Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

IUCr IT WDC

home archive editors for authors for readers submit open access

link to html

Bis[1,3-bis(diphenylphosphino)propane-κ²P,P′]silver(I) hemi[cyclopentyldiphenylbis(trifluoroacetato-κO)stannate(IV)] hemi[triphenylbis(trifluoroacetato-κO)stannate(IV)]

Y. Y. Teo, K. M. Lo and S. W. Ng

In the crystal structure of the title co-crystal, [Ag(C₂₇H₂₆P₂)₂][Sn(C₆H₅)₃(C₂F₃O₄)₂]_0.5[Sn(C₆H₅)₂(C₅H₉)(C₂F₃O₄)₂]_0.5, the Ag atom shows tetrahedral coordination, whereas the Sn atom shows trigonal–bipyramidal coordination. There are no significant interactions between the cations and anions.

Read article Similar articles

Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804023049/sj6007sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536804023049/sj6007Isup2.hkl Contains datablock I

CCDC reference: 252787

checkCIF report

Key indicators

Single-crystal X-ray study
T = 113 K
Mean (C-C) = 0.006 Å
R factor = 0.047
wR factor = 0.133
Data-to-parameter ratio = 14.0

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT220_ALERT_2_A Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       6.52 Ratio

Author Response: The structure is severely disordered.

PLAT222_ALERT_3_A Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       6.54 Ratio

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_A Check High   U(eq) as Compared to Neighbors  for         F2

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_A Check High   U(eq) as Compared to Neighbors  for        C15

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_A Check High   U(eq) as Compared to Neighbors  for        C16

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_A Check High   U(eq) as Compared to Neighbors  for        C17

Author Response: The structure is severely disordered.

PLAT242_ALERT_2_A Check Low    U(eq) as Compared to Neighbors  for       C15'
PLAT242_ALERT_2_A Check Low    U(eq) as Compared to Neighbors  for       C16'
PLAT242_ALERT_2_A Check Low    U(eq) as Compared to Neighbors  for       C17'

Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.94 Ratio

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors  for        C46

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors  for         F3

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors  for        F4'

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors  for        O2'

Author Response: The structure is severely disordered.

PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors  for        C44
PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors  for        C47
PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors  for       C14'
PLAT242_ALERT_2_B Check Low    U(eq) as Compared to Neighbors  for        C20
PLAT301_ALERT_3_B Main Residue  Disorder .........................      26.00 Perc.

Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.98
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.50 Ratio
PLAT165_ALERT_3_C Nr. of Status R Flagged Non-Hydrogen Atoms .....         78
PLAT220_ALERT_2_C Large Non-Solvent    F     Ueq(max)/Ueq(min) ...       2.52 Ratio

Author Response: The structure is severely disordered.

PLAT220_ALERT_2_C Large Non-Solvent    O     Ueq(max)/Ueq(min) ...       3.49 Ratio

Author Response: The structure is severely disordered.

PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.97 Ratio

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        C40

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        C45

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        C49

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        F3'

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        F5'

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for         F6

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        F6'

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for         O4

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for        C13

Author Response: The structure is severely disordered.

PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors  for       C19'

Author Response: The structure is severely disordered.

PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C18'
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C20'
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for        C22
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors  for       C22'
PLAT313_ALERT_2_C Oxygen with three covalent bonds (rare) ........         O4
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          4
            O3  -SN1 -O1  -C19   174.00  2.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          8
            O1  -SN1 -O3  -C21   178.00  2.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         59
            O3' -SN1'-O1' -C19'   42.00  9.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         63
            O1' -SN1'-O3' -C21'  152.00  9.00   1.555   1.555   1.555   1.555
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          8

Alert level G
FORMU01_ALERT_1_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and _chemical_formula_moiety. This is
            usually due to the moiety formula being in the wrong format.
            Atom count from _chemical_formula_sum:   C75.5 H69 Ag1 F6 O4 P4 Sn1
            Atom count from _chemical_formula_moiety:C48.5 H43 Ag1 F6 O4 P2 Sn1

   9 ALERT level A = In general: serious problem
  10 ALERT level B = Potentially serious problem
  28 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  34 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Bis[1,3-bis(diphenylphosphino)propane-κ²P,P']silver(I) hemi[cyclopentyldiphenylbis(trifluoroacetato-κO)stannate(IV)] hemi[triphenylbis(trifluoroacetato)stannate(IV)] top

Crystal data top

C₂₇H₂₆AgP₂⁺·0.5C₂₂H₁₅F₆O₄Sn⁻·0.5C₂₁H₁₉F₆O₄Sn⁻	Z = 2
M_r = 1504.75	F(000) = 1530
Triclinic, P1	D_x = 1.482 Mg m⁻³
Hall symbol: -P 1	Melting point: [Ag (C27 H26 P2)2] [Sn (C6 H5)3 (C2 F3 O4)2]0.5 [Sn (C6 H5)2 (C5 H9) (C2 F3 O4)2]0.5 K
a = 10.6019 (3) Å	Mo Kα radiation, λ = 0.71073 Å
b = 18.0331 (5) Å	Cell parameters from 14392 reflections
c = 18.3529 (5) Å	θ = 2.3–26.4°
α = 91.372 (1)°	µ = 0.82 mm⁻¹
β = 93.985 (1)°	T = 113 K
γ = 105.418 (1)°	Irregular block, colorless
V = 3371.06 (16) Å³	0.60 × 0.51 × 0.42 mm

Data collection top

Siemens P4/CCD area-detector diffractometer	13501 independent reflections
Radiation source: fine-focus sealed tube	10515 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.028
φ and ω scans	θ_max = 26.4°, θ_min = 2.0°
Absorption correction: multi-scan SADABS (Bruker, 2001)	h = −13→13
T_min = 0.616, T_max = 0.710	k = −22→22
26881 measured reflections	l = −22→22

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.047	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.133	H-atom parameters constrained
S = 1.02	w = 1/[σ²(F_o²) + (0.0642P)² + 6.1836P] where P = (F_o² + 2F_c²)/3
13501 reflections	(Δ/σ)_max = 0.001
961 parameters	Δρ_max = 1.04 e Å⁻³
768 restraints	Δρ_min = −0.95 e Å⁻³

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Sn1	1.03906 (6)	0.21566 (4)	0.25204 (4)	0.03687 (15)	0.50
F1	1.0684 (11)	0.3784 (8)	0.4812 (4)	0.110 (4)	0.50
F2	0.9120 (14)	0.4269 (11)	0.4465 (10)	0.161 (10)	0.50
F3	1.0882 (16)	0.4585 (6)	0.3988 (7)	0.116 (5)	0.50
F4	1.1170 (6)	0.0508 (4)	0.0626 (5)	0.110 (3)	0.50
F5	0.9740 (7)	−0.0493 (3)	0.0901 (4)	0.0637 (17)	0.50
F6	0.9151 (9)	0.0287 (5)	0.0197 (4)	0.089 (3)	0.50
O1	1.0518 (7)	0.3137 (5)	0.3331 (5)	0.057 (2)	0.50
O2	0.8416 (6)	0.3149 (6)	0.3538 (6)	0.095 (3)	0.50
O3	1.0524 (8)	0.1240 (4)	0.1711 (4)	0.052 (2)	0.50
O4	0.8526 (9)	0.0416 (6)	0.1641 (6)	0.082 (3)	0.50
C1	0.9745 (6)	0.1422 (4)	0.3395 (3)	0.049 (2)	0.50
C2	0.8530 (6)	0.0880 (5)	0.3350 (3)	0.066 (3)	0.50
H2	0.7958	0.0824	0.2919	0.080*	0.50
C3	0.8153 (6)	0.0420 (4)	0.3937 (4)	0.065 (4)	0.50
H3	0.7323	0.0050	0.3906	0.078*	0.50
C4	0.8991 (8)	0.0502 (4)	0.4568 (3)	0.062 (3)	0.50
H4	0.8733	0.0188	0.4969	0.074*	0.50
C5	1.0205 (7)	0.1044 (4)	0.4613 (3)	0.068 (3)	0.50
H5	1.0778	0.1100	0.5045	0.082*	0.50
C6	1.0582 (5)	0.1504 (4)	0.4027 (3)	0.050 (2)	0.50
H6	1.1412	0.1874	0.4057	0.060*	0.50
C7	1.2483 (5)	0.2586 (4)	0.2506 (3)	0.031 (2)	0.50
C8	1.3238 (7)	0.2071 (3)	0.2420 (4)	0.031 (2)	0.50
H8	1.2828	0.1534	0.2365	0.037*	0.50
C9	1.4593 (7)	0.2342 (5)	0.2414 (5)	0.041 (3)	0.50
H9	1.5109	0.1991	0.2355	0.049*	0.50
C10	1.5193 (5)	0.3128 (5)	0.2495 (6)	0.038 (3)	0.50
H10	1.6120	0.3313	0.2491	0.046*	0.50
C11	1.4438 (7)	0.3643 (4)	0.2581 (5)	0.033 (2)	0.50
H11	1.4849	0.4180	0.2637	0.039*	0.50
C12	1.3083 (7)	0.3372 (4)	0.2587 (4)	0.033 (2)	0.50
H12	1.2567	0.3723	0.2646	0.039*	0.50
C13	0.9130 (11)	0.2566 (7)	0.1790 (6)	0.068 (4)	0.50
C14	0.9581 (12)	0.3280 (7)	0.1491 (8)	0.082 (5)	0.50
H14	1.0455	0.3582	0.1615	0.098*	0.50
C15	0.8753 (18)	0.3554 (8)	0.1011 (9)	0.174 (12)	0.50
H15	0.9061	0.4042	0.0806	0.209*	0.50
C16	0.7474 (17)	0.3113 (11)	0.0830 (10)	0.202 (15)	0.50
H16	0.6909	0.3299	0.0502	0.242*	0.50
C17	0.7023 (11)	0.2398 (10)	0.1130 (9)	0.133 (9)	0.50
H17	0.6149	0.2097	0.1006	0.160*	0.50
C18	0.7851 (12)	0.2125 (6)	0.1610 (7)	0.066 (4)	0.50
H18	0.7542	0.1637	0.1814	0.079*	0.50
C19	0.9623 (7)	0.3355 (5)	0.3627 (5)	0.058 (3)	0.50
C20	1.0038 (10)	0.3967 (6)	0.4226 (5)	0.061 (3)	0.50
C21	0.9634 (8)	0.0685 (5)	0.1447 (4)	0.049 (2)	0.50
C22	0.9949 (7)	0.0260 (4)	0.0790 (4)	0.050 (2)	0.50
Sn1'	1.00926 (6)	0.23419 (4)	0.28654 (4)	0.03829 (15)	0.50
F1'	1.0757 (12)	0.4860 (5)	0.4148 (6)	0.075 (3)	0.50
F2'	0.8968 (10)	0.4137 (9)	0.4552 (8)	0.100 (5)	0.50
F3'	1.0834 (10)	0.4288 (6)	0.5160 (5)	0.112 (3)	0.50
F4'	0.7838 (7)	0.0278 (6)	0.1416 (5)	0.097 (3)	0.50
F5'	0.9485 (7)	−0.0128 (4)	0.1170 (4)	0.0709 (19)	0.50
F6'	0.8805 (9)	0.0615 (4)	0.0451 (3)	0.080 (2)	0.50
O1'	1.0354 (10)	0.3451 (5)	0.3524 (4)	0.057 (2)	0.50
O2'	1.0750 (15)	0.3021 (9)	0.4607 (9)	0.158 (6)	0.50
O3'	0.9782 (6)	0.1216 (3)	0.2238 (3)	0.0451 (14)	0.50
O4'	1.0674 (6)	0.1671 (4)	0.1209 (4)	0.0580 (18)	0.50
C1'	0.9026 (9)	0.1644 (5)	0.3680 (5)	0.057 (3)	0.50
H1'	0.8963	0.2004	0.4090	0.069*	0.50
C2'	0.7676 (10)	0.1232 (6)	0.3417 (5)	0.061 (3)	0.50
H2'a	0.7636	0.0969	0.2932	0.074*	0.50
H2'b	0.7090	0.1578	0.3394	0.074*	0.50
C3'	0.7361 (10)	0.0674 (6)	0.4003 (6)	0.067 (3)	0.50
H3'a	0.6585	0.0246	0.3840	0.081*	0.50
H3'b	0.7162	0.0932	0.4447	0.081*	0.50
C4'	0.8539 (11)	0.0371 (7)	0.4169 (10)	0.066 (4)	0.50
H4'a	0.8506	−0.0084	0.3848	0.079*	0.50
H4'b	0.8610	0.0233	0.4686	0.079*	0.50
C5'	0.9660 (9)	0.1053 (6)	0.4010 (7)	0.066 (3)	0.50
H5'a	1.0204	0.1267	0.4466	0.080*	0.50
H5'b	1.0224	0.0896	0.3662	0.080*	0.50
C7'	1.2169 (5)	0.2649 (4)	0.2780 (4)	0.039 (2)	0.50
C8'	1.2829 (7)	0.2094 (4)	0.2652 (4)	0.043 (3)	0.50
H8'	1.2365	0.1564	0.2623	0.052*	0.50
C9'	1.4169 (7)	0.2314 (5)	0.2568 (5)	0.042 (3)	0.50
H9'	1.4620	0.1935	0.2481	0.051*	0.50
C10'	1.4848 (6)	0.3090 (6)	0.2612 (6)	0.043 (3)	0.50
H10'	1.5764	0.3240	0.2555	0.052*	0.50
C11'	1.4188 (8)	0.3645 (4)	0.2739 (6)	0.047 (3)	0.50
H11'	1.4652	0.4175	0.2769	0.056*	0.50
C12'	1.2848 (8)	0.3425 (4)	0.2823 (4)	0.044 (3)	0.50
H12'	1.2397	0.3804	0.2910	0.052*	0.50
C13'	0.9009 (7)	0.2738 (4)	0.2022 (4)	0.043 (3)	0.50
C14'	0.9628 (6)	0.3419 (4)	0.1707 (4)	0.043 (3)	0.50
H14'	1.0479	0.3707	0.1897	0.051*	0.50
C15'	0.9004 (6)	0.3678 (4)	0.1113 (4)	0.041 (2)	0.50
H15'	0.9428	0.4144	0.0897	0.049*	0.50
C16'	0.7760 (6)	0.3257 (4)	0.0835 (3)	0.038 (2)	0.50
H16'	0.7334	0.3434	0.0430	0.046*	0.50
C17'	0.7140 (6)	0.2576 (4)	0.1151 (4)	0.037 (2)	0.50
H17'	0.6290	0.2288	0.0961	0.044*	0.50
C18'	0.7765 (7)	0.2317 (4)	0.1744 (4)	0.042 (3)	0.50
H18'	0.7341	0.1852	0.1960	0.050*	0.50
C19'	1.0448 (10)	0.3498 (6)	0.4191 (5)	0.106 (5)	0.50
C20'	1.0227 (11)	0.4253 (6)	0.4507 (6)	0.083 (5)	0.50
C21'	0.9915 (8)	0.1198 (5)	0.1566 (4)	0.045 (3)	0.50
C22'	0.9010 (9)	0.0488 (5)	0.1148 (4)	0.050 (2)	0.50
Ag1	0.58132 (3)	0.272074 (17)	0.744869 (15)	0.02957 (9)
P1	0.78814 (9)	0.35548 (6)	0.80422 (6)	0.0319 (2)
P2	0.69659 (11)	0.22752 (7)	0.64521 (6)	0.0361 (2)
P3	0.40813 (9)	0.32289 (6)	0.68322 (5)	0.0288 (2)
P4	0.43551 (10)	0.17721 (6)	0.81783 (5)	0.0328 (2)
C23	0.7804 (3)	0.43699 (14)	0.86436 (13)	0.0327 (8)
C24	0.8393 (3)	0.44869 (17)	0.93526 (14)	0.0557 (13)
H24	0.8909	0.4162	0.9530	0.067*
C25	0.8229 (3)	0.50798 (19)	0.98027 (12)	0.0588 (13)
H25	0.8632	0.5160	1.0287	0.071*
C26	0.7475 (3)	0.55556 (16)	0.95438 (14)	0.0485 (11)
H26	0.7363	0.5961	0.9851	0.058*
C27	0.6886 (3)	0.54386 (17)	0.88349 (15)	0.0549 (12)
H27	0.6370	0.5764	0.8658	0.066*
C28	0.7050 (3)	0.48457 (17)	0.83848 (12)	0.0481 (11)
H28	0.6647	0.4766	0.7900	0.058*
C29	0.8835 (2)	0.30552 (16)	0.86187 (15)	0.0379 (9)
C30	0.81236 (18)	0.24829 (18)	0.90385 (19)	0.0557 (13)
H30	0.7193	0.2367	0.9010	0.067*
C31	0.8774 (3)	0.20808 (18)	0.94997 (19)	0.0666 (15)
H31	0.8288	0.1690	0.9787	0.080*
C32	1.0136 (3)	0.22510 (18)	0.95412 (17)	0.0554 (12)
H32	1.0580	0.1976	0.9857	0.066*
C33	1.08470 (19)	0.28232 (17)	0.91215 (16)	0.0414 (10)
H33	1.1778	0.2940	0.9150	0.050*
C34	1.0197 (2)	0.32253 (14)	0.86602 (15)	0.0378 (9)
H34	1.0683	0.3616	0.8373	0.045*
C35	0.8981 (4)	0.4007 (2)	0.7352 (2)	0.0391 (9)
H35a	0.8557	0.4348	0.7068	0.047*
H35b	0.9799	0.4335	0.7608	0.047*
C36	0.9342 (4)	0.3446 (3)	0.6818 (3)	0.0464 (11)
H36a	0.9550	0.3027	0.7101	0.056*
H36b	1.0153	0.3722	0.6598	0.056*
C37	0.8306 (4)	0.3079 (3)	0.6197 (2)	0.0449 (10)
H37a	0.8748	0.2894	0.5801	0.054*
H37b	0.7922	0.3483	0.5997	0.054*
C38	0.7825 (3)	0.15516 (19)	0.67121 (18)	0.0484 (11)
C39	0.8498 (4)	0.1243 (2)	0.62147 (16)	0.088 (2)
H39	0.8516	0.1403	0.5725	0.105*
C40	0.9147 (5)	0.0699 (3)	0.6433 (2)	0.104 (3)
H40	0.9607	0.0488	0.6093	0.124*
C41	0.9121 (4)	0.0465 (2)	0.7149 (3)	0.088 (2)
H41	0.9564	0.0094	0.7299	0.105*
C42	0.8447 (4)	0.0774 (2)	0.7647 (2)	0.0787 (18)
H42	0.8430	0.0614	0.8136	0.094*
C43	0.7799 (3)	0.1317 (2)	0.74282 (17)	0.0657 (15)
H43	0.7338	0.1528	0.7768	0.079*
C44	0.6062 (3)	0.1889 (2)	0.55860 (14)	0.0466 (11)
C45	0.6313 (5)	0.2264 (2)	0.49372 (19)	0.104 (3)
H45	0.7006	0.2723	0.4932	0.125*
C46	0.5549 (5)	0.1968 (3)	0.42964 (15)	0.129 (3)
H46	0.5720	0.2224	0.3853	0.155*
C47	0.4535 (4)	0.1296 (3)	0.43044 (16)	0.088 (2)
H47	0.4013	0.1094	0.3866	0.106*
C48	0.4285 (4)	0.0922 (3)	0.4953 (2)	0.111 (3)
H48	0.3592	0.0463	0.4959	0.134*
C49	0.5048 (4)	0.1218 (3)	0.55941 (16)	0.106 (3)
H49	0.4877	0.0962	0.6038	0.127*
C50	0.3506 (3)	0.40232 (14)	0.72072 (13)	0.0343 (8)
C51	0.3665 (3)	0.41804 (17)	0.79582 (13)	0.0464 (11)
H51	0.4093	0.3891	0.8266	0.056*
C52	0.3199 (3)	0.47614 (19)	0.82585 (13)	0.0638 (15)
H52	0.3308	0.4869	0.8772	0.077*
C53	0.2573 (3)	0.51852 (16)	0.78078 (19)	0.0651 (15)
H53	0.2254	0.5582	0.8013	0.078*
C54	0.2413 (3)	0.50279 (16)	0.70568 (18)	0.0564 (13)
H54	0.1986	0.5318	0.6749	0.068*
C55	0.2880 (3)	0.44469 (16)	0.67565 (12)	0.0419 (10)
H55	0.2771	0.4339	0.6243	0.050*
C56	0.4434 (3)	0.35230 (16)	0.59116 (11)	0.0343 (8)
C57	0.3626 (3)	0.32060 (18)	0.52907 (15)	0.0578 (13)
H57	0.2826	0.2825	0.5336	0.069*
C58	0.3990 (4)	0.3447 (2)	0.46036 (12)	0.080 (2)
H58	0.3437	0.3230	0.4179	0.096*
C59	0.5161 (4)	0.4005 (2)	0.45374 (11)	0.0774 (19)
H59	0.5409	0.4170	0.4068	0.093*
C60	0.5969 (3)	0.43218 (18)	0.51583 (15)	0.0572 (13)
H60	0.6770	0.4703	0.5113	0.069*
C61	0.5606 (2)	0.40809 (16)	0.58454 (12)	0.0400 (9)
H61	0.6158	0.4298	0.6270	0.048*
C62	0.2561 (4)	0.2445 (2)	0.6732 (2)	0.0328 (8)
H62a	0.1858	0.2637	0.6484	0.039*
H62b	0.2696	0.2024	0.6416	0.039*
C63	0.2108 (4)	0.2118 (2)	0.7470 (2)	0.0353 (9)
H63a	0.2350	0.2544	0.7848	0.042*
H63b	0.1138	0.1927	0.7425	0.042*
C64	0.2673 (4)	0.1464 (2)	0.7739 (2)	0.0392 (9)
H64a	0.2662	0.1110	0.7316	0.047*
H64b	0.2089	0.1170	0.8091	0.047*
C65	0.4128 (3)	0.21354 (16)	0.90956 (11)	0.0380 (9)
C66	0.4791 (3)	0.28885 (16)	0.93188 (13)	0.0426 (10)
H66	0.5350	0.3206	0.9001	0.051*
C67	0.4637 (3)	0.31763 (16)	1.00066 (15)	0.0591 (14)
H67	0.5090	0.3691	1.0159	0.071*
C68	0.3820 (3)	0.2711 (2)	1.04714 (11)	0.0650 (16)
H68	0.3715	0.2908	1.0941	0.078*
C69	0.3157 (3)	0.1958 (2)	1.02482 (14)	0.0644 (17)
H69	0.2599	0.1640	1.0566	0.077*
C70	0.3311 (3)	0.16701 (15)	0.95603 (16)	0.0497 (12)
H70	0.2858	0.1155	0.9408	0.060*
C71	0.4784 (3)	0.08699 (13)	0.83469 (14)	0.0353 (9)
C72	0.4620 (3)	0.03354 (17)	0.77659 (11)	0.0473 (11)
H72	0.4218	0.0422	0.7308	0.057*
C73	0.5044 (3)	−0.03255 (15)	0.78545 (14)	0.0553 (12)
H73	0.4932	−0.0691	0.7457	0.066*
C74	0.5631 (3)	−0.04518 (14)	0.85239 (16)	0.0533 (12)
H74	0.5921	−0.0903	0.8584	0.064*
C75	0.5795 (3)	0.00827 (17)	0.91049 (13)	0.0488 (11)
H75	0.6197	−0.0004	0.9562	0.059*
C76	0.5371 (3)	0.07436 (14)	0.90164 (12)	0.0400 (9)
H76	0.5483	0.1109	0.9413	0.048*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Sn1	0.0391 (3)	0.0385 (3)	0.0337 (3)	0.0106 (3)	0.0055 (3)	0.0052 (3)
F1	0.115 (7)	0.181 (12)	0.058 (5)	0.079 (9)	0.000 (5)	0.029 (6)
F2	0.099 (12)	0.23 (2)	0.138 (15)	0.028 (12)	−0.022 (11)	−0.011 (14)
F3	0.150 (10)	0.096 (9)	0.089 (8)	0.000 (8)	0.049 (7)	0.009 (7)
F4	0.069 (4)	0.075 (5)	0.161 (8)	−0.030 (4)	0.057 (5)	−0.065 (5)
F5	0.073 (4)	0.034 (3)	0.077 (4)	0.005 (3)	0.001 (3)	−0.007 (3)
F6	0.144 (7)	0.095 (6)	0.044 (4)	0.063 (6)	0.001 (4)	0.012 (4)
O1	0.051 (4)	0.058 (5)	0.067 (6)	0.024 (4)	0.012 (4)	−0.013 (4)
O2	0.024 (3)	0.118 (7)	0.138 (8)	0.001 (4)	0.011 (4)	0.055 (6)
O3	0.053 (5)	0.046 (4)	0.049 (4)	0.004 (4)	−0.003 (4)	−0.006 (3)
O4	0.059 (6)	0.084 (7)	0.099 (8)	0.004 (5)	0.042 (6)	0.003 (6)
C1	0.044 (5)	0.057 (5)	0.047 (5)	0.014 (4)	0.008 (4)	0.019 (4)
C2	0.047 (5)	0.086 (7)	0.058 (6)	0.004 (5)	−0.003 (4)	0.024 (5)
C3	0.055 (7)	0.085 (8)	0.066 (7)	0.034 (6)	0.019 (6)	0.021 (6)
C4	0.079 (7)	0.073 (7)	0.036 (5)	0.023 (5)	0.012 (5)	−0.003 (5)
C5	0.093 (7)	0.056 (6)	0.043 (5)	0.003 (5)	−0.011 (5)	0.001 (4)
C6	0.051 (5)	0.042 (5)	0.052 (5)	0.004 (4)	−0.003 (4)	0.009 (4)
C7	0.027 (4)	0.043 (5)	0.019 (4)	0.004 (4)	0.002 (3)	0.003 (3)
C8	0.037 (5)	0.033 (4)	0.024 (4)	0.009 (4)	0.003 (4)	0.006 (3)
C9	0.038 (5)	0.047 (5)	0.041 (5)	0.013 (4)	0.004 (4)	0.012 (4)
C10	0.035 (5)	0.041 (5)	0.039 (5)	0.011 (4)	0.006 (4)	0.011 (4)
C11	0.034 (4)	0.037 (5)	0.024 (4)	0.004 (4)	−0.001 (4)	0.001 (3)
C12	0.034 (5)	0.040 (4)	0.024 (5)	0.009 (4)	0.005 (4)	0.002 (3)
C13	0.054 (6)	0.074 (7)	0.073 (7)	0.011 (5)	−0.012 (6)	0.039 (6)
C14	0.093 (9)	0.075 (8)	0.077 (8)	0.022 (7)	−0.006 (6)	0.015 (7)
C15	0.178 (15)	0.185 (15)	0.162 (15)	0.053 (10)	0.003 (10)	0.027 (10)
C16	0.199 (18)	0.206 (18)	0.197 (17)	0.049 (11)	0.012 (10)	0.019 (10)
C17	0.133 (12)	0.137 (12)	0.131 (13)	0.042 (9)	−0.001 (9)	0.012 (9)
C18	0.070 (7)	0.075 (8)	0.060 (7)	0.034 (6)	−0.001 (6)	−0.004 (6)
C19	0.027 (4)	0.073 (7)	0.067 (6)	−0.003 (4)	0.004 (4)	0.049 (5)
C20	0.057 (6)	0.074 (7)	0.071 (7)	0.036 (5)	0.037 (5)	0.034 (6)
C21	0.042 (5)	0.034 (5)	0.065 (6)	0.004 (4)	0.000 (5)	0.009 (5)
C22	0.049 (5)	0.038 (4)	0.056 (5)	−0.003 (4)	0.013 (4)	0.004 (4)
Sn1'	0.0383 (3)	0.0398 (3)	0.0368 (3)	0.0128 (3)	−0.0060 (3)	−0.0008 (3)
F1'	0.099 (6)	0.062 (5)	0.060 (5)	0.010 (5)	0.013 (5)	0.011 (4)
F2'	0.046 (6)	0.162 (11)	0.107 (9)	0.043 (6)	0.039 (6)	0.063 (9)
F3'	0.111 (7)	0.112 (8)	0.111 (8)	0.022 (6)	0.015 (6)	0.056 (6)
F4'	0.049 (5)	0.105 (7)	0.117 (7)	−0.011 (5)	0.014 (5)	−0.033 (5)
F5'	0.098 (5)	0.054 (4)	0.061 (4)	0.023 (4)	−0.006 (4)	0.003 (3)
F6'	0.138 (7)	0.057 (4)	0.044 (4)	0.030 (4)	−0.021 (4)	−0.005 (3)
O1'	0.091 (7)	0.053 (5)	0.026 (4)	0.015 (5)	0.009 (4)	−0.006 (3)
O2'	0.162 (12)	0.164 (12)	0.144 (10)	0.048 (10)	−0.042 (9)	0.056 (10)
O3'	0.046 (3)	0.047 (3)	0.042 (3)	0.010 (3)	0.007 (3)	0.005 (3)
O4'	0.047 (4)	0.071 (5)	0.051 (4)	0.005 (3)	0.016 (3)	0.008 (4)
C1'	0.082 (6)	0.067 (6)	0.033 (4)	0.034 (5)	0.017 (4)	0.011 (4)
C2'	0.071 (6)	0.074 (6)	0.041 (5)	0.018 (5)	0.019 (4)	0.013 (4)
C3'	0.087 (7)	0.065 (6)	0.055 (5)	0.023 (5)	0.022 (5)	0.016 (5)
C4'	0.059 (7)	0.054 (6)	0.087 (8)	0.017 (5)	0.014 (7)	0.024 (6)
C5'	0.071 (6)	0.056 (6)	0.072 (6)	0.015 (5)	0.008 (5)	0.019 (5)
C7'	0.038 (5)	0.044 (5)	0.036 (5)	0.016 (4)	−0.002 (4)	0.010 (4)
C8'	0.037 (5)	0.049 (5)	0.042 (6)	0.010 (4)	−0.005 (4)	0.004 (4)
C9'	0.044 (6)	0.039 (5)	0.047 (6)	0.017 (5)	0.001 (5)	0.009 (4)
C10'	0.033 (5)	0.056 (6)	0.037 (5)	0.005 (4)	0.000 (4)	0.006 (4)
C11'	0.059 (7)	0.045 (6)	0.036 (6)	0.014 (5)	−0.002 (5)	0.016 (4)
C12'	0.048 (5)	0.050 (5)	0.032 (6)	0.014 (4)	−0.004 (4)	0.008 (4)
C13'	0.047 (5)	0.043 (5)	0.038 (5)	0.009 (4)	0.002 (4)	0.000 (4)
C14'	0.049 (5)	0.042 (5)	0.036 (5)	0.012 (4)	−0.002 (4)	0.006 (4)
C15'	0.038 (4)	0.050 (5)	0.042 (4)	0.023 (4)	0.005 (4)	0.016 (4)
C16'	0.026 (4)	0.056 (5)	0.031 (4)	0.014 (4)	−0.008 (3)	−0.016 (4)
C17'	0.029 (4)	0.052 (5)	0.032 (4)	0.018 (4)	−0.010 (3)	0.003 (4)
C18'	0.036 (5)	0.044 (5)	0.047 (6)	0.017 (4)	−0.010 (4)	−0.010 (5)
C19'	0.090 (8)	0.111 (9)	0.113 (9)	0.014 (7)	0.011 (8)	0.035 (8)
C20'	0.095 (9)	0.063 (7)	0.084 (8)	0.006 (6)	0.035 (7)	−0.012 (7)
C21'	0.031 (5)	0.056 (6)	0.046 (5)	0.011 (5)	0.003 (4)	0.009 (5)
C22'	0.053 (6)	0.052 (5)	0.049 (5)	0.022 (5)	0.002 (5)	0.007 (4)
Ag1	0.02472 (15)	0.03768 (16)	0.02888 (15)	0.01099 (11)	0.00657 (11)	0.00960 (11)
P1	0.0242 (5)	0.0359 (5)	0.0379 (5)	0.0103 (4)	0.0067 (4)	0.0091 (4)
P2	0.0354 (5)	0.0460 (6)	0.0320 (5)	0.0178 (5)	0.0083 (4)	0.0055 (4)
P3	0.0265 (5)	0.0353 (5)	0.0265 (5)	0.0108 (4)	0.0042 (4)	0.0085 (4)
P4	0.0280 (5)	0.0415 (6)	0.0303 (5)	0.0097 (4)	0.0051 (4)	0.0143 (4)
C23	0.0224 (17)	0.040 (2)	0.036 (2)	0.0079 (15)	0.0034 (15)	0.0085 (16)
C24	0.061 (3)	0.068 (3)	0.048 (3)	0.037 (3)	−0.008 (2)	0.002 (2)
C25	0.069 (3)	0.074 (3)	0.041 (2)	0.038 (3)	−0.013 (2)	−0.009 (2)
C26	0.051 (3)	0.055 (3)	0.043 (2)	0.020 (2)	0.002 (2)	−0.006 (2)
C27	0.067 (3)	0.057 (3)	0.050 (3)	0.036 (3)	−0.006 (2)	−0.001 (2)
C28	0.057 (3)	0.053 (3)	0.040 (2)	0.027 (2)	−0.008 (2)	−0.001 (2)
C29	0.030 (2)	0.038 (2)	0.048 (2)	0.0125 (17)	0.0018 (17)	0.0065 (18)
C30	0.034 (2)	0.059 (3)	0.075 (3)	0.012 (2)	−0.001 (2)	0.027 (3)
C31	0.045 (3)	0.072 (3)	0.083 (4)	0.013 (2)	−0.003 (3)	0.036 (3)
C32	0.041 (2)	0.058 (3)	0.070 (3)	0.021 (2)	−0.009 (2)	0.015 (2)
C33	0.030 (2)	0.050 (2)	0.049 (2)	0.0199 (18)	−0.0001 (18)	−0.005 (2)
C34	0.030 (2)	0.042 (2)	0.044 (2)	0.0144 (17)	0.0060 (17)	0.0019 (18)
C35	0.029 (2)	0.041 (2)	0.048 (2)	0.0079 (17)	0.0120 (18)	0.0099 (18)
C36	0.032 (2)	0.053 (3)	0.057 (3)	0.0134 (19)	0.019 (2)	0.005 (2)
C37	0.046 (2)	0.051 (3)	0.043 (2)	0.016 (2)	0.024 (2)	0.0067 (19)
C38	0.044 (2)	0.044 (2)	0.059 (3)	0.018 (2)	−0.008 (2)	−0.006 (2)
C39	0.114 (5)	0.101 (5)	0.071 (4)	0.077 (4)	−0.020 (3)	−0.030 (3)
C40	0.111 (5)	0.103 (5)	0.115 (5)	0.075 (4)	−0.030 (4)	−0.052 (4)
C41	0.094 (5)	0.054 (3)	0.115 (5)	0.032 (3)	−0.034 (4)	0.001 (3)
C42	0.058 (3)	0.074 (4)	0.109 (5)	0.023 (3)	0.003 (3)	0.037 (4)
C43	0.050 (3)	0.069 (3)	0.085 (4)	0.022 (3)	0.012 (3)	0.037 (3)
C44	0.050 (3)	0.065 (3)	0.033 (2)	0.026 (2)	0.0114 (19)	0.000 (2)
C45	0.151 (6)	0.096 (5)	0.039 (3)	−0.010 (4)	−0.002 (4)	0.000 (3)
C46	0.182 (7)	0.128 (6)	0.042 (3)	−0.016 (6)	−0.006 (4)	0.002 (4)
C47	0.095 (5)	0.136 (6)	0.032 (3)	0.031 (4)	−0.001 (3)	−0.002 (3)
C48	0.085 (4)	0.158 (6)	0.048 (3)	−0.043 (4)	0.001 (3)	0.011 (4)
C49	0.083 (4)	0.154 (6)	0.037 (3)	−0.043 (4)	0.000 (3)	0.017 (3)
C50	0.0248 (18)	0.039 (2)	0.039 (2)	0.0076 (16)	0.0064 (16)	0.0042 (17)
C51	0.051 (3)	0.050 (3)	0.038 (2)	0.011 (2)	0.014 (2)	0.0024 (19)
C52	0.068 (3)	0.062 (3)	0.058 (3)	0.007 (3)	0.031 (3)	−0.011 (3)
C53	0.053 (3)	0.048 (3)	0.097 (4)	0.013 (2)	0.036 (3)	−0.002 (3)
C54	0.035 (2)	0.048 (3)	0.090 (4)	0.017 (2)	0.010 (2)	0.008 (3)
C55	0.029 (2)	0.042 (2)	0.055 (3)	0.0095 (17)	0.0021 (18)	0.005 (2)
C56	0.040 (2)	0.035 (2)	0.0297 (19)	0.0105 (17)	0.0075 (16)	0.0082 (16)
C57	0.071 (3)	0.054 (3)	0.034 (2)	−0.007 (2)	0.005 (2)	0.010 (2)
C58	0.106 (5)	0.072 (4)	0.034 (2)	−0.023 (3)	0.004 (3)	0.006 (2)
C59	0.105 (4)	0.072 (4)	0.035 (2)	−0.015 (3)	0.022 (3)	0.006 (2)
C60	0.069 (3)	0.049 (3)	0.045 (3)	−0.004 (2)	0.019 (2)	0.011 (2)
C61	0.044 (2)	0.041 (2)	0.034 (2)	0.0069 (18)	0.0088 (18)	0.0043 (17)
C62	0.0302 (19)	0.036 (2)	0.0319 (19)	0.0076 (16)	0.0004 (15)	0.0086 (16)
C63	0.0255 (18)	0.044 (2)	0.036 (2)	0.0061 (16)	0.0068 (16)	0.0142 (17)
C64	0.030 (2)	0.045 (2)	0.040 (2)	0.0030 (17)	0.0014 (17)	0.0200 (18)
C65	0.0282 (19)	0.064 (3)	0.0305 (19)	0.0253 (19)	0.0077 (16)	0.0185 (19)
C66	0.037 (2)	0.064 (3)	0.031 (2)	0.021 (2)	0.0009 (17)	0.0073 (19)
C67	0.062 (3)	0.093 (4)	0.035 (2)	0.045 (3)	−0.003 (2)	0.002 (2)
C68	0.074 (3)	0.114 (5)	0.033 (2)	0.066 (3)	0.013 (2)	0.023 (3)
C69	0.054 (3)	0.121 (5)	0.048 (3)	0.065 (3)	0.029 (2)	0.054 (3)
C70	0.034 (2)	0.079 (3)	0.049 (2)	0.030 (2)	0.0143 (19)	0.034 (2)
C71	0.0296 (19)	0.037 (2)	0.041 (2)	0.0096 (16)	0.0091 (16)	0.0167 (17)
C72	0.053 (3)	0.053 (3)	0.040 (2)	0.021 (2)	0.007 (2)	0.015 (2)
C73	0.065 (3)	0.054 (3)	0.054 (3)	0.027 (2)	0.008 (2)	0.009 (2)
C74	0.058 (3)	0.051 (3)	0.058 (3)	0.026 (2)	0.008 (2)	0.018 (2)
C75	0.046 (2)	0.057 (3)	0.049 (3)	0.020 (2)	0.004 (2)	0.021 (2)
C76	0.034 (2)	0.049 (2)	0.039 (2)	0.0127 (18)	0.0037 (17)	0.0143 (18)

Geometric parameters (Å, º) top

Sn1—C1	2.139 (4)	P2—C38	1.833 (3)
Sn1—C7	2.149 (5)	P3—C56	1.817 (2)
Sn1—C13	2.110 (7)	P3—C62	1.835 (4)
Sn1—O1	2.252 (8)	P3—C50	1.837 (2)
Sn1—O3	2.236 (6)	P4—C71	1.829 (2)
F1—C20	1.330 (8)	P4—C64	1.842 (4)
F2—C20	1.328 (9)	P4—C65	1.846 (2)
F3—C20	1.335 (9)	C23—C24	1.3900
F4—C22	1.311 (7)	C23—C28	1.3900
F5—C22	1.339 (8)	C24—C25	1.3900
F6—C22	1.341 (8)	C24—H24	0.9500
O1—C19	1.269 (8)	C25—C26	1.3900
O2—C19	1.231 (8)	C25—H25	0.9500
O3—C21	1.239 (8)	C26—C27	1.3900
O4—C21	1.227 (8)	C26—H26	0.9500
C1—C2	1.3900	C27—C28	1.3900
C1—C6	1.3900	C27—H27	0.9500
C2—C3	1.3900	C28—H28	0.9500
C2—H2	0.9500	C29—C30	1.3900
C3—C4	1.3900	C29—C34	1.3900
C3—H3	0.9500	C30—C31	1.3900
C4—C5	1.3900	C30—H30	0.9500
C4—H4	0.9500	C31—C32	1.3900
C5—C6	1.3900	C31—H31	0.9500
C5—H5	0.9500	C32—C33	1.3900
C6—H6	0.9500	C32—H32	0.9500
C7—C8	1.3900	C33—C34	1.3900
C7—C12	1.3900	C33—H33	0.9500
C8—C9	1.3900	C34—H34	0.9500
C8—H8	0.9500	C35—C36	1.531 (6)
C9—C10	1.3900	C35—H35a	0.9900
C9—H9	0.9500	C35—H35b	0.9900
C10—C11	1.3900	C36—C37	1.532 (7)
C10—H10	0.9500	C36—H36a	0.9900
C11—C12	1.3900	C36—H36b	0.9900
C11—H11	0.9500	C37—H37a	0.9900
C12—H12	0.9500	C37—H37b	0.9900
C13—C14	1.3900	C38—C39	1.3900
C13—C18	1.3900	C38—C43	1.3900
C14—C15	1.3900	C39—C40	1.3900
C14—H14	0.9500	C39—H39	0.9500
C15—C16	1.3900	C40—C41	1.3900
C15—H15	0.9500	C40—H40	0.9500
C16—C17	1.3900	C41—C42	1.3900
C16—H16	0.9500	C41—H41	0.9500
C17—C18	1.3900	C42—C43	1.3900
C17—H17	0.9500	C42—H42	0.9500
C18—H18	0.9500	C43—H43	0.9500
C19—C20	1.497 (9)	C44—C45	1.3900
C21—C22	1.518 (8)	C44—C49	1.3900
Sn1'—C1'	2.160 (7)	C45—C46	1.3900
Sn1'—C7'	2.140 (5)	C45—H45	0.9500
Sn1'—C13'	2.114 (4)	C46—C47	1.3900
Sn1'—O1'	2.254 (8)	C46—H46	0.9500
Sn1'—O3'	2.244 (6)	C47—C48	1.3900
F1'—C20'	1.307 (9)	C47—H47	0.9500
F2'—C20'	1.303 (9)	C48—C49	1.3900
F3'—C20'	1.312 (9)	C48—H48	0.9500
F4'—C22'	1.331 (8)	C49—H49	0.9500
F5'—C22'	1.337 (8)	C50—C51	1.3900
F6'—C22'	1.319 (8)	C50—C55	1.3900
O1'—C19'	1.220 (9)	C51—C52	1.3900
O2'—C19'	1.253 (9)	C51—H51	0.9500
O3'—C21'	1.251 (8)	C52—C53	1.3900
O4'—C21'	1.242 (8)	C52—H52	0.9500
C1'—C2'	1.468 (9)	C53—C54	1.3900
C1'—C5'	1.520 (9)	C53—H53	0.9500
C1'—H1'	1.0000	C54—C55	1.3900
C2'—C3'	1.484 (8)	C54—H54	0.9500
C2'—H2'a	0.9900	C55—H55	0.9500
C2'—H2'b	0.9900	C56—C57	1.3900
C3'—C4'	1.506 (9)	C56—C61	1.3900
C3'—H3'a	0.9900	C57—C58	1.3900
C3'—H3'b	0.9900	C57—H57	0.9500
C4'—C5'	1.516 (9)	C58—C59	1.3900
C4'—H4'a	0.9900	C58—H58	0.9500
C4'—H4'b	0.9900	C59—C60	1.3900
C5'—H5'a	0.9900	C59—H59	0.9500
C5'—H5'b	0.9900	C60—C61	1.3900
C7'—C8'	1.3900	C60—H60	0.9500
C7'—C12'	1.3900	C61—H61	0.9500
C8'—C9'	1.3900	C62—C63	1.547 (5)
C8'—H8'	0.9500	C62—H62a	0.9900
C9'—C10'	1.3900	C62—H62b	0.9900
C9'—H9'	0.9500	C63—C64	1.534 (6)
C10'—C11'	1.3900	C63—H63a	0.9900
C10'—H10'	0.9500	C63—H63b	0.9900
C11'—C12'	1.3900	C64—H64a	0.9900
C11'—H11'	0.9500	C64—H64b	0.9900
C12'—H12'	0.9500	C65—C66	1.3900
C13'—C14'	1.3900	C65—C70	1.3900
C13'—C18'	1.3900	C66—C67	1.3900
C14'—C15'	1.3900	C66—H66	0.9500
C14'—H14'	0.9500	C67—C68	1.3900
C15'—C16'	1.3900	C67—H67	0.9500
C15'—H15'	0.9500	C68—C69	1.3900
C16'—C17'	1.3900	C68—H68	0.9500
C16'—H16'	0.9500	C69—C70	1.3900
C17'—C18'	1.3900	C69—H69	0.9500
C17'—H17'	0.9500	C70—H70	0.9500
C18'—H18'	0.9500	C71—C72	1.3900
C19'—C20'	1.548 (9)	C71—C76	1.3900
C21'—C22'	1.532 (8)	C72—C73	1.3900
Ag1—P1	2.468 (1)	C72—H72	0.9500
Ag1—P2	2.499 (1)	C73—C74	1.3900
Ag1—P3	2.479 (1)	C73—H73	0.9500
Ag1—P4	2.470 (1)	C74—C75	1.3900
P1—C29	1.826 (2)	C74—H74	0.9500
P1—C35	1.837 (4)	C75—C76	1.3900
P1—C23	1.840 (2)	C75—H75	0.9500
P2—C44	1.819 (3)	C76—H76	0.9500
P2—C37	1.836 (4)

C1—Sn1—C7	115.0 (2)	C44—P2—Ag1	119.94 (13)
C1—Sn1—C13	124.2 (4)	C37—P2—Ag1	109.52 (14)
C1—Sn1—O1	85.8 (3)	C38—P2—Ag1	114.96 (11)
C1—Sn1—O3	97.4 (3)	C56—P3—C62	105.92 (15)
C7—Sn1—C13	120.4 (4)	C56—P3—C50	102.61 (14)
C7—Sn1—O1	86.4 (3)	C62—P3—C50	101.72 (16)
C7—Sn1—O3	86.7 (3)	C56—P3—Ag1	112.76 (11)
C13—Sn1—O1	91.0 (4)	C62—P3—Ag1	107.80 (13)
C13—Sn1—O3	92.3 (4)	C50—P3—Ag1	124.29 (9)
O3—Sn1—O1	173.1 (3)	C71—P4—C64	104.17 (17)
C19—O1—Sn1	130.7 (7)	C71—P4—C65	104.14 (13)
C21—O3—Sn1	128.2 (6)	C64—P4—C65	103.41 (17)
C2—C1—C6	120.0	C71—P4—Ag1	117.53 (10)
C2—C1—Sn1	122.3 (3)	C64—P4—Ag1	111.27 (13)
C6—C1—Sn1	117.7 (3)	C65—P4—Ag1	114.85 (10)
C3—C2—C1	120.0	C24—C23—C28	120.0
C3—C2—H2	120.0	C24—C23—P1	122.21 (15)
C1—C2—H2	120.0	C28—C23—P1	117.64 (15)
C2—C3—C4	120.0	C25—C24—C23	120.0
C2—C3—H3	120.0	C25—C24—H24	120.0
C4—C3—H3	120.0	C23—C24—H24	120.0
C3—C4—C5	120.0	C24—C25—C26	120.0
C3—C4—H4	120.0	C24—C25—H25	120.0
C5—C4—H4	120.0	C26—C25—H25	120.0
C6—C5—C4	120.0	C27—C26—C25	120.0
C6—C5—H5	120.0	C27—C26—H26	120.0
C4—C5—H5	120.0	C25—C26—H26	120.0
C5—C6—C1	120.0	C26—C27—C28	120.0
C5—C6—H6	120.0	C26—C27—H27	120.0
C1—C6—H6	120.0	C28—C27—H27	120.0
C8—C7—C12	120.0	C27—C28—C23	120.0
C8—C7—Sn1	119.5 (4)	C27—C28—H28	120.0
C12—C7—Sn1	120.5 (4)	C23—C28—H28	120.0
C9—C8—C7	120.0	C30—C29—C34	120.0
C9—C8—H8	120.0	C30—C29—P1	116.27 (15)
C7—C8—H8	120.0	C34—C29—P1	123.73 (15)
C8—C9—C10	120.0	C29—C30—C31	120.0
C8—C9—H9	120.0	C29—C30—H30	120.0
C10—C9—H9	120.0	C31—C30—H30	120.0
C11—C10—C9	120.0	C32—C31—C30	120.0
C11—C10—H10	120.0	C32—C31—H31	120.0
C9—C10—H10	120.0	C30—C31—H31	120.0
C10—C11—C12	120.0	C31—C32—C33	120.0
C10—C11—H11	120.0	C31—C32—H32	120.0
C12—C11—H11	120.0	C33—C32—H32	120.0
C11—C12—C7	120.0	C32—C33—C34	120.0
C11—C12—H12	120.0	C32—C33—H33	120.0
C7—C12—H12	120.0	C34—C33—H33	120.0
C14—C13—C18	120.0	C33—C34—C29	120.0
C14—C13—Sn1	119.8 (7)	C33—C34—H34	120.0
C18—C13—Sn1	120.2 (7)	C29—C34—H34	120.0
C15—C14—C13	120.0	C36—C35—P1	115.1 (3)
C15—C14—H14	120.0	C36—C35—H35a	108.5
C13—C14—H14	120.0	P1—C35—H35a	108.5
C14—C15—C16	120.0	C36—C35—H35b	108.5
C14—C15—H15	120.0	P1—C35—H35b	108.5
C16—C15—H15	120.0	H35a—C35—H35b	107.5
C17—C16—C15	120.0	C35—C36—C37	116.6 (4)
C17—C16—H16	120.0	C35—C36—H36a	108.2
C15—C16—H16	120.0	C37—C36—H36a	108.2
C18—C17—C16	120.0	C35—C36—H36b	108.2
C18—C17—H17	120.0	C37—C36—H36b	108.2
C16—C17—H17	120.0	H36a—C36—H36b	107.3
C17—C18—C13	120.0	C36—C37—P2	115.3 (3)
C17—C18—H18	120.0	C36—C37—H37a	108.4
C13—C18—H18	120.0	P2—C37—H37a	108.4
O2—C19—O1	132.9 (10)	C36—C37—H37b	108.4
O2—C19—C20	109.5 (9)	P2—C37—H37b	108.4
O1—C19—C20	117.6 (8)	H37a—C37—H37b	107.5
F2—C20—F1	107.1 (10)	C39—C38—C43	120.0
F2—C20—F3	101.7 (11)	C39—C38—P2	121.6 (2)
F1—C20—F3	103.9 (10)	C43—C38—P2	118.4 (2)
F2—C20—C19	117.4 (10)	C40—C39—C38	120.0
F1—C20—C19	115.3 (9)	C40—C39—H39	120.0
F3—C20—C19	109.8 (8)	C38—C39—H39	120.0
O4—C21—O3	129.9 (9)	C39—C40—C41	120.0
O4—C21—C22	114.1 (8)	C39—C40—H40	120.0
O3—C21—C22	116.1 (7)	C41—C40—H40	120.0
F4—C22—F6	108.9 (8)	C42—C41—C40	120.0
F4—C22—F5	106.5 (7)	C42—C41—H41	120.0
F6—C22—F5	104.3 (7)	C40—C41—H41	120.0
F4—C22—C21	113.7 (6)	C41—C42—C43	120.0
F6—C22—C21	111.7 (7)	C41—C42—H42	120.0
F5—C22—C21	111.2 (7)	C43—C42—H42	120.0
C1'—Sn1'—C7'	127.0 (3)	C42—C43—C38	120.0
C1'—Sn1'—C13'	118.2 (3)	C42—C43—H43	120.0
C1'—Sn1'—O1'	93.5 (3)	C38—C43—H43	120.0
C1'—Sn1'—O3'	84.5 (3)	C45—C44—C49	120.0
C7'—Sn1'—C13'	114.7 (3)	C45—C44—P2	122.1 (2)
C7'—Sn1'—O1'	88.5 (3)	C49—C44—P2	117.8 (2)
C7'—Sn1'—O3'	93.0 (3)	C44—C45—C46	120.0
C13'—Sn1'—O1'	90.2 (3)	C44—C45—H45	120.0
C13'—Sn1'—O3'	90.4 (3)	C46—C45—H45	120.0
O3'—Sn1'—O1'	178.0 (3)	C47—C46—C45	120.0
C19'—O1'—Sn1'	123.6 (7)	C47—C46—H46	120.0
C21'—O3'—Sn1'	120.7 (5)	C45—C46—H46	120.0
C2'—C1'—C5'	107.1 (8)	C48—C47—C46	120.0
C2'—C1'—Sn1'	113.3 (5)	C48—C47—H47	120.0
C5'—C1'—Sn1'	115.7 (6)	C46—C47—H47	120.0
C2'—C1'—H1'	106.8	C49—C48—C47	120.0
C5'—C1'—H1'	106.8	C49—C48—H48	120.0
Sn1'—C1'—H1'	106.8	C47—C48—H48	120.0
C1'—C2'—C3'	99.5 (7)	C48—C49—C44	120.0
C1'—C2'—H2'a	111.9	C48—C49—H49	120.0
C3'—C2'—H2'a	111.9	C44—C49—H49	120.0
C1'—C2'—H2'b	111.9	C51—C50—C55	120.0
C3'—C2'—H2'b	111.9	C51—C50—P3	118.85 (15)
H2'a—C2'—H2'b	109.6	C55—C50—P3	121.11 (15)
C2'—C3'—C4'	107.7 (8)	C50—C51—C52	120.0
C2'—C3'—H3'a	110.2	C50—C51—H51	120.0
C4'—C3'—H3'a	110.2	C52—C51—H51	120.0
C2'—C3'—H3'b	110.2	C53—C52—C51	120.0
C4'—C3'—H3'b	110.2	C53—C52—H52	120.0
H3'a—C3'—H3'b	108.5	C51—C52—H52	120.0
C3'—C4'—C5'	102.0 (7)	C52—C53—C54	120.0
C3'—C4'—H4'a	111.4	C52—C53—H53	120.0
C5'—C4'—H4'a	111.4	C54—C53—H53	120.0
C3'—C4'—H4'b	111.4	C55—C54—C53	120.0
C5'—C4'—H4'b	111.4	C55—C54—H54	120.0
H4'a—C4'—H4'b	109.2	C53—C54—H54	120.0
C1'—C5'—C4'	105.9 (7)	C54—C55—C50	120.0
C1'—C5'—H5'a	110.6	C54—C55—H55	120.0
C4'—C5'—H5'a	110.6	C50—C55—H55	120.0
C1'—C5'—H5'b	110.6	C57—C56—C61	120.0
C4'—C5'—H5'b	110.6	C57—C56—P3	123.65 (15)
H5'a—C5'—H5'b	108.7	C61—C56—P3	116.32 (15)
C8'—C7'—C12'	120.0	C58—C57—C56	120.0
C8'—C7'—Sn1'	121.4 (4)	C58—C57—H57	120.0
C12'—C7'—Sn1'	118.6 (4)	C56—C57—H57	120.0
C7'—C8'—C9'	120.0	C57—C58—C59	120.0
C7'—C8'—H8'	120.0	C57—C58—H58	120.0
C9'—C8'—H8'	120.0	C59—C58—H58	120.0
C8'—C9'—C10'	120.0	C58—C59—C60	120.0
C8'—C9'—H9'	120.0	C58—C59—H59	120.0
C10'—C9'—H9'	120.0	C60—C59—H59	120.0
C11'—C10'—C9'	120.0	C61—C60—C59	120.0
C11'—C10'—H10'	120.0	C61—C60—H60	120.0
C9'—C10'—H10'	120.0	C59—C60—H60	120.0
C10'—C11'—C12'	120.0	C60—C61—C56	120.0
C10'—C11'—H11'	120.0	C60—C61—H61	120.0
C12'—C11'—H11'	120.0	C56—C61—H61	120.0
C11'—C12'—C7'	120.0	C63—C62—P3	113.1 (3)
C11'—C12'—H12'	120.0	C63—C62—H62a	109.0
C7'—C12'—H12'	120.0	P3—C62—H62a	109.0
C14'—C13'—C18'	120.0	C63—C62—H62b	109.0
C14'—C13'—Sn1'	117.3 (4)	P3—C62—H62b	109.0
C18'—C13'—Sn1'	122.5 (4)	H62a—C62—H62b	107.8
C15'—C14'—C13'	120.0	C64—C63—C62	115.5 (3)
C15'—C14'—H14'	120.0	C64—C63—H63a	108.4
C13'—C14'—H14'	120.0	C62—C63—H63a	108.4
C14'—C15'—C16'	120.0	C64—C63—H63b	108.4
C14'—C15'—H15'	120.0	C62—C63—H63b	108.4
C16'—C15'—H15'	120.0	H63a—C63—H63b	107.5
C17'—C16'—C15'	120.0	C63—C64—P4	115.2 (3)
C17'—C16'—H16'	120.0	C63—C64—H64a	108.5
C15'—C16'—H16'	120.0	P4—C64—H64a	108.5
C18'—C17'—C16'	120.0	C63—C64—H64b	108.5
C18'—C17'—H17'	120.0	P4—C64—H64b	108.5
C16'—C17'—H17'	120.0	H64a—C64—H64b	107.5
C17'—C18'—C13'	120.0	C66—C65—C70	120.0
C17'—C18'—H18'	120.0	C66—C65—P4	118.84 (15)
C13'—C18'—H18'	120.0	C70—C65—P4	121.16 (15)
O1'—C19'—O2'	126.1 (13)	C67—C66—C65	120.0
O1'—C19'—C20'	113.3 (10)	C67—C66—H66	120.0
O2'—C19'—C20'	120.6 (12)	C65—C66—H66	120.0
F2'—C20'—F1'	113.7 (11)	C66—C67—C68	120.0
F2'—C20'—F3'	110.7 (11)	C66—C67—H67	120.0
F1'—C20'—F3'	110.5 (9)	C68—C67—H67	120.0
F2'—C20'—C19'	107.3 (9)	C69—C68—C67	120.0
F1'—C20'—C19'	113.7 (9)	C69—C68—H68	120.0
F3'—C20'—C19'	100.1 (9)	C67—C68—H68	120.0
O4'—C21'—O3'	128.7 (8)	C68—C69—C70	120.0
O4'—C21'—C22'	117.4 (7)	C68—C69—H69	120.0
O3'—C21'—C22'	113.9 (7)	C70—C69—H69	120.0
F6'—C22'—F4'	106.8 (8)	C69—C70—C65	120.0
F6'—C22'—F5'	106.4 (7)	C69—C70—H70	120.0
F4'—C22'—F5'	106.3 (8)	C65—C70—H70	120.0
F6'—C22'—C21'	111.8 (7)	C72—C71—C76	120.0
F4'—C22'—C21'	111.8 (7)	C72—C71—P4	118.25 (15)
F5'—C22'—C21'	113.2 (7)	C76—C71—P4	121.49 (15)
P1—Ag1—P2	92.50 (4)	C73—C72—C71	120.0
P1—Ag1—P3	123.21 (4)	C73—C72—H72	120.0
P1—Ag1—P4	119.25 (3)	C71—C72—H72	120.0
P2—Ag1—P3	106.11 (3)	C74—C73—C72	120.0
P2—Ag1—P4	120.12 (4)	C74—C73—H73	120.0
P3—Ag1—P4	96.84 (3)	C72—C73—H73	120.0
C29—P1—C35	105.22 (17)	C73—C74—C75	120.0
C29—P1—C23	102.72 (14)	C73—C74—H74	120.0
C35—P1—C23	103.80 (17)	C75—C74—H74	120.0
C29—P1—Ag1	114.69 (10)	C76—C75—C74	120.0
C35—P1—Ag1	110.53 (15)	C76—C75—H75	120.0
C23—P1—Ag1	118.52 (10)	C74—C75—H75	120.0
C44—P2—C37	104.24 (19)	C75—C76—C71	120.0
C44—P2—C38	103.81 (18)	C75—C76—H76	120.0
C37—P2—C38	102.5 (2)	C71—C76—H76	120.0

C13—Sn1—O1—C19	55.4 (9)	P3—Ag1—P1—C29	167.69 (11)
C1—Sn1—O1—C19	−68.8 (8)	P2—Ag1—P1—C29	−81.18 (11)
C7—Sn1—O1—C19	175.7 (8)	P4—Ag1—P1—C35	164.43 (15)
O3—Sn1—O1—C19	174 (2)	P3—Ag1—P1—C35	−73.58 (15)
C13—Sn1—O3—C21	−63.8 (8)	P2—Ag1—P1—C35	37.55 (15)
C1—Sn1—O3—C21	61.1 (8)	P4—Ag1—P1—C23	−76.01 (11)
C7—Sn1—O3—C21	176.0 (8)	P3—Ag1—P1—C23	45.98 (12)
O1—Sn1—O3—C21	178 (2)	P2—Ag1—P1—C23	157.11 (11)
C13—Sn1—C1—C2	32.0 (6)	P1—Ag1—P2—C44	−157.92 (15)
C7—Sn1—C1—C2	−155.6 (4)	P4—Ag1—P2—C44	75.87 (15)
O3—Sn1—C1—C2	−65.8 (4)	P3—Ag1—P2—C44	−32.24 (15)
O1—Sn1—C1—C2	120.4 (4)	P1—Ag1—P2—C37	−37.56 (17)
C13—Sn1—C1—C6	−147.5 (5)	P4—Ag1—P2—C37	−163.77 (17)
C7—Sn1—C1—C6	24.9 (5)	P3—Ag1—P2—C37	88.12 (17)
O3—Sn1—C1—C6	114.7 (4)	P1—Ag1—P2—C38	77.19 (14)
O1—Sn1—C1—C6	−59.2 (4)	P4—Ag1—P2—C38	−49.02 (15)
C6—C1—C2—C3	0.0	P3—Ag1—P2—C38	−157.13 (14)
Sn1—C1—C2—C3	−179.5 (5)	P1—Ag1—P3—C56	80.92 (11)
Sn1—C1—C6—C5	179.5 (5)	P4—Ag1—P3—C56	−147.26 (11)
C13—Sn1—C7—C8	−125.1 (5)	P2—Ag1—P3—C56	−23.16 (11)
C1—Sn1—C7—C8	62.2 (4)	P1—Ag1—P3—C62	−162.52 (13)
O3—Sn1—C7—C8	−34.4 (4)	P4—Ag1—P3—C62	−30.70 (14)
O1—Sn1—C7—C8	145.8 (4)	P2—Ag1—P3—C62	93.40 (14)
C13—Sn1—C7—C12	55.3 (6)	P1—Ag1—P3—C50	−44.01 (12)
C1—Sn1—C7—C12	−117.4 (4)	P4—Ag1—P3—C50	87.80 (12)
O3—Sn1—C7—C12	146.0 (4)	P2—Ag1—P3—C50	−148.10 (12)
O1—Sn1—C7—C12	−33.8 (4)	P1—Ag1—P4—C71	−79.73 (12)
Sn1—C7—C8—C9	−179.6 (5)	P3—Ag1—P4—C71	145.89 (11)
Sn1—C7—C12—C11	179.6 (5)	P2—Ag1—P4—C71	32.77 (12)
C1—Sn1—C13—C14	149.0 (7)	P1—Ag1—P4—C64	160.33 (17)
C7—Sn1—C13—C14	−23.0 (9)	P3—Ag1—P4—C64	25.94 (17)
O3—Sn1—C13—C14	−110.5 (7)	P2—Ag1—P4—C64	−87.18 (17)
O1—Sn1—C13—C14	63.5 (8)	P1—Ag1—P4—C65	43.29 (11)
C1—Sn1—C13—C18	−30.8 (9)	P3—Ag1—P4—C65	−91.09 (11)
C7—Sn1—C13—C18	157.2 (7)	P2—Ag1—P4—C65	155.79 (10)
O3—Sn1—C13—C18	69.6 (8)	C29—P1—C23—C24	0.2 (2)
O1—Sn1—C13—C18	−116.4 (8)	C35—P1—C23—C24	−109.3 (2)
Sn1—C13—C14—C15	−179.9 (10)	Ag1—P1—C23—C24	127.75 (17)
Sn1—C13—C18—C17	179.9 (10)	C29—P1—C23—C28	−175.43 (17)
Sn1—O1—C19—O2	−6.0 (14)	C35—P1—C23—C28	75.1 (2)
Sn1—O1—C19—C20	171.7 (6)	Ag1—P1—C23—C28	−47.8 (2)
O2—C19—C20—F2	−10.9 (13)	P1—C23—C24—C25	−175.5 (2)
O1—C19—C20—F2	170.9 (12)	P1—C23—C28—C27	175.7 (2)
O2—C19—C20—F1	116.7 (10)	C35—P1—C29—C30	−161.1 (2)
O1—C19—C20—F1	−61.5 (11)	C23—P1—C29—C30	90.53 (19)
O2—C19—C20—F3	−126.3 (11)	Ag1—P1—C29—C30	−39.45 (18)
O1—C19—C20—F3	55.5 (12)	C35—P1—C29—C34	19.7 (3)
Sn1—O3—C21—O4	−13.9 (14)	C23—P1—C29—C34	−88.6 (2)
Sn1—O3—C21—C22	167.0 (6)	Ag1—P1—C29—C34	141.41 (16)
O4—C21—C22—F4	−174.3 (9)	P1—C29—C30—C31	−179.2 (2)
O3—C21—C22—F4	5.0 (11)	P1—C29—C34—C33	179.1 (2)
O4—C21—C22—F6	61.9 (10)	C29—P1—C35—C36	66.3 (4)
O3—C21—C22—F6	−118.8 (8)	C23—P1—C35—C36	173.8 (3)
O4—C21—C22—F5	−54.1 (10)	Ag1—P1—C35—C36	−58.1 (3)
O3—C21—C22—F5	125.2 (8)	P1—C35—C36—C37	78.1 (5)
C13'—Sn1'—O1'—C19'	149.2 (10)	C35—C36—C37—P2	−78.8 (5)
C7'—Sn1'—O1'—C19'	−96.1 (9)	C44—P2—C37—C36	−172.0 (3)
C1'—Sn1'—O1'—C19'	30.9 (10)	C38—P2—C37—C36	−64.1 (3)
O3'—Sn1'—O1'—C19'	42 (9)	Ag1—P2—C37—C36	58.5 (3)
C13'—Sn1'—O3'—C21'	44.2 (6)	C44—P2—C38—C39	46.4 (3)
C7'—Sn1'—O3'—C21'	−70.6 (6)	C37—P2—C38—C39	−61.9 (3)
C1'—Sn1'—O3'—C21'	162.5 (6)	Ag1—P2—C38—C39	179.32 (19)
O1'—Sn1'—O3'—C21'	152 (9)	C44—P2—C38—C43	−134.1 (2)
C13'—Sn1'—C1'—C2'	25.2 (9)	C37—P2—C38—C43	117.6 (3)
C7'—Sn1'—C1'—C2'	−151.8 (7)	Ag1—P2—C38—C43	−1.2 (3)
O3'—Sn1'—C1'—C2'	−62.2 (7)	P2—C38—C39—C40	179.5 (3)
O1'—Sn1'—C1'—C2'	117.4 (8)	P2—C38—C43—C42	−179.5 (3)
C13'—Sn1'—C1'—C5'	149.4 (7)	C37—P2—C44—C45	−9.5 (3)
C7'—Sn1'—C1'—C5'	−27.7 (9)	C38—P2—C44—C45	−116.5 (3)
O3'—Sn1'—C1'—C5'	61.9 (8)	Ag1—P2—C44—C45	113.5 (3)
O1'—Sn1'—C1'—C5'	−118.5 (8)	C37—P2—C44—C49	173.9 (3)
C5'—C1'—C2'—C3'	37.0 (10)	C38—P2—C44—C49	66.9 (3)
Sn1'—C1'—C2'—C3'	165.8 (7)	Ag1—P2—C44—C49	−63.2 (3)
C1'—C2'—C3'—C4'	−42.6 (12)	P2—C44—C45—C46	−176.6 (3)
C2'—C3'—C4'—C5'	31.0 (15)	P2—C44—C49—C48	176.7 (3)
C2'—C1'—C5'—C4'	−19.3 (13)	C56—P3—C50—C51	−152.98 (16)
Sn1'—C1'—C5'—C4'	−146.7 (9)	C62—P3—C50—C51	97.54 (19)
C3'—C4'—C5'—C1'	−6.9 (14)	Ag1—P3—C50—C51	−23.75 (19)
C13'—Sn1'—C7'—C8'	−114.2 (4)	C56—P3—C50—C55	29.21 (19)
C1'—Sn1'—C7'—C8'	62.9 (6)	C62—P3—C50—C55	−80.3 (2)
O3'—Sn1'—C7'—C8'	−22.4 (4)	Ag1—P3—C50—C55	158.45 (13)
O1'—Sn1'—C7'—C8'	156.2 (4)	P3—C50—C51—C52	−177.8 (2)
C13'—Sn1'—C7'—C12'	63.1 (5)	P3—C50—C55—C54	177.8 (2)
C1'—Sn1'—C7'—C12'	−119.8 (5)	C62—P3—C56—C57	2.4 (3)
O3'—Sn1'—C7'—C12'	154.9 (4)	C50—P3—C56—C57	−103.9 (2)
O1'—Sn1'—C7'—C12'	−26.5 (4)	Ag1—P3—C56—C57	120.09 (19)
Sn1'—C7'—C8'—C9'	177.3 (5)	C62—P3—C56—C61	−175.6 (2)
Sn1'—C7'—C12'—C11'	−177.3 (5)	C50—P3—C56—C61	78.1 (2)
C7'—Sn1'—C13'—C14'	−29.9 (5)	Ag1—P3—C56—C61	−57.94 (19)
C1'—Sn1'—C13'—C14'	152.7 (4)	P3—C56—C57—C58	−178.0 (3)
O3'—Sn1'—C13'—C14'	−123.4 (4)	P3—C56—C61—C60	178.1 (2)
O1'—Sn1'—C13'—C14'	58.6 (5)	C56—P3—C62—C63	179.9 (3)
C7'—Sn1'—C13'—C18'	145.1 (4)	C50—P3—C62—C63	−73.2 (3)
C1'—Sn1'—C13'—C18'	−32.3 (6)	Ag1—P3—C62—C63	58.9 (3)
O3'—Sn1'—C13'—C18'	51.6 (4)	P3—C62—C63—C64	−88.2 (4)
O1'—Sn1'—C13'—C18'	−126.5 (5)	C62—C63—C64—P4	79.8 (4)
Sn1'—C13'—C14'—C15'	175.1 (5)	C71—P4—C64—C63	−174.6 (3)
Sn1'—C13'—C18'—C17'	−174.8 (6)	C65—P4—C64—C63	76.8 (3)
Sn1'—O1'—C19'—O2'	19.5 (15)	Ag1—P4—C64—C63	−47.0 (3)
Sn1'—O1'—C19'—C20'	−163.7 (7)	C71—P4—C65—C66	128.54 (17)
O1'—C19'—C20'—F2'	86.6 (12)	C64—P4—C65—C66	−122.82 (19)
O2'—C19'—C20'—F2'	−96.4 (13)	Ag1—P4—C65—C66	−1.39 (18)
O1'—C19'—C20'—F1'	−40.1 (13)	C71—P4—C65—C70	−51.47 (19)
O2'—C19'—C20'—F1'	136.9 (12)	C64—P4—C65—C70	57.2 (2)
O1'—C19'—C20'—F3'	−157.9 (10)	Ag1—P4—C65—C70	178.59 (12)
O2'—C19'—C20'—F3'	19.1 (12)	P4—C65—C66—C67	180.0 (2)
Sn1'—O3'—C21'—O4'	32.3 (11)	P4—C65—C70—C69	−180.0 (2)
Sn1'—O3'—C21'—C22'	−148.0 (5)	C64—P4—C71—C72	52.0 (2)
O4'—C21'—C22'—F6'	−24.2 (10)	C65—P4—C71—C72	160.11 (16)
O3'—C21'—C22'—F6'	156.1 (8)	Ag1—P4—C71—C72	−71.57 (17)
O4'—C21'—C22'—F4'	−143.9 (9)	C64—P4—C71—C76	−133.8 (2)
O3'—C21'—C22'—F4'	36.4 (10)	C65—P4—C71—C76	−25.8 (2)
O4'—C21'—C22'—F5'	96.0 (9)	Ag1—P4—C71—C76	102.56 (16)
O3'—C21'—C22'—F5'	−83.7 (9)	P4—C71—C72—C73	174.2 (2)
P4—Ag1—P1—C29	45.70 (12)	P4—C71—C76—C75	−174.0 (2)

Follow Acta Cryst. E

Sign up for e-alerts

Follow Acta Cryst. on Twitter

Follow us on facebook

Sign up for RSS feeds

Search IUCr Journals		doi		Advanced search
Author		volume	page