Figure 11
(a) Near-edge X-ray excitation spectra of [(TPP)Fe]2O recorded by tuning the crystal analyzer to the maximum intensity of either the fluorescence line or its satellite. Note the different intensities and location of the pre-edge structure. The excitation spectrum obtained by recording the total fluorescence yield is also shown for reference. (b) High-resolution emission spectrum of [(TPP)Fe]2O in the energy range of the fluorescence line. Note the presence of the spin-polarized satellite. |