Crystal structures and new perspectives on Y₃Au₄ and Y₁₄Au₅₁

Y₃Au₄ (triyttrium tetra­gold) and Y₁₄Au₅₁ (tetra­deca­yttrium henpenta­contagold), two binary representatives of Au-rich rare earth (R) systems crystallize with the space groups R and P6/m, adopting the Pu₃Pd₄ and Gd₁₄Ag₅₁ structure types, respectively (Pearson symbols hR42 and hP65). A variety of binary R–Au compounds have been reported, although only a few have been investigated thoroughly. Many reports lack information or misinter­pret known compounds reported elsewhere. The Pu₃Pd₄ type is fairly common for group 10 elements Ni, Pd, and Pt, while Au representatives are restricted to just five examples, i.e. Ca₃Au₄, Pr₃Au₄, Nd₃Au₄, Gd₃Au₄, and Th₃Au₄. Sm₆Au₇ is suspected to be Sm₃Au₄ due to identical symmetry and close unit-cell parameters. The Pu₃Pd₄ structure type allows for full substitution of the position of the rare earth atom by more electronegative and smaller elements, i.e. Ti and Zr. The Gd₁₄Ag₅₁ type instead is more common for the group 11 metals, while rare representatives of group 12 are known. Y₃Au₄ can be represented as a tunnel structure with encapsulated cations and anionic chains. Though tunnels are present in Y₁₄Au₅₁, this structure is more complex and is best described in terms of polyhedral `pinwheels' around the tunnel forming polyhedra along the c axis.

Computing details

For both structures, data collection: APEX3 (Bruker, 2015); cell refinement: SAINT (Bruker, 2015); data reduction: SAINT (Bruker, 2015); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015b); molecular graphics: 'DIAMOND (Brandenburg, 2006); software used to prepare material for publication: SHELXL2014 (Sheldrick, 2015b).

Triyttrium tetragold (vsY3_0m)

Crystal data

Y3Au4	Dx = 11.386 Mg m^−3
Mr = 1054.60	Mo Kα radiation, λ = 0.71073 Å
Trigonal, R3:H	Cell parameters from 3552 reflections
a = 13.3664 (15) Å	θ = 4.9–32.9°
c = 5.9640 (9) Å	µ = 122.83 mm^−1
V = 922.8 (2) Å^3	T = 296 K
Z = 6	Irregular fragment, grey
F(000) = 2598	0.09 × 0.07 × 0.07 mm

Data collection

Bruker Venture diffractometer	567 reflections with I > 2σ(I)
w scan	Rint = 0.102
Absorption correction: empirical (using intensity measurements) [Blessing (1995) OR SADABS (Krause et al., 2015)]	θmax = 32.9°, θmin = 4.9°
Tmin = 0.02, Tmax = 0.06	h = −20→18
3552 measured reflections	k = −16→20
722 independent reflections	l = −8→8

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	w = 1/[σ^2(Fo^2) + (0.0185P)^2] where P = (Fo^2 + 2Fc^2)/3
R[F^2 > 2σ(F^2)] = 0.047	(Δ/σ)max < 0.001
wR(F^2) = 0.094	Δρmax = 4.07 e Å^−3
S = 1.04	Δρmin = −3.91 e Å^−3
722 reflections	Extinction correction: SHELXL2014 (Sheldrick, 2015b), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
25 parameters	Extinction coefficient: 0.00007 (2)

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Au1	0.39424 (5)	0.11583 (5)	0.04425 (10)	0.00796 (19)
Au2	0.0000	0.0000	0.0000	0.0248 (5)
Au3	0.0000	0.0000	0.5000	0.0246 (4)
Y4	0.04328 (13)	0.21357 (14)	0.2266 (3)	0.0089 (3)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Au1	0.0086 (3)	0.0077 (3)	0.0082 (3)	0.0046 (3)	0.0007 (2)	0.0002 (2)
Au2	0.0096 (5)	0.0096 (5)	0.0554 (13)	0.0048 (3)	0.000	0.000
Au3	0.0230 (6)	0.0230 (6)	0.0278 (10)	0.0115 (3)	0.000	0.000
Y4	0.0069 (7)	0.0120 (8)	0.0079 (7)	0.0047 (6)	−0.0012 (5)	−0.0021 (6)

Geometric parameters (Å, º)

Au1—Y4^i	2.8810 (17)	Au3—Au2^xiv	2.9820 (4)
Au1—Au1^ii	2.9738 (12)	Au3—Y4	3.0808 (17)
Au1—Y4^iii	2.9773 (17)	Au3—Y4^xv	3.0808 (17)
Au1—Au1^iv	3.0577 (9)	Au3—Y4^xii	3.0808 (17)
Au1—Au1^v	3.0578 (9)	Au3—Y4^xvi	3.0808 (17)
Au1—Y4^ii	3.0596 (17)	Au3—Y4^i	3.0808 (17)
Au1—Y4^vi	3.0651 (17)	Au3—Y4^xvii	3.0808 (17)
Au1—Y4^vii	3.1590 (17)	Y4—Au1^xii	2.8810 (17)
Au1—Y4^viii	3.1688 (18)	Y4—Au1^xviii	2.9773 (17)
Au1—Y4^ix	3.2754 (17)	Y4—Au1^ii	3.0596 (17)
Au2—Y4^x	2.9425 (16)	Y4—Au1^xix	3.0651 (17)
Au2—Y4^xi	2.9425 (16)	Y4—Au1^xx	3.1590 (17)
Au2—Y4^i	2.9425 (16)	Y4—Au1^xxi	3.1688 (18)
Au2—Y4^ix	2.9425 (16)	Y4—Au1^xi	3.2755 (17)
Au2—Y4^xii	2.9425 (16)	Y4—Y4^xxii	3.492 (3)
Au2—Y4	2.9425 (16)	Y4—Y4^xi	3.760 (3)
Au2—Au3	2.9820 (4)	Y4—Y4^ix	3.760 (3)
Au2—Au3^xiii	2.9820 (4)
Y4^i—Au1—Au1^ii	63.11 (4)	Au2—Au3—Y4^xvi	121.96 (3)
Y4^i—Au1—Y4^iii	126.13 (5)	Y4—Au3—Y4^xvi	85.43 (4)
Au1^ii—Au1—Y4^iii	121.77 (4)	Y4^xv—Au3—Y4^xvi	94.57 (4)
Y4^i—Au1—Au1^iv	64.41 (3)	Y4^xii—Au3—Y4^xvi	85.43 (4)
Au1^ii—Au1—Au1^iv	103.00 (2)	Au2^xiv—Au3—Y4^i	121.96 (3)
Y4^iii—Au1—Au1^iv	134.16 (4)	Au2—Au3—Y4^i	58.04 (3)
Y4^i—Au1—Au1^v	64.19 (4)	Y4—Au3—Y4^i	94.57 (4)
Au1^ii—Au1—Au1^v	105.38 (4)	Y4^xv—Au3—Y4^i	85.43 (4)
Y4^iii—Au1—Au1^v	63.33 (3)	Y4^xii—Au3—Y4^i	94.57 (4)
Au1^iv—Au1—Au1^v	97.70 (2)	Y4^xvi—Au3—Y4^i	180.0
Y4^i—Au1—Y4^ii	128.93 (6)	Au2^xiv—Au3—Y4^xvii	58.04 (3)
Au1^ii—Au1—Y4^ii	134.78 (4)	Au2—Au3—Y4^xvii	121.96 (3)
Y4^iii—Au1—Y4^ii	87.62 (5)	Y4—Au3—Y4^xvii	180.0
Au1^iv—Au1—Y4^ii	64.75 (4)	Y4^xv—Au3—Y4^xvii	94.57 (4)
Au1^v—Au1—Y4^ii	119.02 (4)	Y4^xii—Au3—Y4^xvii	85.43 (4)
Y4^i—Au1—Y4^vi	120.08 (4)	Y4^xvi—Au3—Y4^xvii	94.57 (4)
Au1^ii—Au1—Y4^vi	56.96 (4)	Y4^i—Au3—Y4^xvii	85.43 (4)
Y4^iii—Au1—Y4^vi	87.52 (5)	Au1^xii—Y4—Au2	107.57 (5)
Au1^iv—Au1—Y4^vi	128.63 (4)	Au1^xii—Y4—Au1^xviii	103.63 (5)
Au1^v—Au1—Y4^vi	131.80 (4)	Au2—Y4—Au1^xviii	131.36 (6)
Y4^ii—Au1—Y4^vi	95.32 (6)	Au1^xii—Y4—Au1^ii	157.52 (6)
Y4^i—Au1—Y4^vii	80.97 (5)	Au2—Y4—Au1^ii	77.42 (4)
Au1^ii—Au1—Y4^vii	64.48 (4)	Au1^xviii—Y4—Au1^ii	87.57 (4)
Y4^iii—Au1—Y4^vii	152.77 (7)	Au1^xii—Y4—Au1^xix	59.92 (4)
Au1^iv—Au1—Y4^vii	55.19 (3)	Au2—Y4—Au1^xix	77.34 (4)
Au1^v—Au1—Y4^vii	143.55 (4)	Au1^xviii—Y4—Au1^xix	87.47 (4)
Y4^ii—Au1—Y4^vii	74.38 (5)	Au1^ii—Y4—Au1^xix	141.21 (6)
Y4^vi—Au1—Y4^vii	74.31 (5)	Au1^xii—Y4—Au3	130.82 (6)
Y4^i—Au1—Y4^viii	80.80 (2)	Au2—Y4—Au3	59.30 (3)
Au1^ii—Au1—Y4^viii	143.91 (4)	Au1^xviii—Y4—Au3	72.07 (4)
Y4^iii—Au1—Y4^viii	79.36 (5)	Au1^ii—Y4—Au3	70.98 (4)
Au1^iv—Au1—Y4^viii	57.10 (3)	Au1^xix—Y4—Au3	70.91 (4)
Au1^v—Au1—Y4^viii	55.09 (3)	Au1^xii—Y4—Au1^xx	60.62 (4)
Y4^ii—Au1—Y4^viii	68.17 (5)	Au2—Y4—Au1^xx	75.87 (4)
Y4^vi—Au1—Y4^viii	159.11 (5)	Au1^xviii—Y4—Au1^xx	152.77 (7)
Y4^vii—Au1—Y4^viii	111.26 (4)	Au1^ii—Y4—Au1^xx	100.96 (5)
Y4^i—Au1—Y4^ix	74.98 (6)	Au1^xix—Y4—Au1^xx	100.84 (5)
Au1^ii—Au1—Y4^ix	60.50 (4)	Au3—Y4—Au1^xx	135.16 (6)
Y4^iii—Au1—Y4^ix	67.70 (5)	Au1^xii—Y4—Au1^xxi	60.50 (3)
Au1^iv—Au1—Y4^ix	139.02 (4)	Au2—Y4—Au1^xxi	167.29 (6)
Au1^v—Au1—Y4^ix	57.66 (3)	Au1^xviii—Y4—Au1^xxi	59.58 (3)
Y4^ii—Au1—Y4^ix	154.05 (5)	Au1^ii—Y4—Au1^xxi	111.83 (5)
Y4^vi—Au1—Y4^ix	76.46 (6)	Au1^xix—Y4—Au1^xxi	98.44 (5)
Y4^vii—Au1—Y4^ix	124.98 (3)	Au3—Y4—Au1^xxi	131.04 (5)
Y4^viii—Au1—Y4^ix	112.58 (2)	Au1^xx—Y4—Au1^xxi	93.40 (5)
Y4^x—Au2—Y4^xi	100.58 (4)	Au1^xii—Y4—Au1^xi	99.94 (5)
Y4^x—Au2—Y4^i	79.42 (4)	Au2—Y4—Au1^xi	98.02 (5)
Y4^xi—Au2—Y4^i	180.00 (7)	Au1^xviii—Y4—Au1^xi	112.30 (5)
Y4^x—Au2—Y4^ix	100.58 (4)	Au1^ii—Y4—Au1^xi	57.60 (3)
Y4^xi—Au2—Y4^ix	100.58 (4)	Au1^xix—Y4—Au1^xi	155.52 (6)
Y4^i—Au2—Y4^ix	79.42 (4)	Au3—Y4—Au1^xi	127.63 (5)
Y4^x—Au2—Y4^xii	79.42 (4)	Au1^xx—Y4—Au1^xi	55.02 (3)
Y4^xi—Au2—Y4^xii	79.42 (4)	Au1^xxi—Y4—Au1^xi	80.81 (4)
Y4^i—Au2—Y4^xii	100.58 (4)	Au1^xii—Y4—Y4^xxii	111.27 (7)
Y4^ix—Au2—Y4^xii	180.00 (9)	Au2—Y4—Y4^xxii	133.98 (8)
Y4^x—Au2—Y4	180.00 (4)	Au1^xviii—Y4—Y4^xxii	60.22 (5)
Y4^xi—Au2—Y4	79.42 (4)	Au1^ii—Y4—Y4^xxii	57.40 (4)
Y4^i—Au2—Y4	100.58 (4)	Au1^xix—Y4—Y4^xxii	144.71 (8)
Y4^ix—Au2—Y4	79.42 (4)	Au3—Y4—Y4^xxii	108.07 (7)
Y4^xii—Au2—Y4	100.58 (4)	Au1^xx—Y4—Y4^xxii	102.73 (7)
Y4^x—Au2—Au3	117.34 (3)	Au1^xxi—Y4—Y4^xxii	54.44 (5)
Y4^xi—Au2—Au3	117.34 (3)	Au1^xi—Y4—Y4^xxii	52.08 (4)
Y4^i—Au2—Au3	62.66 (3)	Au1^xii—Y4—Y4^xi	57.29 (5)
Y4^ix—Au2—Au3	117.34 (3)	Au2—Y4—Y4^xi	50.291 (19)
Y4^xii—Au2—Au3	62.66 (3)	Au1^xviii—Y4—Y4^xi	141.34 (6)
Y4—Au2—Au3	62.66 (3)	Au1^ii—Y4—Y4^xi	123.26 (4)
Y4^x—Au2—Au3^xiii	62.66 (3)	Au1^xix—Y4—Y4^xi	53.99 (3)
Y4^xi—Au2—Au3^xiii	62.66 (3)	Au3—Y4—Y4^xi	94.91 (3)
Y4^i—Au2—Au3^xiii	117.34 (3)	Au1^xx—Y4—Y4^xi	51.60 (5)
Y4^ix—Au2—Au3^xiii	62.66 (3)	Au1^xxi—Y4—Y4^xi	117.55 (5)
Y4^xii—Au2—Au3^xiii	117.34 (3)	Au1^xi—Y4—Y4^xi	104.48 (6)
Y4—Au2—Au3^xiii	117.34 (3)	Y4^xxii—Y4—Y4^xi	154.22 (9)
Au3—Au2—Au3^xiii	180.0	Au1^xii—Y4—Y4^ix	111.70 (7)
Au2^xiv—Au3—Au2	180.0	Au2—Y4—Y4^ix	50.291 (19)
Au2^xiv—Au3—Y4	121.96 (3)	Au1^xviii—Y4—Y4^ix	141.48 (6)
Au2—Au3—Y4	58.04 (3)	Au1^ii—Y4—Y4^ix	54.01 (3)
Au2^xiv—Au3—Y4^xv	58.04 (3)	Au1^xix—Y4—Y4^ix	123.20 (4)
Au2—Au3—Y4^xv	121.96 (3)	Au3—Y4—Y4^ix	94.91 (3)
Y4—Au3—Y4^xv	85.43 (4)	Au1^xx—Y4—Y4^ix	51.70 (5)
Au2^xiv—Au3—Y4^xii	121.96 (3)	Au1^xxi—Y4—Y4^ix	127.39 (5)
Au2—Au3—Y4^xii	58.04 (3)	Au1^xi—Y4—Y4^ix	47.74 (4)
Y4—Au3—Y4^xii	94.57 (4)	Y4^xxii—Y4—Y4^ix	92.07 (6)
Y4^xv—Au3—Y4^xii	180.0	Y4^xi—Y4—Y4^ix	74.04 (6)
Au2^xiv—Au3—Y4^xvi	58.04 (3)

Symmetry codes: (i) −x+y, −x, z; (ii) −x+2/3, −y+1/3, −z+1/3; (iii) −y+2/3, x−y+1/3, z−2/3; (iv) −x+y+2/3, −x+1/3, z+1/3; (v) −y+1/3, x−y−1/3, z−1/3; (vi) x−y+2/3, x+1/3, −z+1/3; (vii) −y+2/3, x−y+1/3, z+1/3; (viii) x+1/3, y−1/3, z−1/3; (ix) y, −x+y, −z; (x) −x, −y, −z; (xi) x−y, x, −z; (xii) −y, x−y, z; (xiii) x, y, z−1; (xiv) x, y, z+1; (xv) y, −x+y, −z+1; (xvi) x−y, x, −z+1; (xvii) −x, −y, −z+1; (xviii) −x+y+1/3, −x+2/3, z+2/3; (xix) y−1/3, −x+y+1/3, −z+1/3; (xx) −x+y+1/3, −x+2/3, z−1/3; (xxi) x−1/3, y+1/3, z+1/3; (xxii) −x+1/3, −y+2/3, −z+2/3.

Tetradecayttrium henpentacontagold (vsYAu_0m)

Crystal data

Y14Au51	Dx = 15.056 Mg m^−3
Mr = 11290.03	Mo Kα radiation, λ = 0.71073 Å
Hexagonal, P6/m	Cell parameters from 12877 reflections
a = 12.5433 (17) Å	θ = 2.2–28.0°
c = 9.1389 (14) Å	µ = 165.57 mm^−1
V = 1245.2 (4) Å^3	T = 293 K
Z = 1	Irregular fragment, grey
F(000) = 4575	0.06 × 0.05 × 0.05 mm

Data collection

Bruker Venture diffractometer	994 reflections with I > 2σ(I)
w scan	Rint = 0.054
Absorption correction: empirical (using intensity measurements) [Blessing (1995) OR SADABS (Krause et al., 2015)]	θmax = 28.0°, θmin = 2.2°
Tmin = 0.01, Tmax = 0.06	h = −13→16
12877 measured reflections	k = −16→13
1075 independent reflections	l = −12→12

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	w = 1/[σ^2(Fo^2) + (0.0098P)^2 + 45.996P] where P = (Fo^2 + 2Fc^2)/3
R[F^2 > 2σ(F^2)] = 0.022	(Δ/σ)max < 0.001
wR(F^2) = 0.044	Δρmax = 2.26 e Å^−3
S = 1.13	Δρmin = −2.50 e Å^−3
1075 reflections	Extinction correction: SHELXL2014 (Sheldrick, 2015b), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
62 parameters	Extinction coefficient: 0.000329 (14)

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Au1	0.10236 (4)	0.44248 (4)	0.33624 (4)	0.00635 (12)
Au2	0.26705 (4)	0.07670 (4)	0.23249 (5)	0.00579 (12)
Au3	0.49390 (4)	0.11652 (4)	0.15151 (4)	0.00630 (12)
Au4	0.05851 (5)	0.23798 (5)	0.5000	0.00462 (14)
Au5	0.02801 (12)	0.13909 (11)	0.0000	0.0075 (3)	0.5
Au6	0.3333	0.6667	0.31031 (8)	0.00596 (16)
Au7	0.3333	0.6667	0.0000	0.0094 (2)
Y1	0.46512 (14)	0.14113 (14)	0.5000	0.0039 (3)
Y2	0.11316 (15)	0.39227 (16)	0.0000	0.0104 (3)
Y3	0.0000	0.0000	0.3018 (3)	0.0034 (5)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Au1	0.0060 (2)	0.0039 (2)	0.0069 (2)	0.00078 (17)	−0.00081 (15)	0.00170 (15)
Au2	0.0045 (2)	0.0066 (2)	0.0072 (2)	0.00352 (17)	0.00225 (16)	0.00177 (16)
Au3	0.0028 (2)	0.0078 (2)	0.00664 (19)	0.00136 (17)	0.00011 (15)	0.00101 (16)
Au4	0.0015 (3)	0.0063 (3)	0.0061 (3)	0.0019 (2)	0.000	0.000
Au5	0.0138 (7)	0.0032 (5)	0.0058 (5)	0.0046 (5)	0.000	0.000
Au6	0.0035 (2)	0.0035 (2)	0.0110 (3)	0.00173 (11)	0.000	0.000
Au7	0.0093 (3)	0.0093 (3)	0.0097 (5)	0.00463 (17)	0.000	0.000
Y1	0.0030 (7)	0.0037 (7)	0.0053 (7)	0.0020 (6)	0.000	0.000
Y2	0.0084 (8)	0.0214 (9)	0.0054 (7)	0.0103 (7)	0.000	0.000
Y3	0.0016 (7)	0.0016 (7)	0.0068 (11)	0.0008 (3)	0.000	0.000

Geometric parameters (Å, º)

Au1—Au3^i	2.7542 (7)	Au5—Y3^xviii	3.188 (2)
Au1—Au4	2.7769 (7)	Au5—Y3	3.188 (2)
Au1—Au6	2.8654 (6)	Au5—Au5^xviii	3.196 (2)
Au1—Au3^ii	2.9686 (7)	Au6—Au7	2.8358 (9)
Au1—Au2^ii	2.9735 (7)	Au6—Au1^xix	2.8653 (6)
Au1—Au1^iii	2.9933 (9)	Au6—Au1^xx	2.8654 (6)
Au1—Y1^iv	3.0393 (14)	Au6—Au3^i	2.8818 (6)
Au1—Y1^v	3.0429 (14)	Au6—Au3^xxi	2.8818 (6)
Au1—Au2^v	3.0640 (7)	Au6—Au3^v	2.8818 (6)
Au1—Y1^i	3.1036 (14)	Au6—Y1^i	3.0189 (13)
Au1—Y2	3.1532 (7)	Au6—Y1^xxii	3.0189 (13)
Au2—Au3	2.7337 (7)	Au6—Y1^v	3.0189 (13)
Au2—Au5^vi	2.7381 (9)	Au7—Au6^xxiii	2.8358 (9)
Au2—Au5^vii	2.8229 (10)	Au7—Au3^xxiv	2.8488 (5)
Au2—Au4^viii	2.8630 (6)	Au7—Au3^xxi	2.8488 (5)
Au2—Au4^vii	2.8708 (6)	Au7—Au3^i	2.8488 (5)
Au2—Au1^ix	2.9735 (7)	Au7—Au3^xii	2.8488 (5)
Au2—Au2^v	2.9872 (6)	Au7—Au3^xvii	2.8488 (5)
Au2—Au2^vii	2.9872 (6)	Au7—Au3^v	2.8488 (5)
Au2—Y3	3.0537 (8)	Au7—Y2	3.1572 (18)
Au2—Au1^vii	3.0639 (7)	Au7—Y2^xxiii	3.1572 (18)
Au2—Y2^vii	3.0723 (13)	Au7—Y2^xxv	3.1572 (18)
Au2—Y2^vi	3.2509 (14)	Y1—Au6^xxii	3.0190 (13)
Au3—Au1^x	2.7542 (7)	Y1—Au6^x	3.0190 (13)
Au3—Au3^xi	2.7692 (9)	Y1—Au1^ix	3.0393 (14)
Au3—Au7^xii	2.8489 (5)	Y1—Au1^viii	3.0393 (14)
Au3—Au6^x	2.8818 (6)	Y1—Au1^xxvi	3.0429 (14)
Au3—Au1^ix	2.9686 (7)	Y1—Au1^vii	3.0429 (14)
Au3—Au3^xiii	3.0024 (10)	Y1—Au1^xxvii	3.1037 (14)
Au3—Y2^vi	3.1167 (15)	Y1—Au1^x	3.1037 (14)
Au3—Y2^x	3.1852 (17)	Y1—Au4^vii	3.1174 (16)
Au3—Y2^vii	3.2096 (16)	Y1—Au4^viii	3.1837 (16)
Au3—Y1	3.2373 (7)	Y1—Au3^iii	3.2374 (7)
Au4—Au4^v	2.6942 (7)	Y2—Au2^xvii	3.0723 (13)
Au4—Au4^vii	2.6942 (7)	Y2—Au2^v	3.0723 (13)
Au4—Au1^iii	2.7769 (7)	Y2—Au3^xvi	3.1167 (15)
Au4—Au2^ii	2.8630 (6)	Y2—Au3^ii	3.1167 (15)
Au4—Au2^iv	2.8630 (6)	Y2—Au1^xi	3.1532 (7)
Au4—Au2^xiv	2.8709 (6)	Y2—Au3^i	3.1852 (16)
Au4—Au2^v	2.8709 (6)	Y2—Au3^xxiv	3.1852 (17)
Au4—Y1^v	3.1175 (17)	Y2—Au3^v	3.2096 (15)
Au4—Y1^iv	3.1837 (16)	Y2—Au3^xvii	3.2096 (15)
Au4—Y3	3.2463 (15)	Y3—Au2^ix	3.0537 (8)
Au4—Y3^xv	3.2463 (15)	Y3—Au2^xxviii	3.0537 (8)
Au5—Au5^vii	1.5982 (12)	Y3—Au2^v	3.0537 (8)
Au5—Au5^v	1.5983 (12)	Y3—Au2^vii	3.0537 (8)
Au5—Au2^xvi	2.7381 (9)	Y3—Au2^ii	3.0537 (8)
Au5—Au2^ii	2.7381 (9)	Y3—Au5^xvi	3.188 (2)
Au5—Au5^vi	2.768 (2)	Y3—Au5^xviii	3.188 (2)
Au5—Au5^xvi	2.768 (2)	Y3—Au5^v	3.188 (2)
Au5—Y2	2.799 (2)	Y3—Au5^vi	3.188 (2)
Au5—Au2^v	2.8228 (10)	Y3—Au5^vii	3.188 (2)
Au5—Au2^xvii	2.8228 (10)
Au3^i—Au1—Au4	171.85 (2)	Y2—Au5—Au5^xviii	171.68 (8)
Au3^i—Au1—Au6	61.666 (16)	Au2^v—Au5—Au5^xviii	108.85 (4)
Au4—Au1—Au6	125.96 (2)	Au2^xvii—Au5—Au5^xviii	108.85 (4)
Au3^i—Au1—Au3^ii	63.156 (19)	Y3^xviii—Au5—Au5^xviii	59.91 (3)
Au4—Au1—Au3^ii	108.88 (2)	Y3—Au5—Au5^xviii	59.91 (3)
Au6—Au1—Au3^ii	124.41 (2)	Au7—Au6—Au1^xix	94.744 (17)
Au3^i—Au1—Au2^ii	112.435 (19)	Au7—Au6—Au1	94.744 (17)
Au4—Au1—Au2^ii	59.603 (16)	Au1^xix—Au6—Au1	119.324 (5)
Au6—Au1—Au2^ii	150.78 (2)	Au7—Au6—Au1^xx	94.744 (17)
Au3^ii—Au1—Au2^ii	54.779 (14)	Au1^xix—Au6—Au1^xx	119.324 (5)
Au3^i—Au1—Au1^iii	127.804 (14)	Au1—Au6—Au1^xx	119.323 (5)
Au4—Au1—Au1^iii	57.388 (12)	Au7—Au6—Au3^i	59.762 (16)
Au6—Au1—Au1^iii	94.744 (17)	Au1^xix—Au6—Au3^i	151.89 (3)
Au3^ii—Au1—Au1^iii	124.659 (13)	Au1—Au6—Au3^i	57.269 (13)
Au2^ii—Au1—Au1^iii	108.595 (12)	Au1^xx—Au6—Au3^i	77.503 (13)
Au3^i—Au1—Y1^iv	109.87 (3)	Au7—Au6—Au3^xxi	59.762 (16)
Au4—Au1—Y1^iv	66.20 (3)	Au1^xix—Au6—Au3^xxi	77.503 (13)
Au6—Au1—Y1^iv	142.78 (3)	Au1—Au6—Au3^xxi	151.89 (3)
Au3^ii—Au1—Y1^iv	65.20 (2)	Au1^xx—Au6—Au3^xxi	57.269 (13)
Au2^ii—Au1—Y1^iv	66.23 (3)	Au3^i—Au6—Au3^xxi	96.87 (2)
Au1^iii—Au1—Y1^iv	60.499 (16)	Au7—Au6—Au3^v	59.762 (16)
Au3^i—Au1—Y1^v	122.94 (3)	Au1^xix—Au6—Au3^v	57.269 (13)
Au4—Au1—Y1^v	64.59 (3)	Au1—Au6—Au3^v	77.504 (13)
Au6—Au1—Y1^v	61.37 (3)	Au1^xx—Au6—Au3^v	151.89 (3)
Au3^ii—Au1—Y1^v	168.96 (3)	Au3^i—Au6—Au3^v	96.87 (2)
Au2^ii—Au1—Y1^v	115.16 (3)	Au3^xxi—Au6—Au3^v	96.87 (2)
Au1^iii—Au1—Y1^v	60.540 (17)	Au7—Au6—Y1^i	125.05 (2)
Y1^iv—Au1—Y1^v	116.82 (3)	Au1^xix—Au6—Y1^i	140.20 (3)
Au3^i—Au1—Au2^v	120.06 (2)	Au1—Au6—Y1^i	63.60 (3)
Au4—Au1—Au2^v	58.635 (16)	Au1^xx—Au6—Y1^i	62.21 (3)
Au6—Au1—Au2^v	97.393 (15)	Au3^i—Au6—Y1^i	66.50 (2)
Au3^ii—Au1—Au2^v	104.016 (18)	Au3^xxi—Au6—Y1^i	119.40 (3)
Au2^ii—Au1—Au2^v	59.287 (16)	Au3^v—Au6—Y1^i	140.85 (3)
Au1^iii—Au1—Au2^v	108.028 (11)	Au7—Au6—Y1^xxii	125.05 (2)
Y1^iv—Au1—Au2^v	115.85 (3)	Au1^xix—Au6—Y1^xxii	62.21 (3)
Y1^v—Au1—Au2^v	65.09 (3)	Au1—Au6—Y1^xxii	140.20 (3)
Au3^i—Au1—Y1^i	66.79 (2)	Au1^xx—Au6—Y1^xxii	63.60 (3)
Au4—Au1—Y1^i	118.50 (2)	Au3^i—Au6—Y1^xxii	140.85 (3)
Au6—Au1—Y1^i	60.61 (3)	Au3^xxi—Au6—Y1^xxii	66.50 (2)
Au3^ii—Au1—Y1^i	102.75 (3)	Au3^v—Au6—Y1^xxii	119.40 (3)
Au2^ii—Au1—Y1^i	146.74 (3)	Y1^i—Au6—Y1^xxii	90.31 (3)
Au1^iii—Au1—Y1^i	61.169 (16)	Au7—Au6—Y1^v	125.05 (2)
Y1^iv—Au1—Y1^i	82.47 (4)	Au1^xix—Au6—Y1^v	63.60 (3)
Y1^v—Au1—Y1^i	88.28 (5)	Au1—Au6—Y1^v	62.21 (3)
Au2^v—Au1—Y1^i	152.17 (3)	Au1^xx—Au6—Y1^v	140.20 (3)
Au3^i—Au1—Y2	64.84 (3)	Au3^i—Au6—Y1^v	119.40 (3)
Au4—Au1—Y2	110.44 (4)	Au3^xxi—Au6—Y1^v	140.85 (3)
Au6—Au1—Y2	89.55 (4)	Au3^v—Au6—Y1^v	66.50 (2)
Au3^ii—Au1—Y2	61.12 (3)	Y1^i—Au6—Y1^v	90.31 (3)
Au2^ii—Au1—Y2	64.01 (3)	Y1^xxii—Au6—Y1^v	90.31 (3)
Au1^iii—Au1—Y2	167.04 (3)	Au6^xxiii—Au7—Au6	180.0
Y1^iv—Au1—Y2	121.01 (4)	Au6^xxiii—Au7—Au3^xxiv	60.922 (10)
Y1^v—Au1—Y2	111.68 (4)	Au6—Au7—Au3^xxiv	119.079 (10)
Au2^v—Au1—Y2	59.21 (3)	Au6^xxiii—Au7—Au3^xxi	119.080 (10)
Y1^i—Au1—Y2	131.02 (4)	Au6—Au7—Au3^xxi	60.921 (10)
Au3—Au2—Au5^vi	107.84 (3)	Au3^xxiv—Au7—Au3^xxi	128.178 (5)
Au3—Au2—Au5^vii	112.81 (3)	Au6^xxiii—Au7—Au3^i	119.080 (10)
Au5^vi—Au2—Au5^vii	33.36 (3)	Au6—Au7—Au3^i	60.921 (10)
Au3—Au2—Au4^viii	113.29 (2)	Au3^xxiv—Au7—Au3^i	58.16 (2)
Au5^vi—Au2—Au4^viii	114.08 (3)	Au3^xxi—Au7—Au3^i	98.377 (12)
Au5^vii—Au2—Au4^viii	130.86 (3)	Au6^xxiii—Au7—Au3^xii	60.921 (10)
Au3—Au2—Au4^vii	120.19 (2)	Au6—Au7—Au3^xii	119.079 (10)
Au5^vi—Au2—Au4^vii	130.96 (3)	Au3^xxiv—Au7—Au3^xii	98.377 (12)
Au5^vii—Au2—Au4^vii	111.27 (3)	Au3^xxi—Au7—Au3^xii	58.158 (19)
Au4^viii—Au2—Au4^vii	56.052 (18)	Au3^i—Au7—Au3^xii	128.178 (5)
Au3—Au2—Au1^ix	62.518 (15)	Au6^xxiii—Au7—Au3^xvii	60.920 (10)
Au5^vi—Au2—Au1^ix	107.53 (3)	Au6—Au7—Au3^xvii	119.079 (10)
Au5^vii—Au2—Au1^ix	140.26 (3)	Au3^xxiv—Au7—Au3^xvii	98.377 (12)
Au4^viii—Au2—Au1^ix	56.781 (16)	Au3^xxi—Au7—Au3^xvii	128.178 (5)
Au4^vii—Au2—Au1^ix	102.94 (2)	Au3^i—Au7—Au3^xvii	128.178 (5)
Au3—Au2—Au2^v	125.154 (19)	Au3^xii—Au7—Au3^xvii	98.377 (13)
Au5^vi—Au2—Au2^v	86.85 (3)	Au6^xxiii—Au7—Au3^v	119.078 (10)
Au5^vii—Au2—Au2^v	56.15 (2)	Au6—Au7—Au3^v	60.921 (10)
Au4^viii—Au2—Au2^v	106.976 (13)	Au3^xxiv—Au7—Au3^v	128.178 (5)
Au4^vii—Au2—Au2^v	58.475 (14)	Au3^xxi—Au7—Au3^v	98.377 (12)
Au1^ix—Au2—Au2^v	161.406 (12)	Au3^i—Au7—Au3^v	98.377 (12)
Au3—Au2—Au2^vii	112.347 (19)	Au3^xii—Au7—Au3^v	128.178 (5)
Au5^vi—Au2—Au2^vii	58.89 (3)	Au3^xvii—Au7—Au3^v	58.16 (2)
Au5^vii—Au2—Au2^vii	88.54 (3)	Au6^xxiii—Au7—Y2	90.0
Au4^viii—Au2—Au2^vii	58.731 (14)	Au6—Au7—Y2	90.0
Au4^vii—Au2—Au2^vii	107.084 (13)	Au3^xxiv—Au7—Y2	63.81 (3)
Au1^ix—Au2—Au2^vii	61.863 (16)	Au3^xxi—Au7—Y2	150.919 (10)
Au2^v—Au2—Au2^vii	120.0	Au3^i—Au7—Y2	63.81 (3)
Au3—Au2—Y3	172.47 (3)	Au3^xii—Au7—Y2	150.919 (10)
Au5^vi—Au2—Y3	66.54 (5)	Au3^xvii—Au7—Y2	64.37 (3)
Au5^vii—Au2—Y3	65.57 (5)	Au3^v—Au7—Y2	64.37 (3)
Au4^viii—Au2—Y3	66.46 (4)	Au6^xxiii—Au7—Y2^xxiii	90.0
Au4^vii—Au2—Y3	66.37 (4)	Au6—Au7—Y2^xxiii	90.0
Au1^ix—Au2—Y3	113.56 (3)	Au3^xxiv—Au7—Y2^xxiii	64.37 (3)
Au2^v—Au2—Y3	60.718 (6)	Au3^xxi—Au7—Y2^xxiii	63.81 (3)
Au2^vii—Au2—Y3	60.718 (6)	Au3^i—Au7—Y2^xxiii	64.37 (3)
Au3—Au2—Au1^vii	76.470 (16)	Au3^xii—Au7—Y2^xxiii	63.81 (3)
Au5^vi—Au2—Au1^vii	135.48 (3)	Au3^xvii—Au7—Y2^xxiii	150.919 (10)
Au5^vii—Au2—Au1^vii	102.99 (3)	Au3^v—Au7—Y2^xxiii	150.919 (10)
Au4^viii—Au2—Au1^vii	103.33 (2)	Y2—Au7—Y2^xxiii	120.000 (1)
Au4^vii—Au2—Au1^vii	55.682 (15)	Au6^xxiii—Au7—Y2^xxv	90.0
Au1^ix—Au2—Au1^vii	112.921 (16)	Au6—Au7—Y2^xxv	90.0
Au2^v—Au2—Au1^vii	58.850 (15)	Au3^xxiv—Au7—Y2^xxv	150.919 (10)
Au2^vii—Au2—Au1^vii	161.742 (11)	Au3^xxi—Au7—Y2^xxv	64.37 (3)
Y3—Au2—Au1^vii	111.02 (2)	Au3^i—Au7—Y2^xxv	150.919 (10)
Au3—Au2—Y2^vii	66.83 (3)	Au3^xii—Au7—Y2^xxv	64.37 (3)
Au5^vi—Au2—Y2^vii	78.88 (4)	Au3^xvii—Au7—Y2^xxv	63.81 (3)
Au5^vii—Au2—Y2^vii	56.50 (4)	Au3^v—Au7—Y2^xxv	63.81 (3)
Au4^viii—Au2—Y2^vii	165.07 (3)	Y2—Au7—Y2^xxv	120.0
Au4^vii—Au2—Y2^vii	110.19 (3)	Y2^xxiii—Au7—Y2^xxv	120.0
Au1^ix—Au2—Y2^vii	128.42 (3)	Au6^xxii—Y1—Au6^x	70.09 (4)
Au2^v—Au2—Y2^vii	64.87 (3)	Au6^xxii—Y1—Au1^ix	152.94 (5)
Au2^vii—Au2—Y2^vii	135.92 (2)	Au6^x—Y1—Au1^ix	108.96 (2)
Y3—Au2—Y2^vii	115.52 (5)	Au6^xxii—Y1—Au1^viii	108.96 (2)
Au1^vii—Au2—Y2^vii	61.84 (3)	Au6^x—Y1—Au1^viii	152.94 (5)
Au3—Au2—Y2^vi	62.06 (3)	Au1^ix—Y1—Au1^viii	59.00 (3)
Au5^vi—Au2—Y2^vi	54.92 (4)	Au6^xxii—Y1—Au1^xxvi	56.41 (2)
Au5^vii—Au2—Y2^vi	81.85 (4)	Au6^x—Y1—Au1^xxvi	90.67 (4)
Au4^viii—Au2—Y2^vi	105.59 (3)	Au1^ix—Y1—Au1^xxvi	148.61 (6)
Au4^vii—Au2—Y2^vi	161.51 (3)	Au1^viii—Y1—Au1^xxvi	111.67 (3)
Au1^ix—Au2—Y2^vi	60.68 (3)	Au6^xxii—Y1—Au1^vii	90.67 (4)
Au2^v—Au2—Y2^vi	137.48 (2)	Au6^x—Y1—Au1^vii	56.41 (2)
Au2^vii—Au2—Y2^vi	58.83 (3)	Au1^ix—Y1—Au1^vii	111.67 (3)
Y3—Au2—Y2^vi	110.51 (4)	Au1^viii—Y1—Au1^vii	148.61 (6)
Au1^vii—Au2—Y2^vi	136.12 (3)	Au1^xxvi—Y1—Au1^vii	58.92 (3)
Y2^vii—Au2—Y2^vi	87.798 (17)	Au6^xxii—Y1—Au1^xxvii	55.79 (2)
Au2—Au3—Au1^x	125.00 (2)	Au6^x—Y1—Au1^xxvii	89.52 (4)
Au2—Au3—Au3^xi	105.707 (13)	Au1^ix—Y1—Au1^xxvii	97.53 (4)
Au1^x—Au3—Au3^xi	127.803 (14)	Au1^viii—Y1—Au1^xxvii	69.88 (3)
Au2—Au3—Au7^xii	122.101 (18)	Au1^xxvi—Y1—Au1^xxvii	107.15 (3)
Au1^x—Au3—Au7^xii	96.937 (17)	Au1^vii—Y1—Au1^xxvii	140.29 (5)
Au3^xi—Au3—Au7^xii	60.921 (10)	Au6^xxii—Y1—Au1^x	89.52 (4)
Au2—Au3—Au6^x	105.008 (18)	Au6^x—Y1—Au1^x	55.79 (2)
Au1^x—Au3—Au6^x	61.068 (14)	Au1^ix—Y1—Au1^x	69.88 (3)
Au3^xi—Au3—Au6^x	120.237 (16)	Au1^viii—Y1—Au1^x	97.53 (4)
Au7^xii—Au3—Au6^x	59.317 (18)	Au1^xxvi—Y1—Au1^x	140.29 (5)
Au2—Au3—Au1^ix	62.702 (15)	Au1^vii—Y1—Au1^x	107.15 (3)
Au1^x—Au3—Au1^ix	75.78 (2)	Au1^xxvii—Y1—Au1^x	57.66 (3)
Au3^xi—Au3—Au1^ix	124.659 (13)	Au6^xxii—Y1—Au4^vii	109.98 (4)
Au7^xii—Au3—Au1^ix	172.590 (18)	Au6^x—Y1—Au4^vii	109.98 (4)
Au6^x—Au3—Au1^ix	114.88 (2)	Au1^ix—Y1—Au4^vii	95.91 (4)
Au2—Au3—Au3^xiii	112.16 (2)	Au1^viii—Y1—Au4^vii	95.91 (4)
Au1^x—Au3—Au3^xiii	61.909 (15)	Au1^xxvi—Y1—Au4^vii	53.57 (3)
Au3^xi—Au3—Au3^xiii	90.0	Au1^vii—Y1—Au4^vii	53.57 (3)
Au7^xii—Au3—Au3^xiii	123.004 (19)	Au1^xxvii—Y1—Au4^vii	151.146 (16)
Au6^x—Au3—Au3^xiii	122.580 (19)	Au1^x—Y1—Au4^vii	151.146 (16)
Au1^ix—Au3—Au3^xiii	54.935 (14)	Au6^xxii—Y1—Au4^viii	142.36 (3)
Au2—Au3—Y2^vi	67.15 (3)	Au6^x—Y1—Au4^viii	142.36 (3)
Au1^x—Au3—Y2^vi	123.00 (3)	Au1^ix—Y1—Au4^viii	52.94 (3)
Au3^xi—Au3—Y2^vi	63.624 (16)	Au1^viii—Y1—Au4^viii	52.94 (3)
Au7^xii—Au3—Y2^vi	124.05 (2)	Au1^xxvi—Y1—Au4^viii	96.62 (4)
Au6^x—Au3—Y2^vi	172.15 (3)	Au1^vii—Y1—Au4^viii	96.62 (4)
Au1^ix—Au3—Y2^vi	62.36 (2)	Au1^xxvii—Y1—Au4^viii	122.77 (4)
Au3^xiii—Au3—Y2^vi	62.70 (3)	Au1^x—Y1—Au4^viii	122.77 (4)
Au2—Au3—Y2^x	166.16 (3)	Au4^vii—Y1—Au4^viii	50.61 (3)
Au1^x—Au3—Y2^x	63.65 (2)	Au6^xxii—Y1—Au3	123.52 (5)
Au3^xi—Au3—Y2^x	64.234 (16)	Au6^x—Y1—Au3	54.720 (18)
Au7^xii—Au3—Y2^x	62.81 (3)	Au1^ix—Y1—Au3	56.346 (17)
Au6^x—Au3—Y2^x	88.63 (3)	Au1^viii—Y1—Au3	114.50 (4)
Au1^ix—Au3—Y2^x	114.00 (3)	Au1^xxvi—Y1—Au3	128.51 (4)
Au3^xiii—Au3—Y2^x	60.40 (3)	Au1^vii—Y1—Au3	69.815 (18)
Y2^vi—Au3—Y2^x	99.21 (4)	Au1^xxvii—Y1—Au3	108.99 (4)
Au2—Au3—Y2^vii	61.64 (3)	Au1^x—Y1—Au3	51.435 (17)
Au1^x—Au3—Y2^vii	149.16 (3)	Au4^vii—Y1—Au3	99.72 (3)
Au3^xi—Au3—Y2^vii	64.444 (15)	Au4^viii—Y1—Au3	93.46 (3)
Au7^xii—Au3—Y2^vii	62.48 (3)	Au6^xxii—Y1—Au3^iii	54.720 (18)
Au6^x—Au3—Y2^vii	88.15 (3)	Au6^x—Y1—Au3^iii	123.52 (5)
Au1^ix—Au3—Y2^vii	123.51 (3)	Au1^ix—Y1—Au3^iii	114.50 (4)
Au3^xiii—Au3—Y2^vii	148.03 (3)	Au1^viii—Y1—Au3^iii	56.346 (17)
Y2^vi—Au3—Y2^vii	87.78 (5)	Au1^xxvi—Y1—Au3^iii	69.815 (18)
Y2^x—Au3—Y2^vii	117.55 (5)	Au1^vii—Y1—Au3^iii	128.51 (4)
Au2—Au3—Y1	66.14 (3)	Au1^xxvii—Y1—Au3^iii	51.435 (17)
Au1^x—Au3—Y1	61.78 (3)	Au1^x—Y1—Au3^iii	108.99 (4)
Au3^xi—Au3—Y1	169.67 (3)	Au4^vii—Y1—Au3^iii	99.72 (3)
Au7^xii—Au3—Y1	117.06 (3)	Au4^viii—Y1—Au3^iii	93.46 (3)
Au6^x—Au3—Y1	58.78 (3)	Au3—Y1—Au3^iii	159.33 (5)
Au1^ix—Au3—Y1	58.46 (3)	Au5—Y2—Au2^xvii	57.25 (3)
Au3^xiii—Au3—Y1	98.93 (3)	Au5—Y2—Au2^v	57.25 (3)
Y2^vi—Au3—Y1	116.05 (3)	Au2^xvii—Y2—Au2^v	87.50 (5)
Y2^x—Au3—Y1	124.89 (3)	Au5—Y2—Au3^xvi	96.61 (5)
Y2^vii—Au3—Y1	105.37 (3)	Au2^xvii—Y2—Au3^xvi	100.39 (3)
Au4^v—Au4—Au4^vii	120.000 (1)	Au2^v—Y2—Au3^xvi	142.63 (6)
Au4^v—Au4—Au1	113.38 (2)	Au5—Y2—Au3^ii	96.61 (5)
Au4^vii—Au4—Au1	116.43 (2)	Au2^xvii—Y2—Au3^ii	142.63 (6)
Au4^v—Au4—Au1^iii	113.38 (2)	Au2^v—Y2—Au3^ii	100.39 (3)
Au4^vii—Au4—Au1^iii	116.43 (2)	Au3^xvi—Y2—Au3^ii	52.75 (3)
Au1—Au4—Au1^iii	65.23 (2)	Au5—Y2—Au1	101.33 (3)
Au4^v—Au4—Au2^ii	62.122 (16)	Au2^xvii—Y2—Au1	146.31 (5)
Au4^vii—Au4—Au2^ii	115.570 (12)	Au2^v—Y2—Au1	58.949 (16)
Au1—Au4—Au2^ii	63.616 (15)	Au3^xvi—Y2—Au1	108.31 (4)
Au1^iii—Au4—Au2^ii	118.43 (2)	Au3^ii—Y2—Au1	56.516 (19)
Au4^v—Au4—Au2^iv	62.122 (16)	Au5—Y2—Au1^xi	101.33 (3)
Au4^vii—Au4—Au2^iv	115.570 (12)	Au2^xvii—Y2—Au1^xi	58.950 (16)
Au1—Au4—Au2^iv	118.43 (2)	Au2^v—Y2—Au1^xi	146.31 (5)
Au1^iii—Au4—Au2^iv	63.615 (15)	Au3^xvi—Y2—Au1^xi	56.515 (19)
Au2^ii—Au4—Au2^iv	117.28 (3)	Au3^ii—Y2—Au1^xi	108.31 (4)
Au4^v—Au4—Au2^xiv	115.680 (12)	Au1—Y2—Au1^xi	154.07 (6)
Au4^vii—Au4—Au2^xiv	61.827 (16)	Au5—Y2—Au7	150.05 (6)
Au1—Au4—Au2^xiv	120.41 (2)	Au2^xvii—Y2—Au7	103.29 (4)
Au1^iii—Au4—Au2^xiv	65.686 (15)	Au2^v—Y2—Au7	103.29 (4)
Au2^ii—Au4—Au2^xiv	175.71 (3)	Au3^xvi—Y2—Au7	110.11 (5)
Au2^iv—Au4—Au2^xiv	62.795 (16)	Au3^ii—Y2—Au7	110.11 (5)
Au4^v—Au4—Au2^v	115.680 (13)	Au1—Y2—Au7	83.33 (3)
Au4^vii—Au4—Au2^v	61.827 (16)	Au1^xi—Y2—Au7	83.33 (3)
Au1—Au4—Au2^v	65.685 (15)	Au5—Y2—Au3^i	148.61 (4)
Au1^iii—Au4—Au2^v	120.41 (2)	Au2^xvii—Y2—Au3^i	154.12 (5)
Au2^ii—Au4—Au2^v	62.795 (16)	Au2^v—Y2—Au3^i	107.37 (2)
Au2^iv—Au4—Au2^v	175.71 (3)	Au3^xvi—Y2—Au3^i	80.79 (4)
Au2^xiv—Au4—Au2^v	116.77 (3)	Au3^ii—Y2—Au3^i	56.89 (3)
Au4^v—Au4—Y1^v	174.03 (3)	Au1—Y2—Au3^i	51.51 (2)
Au4^vii—Au4—Y1^v	65.97 (3)	Au1^xi—Y2—Au3^i	102.99 (5)
Au1—Au4—Y1^v	61.84 (3)	Au7—Y2—Au3^i	53.38 (3)
Au1^iii—Au4—Y1^v	61.84 (3)	Au5—Y2—Au3^xxiv	148.61 (4)
Au2^ii—Au4—Y1^v	116.188 (17)	Au2^xvii—Y2—Au3^xxiv	107.37 (2)
Au2^iv—Au4—Y1^v	116.188 (17)	Au2^v—Y2—Au3^xxiv	154.12 (5)
Au2^xiv—Au4—Y1^v	66.401 (18)	Au3^xvi—Y2—Au3^xxiv	56.89 (3)
Au2^v—Au4—Y1^v	66.401 (18)	Au3^ii—Y2—Au3^xxiv	80.79 (4)
Au4^v—Au4—Y1^iv	63.42 (3)	Au1—Y2—Au3^xxiv	102.99 (5)
Au4^vii—Au4—Y1^iv	176.58 (3)	Au1^xi—Y2—Au3^xxiv	51.51 (2)
Au1—Au4—Y1^iv	60.86 (3)	Au7—Y2—Au3^xxiv	53.38 (3)
Au1^iii—Au4—Y1^iv	60.86 (3)	Au3^i—Y2—Au3^xxiv	51.53 (3)
Au2^ii—Au4—Y1^iv	65.576 (17)	Au5—Y2—Au3^v	100.55 (5)
Au2^iv—Au4—Y1^iv	65.576 (17)	Au2^xvii—Y2—Au3^v	88.54 (4)
Au2^xiv—Au4—Y1^iv	117.239 (17)	Au2^v—Y2—Au3^v	51.53 (2)
Au2^v—Au4—Y1^iv	117.239 (17)	Au3^xvi—Y2—Au3^v	162.83 (6)
Y1^v—Au4—Y1^iv	110.61 (3)	Au3^ii—Y2—Au3^v	124.90 (2)
Au4^v—Au4—Y3	65.483 (12)	Au1—Y2—Au3^v	68.85 (2)
Au4^vii—Au4—Y3	65.483 (12)	Au1^xi—Y2—Au3^v	118.69 (4)
Au1—Au4—Y3	113.46 (4)	Au7—Y2—Au3^v	53.15 (3)
Au1^iii—Au4—Y3	177.95 (3)	Au3^i—Y2—Au3^v	84.81 (4)
Au2^ii—Au4—Y3	59.59 (3)	Au3^xxiv—Y2—Au3^v	106.53 (5)
Au2^iv—Au4—Y3	116.52 (4)	Au5—Y2—Au3^xvii	100.55 (5)
Au2^xiv—Au4—Y3	116.29 (4)	Au2^xvii—Y2—Au3^xvii	51.53 (2)
Au2^v—Au4—Y3	59.52 (3)	Au2^v—Y2—Au3^xvii	88.54 (4)
Y1^v—Au4—Y3	119.17 (3)	Au3^xvi—Y2—Au3^xvii	124.90 (2)
Y1^iv—Au4—Y3	117.20 (3)	Au3^ii—Y2—Au3^xvii	162.83 (6)
Au4^v—Au4—Y3^xv	65.483 (12)	Au1—Y2—Au3^xvii	118.69 (4)
Au4^vii—Au4—Y3^xv	65.483 (12)	Au1^xi—Y2—Au3^xvii	68.85 (2)
Au1—Au4—Y3^xv	177.95 (3)	Au7—Y2—Au3^xvii	53.15 (3)
Au1^iii—Au4—Y3^xv	113.45 (4)	Au3^i—Y2—Au3^xvii	106.53 (5)
Au2^ii—Au4—Y3^xv	116.52 (4)	Au3^xxiv—Y2—Au3^xvii	84.81 (4)
Au2^iv—Au4—Y3^xv	59.59 (3)	Au3^v—Y2—Au3^xvii	51.11 (3)
Au2^xiv—Au4—Y3^xv	59.52 (3)	Au2—Y3—Au2^ix	115.81 (3)
Au2^v—Au4—Y3^xv	116.29 (4)	Au2—Y3—Au2^xxviii	156.04 (9)
Y1^v—Au4—Y3^xv	119.17 (3)	Au2^ix—Y3—Au2^xxviii	58.564 (11)
Y1^iv—Au4—Y3^xv	117.20 (3)	Au2—Y3—Au2^v	58.564 (11)
Y3—Au4—Y3^xv	67.82 (8)	Au2^ix—Y3—Au2^v	156.04 (9)
Au5^vii—Au5—Au5^v	120.0	Au2^xxviii—Y3—Au2^v	115.81 (3)
Au5^vii—Au5—Au2^xvi	128.67 (3)	Au2—Y3—Au2^vii	58.565 (11)
Au5^v—Au5—Au2^xvi	76.23 (5)	Au2^ix—Y3—Au2^vii	58.564 (11)
Au5^vii—Au5—Au2^ii	128.67 (3)	Au2^xxviii—Y3—Au2^vii	115.81 (3)
Au5^v—Au5—Au2^ii	76.23 (5)	Au2^v—Y3—Au2^vii	115.81 (3)
Au2^xvi—Au5—Au2^ii	101.79 (5)	Au2—Y3—Au2^ii	115.81 (3)
Au5^vii—Au5—Au5^vi	30.0	Au2^ix—Y3—Au2^ii	115.81 (3)
Au5^v—Au5—Au5^vi	90.0	Au2^xxviii—Y3—Au2^ii	58.564 (11)
Au2^xvi—Au5—Au5^vi	125.74 (2)	Au2^v—Y3—Au2^ii	58.564 (11)
Au2^ii—Au5—Au5^vi	125.74 (2)	Au2^vii—Y3—Au2^ii	156.04 (9)
Au5^vii—Au5—Au5^xvi	90.000 (1)	Au2—Y3—Au5^xvi	103.44 (7)
Au5^v—Au5—Au5^xvi	30.0	Au2^ix—Y3—Au5^xvi	51.98 (3)
Au2^xvi—Au5—Au5^xvi	94.93 (5)	Au2^xxviii—Y3—Au5^xvi	53.72 (3)
Au2^ii—Au5—Au5^xvi	94.93 (5)	Au2^v—Y3—Au5^xvi	104.88 (7)
Au5^vi—Au5—Au5^xvi	60.0	Au2^vii—Y3—Au5^xvi	78.24 (5)
Au5^vii—Au5—Y2	111.68 (8)	Au2^ii—Y3—Au5^xvi	81.06 (5)
Au5^v—Au5—Y2	128.32 (8)	Au2—Y3—Au5^xviii	78.24 (5)
Au2^xvi—Au5—Y2	71.90 (3)	Au2^ix—Y3—Au5^xviii	53.72 (3)
Au2^ii—Au5—Y2	71.90 (3)	Au2^xxviii—Y3—Au5^xviii	81.06 (5)
Au5^vi—Au5—Y2	141.68 (8)	Au2^v—Y3—Au5^xviii	103.44 (7)
Au5^xvi—Au5—Y2	158.32 (8)	Au2^vii—Y3—Au5^xviii	51.98 (3)
Au5^vii—Au5—Au2^v	70.41 (5)	Au2^ii—Y3—Au5^xviii	104.88 (7)
Au5^v—Au5—Au2^v	131.18 (2)	Au5^xvi—Y3—Au5^xviii	29.03 (3)
Au2^xvi—Au5—Au2^v	138.15 (5)	Au2—Y3—Au5^v	104.88 (7)
Au2^ii—Au5—Au2^v	64.963 (16)	Au2^ix—Y3—Au5^v	78.24 (5)
Au5^vi—Au5—Au2^v	89.59 (5)	Au2^xxviii—Y3—Au5^v	51.98 (3)
Au5^xvi—Au5—Au2^v	124.51 (3)	Au2^v—Y3—Au5^v	81.06 (5)
Y2—Au5—Au2^v	66.25 (3)	Au2^vii—Y3—Au5^v	103.44 (7)
Au5^vii—Au5—Au2^xvii	70.41 (5)	Au2^ii—Y3—Au5^v	53.72 (3)
Au5^v—Au5—Au2^xvii	131.18 (2)	Au5^xvi—Y3—Au5^v	29.03 (3)
Au2^xvi—Au5—Au2^xvii	64.963 (17)	Au5^xviii—Y3—Au5^v	51.46 (5)
Au2^ii—Au5—Au2^xvii	138.15 (5)	Au2—Y3—Au5^vi	51.98 (3)
Au5^vi—Au5—Au2^xvii	89.59 (5)	Au2^ix—Y3—Au5^vi	81.06 (5)
Au5^xvi—Au5—Au2^xvii	124.51 (3)	Au2^xxviii—Y3—Au5^vi	104.88 (7)
Y2—Au5—Au2^xvii	66.25 (3)	Au2^v—Y3—Au5^vi	78.24 (5)
Au2^v—Au5—Au2^xvii	97.64 (4)	Au2^vii—Y3—Au5^vi	53.72 (3)
Au5^vii—Au5—Y3^xviii	75.483 (13)	Au2^ii—Y3—Au5^vi	103.44 (7)
Au5^v—Au5—Y3^xviii	75.483 (13)	Au5^xvi—Y3—Au5^vi	51.46 (5)
Au2^xvi—Au5—Y3^xviii	61.48 (2)	Au5^xviii—Y3—Au5^vi	29.03 (3)
Au2^ii—Au5—Y3^xviii	149.93 (5)	Au5^v—Y3—Au5^vi	60.18 (6)
Au5^vi—Au5—Y3^xviii	64.27 (2)	Au2—Y3—Au5^vii	53.72 (3)
Au5^xvi—Au5—Y3^xviii	64.27 (3)	Au2^ix—Y3—Au5^vii	104.88 (7)
Y2—Au5—Y3^xviii	119.74 (3)	Au2^xxviii—Y3—Au5^vii	103.44 (7)
Au2^v—Au5—Y3^xviii	144.41 (5)	Au2^v—Y3—Au5^vii	51.98 (3)
Au2^xvii—Au5—Y3^xviii	60.71 (2)	Au2^vii—Y3—Au5^vii	81.06 (5)
Au5^vii—Au5—Y3	75.483 (13)	Au2^ii—Y3—Au5^vii	78.24 (5)
Au5^v—Au5—Y3	75.483 (13)	Au5^xvi—Y3—Au5^vii	60.18 (6)
Au2^xvi—Au5—Y3	149.93 (5)	Au5^xviii—Y3—Au5^vii	51.46 (5)
Au2^ii—Au5—Y3	61.48 (2)	Au5^v—Y3—Au5^vii	51.46 (5)
Au5^vi—Au5—Y3	64.27 (2)	Au5^vi—Y3—Au5^vii	29.03 (3)
Au5^xvi—Au5—Y3	64.27 (2)	Au2—Y3—Au5	81.06 (5)
Y2—Au5—Y3	119.74 (3)	Au2^ix—Y3—Au5	103.44 (7)
Au2^v—Au5—Y3	60.71 (2)	Au2^xxviii—Y3—Au5	78.24 (5)
Au2^xvii—Au5—Y3	144.41 (5)	Au2^v—Y3—Au5	53.72 (3)
Y3^xviii—Au5—Y3	119.82 (6)	Au2^vii—Y3—Au5	104.87 (7)
Au5^vii—Au5—Au5^xviii	60.0	Au2^ii—Y3—Au5	51.98 (3)
Au5^v—Au5—Au5^xviii	60.0	Au5^xvi—Y3—Au5	51.46 (5)
Au2^xvi—Au5—Au5^xviii	112.76 (4)	Au5^xviii—Y3—Au5	60.18 (6)
Au2^ii—Au5—Au5^xviii	112.76 (4)	Au5^v—Y3—Au5	29.03 (3)
Au5^vi—Au5—Au5^xviii	30.0	Au5^vi—Y3—Au5	51.46 (5)
Au5^xvi—Au5—Au5^xviii	30.0	Au5^vii—Y3—Au5	29.03 (3)

Symmetry codes: (i) y, −x+y+1, z; (ii) −y, x−y, z; (iii) x, y, −z+1; (iv) −y, x−y, −z+1; (v) x−y, x, z; (vi) −x+y, −x, −z; (vii) y, −x+y, z; (viii) −x+y, −x, −z+1; (ix) −x+y, −x, z; (x) x−y+1, x, z; (xi) x, y, −z; (xii) −x+1, −y+1, −z; (xiii) −x+1, −y, z; (xiv) x−y, x, −z+1; (xv) −x, −y, −z+1; (xvi) −y, x−y, −z; (xvii) x−y, x, −z; (xviii) −x, −y, −z; (xix) −y+1, x−y+1, z; (xx) −x+y, −x+1, z; (xxi) −x+1, −y+1, z; (xxii) −x+1, −y+1, −z+1; (xxiii) −x+y, −x+1, −z; (xxiv) y, −x+y+1, −z; (xxv) −y+1, x−y+1, −z; (xxvi) y, −x+y, −z+1; (xxvii) x−y+1, x, −z+1; (xxviii) −x, −y, z.