Bis­[μ-bis­(di­phenyl­phosphino)­methane]­digold(I) bis­(hexa­fluoro­phosphate) di­chloro­methane disolvate

The dication in the title compound, [Au₂(C₂₅H₂₂P₂)₂](PF₆)₂·2CH₂Cl₂ or [Au₂(μ-dppm)₂](PF₆)₂·2CH₂Cl₂, where dppm is bis­(di­phenyl­phosphino)­methane, is situated about a twofold axis and each anion lies on a mirror plane. Each Au atom is two-coordinate and exists in an approximately linear geometry.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.026 Å
• R factor = 0.066
• wR factor = 0.160
• Data-to-parameter ratio = 14.5

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry

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S1. Comment

Binuclear complexes of gold with certain bidentate ligands are of interest owing to their rich luminescence and bonding properties (Jaw et al., 1989; Khan et al., 1988; King et al., 1989). In this context, several compounds of binuclear [Au₂(µ-dppm)₂]²⁺ have been characterized previously (Jaw et al., 1989; Khan et al., 1989; Porter et al., 1989; Liou et al., 1994; Wang et al., 1994; Bauer et al., 1997) counterbalanced by various anionic species. Herein, we described another crystal structure determination of the dication but isolated as the hexafluorophosphate salt, i.e. [Au₂(µ-dppm)₂](PF₆)₂·2CH₂Cl₂, (I) (Fig. 1 and Table 1).

The asymmetric unit of (I) comprises half a dication, [Au₂(µ-dppm)₂]²⁺, situated about a twofold axis of symmetry, two independent PF₆⁻ anions, each lying on Au gold atoms are doubly bridged by two dppm ligands. The Au center exists in the expected linear geometry with the P1—Au—P2 angle being 177.85 (13)°. The intramolecular Au···Au separation is 2.9792 (10) Å. The overall molecular geometry is in essential agreement with the previously determined structures cited above.

S2. Experimental

The title compound was synthesized by a modification of a literature procedure (Porter et al., 1989). The complex was obtained by the reaction between [Au₂(µ-dppm)₂]Cl₂ and AgPF₆ in a 1:2 ratio in acetonitrile solution under anaerobic conditions for 12 h. After the white precipitate, AgCl, was filtered off, the solution was evaporated under vacuum affording [Au₂(µ-dppm)₂](PF₆)₂ in good yield. Well formed colorless crystals suitable for X-ray diffraction measurements were grown by the slow diffusion of diethyl ether into a mixture of dichloromethane and a minimum of acetonitrile at room temperature.

S3. Refinement

The positions of the H atoms were generated geometrically (C—H bonds lengths were fixed at 0.96 Å), assigned isotropic displacement parameters and allowed to ride on their respective parent C atoms. The maximum (?) residual electron-density peak was located near the Au atom.

Computing details

Data collection: SMART (Siemens, 1996); cell refinement: SMART and SAINT (Siemens, 1994); data reduction: XPREP in SHELXTL (Siemens, 1994); program(s) used to solve structure: SHELXTL; program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Figures

Fig. 1. View of the dication of (I), showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.

Bis[bis(diphenylphosphino)methane)digold(I) bishexafluorophosphatedichloromethane disolvate

Crystal data

[Au2(C25H22P2)2](PF6)2·2C2H4Cl4	F(000) = 3136
Mr = 1622.46	Dx = 1.869 Mg m^−3
Orthorhombic, Pnma	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2n	Cell parameters from 4469 reflections
a = 20.6825 (10) Å	θ = 1.8–25.1°
b = 21.0325 (9) Å	µ = 5.51 mm^−1
c = 13.2577 (6) Å	T = 293 K
V = 5767.2 (5) Å^3	Block, colorless
Z = 4	0.42 × 0.40 × 0.20 mm

Data collection

Siemens SMART CCD diffractometer	5246 independent reflections
Radiation source: fine-focus sealed tube	3249 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.097
ω scans	θmax = 25.1°, θmin = 1.8°
Absorption correction: empirical (using intensity measurements) (SADABS; Sheldrick, 1996)	h = −24→24
Tmin = 0.121, Tmax = 0.332	k = −20→25
16736 measured reflections	l = −15→13

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.066	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.160	H-atom parameters constrained
S = 1.13	w = 1[s^2(Fo^2) + (0.0355P)^2 + 11.5869P] where P = (Fo^2 + 2Fc^2)3
5246 reflections	(Δ/σ)max = 0.001
361 parameters	Δρmax = 1.79 e Å^−3
10 restraints	Δρmin = −1.15 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Au	0.89681 (2)	0.17918 (2)	0.06337 (4)	0.03926 (18)
Cl1	1.0149 (6)	0.0193 (5)	0.6436 (7)	0.217 (5)
Cl2	1.1365 (4)	−0.0067 (4)	0.7345 (7)	0.164 (3)
P1	0.79368 (14)	0.17692 (18)	−0.0043 (3)	0.0394 (8)
P2	0.99966 (14)	0.17747 (17)	0.1328 (2)	0.0349 (7)
P3	0.7473 (3)	0.7500	0.8759 (5)	0.0579 (16)
P4	0.4626 (3)	0.7500	0.2775 (5)	0.0674 (19)
F11	0.7454 (6)	0.8237 (5)	0.8747 (8)	0.105 (4)
F12	0.7942 (6)	0.7500	0.9696 (9)	0.082 (4)
F13	0.8062 (6)	0.7500	0.8012 (10)	0.108 (6)
F14	0.7022 (5)	0.7500	0.7778 (9)	0.079 (4)
F15	0.6863 (6)	0.7500	0.9475 (10)	0.094 (5)
F21	0.4632 (11)	0.6818 (7)	0.2741 (19)	0.303 (17)
F22	0.5104 (8)	0.7500	0.3672 (12)	0.211 (15)
F23	0.5215 (7)	0.7500	0.2021 (11)	0.121 (6)
F24	0.4179 (8)	0.7500	0.1869 (15)	0.31 (3)
F25	0.4039 (6)	0.7500	0.3539 (11)	0.128 (7)
C1	0.7496 (8)	0.2500	0.0251 (14)	0.038 (5)
H1A	0.7093	0.2500	−0.0123	0.046*
H1B	0.7390	0.2500	0.0963	0.046*
C01	1.0786 (15)	0.0484 (14)	0.699 (3)	0.209 (18)
H01A	1.0647	0.0712	0.7590	0.250*
H01B	1.0986	0.0790	0.6543	0.250*
C2	1.0434 (8)	0.2500	0.1018 (14)	0.035 (4)
H2A	1.0843	0.2500	0.1377	0.041*
H2B	1.0529	0.2500	0.0301	0.041*
C11	0.7452 (6)	0.1135 (6)	0.0494 (11)	0.040 (3)
C12	0.7378 (8)	0.1131 (8)	0.1551 (13)	0.069 (5)
H12A	0.7565	0.1451	0.1937	0.082*
C13	0.7032 (9)	0.0658 (8)	0.2013 (16)	0.085 (6)
H13A	0.6957	0.0674	0.2704	0.101*
C14	0.6794 (10)	0.0158 (10)	0.145 (2)	0.107 (9)
H14A	0.6571	−0.0171	0.1767	0.128*
C15	0.6889 (10)	0.0150 (8)	0.0449 (19)	0.097 (7)
H15A	0.6735	−0.0192	0.0075	0.116*
C16	0.7209 (7)	0.0635 (7)	−0.0037 (14)	0.066 (5)
H16A	0.7259	0.0622	−0.0734	0.079*
C21	0.7921 (6)	0.1684 (6)	−0.1397 (10)	0.045 (4)
C22	0.7340 (8)	0.1692 (8)	−0.1926 (15)	0.077 (5)
H22A	0.6947	0.1723	−0.1588	0.093*
C23	0.7360 (10)	0.1652 (8)	−0.2969 (14)	0.075 (5)
H23A	0.6975	0.1672	−0.3330	0.091*
C24	0.7919 (11)	0.1586 (8)	−0.3474 (13)	0.081 (6)
H24A	0.7920	0.1555	−0.4174	0.097*
C25	0.8489 (9)	0.1566 (8)	−0.2944 (15)	0.073 (5)
H25A	0.8878	0.1524	−0.3288	0.087*
C26	0.8491 (7)	0.1607 (7)	−0.1901 (12)	0.059 (4)
H26A	0.8878	0.1581	−0.1547	0.071*
C31	1.0006 (6)	0.1692 (7)	0.2668 (10)	0.046 (4)
C32	0.9441 (9)	0.1680 (8)	0.3219 (13)	0.076 (5)
H32A	0.9046	0.1701	0.2886	0.092*
C33	0.9454 (11)	0.1637 (10)	0.4269 (13)	0.093 (7)
H33A	0.9071	0.1630	0.4636	0.112*
C34	1.0040 (11)	0.1606 (9)	0.4753 (13)	0.083 (6)
H34A	1.0055	0.1588	0.5453	0.100*
C35	1.0586 (10)	0.1602 (9)	0.4223 (13)	0.079 (6)
H35A	1.0980	0.1566	0.4556	0.095*
C36	1.0576 (7)	0.1650 (8)	0.3203 (12)	0.063 (5)
H36A	1.0965	0.1655	0.2853	0.075*
C41	1.0487 (6)	0.1122 (6)	0.0869 (9)	0.036 (3)
C42	1.1027 (8)	0.1183 (8)	0.0261 (15)	0.084 (6)
H42A	1.1164	0.1580	0.0041	0.101*
C43	1.1356 (9)	0.0639 (11)	−0.0012 (19)	0.107 (8)
H43A	1.1719	0.0684	−0.0420	0.128*
C44	1.1191 (8)	0.0067 (9)	0.0265 (15)	0.077 (5)
H44A	1.1431	−0.0285	0.0063	0.092*
C45	1.0652 (11)	−0.0004 (9)	0.0863 (18)	0.110 (8)
H45A	1.0514	−0.0406	0.1059	0.132*
C46	1.0321 (9)	0.0530 (8)	0.1166 (16)	0.093 (7)
H46A	0.9969	0.0481	0.1594	0.112*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Au	0.0234 (2)	0.0362 (3)	0.0581 (3)	−0.0001 (2)	−0.0057 (2)	−0.0006 (3)
Cl1	0.257 (12)	0.202 (11)	0.190 (8)	0.000 (9)	−0.043 (9)	0.091 (8)
Cl2	0.160 (7)	0.145 (7)	0.186 (7)	0.003 (6)	0.057 (6)	0.023 (6)
P1	0.0210 (16)	0.0395 (19)	0.058 (2)	0.0005 (16)	−0.0047 (15)	−0.0070 (19)
P2	0.0224 (15)	0.0340 (18)	0.0484 (19)	−0.0004 (15)	−0.0036 (14)	0.0018 (18)
P3	0.033 (3)	0.078 (5)	0.063 (4)	0.000	0.000 (3)	0.000
P4	0.042 (3)	0.090 (6)	0.071 (4)	0.000	0.004 (3)	0.000
F11	0.132 (10)	0.091 (9)	0.092 (8)	−0.014 (8)	−0.022 (7)	0.002 (7)
F12	0.048 (7)	0.142 (14)	0.056 (8)	0.000	−0.022 (6)	0.000
F13	0.044 (8)	0.206 (19)	0.072 (9)	0.000	0.010 (7)	0.000
F14	0.045 (7)	0.123 (12)	0.070 (9)	0.000	−0.018 (7)	0.000
F15	0.075 (9)	0.125 (13)	0.083 (10)	0.000	0.007 (8)	0.000
F21	0.40 (4)	0.083 (12)	0.43 (4)	−0.077 (17)	0.21 (3)	−0.053 (17)
F22	0.077 (13)	0.49 (5)	0.069 (11)	0.000	−0.007 (10)	0.000
F23	0.070 (10)	0.20 (2)	0.088 (11)	0.000	0.018 (9)	0.000
F24	0.060 (13)	0.77 (9)	0.106 (16)	0.000	0.005 (12)	0.000
F25	0.054 (9)	0.24 (2)	0.093 (11)	0.000	0.012 (9)	0.000
C1	0.026 (9)	0.039 (11)	0.050 (11)	0.000	−0.006 (8)	0.000
C01	0.16 (3)	0.10 (2)	0.36 (6)	−0.04 (2)	0.09 (3)	0.02 (3)
C2	0.020 (9)	0.029 (10)	0.055 (12)	0.000	0.008 (8)	0.000
C11	0.024 (6)	0.025 (7)	0.069 (10)	0.000 (5)	0.004 (7)	0.006 (7)
C12	0.073 (12)	0.060 (12)	0.073 (12)	−0.015 (9)	0.004 (9)	0.006 (9)
C13	0.096 (14)	0.052 (11)	0.106 (15)	−0.007 (11)	0.025 (12)	0.024 (11)
C14	0.077 (14)	0.064 (14)	0.18 (2)	−0.018 (11)	0.052 (16)	0.036 (16)
C15	0.081 (14)	0.040 (10)	0.17 (2)	−0.025 (10)	0.008 (15)	0.016 (13)
C16	0.067 (11)	0.041 (10)	0.089 (12)	−0.016 (8)	−0.005 (10)	−0.012 (9)
C21	0.043 (8)	0.041 (9)	0.051 (8)	−0.011 (7)	−0.007 (7)	0.000 (7)
C22	0.046 (9)	0.089 (14)	0.097 (14)	0.012 (9)	−0.026 (9)	−0.018 (12)
C23	0.096 (14)	0.070 (13)	0.061 (12)	0.014 (11)	−0.032 (11)	−0.004 (10)
C24	0.131 (19)	0.062 (12)	0.050 (11)	0.013 (12)	0.007 (12)	0.004 (9)
C25	0.073 (12)	0.063 (12)	0.083 (13)	−0.008 (9)	0.003 (11)	0.001 (10)
C26	0.050 (9)	0.070 (12)	0.058 (10)	−0.010 (8)	0.011 (8)	−0.006 (9)
C31	0.033 (7)	0.057 (10)	0.049 (8)	−0.002 (7)	0.007 (6)	−0.004 (7)
C32	0.068 (11)	0.086 (14)	0.075 (12)	0.024 (10)	0.020 (10)	0.014 (11)
C33	0.098 (15)	0.123 (19)	0.059 (12)	0.046 (13)	0.022 (11)	0.018 (12)
C34	0.114 (17)	0.080 (14)	0.055 (11)	0.038 (12)	0.003 (12)	0.011 (10)
C35	0.075 (13)	0.105 (16)	0.057 (11)	−0.006 (11)	−0.023 (10)	0.009 (10)
C36	0.039 (8)	0.094 (14)	0.055 (10)	−0.002 (8)	−0.006 (7)	0.005 (9)
C41	0.035 (7)	0.028 (8)	0.043 (8)	0.001 (5)	−0.006 (6)	0.001 (6)
C42	0.077 (12)	0.038 (9)	0.138 (17)	0.007 (9)	0.047 (13)	−0.002 (10)
C43	0.073 (13)	0.082 (16)	0.17 (2)	0.004 (12)	0.051 (14)	−0.017 (15)
C44	0.059 (11)	0.055 (12)	0.116 (15)	0.012 (9)	0.013 (10)	−0.025 (11)
C45	0.109 (17)	0.040 (11)	0.18 (2)	0.014 (11)	0.037 (17)	0.005 (13)
C46	0.095 (14)	0.045 (11)	0.139 (17)	0.015 (10)	0.056 (13)	0.001 (11)

Geometric parameters (Å, º)

Au—P1	2.314 (3)	C14—H14A	0.9300
Au—P2	2.318 (3)	C15—C16	1.38 (2)
Au—Au^i	2.9792 (10)	C15—H15A	0.9300
Cl1—C01	1.63 (3)	C16—H16A	0.9300
Cl2—C01	1.73 (3)	C21—C26	1.365 (19)
P1—C21	1.804 (14)	C21—C22	1.392 (19)
P1—C11	1.815 (13)	C22—C23	1.39 (2)
P1—C1	1.829 (10)	C22—H22A	0.9300
P2—C31	1.786 (13)	C23—C24	1.34 (2)
P2—C41	1.811 (13)	C23—H23A	0.9300
P2—C2	1.821 (9)	C24—C25	1.37 (2)
P3—F11	1.551 (11)	C24—H24A	0.9300
P3—F11^ii	1.551 (11)	C25—C26	1.38 (2)
P3—F13	1.570 (13)	C25—H25A	0.9300
P3—F12	1.577 (12)	C26—H26A	0.9300
P3—F15	1.579 (14)	C31—C32	1.377 (19)
P3—F14	1.599 (12)	C31—C36	1.378 (18)
P4—F21	1.435 (15)	C32—C33	1.40 (2)
P4—F21^ii	1.435 (15)	C32—H32A	0.9300
P4—F24	1.516 (19)	C33—C34	1.37 (3)
P4—F22	1.547 (16)	C33—H33A	0.9300
P4—F23	1.576 (14)	C34—C35	1.33 (2)
P4—F25	1.581 (14)	C34—H34A	0.9300
C1—P1^i	1.829 (10)	C35—C36	1.36 (2)
C1—H1A	0.9700	C35—H35A	0.9300
C1—H1B	0.9700	C36—H36A	0.9300
C01—H01A	0.9700	C41—C46	1.35 (2)
C01—H01B	0.9700	C41—C42	1.383 (19)
C2—P2^i	1.821 (9)	C42—C43	1.38 (2)
C2—H2A	0.9700	C42—H42A	0.9300
C2—H2B	0.9700	C43—C44	1.30 (3)
C11—C16	1.360 (19)	C43—H43A	0.9300
C11—C12	1.41 (2)	C44—C45	1.38 (3)
C12—C13	1.37 (2)	C44—H44A	0.9300
C12—H12A	0.9300	C45—C46	1.37 (2)
C13—C14	1.38 (3)	C45—H45A	0.9300
C13—H13A	0.9300	C46—H46A	0.9300
C14—C15	1.35 (3)
P1—Au—P2	177.85 (13)	C11—C12—H12A	119.8
P1—Au—Au^i	91.18 (10)	C12—C13—C14	120.0 (19)
P2—Au—Au^i	90.89 (9)	C12—C13—H13A	120.0
C21—P1—C11	107.9 (7)	C14—C13—H13A	120.0
C21—P1—C1	106.6 (8)	C15—C14—C13	119.4 (18)
C11—P1—C1	105.0 (6)	C15—C14—H14A	120.3
C21—P1—Au	113.9 (5)	C13—C14—H14A	120.3
C11—P1—Au	111.9 (4)	C14—C15—C16	122 (2)
C1—P1—Au	111.1 (5)	C14—C15—H15A	119.2
C31—P2—C41	104.7 (6)	C16—C15—H15A	119.2
C31—P2—C2	107.5 (8)	C11—C16—C15	120.5 (18)
C41—P2—C2	106.3 (6)	C11—C16—H16A	119.8
C31—P2—Au	114.0 (4)	C15—C16—H16A	119.8
C41—P2—Au	113.1 (4)	C26—C21—C22	120.0 (14)
C2—P2—Au	110.7 (5)	C26—C21—P1	118.9 (11)
F11—P3—F11^ii	176.9 (10)	C22—C21—P1	121.1 (12)
F11—P3—F13	90.8 (5)	C23—C22—C21	118.5 (17)
F11^ii—P3—F13	90.8 (5)	C23—C22—H22A	120.8
F11—P3—F12	91.3 (5)	C21—C22—H22A	120.8
F11^ii—P3—F12	91.3 (5)	C24—C23—C22	122.0 (17)
F13—P3—F12	91.0 (7)	C24—C23—H23A	119.0
F11—P3—F15	89.2 (5)	C22—C23—H23A	119.0
F11^ii—P3—F15	89.2 (5)	C23—C24—C25	119.1 (17)
F13—P3—F15	177.9 (8)	C23—C24—H24A	120.4
F12—P3—F15	91.0 (7)	C25—C24—H24A	120.4
F11—P3—F14	88.7 (5)	C24—C25—C26	120.8 (18)
F11^ii—P3—F14	88.7 (5)	C24—C25—H25A	119.6
F13—P3—F14	86.5 (7)	C26—C25—H25A	119.6
F12—P3—F14	177.6 (7)	C21—C26—C25	119.6 (16)
F15—P3—F14	91.4 (7)	C21—C26—H26A	120.2
F21—P4—F21^ii	176.3 (19)	C25—C26—H26A	120.2
F21—P4—F24	88.9 (12)	C32—C31—C36	116.9 (14)
F21^ii—P4—F24	88.9 (12)	C32—C31—P2	121.4 (12)
F21—P4—F22	91.1 (12)	C36—C31—P2	121.8 (10)
F21^ii—P4—F22	91.1 (12)	C31—C32—C33	120.9 (18)
F24—P4—F22	177.8 (10)	C31—C32—H32A	119.5
F21—P4—F23	88.5 (8)	C33—C32—H32A	119.5
F21^ii—P4—F23	88.5 (8)	C34—C33—C32	119.1 (18)
F24—P4—F23	88.2 (9)	C34—C33—H33A	120.5
F22—P4—F23	89.6 (9)	C32—C33—H33A	120.5
F21—P4—F25	91.5 (8)	C35—C34—C33	120.2 (16)
F21^ii—P4—F25	91.5 (8)	C35—C34—H34A	119.9
F24—P4—F25	92.2 (9)	C33—C34—H34A	119.9
F22—P4—F25	89.9 (8)	C34—C35—C36	120.9 (17)
F23—P4—F25	179.6 (9)	C34—C35—H35A	119.6
P1^i—C1—P1	114.4 (9)	C36—C35—H35A	119.6
P1^i—C1—H1A	108.7	C35—C36—C31	122.0 (16)
P1—C1—H1A	108.7	C35—C36—H36A	119.0
P1^i—C1—H1B	108.7	C31—C36—H36A	119.0
P1—C1—H1B	108.7	C46—C41—C42	117.3 (13)
H1A—C1—H1B	107.6	C46—C41—P2	117.3 (11)
Cl1—C01—Cl2	115.5 (18)	C42—C41—P2	125.3 (11)
Cl1—C01—H01A	108.4	C43—C42—C41	118.4 (16)
Cl2—C01—H01A	108.4	C43—C42—H42A	120.8
Cl1—C01—H01B	108.4	C41—C42—H42A	120.8
Cl2—C01—H01B	108.4	C44—C43—C42	124.2 (19)
H01A—C01—H01B	107.5	C44—C43—H43A	117.9
P2^i—C2—P2	113.8 (9)	C42—C43—H43A	117.9
P2^i—C2—H2A	108.8	C43—C44—C45	118.3 (17)
P2—C2—H2A	108.8	C43—C44—H44A	120.8
P2^i—C2—H2B	108.8	C45—C44—H44A	120.8
P2—C2—H2B	108.8	C46—C45—C44	119.0 (18)
H2A—C2—H2B	107.7	C46—C45—H45A	120.5
C16—C11—C12	118.0 (14)	C44—C45—H45A	120.5
C16—C11—P1	124.6 (13)	C41—C46—C45	122.8 (17)
C12—C11—P1	117.0 (11)	C41—C46—H46A	118.6
C13—C12—C11	120.3 (17)	C45—C46—H46A	118.6
C13—C12—H12A	119.8

Symmetry codes: (i) x, −y+1/2, z; (ii) x, −y+3/2, z.