Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802008978/wn6099sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536802008978/wn6099Isup2.hkl |
CCDC reference: 189305
Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SHELXTL (Bruker, 2000); program(s) used to solve structure: PATTY in DIRDIF92 (Beurskens et al., 1992); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97 and PLATON (Spek, 2000).
[Sn6O6(C3H7)6(C2H3O2)6]·4CHCl3 | F(000) = 1832 |
Mr = 1898.39 | Dx = 2.022 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71069 Å |
Hall symbol: -P 2ybc | Cell parameters from 25440 reflections |
a = 13.2736 (14) Å | θ = 1.5–30.1° |
b = 13.5405 (16) Å | µ = 2.94 mm−1 |
c = 17.3572 (19) Å | T = 193 K |
β = 92.007 (3)° | Block, colourless |
V = 3117.7 (6) Å3 | 0.20 × 0.10 × 0.05 mm |
Z = 2 |
Bruker AXS SMART CCD diffractometer | 9084 independent reflections |
Radiation source: fine-focus sealed tube | 6796 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.051 |
ω scans | θmax = 30.1°, θmin = 1.5° |
Absorption correction: multi-scan (SADABS; Bruker, 2000) | h = −17→18 |
Tmin = 0.683, Tmax = 0.863 | k = −15→19 |
25440 measured reflections | l = −24→20 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.042 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.091 | H-atom parameters constrained |
S = 1.01 | w = 1/[σ2(Fo2) + (0.0368P)2] where P = (Fo2 + 2Fc2)/3 |
9084 reflections | (Δ/σ)max = 0.001 |
316 parameters | Δρmax = 1.33 e Å−3 |
0 restraints | Δρmin = −0.71 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Sn1 | −0.15982 (2) | 0.06291 (2) | 0.551298 (16) | 0.01713 (7) | |
Sn2 | 0.05108 (2) | 0.01965 (2) | 0.639897 (16) | 0.01706 (7) | |
Sn3 | 0.09790 (2) | 0.15655 (2) | 0.495538 (16) | 0.01682 (7) | |
Cl1 | 0.55261 (12) | 0.21831 (13) | 0.73749 (10) | 0.0601 (4) | |
Cl2 | 0.44219 (14) | 0.09192 (14) | 0.63131 (10) | 0.0616 (4) | |
Cl3 | 0.54342 (15) | 0.00896 (14) | 0.76583 (10) | 0.0652 (5) | |
Cl4 | 0.45731 (13) | 0.35390 (14) | 0.55989 (12) | 0.0687 (5) | |
Cl5 | 0.28630 (14) | 0.48248 (13) | 0.54934 (10) | 0.0602 (4) | |
Cl6 | 0.38157 (15) | 0.42224 (14) | 0.41133 (10) | 0.0673 (5) | |
O1 | −0.0184 (2) | 0.1262 (2) | 0.57069 (16) | 0.0183 (6) | |
O2 | −0.0759 (2) | −0.0563 (2) | 0.59474 (15) | 0.0180 (6) | |
O3 | 0.1467 (2) | 0.0252 (2) | 0.54708 (16) | 0.0191 (6) | |
O4 | −0.1925 (2) | 0.0999 (2) | 0.66962 (17) | 0.0253 (7) | |
O5 | −0.0450 (2) | 0.0671 (2) | 0.73157 (17) | 0.0235 (7) | |
O6 | 0.1410 (2) | 0.1383 (2) | 0.69017 (17) | 0.0257 (7) | |
O7 | 0.1771 (2) | 0.2330 (2) | 0.58902 (16) | 0.0249 (7) | |
O8 | 0.2487 (2) | 0.1756 (2) | 0.45239 (18) | 0.0241 (7) | |
O9 | 0.2959 (2) | 0.0207 (2) | 0.42572 (18) | 0.0235 (7) | |
C1 | −0.1356 (4) | 0.0937 (3) | 0.7296 (3) | 0.0241 (9) | |
C2 | −0.1815 (4) | 0.1204 (4) | 0.8043 (3) | 0.0361 (12) | |
H2A | −0.2521 | 0.1394 | 0.7948 | 0.054* | |
H2B | −0.1443 | 0.1758 | 0.8279 | 0.054* | |
H2C | −0.1781 | 0.0634 | 0.8391 | 0.054* | |
C3 | 0.1828 (3) | 0.2113 (4) | 0.6598 (3) | 0.0239 (9) | |
C4 | 0.2442 (4) | 0.2794 (4) | 0.7117 (3) | 0.0364 (12) | |
H4A | 0.2717 | 0.3331 | 0.6809 | 0.055* | |
H4B | 0.2996 | 0.2423 | 0.7367 | 0.055* | |
H4C | 0.2012 | 0.3070 | 0.7510 | 0.055* | |
C5 | 0.3115 (3) | 0.1124 (4) | 0.4301 (2) | 0.0241 (9) | |
C6 | 0.4113 (4) | 0.1502 (4) | 0.4049 (3) | 0.0389 (13) | |
H6A | 0.4528 | 0.0947 | 0.3886 | 0.058* | |
H6B | 0.4457 | 0.1846 | 0.4480 | 0.058* | |
H6C | 0.4005 | 0.1962 | 0.3618 | 0.058* | |
C7 | −0.2387 (3) | 0.1866 (3) | 0.5006 (3) | 0.0247 (9) | |
H7 | −0.1910 | 0.2193 | 0.4653 | 0.030* | |
C8 | −0.2667 (4) | 0.2636 (4) | 0.5601 (3) | 0.0428 (14) | |
H8A | −0.2065 | 0.2821 | 0.5911 | 0.064* | |
H8B | −0.3174 | 0.2361 | 0.5938 | 0.064* | |
H8C | −0.2942 | 0.3222 | 0.5337 | 0.064* | |
C9 | −0.3286 (4) | 0.1547 (5) | 0.4517 (3) | 0.0449 (14) | |
H9A | −0.3078 | 0.1050 | 0.4144 | 0.067* | |
H9B | −0.3571 | 0.2120 | 0.4242 | 0.067* | |
H9C | −0.3796 | 0.1263 | 0.4847 | 0.067* | |
C10 | 0.1208 (3) | −0.0964 (3) | 0.7072 (3) | 0.0252 (9) | |
H10 | 0.1412 | −0.1484 | 0.6699 | 0.030* | |
C11 | 0.0456 (4) | −0.1449 (4) | 0.7600 (3) | 0.0395 (13) | |
H11A | −0.0144 | −0.1654 | 0.7295 | 0.059* | |
H11B | 0.0260 | −0.0975 | 0.7995 | 0.059* | |
H11C | 0.0767 | −0.2028 | 0.7849 | 0.059* | |
C12 | 0.2162 (4) | −0.0639 (4) | 0.7504 (3) | 0.0400 (13) | |
H12A | 0.2621 | −0.0336 | 0.7143 | 0.060* | |
H12B | 0.2488 | −0.1213 | 0.7749 | 0.060* | |
H12C | 0.1992 | −0.0157 | 0.7900 | 0.060* | |
C13 | 0.0328 (3) | 0.2876 (3) | 0.4458 (3) | 0.0233 (9) | |
H13 | −0.0296 | 0.2665 | 0.4163 | 0.028* | |
C14 | −0.0014 (4) | 0.3583 (4) | 0.5089 (3) | 0.0390 (13) | |
H14A | −0.0444 | 0.3227 | 0.5443 | 0.059* | |
H14B | −0.0395 | 0.4131 | 0.4852 | 0.059* | |
H14C | 0.0578 | 0.3843 | 0.5375 | 0.059* | |
C15 | 0.0983 (4) | 0.3397 (4) | 0.3890 (3) | 0.0390 (13) | |
H15A | 0.1187 | 0.2928 | 0.3494 | 0.059* | |
H15B | 0.1585 | 0.3660 | 0.4161 | 0.059* | |
H15C | 0.0604 | 0.3940 | 0.3645 | 0.059* | |
C16 | 0.5475 (4) | 0.1013 (4) | 0.6944 (3) | 0.0390 (13) | |
H16 | 0.6096 | 0.0916 | 0.6644 | 0.047* | |
C17 | 0.3504 (4) | 0.3870 (4) | 0.5044 (3) | 0.0393 (12) | |
H17 | 0.3047 | 0.3283 | 0.5004 | 0.047* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Sn1 | 0.01496 (13) | 0.01916 (15) | 0.01732 (14) | 0.00026 (11) | 0.00110 (10) | −0.00110 (10) |
Sn2 | 0.01705 (14) | 0.01957 (15) | 0.01451 (13) | −0.00099 (11) | −0.00036 (10) | 0.00010 (10) |
Sn3 | 0.01678 (14) | 0.01707 (14) | 0.01664 (14) | −0.00179 (11) | 0.00096 (10) | −0.00014 (10) |
Cl1 | 0.0550 (10) | 0.0567 (11) | 0.0685 (11) | 0.0016 (8) | 0.0039 (8) | −0.0209 (8) |
Cl2 | 0.0696 (11) | 0.0547 (11) | 0.0596 (10) | 0.0042 (8) | −0.0134 (9) | −0.0054 (8) |
Cl3 | 0.0835 (13) | 0.0673 (12) | 0.0456 (9) | 0.0087 (10) | 0.0125 (9) | 0.0129 (8) |
Cl4 | 0.0573 (10) | 0.0604 (12) | 0.0866 (13) | 0.0059 (8) | −0.0240 (9) | −0.0128 (9) |
Cl5 | 0.0739 (11) | 0.0438 (10) | 0.0636 (11) | 0.0094 (8) | 0.0143 (9) | −0.0074 (8) |
Cl6 | 0.0941 (13) | 0.0589 (11) | 0.0503 (10) | −0.0209 (10) | 0.0238 (9) | 0.0023 (8) |
O1 | 0.0163 (14) | 0.0199 (16) | 0.0186 (15) | −0.0003 (11) | 0.0019 (11) | −0.0013 (11) |
O2 | 0.0186 (14) | 0.0203 (16) | 0.0150 (14) | −0.0007 (12) | −0.0005 (11) | −0.0007 (11) |
O3 | 0.0183 (14) | 0.0206 (16) | 0.0185 (14) | 0.0003 (12) | 0.0012 (11) | −0.0004 (11) |
O4 | 0.0239 (16) | 0.0331 (19) | 0.0193 (16) | 0.0017 (14) | 0.0059 (13) | −0.0021 (13) |
O5 | 0.0226 (15) | 0.0293 (18) | 0.0185 (15) | −0.0012 (13) | −0.0001 (12) | −0.0011 (12) |
O6 | 0.0283 (17) | 0.0304 (19) | 0.0184 (15) | −0.0073 (14) | −0.0009 (13) | −0.0021 (12) |
O7 | 0.0299 (17) | 0.0263 (18) | 0.0183 (15) | −0.0078 (13) | −0.0009 (13) | −0.0025 (12) |
O8 | 0.0189 (15) | 0.0251 (18) | 0.0287 (17) | −0.0047 (12) | 0.0038 (13) | −0.0028 (13) |
O9 | 0.0176 (15) | 0.0271 (18) | 0.0261 (16) | −0.0012 (13) | 0.0043 (12) | −0.0026 (13) |
C1 | 0.032 (2) | 0.020 (2) | 0.021 (2) | −0.0047 (18) | 0.0056 (19) | −0.0002 (16) |
C2 | 0.030 (3) | 0.055 (4) | 0.024 (2) | −0.004 (2) | 0.007 (2) | −0.010 (2) |
C3 | 0.018 (2) | 0.028 (3) | 0.025 (2) | −0.0005 (18) | −0.0006 (17) | −0.0047 (18) |
C4 | 0.041 (3) | 0.039 (3) | 0.029 (3) | −0.016 (2) | −0.002 (2) | −0.004 (2) |
C5 | 0.018 (2) | 0.035 (3) | 0.019 (2) | −0.0044 (19) | 0.0021 (17) | −0.0022 (18) |
C6 | 0.023 (2) | 0.035 (3) | 0.060 (4) | −0.007 (2) | 0.013 (2) | −0.005 (3) |
C7 | 0.020 (2) | 0.026 (2) | 0.029 (2) | −0.0011 (18) | −0.0021 (18) | 0.0039 (18) |
C8 | 0.055 (4) | 0.032 (3) | 0.042 (3) | 0.018 (3) | 0.009 (3) | 0.004 (2) |
C9 | 0.030 (3) | 0.049 (4) | 0.055 (4) | 0.005 (2) | −0.014 (3) | 0.013 (3) |
C10 | 0.029 (2) | 0.025 (2) | 0.022 (2) | 0.0044 (19) | 0.0000 (18) | 0.0036 (17) |
C11 | 0.045 (3) | 0.040 (3) | 0.034 (3) | 0.000 (2) | 0.007 (2) | 0.016 (2) |
C12 | 0.030 (3) | 0.044 (3) | 0.045 (3) | 0.004 (2) | −0.015 (2) | 0.007 (3) |
C13 | 0.022 (2) | 0.022 (2) | 0.026 (2) | −0.0017 (18) | −0.0021 (18) | 0.0025 (17) |
C14 | 0.053 (3) | 0.022 (3) | 0.043 (3) | 0.005 (2) | 0.009 (3) | −0.001 (2) |
C15 | 0.040 (3) | 0.041 (3) | 0.036 (3) | −0.004 (2) | 0.006 (2) | 0.020 (2) |
C16 | 0.041 (3) | 0.040 (3) | 0.037 (3) | 0.002 (2) | 0.010 (2) | −0.002 (2) |
C17 | 0.045 (3) | 0.031 (3) | 0.042 (3) | −0.007 (2) | 0.003 (3) | −0.001 (2) |
Sn1—O1 | 2.081 (3) | C3—C4 | 1.507 (6) |
Sn1—O2 | 2.087 (3) | C4—H4A | 0.9800 |
Sn1—O3i | 2.096 (3) | C4—H4B | 0.9800 |
Sn1—O4 | 2.172 (3) | C4—H4C | 0.9800 |
Sn1—O9i | 2.180 (3) | C5—C6 | 1.499 (6) |
Sn1—C7 | 2.147 (5) | C6—H6A | 0.9800 |
Sn2—O1 | 2.073 (3) | C6—H6B | 0.9800 |
Sn2—O2 | 2.103 (3) | C6—H6C | 0.9800 |
Sn2—O3 | 2.087 (3) | C7—C8 | 1.523 (7) |
Sn2—O5 | 2.171 (3) | C7—C9 | 1.504 (7) |
Sn2—O6 | 2.166 (3) | C7—H7 | 1.0000 |
Sn2—C10 | 2.148 (4) | C8—H8A | 0.9800 |
Sn3—O1 | 2.096 (3) | C8—H8B | 0.9800 |
Sn3—O2i | 2.086 (3) | C8—H8C | 0.9800 |
Sn3—O3 | 2.083 (3) | C9—H9A | 0.9800 |
Sn3—O7 | 2.166 (3) | C9—H9B | 0.9800 |
Sn3—O8 | 2.177 (3) | C9—H9C | 0.9800 |
Sn3—C13 | 2.142 (4) | C10—C12 | 1.514 (6) |
Cl1—C16 | 1.752 (6) | C10—C11 | 1.527 (6) |
Cl2—C16 | 1.750 (6) | C10—H10 | 1.0000 |
Cl3—C16 | 1.762 (6) | C11—H11A | 0.9800 |
Cl4—C17 | 1.745 (6) | C11—H11B | 0.9800 |
Cl5—C17 | 1.747 (6) | C11—H11C | 0.9800 |
Cl6—C17 | 1.748 (6) | C12—H12A | 0.9800 |
O2—Sn3i | 2.086 (3) | C12—H12B | 0.9800 |
O3—Sn1i | 2.096 (3) | C12—H12C | 0.9800 |
O4—C1 | 1.267 (5) | C13—C15 | 1.513 (6) |
O5—C1 | 1.255 (5) | C13—C14 | 1.535 (7) |
O6—C3 | 1.259 (5) | C13—H13 | 1.0000 |
O7—C3 | 1.263 (5) | C14—H14A | 0.9800 |
O8—C5 | 1.265 (5) | C14—H14B | 0.9800 |
O9—C5 | 1.261 (6) | C14—H14C | 0.9800 |
O9—Sn1i | 2.180 (3) | C15—H15A | 0.9800 |
C1—C2 | 1.496 (6) | C15—H15B | 0.9800 |
C2—H2A | 0.9800 | C15—H15C | 0.9800 |
C2—H2B | 0.9800 | C16—H16 | 1.0000 |
C2—H2C | 0.9800 | C17—H17 | 1.0000 |
O1—Sn1—O2 | 78.08 (11) | H4B—C4—H4C | 109.5 |
O1—Sn1—O3i | 105.45 (11) | O8—C5—O9 | 125.2 (4) |
O1—Sn1—O4 | 87.76 (11) | O8—C5—C6 | 117.1 (4) |
O1—Sn1—O9i | 158.91 (11) | O9—C5—C6 | 117.7 (4) |
O1—Sn1—C7 | 99.73 (14) | C5—C6—H6A | 109.5 |
O2—Sn1—O3i | 78.19 (11) | C5—C6—H6B | 109.5 |
O2—Sn1—O4 | 87.63 (11) | H6A—C6—H6B | 109.5 |
O2—Sn1—C7 | 176.09 (14) | C5—C6—H6C | 109.5 |
O2—Sn1—O9i | 88.13 (11) | H6A—C6—H6C | 109.5 |
O3i—Sn1—O4 | 157.93 (12) | H6B—C6—H6C | 109.5 |
O3i—Sn1—O9i | 86.93 (11) | C8—C7—C9 | 111.8 (4) |
O3i—Sn1—C7 | 99.41 (15) | C8—C7—Sn1 | 112.5 (3) |
O4—Sn1—O9i | 75.68 (12) | C9—C7—Sn1 | 111.9 (3) |
O4—Sn1—C7 | 95.55 (15) | C8—C7—H7 | 106.7 |
O9i—Sn1—C7 | 94.85 (15) | C9—C7—H7 | 106.7 |
O1—Sn2—O2 | 77.87 (11) | Sn1—C7—H7 | 106.7 |
O1—Sn2—O3 | 78.33 (11) | C7—C8—H8A | 109.5 |
O1—Sn2—O5 | 87.59 (11) | C7—C8—H8B | 109.5 |
O1—Sn2—O6 | 86.84 (12) | H8A—C8—H8B | 109.5 |
O1—Sn2—C10 | 177.03 (15) | C7—C8—H8C | 109.5 |
O2—Sn2—O3 | 103.38 (11) | H8A—C8—H8C | 109.5 |
O2—Sn2—O5 | 86.21 (11) | H8B—C8—H8C | 109.5 |
O2—Sn2—O6 | 159.38 (12) | C7—C9—H9A | 109.5 |
O2—Sn2—C10 | 99.76 (15) | C7—C9—H9B | 109.5 |
O3—Sn2—O5 | 160.70 (12) | H9A—C9—H9B | 109.5 |
O3—Sn2—O6 | 86.71 (11) | C7—C9—H9C | 109.5 |
O3—Sn2—C10 | 100.62 (14) | H9A—C9—H9C | 109.5 |
O5—Sn2—O6 | 79.33 (12) | H9B—C9—H9C | 109.5 |
O5—Sn2—C10 | 94.06 (15) | C12—C10—C11 | 112.4 (4) |
O6—Sn2—C10 | 95.89 (15) | C12—C10—Sn2 | 113.2 (3) |
O1—Sn3—O3 | 77.90 (11) | C11—C10—Sn2 | 111.2 (3) |
O1—Sn3—O2i | 104.68 (11) | C12—C10—H10 | 106.5 |
O1—Sn3—O7 | 88.63 (11) | C11—C10—H10 | 106.5 |
O1—Sn3—O8 | 160.61 (11) | Sn2—C10—H10 | 106.5 |
O1—Sn3—C13 | 96.74 (14) | C10—C11—H11A | 109.5 |
O2i—Sn3—O3 | 78.48 (11) | C10—C11—H11B | 109.5 |
O2i—Sn3—O7 | 157.70 (11) | H11A—C11—H11B | 109.5 |
O2i—Sn3—O8 | 85.68 (11) | C10—C11—H11C | 109.5 |
O2i—Sn3—C13 | 101.11 (14) | H11A—C11—H11C | 109.5 |
O3—Sn3—O7 | 87.17 (12) | H11B—C11—H11C | 109.5 |
O3—Sn3—O8 | 88.45 (11) | C10—C12—H12A | 109.5 |
O3—Sn3—C13 | 174.24 (14) | C10—C12—H12B | 109.5 |
O7—Sn3—O8 | 76.88 (11) | H12A—C12—H12B | 109.5 |
O7—Sn3—C13 | 94.85 (15) | C10—C12—H12C | 109.5 |
O8—Sn3—C13 | 97.25 (14) | H12A—C12—H12C | 109.5 |
Sn1—O1—Sn2 | 100.79 (12) | H12B—C12—H12C | 109.5 |
Sn1—O1—Sn3 | 131.30 (14) | C15—C13—C14 | 111.5 (4) |
Sn2—O1—Sn3 | 100.05 (12) | C15—C13—Sn3 | 114.6 (3) |
Sn1—O2—Sn2 | 99.63 (12) | C14—C13—Sn3 | 110.8 (3) |
Sn1—O2—Sn3i | 99.98 (11) | C15—C13—H13 | 106.5 |
Sn2—O2—Sn3i | 133.42 (13) | C14—C13—H13 | 106.5 |
Sn1i—O3—Sn2 | 132.72 (15) | Sn3—C13—H13 | 106.5 |
Sn1i—O3—Sn3 | 99.77 (12) | C13—C14—H14A | 109.5 |
Sn2—O3—Sn3 | 100.02 (12) | C13—C14—H14B | 109.5 |
Sn1—O4—C1 | 128.9 (3) | H14A—C14—H14B | 109.5 |
Sn2—O5—C1 | 130.7 (3) | C13—C14—H14C | 109.5 |
Sn2—O6—C3 | 131.2 (3) | H14A—C14—H14C | 109.5 |
Sn3—O7—C3 | 129.0 (3) | H14B—C14—H14C | 109.5 |
Sn3—O8—C5 | 130.4 (3) | C13—C15—H15A | 109.5 |
Sn1i—O9—C5 | 129.5 (3) | C13—C15—H15B | 109.5 |
O4—C1—O5 | 125.8 (4) | H15A—C15—H15B | 109.5 |
O5—C1—C2 | 117.6 (4) | C13—C15—H15C | 109.5 |
O4—C1—C2 | 116.5 (4) | H15A—C15—H15C | 109.5 |
C1—C2—H2A | 109.5 | H15B—C15—H15C | 109.5 |
C1—C2—H2B | 109.5 | Cl2—C16—Cl1 | 110.5 (3) |
H2A—C2—H2B | 109.5 | Cl2—C16—Cl3 | 110.2 (3) |
C1—C2—H2C | 109.5 | Cl1—C16—Cl3 | 110.1 (3) |
H2A—C2—H2C | 109.5 | Cl2—C16—H16 | 108.7 |
H2B—C2—H2C | 109.5 | Cl1—C16—H16 | 108.7 |
O6—C3—O7 | 125.3 (4) | Cl3—C16—H16 | 108.7 |
O6—C3—C4 | 117.9 (4) | Cl5—C17—Cl4 | 110.1 (3) |
O7—C3—C4 | 116.8 (4) | Cl5—C17—Cl6 | 110.2 (3) |
C3—C4—H4A | 109.5 | Cl4—C17—Cl6 | 111.4 (3) |
C3—C4—H4B | 109.5 | Cl5—C17—H17 | 108.4 |
H4A—C4—H4B | 109.5 | Cl4—C17—H17 | 108.4 |
C3—C4—H4C | 109.5 | Cl6—C17—H17 | 108.4 |
H4A—C4—H4C | 109.5 |
Symmetry code: (i) −x, −y, −z+1. |