The K_2nCoMo_2+nO_7+4n family of structures, with n = 2, 3 or 5

The compounds K₄CoMo₄O₁₅ (tetra­potassium cobalt tetra­molybdate), K₆CoMo₅O₁₉ (hexa­potassium cobalt pentamolybdate) and K₁₀CoMo₇O₂₇ (deca­potassium cobalt hepta­molybdate) belong to a series of compounds with closely related crystal structures. In K₄CoMo₄O₁₅, the Co atom and one of the two unique Mo atoms are at sites with threefold symmetry; two of the three unique K atoms lie at sites with symmetry. K₆CoMo₅O₁₉ crystallizes in a new monoclinic structure type. Each [CoO₆] octa­hedron is surrounded by one face-sharing [MoO₆] octa­hedron and six corner-sharing [MoO₄] tetra­hedra. All three compounds have this structural unit in common, but differ in the degree of connectivity between these units. They form layers in K₄CoMo₄O₁₅ and zigzag chains in K₆CoMo₅O₁₉, both by sharing [MoO₄] tetra­hedra. In K₁₀CoMo₇O₂₇, the structural units are isolated from each other.

S1. Comment

Quarternary compounds of alkali metals (A), 3 d transition metals (T), molybdenum and oxygen exist with a rich variety of crystal structures. The most common types are orthomolybdates A_xT_y(MoO₄)_z with networks of [TO₆] octahedra and [MoO₄] tetrahedra. In the course of a systematic investigation of crystalline phases in the Na–Fe–Mo–O system, four orthomolybdate structures, namely α-NaFe₂(MoO₄)₃, β-NaFe₂(MoO₄)₃, Na₃Fe₂(MoO₄)₃ and NaFe₄(MoO₄)₅, were established (Muessig et al., 2003) and only one phase, Na₃Fe₂Mo₅O₁₆, with both [MoO₄] tetrahedra and [MoO₆] octahedra (Bramnik et al., 2003). This study has now been extended to the K–Co–Mo–O system. To date, only one orthomolybdate, K₂Co₂(MoO₄)₃, has been reported for this system in full detail (Klevtsova et al., 1980). Furthermore, a second orthomolybdate, K₄Co(MoO₄)₃, is described as isostructural with K₄Mn(MoO₄)₃ (Solodovnikov et al., 1998). For two other compounds, K₄TMo₄O₁₅ and K₁₀TMo₇O₂₇, crystal structures with both [MoO₄] tetrahedra and [MoO₆] octahedra have been established for T = Mn from single-crystal X-ray diffraction and are reported as isostructural for T = Co, but based on powder diffraction data only (Solodovnikov, Klevtsova et al., 1997; Solodovnikov, Zolotova et al., 1997). In this contribution, we present structural data for K₄CoMo₄O₁₅ and for a new compound, K₆CoMo₅O₁₉, both from single-crystal X-ray diffraction studies. The crystal structures of K₄CoMo₄O₁₅, K₆CoMo₅O₁₉, and K₁₀CoMo₇O₂₇ are closely related to each other and can be considered as three members of one structure family of compounds K_2nCoMo_{2 + n}O_{7 + 4n}, with n = 2, 3 and 5.

The present results confirm the proposed structure model for K₄CoMo₄O₁₅ (Solodovnikov, Zolotova et al., 1997), while the crystal structure of the new compound, K₆CoMo₅O₁₉, has been solved and refined. It is now evident from its crystal structure that K₆CoMo₅O₁₉ fits into a series of structures of compounds with the general formula K_2nCoMo_{2 + n}O_{7 + 4n} with n = 3. Other representatives are known for n = 2 (K₄CoMo₄O₁₅; Solodovnikov, Zolotova et al., 1997) and n = 5 (K₁₀CoMo₇O₂₇; Solodovnikov, Klevtsova et al., 1997). Bond lengths and charge balances are in agreement with formal oxidation states of Co²⁺ and Mo⁶⁺ for all compounds. The structures have one motif in common: [CoO₆] and [MoO₆] octahedra share faces and, in addition, each [CoO₆] octahedron is further connected with six [MoO₄] tetrahedra by sharing corners. The difference between these structures is the connectivity of these CoO₆ octahedra with each other. If m is the number of neighbouring octahedral units linked by sharing of [MoO₄] tetrahedra, the equation m + n = 5 holds for all three representatives.

A comparison of the different connectivity schemes is shown in Fig. 1. In all structures, the orientations of the face-sharing [MoO₆] and [CoO₆] pairs of octahedra alternate. Note that in Fig. 1 the smaller [MoO₆] octahedra behind the [CoO₆] octahedra cannot be seen.

In terms of the structural systematics outlined here, dimers of face-sharing octahedra (m = 1) linked by [MoO₄] tetrahedra should be observed for the hypothetical compound K₈CoMo₆O₂₃ (n = 4). This proposed member of the structure family has not yet been found.

S2. Experimental

All samples were prepared from K₂MoO₄ (Aldrich, 98%), CoO (Alfa Aesar, 99.999%) and MoO₃ (Sigma–Aldrich, 99.5+%). Different ratios [Brief details?] were mixed in an agate mortar, pressed into pellets and placed in silica tubes, which were then sealed with an ambient air atmosphere inside. The samples were heated to temperatures between 773 and 923 K for 48 h and then cooled to room temperature. The samples thus obtained consist of several K–Mo–O and Co–Mo–O ternary and K–Co–Mo–O quarternary phases.

Computing details

For both compounds, data collection: CrysAlis CCD (Oxford Diffraction, 2003); cell refinement: CrysAlis RED (Oxford Diffraction, 2003); data reduction: CrysAlis RED; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg, 2001); software used to prepare material for publication: SHELXL97.

Figures

Fig. 1. Different connectivity schemes for the same basic structural units in K2nCoMo2 + nO7 + 4n compounds for n = 2, 3 and 5 (from top to bottom, respectively). [MoO4] and [CoO6/MoO6] polyhedra are shown in light grey, while the K^+ ions are shown as isolated black circles.

(I) tetrapotassium cobalt tetramolybdate

Crystal data

K4CoMo4O15	Dx = 3.738 Mg m^−3
Mr = 839.09	Mo Kα radiation, λ = 0.71073 Å
Trigonal, P3	Cell parameters from 2013 reflections
a = 10.292 (1) Å	θ = 2.3–30.1°
c = 8.1271 (8) Å	µ = 5.55 mm^−1
V = 745.53 (13) Å^3	T = 298 K
Z = 2	Prism, blue
F(000) = 782	0.04 × 0.04 × 0.03 mm

Data collection

Oxford Xcalibur with Sapphire CCD area detector diffractometer	1318 independent reflections
Radiation source: fine-focus sealed tube	1041 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.047
ω and ϕ scans	θmax = 30.0°, θmin = 3.4°
Absorption correction: numerical [CrysAlis RED (Oxford Diffraction Ltd, 2003); analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid (Reference?)].	h = −13→14
Tmin = 0.771, Tmax = 0.835	k = −14→14
3620 measured reflections	l = −10→11

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.045	w = 1/[σ^2(Fo^2) + (0.0329P)^2 + 3.9972P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.094	(Δ/σ)max < 0.001
S = 1.09	Δρmax = 1.72 e Å^−3
1318 reflections	Δρmin = −1.09 e Å^−3
75 parameters	Extinction correction: SHELXL97 (Sheldrick, 1997), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
0 restraints	Extinction coefficient: 0.0009 (4)

Special details

Experimental. Suitable single crystals for X-ray diffraction studies were selected under a light microscope and were fixed on glass fibres. Diffraction data were collected in ω- and ϕ-scan mode on the Xcalibur system from Oxford Diffraction, equipped with a Sapphire2 CCD detector and the ENHANCE X-ray source option.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Mo1	0.65875 (6)	−0.01422 (6)	0.63700 (6)	0.01147 (17)
Mo2	0.6667	0.3333	1.14197 (12)	0.0160 (3)
Co1	0.6667	0.3333	0.53410 (16)	0.0067 (3)
K1	0.3920 (2)	0.0873 (2)	0.8608 (2)	0.0274 (4)
K2	1.0000	0.0000	0.0000	0.0239 (9)
K3	0.0000	0.0000	0.5000	0.0295 (10)
O1	0.6376 (5)	0.1466 (5)	0.6613 (6)	0.0170 (10)
O2	0.7817 (6)	−0.0071 (6)	0.7902 (6)	0.0200 (11)
O3	0.4792 (5)	−0.1839 (5)	0.6590 (6)	0.0173 (10)
O4	0.7266 (6)	−0.0116 (5)	0.4418 (6)	0.0207 (11)
O5	0.5178 (6)	0.3414 (6)	1.0504 (6)	0.0267 (12)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Mo1	0.0100 (3)	0.0106 (3)	0.0134 (3)	0.0048 (2)	−0.0008 (2)	−0.0001 (2)
Mo2	0.0174 (4)	0.0174 (4)	0.0132 (5)	0.00868 (18)	0.000	0.000
Co1	0.0061 (4)	0.0061 (4)	0.0079 (7)	0.0030 (2)	0.000	0.000
K1	0.0333 (10)	0.0267 (10)	0.0264 (8)	0.0182 (8)	−0.0059 (7)	−0.0002 (7)
K2	0.0247 (13)	0.0247 (13)	0.0223 (19)	0.0124 (7)	0.000	0.000
K3	0.0140 (12)	0.0140 (12)	0.060 (3)	0.0070 (6)	0.000	0.000
O1	0.018 (3)	0.018 (3)	0.020 (2)	0.012 (2)	0.0035 (19)	0.0040 (19)
O2	0.021 (3)	0.018 (3)	0.022 (2)	0.012 (2)	−0.012 (2)	−0.004 (2)
O3	0.016 (3)	0.013 (2)	0.020 (2)	0.005 (2)	0.0001 (19)	0.0017 (19)
O4	0.021 (3)	0.021 (3)	0.020 (2)	0.011 (2)	0.001 (2)	−0.003 (2)
O5	0.027 (3)	0.033 (3)	0.022 (3)	0.017 (3)	−0.005 (2)	0.001 (2)

Geometric parameters (Å, º)

Mo1—O4	1.728 (5)	K1—Mo1^iv	3.5124 (18)
Mo1—O2	1.751 (4)	K1—K2^xi	3.8394 (19)
Mo1—O1	1.785 (5)	K2—O2^xii	2.791 (4)
Mo1—O3	1.808 (5)	K2—O2^xiii	2.791 (4)
Mo1—K1^i	3.5124 (18)	K2—O2^xiv	2.791 (4)
Mo1—K3^ii	3.6169 (7)	K2—O2^xv	2.791 (4)
Mo1—K1	3.8477 (19)	K2—O2^viii	2.791 (4)
Mo1—K1^iii	4.1007 (18)	K2—O2^xvi	2.791 (4)
Mo2—O5^i	1.743 (5)	K2—K1^xvii	3.8394 (19)
Mo2—O5^iv	1.743 (5)	K2—K1^xviii	3.8394 (19)
Mo2—O5	1.743 (5)	K2—K1^xix	3.8394 (19)
Mo2—O3^v	2.220 (5)	K2—K1^xx	3.8394 (19)
Mo2—O3^vi	2.220 (5)	K2—K1^iii	3.8394 (19)
Mo2—O3^vii	2.220 (5)	K2—K1^xxi	3.8394 (19)
Mo2—K1	3.5305 (19)	K3—O4^xxii	2.797 (5)
Mo2—K1^i	3.5305 (19)	K3—O4^iii	2.797 (5)
Mo2—K1^iv	3.5305 (19)	K3—O4^iv	2.797 (5)
Mo2—K1^vi	4.0610 (18)	K3—O4^xxiii	2.797 (5)
Mo2—K1^v	4.0610 (18)	K3—O4^xxiv	2.797 (5)
Mo2—K1^vii	4.0610 (18)	K3—O4^xxv	2.797 (5)
Co1—O1	2.068 (5)	K3—O2^xxii	3.233 (5)
Co1—O1^i	2.068 (5)	K3—O2^iv	3.233 (5)
Co1—O1^iv	2.068 (5)	K3—O2^xxiii	3.233 (5)
Co1—O3^iii	2.185 (5)	K3—O2^iii	3.233 (5)
Co1—O3^viii	2.185 (5)	K3—O2^xxiv	3.233 (5)
Co1—O3^ix	2.185 (5)	K3—O2^xxv	3.233 (5)
Co1—K1^i	3.781 (2)	O1—K1^i	2.947 (5)
Co1—K1	3.781 (2)	O2—K2^xxvi	2.791 (4)
Co1—K1^iv	3.781 (2)	O2—K1^i	2.850 (5)
K1—O5^x	2.596 (6)	O2—K1^vi	3.232 (5)
K1—O4^iii	2.682 (5)	O2—K3^ii	3.233 (5)
K1—O5	2.739 (6)	O3—Co1^iii	2.185 (5)
K1—O1	2.801 (5)	O3—Mo2^vi	2.220 (5)
K1—O2^iv	2.850 (5)	O4—K1^iii	2.682 (5)
K1—O5^i	2.868 (6)	O4—K3^ii	2.797 (5)
K1—O1^iv	2.947 (5)	O5—K1^vii	2.596 (6)
K1—O2^vi	3.232 (5)	O5—K1^iv	2.868 (6)
O4—Mo1—O2	112.0 (2)	O1—K1—Co1	32.51 (10)
O4—Mo1—O1	108.8 (2)	O2^iv—K1—Co1	89.33 (10)
O2—Mo1—O1	107.7 (2)	O5^i—K1—Co1	83.57 (12)
O4—Mo1—O3	108.4 (2)	O1^iv—K1—Co1	32.94 (9)
O2—Mo1—O3	109.8 (2)	O2^vi—K1—Co1	156.95 (11)
O1—Mo1—O3	110.2 (2)	Mo1^iv—K1—Co1	59.65 (3)
O4—Mo1—K1^i	110.78 (17)	Mo2—K1—Co1	84.94 (4)
O2—Mo1—K1^i	53.71 (16)	O5^x—K1—K2^xi	92.03 (13)
O1—Mo1—K1^i	56.96 (16)	O4^iii—K1—K2^xi	85.97 (12)
O3—Mo1—K1^i	140.81 (15)	O5—K1—K2^xi	89.84 (12)
O4—Mo1—K3^ii	48.72 (17)	O1—K1—K2^xi	161.74 (11)
O2—Mo1—K3^ii	63.27 (17)	O2^iv—K1—K2^xi	46.48 (9)
O1—Mo1—K3^ii	124.25 (15)	O5^i—K1—K2^xi	129.94 (11)
O3—Mo1—K3^ii	124.90 (15)	O1^iv—K1—K2^xi	105.28 (10)
K1^i—Mo1—K3^ii	82.41 (3)	O2^vi—K1—K2^xi	45.50 (8)
O4—Mo1—K1	140.10 (18)	Mo1^iv—K1—K2^xi	75.98 (3)
O2—Mo1—K1	104.56 (17)	Mo2—K1—K2^xi	110.37 (4)
O1—Mo1—K1	42.39 (15)	Co1—K1—K2^xi	135.22 (5)
O3—Mo1—K1	72.08 (16)	O2^xii—K2—O2^xiii	93.40 (15)
K1^i—Mo1—K1	78.46 (6)	O2^xii—K2—O2^xiv	86.60 (15)
K3^ii—Mo1—K1	160.86 (3)	O2^xiii—K2—O2^xiv	180.00 (19)
O4—Mo1—K1^iii	27.19 (17)	O2^xii—K2—O2^xv	93.40 (15)
O2—Mo1—K1^iii	137.10 (17)	O2^xiii—K2—O2^xv	86.60 (15)
O1—Mo1—K1^iii	102.47 (15)	O2^xiv—K2—O2^xv	93.40 (15)
O3—Mo1—K1^iii	86.87 (15)	O2^xii—K2—O2^viii	180.00 (15)
K1^i—Mo1—K1^iii	130.50 (4)	O2^xiii—K2—O2^viii	86.60 (15)
K3^ii—Mo1—K1^iii	74.68 (3)	O2^xiv—K2—O2^viii	93.40 (15)
K1—Mo1—K1^iii	118.26 (3)	O2^xv—K2—O2^viii	86.60 (15)
O5^i—Mo2—O5^iv	103.1 (2)	O2^xii—K2—O2^xvi	86.60 (15)
O5^i—Mo2—O5	103.1 (2)	O2^xiii—K2—O2^xvi	93.40 (15)
O5^iv—Mo2—O5	103.1 (2)	O2^xiv—K2—O2^xvi	86.60 (15)
O5^i—Mo2—O3^v	92.2 (2)	O2^xv—K2—O2^xvi	180.0
O5^iv—Mo2—O3^v	88.1 (2)	O2^viii—K2—O2^xvi	93.40 (15)
O5—Mo2—O3^v	158.3 (2)	O2^xii—K2—K1^xvii	47.75 (10)
O5^i—Mo2—O3^vi	88.1 (2)	O2^xiii—K2—K1^xvii	115.55 (10)
O5^iv—Mo2—O3^vi	158.3 (2)	O2^xiv—K2—K1^xvii	64.45 (10)
O5—Mo2—O3^vi	92.2 (2)	O2^xv—K2—K1^xvii	55.67 (11)
O3^v—Mo2—O3^vi	72.74 (19)	O2^viii—K2—K1^xvii	132.25 (10)
O5^i—Mo2—O3^vii	158.3 (2)	O2^xvi—K2—K1^xvii	124.33 (11)
O5^iv—Mo2—O3^vii	92.2 (2)	O2^xii—K2—K1^xviii	132.25 (10)
O5—Mo2—O3^vii	88.1 (2)	O2^xiii—K2—K1^xviii	64.45 (10)
O3^v—Mo2—O3^vii	72.74 (19)	O2^xiv—K2—K1^xviii	115.55 (10)
O3^vi—Mo2—O3^vii	72.74 (19)	O2^xv—K2—K1^xviii	124.33 (11)
O5^i—Mo2—K1	53.74 (18)	O2^viii—K2—K1^xviii	47.75 (10)
O5^iv—Mo2—K1	114.34 (18)	O2^xvi—K2—K1^xviii	55.67 (11)
O5—Mo2—K1	49.47 (18)	K1^xvii—K2—K1^xviii	180.00 (5)
O3^v—Mo2—K1	141.54 (13)	O2^xii—K2—K1^xix	55.67 (11)
O3^vi—Mo2—K1	87.31 (13)	O2^xiii—K2—K1^xix	47.75 (10)
O3^vii—Mo2—K1	132.75 (13)	O2^xiv—K2—K1^xix	132.25 (10)
O5^i—Mo2—K1^i	49.47 (18)	O2^xv—K2—K1^xix	64.45 (10)
O5^iv—Mo2—K1^i	53.74 (18)	O2^viii—K2—K1^xix	124.33 (11)
O5—Mo2—K1^i	114.34 (18)	O2^xvi—K2—K1^xix	115.55 (10)
O3^v—Mo2—K1^i	87.31 (13)	K1^xvii—K2—K1^xix	68.29 (2)
O3^vi—Mo2—K1^i	132.75 (13)	K1^xviii—K2—K1^xix	111.71 (2)
O3^vii—Mo2—K1^i	141.54 (13)	O2^xii—K2—K1^xx	64.45 (10)
K1—Mo2—K1^i	82.63 (5)	O2^xiii—K2—K1^xx	55.67 (11)
O5^i—Mo2—K1^iv	114.34 (18)	O2^xiv—K2—K1^xx	124.33 (11)
O5^iv—Mo2—K1^iv	49.47 (18)	O2^xv—K2—K1^xx	132.25 (10)
O5—Mo2—K1^iv	53.74 (18)	O2^viii—K2—K1^xx	115.55 (10)
O3^v—Mo2—K1^iv	132.75 (13)	O2^xvi—K2—K1^xx	47.75 (10)
O3^vi—Mo2—K1^iv	141.54 (13)	K1^xvii—K2—K1^xx	111.71 (2)
O3^vii—Mo2—K1^iv	87.31 (13)	K1^xviii—K2—K1^xx	68.29 (2)
K1—Mo2—K1^iv	82.63 (5)	K1^xix—K2—K1^xx	68.29 (2)
K1^i—Mo2—K1^iv	82.63 (5)	O2^xii—K2—K1^iii	115.55 (10)
O5^i—Mo2—K1^vi	25.38 (17)	O2^xiii—K2—K1^iii	124.33 (11)
O5^iv—Mo2—K1^vi	120.88 (18)	O2^xiv—K2—K1^iii	55.67 (11)
O5—Mo2—K1^vi	112.52 (18)	O2^xv—K2—K1^iii	47.75 (10)
O3^v—Mo2—K1^vi	75.76 (13)	O2^viii—K2—K1^iii	64.45 (10)
O3^vi—Mo2—K1^vi	64.98 (13)	O2^xvi—K2—K1^iii	132.25 (10)
O3^vii—Mo2—K1^vi	132.93 (13)	K1^xvii—K2—K1^iii	68.29 (2)
K1—Mo2—K1^vi	65.97 (4)	K1^xviii—K2—K1^iii	111.71 (2)
K1^i—Mo2—K1^vi	68.78 (5)	K1^xix—K2—K1^iii	111.71 (2)
K1^iv—Mo2—K1^vi	139.31 (3)	K1^xx—K2—K1^iii	180.0
O5^i—Mo2—K1^v	112.52 (19)	O2^xii—K2—K1^xxi	124.33 (11)
O5^iv—Mo2—K1^v	25.38 (17)	O2^xiii—K2—K1^xxi	132.25 (10)
O5—Mo2—K1^v	120.88 (19)	O2^xiv—K2—K1^xxi	47.75 (10)
O3^v—Mo2—K1^v	64.98 (13)	O2^xv—K2—K1^xxi	115.55 (10)
O3^vi—Mo2—K1^v	132.93 (13)	O2^viii—K2—K1^xxi	55.67 (11)
O3^vii—Mo2—K1^v	75.76 (13)	O2^xvi—K2—K1^xxi	64.45 (10)
K1—Mo2—K1^v	139.31 (3)	K1^xvii—K2—K1^xxi	111.71 (2)
K1^i—Mo2—K1^v	65.97 (4)	K1^xviii—K2—K1^xxi	68.29 (2)
K1^iv—Mo2—K1^v	68.78 (5)	K1^xix—K2—K1^xxi	180.00 (5)
K1^vi—Mo2—K1^v	119.997 (1)	K1^xx—K2—K1^xxi	111.71 (2)
O5^i—Mo2—K1^vii	120.88 (18)	K1^iii—K2—K1^xxi	68.29 (2)
O5^iv—Mo2—K1^vii	112.52 (18)	O4^xxii—K3—O4^iii	117.20 (5)
O5—Mo2—K1^vii	25.38 (17)	O4^xxii—K3—O4^iv	180.0 (3)
O3^v—Mo2—K1^vii	132.93 (13)	O4^iii—K3—O4^iv	62.80 (5)
O3^vi—Mo2—K1^vii	75.76 (13)	O4^xxii—K3—O4^xxiii	62.80 (5)
O3^vii—Mo2—K1^vii	64.98 (13)	O4^iii—K3—O4^xxiii	62.80 (5)
K1—Mo2—K1^vii	68.78 (5)	O4^iv—K3—O4^xxiii	117.20 (5)
K1^i—Mo2—K1^vii	139.31 (3)	O4^xxii—K3—O4^xxiv	62.80 (5)
K1^iv—Mo2—K1^vii	65.97 (4)	O4^iii—K3—O4^xxiv	180.0
K1^vi—Mo2—K1^vii	119.997 (1)	O4^iv—K3—O4^xxiv	117.20 (5)
K1^v—Mo2—K1^vii	119.997 (1)	O4^xxiii—K3—O4^xxiv	117.20 (5)
O1—Co1—O1^i	97.19 (17)	O4^xxii—K3—O4^xxv	117.20 (5)
O1—Co1—O1^iv	97.19 (17)	O4^iii—K3—O4^xxv	117.20 (5)
O1^i—Co1—O1^iv	97.19 (17)	O4^iv—K3—O4^xxv	62.80 (5)
O1—Co1—O3^iii	88.61 (18)	O4^xxiii—K3—O4^xxv	180.000 (1)
O1^i—Co1—O3^iii	162.44 (19)	O4^xxiv—K3—O4^xxv	62.80 (5)
O1^iv—Co1—O3^iii	98.52 (18)	O4^xxii—K3—O2^xxii	56.60 (13)
O1—Co1—O3^viii	98.52 (17)	O4^iii—K3—O2^xxii	117.74 (13)
O1^i—Co1—O3^viii	88.61 (18)	O4^iv—K3—O2^xxii	123.40 (13)
O1^iv—Co1—O3^viii	162.44 (19)	O4^xxiii—K3—O2^xxii	62.91 (13)
O3^iii—Co1—O3^viii	74.10 (19)	O4^xxiv—K3—O2^xxii	62.26 (13)
O1—Co1—O3^ix	162.44 (19)	O4^xxv—K3—O2^xxii	117.09 (13)
O1^i—Co1—O3^ix	98.52 (18)	O4^xxii—K3—O2^iv	123.40 (13)
O1^iv—Co1—O3^ix	88.61 (18)	O4^iii—K3—O2^iv	62.26 (13)
O3^iii—Co1—O3^ix	74.10 (19)	O4^iv—K3—O2^iv	56.60 (13)
O3^viii—Co1—O3^ix	74.10 (19)	O4^xxiii—K3—O2^iv	117.09 (13)
O1—Co1—K1^i	50.79 (14)	O4^xxiv—K3—O2^iv	117.74 (13)
O1^i—Co1—K1^i	46.70 (13)	O4^xxv—K3—O2^iv	62.91 (13)
O1^iv—Co1—K1^i	105.35 (14)	O2^xxii—K3—O2^iv	180.0
O3^iii—Co1—K1^i	134.51 (13)	O4^xxii—K3—O2^xxiii	62.26 (13)
O3^viii—Co1—K1^i	90.72 (12)	O4^iii—K3—O2^xxiii	62.91 (13)
O3^ix—Co1—K1^i	143.12 (13)	O4^iv—K3—O2^xxiii	117.74 (13)
O1—Co1—K1	46.70 (13)	O4^xxiii—K3—O2^xxiii	56.60 (12)
O1^i—Co1—K1	105.35 (14)	O4^xxiv—K3—O2^xxiii	117.09 (13)
O1^iv—Co1—K1	50.79 (14)	O4^xxv—K3—O2^xxiii	123.40 (12)
O3^iii—Co1—K1	90.72 (12)	O2^xxii—K3—O2^xxiii	107.38 (12)
O3^viii—Co1—K1	143.12 (13)	O2^iv—K3—O2^xxiii	72.62 (12)
O3^ix—Co1—K1	134.51 (13)	O4^xxii—K3—O2^iii	117.09 (13)
K1^i—Co1—K1	76.12 (5)	O4^iii—K3—O2^iii	56.60 (12)
O1—Co1—K1^iv	105.35 (14)	O4^iv—K3—O2^iii	62.91 (13)
O1^i—Co1—K1^iv	50.79 (14)	O4^xxiii—K3—O2^iii	62.26 (13)
O1^iv—Co1—K1^iv	46.70 (13)	O4^xxiv—K3—O2^iii	123.40 (12)
O3^iii—Co1—K1^iv	143.12 (13)	O4^xxv—K3—O2^iii	117.74 (13)
O3^viii—Co1—K1^iv	134.51 (13)	O2^xxii—K3—O2^iii	72.62 (12)
O3^ix—Co1—K1^iv	90.72 (12)	O2^iv—K3—O2^iii	107.38 (12)
K1^i—Co1—K1^iv	76.12 (5)	O2^xxiii—K3—O2^iii	107.38 (12)
K1—Co1—K1^iv	76.12 (5)	O4^xxii—K3—O2^xxiv	62.91 (13)
O5^x—K1—O4^iii	97.29 (16)	O4^iii—K3—O2^xxiv	123.40 (12)
O5^x—K1—O5	126.42 (7)	O4^iv—K3—O2^xxiv	117.09 (13)
O4^iii—K1—O5	136.23 (16)	O4^xxiii—K3—O2^xxiv	117.74 (13)
O5^x—K1—O1	94.37 (16)	O4^xxiv—K3—O2^xxiv	56.60 (12)
O4^iii—K1—O1	76.27 (15)	O4^xxv—K3—O2^xxiv	62.26 (13)
O5—K1—O1	99.99 (16)	O2^xxii—K3—O2^xxiv	107.38 (12)
O5^x—K1—O2^iv	135.49 (18)	O2^iv—K3—O2^xxiv	72.62 (12)
O4^iii—K1—O2^iv	69.07 (15)	O2^xxiii—K3—O2^xxiv	72.62 (12)
O5—K1—O2^iv	76.70 (15)	O2^iii—K3—O2^xxiv	180.00 (15)
O1—K1—O2^iv	120.81 (14)	O4^xxii—K3—O2^xxv	117.74 (13)
O5^x—K1—O5^i	81.06 (18)	O4^iii—K3—O2^xxv	117.09 (13)
O4^iii—K1—O5^i	144.00 (16)	O4^iv—K3—O2^xxv	62.26 (13)
O5—K1—O5^i	58.2 (2)	O4^xxiii—K3—O2^xxv	123.40 (12)
O1—K1—O5^i	68.08 (15)	O4^xxiv—K3—O2^xxv	62.91 (13)
O2^iv—K1—O5^i	134.73 (17)	O4^xxv—K3—O2^xxv	56.60 (12)
O5^x—K1—O1^iv	158.28 (17)	O2^xxii—K3—O2^xxv	72.62 (12)
O4^iii—K1—O1^iv	71.50 (14)	O2^iv—K3—O2^xxv	107.38 (12)
O5—K1—O1^iv	67.73 (15)	O2^xxiii—K3—O2^xxv	180.0
O1—K1—O1^iv	65.27 (19)	O2^iii—K3—O2^xxv	72.62 (12)
O2^iv—K1—O1^iv	58.97 (13)	O2^xxiv—K3—O2^xxv	107.38 (12)
O5^i—K1—O1^iv	97.05 (15)	Mo1—O1—Co1	141.1 (3)
O5^x—K1—O2^vi	72.13 (15)	Mo1—O1—K1	112.2 (2)
O4^iii—K1—O2^vi	128.09 (15)	Co1—O1—K1	100.80 (18)
O5—K1—O2^vi	71.78 (15)	Mo1—O1—K1^i	92.53 (18)
O1—K1—O2^vi	152.54 (14)	Co1—O1—K1^i	96.26 (18)
O2^iv—K1—O2^vi	83.59 (16)	K1—O1—K1^i	108.35 (16)
O5^i—K1—O2^vi	85.93 (14)	Mo1—O2—K2^xxvi	172.2 (3)
O1^iv—K1—O2^vi	129.49 (14)	Mo1—O2—K1^i	96.6 (2)
O5^x—K1—Mo1^iv	155.27 (13)	K2^xxvi—O2—K1^i	85.77 (13)
O4^iii—K1—Mo1^iv	60.85 (11)	Mo1—O2—K1^vi	108.5 (2)
O5—K1—Mo1^iv	75.85 (11)	K2^xxvi—O2—K1^vi	78.83 (12)
O1—K1—Mo1^iv	91.43 (11)	K1^i—O2—K1^vi	90.04 (13)
O2^iv—K1—Mo1^iv	29.69 (9)	Mo1—O2—K3^ii	87.80 (18)
O5^i—K1—Mo1^iv	123.24 (12)	K2^xxvi—O2—K3^ii	84.50 (13)
O1^iv—K1—Mo1^iv	30.51 (9)	K1^i—O2—K3^ii	100.91 (16)
O2^vi—K1—Mo1^iv	110.94 (10)	K1^vi—O2—K3^ii	159.32 (17)
O5^x—K1—Mo2	103.88 (13)	Mo1—O3—Co1^iii	128.3 (2)
O4^iii—K1—Mo2	152.45 (13)	Mo1—O3—Mo2^vi	138.7 (2)
O5—K1—Mo2	28.92 (11)	Co1^iii—O3—Mo2^vi	92.70 (18)
O1—K1—Mo2	84.65 (11)	Mo1—O4—K1^iii	135.7 (3)
O2^iv—K1—Mo2	105.61 (12)	Mo1—O4—K3^ii	103.6 (2)
O5^i—K1—Mo2	29.35 (11)	K1^iii—O4—K3^ii	118.01 (18)
O1^iv—K1—Mo2	82.59 (10)	Mo2—O5—K1^vii	137.9 (3)
O2^vi—K1—Mo2	75.98 (9)	Mo2—O5—K1	101.6 (2)
Mo1^iv—K1—Mo2	100.58 (5)	K1^vii—O5—K1	107.7 (2)
O5^x—K1—Co1	125.96 (13)	Mo2—O5—K1^iv	96.9 (2)
O4^iii—K1—Co1	68.28 (11)	K1^vii—O5—K1^iv	98.94 (18)
O5—K1—Co1	85.26 (12)	K1—O5—K1^iv	112.47 (18)
O5^i—Mo2—K1—O5^x	40.0 (3)	O3^viii—Co1—K1—Mo2	111.5 (2)
O5^iv—Mo2—K1—O5^x	128.6 (3)	O3^ix—Co1—K1—Mo2	−116.43 (18)
O5—Mo2—K1—O5^x	−144.8 (3)	K1^i—Co1—K1—Mo2	39.43 (5)
O3^v—Mo2—K1—O5^x	7.9 (2)	K1^iv—Co1—K1—Mo2	−39.43 (5)
O3^vi—Mo2—K1—O5^x	−49.64 (18)	O1—Co1—K1—K2^xi	−158.0 (2)
O3^vii—Mo2—K1—O5^x	−113.0 (2)	O1^i—Co1—K1—K2^xi	116.59 (15)
K1^i—Mo2—K1—O5^x	84.09 (14)	O1^iv—Co1—K1—K2^xi	29.83 (17)
K1^iv—Mo2—K1—O5^x	167.57 (13)	O3^iii—Co1—K1—K2^xi	−70.60 (14)
K1^vi—Mo2—K1—O5^x	14.09 (12)	O3^viii—Co1—K1—K2^xi	−134.5 (2)
K1^v—Mo2—K1—O5^x	122.81 (12)	O3^ix—Co1—K1—K2^xi	−2.4 (2)
K1^vii—Mo2—K1—O5^x	−125.40 (13)	K1^i—Co1—K1—K2^xi	153.43 (7)
O5^i—Mo2—K1—O4^iii	−99.2 (3)	K1^iv—Co1—K1—K2^xi	74.58 (9)
O5^iv—Mo2—K1—O4^iii	−10.5 (3)	O4—Mo1—O1—Co1	0.2 (5)
O5—Mo2—K1—O4^iii	76.0 (3)	O2—Mo1—O1—Co1	121.8 (4)
O3^v—Mo2—K1—O4^iii	−131.2 (3)	O3—Mo1—O1—Co1	−118.5 (4)
O3^vi—Mo2—K1—O4^iii	171.2 (3)	K1^i—Mo1—O1—Co1	103.2 (4)
O3^vii—Mo2—K1—O4^iii	107.8 (3)	K3^ii—Mo1—O1—Co1	52.5 (5)
K1^i—Mo2—K1—O4^iii	−55.1 (3)	K1—Mo1—O1—Co1	−145.8 (6)
K1^iv—Mo2—K1—O4^iii	28.4 (3)	K1^iii—Mo1—O1—Co1	−27.3 (4)
K1^vi—Mo2—K1—O4^iii	−125.1 (3)	O4—Mo1—O1—K1	146.0 (2)
K1^v—Mo2—K1—O4^iii	−16.3 (3)	O2—Mo1—O1—K1	−92.4 (3)
K1^vii—Mo2—K1—O4^iii	95.4 (3)	O3—Mo1—O1—K1	27.2 (3)
O5^i—Mo2—K1—O5	−175.2 (4)	K1^i—Mo1—O1—K1	−111.0 (2)
O5^iv—Mo2—K1—O5	−86.6 (2)	K3^ii—Mo1—O1—K1	−161.69 (9)
O3^v—Mo2—K1—O5	152.7 (3)	K1^iii—Mo1—O1—K1	118.49 (16)
O3^vi—Mo2—K1—O5	95.2 (3)	O4—Mo1—O1—K1^i	−103.0 (2)
O3^vii—Mo2—K1—O5	31.8 (3)	O2—Mo1—O1—K1^i	18.6 (2)
K1^i—Mo2—K1—O5	−131.1 (2)	O3—Mo1—O1—K1^i	138.24 (17)
K1^iv—Mo2—K1—O5	−47.6 (2)	K3^ii—Mo1—O1—K1^i	−50.69 (18)
K1^vi—Mo2—K1—O5	158.9 (2)	K1—Mo1—O1—K1^i	111.0 (2)
K1^v—Mo2—K1—O5	−92.4 (2)	K1^iii—Mo1—O1—K1^i	−130.51 (9)
K1^vii—Mo2—K1—O5	19.4 (2)	O1^i—Co1—O1—Mo1	−107.7 (5)
O5^i—Mo2—K1—O1	−53.2 (2)	O1^iv—Co1—O1—Mo1	154.1 (5)
O5^iv—Mo2—K1—O1	35.4 (2)	O3^iii—Co1—O1—Mo1	55.7 (4)
O5—Mo2—K1—O1	122.0 (2)	O3^viii—Co1—O1—Mo1	−18.0 (5)
O3^v—Mo2—K1—O1	−85.3 (2)	O3^ix—Co1—O1—Mo1	45.6 (8)
O3^vi—Mo2—K1—O1	−142.83 (16)	K1^i—Co1—O1—Mo1	−101.9 (4)
O3^vii—Mo2—K1—O1	153.78 (19)	K1—Co1—O1—Mo1	148.0 (5)
K1^i—Mo2—K1—O1	−9.09 (10)	K1^iv—Co1—O1—Mo1	−158.9 (4)
K1^iv—Mo2—K1—O1	74.38 (10)	O1^i—Co1—O1—K1	104.4 (2)
K1^vi—Mo2—K1—O1	−79.10 (11)	O1^iv—Co1—O1—K1	6.1 (2)
K1^v—Mo2—K1—O1	29.62 (13)	O3^iii—Co1—O1—K1	−92.29 (18)
K1^vii—Mo2—K1—O1	141.41 (11)	O3^viii—Co1—O1—K1	−165.99 (16)
O5^i—Mo2—K1—O2^iv	−173.7 (2)	O3^ix—Co1—O1—K1	−102.4 (6)
O5^iv—Mo2—K1—O2^iv	−85.1 (2)	K1^i—Co1—O1—K1	110.1 (2)
O5—Mo2—K1—O2^iv	1.5 (2)	K1^iv—Co1—O1—K1	53.10 (16)
O3^v—Mo2—K1—O2^iv	154.2 (2)	O1^i—Co1—O1—K1^i	−5.7 (2)
O3^vi—Mo2—K1—O2^iv	96.65 (16)	O1^iv—Co1—O1—K1^i	−104.0 (2)
O3^vii—Mo2—K1—O2^iv	33.3 (2)	O3^iii—Co1—O1—K1^i	157.62 (16)
K1^i—Mo2—K1—O2^iv	−129.62 (10)	O3^viii—Co1—O1—K1^i	83.92 (17)
K1^iv—Mo2—K1—O2^iv	−46.15 (11)	O3^ix—Co1—O1—K1^i	147.5 (5)
K1^vi—Mo2—K1—O2^iv	160.37 (13)	K1—Co1—O1—K1^i	−110.1 (2)
K1^v—Mo2—K1—O2^iv	−90.90 (13)	K1^iv—Co1—O1—K1^i	−56.98 (13)
K1^vii—Mo2—K1—O2^iv	20.88 (10)	O5^x—K1—O1—Mo1	8.5 (3)
O5^iv—Mo2—K1—O5^i	88.6 (2)	O4^iii—K1—O1—Mo1	−87.9 (2)
O5—Mo2—K1—O5^i	175.2 (4)	O5—K1—O1—Mo1	136.7 (2)
O3^v—Mo2—K1—O5^i	−32.1 (3)	O2^iv—K1—O1—Mo1	−142.9 (2)
O3^vi—Mo2—K1—O5^i	−89.6 (2)	O5^i—K1—O1—Mo1	87.1 (2)
O3^vii—Mo2—K1—O5^i	−153.0 (3)	O1^iv—K1—O1—Mo1	−163.6 (2)
K1^i—Mo2—K1—O5^i	44.1 (2)	O2^vi—K1—O1—Mo1	67.2 (4)
K1^iv—Mo2—K1—O5^i	127.6 (2)	Mo1^iv—K1—O1—Mo1	−147.4 (2)
K1^vi—Mo2—K1—O5^i	−25.9 (2)	Mo2—K1—O1—Mo1	112.1 (2)
K1^v—Mo2—K1—O5^i	82.8 (2)	Co1—K1—O1—Mo1	−158.9 (4)
K1^vii—Mo2—K1—O5^i	−165.4 (2)	K2^xi—K1—O1—Mo1	−101.6 (4)
O5^i—Mo2—K1—O1^iv	−118.9 (2)	O5^x—K1—O1—Co1	167.46 (19)
O5^iv—Mo2—K1—O1^iv	−30.3 (2)	O4^iii—K1—O1—Co1	71.01 (19)
O5—Mo2—K1—O1^iv	56.3 (2)	O5—K1—O1—Co1	−64.4 (2)
O3^v—Mo2—K1—O1^iv	−151.0 (2)	O2^iv—K1—O1—Co1	16.0 (3)
O3^vi—Mo2—K1—O1^iv	151.47 (16)	O5^i—K1—O1—Co1	−114.0 (2)
O3^vii—Mo2—K1—O1^iv	88.1 (2)	O1^iv—K1—O1—Co1	−4.69 (17)
K1^i—Mo2—K1—O1^iv	−74.80 (9)	O2^vi—K1—O1—Co1	−133.9 (3)
K1^iv—Mo2—K1—O1^iv	8.68 (10)	Mo1^iv—K1—O1—Co1	11.51 (16)
K1^vi—Mo2—K1—O1^iv	−144.81 (12)	Mo2—K1—O1—Co1	−88.98 (16)
K1^v—Mo2—K1—O1^iv	−36.08 (13)	K2^xi—K1—O1—Co1	57.3 (5)
K1^vii—Mo2—K1—O1^iv	75.70 (10)	O5^x—K1—O1—K1^i	−92.16 (18)
O5^i—Mo2—K1—O2^vi	107.2 (2)	O4^iii—K1—O1—K1^i	171.39 (19)
O5^iv—Mo2—K1—O2^vi	−164.2 (2)	O5—K1—O1—K1^i	36.02 (19)
O5—Mo2—K1—O2^vi	−77.6 (2)	O2^iv—K1—O1—K1^i	116.41 (18)
O3^v—Mo2—K1—O2^vi	75.1 (2)	O5^i—K1—O1—K1^i	−13.62 (15)
O3^vi—Mo2—K1—O2^vi	17.56 (15)	O1^iv—K1—O1—K1^i	95.70 (15)
O3^vii—Mo2—K1—O2^vi	−45.83 (19)	O2^vi—K1—O1—K1^i	−33.5 (4)
K1^i—Mo2—K1—O2^vi	151.29 (10)	Mo1^iv—K1—O1—K1^i	111.90 (13)
K1^iv—Mo2—K1—O2^vi	−125.24 (10)	Mo2—K1—O1—K1^i	11.41 (13)
K1^vi—Mo2—K1—O2^vi	81.28 (10)	Co1—K1—O1—K1^i	100.4 (2)
K1^v—Mo2—K1—O2^vi	−169.99 (10)	K2^xi—K1—O1—K1^i	157.7 (3)
K1^vii—Mo2—K1—O2^vi	−58.21 (9)	O4—Mo1—O2—K1^i	100.3 (2)
O5^i—Mo2—K1—Mo1^iv	−143.7 (2)	O1—Mo1—O2—K1^i	−19.3 (2)
O5^iv—Mo2—K1—Mo1^iv	−55.0 (2)	O3—Mo1—O2—K1^i	−139.28 (19)
O5—Mo2—K1—Mo1^iv	31.5 (2)	K3^ii—Mo1—O2—K1^i	100.74 (17)
O3^v—Mo2—K1—Mo1^iv	−175.7 (2)	K1—Mo1—O2—K1^i	−63.43 (16)
O3^vi—Mo2—K1—Mo1^iv	126.71 (13)	K1^iii—Mo1—O2—K1^i	113.16 (18)
O3^vii—Mo2—K1—Mo1^iv	63.32 (18)	O4—Mo1—O2—K1^vi	−167.5 (2)
K1^i—Mo2—K1—Mo1^iv	−99.56 (6)	O1—Mo1—O2—K1^vi	72.9 (2)
K1^iv—Mo2—K1—Mo1^iv	−16.08 (5)	O3—Mo1—O2—K1^vi	−47.0 (2)
K1^vi—Mo2—K1—Mo1^iv	−169.56 (8)	K1^i—Mo1—O2—K1^vi	92.26 (19)
K1^v—Mo2—K1—Mo1^iv	−60.84 (9)	K3^ii—Mo1—O2—K1^vi	−167.0 (2)
K1^vii—Mo2—K1—Mo1^iv	50.95 (4)	K1—Mo1—O2—K1^vi	28.83 (19)
O5^i—Mo2—K1—Co1	−85.9 (2)	K1^iii—Mo1—O2—K1^vi	−154.58 (11)
O5^iv—Mo2—K1—Co1	2.8 (2)	O4—Mo1—O2—K3^ii	−0.5 (2)
O5—Mo2—K1—Co1	89.4 (2)	O1—Mo1—O2—K3^ii	−120.06 (17)
O3^v—Mo2—K1—Co1	−117.9 (2)	O3—Mo1—O2—K3^ii	119.98 (18)
O3^vi—Mo2—K1—Co1	−175.47 (13)	K1^i—Mo1—O2—K3^ii	−100.74 (17)
O3^vii—Mo2—K1—Co1	121.14 (17)	K1—Mo1—O2—K3^ii	−164.17 (5)
K1^i—Mo2—K1—Co1	−41.74 (5)	K1^iii—Mo1—O2—K3^ii	12.4 (3)
K1^iv—Mo2—K1—Co1	41.74 (5)	O4—Mo1—O3—Co1^iii	−16.5 (4)
K1^vi—Mo2—K1—Co1	−111.74 (5)	O2—Mo1—O3—Co1^iii	−139.2 (3)
K1^v—Mo2—K1—Co1	−3.02 (8)	O1—Mo1—O3—Co1^iii	102.4 (3)
K1^vii—Mo2—K1—Co1	108.76 (4)	K1^i—Mo1—O3—Co1^iii	164.53 (12)
O5^i—Mo2—K1—K2^xi	137.5 (2)	K3^ii—Mo1—O3—Co1^iii	−68.5 (3)
O5^iv—Mo2—K1—K2^xi	−133.9 (2)	K1—Mo1—O3—Co1^iii	121.4 (3)
O5—Mo2—K1—K2^xi	−47.3 (2)	K1^iii—Mo1—O3—Co1^iii	0.3 (3)
O3^v—Mo2—K1—K2^xi	105.4 (2)	O4—Mo1—O3—Mo2^vi	155.8 (4)
O3^vi—Mo2—K1—K2^xi	47.87 (13)	O2—Mo1—O3—Mo2^vi	33.2 (4)
O3^vii—Mo2—K1—K2^xi	−15.52 (18)	O1—Mo1—O3—Mo2^vi	−85.2 (4)
K1^i—Mo2—K1—K2^xi	−178.40 (5)	K1^i—Mo1—O3—Mo2^vi	−23.1 (5)
K1^iv—Mo2—K1—K2^xi	−94.92 (7)	K3^ii—Mo1—O3—Mo2^vi	103.8 (4)
K1^vi—Mo2—K1—K2^xi	111.60 (7)	K1—Mo1—O3—Mo2^vi	−66.3 (3)
K1^v—Mo2—K1—K2^xi	−139.68 (6)	K1^iii—Mo1—O3—Mo2^vi	172.7 (4)
K1^vii—Mo2—K1—K2^xi	−27.90 (3)	O2—Mo1—O4—K1^iii	160.6 (3)
O1—Co1—K1—O5^x	−15.5 (2)	O1—Mo1—O4—K1^iii	−80.5 (4)
O1^i—Co1—K1—O5^x	−100.9 (2)	O3—Mo1—O4—K1^iii	39.3 (4)
O1^iv—Co1—K1—O5^x	172.3 (2)	K1^i—Mo1—O4—K1^iii	−141.4 (3)
O3^iii—Co1—K1—O5^x	71.9 (2)	K3^ii—Mo1—O4—K1^iii	160.0 (5)
O3^viii—Co1—K1—O5^x	8.0 (3)	K1—Mo1—O4—K1^iii	−44.5 (5)
O3^ix—Co1—K1—O5^x	140.1 (2)	O2—Mo1—O4—K3^ii	0.6 (3)
K1^i—Co1—K1—O5^x	−64.08 (17)	O1—Mo1—O4—K3^ii	119.5 (2)
K1^iv—Co1—K1—O5^x	−142.92 (16)	O3—Mo1—O4—K3^ii	−120.7 (2)
O1—Co1—K1—O4^iii	−98.6 (2)	K1^i—Mo1—O4—K3^ii	58.59 (19)
O1^i—Co1—K1—O4^iii	176.00 (18)	K1—Mo1—O4—K3^ii	155.49 (11)
O1^iv—Co1—K1—O4^iii	89.2 (2)	K1^iii—Mo1—O4—K3^ii	−160.0 (5)
O3^iii—Co1—K1—O4^iii	−11.19 (17)	O5^i—Mo2—O5—K1^vii	137.7 (5)
O3^viii—Co1—K1—O4^iii	−75.1 (2)	O5^iv—Mo2—O5—K1^vii	−115.3 (5)
O3^ix—Co1—K1—O4^iii	57.0 (2)	O3^v—Mo2—O5—K1^vii	4.1 (9)
K1^i—Co1—K1—O4^iii	−147.17 (13)	O3^vi—Mo2—O5—K1^vii	49.1 (4)
K1^iv—Co1—K1—O4^iii	133.99 (13)	O3^vii—Mo2—O5—K1^vii	−23.5 (4)
O1—Co1—K1—O5	117.0 (2)	K1—Mo2—O5—K1^vii	133.7 (5)
O1^i—Co1—K1—O5	31.61 (18)	K1^i—Mo2—O5—K1^vii	−171.2 (3)
O1^iv—Co1—K1—O5	−55.2 (2)	K1^iv—Mo2—O5—K1^vii	−111.6 (5)
O3^iii—Co1—K1—O5	−155.57 (17)	K1^vi—Mo2—O5—K1^vii	112.9 (4)
O3^viii—Co1—K1—O5	140.5 (2)	K1^v—Mo2—O5—K1^vii	−95.7 (4)
O3^ix—Co1—K1—O5	−87.4 (2)	O5^i—Mo2—O5—K1	4.0 (3)
K1^i—Co1—K1—O5	68.45 (11)	O5^iv—Mo2—O5—K1	111.0 (2)
K1^iv—Co1—K1—O5	−10.40 (11)	O3^v—Mo2—O5—K1	−129.6 (5)
O1^i—Co1—K1—O1	−85.39 (15)	O3^vi—Mo2—O5—K1	−84.6 (2)
O1^iv—Co1—K1—O1	−172.2 (3)	O3^vii—Mo2—O5—K1	−157.2 (2)
O3^iii—Co1—K1—O1	87.4 (2)	K1^i—Mo2—O5—K1	55.1 (2)
O3^viii—Co1—K1—O1	23.5 (3)	K1^iv—Mo2—O5—K1	114.7 (2)
O3^ix—Co1—K1—O1	155.6 (3)	K1^vi—Mo2—O5—K1	−20.9 (2)
K1^i—Co1—K1—O1	−48.56 (19)	K1^v—Mo2—O5—K1	130.62 (13)
K1^iv—Co1—K1—O1	−127.40 (19)	K1^vii—Mo2—O5—K1	−133.7 (5)
O1—Co1—K1—O2^iv	−166.3 (2)	O5^i—Mo2—O5—K1^iv	−110.7 (2)
O1^i—Co1—K1—O2^iv	108.33 (17)	O5^iv—Mo2—O5—K1^iv	−3.7 (3)
O1^iv—Co1—K1—O2^iv	21.56 (19)	O3^v—Mo2—O5—K1^iv	115.7 (5)
O3^iii—Co1—K1—O2^iv	−78.86 (17)	O3^vi—Mo2—O5—K1^iv	160.71 (17)
O3^viii—Co1—K1—O2^iv	−142.8 (2)	O3^vii—Mo2—O5—K1^iv	88.07 (18)
O3^ix—Co1—K1—O2^iv	−10.7 (2)	K1—Mo2—O5—K1^iv	−114.7 (2)
K1^i—Co1—K1—O2^iv	145.16 (11)	K1^i—Mo2—O5—K1^iv	−59.58 (19)
K1^iv—Co1—K1—O2^iv	66.31 (12)	K1^vi—Mo2—O5—K1^iv	−135.55 (10)
O1—Co1—K1—O5^i	58.5 (2)	K1^v—Mo2—O5—K1^iv	15.9 (2)
O1^i—Co1—K1—O5^i	−26.88 (17)	K1^vii—Mo2—O5—K1^iv	111.6 (5)
O1^iv—Co1—K1—O5^i	−113.6 (2)	O5^x—K1—O5—Mo2	44.0 (4)
O3^iii—Co1—K1—O5^i	145.93 (16)	O4^iii—K1—O5—Mo2	−139.6 (2)
O3^viii—Co1—K1—O5^i	82.0 (2)	O1—K1—O5—Mo2	−59.0 (2)
O3^ix—Co1—K1—O5^i	−145.9 (2)	O2^iv—K1—O5—Mo2	−178.5 (2)
K1^i—Co1—K1—O5^i	9.96 (11)	O5^i—K1—O5—Mo2	−2.8 (2)
K1^iv—Co1—K1—O5^i	−68.89 (10)	O1^iv—K1—O5—Mo2	−116.9 (2)
O1—Co1—K1—O1^iv	172.2 (3)	O2^vi—K1—O5—Mo2	93.9 (2)
O1^i—Co1—K1—O1^iv	86.77 (15)	Mo1^iv—K1—O5—Mo2	−148.0 (2)
O3^iii—Co1—K1—O1^iv	−100.4 (2)	Co1—K1—O5—Mo2	−88.1 (2)
O3^viii—Co1—K1—O1^iv	−164.3 (3)	K2^xi—K1—O5—Mo2	136.4 (2)
O3^ix—Co1—K1—O1^iv	−32.3 (2)	O5^x—K1—O5—K1^vii	−105.4 (2)
K1^i—Co1—K1—O1^iv	123.60 (17)	O4^iii—K1—O5—K1^vii	71.0 (3)
K1^iv—Co1—K1—O1^iv	44.75 (17)	O1—K1—O5—K1^vii	151.56 (18)
O1—Co1—K1—O2^vi	121.9 (3)	O2^iv—K1—O5—K1^vii	32.04 (17)
O1^i—Co1—K1—O2^vi	36.5 (3)	O5^i—K1—O5—K1^vii	−152.2 (2)
O1^iv—Co1—K1—O2^vi	−50.2 (3)	O1^iv—K1—O5—K1^vii	93.64 (19)
O3^iii—Co1—K1—O2^vi	−150.6 (3)	O2^vi—K1—O5—K1^vii	−55.50 (16)
O3^viii—Co1—K1—O2^vi	145.5 (3)	Mo1^iv—K1—O5—K1^vii	62.60 (15)
O3^ix—Co1—K1—O2^vi	−82.5 (3)	Mo2—K1—O5—K1^vii	−149.4 (3)
K1^i—Co1—K1—O2^vi	73.4 (2)	Co1—K1—O5—K1^vii	122.47 (16)
K1^iv—Co1—K1—O2^vi	−5.5 (2)	K2^xi—K1—O5—K1^vii	−12.97 (16)
O1—Co1—K1—Mo1^iv	−166.63 (19)	O5^x—K1—O5—K1^iv	146.6 (2)
O1^i—Co1—K1—Mo1^iv	107.98 (14)	O4^iii—K1—O5—K1^iv	−37.0 (3)
O1^iv—Co1—K1—Mo1^iv	21.21 (16)	O1—K1—O5—K1^iv	43.6 (2)
O3^iii—Co1—K1—Mo1^iv	−79.21 (13)	O2^iv—K1—O5—K1^iv	−75.96 (19)
O3^viii—Co1—K1—Mo1^iv	−143.1 (2)	O5^i—K1—O5—K1^iv	99.83 (18)
O3^ix—Co1—K1—Mo1^iv	−11.04 (18)	O1^iv—K1—O5—K1^iv	−14.36 (16)
K1^i—Co1—K1—Mo1^iv	144.81 (4)	O2^vi—K1—O5—K1^iv	−163.5 (2)
K1^iv—Co1—K1—Mo1^iv	65.97 (4)	Mo1^iv—K1—O5—K1^iv	−45.39 (15)
O1—Co1—K1—Mo2	87.98 (19)	Mo2—K1—O5—K1^iv	102.6 (3)
O1^i—Co1—K1—Mo2	2.59 (14)	Co1—K1—O5—K1^iv	14.48 (16)
O1^iv—Co1—K1—Mo2	−84.18 (17)	K2^xi—K1—O5—K1^iv	−120.97 (17)
O3^iii—Co1—K1—Mo2	175.40 (13)

Symmetry codes: (i) −y+1, x−y, z; (ii) x+1, y, z; (iii) −x+1, −y, −z+1; (iv) −x+y+1, −x+1, z; (v) y+1, −x+y+1, −z+2; (vi) −x+1, −y, −z+2; (vii) x−y, x, −z+2; (viii) y+1, −x+y+1, −z+1; (ix) x−y, x, −z+1; (x) y, −x+y, −z+2; (xi) x−1, y, z+1; (xii) −y+1, x−y−1, z−1; (xiii) −x+2, −y, −z+1; (xiv) x, y, z−1; (xv) x−y, x−1, −z+1; (xvi) −x+y+2, −x+1, z−1; (xvii) −x+y+1, −x, z−1; (xviii) x−y+1, x, −z+1; (xix) y+1, −x+y, −z+1; (xx) x+1, y, z−1; (xxi) −y+1, x−y, z−1; (xxii) x−y−1, x−1, −z+1; (xxiii) −y, x−y−1, z; (xxiv) x−1, y, z; (xxv) y, −x+y+1, −z+1; (xxvi) x, y, z+1.

(II) hexapotassium cobalt pentamolybdate

Crystal data

K6CoMo5O19	F(000) = 2012
Mr = 1077.23	Dx = 3.523 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 8.0804 (6) Å	Cell parameters from 6106 reflections
b = 10.3856 (4) Å	θ = 3.3–30.3°
c = 24.2048 (11) Å	µ = 5.11 mm^−1
β = 90.728 (5)°	T = 298 K
V = 2031.10 (19) Å^3	Prism, blue
Z = 4	0.08 × 0.07 × 0.06 mm

Data collection

Oxford Xcalibur with Sapphire CCD area detector diffractometer	5522 independent reflections
Radiation source: fine-focus sealed tube	4488 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.042
ω and ϕ scans	θmax = 30.1°, θmin = 2.6°
Absorption correction: numerical [CrysAlis RED (Oxford Diffraction, 2003); analytical numeric absorption correction using a multifaceted crystal model based on expressions derived by R.C. Clark & J.S. Reid (Reference?).	h = −10→11
Tmin = 0.640, Tmax = 0.772	k = −14→14
27463 measured reflections	l = −32→32

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.044	w = 1/[σ^2(Fo^2) + (0.0257P)^2 + 23.4209P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.114	(Δ/σ)max < 0.001
S = 1.35	Δρmax = 1.76 e Å^−3
5522 reflections	Δρmin = −1.36 e Å^−3
281 parameters	Extinction correction: SHELXL97 (Sheldrick, 1997), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
0 restraints	Extinction coefficient: 0.00024 (5)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Mo1	0.33560 (9)	0.41918 (6)	0.17553 (3)	0.01676 (16)
Mo2	0.35812 (8)	0.40807 (6)	−0.06042 (3)	0.01195 (14)
Mo3	0.70519 (9)	0.09636 (6)	0.18804 (3)	0.01528 (15)
Mo4	0.37039 (8)	−0.07013 (6)	0.06681 (3)	0.01235 (14)
Mo5	0.14112 (8)	0.25850 (6)	0.05900 (3)	0.01339 (15)
Co1	0.53059 (13)	0.25021 (9)	0.05966 (4)	0.0121 (2)
K1	0.5151 (2)	0.24526 (18)	0.30639 (8)	0.0243 (4)
K2	0.1978 (3)	0.06480 (19)	0.19656 (8)	0.0282 (4)
K3	0.8639 (2)	−0.00366 (18)	0.06670 (8)	0.0225 (4)
K4	0.1413 (2)	−0.35491 (17)	0.04668 (9)	0.0245 (4)
K5	0.4913 (3)	0.75918 (18)	0.18770 (8)	0.0261 (4)
K6	−0.1386 (3)	0.40468 (19)	0.16073 (9)	0.0306 (5)
O1	0.3421 (7)	0.3196 (5)	0.0041 (2)	0.0160 (11)
O2	0.3465 (7)	−0.1467 (5)	0.0016 (2)	0.0168 (11)
O3	0.6609 (7)	0.1789 (5)	0.1247 (2)	0.0181 (12)
O4	0.3458 (7)	0.3293 (5)	0.1109 (2)	0.0159 (11)
O5	0.0463 (7)	0.1703 (6)	0.0057 (2)	0.0210 (12)
O6	0.8534 (8)	−0.0235 (5)	0.1772 (3)	0.0234 (13)
O7	0.2023 (7)	0.3627 (5)	−0.1070 (2)	0.0215 (12)
O8	0.3419 (7)	0.5766 (5)	−0.0501 (2)	0.0195 (12)
O9	0.3407 (7)	0.1020 (5)	0.0617 (2)	0.0181 (12)
O10	0.0469 (7)	0.4077 (5)	0.0533 (3)	0.0230 (13)
O11	0.2223 (7)	−0.1301 (5)	0.1130 (2)	0.0210 (13)
O12	0.0536 (7)	0.1946 (6)	0.1186 (2)	0.0226 (13)
O13	0.5658 (7)	−0.1005 (6)	0.0942 (2)	0.0214 (12)
O14	0.5266 (8)	0.0308 (6)	0.2173 (3)	0.0309 (15)
O15	0.5487 (7)	0.3756 (6)	−0.0888 (3)	0.0232 (13)
O16	0.7845 (8)	0.2123 (6)	0.2346 (3)	0.0277 (14)
O17	0.2701 (9)	0.3165 (6)	0.2292 (3)	0.0303 (15)
O18	0.1940 (9)	0.5456 (6)	0.1716 (3)	0.0346 (17)
O19	0.5268 (9)	0.4815 (7)	0.1948 (3)	0.0374 (17)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Mo1	0.0248 (4)	0.0142 (3)	0.0112 (3)	0.0021 (3)	−0.0002 (3)	−0.0024 (2)
Mo2	0.0148 (3)	0.0111 (3)	0.0099 (3)	−0.0011 (2)	−0.0010 (2)	0.0010 (2)
Mo3	0.0195 (3)	0.0136 (3)	0.0127 (3)	0.0015 (2)	0.0014 (3)	0.0010 (2)
Mo4	0.0156 (3)	0.0106 (3)	0.0108 (3)	0.0000 (2)	0.0005 (2)	−0.0003 (2)
Mo5	0.0134 (3)	0.0133 (3)	0.0134 (3)	−0.0009 (2)	−0.0002 (2)	0.0006 (2)
Co1	0.0153 (5)	0.0103 (4)	0.0107 (5)	0.0007 (4)	0.0003 (4)	0.0001 (4)
K1	0.0271 (10)	0.0206 (8)	0.0253 (10)	−0.0030 (7)	−0.0005 (8)	0.0010 (7)
K2	0.0374 (11)	0.0238 (9)	0.0233 (10)	0.0021 (8)	−0.0026 (9)	−0.0008 (7)
K3	0.0248 (9)	0.0252 (9)	0.0175 (9)	−0.0018 (7)	0.0053 (7)	−0.0040 (7)
K4	0.0235 (9)	0.0173 (8)	0.0324 (11)	−0.0016 (7)	−0.0059 (8)	0.0015 (7)
K5	0.0397 (12)	0.0207 (9)	0.0179 (9)	0.0024 (8)	−0.0049 (8)	0.0031 (7)
K6	0.0318 (11)	0.0227 (9)	0.0375 (12)	0.0026 (8)	0.0028 (9)	0.0086 (8)
O1	0.015 (3)	0.019 (3)	0.014 (3)	−0.004 (2)	−0.001 (2)	0.003 (2)
O2	0.021 (3)	0.019 (3)	0.011 (3)	0.004 (2)	−0.001 (2)	−0.004 (2)
O3	0.023 (3)	0.017 (3)	0.014 (3)	0.003 (2)	−0.006 (2)	0.003 (2)
O4	0.018 (3)	0.018 (3)	0.011 (3)	0.001 (2)	0.000 (2)	−0.003 (2)
O5	0.020 (3)	0.025 (3)	0.018 (3)	−0.003 (2)	−0.001 (2)	−0.003 (2)
O6	0.029 (3)	0.019 (3)	0.022 (3)	0.011 (2)	−0.003 (3)	0.004 (2)
O7	0.025 (3)	0.021 (3)	0.018 (3)	−0.003 (2)	−0.010 (2)	0.002 (2)
O8	0.021 (3)	0.010 (2)	0.028 (3)	0.000 (2)	0.001 (2)	−0.002 (2)
O9	0.019 (3)	0.011 (2)	0.024 (3)	0.003 (2)	0.003 (2)	0.000 (2)
O10	0.024 (3)	0.015 (3)	0.030 (3)	0.002 (2)	−0.003 (3)	0.001 (2)
O11	0.025 (3)	0.020 (3)	0.018 (3)	−0.003 (2)	0.010 (2)	0.000 (2)
O12	0.022 (3)	0.026 (3)	0.019 (3)	−0.001 (2)	0.005 (2)	0.005 (2)
O13	0.022 (3)	0.024 (3)	0.018 (3)	−0.005 (2)	−0.006 (2)	0.007 (2)
O14	0.027 (3)	0.033 (3)	0.033 (4)	−0.006 (3)	0.011 (3)	−0.001 (3)
O15	0.017 (3)	0.028 (3)	0.025 (3)	0.001 (2)	0.007 (3)	−0.001 (3)
O16	0.040 (4)	0.024 (3)	0.019 (3)	−0.001 (3)	−0.008 (3)	0.000 (3)
O17	0.045 (4)	0.027 (3)	0.019 (3)	0.001 (3)	0.005 (3)	0.004 (3)
O18	0.045 (4)	0.028 (3)	0.031 (4)	0.016 (3)	0.015 (3)	0.004 (3)
O19	0.042 (4)	0.038 (4)	0.033 (4)	−0.010 (3)	−0.010 (3)	−0.004 (3)

Geometric parameters (Å, º)

Mo1—O19	1.734 (7)	K3—O5^vi	2.574 (6)
Mo1—O18	1.744 (6)	K3—O6	2.684 (7)
Mo1—O17	1.768 (6)	K3—O13	2.701 (6)
Mo1—O4	1.825 (5)	K3—O5^vii	2.769 (6)
Mo1—K2^i	3.459 (2)	K3—O2^vi	2.827 (6)
Mo1—K5	3.759 (2)	K3—O12^vii	2.849 (6)
Mo1—K6	3.847 (2)	K3—O3	2.884 (6)
Mo1—K2	3.881 (2)	K3—O11^vii	3.359 (6)
Mo1—K1	3.909 (2)	K3—Mo5^vii	3.5320 (19)
Mo2—O15	1.728 (6)	K3—Mo4^vi	3.803 (2)
Mo2—O7	1.743 (6)	K4—O10^viii	2.586 (6)
Mo2—O8	1.773 (5)	K4—O15^vi	2.701 (6)
Mo2—O1	1.818 (5)	K4—O5^v	2.745 (6)
Mo2—K6^ii	3.565 (2)	K4—O10^v	2.894 (7)
Mo2—K5^iii	3.753 (2)	K4—O11	2.904 (6)
Mo2—K4^iv	3.996 (2)	K4—O2	2.943 (6)
Mo2—K4^v	4.091 (2)	K4—O8^viii	2.952 (6)
Mo2—K4^vi	4.092 (2)	K4—O7^v	3.154 (6)
Mo3—O6	1.750 (6)	K4—O18^viii	3.219 (7)
Mo3—O14	1.753 (6)	K4—Mo5^v	3.550 (2)
Mo3—O16	1.765 (6)	K4—Co1^vi	3.875 (2)
Mo3—O3	1.788 (5)	K5—O16^x	2.639 (7)
Mo3—K3	3.3833 (19)	K5—O13^iv	2.766 (6)
Mo3—K6^vii	3.508 (2)	K5—O15^iii	2.788 (7)
Mo3—K1	3.615 (2)	K5—O19	2.903 (7)
Mo3—K5^viii	3.905 (2)	K5—O14^iv	2.924 (7)
Mo3—K2^vii	3.997 (2)	K5—O17^i	2.994 (7)
Mo3—K2	4.121 (2)	K5—O11^iv	3.035 (7)
Mo4—O13	1.733 (6)	K5—O18	3.289 (8)
Mo4—O11	1.762 (5)	K5—O7^iii	3.417 (7)
Mo4—O2	1.776 (5)	K5—Mo4^iv	3.548 (2)
Mo4—O9	1.808 (5)	K5—Mo2^iii	3.753 (2)
Mo4—K4	3.5199 (19)	K6—O16^ix	2.758 (7)
Mo4—K5^viii	3.548 (2)	K6—O7^ii	2.789 (6)
Mo4—K2	3.726 (2)	K6—O12	2.873 (6)
Mo4—K3^vi	3.803 (2)	K6—O19^ix	2.946 (8)
Mo4—K3	4.047 (2)	K6—O3^ix	2.974 (6)
Mo5—O10	1.731 (6)	K6—O10	3.018 (7)
Mo5—O12	1.746 (6)	K6—O18	3.069 (8)
Mo5—O5	1.751 (6)	K6—O8^ii	3.130 (6)
Mo5—O4	2.191 (6)	K6—O14^i	3.345 (8)
Mo5—O1	2.205 (5)	K6—Mo3^ix	3.508 (2)
Mo5—O9	2.290 (5)	K6—Mo2^ii	3.566 (2)
Mo5—K3^ix	3.5320 (19)	O2—Co1^vi	2.092 (5)
Mo5—K4^v	3.550 (2)	O2—K3^vi	2.827 (6)
Mo5—K6	3.690 (2)	O3—K6^vii	2.974 (6)
Mo5—K2	3.912 (2)	O5—K3^vi	2.574 (6)
Mo5—K4^iv	4.0260 (19)	O5—K4^v	2.745 (6)
Mo5—K3^vi	4.0323 (19)	O5—K3^ix	2.769 (6)
Co1—O3	2.024 (5)	O6—K1^xiii	2.654 (6)
Co1—O8^iii	2.088 (5)	O6—K2^vii	2.962 (7)
Co1—O2^vi	2.092 (5)	O7—K6^ii	2.789 (6)
Co1—O4	2.118 (5)	O7—K1^xiv	2.804 (6)
Co1—O1	2.144 (6)	O7—K4^v	3.154 (6)
Co1—O9	2.174 (6)	O7—K5^iii	3.417 (7)
Co1—K3	3.772 (2)	O8—Co1^iii	2.088 (5)
Co1—K4^vi	3.875 (2)	O8—K4^iv	2.952 (6)
Co1—K6^vii	3.942 (3)	O8—K6^ii	3.130 (6)
K1—O6^x	2.654 (6)	O10—K4^iv	2.586 (6)
K1—O18^xi	2.731 (6)	O10—K4^v	2.894 (7)
K1—O17	2.804 (7)	O11—K5^viii	3.035 (7)
K1—O7^xii	2.804 (6)	O11—K1^xi	3.042 (6)
K1—O16	2.823 (7)	O11—K3^ix	3.359 (6)
K1—O11^i	3.042 (6)	O12—K3^ix	2.849 (6)
K1—O14	3.103 (7)	O13—K5^viii	2.766 (6)
K1—K2^i	3.738 (3)	O14—K5^viii	2.924 (7)
K1—K6^xi	3.758 (3)	O14—K6^xi	3.345 (8)
K1—K4^i	3.929 (3)	O15—K4^vi	2.701 (6)
K2—O12	2.584 (6)	O15—K5^iii	2.788 (7)
K2—O14	2.721 (7)	O16—K5^xiii	2.639 (7)
K2—O17	2.790 (7)	O16—K6^vii	2.758 (7)
K2—O11	2.870 (6)	O17—K5^xi	2.994 (7)
K2—O6^ix	2.962 (7)	O17—K2^i	3.152 (7)
K2—O17^xi	3.152 (7)	O18—K1^i	2.731 (6)
K2—O18^xi	3.304 (8)	O18—K4^iv	3.219 (7)
K2—O19^xi	3.328 (8)	O18—K2^i	3.304 (8)
K2—Mo1^xi	3.459 (2)	O19—K6^vii	2.946 (8)
K2—K1^xi	3.738 (3)	O19—K2^i	3.328 (8)
K2—K5^xi	3.791 (3)
O19—Mo1—O18	108.4 (4)	O5^vi—K3—O5^vii	85.35 (19)
O19—Mo1—O17	107.6 (3)	O6—K3—O5^vii	127.2 (2)
O18—Mo1—O17	107.0 (3)	O13—K3—O5^vii	148.89 (19)
O19—Mo1—O4	111.8 (3)	O5^vi—K3—O2^vi	98.40 (18)
O18—Mo1—O4	112.0 (3)	O6—K3—O2^vi	126.75 (17)
O17—Mo1—O4	109.8 (3)	O13—K3—O2^vi	79.51 (17)
O19—Mo1—K2^i	71.1 (3)	O5^vii—K3—O2^vi	69.39 (17)
O18—Mo1—K2^i	70.2 (2)	O5^vi—K3—O12^vii	129.16 (19)
O17—Mo1—K2^i	65.1 (2)	O6—K3—O12^vii	68.88 (18)
O4—Mo1—K2^i	174.88 (17)	O13—K3—O12^vii	129.55 (19)
O19—Mo1—K5	48.1 (2)	O5^vii—K3—O12^vii	58.47 (17)
O18—Mo1—K5	61.0 (3)	O2^vi—K3—O12^vii	100.06 (17)
O17—Mo1—K5	127.8 (2)	O5^vi—K3—O3	160.16 (19)
O4—Mo1—K5	121.92 (17)	O6—K3—O3	62.60 (16)
K2^i—Mo1—K5	63.19 (5)	O13—K3—O3	67.07 (18)
O19—Mo1—K6	157.4 (3)	O5^vii—K3—O3	98.09 (17)
O18—Mo1—K6	51.1 (3)	O2^vi—K3—O3	65.16 (16)
O17—Mo1—K6	74.8 (2)	O12^vii—K3—O3	67.43 (17)
O4—Mo1—K6	87.47 (18)	O5^vi—K3—O11^vii	73.46 (17)
K2^i—Mo1—K6	90.66 (5)	O6—K3—O11^vii	71.07 (17)
K5—Mo1—K6	112.09 (5)	O13—K3—O11^vii	122.69 (17)
O19—Mo1—K2	125.1 (2)	O5^vii—K3—O11^vii	88.32 (16)
O18—Mo1—K2	122.2 (2)	O2^vi—K3—O11^vii	157.02 (16)
O17—Mo1—K2	40.7 (2)	O12^vii—K3—O11^vii	71.26 (16)
O4—Mo1—K2	69.13 (17)	O3—K3—O11^vii	125.99 (16)
K2^i—Mo1—K2	105.75 (3)	O5^vi—K3—Mo3	155.62 (15)
K5—Mo1—K2	167.69 (5)	O6—K3—Mo3	30.86 (12)
K6—Mo1—K2	71.82 (5)	O13—K3—Mo3	63.36 (13)
O19—Mo1—K1	68.5 (2)	O5^vii—K3—Mo3	118.21 (13)
O18—Mo1—K1	128.9 (2)	O2^vi—K3—Mo3	96.09 (12)
O17—Mo1—K1	40.3 (2)	O12^vii—K3—Mo3	66.61 (12)
O4—Mo1—K1	116.00 (17)	O3—K3—Mo3	31.90 (11)
K2^i—Mo1—K1	60.61 (5)	O11^vii—K3—Mo3	99.50 (11)
K5—Mo1—K1	104.49 (4)	O5^vi—K3—Mo5^vii	107.33 (14)
K6—Mo1—K1	114.60 (5)	O6—K3—Mo5^vii	98.04 (15)
K2—Mo1—K1	63.87 (4)	O13—K3—Mo5^vii	150.23 (14)
O15—Mo2—O7	109.3 (3)	O5^vii—K3—Mo5^vii	29.19 (12)
O15—Mo2—O8	108.5 (3)	O2^vi—K3—Mo5^vii	85.43 (12)
O7—Mo2—O8	107.7 (3)	O12^vii—K3—Mo5^vii	29.35 (12)
O15—Mo2—O1	108.5 (3)	O3—K3—Mo5^vii	83.33 (12)
O7—Mo2—O1	111.1 (3)	O11^vii—K3—Mo5^vii	76.96 (10)
O8—Mo2—O1	111.8 (3)	Mo3—K3—Mo5^vii	93.26 (5)
O15—Mo2—K6^ii	105.9 (2)	O5^vi—K3—Co1	130.28 (15)
O7—Mo2—K6^ii	50.09 (19)	O6—K3—Co1	93.84 (13)
O8—Mo2—K6^ii	61.4 (2)	O13—K3—Co1	68.45 (13)
O1—Mo2—K6^ii	145.12 (18)	O5^vii—K3—Co1	84.52 (13)
O15—Mo2—K5^iii	44.2 (2)	O2^vi—K3—Co1	33.21 (11)
O7—Mo2—K5^iii	65.4 (2)	O12^vii—K3—Co1	83.95 (13)
O8—Mo2—K5^iii	126.7 (2)	O3—K3—Co1	32.02 (11)
O1—Mo2—K5^iii	119.89 (18)	O11^vii—K3—Co1	154.22 (12)
K6^ii—Mo2—K5^iii	81.78 (5)	Mo3—K3—Co1	63.01 (4)
O15—Mo2—K4^iv	141.2 (2)	Mo5^vii—K3—Co1	84.93 (4)
O7—Mo2—K4^iv	105.5 (2)	O5^vi—K3—Mo4^vi	72.45 (14)
O8—Mo2—K4^iv	42.81 (19)	O6—K3—Mo4^vi	147.16 (15)
O1—Mo2—K4^iv	73.60 (18)	O13—K3—Mo4^vi	81.26 (13)
K6^ii—Mo2—K4^iv	83.53 (5)	O5^vii—K3—Mo4^vi	71.22 (13)
K5^iii—Mo2—K4^iv	165.28 (4)	O2^vi—K3—Mo4^vi	26.17 (11)
O15—Mo2—K4^v	153.0 (2)	O12^vii—K3—Mo4^vi	119.24 (13)
O7—Mo2—K4^v	46.5 (2)	O3—K3—Mo4^vi	90.07 (12)
O8—Mo2—K4^v	92.69 (19)	O11^vii—K3—Mo4^vi	141.29 (11)
O1—Mo2—K4^v	77.33 (17)	Mo3—K3—Mo4^vi	119.05 (6)
K6^ii—Mo2—K4^v	69.28 (4)	Mo5^vii—K3—Mo4^vi	96.26 (5)
K5^iii—Mo2—K4^v	109.55 (5)	Co1—K3—Mo4^vi	58.20 (3)
K4^iv—Mo2—K4^v	65.75 (5)	O10^viii—K4—O15^vi	99.99 (19)
O15—Mo2—K4^vi	28.4 (2)	O10^viii—K4—O5^v	122.22 (19)
O7—Mo2—K4^vi	136.1 (2)	O15^vi—K4—O5^v	137.22 (19)
O8—Mo2—K4^vi	101.33 (19)	O10^viii—K4—O10^v	73.7 (2)
O1—Mo2—K4^vi	86.75 (17)	O15^vi—K4—O10^v	140.85 (19)
K6^ii—Mo2—K4^vi	127.71 (5)	O5^v—K4—O10^v	57.65 (17)
K5^iii—Mo2—K4^vi	70.96 (4)	O10^viii—K4—O11	142.8 (2)
K4^iv—Mo2—K4^vi	118.14 (3)	O15^vi—K4—O11	69.73 (18)
K4^v—Mo2—K4^vi	161.87 (5)	O5^v—K4—O11	79.22 (18)
O6—Mo3—O14	110.7 (3)	O10^v—K4—O11	136.65 (18)
O6—Mo3—O16	109.7 (3)	O10^viii—K4—O2	153.03 (19)
O14—Mo3—O16	107.5 (3)	O15^vi—K4—O2	70.99 (17)
O6—Mo3—O3	110.0 (3)	O5^v—K4—O2	68.02 (17)
O14—Mo3—O3	112.1 (3)	O10^v—K4—O2	96.97 (17)
O16—Mo3—O3	106.7 (3)	O11—K4—O2	59.35 (15)
O6—Mo3—K3	51.9 (2)	O10^viii—K4—O8^viii	89.12 (18)
O14—Mo3—K3	123.7 (2)	O15^vi—K4—O8^viii	76.37 (18)
O16—Mo3—K3	128.7 (2)	O5^v—K4—O8^viii	96.17 (17)
O3—Mo3—K3	58.47 (18)	O10^v—K4—O8^viii	65.10 (17)
O6—Mo3—K6^vii	111.9 (2)	O11—K4—O8^viii	120.67 (16)
O14—Mo3—K6^vii	136.9 (2)	O2—K4—O8^viii	64.22 (15)
O16—Mo3—K6^vii	50.9 (2)	O10^viii—K4—O7^v	71.63 (17)
O3—Mo3—K6^vii	57.95 (18)	O15^vi—K4—O7^v	129.86 (18)
K3—Mo3—K6^vii	88.59 (5)	O5^v—K4—O7^v	75.38 (17)
O6—Mo3—K1	136.2 (2)	O10^v—K4—O7^v	85.74 (17)
O14—Mo3—K1	59.1 (2)	O11—K4—O7^v	87.63 (16)
O16—Mo3—K1	49.9 (2)	O2—K4—O7^v	133.95 (16)
O3—Mo3—K1	113.06 (18)	O8^viii—K4—O7^v	148.90 (17)
K3—Mo3—K1	171.43 (5)	O10^viii—K4—O18^viii	70.8 (2)
K6^vii—Mo3—K1	85.20 (5)	O15^vi—K4—O18^viii	60.58 (19)
O6—Mo3—K5^viii	70.5 (2)	O5^v—K4—O18^viii	136.38 (18)
O14—Mo3—K5^viii	44.4 (2)	O10^v—K4—O18^viii	141.88 (19)
O16—Mo3—K5^viii	140.4 (2)	O11—K4—O18^viii	73.28 (18)
O3—Mo3—K5^viii	110.14 (18)	O2—K4—O18^viii	121.05 (18)
K3—Mo3—K5^viii	84.00 (5)	O8^viii—K4—O18^viii	126.90 (17)
K6^vii—Mo3—K5^viii	168.09 (5)	O7^v—K4—O18^viii	70.35 (17)
K1—Mo3—K5^viii	101.12 (4)	O10^viii—K4—Mo4	161.34 (15)
O6—Mo3—K2^vii	42.8 (2)	O15^vi—K4—Mo4	62.03 (13)
O14—Mo3—K2^vii	140.5 (2)	O5^v—K4—Mo4	76.30 (13)
O16—Mo3—K2^vii	70.7 (2)	O10^v—K4—Mo4	123.00 (13)
O3—Mo3—K2^vii	105.77 (19)	O11—K4—Mo4	29.92 (11)
K3—Mo3—K2^vii	68.36 (5)	O2—K4—Mo4	30.26 (11)
K6^vii—Mo3—K2^vii	73.98 (5)	O8^viii—K4—Mo4	91.10 (11)
K1—Mo3—K2^vii	115.29 (5)	O7^v—K4—Mo4	114.98 (12)
K5^viii—Mo3—K2^vii	111.53 (4)	O18^viii—K4—Mo4	94.39 (14)
O6—Mo3—K2	129.4 (2)	O10^viii—K4—Mo5^v	97.25 (15)
O14—Mo3—K2	28.9 (2)	O15^vi—K4—Mo5^v	151.52 (15)
O16—Mo3—K2	112.1 (2)	O5^v—K4—Mo5^v	28.84 (12)
O3—Mo3—K2	83.84 (19)	O10^v—K4—Mo5^v	28.94 (11)
K3—Mo3—K2	114.05 (5)	O11—K4—Mo5^v	108.06 (13)
K6^vii—Mo3—K2	116.27 (5)	O2—K4—Mo5^v	83.43 (12)
K1—Mo3—K2	63.98 (4)	O8^viii—K4—Mo5^v	81.42 (12)
K5^viii—Mo3—K2	59.22 (4)	O7^v—K4—Mo5^v	77.24 (11)
K2^vii—Mo3—K2	169.05 (6)	O18^viii—K4—Mo5^v	147.52 (14)
O13—Mo4—O11	108.4 (3)	Mo4—K4—Mo5^v	101.24 (5)
O13—Mo4—O2	110.3 (3)	O10^viii—K4—Co1^vi	120.90 (15)
O11—Mo4—O2	109.8 (3)	O15^vi—K4—Co1^vi	68.53 (13)
O13—Mo4—O9	109.0 (3)	O5^v—K4—Co1^vi	82.85 (13)
O11—Mo4—O9	107.6 (3)	O10^v—K4—Co1^vi	81.62 (13)
O2—Mo4—O9	111.6 (3)	O11—K4—Co1^vi	89.44 (12)
O13—Mo4—K4	112.03 (19)	O2—K4—Co1^vi	32.20 (10)
O11—Mo4—K4	55.30 (19)	O8^viii—K4—Co1^vi	32.15 (10)
O2—Mo4—K4	56.60 (18)	O7^v—K4—Co1^vi	158.20 (12)
O9—Mo4—K4	138.78 (18)	O18^viii—K4—Co1^vi	129.10 (14)
O13—Mo4—K5^viii	49.77 (19)	Mo4—K4—Co1^vi	59.53 (3)
O11—Mo4—K5^viii	58.8 (2)	Mo5^v—K4—Co1^vi	83.18 (5)
O2—Mo4—K5^viii	122.34 (18)	O16^x—K5—O13^iv	121.7 (2)
O9—Mo4—K5^viii	125.87 (19)	O16^x—K5—O15^iii	126.2 (2)
K4—Mo4—K5^viii	80.40 (5)	O13^iv—K5—O15^iii	65.53 (18)
O13—Mo4—K2	95.5 (2)	O16^x—K5—O19	73.0 (2)
O11—Mo4—K2	48.19 (19)	O13^iv—K5—O19	123.3 (2)
O2—Mo4—K2	151.64 (19)	O15^iii—K5—O19	64.0 (2)
O9—Mo4—K2	68.62 (18)	O16^x—K5—O14^iv	86.5 (2)
K4—Mo4—K2	103.34 (5)	O13^iv—K5—O14^iv	70.76 (19)
K5^viii—Mo4—K2	66.10 (5)	O15^iii—K5—O14^iv	134.8 (2)
O13—Mo4—K3^vi	143.4 (2)	O19—K5—O14^iv	159.2 (2)
O11—Mo4—K3^vi	106.0 (2)	O16^x—K5—O17^i	92.4 (2)
O2—Mo4—K3^vi	44.57 (18)	O13^iv—K5—O17^i	127.43 (19)
O9—Mo4—K3^vi	71.20 (19)	O15^iii—K5—O17^i	126.94 (19)
K4—Mo4—K3^vi	78.25 (5)	O19—K5—O17^i	103.2 (2)
K5^viii—Mo4—K3^vi	158.52 (5)	O14^iv—K5—O17^i	73.22 (18)
K2—Mo4—K3^vi	116.92 (5)	O16^x—K5—O11^iv	166.85 (19)
O13—Mo4—K3	30.50 (19)	O13^iv—K5—O11^iv	58.29 (16)
O11—Mo4—K3	137.5 (2)	O15^iii—K5—O11^iv	66.71 (17)
O2—Mo4—K3	99.90 (18)	O19—K5—O11^iv	118.76 (19)
O9—Mo4—K3	87.78 (18)	O14^iv—K5—O11^iv	81.21 (18)
K4—Mo4—K3	131.28 (4)	O17^i—K5—O11^iv	79.55 (18)
K5^viii—Mo4—K3	79.90 (5)	O16^x—K5—O18	116.98 (19)
K2—Mo4—K3	108.41 (5)	O13^iv—K5—O18	115.14 (18)
K3^vi—Mo4—K3	116.43 (3)	O15^iii—K5—O18	58.89 (17)
O10—Mo5—O12	102.9 (3)	O19—K5—O18	53.75 (19)
O10—Mo5—O5	102.8 (3)	O14^iv—K5—O18	138.46 (18)
O12—Mo5—O5	103.4 (3)	O17^i—K5—O18	72.12 (18)
O10—Mo5—O4	94.2 (2)	O11^iv—K5—O18	70.65 (16)
O12—Mo5—O4	88.0 (2)	O16^x—K5—O7^iii	80.99 (18)
O5—Mo5—O4	156.6 (2)	O13^iv—K5—O7^iii	63.91 (16)
O10—Mo5—O1	91.2 (2)	O15^iii—K5—O7^iii	53.13 (16)
O12—Mo5—O1	156.5 (3)	O19—K5—O7^iii	66.04 (18)
O5—Mo5—O1	91.4 (2)	O14^iv—K5—O7^iii	115.37 (17)
O4—Mo5—O1	72.1 (2)	O17^i—K5—O7^iii	168.56 (17)
O10—Mo5—O9	161.2 (2)	O11^iv—K5—O7^iii	108.56 (15)
O12—Mo5—O9	90.0 (2)	O18—K5—O7^iii	102.47 (15)
O5—Mo5—O9	87.2 (2)	O16^x—K5—Mo4^iv	149.20 (16)
O4—Mo5—O9	72.3 (2)	O13^iv—K5—Mo4^iv	28.59 (12)
O1—Mo5—O9	72.4 (2)	O15^iii—K5—Mo4^iv	60.99 (13)
O10—Mo5—K3^ix	114.6 (2)	O19—K5—Mo4^iv	124.84 (16)
O12—Mo5—K3^ix	53.1 (2)	O14^iv—K5—Mo4^iv	75.22 (15)
O5—Mo5—K3^ix	50.47 (19)	O17^i—K5—Mo4^iv	105.38 (14)
O4—Mo5—K3^ix	134.68 (15)	O11^iv—K5—Mo4^iv	29.76 (10)
O1—Mo5—K3^ix	136.54 (15)	O18—K5—Mo4^iv	92.65 (13)
O9—Mo5—K3^ix	84.16 (14)	O7^iii—K5—Mo4^iv	84.69 (11)
O10—Mo5—K4^v	54.0 (2)	O16^x—K5—Mo2^iii	105.83 (16)
O12—Mo5—K4^v	116.1 (2)	O13^iv—K5—Mo2^iii	59.71 (13)
O5—Mo5—K4^v	49.1 (2)	O15^iii—K5—Mo2^iii	25.60 (12)
O4—Mo5—K4^v	142.36 (14)	O19—K5—Mo2^iii	63.64 (16)
O1—Mo5—K4^v	87.48 (15)	O14^iv—K5—Mo2^iii	128.03 (14)
O9—Mo5—K4^v	131.79 (15)	O17^i—K5—Mo2^iii	151.88 (15)
K3^ix—Mo5—K4^v	81.56 (5)	O11^iv—K5—Mo2^iii	85.62 (11)
O10—Mo5—K6	54.0 (2)	O18—K5—Mo2^iii	80.49 (12)
O12—Mo5—K6	49.2 (2)	O7^iii—K5—Mo2^iii	27.64 (10)
O5—Mo5—K6	116.2 (2)	Mo4^iv—K5—Mo2^iii	69.08 (4)
O4—Mo5—K6	86.79 (14)	O16^x—K5—Mo1	96.24 (14)
O1—Mo5—K6	138.25 (15)	O13^iv—K5—Mo1	120.47 (14)
O9—Mo5—K6	135.26 (15)	O15^iii—K5—Mo1	54.97 (13)
K3^ix—Mo5—K6	83.55 (5)	O19—K5—Mo1	26.38 (15)
K4^v—Mo5—K6	88.35 (5)	O14^iv—K5—Mo1	163.17 (14)
O10—Mo5—K2	125.1 (2)	O17^i—K5—Mo1	90.05 (13)
O12—Mo5—K2	31.3 (2)	O11^iv—K5—Mo1	94.18 (12)
O5—Mo5—K2	113.8 (2)	O18—K5—Mo1	27.63 (11)
O4—Mo5—K2	66.77 (15)	O7^iii—K5—Mo1	81.45 (10)
O1—Mo5—K2	125.59 (15)	Mo4^iv—K5—Mo1	108.44 (5)
O9—Mo5—K2	62.37 (15)	Mo2^iii—K5—Mo1	67.21 (4)
K3^ix—Mo5—K2	68.04 (5)	O16^ix—K6—O7^ii	152.7 (2)
K4^v—Mo5—K2	145.64 (5)	O16^ix—K6—O12	78.88 (18)
K6—Mo5—K2	73.13 (5)	O7^ii—K6—O12	126.14 (19)
O10—Mo5—K4^iv	26.1 (2)	O16^ix—K6—O19^ix	78.4 (2)
O12—Mo5—K4^iv	116.2 (2)	O7^ii—K6—O19^ix	74.4 (2)
O5—Mo5—K4^iv	117.9 (2)	O12—K6—O19^ix	143.8 (2)
O4—Mo5—K4^iv	72.94 (14)	O16^ix—K6—O3^ix	59.51 (17)
O1—Mo5—K4^iv	70.59 (14)	O7^ii—K6—O3^ix	116.72 (17)
O9—Mo5—K4^iv	135.15 (14)	O12—K6—O3^ix	65.92 (17)
K3^ix—Mo5—K4^iv	140.67 (5)	O19^ix—K6—O3^ix	78.31 (18)
K4^v—Mo5—K4^iv	70.50 (5)	O16^ix—K6—O10	133.22 (19)
K6—Mo5—K4^iv	68.89 (4)	O7^ii—K6—O10	71.32 (17)
K2—Mo5—K4^iv	125.15 (5)	O12—K6—O10	54.93 (16)
O10—Mo5—K3^vi	121.8 (2)	O19^ix—K6—O10	134.9 (2)
O12—Mo5—K3^vi	111.9 (2)	O3^ix—K6—O10	91.74 (17)
O5—Mo5—K3^vi	25.91 (19)	O16^ix—K6—O18	119.6 (2)
O4—Mo5—K3^vi	130.77 (14)	O7^ii—K6—O18	77.48 (18)
O1—Mo5—K3^vi	74.59 (15)	O12—K6—O18	85.18 (18)
O9—Mo5—K3^vi	63.62 (15)	O19^ix—K6—O18	130.72 (19)
K3^ix—Mo5—K3^vi	62.19 (5)	O3^ix—K6—O18	150.97 (18)
K4^v—Mo5—K3^vi	68.97 (4)	O10—K6—O18	67.98 (18)
K6—Mo5—K3^vi	140.63 (5)	O16^ix—K6—O8^ii	118.70 (18)
K2—Mo5—K3^vi	107.73 (4)	O7^ii—K6—O8^ii	56.98 (16)
K4^iv—Mo5—K3^vi	126.78 (4)	O12—K6—O8^ii	91.37 (17)
O3—Co1—O8^iii	98.6 (2)	O19^ix—K6—O8^ii	75.48 (18)
O3—Co1—O2^vi	96.7 (2)	O3^ix—K6—O8^ii	61.35 (15)
O8^iii—Co1—O2^vi	97.1 (2)	O10—K6—O8^ii	61.52 (16)
O3—Co1—O4	92.9 (2)	O18—K6—O8^ii	119.56 (18)
O8^iii—Co1—O4	94.8 (2)	O16^ix—K6—O14^i	76.80 (18)
O2^vi—Co1—O4	163.4 (2)	O7^ii—K6—O14^i	96.83 (18)
O3—Co1—O1	165.9 (2)	O12—K6—O14^i	117.99 (18)
O8^iii—Co1—O1	89.3 (2)	O19^ix—K6—O14^i	83.43 (18)
O2^vi—Co1—O1	93.9 (2)	O3^ix—K6—O14^i	135.05 (17)
O4—Co1—O1	74.7 (2)	O10—K6—O14^i	128.67 (17)
O3—Co1—O9	94.8 (2)	O18—K6—O14^i	60.69 (17)
O8^iii—Co1—O9	164.1 (2)	O8^ii—K6—O14^i	149.79 (16)
O2^vi—Co1—O9	89.6 (2)	O16^ix—K6—Mo3^ix	29.77 (13)
O4—Co1—O9	76.0 (2)	O7^ii—K6—Mo3^ix	144.49 (14)
O1—Co1—O9	75.9 (2)	O12—K6—Mo3^ix	64.59 (12)
O3—Co1—K3	49.06 (16)	O19^ix—K6—Mo3^ix	82.00 (15)
O8^iii—Co1—K3	104.73 (16)	O3^ix—K6—Mo3^ix	30.63 (11)
O2^vi—Co1—K3	47.75 (15)	O10—K6—Mo3^ix	110.83 (13)
O4—Co1—K3	138.85 (15)	O18—K6—Mo3^ix	137.40 (14)
O1—Co1—K3	139.86 (16)	O8^ii—K6—Mo3^ix	91.83 (11)
O9—Co1—K3	90.46 (14)	O14^i—K6—Mo3^ix	106.57 (13)
O3—Co1—K4^vi	105.42 (17)	O16^ix—K6—Mo2^ii	136.28 (16)
O8^iii—Co1—K4^vi	48.81 (16)	O7^ii—K6—Mo2^ii	28.66 (12)
O2^vi—Co1—K4^vi	48.57 (16)	O12—K6—Mo2^ii	116.05 (14)
O4—Co1—K4^vi	140.65 (15)	O19^ix—K6—Mo2^ii	65.97 (15)
O1—Co1—K4^vi	88.60 (15)	O3^ix—K6—Mo2^ii	88.07 (12)
O9—Co1—K4^vi	134.63 (16)	O10—K6—Mo2^ii	69.87 (12)
K3—Co1—K4^vi	74.44 (4)	O18—K6—Mo2^ii	103.06 (14)
O3—Co1—K6^vii	47.46 (16)	O8^ii—K6—Mo2^ii	29.81 (10)
O8^iii—Co1—K6^vii	52.16 (17)	O14^i—K6—Mo2^ii	120.94 (13)
O2^vi—Co1—K6^vii	108.93 (16)	Mo3^ix—K6—Mo2^ii	116.69 (6)
O4—Co1—K6^vii	87.51 (15)	O16^ix—K6—Mo5	106.25 (15)
O1—Co1—K6^vii	136.34 (15)	O7^ii—K6—Mo5	98.97 (14)
O9—Co1—K6^vii	138.38 (16)	O12—K6—Mo5	27.41 (12)
K3—Co1—K6^vii	77.18 (5)	O19^ix—K6—Mo5	150.47 (16)
K4^vi—Co1—K6^vii	80.43 (5)	O3^ix—K6—Mo5	79.40 (12)
O6^x—K1—O18^xi	154.8 (2)	O10—K6—Mo5	27.65 (11)
O6^x—K1—O17	98.0 (2)	O18—K6—Mo5	73.17 (13)
O18^xi—K1—O17	84.1 (2)	O8^ii—K6—Mo5	76.93 (11)
O6^x—K1—O7^xii	92.21 (19)	O14^i—K6—Mo5	126.09 (13)
O18^xi—K1—O7^xii	83.1 (2)	Mo3^ix—K6—Mo5	88.57 (5)
O17—K1—O7^xii	166.7 (2)	Mo2^ii—K6—Mo5	94.22 (5)
O6^x—K1—O16	83.77 (19)	Mo2—O1—Co1	130.6 (3)
O18^xi—K1—O16	120.8 (2)	Mo2—O1—Mo5	136.4 (3)
O17—K1—O16	99.5 (2)	Co1—O1—Mo5	92.7 (2)
O7^xii—K1—O16	89.92 (19)	Mo4—O2—Co1^vi	144.4 (3)
O6^x—K1—O11^i	76.90 (18)	Mo4—O2—K3^vi	109.3 (2)
O18^xi—K1—O11^i	78.55 (19)	Co1^vi—O2—K3^vi	99.0 (2)
O17—K1—O11^i	82.48 (18)	Mo4—O2—K4	93.1 (2)
O7^xii—K1—O11^i	91.68 (18)	Co1^vi—O2—K4	99.2 (2)
O16—K1—O11^i	160.65 (18)	K3^vi—O2—K4	106.57 (19)
O6^x—K1—O14	137.58 (19)	Mo3—O3—Co1	159.9 (3)
O18^xi—K1—O14	67.33 (19)	Mo3—O3—K3	89.6 (2)
O17—K1—O14	75.73 (19)	Co1—O3—K3	98.9 (2)
O7^xii—K1—O14	102.24 (19)	Mo3—O3—K6^vii	91.4 (2)
O16—K1—O14	56.98 (17)	Co1—O3—K6^vii	102.4 (2)
O11^i—K1—O14	140.89 (18)	K3—O3—K6^vii	110.49 (19)
O6^x—K1—Mo3	109.42 (15)	Mo1—O4—Co1	137.7 (3)
O18^xi—K1—Mo3	95.72 (15)	Mo1—O4—Mo5	128.4 (3)
O17—K1—Mo3	83.61 (14)	Co1—O4—Mo5	93.9 (2)
O7^xii—K1—Mo3	101.00 (13)	Mo5—O5—K3^vi	136.8 (3)
O16—K1—Mo3	28.59 (13)	Mo5—O5—K4^v	102.0 (2)
O11^i—K1—Mo3	165.42 (14)	K3^vi—O5—K4^v	108.3 (2)
O14—K1—Mo3	28.98 (12)	Mo5—O5—K3^ix	100.3 (3)
O6^x—K1—K2^i	51.89 (15)	K3^vi—O5—K3^ix	94.65 (19)
O18^xi—K1—K2^i	113.09 (17)	K4^v—O5—K3^ix	114.1 (2)
O17—K1—K2^i	55.41 (14)	Mo3—O6—K1^xiii	153.5 (3)
O7^xii—K1—K2^i	127.81 (14)	Mo3—O6—K3	97.2 (2)
O16—K1—K2^i	117.01 (14)	K1^xiii—O6—K3	101.6 (2)
O11^i—K1—K2^i	48.76 (11)	Mo3—O6—K2^vii	113.5 (3)
O14—K1—K2^i	129.93 (15)	K1^xiii—O6—K2^vii	83.27 (17)
Mo3—K1—K2^i	124.38 (6)	K3—O6—K2^vii	95.3 (2)
O6^x—K1—K6^xi	135.65 (16)	Mo2—O7—K6^ii	101.3 (2)
O18^xi—K1—K6^xi	53.66 (17)	Mo2—O7—K1^xiv	165.8 (3)
O17—K1—K6^xi	124.94 (15)	K6^ii—O7—K1^xiv	84.42 (17)
O7^xii—K1—K6^xi	47.61 (12)	Mo2—O7—K4^v	109.9 (3)
O16—K1—K6^xi	79.13 (14)	K6^ii—O7—K4^v	94.58 (18)
O11^i—K1—K6^xi	115.64 (12)	K1^xiv—O7—K4^v	82.30 (16)
O14—K1—K6^xi	57.41 (14)	Mo2—O7—K5^iii	87.0 (2)
Mo3—K1—K6^xi	69.56 (5)	K6^ii—O7—K5^iii	100.65 (18)
K2^i—K1—K6^xi	163.87 (7)	K1^xiv—O7—K5^iii	79.16 (15)
O6^x—K1—Mo1	81.21 (15)	K4^v—O7—K5^iii	154.6 (2)
O18^xi—K1—Mo1	106.54 (17)	Mo2—O8—Co1^iii	142.9 (3)
O17—K1—Mo1	24.06 (14)	Mo2—O8—K4^iv	113.1 (3)
O7^xii—K1—Mo1	169.05 (15)	Co1^iii—O8—K4^iv	99.0 (2)
O16—K1—Mo1	80.71 (13)	Mo2—O8—K6^ii	88.8 (2)
O11^i—K1—Mo1	95.30 (12)	Co1^iii—O8—K6^ii	96.1 (2)
O14—K1—Mo1	77.44 (14)	K4^iv—O8—K6^ii	112.10 (18)
Mo3—K1—Mo1	73.30 (4)	Mo4—O9—Co1	127.5 (3)
K2^i—K1—Mo1	53.73 (4)	Mo4—O9—Mo5	142.8 (3)
K6^xi—K1—Mo1	134.53 (6)	Co1—O9—Mo5	89.66 (19)
O6^x—K1—K4^i	103.68 (15)	Mo5—O10—K4^iv	136.8 (3)
O18^xi—K1—K4^i	54.26 (15)	Mo5—O10—K4^v	97.1 (2)
O17—K1—K4^i	116.12 (15)	K4^iv—O10—K4^v	106.3 (2)
O7^xii—K1—K4^i	52.69 (13)	Mo5—O10—K6	98.3 (3)
O16—K1—K4^i	141.63 (14)	K4^iv—O10—K6	102.3 (2)
O11^i—K1—K4^i	47.14 (11)	K4^v—O10—K6	117.2 (2)
O14—K1—K4^i	116.87 (13)	Mo4—O11—K2	104.6 (2)
Mo3—K1—K4^i	138.47 (6)	Mo4—O11—K4	94.8 (2)
K2^i—K1—K4^i	95.69 (6)	K2—O11—K4	160.0 (2)
K6^xi—K1—K4^i	69.31 (5)	Mo4—O11—K5^viii	91.4 (2)
Mo1—K1—K4^i	137.34 (6)	K2—O11—K5^viii	84.43 (17)
O12—K2—O14	129.2 (2)	K4—O11—K5^viii	100.34 (18)
O12—K2—O17	79.0 (2)	Mo4—O11—K1^xi	175.0 (3)
O14—K2—O17	82.5 (2)	K2—O11—K1^xi	78.38 (15)
O12—K2—O11	83.57 (19)	K4—O11—K1^xi	82.69 (15)
O14—K2—O11	87.8 (2)	K5^viii—O11—K1^xi	84.81 (16)
O17—K2—O11	147.60 (19)	Mo4—O11—K3^ix	103.8 (2)
O12—K2—O6^ix	68.39 (18)	K2—O11—K3^ix	83.83 (15)
O14—K2—O6^ix	154.49 (19)	K4—O11—K3^ix	86.69 (16)
O17—K2—O6^ix	121.9 (2)	K5^viii—O11—K3^ix	162.7 (2)
O11—K2—O6^ix	75.12 (17)	K1^xi—O11—K3^ix	80.35 (14)
O12—K2—O17^xi	151.2 (2)	Mo5—O12—K2	128.2 (3)
O14—K2—O17^xi	73.5 (2)	Mo5—O12—K3^ix	97.6 (3)
O17—K2—O17^xi	126.12 (8)	K2—O12—K3^ix	100.4 (2)
O11—K2—O17^xi	79.54 (17)	Mo5—O12—K6	103.4 (3)
O6^ix—K2—O17^xi	84.69 (18)	K2—O12—K6	112.2 (2)
O12—K2—O18^xi	148.0 (2)	K3^ix—O12—K6	114.5 (2)
O14—K2—O18^xi	64.42 (19)	Mo4—O13—K3	130.5 (3)
O17—K2—O18^xi	74.38 (18)	Mo4—O13—K5^viii	101.6 (3)
O11—K2—O18^xi	128.19 (18)	K3—O13—K5^viii	127.0 (2)
O6^ix—K2—O18^xi	111.79 (18)	Mo3—O14—K2	133.0 (4)
O17^xi—K2—O18^xi	51.79 (17)	Mo3—O14—K5^viii	110.7 (3)
O12—K2—O19^xi	117.83 (19)	K2—O14—K5^viii	89.3 (2)
O14—K2—O19^xi	111.2 (2)	Mo3—O14—K1	92.0 (3)
O17—K2—O19^xi	97.68 (19)	K2—O14—K1	89.83 (19)
O11—K2—O19^xi	114.62 (18)	K5^viii—O14—K1	149.2 (2)
O6^ix—K2—O19^xi	61.58 (18)	Mo3—O14—K6^xi	107.1 (3)
O17^xi—K2—O19^xi	51.61 (17)	K2—O14—K6^xi	117.8 (2)
O18^xi—K2—O19^xi	50.33 (17)	K5^viii—O14—K6^xi	82.11 (17)
O12—K2—Mo1^xi	147.33 (15)	K1—O14—K6^xi	71.19 (15)
O14—K2—Mo1^xi	82.27 (15)	Mo2—O15—K4^vi	133.8 (3)
O17—K2—Mo1^xi	100.03 (14)	Mo2—O15—K5^iii	110.2 (3)
O11—K2—Mo1^xi	109.22 (13)	K4^vi—O15—K5^iii	112.4 (2)
O6^ix—K2—Mo1^xi	85.57 (13)	Mo3—O16—K5^xiii	145.2 (3)
O17^xi—K2—Mo1^xi	30.57 (12)	Mo3—O16—K6^vii	99.4 (3)
O18^xi—K2—Mo1^xi	29.77 (11)	K5^xiii—O16—K6^vii	99.8 (2)
O19^xi—K2—Mo1^xi	29.52 (12)	Mo3—O16—K1	101.5 (3)
O12—K2—Mo4	75.58 (14)	K5^xiii—O16—K1	93.9 (2)
O14—K2—Mo4	74.43 (15)	K6^vii—O16—K1	119.5 (2)
O17—K2—Mo4	120.80 (15)	Mo1—O17—K2	114.8 (3)
O11—K2—Mo4	27.23 (11)	Mo1—O17—K1	115.7 (3)
O6^ix—K2—Mo4	96.37 (13)	K2—O17—K1	94.9 (2)
O17^xi—K2—Mo4	98.25 (12)	Mo1—O17—K5^xi	146.5 (3)
O18^xi—K2—Mo4	133.95 (14)	K2—O17—K5^xi	81.80 (18)
O19^xi—K2—Mo4	141.43 (14)	K1—O17—K5^xi	89.92 (18)
Mo1^xi—K2—Mo4	128.63 (6)	Mo1—O17—K2^i	84.4 (2)
O12—K2—K1^xi	104.24 (15)	K2—O17—K2^i	160.6 (2)
O14—K2—K1^xi	109.66 (15)	K1—O17—K2^i	77.52 (17)
O17—K2—K1^xi	158.67 (16)	K5^xi—O17—K2^i	80.43 (16)
O11—K2—K1^xi	52.86 (12)	Mo1—O18—K1^i	165.6 (4)
O6^ix—K2—K1^xi	44.84 (11)	Mo1—O18—K6	102.6 (3)
O17^xi—K2—K1^xi	47.08 (13)	K1^i—O18—K6	80.55 (19)
O18^xi—K2—K1^xi	94.65 (12)	Mo1—O18—K4^iv	111.8 (3)
O19^xi—K2—K1^xi	61.90 (14)	K1^i—O18—K4^iv	82.22 (18)
Mo1^xi—K2—K1^xi	65.66 (5)	K6—O18—K4^iv	88.1 (2)
Mo4—K2—K1^xi	80.04 (5)	Mo1—O18—K5	91.3 (3)
O12—K2—K5^xi	94.56 (15)	K1^i—O18—K5	85.28 (19)
O14—K2—K5^xi	109.56 (16)	K6—O18—K5	165.8 (2)
O17—K2—K5^xi	51.43 (14)	K4^iv—O18—K5	89.00 (17)
O11—K2—K5^xi	158.21 (14)	Mo1—O18—K2^i	80.1 (3)
O6^ix—K2—K5^xi	83.99 (13)	K1^i—O18—K2^i	85.58 (18)
O17^xi—K2—K5^xi	92.62 (13)	K6—O18—K2^i	109.4 (2)
O18^xi—K2—K5^xi	54.73 (13)	K4^iv—O18—K2^i	156.7 (2)
O19^xi—K2—K5^xi	47.59 (13)	K5—O18—K2^i	70.19 (16)
Mo1^xi—K2—K5^xi	62.26 (5)	Mo1—O19—K5	105.5 (3)
Mo4—K2—K5^xi	169.11 (7)	Mo1—O19—K6^vii	129.9 (4)
K1^xi—K2—K5^xi	107.29 (7)	K5—O19—K6^vii	110.0 (2)
O5^vi—K3—O6	129.76 (19)	Mo1—O19—K2^i	79.4 (3)
O5^vi—K3—O13	100.21 (19)	K5—O19—K2^i	74.58 (18)
O6—K3—O13	71.74 (19)	K6^vii—O19—K2^i	143.4 (3)

Symmetry codes: (i) −x+1/2, y+1/2, −z+1/2; (ii) −x, −y+1, −z; (iii) −x+1, −y+1, −z; (iv) x, y+1, z; (v) −x, −y, −z; (vi) −x+1, −y, −z; (vii) x+1, y, z; (viii) x, y−1, z; (ix) x−1, y, z; (x) −x+3/2, y+1/2, −z+1/2; (xi) −x+1/2, y−1/2, −z+1/2; (xii) x+1/2, −y+1/2, z+1/2; (xiii) −x+3/2, y−1/2, −z+1/2; (xiv) x−1/2, −y+1/2, z−1/2.