Tris(1,10-phenanthroline-N,N')chromium(III) triperchlorate hydrate

The structure of the cation in [Cr(C₁₂H₈N₂)₃](ClO₄)₃·H₂O consists of the Cr atom bonded to the N atoms of the three 1,10-phenanthroline (phen) ligands, resulting in a distorted octahedral arrangement with the six Cr-N distances ranging from 2.040 (4) to 2.055 (4) Å. One of the perchlorate anions is disordered and is located around two special positions.

Computing details

Data collection: KappaCCD Software (Nonius, 1999); cell refinement: DENZO and SCALEPAK (Otwinowski & Minor, 1997); data reduction: DENZO and SCALEPAK; program(s) used to solve structure: SIR97 (Altomare et al., 1998); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); software used to prepare material for publication: WinGX (Farrugia, 1998).

(I)

Crystal data

[Cr(C12H8N2)3](ClO4)3·H2O	F(000) = 3704
Mr = 908.98	Dx = 1.629 Mg m^−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
a = 17.6320 (4) Å	Cell parameters from 47108 reflections
b = 18.2840 (4) Å	θ = 1.0–30.0°
c = 22.9980 (4) Å	µ = 0.60 mm^−1
β = 91.2700 (14)°	T = 100 K
V = 7412.4 (3) Å^3	Fragment, red–yellow
Z = 8	0.20 × 0.17 × 0.10 mm

Data collection

KappaCCD diffractometer	10833 independent reflections
Radiation source: fine-focus sealed tube	4967 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.049
φ and ω scans with κ offsets	θmax = 30.1°, θmin = 1.6°
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	h = −24→24
Tmin = 0.79, Tmax = 0.94	k = −25→25
47108 measured reflections	l = −32→32

Refinement

Refinement on F^2	40 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.075	w = 1/[σ^2(Fo^2) + (0.1132*P)^2], where P = (max(Fo^2,0) + 2*Fc^2)/3
wR(F^2) = 0.241	(Δ/σ)max = 0.001
S = 1.03	Δρmax = 1.14 e Å^−3
10833 reflections	Δρmin = −0.58 e Å^−3
586 parameters

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Cr1	0.72094 (4)	0.02683 (4)	0.37656 (3)	0.0319 (2)
Cl1	0.45649 (7)	0.13697 (7)	0.46656 (5)	0.0437 (3)
O11	0.4854 (2)	0.0804 (2)	0.42957 (16)	0.0548 (10)
O12	0.4731 (2)	0.2052 (2)	0.4394 (2)	0.0821 (15)
O13	0.37564 (18)	0.12992 (19)	0.47144 (15)	0.0473 (9)
O14	0.4923 (3)	0.1334 (4)	0.52229 (18)	0.117 (2)
Cl2	0.68383 (7)	0.21587 (9)	0.73064 (5)	0.0518 (4)
O21	0.73669 (19)	0.2070 (2)	0.77732 (14)	0.0485 (9)
O22	0.7216 (2)	0.2423 (2)	0.67984 (14)	0.0539 (10)
O23	0.6226 (3)	0.2614 (3)	0.74633 (18)	0.114 (2)
O24	0.6506 (2)	0.1442 (3)	0.71789 (18)	0.0873 (16)
Cl3	0.94375 (16)	0.01916 (18)	0.07176 (12)	0.0576 (8)	0.486 (2)
O31	0.9015 (4)	0.0778 (4)	0.0919 (3)	0.0521 (19)	0.486 (2)
O32	0.8897 (5)	−0.0247 (5)	0.0480 (3)	0.078 (3)	0.486 (2)
O33	0.9956 (6)	0.0391 (6)	0.0297 (4)	0.102 (4)	0.486 (2)
O34	0.9809 (8)	−0.0114 (7)	0.1190 (5)	0.130 (5)	0.486 (2)
Cl4	1.00489 (17)	−0.09442 (19)	0.16678 (13)	0.0676 (9)	0.514 (2)
O41	1.0516 (4)	−0.1485 (4)	0.1726 (3)	0.0483 (17)*	0.514 (2)
O42	0.9398 (4)	−0.1160 (4)	0.1338 (3)	0.071 (2)	0.514 (2)
O43	1.0366 (6)	−0.0317 (5)	0.1411 (7)	0.128 (5)	0.514 (2)
O44	0.9820 (7)	−0.0740 (9)	0.2218 (4)	0.168 (7)	0.514 (2)
O50	0.5873 (6)	0.3942 (6)	0.7921 (5)	0.075 (3)	0.53
O501	0.5519 (7)	0.4069 (9)	0.7690 (5)	0.100 (5)	0.47
N1	0.69576 (19)	0.0595 (2)	0.45918 (15)	0.0325 (8)
N2	0.8119 (2)	0.0935 (2)	0.39209 (14)	0.0309 (8)
C1	0.8698 (2)	0.1095 (3)	0.35823 (19)	0.0363 (10)
H1	0.8723	0.0867	0.3212	0.054*
C2	0.9268 (3)	0.1584 (3)	0.3748 (2)	0.0443 (12)
H2	0.967	0.1684	0.3492	0.067*
C3	0.9251 (3)	0.1921 (3)	0.4283 (2)	0.0402 (11)
H3	0.9641	0.2254	0.4399	0.06*
C4	0.8646 (2)	0.1767 (3)	0.46594 (18)	0.0338 (10)
C5	0.8575 (3)	0.2061 (3)	0.5229 (2)	0.0406 (11)
H5	0.8946	0.2397	0.537	0.061*
C6	0.7999 (3)	0.1878 (3)	0.5574 (2)	0.0413 (11)
H6	0.7973	0.2086	0.5952	0.062*
C7	0.7422 (3)	0.1373 (3)	0.53808 (19)	0.0362 (10)
C8	0.6833 (3)	0.1125 (3)	0.57227 (19)	0.0384 (11)
H8	0.6776	0.1308	0.6106	0.058*
C9	0.6334 (3)	0.0612 (3)	0.55017 (19)	0.0398 (11)
H9	0.5943	0.0424	0.5737	0.06*
C10	0.6404 (3)	0.0370 (3)	0.49325 (19)	0.0367 (10)
H10	0.6043	0.0031	0.4781	0.055*
C11	0.7475 (2)	0.1078 (2)	0.48176 (17)	0.0308 (9)
C12	0.8096 (2)	0.1276 (3)	0.44603 (17)	0.0332 (10)
N3	0.6650 (2)	0.1100 (2)	0.33495 (15)	0.0338 (8)
N4	0.7536 (2)	0.0046 (2)	0.29317 (16)	0.0392 (9)
C13	0.6209 (3)	0.1617 (3)	0.3571 (2)	0.0414 (11)
H13	0.6125	0.1621	0.3977	0.062*
C14	0.5864 (3)	0.2160 (3)	0.3216 (2)	0.0524 (13)
H14	0.5554	0.2525	0.3384	0.079*
C15	0.5980 (3)	0.2154 (3)	0.2632 (2)	0.0549 (15)
H15	0.5754	0.2523	0.2394	0.082*
C16	0.6426 (3)	0.1613 (3)	0.2377 (2)	0.0478 (13)
C17	0.6566 (3)	0.1531 (4)	0.1765 (2)	0.0584 (16)
H17	0.6345	0.1869	0.1498	0.088*
C18	0.7007 (4)	0.0979 (4)	0.1561 (2)	0.0613 (17)
H18	0.7081	0.0937	0.1154	0.092*
C19	0.7357 (3)	0.0469 (3)	0.1944 (2)	0.0523 (15)
C20	0.7831 (3)	−0.0103 (4)	0.1769 (2)	0.0623 (18)
H20	0.7936	−0.016	0.1368	0.094*
C21	0.8143 (4)	−0.0578 (4)	0.2162 (3)	0.0631 (17)
H21	0.8468	−0.096	0.204	0.095*
C22	0.7980 (3)	−0.0497 (3)	0.2738 (2)	0.0495 (13)
H22	0.8189	−0.0835	0.3011	0.074*
C23	0.7224 (3)	0.0523 (3)	0.25373 (19)	0.0415 (12)
C24	0.6761 (3)	0.1085 (3)	0.2753 (2)	0.0434 (12)
N5	0.6305 (2)	−0.0423 (2)	0.36434 (15)	0.0314 (8)
N6	0.7685 (2)	−0.0666 (2)	0.40930 (16)	0.0371 (9)
C25	0.5617 (2)	−0.0295 (3)	0.34095 (17)	0.0342 (10)
H25	0.5482	0.0196	0.332	0.051*
C26	0.5090 (3)	−0.0842 (3)	0.32908 (19)	0.0381 (11)
H26	0.4609	−0.0726	0.3121	0.057*
C27	0.5275 (3)	−0.1547 (3)	0.34218 (19)	0.0437 (12)
H27	0.4922	−0.1927	0.3336	0.065*
C28	0.5980 (3)	−0.1721 (3)	0.36824 (19)	0.0384 (11)
C29	0.6222 (3)	−0.2429 (3)	0.3854 (2)	0.0475 (13)
H29	0.5893	−0.2834	0.3787	0.071*
C30	0.6900 (3)	−0.2540 (3)	0.4107 (2)	0.0483 (13)
H30	0.7033	−0.3021	0.4228	0.072*
C31	0.7432 (3)	−0.1964 (3)	0.4203 (2)	0.0433 (12)
C32	0.8150 (3)	−0.2049 (3)	0.4456 (2)	0.0510 (13)
H32	0.8319	−0.2519	0.4577	0.077*
C33	0.8614 (3)	−0.1451 (3)	0.4528 (2)	0.0561 (15)
H33	0.9101	−0.1507	0.4707	0.084*
C34	0.8371 (3)	−0.0758 (3)	0.4339 (2)	0.0475 (12)
H34	0.8699	−0.0349	0.4386	0.071*
C35	0.7219 (3)	−0.1254 (3)	0.40331 (19)	0.0364 (11)
C36	0.6487 (3)	−0.1130 (3)	0.37809 (18)	0.0365 (11)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cr1	0.0309 (4)	0.0389 (4)	0.0259 (3)	−0.0015 (3)	0.0005 (3)	−0.0012 (3)
Cl1	0.0402 (6)	0.0529 (8)	0.0379 (6)	0.0115 (6)	−0.0024 (5)	−0.0098 (5)
O11	0.052 (2)	0.056 (2)	0.057 (2)	0.0093 (18)	0.0141 (18)	−0.0136 (19)
O12	0.051 (2)	0.045 (2)	0.151 (5)	−0.0030 (19)	0.024 (3)	−0.003 (3)
O13	0.0392 (19)	0.046 (2)	0.058 (2)	0.0030 (16)	0.0100 (16)	−0.0026 (17)
O14	0.086 (3)	0.219 (7)	0.045 (2)	0.094 (4)	−0.021 (2)	−0.035 (3)
Cl2	0.0452 (7)	0.0801 (10)	0.0301 (6)	0.0153 (7)	0.0036 (5)	−0.0037 (6)
O21	0.052 (2)	0.052 (2)	0.0404 (18)	−0.0090 (17)	−0.0039 (16)	0.0010 (16)
O22	0.059 (2)	0.067 (3)	0.0364 (18)	0.0066 (19)	0.0073 (16)	0.0023 (17)
O23	0.125 (4)	0.165 (5)	0.051 (3)	0.100 (4)	0.034 (3)	0.036 (3)
O24	0.062 (3)	0.140 (5)	0.060 (3)	−0.053 (3)	0.004 (2)	−0.022 (3)
Cl3	0.0560 (16)	0.075 (2)	0.0421 (14)	−0.0114 (15)	0.0002 (12)	0.0105 (14)
O31	0.047 (4)	0.042 (4)	0.068 (5)	0.006 (3)	0.009 (4)	0.024 (4)
O32	0.126 (8)	0.061 (6)	0.048 (5)	−0.053 (6)	0.015 (5)	−0.006 (4)
O33	0.104 (8)	0.124 (9)	0.078 (7)	−0.045 (7)	0.017 (6)	−0.004 (6)
O34	0.122 (11)	0.139 (12)	0.126 (10)	0.004 (10)	−0.031 (9)	0.064 (9)
Cl4	0.0550 (17)	0.083 (2)	0.0648 (18)	−0.0136 (16)	0.0089 (14)	−0.0168 (16)
O42	0.071 (5)	0.072 (6)	0.069 (5)	−0.001 (4)	−0.005 (4)	−0.021 (4)
O43	0.077 (7)	0.046 (6)	0.261 (17)	−0.019 (5)	0.033 (9)	0.002 (8)
O44	0.116 (10)	0.32 (2)	0.061 (6)	−0.030 (13)	−0.014 (6)	−0.032 (10)
O50	0.062 (6)	0.075 (6)	0.085 (7)	−0.015 (5)	−0.013 (5)	−0.002 (6)
O501	0.072 (8)	0.171 (14)	0.056 (7)	−0.027 (9)	−0.002 (5)	−0.026 (8)
N1	0.0290 (18)	0.041 (2)	0.0273 (17)	0.0021 (16)	−0.0005 (15)	0.0027 (16)
N2	0.0321 (19)	0.034 (2)	0.0265 (17)	−0.0010 (16)	0.0014 (14)	−0.0017 (15)
C1	0.034 (2)	0.043 (3)	0.032 (2)	−0.001 (2)	0.0031 (18)	−0.002 (2)
C2	0.035 (3)	0.060 (3)	0.039 (3)	−0.002 (2)	0.004 (2)	−0.008 (2)
C3	0.030 (2)	0.049 (3)	0.042 (3)	−0.003 (2)	−0.0024 (19)	−0.006 (2)
C4	0.034 (2)	0.037 (3)	0.031 (2)	−0.0020 (19)	−0.0005 (18)	−0.0020 (19)
C5	0.042 (3)	0.041 (3)	0.039 (2)	−0.002 (2)	−0.003 (2)	−0.008 (2)
C6	0.047 (3)	0.042 (3)	0.035 (2)	0.005 (2)	−0.004 (2)	−0.011 (2)
C7	0.037 (2)	0.039 (3)	0.033 (2)	0.007 (2)	−0.0002 (19)	−0.002 (2)
C8	0.037 (2)	0.049 (3)	0.029 (2)	0.006 (2)	0.0016 (19)	−0.002 (2)
C9	0.036 (2)	0.055 (3)	0.029 (2)	0.005 (2)	0.0022 (19)	0.004 (2)
C10	0.035 (2)	0.043 (3)	0.033 (2)	0.000 (2)	0.0014 (18)	0.002 (2)
C11	0.032 (2)	0.032 (2)	0.029 (2)	0.0042 (19)	−0.0030 (17)	0.0004 (18)
C12	0.034 (2)	0.041 (3)	0.025 (2)	0.005 (2)	0.0002 (17)	−0.0009 (19)
N3	0.0333 (19)	0.040 (2)	0.0279 (18)	−0.0038 (17)	−0.0015 (15)	0.0023 (16)
N4	0.036 (2)	0.048 (2)	0.034 (2)	−0.0102 (18)	0.0048 (16)	−0.0059 (18)
C13	0.037 (3)	0.048 (3)	0.038 (2)	−0.003 (2)	0.001 (2)	0.001 (2)
C14	0.043 (3)	0.049 (3)	0.064 (4)	−0.003 (2)	−0.010 (3)	0.009 (3)
C15	0.045 (3)	0.065 (4)	0.054 (3)	−0.012 (3)	−0.018 (2)	0.031 (3)
C16	0.040 (3)	0.064 (4)	0.039 (3)	−0.014 (3)	−0.008 (2)	0.016 (3)
C17	0.064 (4)	0.068 (4)	0.042 (3)	−0.030 (3)	−0.017 (3)	0.019 (3)
C18	0.070 (4)	0.078 (5)	0.036 (3)	−0.036 (4)	0.001 (3)	0.007 (3)
C19	0.052 (3)	0.075 (4)	0.030 (2)	−0.032 (3)	0.003 (2)	−0.006 (3)
C20	0.072 (4)	0.076 (4)	0.040 (3)	−0.037 (3)	0.023 (3)	−0.022 (3)
C21	0.071 (4)	0.070 (4)	0.050 (3)	−0.023 (3)	0.023 (3)	−0.025 (3)
C22	0.047 (3)	0.052 (3)	0.049 (3)	−0.015 (2)	0.012 (2)	−0.016 (2)
C23	0.041 (3)	0.052 (3)	0.031 (2)	−0.018 (2)	0.000 (2)	−0.003 (2)
C24	0.041 (3)	0.057 (3)	0.032 (2)	−0.020 (2)	−0.004 (2)	0.004 (2)
N5	0.035 (2)	0.035 (2)	0.0249 (17)	−0.0040 (16)	0.0050 (15)	−0.0040 (15)
N6	0.0305 (19)	0.045 (2)	0.036 (2)	0.0073 (17)	−0.0005 (16)	−0.0030 (18)
C25	0.034 (2)	0.043 (3)	0.026 (2)	0.001 (2)	0.0018 (17)	0.000 (2)
C26	0.036 (2)	0.044 (3)	0.034 (2)	−0.005 (2)	0.0042 (19)	−0.005 (2)
C27	0.043 (3)	0.054 (3)	0.034 (2)	−0.015 (2)	0.011 (2)	−0.012 (2)
C28	0.046 (3)	0.036 (3)	0.033 (2)	−0.003 (2)	0.013 (2)	−0.004 (2)
C29	0.058 (3)	0.041 (3)	0.045 (3)	−0.004 (2)	0.014 (3)	−0.005 (2)
C30	0.070 (4)	0.033 (3)	0.043 (3)	0.008 (3)	0.020 (3)	−0.003 (2)
C31	0.049 (3)	0.045 (3)	0.036 (2)	0.010 (2)	0.011 (2)	−0.007 (2)
C32	0.060 (3)	0.049 (3)	0.045 (3)	0.017 (3)	0.006 (3)	−0.003 (3)
C33	0.050 (3)	0.068 (4)	0.050 (3)	0.023 (3)	−0.005 (2)	−0.003 (3)
C34	0.046 (3)	0.050 (3)	0.046 (3)	0.008 (2)	−0.007 (2)	−0.004 (2)
C35	0.045 (3)	0.036 (3)	0.028 (2)	0.006 (2)	0.0075 (19)	−0.0056 (19)
C36	0.039 (2)	0.044 (3)	0.026 (2)	0.004 (2)	0.0095 (19)	−0.008 (2)

Geometric parameters (Å, º)

Cr1—N2	2.040 (4)	C7—C8	1.393 (6)
Cr1—N6	2.040 (4)	C7—C11	1.407 (6)
Cr1—N3	2.040 (4)	C8—C9	1.375 (7)
Cr1—N5	2.049 (4)	C9—C10	1.390 (6)
Cr1—N1	2.050 (3)	C11—C12	1.429 (6)
Cr1—N4	2.055 (4)	N3—C13	1.331 (6)
Cl1—O14	1.418 (4)	N3—C24	1.391 (6)
Cl1—O12	1.429 (4)	N4—C22	1.346 (6)
Cl1—O13	1.438 (3)	N4—C23	1.365 (6)
Cl1—O11	1.440 (3)	C13—C14	1.413 (7)
Cl2—O21	1.415 (3)	C14—C15	1.363 (8)
Cl2—O23	1.416 (4)	C15—C16	1.401 (8)
Cl2—O22	1.441 (3)	C16—C24	1.415 (7)
Cl2—O24	1.463 (5)	C16—C17	1.443 (7)
Cl3—O32	1.352 (8)	C17—C18	1.364 (9)
Cl3—O34	1.376 (10)	C18—C19	1.415 (8)
Cl3—O31	1.391 (7)	C19—C23	1.393 (6)
Cl3—O33	1.394 (9)	C19—C20	1.404 (9)
O34—O43	1.156 (14)	C20—C21	1.362 (9)
O34—Cl4	1.915 (11)	C21—C22	1.369 (7)
Cl4—O41	1.292 (7)	C23—C24	1.409 (7)
Cl4—O44	1.388 (10)	N5—C25	1.337 (5)
Cl4—O43	1.411 (9)	N5—C36	1.368 (6)
Cl4—O42	1.418 (8)	N6—C34	1.335 (6)
O44—O44^i	1.432 (19)	N6—C35	1.359 (6)
O50—O501	0.843 (13)	C25—C26	1.388 (6)
N1—C10	1.330 (5)	C26—C27	1.363 (7)
N1—C11	1.365 (6)	C27—C28	1.405 (7)
N2—C1	1.330 (5)	C28—C36	1.416 (7)
N2—C12	1.390 (5)	C28—C29	1.417 (7)
C1—C2	1.392 (7)	C29—C30	1.334 (8)
C2—C3	1.378 (6)	C30—C31	1.424 (7)
C3—C4	1.416 (6)	C31—C32	1.390 (7)
C4—C12	1.392 (6)	C31—C35	1.404 (7)
C4—C5	1.425 (6)	C32—C33	1.373 (8)
C5—C6	1.344 (6)	C33—C34	1.404 (8)
C6—C7	1.438 (7)	C35—C36	1.421 (7)
N2—Cr1—N6	96.94 (15)	C8—C7—C6	124.5 (4)
N2—Cr1—N3	90.38 (15)	C11—C7—C6	118.0 (4)
N6—Cr1—N3	171.23 (15)	C9—C8—C7	119.5 (4)
N2—Cr1—N5	177.53 (14)	C8—C9—C10	119.7 (4)
N6—Cr1—N5	81.15 (15)	N1—C10—C9	122.6 (4)
N3—Cr1—N5	91.65 (15)	N1—C11—C7	122.7 (4)
N2—Cr1—N1	81.31 (14)	N1—C11—C12	117.3 (4)
N6—Cr1—N1	89.88 (14)	C7—C11—C12	120.0 (4)
N3—Cr1—N1	96.01 (14)	N2—C12—C4	123.3 (4)
N5—Cr1—N1	97.07 (14)	N2—C12—C11	115.9 (4)
N2—Cr1—N4	92.65 (14)	C4—C12—C11	120.8 (4)
N6—Cr1—N4	93.31 (16)	C13—N3—C24	119.2 (4)
N3—Cr1—N4	81.49 (16)	C13—N3—Cr1	129.1 (3)
N5—Cr1—N4	89.04 (14)	C24—N3—Cr1	111.7 (3)
N1—Cr1—N4	173.48 (15)	C22—N4—C23	118.7 (4)
O14—Cl1—O12	110.1 (4)	C22—N4—Cr1	129.1 (4)
O14—Cl1—O13	110.4 (3)	C23—N4—Cr1	112.1 (3)
O12—Cl1—O13	109.0 (2)	N3—C13—C14	121.7 (5)
O14—Cl1—O11	110.1 (3)	C15—C14—C13	119.4 (5)
O12—Cl1—O11	106.9 (2)	C14—C15—C16	121.0 (5)
O13—Cl1—O11	110.3 (2)	C15—C16—C24	117.2 (5)
O21—Cl2—O23	111.5 (3)	C15—C16—C17	126.2 (5)
O21—Cl2—O22	110.2 (2)	C24—C16—C17	116.5 (5)
O23—Cl2—O22	112.2 (3)	C18—C17—C16	121.6 (5)
O21—Cl2—O24	107.7 (3)	C17—C18—C19	121.1 (5)
O23—Cl2—O24	105.9 (3)	C23—C19—C20	116.6 (5)
O22—Cl2—O24	109.2 (2)	C23—C19—C18	118.9 (6)
O32—Cl3—O34	113.4 (7)	C20—C19—C18	124.5 (5)
O32—Cl3—O31	102.4 (5)	C21—C20—C19	121.3 (5)
O34—Cl3—O31	107.5 (7)	C20—C21—C22	118.9 (6)
O32—Cl3—O33	110.0 (5)	N4—C22—C21	122.4 (6)
O34—Cl3—O33	110.3 (7)	N4—C23—C19	122.1 (5)
O31—Cl3—O33	113.2 (6)	N4—C23—C24	117.4 (4)
O43—O34—Cl3	149.6 (14)	C19—C23—C24	120.5 (5)
O43—O34—Cl4	47.1 (6)	N3—C24—C23	117.2 (4)
Cl3—O34—Cl4	150.5 (10)	N3—C24—C16	121.5 (5)
O41—Cl4—O44	108.1 (7)	C23—C24—C16	121.3 (4)
O41—Cl4—O43	114.0 (5)	C25—N5—C36	117.7 (4)
O44—Cl4—O43	106.8 (8)	C25—N5—Cr1	130.1 (3)
O41—Cl4—O42	110.4 (5)	C36—N5—Cr1	111.9 (3)
O44—Cl4—O42	108.3 (6)	C34—N6—C35	119.0 (4)
O43—Cl4—O42	109.0 (7)	C34—N6—Cr1	128.5 (4)
O41—Cl4—O34	142.9 (6)	C35—N6—Cr1	112.5 (3)
O44—Cl4—O34	104.1 (8)	N5—C25—C26	123.4 (4)
O43—Cl4—O34	36.9 (6)	C27—C26—C25	118.9 (5)
O42—Cl4—O34	75.4 (6)	C26—C27—C28	120.9 (5)
O34—O43—Cl4	96.0 (9)	C27—C28—C36	116.4 (4)
Cl4—O44—O44^i	133.9 (13)	C27—C28—C29	125.7 (5)
C10—N1—C11	118.0 (4)	C36—C28—C29	117.9 (5)
C10—N1—Cr1	129.2 (3)	C30—C29—C28	121.4 (5)
C11—N1—Cr1	112.6 (3)	C29—C30—C31	122.4 (5)
C1—N2—C12	117.5 (4)	C32—C31—C35	117.1 (5)
C1—N2—Cr1	129.8 (3)	C32—C31—C30	124.9 (5)
C12—N2—Cr1	112.7 (3)	C35—C31—C30	118.0 (5)
N2—C1—C2	122.7 (4)	C33—C32—C31	119.8 (5)
C3—C2—C1	120.2 (4)	C32—C33—C34	120.3 (5)
C2—C3—C4	119.2 (4)	N6—C34—C33	120.8 (5)
C12—C4—C3	117.2 (4)	N6—C35—C31	123.1 (4)
C12—C4—C5	118.0 (4)	N6—C35—C36	117.2 (4)
C3—C4—C5	124.8 (4)	C31—C35—C36	119.7 (5)
C6—C5—C4	122.2 (4)	N5—C36—C28	122.7 (4)
C5—C6—C7	121.0 (4)	N5—C36—C35	116.8 (4)
C8—C7—C11	117.4 (4)	C28—C36—C35	120.5 (4)

Symmetry code: (i) −x+2, y, −z+1/2.