
Leonotinin has been elucidated as 8
,17:9,13-diepoxylabdane-16,15:19,6
- diolactone, [2aS-(2a
,5a
,6
,7
,8a
,8b
)]-6-[2-(3-furanyl)ethyl]octahydro- 6-hydroxy-2a,5a-dimethylspiro[2H-naphtho[1,8-bc]furan-7(3H),2'-oxiran]-2-one, C20H26O5. The furan ring is exocyclic to the fused ring system. The three-membered oxirane ring is inclined to the furan ring at 67.4 (5)°. The packing of the molecules in the unit cell is purely the result of van der Waals interactions.
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Supporting information
![]() | Crystallographic Information File (CIF) |
CCDC reference: 127138