In the title compound, C
35H
33FN
3O
2P, the coordination environment around the P atom is approximately tetrahedral and the P(O) and C(O) groups are
anti with respect to each other. In the crystalline state, the molecules form centrosymmetric dimers
via pairs of linear N—H
O hydrogen bonds.
Supporting information
CCDC reference: 643683
Key indicators
- Single-crystal X-ray study
- T = 100 K
- Mean (C-C) = 0.002 Å
- R factor = 0.037
- wR factor = 0.104
- Data-to-parameter ratio = 23.0
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ?
PLAT154_ALERT_1_C The su's on the Cell Angles are Equal (x 10000) 100 Deg.
PLAT180_ALERT_3_C Check Cell Rounding: # of Values Ending with 0 = 3
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
3 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
0 ALERT type 2 Indicator that the structure model may be wrong or deficient
1 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
0 ALERT type 5 Informative message, check
Data collection: APEX2 (Bruker, 2005); cell refinement: APEX2; data reduction: APEX2; program(s) used to solve structure: SHELXTL (Sheldrick, 1998); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
N,
N,
N',
N'-Tetrabenzyl-
N''-(2-fluorobenzoyl)phosphoric diamide
top
Crystal data top
C35H33FN3O2P | Z = 2 |
Mr = 577.61 | F(000) = 608 |
Triclinic, P1 | Dx = 1.323 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.71073 Å |
a = 10.7637 (5) Å | Cell parameters from 9484 reflections |
b = 11.3489 (5) Å | θ = 2.3–34.6° |
c = 14.0195 (6) Å | µ = 0.14 mm−1 |
α = 66.535 (1)° | T = 100 K |
β = 74.514 (1)° | Prism, colourless |
γ = 68.849 (1)° | 0.50 × 0.30 × 0.30 mm |
V = 1449.81 (11) Å3 | |
Data collection top
Bruker SMART APEXII CCD area-detector diffractometer | 8723 independent reflections |
Radiation source: fine-focus sealed tube | 7598 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.021 |
Detector resolution: 0 pixels mm-1 | θmax = 30.5°, θmin = 1.6° |
φ and ω scans | h = −15→15 |
Absorption correction: multi-scan (APEX2; Bruker, 2005) | k = −16→16 |
Tmin = 0.934, Tmax = 0.960 | l = −20→19 |
16846 measured reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.037 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.104 | H-atom parameters constrained |
S = 1.04 | w = 1/[σ2(Fo2) + (0.0551P)2 + 0.4604P] where P = (Fo2 + 2Fc2)/3 |
8723 reflections | (Δ/σ)max = 0.001 |
380 parameters | Δρmax = 0.48 e Å−3 |
0 restraints | Δρmin = −0.41 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
P1 | −0.00611 (2) | 0.60122 (2) | 0.322032 (18) | 0.01041 (6) | |
F1 | 0.01689 (7) | 0.86833 (7) | 0.47765 (6) | 0.02568 (15) | |
O1 | −0.07650 (7) | 0.50796 (7) | 0.40701 (5) | 0.01426 (14) | |
O2 | 0.17037 (8) | 0.79316 (7) | 0.24406 (6) | 0.01719 (15) | |
N1 | 0.08637 (8) | 0.63593 (8) | 0.38173 (6) | 0.01262 (15) | |
H1 | 0.0836 | 0.5881 | 0.4525 | 0.021 (4)* | |
N2 | −0.11725 (8) | 0.73670 (8) | 0.26045 (6) | 0.01217 (15) | |
N3 | 0.10064 (8) | 0.54619 (8) | 0.23063 (6) | 0.01209 (15) | |
C1 | 0.15730 (10) | 0.72823 (9) | 0.33756 (8) | 0.01270 (17) | |
C2 | 0.22390 (10) | 0.74026 (10) | 0.41378 (8) | 0.01342 (17) | |
C3 | 0.36140 (11) | 0.68153 (12) | 0.41760 (9) | 0.0205 (2) | |
H3A | 0.4141 | 0.6322 | 0.3722 | 0.025* | |
C4 | 0.42203 (12) | 0.69457 (13) | 0.48751 (9) | 0.0243 (2) | |
H4A | 0.5155 | 0.6527 | 0.4907 | 0.029* | |
C5 | 0.34598 (12) | 0.76879 (12) | 0.55280 (9) | 0.0226 (2) | |
H5A | 0.3879 | 0.7784 | 0.5999 | 0.027* | |
C6 | 0.20900 (12) | 0.82896 (11) | 0.54944 (9) | 0.0215 (2) | |
H6A | 0.1565 | 0.8809 | 0.5930 | 0.026* | |
C7 | 0.15096 (11) | 0.81142 (10) | 0.48116 (8) | 0.01673 (19) | |
C8 | −0.08551 (10) | 0.82137 (9) | 0.15174 (7) | 0.01353 (17) | |
H8A | −0.1216 | 0.7996 | 0.1048 | 0.016* | |
H8B | 0.0136 | 0.7988 | 0.1323 | 0.016* | |
C9 | −0.14095 (9) | 0.97076 (9) | 0.13254 (8) | 0.01293 (17) | |
C10 | −0.13130 (11) | 1.02893 (11) | 0.20005 (8) | 0.0193 (2) | |
H10A | −0.0935 | 0.9737 | 0.2629 | 0.023* | |
C11 | −0.17690 (12) | 1.16786 (11) | 0.17578 (9) | 0.0214 (2) | |
H11A | −0.1697 | 1.2068 | 0.2221 | 0.026* | |
C12 | −0.23285 (11) | 1.24969 (10) | 0.08419 (9) | 0.0184 (2) | |
H12A | −0.2647 | 1.3442 | 0.0682 | 0.022* | |
C13 | −0.24192 (11) | 1.19245 (10) | 0.01623 (8) | 0.0187 (2) | |
H13A | −0.2792 | 1.2479 | −0.0468 | 0.022* | |
C14 | −0.19628 (11) | 1.05373 (10) | 0.04058 (8) | 0.01651 (19) | |
H14A | −0.2030 | 1.0151 | −0.0062 | 0.020* | |
C15 | −0.26184 (10) | 0.75816 (10) | 0.30283 (8) | 0.01502 (18) | |
H15A | −0.3044 | 0.8543 | 0.2944 | 0.018* | |
H15B | −0.2715 | 0.7064 | 0.3789 | 0.018* | |
C16 | −0.33509 (10) | 0.71608 (11) | 0.24872 (8) | 0.01583 (18) | |
C17 | −0.42547 (11) | 0.81170 (12) | 0.18089 (9) | 0.0211 (2) | |
H17A | −0.4435 | 0.9042 | 0.1698 | 0.025* | |
C18 | −0.48975 (12) | 0.77294 (13) | 0.12909 (10) | 0.0257 (2) | |
H18A | −0.5517 | 0.8388 | 0.0833 | 0.031* | |
C19 | −0.46325 (12) | 0.63800 (13) | 0.14445 (9) | 0.0242 (2) | |
H19A | −0.5050 | 0.6117 | 0.1076 | 0.029* | |
C20 | −0.37546 (11) | 0.54138 (12) | 0.21383 (10) | 0.0221 (2) | |
H20A | −0.3588 | 0.4489 | 0.2255 | 0.027* | |
C21 | −0.31202 (11) | 0.58009 (11) | 0.26620 (9) | 0.0186 (2) | |
H21A | −0.2528 | 0.5138 | 0.3140 | 0.022* | |
C22 | 0.24813 (10) | 0.50280 (9) | 0.22219 (8) | 0.01398 (18) | |
H22A | 0.2746 | 0.5569 | 0.2497 | 0.017* | |
H22B | 0.2861 | 0.5236 | 0.1468 | 0.017* | |
C23 | 0.31258 (10) | 0.35573 (10) | 0.27885 (8) | 0.01473 (18) | |
C24 | 0.27158 (11) | 0.29335 (11) | 0.38510 (9) | 0.0191 (2) | |
H24A | 0.2034 | 0.3441 | 0.4242 | 0.023* | |
C25 | 0.33003 (12) | 0.15728 (11) | 0.43404 (9) | 0.0229 (2) | |
H25A | 0.3004 | 0.1152 | 0.5060 | 0.027* | |
C26 | 0.43160 (12) | 0.08265 (11) | 0.37797 (10) | 0.0236 (2) | |
H26A | 0.4704 | −0.0105 | 0.4112 | 0.028* | |
C27 | 0.47601 (12) | 0.14484 (11) | 0.27321 (10) | 0.0228 (2) | |
H27A | 0.5471 | 0.0949 | 0.2351 | 0.027* | |
C28 | 0.41610 (11) | 0.28075 (11) | 0.22400 (9) | 0.0183 (2) | |
H28A | 0.4463 | 0.3227 | 0.1521 | 0.022* | |
C29 | 0.04617 (10) | 0.52403 (10) | 0.15486 (8) | 0.01443 (18) | |
H29A | 0.0750 | 0.5795 | 0.0828 | 0.017* | |
H29B | −0.0534 | 0.5543 | 0.1684 | 0.017* | |
C30 | 0.09136 (10) | 0.37904 (10) | 0.16091 (8) | 0.01417 (18) | |
C31 | 0.06868 (11) | 0.27892 (10) | 0.25600 (8) | 0.01788 (19) | |
H31A | 0.0192 | 0.3026 | 0.3161 | 0.021* | |
C32 | 0.11804 (12) | 0.14492 (11) | 0.26322 (10) | 0.0231 (2) | |
H32A | 0.1035 | 0.0773 | 0.3285 | 0.028* | |
C33 | 0.18871 (12) | 0.10924 (12) | 0.17518 (10) | 0.0249 (2) | |
H33A | 0.2225 | 0.0175 | 0.1802 | 0.030* | |
C34 | 0.20932 (12) | 0.20839 (12) | 0.08026 (10) | 0.0238 (2) | |
H34A | 0.2565 | 0.1846 | 0.0198 | 0.029* | |
C35 | 0.16107 (11) | 0.34321 (11) | 0.07293 (9) | 0.0190 (2) | |
H35A | 0.1759 | 0.4107 | 0.0076 | 0.023* | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
P1 | 0.01109 (11) | 0.01032 (11) | 0.00963 (11) | −0.00349 (8) | −0.00258 (8) | −0.00211 (8) |
F1 | 0.0194 (3) | 0.0294 (4) | 0.0278 (4) | 0.0030 (3) | −0.0053 (3) | −0.0168 (3) |
O1 | 0.0157 (3) | 0.0156 (3) | 0.0118 (3) | −0.0078 (3) | −0.0027 (2) | −0.0015 (3) |
O2 | 0.0224 (4) | 0.0161 (3) | 0.0134 (3) | −0.0088 (3) | −0.0036 (3) | −0.0017 (3) |
N1 | 0.0147 (4) | 0.0138 (4) | 0.0106 (3) | −0.0065 (3) | −0.0033 (3) | −0.0021 (3) |
N2 | 0.0103 (3) | 0.0122 (3) | 0.0112 (3) | −0.0023 (3) | −0.0019 (3) | −0.0018 (3) |
N3 | 0.0112 (3) | 0.0121 (3) | 0.0132 (4) | −0.0019 (3) | −0.0031 (3) | −0.0050 (3) |
C1 | 0.0122 (4) | 0.0120 (4) | 0.0142 (4) | −0.0031 (3) | −0.0018 (3) | −0.0052 (3) |
C2 | 0.0152 (4) | 0.0144 (4) | 0.0122 (4) | −0.0075 (3) | −0.0015 (3) | −0.0035 (3) |
C3 | 0.0151 (5) | 0.0293 (5) | 0.0196 (5) | −0.0070 (4) | −0.0010 (4) | −0.0114 (4) |
C4 | 0.0176 (5) | 0.0371 (6) | 0.0218 (5) | −0.0122 (5) | −0.0041 (4) | −0.0087 (5) |
C5 | 0.0301 (6) | 0.0280 (5) | 0.0167 (5) | −0.0177 (5) | −0.0061 (4) | −0.0045 (4) |
C6 | 0.0307 (6) | 0.0207 (5) | 0.0168 (5) | −0.0094 (4) | −0.0033 (4) | −0.0084 (4) |
C7 | 0.0177 (5) | 0.0160 (4) | 0.0166 (4) | −0.0044 (4) | −0.0027 (4) | −0.0058 (4) |
C8 | 0.0155 (4) | 0.0113 (4) | 0.0109 (4) | −0.0013 (3) | −0.0034 (3) | −0.0022 (3) |
C9 | 0.0117 (4) | 0.0119 (4) | 0.0133 (4) | −0.0024 (3) | −0.0027 (3) | −0.0026 (3) |
C10 | 0.0242 (5) | 0.0164 (5) | 0.0167 (5) | −0.0013 (4) | −0.0088 (4) | −0.0053 (4) |
C11 | 0.0274 (5) | 0.0174 (5) | 0.0212 (5) | −0.0031 (4) | −0.0069 (4) | −0.0093 (4) |
C12 | 0.0189 (5) | 0.0126 (4) | 0.0203 (5) | −0.0035 (4) | −0.0017 (4) | −0.0039 (4) |
C13 | 0.0219 (5) | 0.0135 (4) | 0.0176 (5) | −0.0041 (4) | −0.0075 (4) | 0.0001 (4) |
C14 | 0.0202 (5) | 0.0134 (4) | 0.0160 (4) | −0.0045 (4) | −0.0070 (4) | −0.0026 (3) |
C15 | 0.0111 (4) | 0.0173 (4) | 0.0161 (4) | −0.0026 (3) | −0.0011 (3) | −0.0069 (4) |
C16 | 0.0110 (4) | 0.0201 (5) | 0.0163 (4) | −0.0046 (3) | −0.0004 (3) | −0.0070 (4) |
C17 | 0.0167 (5) | 0.0226 (5) | 0.0227 (5) | −0.0056 (4) | −0.0054 (4) | −0.0048 (4) |
C18 | 0.0201 (5) | 0.0329 (6) | 0.0246 (6) | −0.0089 (5) | −0.0092 (4) | −0.0051 (5) |
C19 | 0.0193 (5) | 0.0370 (6) | 0.0233 (5) | −0.0131 (5) | −0.0024 (4) | −0.0128 (5) |
C20 | 0.0173 (5) | 0.0266 (5) | 0.0270 (5) | −0.0081 (4) | −0.0005 (4) | −0.0137 (4) |
C21 | 0.0143 (4) | 0.0208 (5) | 0.0212 (5) | −0.0043 (4) | −0.0023 (4) | −0.0083 (4) |
C22 | 0.0116 (4) | 0.0122 (4) | 0.0162 (4) | −0.0025 (3) | −0.0012 (3) | −0.0041 (3) |
C23 | 0.0130 (4) | 0.0125 (4) | 0.0186 (5) | −0.0022 (3) | −0.0055 (3) | −0.0044 (3) |
C24 | 0.0186 (5) | 0.0172 (5) | 0.0177 (5) | −0.0018 (4) | −0.0047 (4) | −0.0038 (4) |
C25 | 0.0249 (5) | 0.0178 (5) | 0.0206 (5) | −0.0037 (4) | −0.0092 (4) | 0.0004 (4) |
C26 | 0.0239 (5) | 0.0138 (4) | 0.0312 (6) | −0.0004 (4) | −0.0139 (5) | −0.0038 (4) |
C27 | 0.0203 (5) | 0.0162 (5) | 0.0307 (6) | 0.0016 (4) | −0.0075 (4) | −0.0102 (4) |
C28 | 0.0160 (5) | 0.0158 (4) | 0.0215 (5) | −0.0019 (4) | −0.0030 (4) | −0.0068 (4) |
C29 | 0.0172 (4) | 0.0144 (4) | 0.0122 (4) | −0.0036 (3) | −0.0041 (3) | −0.0046 (3) |
C30 | 0.0151 (4) | 0.0147 (4) | 0.0155 (4) | −0.0046 (3) | −0.0036 (3) | −0.0066 (3) |
C31 | 0.0203 (5) | 0.0167 (4) | 0.0178 (5) | −0.0074 (4) | −0.0006 (4) | −0.0065 (4) |
C32 | 0.0277 (6) | 0.0162 (5) | 0.0260 (5) | −0.0093 (4) | −0.0034 (4) | −0.0053 (4) |
C33 | 0.0259 (5) | 0.0190 (5) | 0.0364 (6) | −0.0067 (4) | −0.0047 (5) | −0.0155 (5) |
C34 | 0.0251 (5) | 0.0264 (5) | 0.0276 (6) | −0.0078 (4) | −0.0002 (4) | −0.0189 (5) |
C35 | 0.0222 (5) | 0.0215 (5) | 0.0168 (5) | −0.0079 (4) | −0.0013 (4) | −0.0093 (4) |
Geometric parameters (Å, º) top
P1—O1 | 1.4853 (7) | C16—C17 | 1.3923 (15) |
P1—N1 | 1.6843 (9) | C16—C21 | 1.3993 (15) |
P1—N2 | 1.6454 (8) | C17—C18 | 1.3935 (16) |
P1—N3 | 1.6388 (8) | C17—H17A | 0.9500 |
F1—C7 | 1.3573 (12) | C18—C19 | 1.3886 (18) |
O2—C1 | 1.2199 (12) | C18—H18A | 0.9500 |
N1—C1 | 1.3681 (12) | C19—C20 | 1.3911 (17) |
N1—H1 | 0.9200 | C19—H19A | 0.9500 |
N2—C8 | 1.4681 (12) | C20—C21 | 1.3927 (15) |
N2—C15 | 1.4773 (12) | C20—H20A | 0.9500 |
N3—C22 | 1.4693 (12) | C21—H21A | 0.9500 |
N3—C29 | 1.4789 (12) | C22—C23 | 1.5169 (13) |
C1—C2 | 1.5068 (13) | C22—H22A | 0.9900 |
C2—C7 | 1.3838 (14) | C22—H22B | 0.9900 |
C2—C3 | 1.3928 (15) | C23—C28 | 1.3915 (14) |
C3—C4 | 1.3910 (16) | C23—C24 | 1.3963 (15) |
C3—H3A | 0.9500 | C24—C25 | 1.3917 (15) |
C4—C5 | 1.3906 (17) | C24—H24A | 0.9500 |
C4—H4A | 0.9500 | C25—C26 | 1.3905 (17) |
C5—C6 | 1.3883 (17) | C25—H25A | 0.9500 |
C5—H5A | 0.9500 | C26—C27 | 1.3880 (18) |
C6—C7 | 1.3809 (15) | C26—H26A | 0.9500 |
C6—H6A | 0.9500 | C27—C28 | 1.3939 (15) |
C8—C9 | 1.5150 (13) | C27—H27A | 0.9500 |
C8—H8A | 0.9900 | C28—H28A | 0.9500 |
C8—H8B | 0.9900 | C29—C30 | 1.5115 (13) |
C9—C10 | 1.3936 (14) | C29—H29A | 0.9900 |
C9—C14 | 1.3935 (14) | C29—H29B | 0.9900 |
C10—C11 | 1.3950 (15) | C30—C35 | 1.3910 (14) |
C10—H10A | 0.9500 | C30—C31 | 1.3956 (14) |
C11—C12 | 1.3906 (16) | C31—C32 | 1.3886 (15) |
C11—H11A | 0.9500 | C31—H31A | 0.9500 |
C12—C13 | 1.3883 (15) | C32—C33 | 1.3931 (17) |
C12—H12A | 0.9500 | C32—H32A | 0.9500 |
C13—C14 | 1.3928 (14) | C33—C34 | 1.3843 (18) |
C13—H13A | 0.9500 | C33—H33A | 0.9500 |
C14—H14A | 0.9500 | C34—C35 | 1.3969 (15) |
C15—C16 | 1.5182 (14) | C34—H34A | 0.9500 |
C15—H15A | 0.9900 | C35—H35A | 0.9500 |
C15—H15B | 0.9900 | | |
| | | |
O1—P1—N1 | 105.78 (4) | C17—C16—C21 | 119.08 (10) |
O1—P1—N2 | 109.75 (4) | C17—C16—C15 | 120.70 (10) |
O1—P1—N3 | 117.82 (4) | C21—C16—C15 | 120.21 (9) |
N3—P1—N2 | 106.08 (4) | C16—C17—C18 | 120.57 (11) |
N3—P1—N1 | 105.30 (4) | C16—C17—H17A | 119.7 |
N2—P1—N1 | 112.15 (4) | C18—C17—H17A | 119.7 |
C1—N1—P1 | 127.33 (7) | C19—C18—C17 | 119.99 (11) |
C8—N2—C15 | 115.85 (8) | C19—C18—H18A | 120.0 |
C8—N2—P1 | 122.67 (6) | C17—C18—H18A | 120.0 |
C15—N2—P1 | 119.68 (7) | C18—C19—C20 | 119.95 (11) |
C22—N3—C29 | 115.42 (8) | C18—C19—H19A | 120.0 |
C22—N3—P1 | 126.22 (7) | C20—C19—H19A | 120.0 |
C29—N3—P1 | 118.05 (6) | C21—C20—C19 | 120.03 (11) |
C1—N1—H1 | 119.1 | C21—C20—H20A | 120.0 |
P1—N1—H1 | 113.5 | C19—C20—H20A | 120.0 |
O2—C1—N1 | 123.79 (9) | C20—C21—C16 | 120.33 (10) |
O2—C1—C2 | 121.86 (9) | C20—C21—H21A | 119.8 |
N1—C1—C2 | 114.31 (8) | C16—C21—H21A | 119.8 |
C7—C2—C3 | 117.87 (9) | N3—C22—C23 | 116.30 (8) |
C7—C2—C1 | 121.17 (9) | N3—C22—H22A | 108.2 |
C3—C2—C1 | 120.96 (9) | C23—C22—H22A | 108.2 |
C4—C3—C2 | 120.44 (10) | N3—C22—H22B | 108.2 |
C4—C3—H3A | 119.8 | C23—C22—H22B | 108.2 |
C2—C3—H3A | 119.8 | H22A—C22—H22B | 107.4 |
C5—C4—C3 | 120.11 (11) | C28—C23—C24 | 118.87 (9) |
C5—C4—H4A | 119.9 | C28—C23—C22 | 119.34 (9) |
C3—C4—H4A | 119.9 | C24—C23—C22 | 121.79 (9) |
C6—C5—C4 | 120.23 (10) | C25—C24—C23 | 120.38 (10) |
C6—C5—H5A | 119.9 | C25—C24—H24A | 119.8 |
C4—C5—H5A | 119.9 | C23—C24—H24A | 119.8 |
C7—C6—C5 | 118.35 (10) | C24—C25—C26 | 120.26 (11) |
C7—C6—H6A | 120.8 | C24—C25—H25A | 119.9 |
C5—C6—H6A | 120.8 | C26—C25—H25A | 119.9 |
F1—C7—C6 | 119.15 (9) | C27—C26—C25 | 119.72 (10) |
F1—C7—C2 | 117.87 (9) | C27—C26—H26A | 120.1 |
C6—C7—C2 | 122.97 (10) | C25—C26—H26A | 120.1 |
N2—C8—C9 | 114.54 (8) | C26—C27—C28 | 119.90 (10) |
N2—C8—H8A | 108.6 | C26—C27—H27A | 120.1 |
C9—C8—H8A | 108.6 | C28—C27—H27A | 120.1 |
N2—C8—H8B | 108.6 | C23—C28—C27 | 120.82 (10) |
C9—C8—H8B | 108.6 | C23—C28—H28A | 119.6 |
H8A—C8—H8B | 107.6 | C27—C28—H28A | 119.6 |
C10—C9—C14 | 118.86 (9) | N3—C29—C30 | 113.15 (8) |
C10—C9—C8 | 122.48 (9) | N3—C29—H29A | 108.9 |
C14—C9—C8 | 118.54 (9) | C30—C29—H29A | 108.9 |
C9—C10—C11 | 120.32 (10) | N3—C29—H29B | 108.9 |
C9—C10—H10A | 119.8 | C30—C29—H29B | 108.9 |
C11—C10—H10A | 119.8 | H29A—C29—H29B | 107.8 |
C12—C11—C10 | 120.36 (10) | C35—C30—C31 | 119.22 (9) |
C12—C11—H11A | 119.8 | C35—C30—C29 | 120.39 (9) |
C10—C11—H11A | 119.8 | C31—C30—C29 | 120.32 (9) |
C11—C12—C13 | 119.61 (10) | C32—C31—C30 | 120.33 (10) |
C11—C12—H12A | 120.2 | C32—C31—H31A | 119.8 |
C13—C12—H12A | 120.2 | C30—C31—H31A | 119.8 |
C12—C13—C14 | 119.93 (10) | C31—C32—C33 | 120.32 (11) |
C12—C13—H13A | 120.0 | C31—C32—H32A | 119.8 |
C14—C13—H13A | 120.0 | C33—C32—H32A | 119.8 |
C13—C14—C9 | 120.91 (10) | C34—C33—C32 | 119.52 (10) |
C13—C14—H14A | 119.5 | C34—C33—H33A | 120.2 |
C9—C14—H14A | 119.5 | C32—C33—H33A | 120.2 |
N2—C15—C16 | 112.62 (8) | C33—C34—C35 | 120.34 (10) |
N2—C15—H15A | 109.1 | C33—C34—H34A | 119.8 |
C16—C15—H15A | 109.1 | C35—C34—H34A | 119.8 |
N2—C15—H15B | 109.1 | C30—C35—C34 | 120.25 (10) |
C16—C15—H15B | 109.1 | C30—C35—H35A | 119.9 |
H15A—C15—H15B | 107.8 | C34—C35—H35A | 119.9 |
| | | |
O1—P1—N1—C1 | −172.49 (8) | C11—C12—C13—C14 | 0.62 (16) |
N3—P1—N1—C1 | 62.05 (9) | C12—C13—C14—C9 | −0.15 (16) |
N2—P1—N1—C1 | −52.87 (10) | C10—C9—C14—C13 | −0.29 (15) |
O1—P1—N2—C8 | −155.48 (7) | C8—C9—C14—C13 | −176.44 (9) |
N3—P1—N2—C8 | −27.20 (9) | C8—N2—C15—C16 | 67.09 (11) |
N1—P1—N2—C8 | 87.25 (8) | P1—N2—C15—C16 | −98.05 (9) |
O1—P1—N2—C15 | 8.61 (9) | N2—C15—C16—C17 | −108.57 (11) |
N3—P1—N2—C15 | 136.88 (7) | N2—C15—C16—C21 | 71.18 (12) |
N1—P1—N2—C15 | −108.66 (8) | C21—C16—C17—C18 | −1.53 (16) |
O1—P1—N3—C22 | −102.89 (8) | C15—C16—C17—C18 | 178.22 (10) |
N2—P1—N3—C22 | 133.77 (8) | C16—C17—C18—C19 | −0.39 (18) |
N1—P1—N3—C22 | 14.71 (9) | C17—C18—C19—C20 | 1.83 (18) |
O1—P1—N3—C29 | 70.36 (8) | C18—C19—C20—C21 | −1.34 (17) |
N2—P1—N3—C29 | −52.99 (8) | C19—C20—C21—C16 | −0.59 (16) |
N1—P1—N3—C29 | −172.05 (7) | C17—C16—C21—C20 | 2.01 (15) |
P1—N1—C1—O2 | −5.36 (15) | C15—C16—C21—C20 | −177.73 (9) |
P1—N1—C1—C2 | 176.89 (7) | C29—N3—C22—C23 | −83.94 (10) |
O2—C1—C2—C7 | 103.88 (12) | P1—N3—C22—C23 | 89.46 (10) |
N1—C1—C2—C7 | −78.33 (12) | N3—C22—C23—C28 | 127.80 (10) |
O2—C1—C2—C3 | −75.23 (13) | N3—C22—C23—C24 | −52.69 (13) |
N1—C1—C2—C3 | 102.56 (11) | C28—C23—C24—C25 | −2.38 (16) |
C7—C2—C3—C4 | 0.15 (16) | C22—C23—C24—C25 | 178.11 (10) |
C1—C2—C3—C4 | 179.29 (10) | C23—C24—C25—C26 | 1.15 (18) |
C2—C3—C4—C5 | −1.27 (18) | C24—C25—C26—C27 | 0.96 (18) |
C3—C4—C5—C6 | 0.73 (18) | C25—C26—C27—C28 | −1.80 (18) |
C4—C5—C6—C7 | 0.90 (17) | C24—C23—C28—C27 | 1.54 (16) |
C5—C6—C7—F1 | 179.30 (10) | C22—C23—C28—C27 | −178.94 (10) |
C5—C6—C7—C2 | −2.10 (16) | C26—C27—C28—C23 | 0.54 (17) |
C3—C2—C7—F1 | −179.81 (9) | C22—N3—C29—C30 | 57.17 (11) |
C1—C2—C7—F1 | 1.05 (14) | P1—N3—C29—C30 | −116.80 (8) |
C3—C2—C7—C6 | 1.57 (16) | N3—C29—C30—C35 | −121.69 (10) |
C1—C2—C7—C6 | −177.57 (9) | N3—C29—C30—C31 | 55.54 (12) |
C15—N2—C8—C9 | 57.85 (11) | C35—C30—C31—C32 | 1.56 (16) |
P1—N2—C8—C9 | −137.49 (8) | C29—C30—C31—C32 | −175.70 (10) |
N2—C8—C9—C10 | 45.21 (13) | C30—C31—C32—C33 | −1.09 (17) |
N2—C8—C9—C14 | −138.78 (9) | C31—C32—C33—C34 | −0.07 (18) |
C14—C9—C10—C11 | 0.26 (16) | C32—C33—C34—C35 | 0.75 (18) |
C8—C9—C10—C11 | 176.25 (10) | C31—C30—C35—C34 | −0.88 (16) |
C9—C10—C11—C12 | 0.21 (17) | C29—C30—C35—C34 | 176.38 (10) |
C10—C11—C12—C13 | −0.65 (17) | C33—C34—C35—C30 | −0.28 (18) |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
N1—H1···O1i | 0.92 | 1.83 | 2.7487 (10) | 179 |
Symmetry code: (i) −x, −y+1, −z+1. |