0.047 (4)	0.044 (3)	−0.013 (3)	0.008 (3)	−0.011 (3)
C17	0.038 (4)	0.053 (4)	0.042 (4)	−0.009 (3)	0.011 (3)	−0.008 (3)
C18	0.042 (3)	0.030 (3)	0.030 (3)	−0.004 (3)	0.002 (2)	−0.004 (2)
C19	0.037 (3)	0.042 (3)	0.037 (3)	−0.004 (3)	0.004 (3)	−0.006 (3)
C20	0.049 (4)	0.041 (3)	0.038 (3)	0.003 (3)	0.008 (3)	−0.008 (3)
C21	0.039 (4)	0.044 (4)	0.051 (4)	0.007 (3)	−0.012 (3)	−0.015 (3)
C22	0.042 (4)	0.048 (4)	0.054 (4)	0.008 (3)	−0.004 (3)	−0.020 (3)

Geometric parameters (Å, º)

Cu1—N1	1.998 (4)	C8—C9	1.41 (1)
Cu1—N2	2.028 (5)	C9—C10	1.35 (1)
Cu1—N3	2.009 (4)	C10—C11	1.384 (9)
Cu1—N4^i	2.025 (5)	C13—C14	1.361 (8)
Cu1—O1	2.382 (4)	C14—C15	1.374 (8)
Cu1—O5	2.731 (5)	C15—C16	1.389 (8)
Cl1—O3	1.365 (6)	C15—C18	1.484 (7)
Cl1—O2	1.395 (5)	C16—C17	1.361 (8)
Cl1—O4	1.404 (6)	C18—C22	1.366 (8)
Cl1—O1	1.430 (4)	C18—C19	1.384 (8)
Cl2—O8	1.393 (5)	C19—C20	1.361 (8)
Cl2—O7	1.394 (5)	C21—C22	1.355 (8)
Cl2—O6	1.415 (5)	O1W—H1W1	0.90
Cl2—O5	1.418 (4)	O1W—H1W2	0.90
N1—C2	1.329 (7)	C2—H2	0.9300
N1—C1	1.345 (7)	C3—H3	0.9300
N2—C11	1.322 (7)	C4—H4	0.9300
N2—C12	1.355 (7)	C6—H6	0.9300
N3—C13	1.331 (7)	C7—H7	0.9300
N3—C17	1.339 (7)	C9—H9	0.9300
N4—C20	1.339 (8)	C10—H10	0.9301
N4—C21	1.351 (8)	C11—H11	0.9299
C1—C5	1.402 (8)	C13—H13	0.9301
C1—C12	1.415 (8)	C14—H14	0.9299
C2—C3	1.385 (9)	C16—H16	0.9301
C3—C4	1.36 (1)	C17—H17	0.9300
C4—C5	1.41 (1)	C19—H19	0.9299
C5—C6	1.43 (1)	C20—H20	0.9300
C6—C7	1.33 (1)	C21—H21	0.9300
C7—C8	1.43 (1)	C22—H22	0.9300
C8—C12	1.395 (8)
N1—Cu1—N2	82.0 (2)	C9—C8—C7	125.4 (6)
N1—Cu1—N3	169.7 (2)	C10—C9—C8	120.7 (6)
N1—Cu1—N4^i	96.2 (2)	C9—C10—C11	119.0 (6)
N1—Cu1—O1	96.5 (2)	N2—C11—C10	123.0 (6)
N1—Cu1—O5	78.6 (2)	N2—C12—C8	122.8 (5)
N2—Cu1—N3	93.5 (2)	N2—C12—C1	117.2 (5)
N2—Cu1—N4^i	177.0 (2)	C8—C12—C1	120.0 (5)
N2—Cu1—O1	88.9 (2)	N3—C13—C14	122.2 (5)
N2—Cu1—O5	89.8 (2)	C13—C14—C15	120.8 (5)
N3—Cu1—N4^i	87.9 (2)	C14—C15—C16	116.5 (5)
N3—Cu1—O1	92.7 (2)	C14—C15—C18	122.7 (5)
N3—Cu1—O5	92.2 (2)	C16—C15—C18	120.8 (5)
N4^i—Cu1—O1	93.7 (2)	C17—C16—C15	119.9 (5)
N4^i—Cu1—O5	87.5 (2)	C22—C18—C19	117.2 (5)
O1—Cu1—O5	175.1 (2)	C22—C18—C15	123.3 (5)
O3—Cl1—O2	113.6 (6)	C19—C18—C15	119.4 (5)
O3—Cl1—O4	106.5 (7)	C20—C19—C18	119.8 (6)
O2—Cl1—O4	108.7 (6)	N3—C17—C16	122.6 (5)
O3—Cl1—O1	110.5 (4)	N4—C20—C19	122.6 (6)
O2—Cl1—O1	110.4 (4)	N4—C21—C22	122.0 (6)
O4—Cl1—O1	106.7 (4)	C21—C22—C18	120.9 (6)
O8—Cl2—O7	112.2 (5)	H1W1—O1W—H1W2	99
O8—Cl2—O6	109.8 (5)	N1—C2—H2	118.9
O7—Cl2—O6	108.5 (4)	C3—C2—H2	118.8
O8—Cl2—O5	108.9 (4)	C4—C3—H3	120.0
O7—Cl2—O5	109.8 (4)	C2—C3—H3	120.1
O6—Cl2—O5	107.6 (3)	C3—C4—H4	120.3
Cl1—O1—Cu1	129.7 (3)	C5—C4—H4	120.0
Cl2—O5—Cu1	139.7 (3)	C7—C6—H6	119.9
C2—N1—C1	118.4 (5)	C5—C6—H6	119.8
C2—N1—Cu1	128.9 (4)	C6—C7—H7	118.9
C1—N1—Cu1	112.6 (4)	C8—C7—H7	118.9
C11—N2—C12	118.3 (5)	C10—C9—H9	119.6
C11—N2—Cu1	130.7 (4)	C8—C9—H9	119.7
C12—N2—Cu1	111.0 (4)	C9—C10—H10	120.6
C13—N3—C17	117.8 (5)	C11—C10—H10	120.4
C13—N3—Cu1	120.1 (4)	N2—C11—H11	118.5
C17—N3—Cu1	122.1 (4)	C10—C11—H11	118.5
C20—N4—C21	117.4 (5)	N3—C13—H13	118.9
C20—N4—Cu1^ii	118.7 (4)	C14—C13—H13	118.8
C21—N4—Cu1^ii	122.5 (4)	C13—C14—H14	119.7
N1—C1—C5	123.2 (6)	C15—C14—H14	119.5
N1—C1—C12	116.9 (5)	C17—C16—H16	120.0
C5—C1—C12	119.9 (5)	C15—C16—H16	120.0
N1—C2—C3	122.2 (6)	N3—C17—H17	118.7
C4—C3—C2	119.9 (7)	C16—C17—H17	118.7
C3—C4—C5	119.7 (6)	C20—C19—H19	120.1
C1—C5—C4	116.5 (6)	C18—C19—H19	120.1
C1—C5—C6	119.2 (6)	N4—C20—H20	118.7
C4—C5—C6	124.3 (6)	C19—C20—H20	118.6
C7—C6—C5	120.3 (7)	N4—C21—H21	119.1
C6—C7—C8	122.2 (7)	C22—C21—H21	118.9
C12—C8—C9	116.2 (6)	C21—C22—H22	119.6
C12—C8—C7	118.4 (6)	C18—C22—H22	119.5
O3—Cl1—O1—Cu1	−38.3 (7)	N1—C1—C5—C4	0.6 (9)
O2—Cl1—O1—Cu1	−164.9 (5)	C12—C1—C5—C4	−179.1 (6)
O4—Cl1—O1—Cu1	77.1 (6)	N1—C1—C5—C6	−180.0 (6)
N1—Cu1—O1—Cl1	−11.1 (4)	C12—C1—C5—C6	0.3 (9)
N3—Cu1—O1—Cl1	164.1 (4)	C3—C4—C5—C1	0 (1)
N4^i—Cu1—O1—Cl1	−107.8 (4)	C3—C4—C5—C6	−179.3 (7)
N2—Cu1—O1—Cl1	70.7 (4)	C1—C5—C6—C7	−1 (1)
O5—Cu1—O1—Cl1	−4 (2)	C4—C5—C6—C7	178.9 (7)
O8—Cl2—O5—Cu1	−41.6 (7)	C5—C6—C7—C8	−1 (1)
O7—Cl2—O5—Cu1	−164.8 (5)	C6—C7—C8—C12	2 (1)
O6—Cl2—O5—Cu1	77.3 (6)	C6—C7—C8—C9	−178.0 (7)
N1—Cu1—O5—Cl2	82.0 (5)	C12—C8—C9—C10	−1 (1)
N3—Cu1—O5—Cl2	−93.3 (5)	C7—C8—C9—C10	179.0 (6)
N4^i—Cu1—O5—Cl2	178.9 (5)	C8—C9—C10—C11	1 (1)
N2—Cu1—O5—Cl2	0.1 (5)	C12—N2—C11—C10	−1.3 (9)
O1—Cu1—O5—Cl2	75 (2)	Cu1—N2—C11—C10	177.5 (5)
N3—Cu1—N1—C2	116.6 (11)	C9—C10—C11—N2	−1 (1)
N4^i—Cu1—N1—C2	3.6 (5)	C11—N2—C12—C8	1.9 (8)
N2—Cu1—N1—C2	−178.8 (5)	Cu1—N2—C12—C8	−177.2 (4)
O1—Cu1—N1—C2	−90.9 (5)	C11—N2—C12—C1	−176.9 (5)
O5—Cu1—N1—C2	89.7 (5)	Cu1—N2—C12—C1	4.0 (6)
N3—Cu1—N1—C1	−59.7 (12)	C9—C8—C12—N2	−0.9 (8)
N4^i—Cu1—N1—C1	−172.8 (4)	C7—C8—C12—N2	179.3 (5)
N2—Cu1—N1—C1	4.8 (4)	C9—C8—C12—C1	177.9 (5)
O1—Cu1—N1—C1	92.8 (4)	C7—C8—C12—C1	−1.9 (9)
O5—Cu1—N1—C1	−86.6 (4)	N1—C1—C12—N2	0.0 (8)
N1—Cu1—N2—C11	176.3 (6)	C5—C1—C12—N2	179.7 (5)
N3—Cu1—N2—C11	−13.0 (6)	N1—C1—C12—C8	−178.8 (5)
N4^i—Cu1—N2—C11	−130 (4)	C5—C1—C12—C8	0.9 (8)
O1—Cu1—N2—C11	79.6 (5)	C17—N3—C13—C14	1.7 (9)
O5—Cu1—N2—C11	−105.2 (6)	Cu1—N3—C13—C14	−175.2 (5)
N1—Cu1—N2—C12	−4.8 (4)	N3—C13—C14—C15	2 (1)
N3—Cu1—N2—C12	165.9 (4)	C13—C14—C15—C16	−3.8 (9)
N4^i—Cu1—N2—C12	49 (4)	C13—C14—C15—C18	172.8 (6)
O1—Cu1—N2—C12	−101.5 (4)	C14—C15—C16—C17	2.4 (9)
O5—Cu1—N2—C12	73.7 (4)	C18—C15—C16—C17	−174.3 (6)
N1—Cu1—N3—C13	−179.0 (9)	C13—N3—C17—C16	−3.2 (9)
N4^i—Cu1—N3—C13	−65.3 (5)	Cu1—N3—C17—C16	173.6 (5)
N2—Cu1—N3—C13	117.4 (5)	C15—C16—C17—N3	1 (1)
O1—Cu1—N3—C13	28.3 (5)	C14—C15—C18—C22	143.4 (7)
O5—Cu1—N3—C13	−152.7 (5)	C16—C15—C18—C22	−40.1 (9)
N1—Cu1—N3—C17	4 (1)	C14—C15—C18—C19	−40.3 (8)
N4^i—Cu1—N3—C17	117.9 (5)	C16—C15—C18—C19	136.2 (6)
N2—Cu1—N3—C17	−59.4 (5)	C22—C18—C19—C20	2.6 (9)
O1—Cu1—N3—C17	−148.5 (5)	C15—C18—C19—C20	−174.0 (5)
O5—Cu1—N3—C17	30.5 (5)	C21—N4—C20—C19	−0.5 (9)
C2—N1—C1—C5	−0.6 (8)	Cu1^ii—N4—C20—C19	166.6 (5)
Cu1—N1—C1—C5	176.2 (5)	C18—C19—C20—N4	−1.3 (9)
C2—N1—C1—C12	179.1 (5)	C20—N4—C21—C22	0.9 (9)
Cu1—N1—C1—C12	−4.1 (6)	Cu1^ii—N4—C21—C22	−165.6 (5)
C1—N1—C2—C3	−0.1 (9)	N4—C21—C22—C18	1 (1)
Cu1—N1—C2—C3	−176.3 (5)	C19—C18—C22—C21	−2 (1)
N1—C2—C3—C4	1 (1)	C15—C18—C22—C21	174.2 (6)
C2—C3—C4—C5	−1 (1)

Symmetry codes: (i) −x+3/2, y−1/2, −z+1/2; (ii) −x+3/2, y+1/2, −z+1/2.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1W1···O4	0.90	2.13	3.00 (2)	159
O1W—H1W2···O8^iii	0.90	2.22	2.64 (2)	108

Symmetry code: (iii) x−1/2, −y+1/2, z+1/2.